JP2003113024A - Oily cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an oily cosmetic which gives scarcely sticky makeup films having excellent gloss, has no smell, scarcely has a heavy touch, has excellent shape retainability, such as stickiness and makeup sustainability, to applied sites, excellent adhesiveness, and excellent temporal stability, and has excellent transparency, when the cosmetic is transparent. SOLUTION: This oily cosmetic is characterized by containing (a) 0.1 to 20% of a dextrin fatty acid ester, (b) 46 to 95% of diisostearyl malate, and preferably further (c) a liquid olefin polymer in a smaller amount than the amount of the component (b).

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an oil-based cosmetic composition, which is excellent in gloss of a cosmetic film, has no odor, has a heavy feeling of use and little stickiness of the cosmetic film, shape retention, adhesiveness, and stability over time. It provides an excellent oily cosmetic composition.

[0002]

2. Description of the Related Art Conventionally, many oily cosmetics have improved the gloss of a cosmetic film by highly blending a liquid olefin polymer represented by polybutene or heavy liquid isoparaffin. Among them, regarding oily cosmetics having a transparent appearance, a technique of gelling (solidifying) the oily agent with dextrin fatty acid ester, 12-hydroxystearic acid or the like is disclosed. (JP-A-9-23
No. 5210)

[0003]

However, there is a limit to the production of the gloss of the cosmetic film by the liquid olefin polymer. Furthermore, since some of them have a unique raw material odor, they may be accompanied by an unpleasant odor when mixed in a high amount,
In addition, since the viscosity is extremely high, there is a drawback that the usability becomes extremely heavy. In addition, since the dextrin fatty acid ester has a low gelling power to the liquid olefin polymer, the shape retention of the system and the stability over time can be ensured unless a liquid oil capable of suitably gelling the dextrin fatty acid ester is used together. There wasn't.

[0004]

Means for Solving the Problems As a result of intensive studies for solving the above problems, the present inventors have found that the component (a) dextrin fatty acid ester is 0.1 to 20% by mass (hereinafter simply referred to as “%”). .) And component (b) of diisostearyl malate in an amount of 46 to 95%, the cosmetic film has excellent gloss, has no odor, has a heavy feeling of use and less stickiness of the cosmetic film, shape retention, and an applied part. It was found that an oil-based cosmetic having excellent adhesion to skin, adhesion such as makeup lasting, and stability over time can be obtained, and further, that cosmetics having a transparent feeling have excellent transparency, and completed the present invention. did. That is, the present invention comprises 0.1 to 20% of the component (a) dextrin fatty acid ester,
The present invention provides an oily cosmetic characterized by containing component (b) diisostearyl malate in an amount of 46 to 95%.

[0005]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below.
As the dextrin fatty acid ester of the component (a) used in the present invention, an ester of dextrin and a higher fatty acid having 12 to 22 carbon atoms is used, and specifically, dextrin laurate, dextrin myristate, dextrin palmitate, Examples thereof include stearic acid dextrin, behenic acid dextrin, coconut oil fatty acid dextrin, palmitic acid / 2-ethylhexanoic acid dextrin.
Commercially available products are "Leopearl KL" and "Leopearl T".
L ”,“ Leopearl TT ”(both manufactured by Chiba Flour Milling Co., Ltd.) and the like can be exemplified. Moreover, these can use 1 type (s) or 2 or more types as needed. The amount of the dextrin fatty acid ester as the component (a) used in the present invention is 0.
It is 1 to 20%, preferably 1 to 15%. If the content is less than 0.1%, the shape retention, adhesion and stability with time are not good, and if it exceeds 20%, good gloss, transparency and usability cannot be obtained.

The component (b), diisostearyl malate, used in the present invention comprises malic acid and a diester of 5,7,7-trimethyl-2- (1,3,3-trimethylbutyl) -octanol. Although it is a colorless to pale yellow transparent viscous liquid oil, it is a highly polar liquid oil. As a commercially available product, "Cosmol 222" (manufactured by Nisshin Oil Co., Ltd.)
Etc. can be illustrated. The amount of component (b), diisostearyl malate, used in the present invention is 46 to 95%, preferably 50 to 80%. When the content is less than 46%, the gloss and shape retention are not good, and when the content exceeds 95%, good shape retention and stability with time cannot be obtained.

