JP2014193825A - Oil-based hair cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an oil-based hair cosmetic that is free from squeaky and sticky feeling when applied, provides an effect of imparting smoothness and flexibility equivalent to or better than that of silicone oil even without containing silicone oil, and gives excellent finger combability.SOLUTION: An oil-based hair cosmetic that is free from squeaky and sticky feeling when applied and gives excellent smoothness, flexibility, and finger combability after use contains 30 to 80 mass% of triglyceride with specific fatty acid composition, 10 to 50 mass% of nonvolatile hydrocarbon oil with a specific viscosity, 5 to 20 mass% of volatile hydrocarbon oil with a boiling point of 300°C or lower, and 0.05 to 1 mass% of nonionic surfactant.

Description

  The present invention relates to an oily hair cosmetic, and more specifically, triglyceride having a specific fatty acid composition, a non-volatile hydrocarbon oil having a specific viscosity, a volatile hydrocarbon oil having a boiling point of 300 ° C. or less, and a nonionic property The present invention relates to an oily hair cosmetic composition containing a surfactant, which suppresses stickiness, has no bundle feeling, is excellent in natural fingering, and has good stability.

    Oily hair cosmetics such as hair oil is a type of hair cosmetics used for the purpose of supplementing the oil with hair and giving gloss, smoothness, flexibility, etc., and conventionally, hydrocarbon oils, ester oils, Vegetable oils, silicone oils and the like have been used as main components. In particular, when imparting smoothness to hair, silicone oil is widely used, and in combination with volatile oil in order to suppress the weight and stickiness of the finish. For example, Patent Document 1 discloses a technology that suppresses stickiness by blending a specific amount of non-volatile silicone, volatile oil, and non-volatile saturated oil to achieve cohesiveness and a smooth feel. Patent Document 2 discloses vegetable oil. , Volatile oil, high molecular weight dimethylpolysiloxane, and dimethylpolysiloxane with specific functional groups are blended to provide a moist and smooth feeling that is contrary to the sense of use, gloss, and smoothness. .

Special table 2008-143869 JP 2009-221143 A

  However, oily hair cosmetics containing a large amount of volatile oil have a strong squeaky sensation and may not be able to give the finish flexibility. In addition, an oily hair cosmetic containing silicone oil may feel an artificial smoothness and squeaky feeling peculiar to silicone oil as an uncomfortable feeling, resulting in a finish different from natural fingering. Furthermore, the need for non-silicone has increased due to concerns over the accumulation of silicone oil.

  For this reason, there is no squeaky or sticky feeling at the time of application, an oily hair cosmetic with an effect of imparting a smoothness or suppleness equal to or greater than that without adding silicone oil, and a natural finger feeling The development of was demanded.

  In view of the above situation, as a result of intensive studies, the present inventors have determined that triglyceride having a specific fatty acid composition, non-volatile hydrocarbon oil having a specific viscosity, volatile hydrocarbon oil having a boiling point of 300 ° C. or less, and nonionic It has been found that by containing a surfactant, an oily hair cosmetic that is smooth and supple after use and has excellent natural fingering can be obtained. Completed the invention.

That is, the present invention provides the following components (A) to (D);
(A) 30-80 mass% of triglycerides whose fatty acid composition is 20-60% linoleic acid and 20-60% oleic acid
(B) Non-volatile hydrocarbon oil having a kinematic viscosity at 37.8 ° C. of 10 to 100 mm 2 / S 10 to 50% by mass
(C) Volatile hydrocarbon oil having a boiling point of 300 ° C. or less 5 to 20% by mass
(D) HLB3-9 nonionic surfactant 0.05-1 mass%
Oil-based hair cosmetics characterized by containing the above.
Furthermore, the present invention provides an oily hair cosmetic in which the triglyceride of component (A) is one or more of rice bran oil, corn oil, and sesame oil, and further, the content of silicone oil Provides an oily hair cosmetic with a content of less than 1% by mass.