In the oily cosmetic of the present invention, the adhesiveness is remarkably improved by blending the liquid olefin polymer as the component (c). The liquid olefin polymer as the component (c) is a liquid oil obtained by copolymerizing olefins (ethylene series hydrocarbons), such as polybutene obtained by polymerizing a mixed gas of butane and butene, and a heavy fluid obtained by further hydrogenating it. Examples include isoparaffin and the like. However, when they are blended in an amount exceeding the amount of the component (b), diisostearyl malate, there is a drawback that an unpleasant odor is accompanied and the usability becomes significantly heavy. Therefore, the blending amount must be smaller than that of the component (c). There is.

The cosmetics of the present invention may contain various components other than the above-mentioned essential components such as oily components, powders, surfactants, ultraviolet absorbers, etc., if necessary, to the extent that the effects of the present invention are not impaired. Moisturizer, film-forming agent, anti-fading agent, antioxidant,
An antifoaming agent, a beauty ingredient, an antiseptic, a fragrance and the like can be appropriately added in order to impart various effects.

Oily components used for the purpose of ensuring good usability and stability over time include the origins of animal oils, vegetable oils, synthetic oils, etc., and the properties of solid oils, semi-solid oils, liquid oils, volatile oils, etc. Hydrocarbons, fats and oils, waxes, hydrogenated oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine-based oils, lanolin derivatives, oily gelling agents, etc. To be Specifically, liquid paraffin, squalane, petrolatum, polyethylene wax, ethylene-propylene copolymer, paraffin wax,
Hydrocarbons such as montan wax and Fischer-Tropsch wax, oils and fats such as sorghum, olive oil, castor oil, jojoba oil, mink oil, macadamian nut oil, waxes such as beeswax, gay wax, carnauba wax and candelilla wax, Cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, polyglyceryl diisostearate, pentaerythritol rosinate, neopentyl glycol dioctanoate, cholesterol fatty acid ester, esters of triglyceride, stearic acid, lauric acid , Fatty acids such as myristic acid, behenic acid, isostearic acid, oleic acid, 12-hydroxystearic acid, stearyl alcohol, cetyl alcohol, lauryl Higher alcohols such as rucol, oleyl alcohol, isostearyl alcohol, behenyl alcohol, low polymerization degree dimethyl polysiloxane, high polymerization degree dimethyl polysiloxane, methylphenyl polysiloxane, decamethyl cyclopentasiloxane, octamethyl cyclotetrasiloxane, polyether modification Silicone such as polysiloxane, polyoxyalkylene / alkylmethylpolysiloxane / methylpolysiloxane copolymer, alkoxy-modified polysiloxane, crosslinkable organopolysiloxane, fluorine-modified polysiloxane, perfluorodecane, perfluorooctane, perfluoropolysiloxane Fluorine oils such as ether, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, sucrose fatty acid ester Ether, starch fatty acid esters, oil-based gelling agents such as isostearic acid aluminum.

If it is a powder for the purpose of ensuring stability over time, it may have a spherical, plate-like or needle-like shape, a mist-like shape, fine particles, a particle size such as pigment grade, a porous or non-porous particle structure. It is not particularly limited by the above, and examples thereof include inorganic powders, glittering powders, organic powders, pigment powders, metal powders, composite powders and the like. Specifically, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide and barium sulfate, iron oxide, carbon black, titanium black, chromium oxide, chromium hydroxide, dark blue, colored inorganic pigments such as ultramarine blue, talc. , Muscovite, phlogopite, phlogopite, biotite, synthetic mica, sericite, synthetic sericite, kaolin, silicon carbide, bentonite, smectite, silicic acid anhydride, aluminum oxide, magnesium oxide, zirconium oxide, oxidation White powder such as antimony, diatomaceous earth, aluminum silicate, magnesium aluminum metasilicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, titanium dioxide coated mica, Titanium dioxide coated bismuth oxychloride, oxidized Mica titanium, iron blue treated mica titanium, carmine treated mica titanium, bismuth oxychloride,
Glittering powder such as fish scale foil, iron oxide / titanium oxide coated synthetic phlogopite, titanium dioxide coated glass flake, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethylmethacrylate laminated film powder, etc. Body, polyamide resin, polyethylene resin, polyacrylic resin, polyester resin,
Fluorine resin, cellulose resin, polystyrene resin, copolymer resin such as styrene-acryl copolymer resin, polypropylene resin, silicone resin, organic polymer resin powder such as urethane resin, zinc stearate, N-
Organic low molecular weight powders such as acyl lysine, natural organic powders such as starch, silk powder and cellulose powder, Red No. 201,
Red No. 202, Red No. 205, Red No. 226, Red No. 22
No. 8, Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401 and other organic pigment powders, Red No. 3, Red No. 104
No. 106, Red No. 106, Orange No. 205, Yellow No. 4, Yellow 5
No. 3, Green No. 3, Blue No. 1, etc., organic pigment powders such as zirconium, barium or aluminum lake, or metal powders such as aluminum powder, gold powder, silver powder, etc., fine titanium oxide coated titanium mica, fine zinc oxide coated mica titanium. ,
Examples include composite powders of barium sulfate-coated titanium mica, titanium dioxide-containing silicon dioxide, zinc oxide-containing silicon dioxide, and the like. These powders may be used alone or in combination of two or more. May be used. These powders include fluorine compounds, silicone compounds, metal soaps, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes, surfactants, amino acid compounds, water-soluble compounds. The surface treatment may be performed using one kind or two or more kinds of a polymer having high affinity.

The surfactant for improving the dispersibility of the powder may be any surfactant generally used in cosmetics, including nonionic surfactants, anionic surfactants, cationic surfactants, Examples include amphoteric surfactants. Examples of the nonionic surfactant include glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, propylene glycol fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct. , Fatty acid ester of sorbitol and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, lanolin alkylene glycol Adduct, polyoxyalkylene-modified silicone, polyoxyalkylene alkyl co-modified silicone Corn and the like.
As the anionic surfactant, for example, stearic acid,
Fatty acids such as lauric acid and their inorganic and organic salts, alkylbenzene sulphates, alkyl sulphonates, α-olefin sulphonates, dialkyl sulfosuccinates, α-sulphonated fatty acid salts, acylmethyl taurine salts, N- Methyl-N-alkyl taurine salt, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkylphenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkylphenyl ether phosphate, N-
Acyl amino acid salts, N-acyl-N-alkyl amino acid salts, o-alkyl substituted malates, alkyl sulfosuccinates and the like can be mentioned. As a cationic surfactant,
Examples thereof include alkylamine salts, polyamine and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, and cyclic quaternary ammonium salts. As the amphoteric surfactant, there are amino acid type and betaine type carboxylic acid type, sulfuric acid ester type, sulfonic acid type and phosphoric acid ester type, and those which are safe for the human body can be used. For example, soybean phospholipid, N, N-dimethyl-N
-Alkyl-N-carboxymethylammonium betaine, N, N-dialkylaminoalkylenecarboxylic acid, N, N, N-trialkyl-N-sulfoalkyleneammonium betaine, N, N-dialkyl-N, N
-Bis (polyoxyethylene sulfate) ammonium betaine, 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine and the like can be mentioned.

The aqueous component used for the purpose of imparting a moisture effect may be water or a component soluble in water. In addition to water, for example, alcohols such as ethyl alcohol, propylene glycol, 1, Glycols such as 3-butylene glycol, dipropylene glycol and polyethylene glycol, glycerols such as glycerin, diglycerin and polyglycerin, aloe vera,
Examples include plant extracts such as witch hazel, hamamelis, cucumber, lemon, lavender and rose.

Examples of the water-soluble polymer for the purpose of ensuring stability over time include natural ones such as guar gum, sodium chondroitin sulfate, hyaluronic acid, gum arabic, sodium alginate and carrageenan, methyl cellulose, hydroxyethyl cellulose, carboxymethyl cellulose and the like. Examples of the semi-synthetic system, carboxyvinyl polymer, polyvinyl alcohol, polyvinylpyrrolidone, sodium polyacrylate, and the like.

Examples of the ultraviolet absorber include 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid, and 2-hydroxy-4-methoxybenzophenone-5 as the benzophenone type. Sodium sulfonate, 2,2 '
-Dihydroxy-4,4'-dimethoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone-5-sodium sulfonate, 2,4-dihydroxybenzophenone, 2,2 ', 4,4'-tetra Examples thereof include hydroxybenzophenone, and examples of PABA-based compounds include p-aminobenzoic acid, ethyl p-aminobenzoate, glyceryl p-aminobenzoate, amyl p-dimethylaminobenzoate, p-dimethylaminobenzoic acid-2.
-Ethylhexyl, ethyl p-dihydroxypropylbenzoate and the like, and as the cinnamic acid, 2-ethylhexyl p-methoxycinnamate, 2-ethoxyethyl 4-methoxycinnamate and the like, salicylic acid-based Examples include 2-ethylhexyl salicylate, phenyl salicylate, homomenthyl salicylate, and the like.
2- (2-hydroxy-5-methylphenyl) benzotriazole, 4-tert-butyl-4′-methoxydibenzoylmethane, oxybenzone and the like can be mentioned.

Examples of moisturizers include proteins, mucopolysaccharides, collagen, elastin, keratin and the like. Examples of the antioxidant include α-tocopherol,
Examples thereof include ascorbic acid. Examples of the cosmetic ingredients include vitamins, antiphlogistics, crude drugs and the like, and examples of the preservatives include alkyl p-oxybenzoate, phenoxyethanol and the like.

The oily cosmetic of the present invention can be used in various cosmetics such as make-up, skin care, hair products and the like, and its shape is liquid, gel, pouring type or solid type such as stick. Also, lipstick, lip gloss, lip base for base, lipstick overcoat,
Lip cream, eye color, face color, foundation, oil cleansing, eye cream, tic, etc. are used to maximize their effects. Of these, lip cosmetics are preferred.

[0017]

The present invention will be further described with reference to the following examples and reference examples. These do not limit the present invention in any way.

Examples 1 to 5 and Comparative Examples 1 to 5: Dish-shaped solid lip gloss Examples 1 to 5 according to the formulation shown in Table 1 and the following production method.
The lip glosses of Comparative Examples 1 to 5 were produced, and the gloss of the cosmetic film, no odor, usability, non-stickiness of the cosmetic film, shape retention, adhesiveness, stability over time, and transparency of appearance were as follows. Evaluation was performed by the method. The results are also shown in Table 1.

[0019]

[Table 1]

* 1: dextrin palmitate * 2: Polybutene 35R (made by Idemitsu Petrochemical Co., Ltd.) * 3: Pearlream 18 (made by NOF Corporation) * 4: AEROSIL200 (manufactured by Nippon Aerozil)

(Manufacturing Method) A. The components (1) to (6) are heated and dissolved at 100 ° C. B. Components (7) to (9) are added to "A", and the mixture is stirred. C. "B" was melt-filled and molded to obtain lip gloss.

Each of the following evaluation items was evaluated. (Evaluation item) I. Makeup film gloss B. No odor C. Usability D. The non-stickiness of the cosmetic film E. Shape retention F. Adhesiveness G. Stability over time H. Transparency of appearance

(Evaluation method) The gloss of the cosmetic film of item (a), the odor of item (b), the feel (usability) when using the item of item (c), the non-greasiness of the cosmetic film of item (d), Regarding the shape retention of the item and the adhesiveness of the item, each sample was subjected to a usage test by 20 professional evaluation panels, and each panel person evaluated each sample in 7 grades with the following absolute evaluation, and each sample was evaluated. The average value was calculated from the sum of the scores of all of the panel, and judged according to the following four-step judgment criteria. still,
Regarding the shape retention of the item (e), the state of each sample after use was observed, and changes in appearance such as shape collapse and separation were evaluated. Regarding the adhesiveness in the item (3), each sample was applied to the lips, and the panel was allowed to have a normal life, and the cosmetic effect after 6 hours was evaluated. Regarding the evaluation of the time-dependent stability of the above item, the state of each sample stored at 40 ° C. for one month was observed, and compared with the product stored at 25 ° C., and the evaluation was made according to the following four-stage determination criteria. For the transparency of the appearance of the item
The state of each sample at the time of filling was visually observed, and its transparency was judged according to the following four-step judgment criteria.

(Gloss of cosmetic film), (No odor), (Usability), (No stickiness of cosmetic film) (Shape retention) and (Adhesiveness) Evaluation and judgment 4-stage judgment standard (average value): (judgment) Exceeding 5 points: Very good: ◎ Exceeding 3 points and 5 points or less: Good: ○ Exceeding 1 point and 3 points or less: Slightly bad: △ 1 point or less : Poor: X (Stability over time) judgment (judgment criteria): (Judgment) Very good: ◎ Good: ○ Slightly poor: △ Poor: X (transparency of appearance) judgment (judgment criteria): (Judgment) Very transparent: ◎ Slightly cloudy, but transparent: ○ Cloudy, little transparency: △ Totally opaque: ×

As is clear from the results shown in Table 1, the lip glosses of Examples 1 to 5 of the present invention had a glossy cosmetic film, no odor, usability, no stickiness of the cosmetic film, and shape retention.
What was excellent in adhesiveness, stability over time, and transparency in appearance was obtained. On the other hand, in Comparative Example 1 in which the amount of the component (b), diisostearyl malate, was less than 46%, the gloss, usability, and adhesiveness of the cosmetic film were improved. In Comparative Example 2, the cosmetic film had no stickiness and shape. Satisfactory retention results were not obtained. Furthermore, in Comparative Example 3 in which 25% of the dextrin fatty acid ester of the component (a) is blended, the amount of the component (c) which exceeds the amount of the diisostearyl malate as the component (b) in the gloss, usability and transparency of the cosmetic film. In Comparative Example 4 in which the liquid olefin polymer was blended, satisfactory results were obtained in terms of the non-stickiness of the cosmetic film, and in Comparative Example 5 in which it was not blended at all, usability, shape retention, adhesion and stability over time were obtained. There wasn't.

Example 6 Dish-shaped solid lipstick A lipstick was produced by the following formulation and production method. (Component) (%) 1. Dextrin fatty acid ester * 1 12 2. Diisostearyl malate 60 3. Rosin acid pentaerythritol 5 4. Liquid paraffin remaining 5. Lanolin acetate 26. Methylphenyl polysiloxane * 5 2 7. Silicic anhydride * 6 0.5 8. Mica titanium 5 9. Red No. 104 2 10. Yellow No. 4 4 11. Black iron oxide 1.5 12. Ultramarine 0.5 13. Natural Vitamin E Suitable amount 14. Fragrance suitable amount * 5: Silicon KF-56 (manufactured by Shin-Etsu Chemical Co., Ltd.) * 6: AEROSIL300 (manufactured by Nippon Aerozil Co., Ltd.) (manufacturing method) A. Components (1) to (6) are uniformly dissolved at 80 to 100 ° C. B. Components (7) to (14) are added to "A", and the mixture is mixed and stirred uniformly. C. "B" was poured into a gold plate to obtain lipstick. The dish-shaped solid lipstick of the present invention has a gloss of cosmetic film, no odor,
It was excellent in usability, non-stickiness of the cosmetic film, shape retention, adhesiveness, stability over time, and transparency in appearance.

Example 7 Solid Foundation (Component) (%) 1. Dextrin fatty acid ester * 7 5 2. Ethylene / Propylene Copolymer 5 3. Diisostearyl malate 50 4. α-Olefin oligomer * 8 0.5 5. Volatile silicone 12 6. Silicone resin * 9 3 7. Silylation treated silicic acid anhydride * 10 0.5 8. 8. N-lauroyl-L-glutamate di (cholesteryl behenyl octyldodecyl) 2 9. Glyceryl tri (caprylic / capric acid) balance 10. Acrylic acid / alkyl (meth) acrylate copolymer * 11 0.05 11. Fine particle titanium oxide 1 12. Fine particle zinc oxide 1 13. Titanium oxide 8 14. Barium sulfate 2 15. Sericite 5 16. Bengal 1 17. Yellow iron oxide 2 18. Black iron oxide 0.5 19. Aloe extract proper amount 20. Perfume Suitable amount * 7: Dextrin stearate * 8: α-olefin oligomer having a mass average molecular weight of 1500 * 9: Trimethylsiloxysilicic acid * 10: AEROSIL R972 (manufactured by Nippon Aerogel Co., Ltd.) * 11: Pemulen TR-1 (BF) (Manufactured by Goodrich Chemical Co.) (Production method) A: Components (1) to (10) are uniformly dissolved at 100 ° C. B: Add components (11) to (20) to "A", mix and stir uniformly. C: "B" was poured into a gold plate and cooled to solidify to obtain a foundation. The solid foundation of the present invention was excellent in gloss of the cosmetic film, no odor, usability, stickiness of the cosmetic film, shape retention and adhesion, and excellent stability over time.

Example 8 Solid Eye Shadow (Component) (%) 1. Dextrin fatty acid ester * 1 10 2. Microcrystalline wax 3 3. Diisostearyl malate 70 4. Heavy liquid isoparaffin * 12 5 5. Stearyl modified acrylate silicone * 13 2 6. Sorbitan sesquioleate 0.2 7. Spherical nylon powder 28. Silicone treated talc 2 9. Red No. 202 0.5 10. Blue No. 1 1 11. Mica titanium 2 12. Polyethylene terephthalate / aluminum / epoxy laminated powder 1 13. Collagen aqueous solution 14. Perfume proper amount * 12: Pearlream 6 (manufactured by NOF CORPORATION) * 13: Silicon KP-561 (manufactured by Shin-Etsu Chemical Co., Ltd.) (Production method) A: Components (1) to (6) are uniformly dissolved at 100 ° C. B: Add components (7) to (14) to "A", mix and stir uniformly. C: "B" was poured into a gold plate and cooled and solidified to obtain a solid eye shadow. The solid eye shadow of the present invention was excellent in gloss of the cosmetic film, no odor, usability, non-stickiness of the cosmetic film, shape retention and adhesion, and excellent stability over time.

Example 9 Gel-like eye-gloss (component) (%) 1.12-hydroxystearic acid 0.2 2. Dextrin fatty acid ester * 14 8 3. Rosin acid pentaerythritol 0.1 4. Diisostearyl malate 65 5. Isotridecyl isononanoate 8 6. Diglyceryl triisostearate 6 7. Liquid paraffin remaining 8. Silicic anhydride * 4 4 9. Ultraviolet absorber (2-ethylhexyl paramethoxycinnamate) 0.1 10. Red No. 202 0.4 11. Ultramarine 0.6 12. Synthetic mica 5 13. Titanium oxide treated synthetic phlogopite 0.2 * 14: dextrin palmitate 2-ethylhexanoate (manufacturing method) A: The components (1) to (7) are heated at 100 ° C. and uniformly dissolved. B: Components (8) to (13) are added to "A", and the mixture is uniformly mixed and dispersed. C: B was poured into a container and cooled to obtain a gel eyegloss. The gel-like eye-gloss of the present invention is excellent in gloss of cosmetic film, odorlessness, usability, non-stickiness of cosmetic film, shape retention, adhesiveness, stability over time, and excellent transparency in appearance. It was

Example 10 Gel foundation (component) (%) 1. Dextrin fatty acid ester * 1 0.5 2. Diisostearyl malate 46 3. Glyceryl trioctanoate 2 4. Polybutene * 15 2 5. Liquid paraffin remaining 6. Ceresin wax 5 7. Mica 15 8. Titanium oxide 15 9. Silicic anhydride * 6 10 10. Red iron oxide 0.5 11. Yellow iron oxide 1 12. Black iron oxide 0.2 13. Natural Vitamin E 0.1 * 15 Polybutene 2000H (manufactured by Idemitsu Petrochemical Co., Ltd.) (Production method) A: Components (1) to (6) are uniformly dissolved at 100 ° C. B: Components (7) to (13) are added to "A" and mixed and dispersed uniformly. C: B was poured into a container and cooled to obtain a gel foundation. The gel foundation of the present invention was excellent in gloss of the cosmetic film, no odor, usability, non-stickiness of the cosmetic film, shape retention and adhesion, and excellent stability over time.

Example 11 Paste-like hair styling composition (ingredient) (%) 1. Diisostearyl malate 60 2. Purified mokuro 10 3. Dextrin fatty acid ester * 7 20 4. Heavy liquid isoparaffin * 3 5 5. Fragrance 2 6. Appropriate amount of dye 7. Antioxidant Proper amount (manufacturing method) A. The components (1) to (7) are heated uniformly and mixed uniformly. B. A was filled in a dish to obtain a paste-like hair styling product. The oily paste-like hair preparation of the present invention is excellent in gloss of cosmetic film, odorlessness, usability, non-stickiness of cosmetic film, shape retention, adhesiveness, stability over time, and transparency in appearance. Met.

Example 12 Liquid makeup remover (ingredient) (%) 1. Dextrin palmitate * 1 0.1 2. Diisostearyl malate 55 3. Light isoparaffin 5 4. Liquid paraffin remaining 5. Safflower oil 0.1 (Production method) A: Components (1) and (2) are uniformly dissolved at 100 ° C. and cooled. B: Ingredients (3) to (5) are added to "A" and mixed and dispersed uniformly. C: B was poured into a container to obtain a liquid makeup remover. The liquid makeup remover of the present invention has no odor,
Usability, non-stickiness of cosmetic film, adhesion to cosmetics,
It had excellent stability over time and excellent transparency in appearance.

[0033]

EFFECT OF THE INVENTION The oil-based cosmetic composition of the present invention is excellent in gloss of the cosmetic film, has no odor, has a heavy feeling of use and little stickiness of the cosmetic film, and is excellent in shape retention, adhesiveness, and stability over time. In addition, in a transparent cosmetic, it had excellent transparency.

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁷ Identification code FI theme code (reference) A61K 7/025 A61K 7/025 7/032 7/032 7/11 7/11 (72) Inventor Megumi 48-18 Sakaemachi, Kita-ku, Tokyo Co., Ltd., Research Headquarters (72) Inventor Toru Watanabe 48-18 Sakaemachi, Kita-ku, Tokyo F-Term (Reference), Research Center, Korse Co., Ltd. 4C083 AA112 AA122 AB172 AB212 AB232 AB242 AB362 AB432 AC012 AC022 AC302 AC342 AC371 AC372 AC392 AC422 AC442 AC662 AC792 AC842 AC852 AC912 AD021 AD022 AD072 AD092 AD152 AD162 AD241 AD242 AD432 AD512 AD662 BB12 CC11 CC12 CC13 CC14 CC32 DD01 DD30 DD41 EE01 EE06 EE07

Claims (3)

[Claims] 1. An oily cosmetic comprising component (a) dextrin fatty acid ester of 0.1 to 20 mass% and component (b) diisostearyl malate of 46 to 95 mass%. 2. The oily cosmetic according to claim 1, further comprising a component (c) liquid olefin polymer in an amount smaller than that of the component (b). 3. The oily cosmetic according to claim 1, which is transparent or translucent in appearance.