  The oily hair cosmetic composition of the present invention has no squeaky feeling or stickiness when applied, and is excellent in smoothness, suppleness and natural fingering feeling after use.

  Hereinafter, the present invention will be described in detail. In the present specification, “to” means a range including numerical values before and after.

  The component (A) used in the oily hair cosmetic composition of the present invention is triglyceride having a fatty acid composition of 20 to 60% linoleic acid and 20 to 60% oleic acid. Triglycerides are fats and oils mainly composed of fatty acid and glycerin triester, and are widely present in the natural animal and plant kingdoms. These triglycerides are used in various industries including edible, but recently, plant-derived triglycerides with less smell and color tend to be frequently used. As a method for collecting triglyceride from a plant, a method of squeezing seeds or fruits or solvent extraction is common. The fatty acid composition of triglyceride is mixed with unsaturated fatty acids such as oleic acid and linoleic acid, saturated fatty acids such as myristic acid, palmitic acid, and stearic acid, and the composition varies depending on the type of plant. Here, the fatty acid composition of triglyceride is a percentage of the peak area according to the “reference oil analysis method” 2.4.2 fatty acid composition (Japan Oil Chemical Society).

The triglyceride of component (A) used in the present invention has a fatty acid composition of 20-60% linoleic acid and 20-60% oleic acid. As such triglycerides, rice bran oil, sesame oil, soybean oil, sunflower seed oil, Examples include corn oil, safflower oil, cottonseed oil, and peanut oil. Of these, rice bran oil, corn oil, and sesame oil can be preferably used, and rice bran oil is particularly suitable. As rice bran oil, for example, rice salad oil manufactured by Tsukino Food Industry Co., Ltd., as corn oil, for example, NIKKOL corn germ oil manufactured by Nikko Chemicals, etc., and as sesame oil, for example, bedakarum manufactured by Ikeda Bussan Co., Ltd. Etc. are exemplified.
When the linoleic acid is 60% or more, the finish is light and moist, and when the oleic acid is 60% or more, the finish is heavily bundled.

  In the oily hair cosmetic composition of the present invention, the triglyceride of component (A) can be used singly or in combination of two or more, and the content is preferably 30 to 80% by mass (hereinafter simply referred to as “%”). 40 to 70% is more preferable. If it is this range, the stickiness of a finish can be suppressed and the oil-based hair cosmetics which were very excellent in the natural fingering feeling can be obtained.

The non-volatile hydrocarbon oil of component (B) used in the oily hair cosmetic composition of the present invention has a kinematic viscosity at 37.8 ° C. of 10 to 100 mm ² / S. The kinematic viscosity is measured according to JIS K-2283. Such a non-volatile hydrocarbon oil is not particularly limited as long as it is a non-volatile hydrocarbon oil that can be normally used in cosmetics. For example, liquid paraffin, squalane, vegetable squalane, squalene, α-olefin oligomer, etc. Is mentioned.

  In the oily hair cosmetic composition of the present invention, the non-volatile hydrocarbon oil of component (B) can be used singly or in combination of two or more, and its content is preferably 10 to 50%, preferably 20 to 40%. More preferred. If it is this range, bundling can be suppressed and the oily hair cosmetics which were very excellent in the natural fingering feeling can be obtained.

The volatile hydrocarbon oil having a boiling point of 300 ° C. or less of the component (C) used in the oily hair cosmetic of the present invention is usually usable in cosmetics, and has the property of quickly evaporating on the hair and drying. If it has, there will be no restriction | limiting in particular. Examples of such volatile hydrocarbon oils include volatile isoparaffinic hydrocarbons, hydrogenated polyisobutene, isohexadecane, and isododecane.
Examples of volatile isoparaffinic hydrocarbons include IP Solvent 1620 and 2028 manufactured by Idemitsu Kosan Co., Ltd.

  In the oily hair cosmetic composition of the present invention, the volatile hydrocarbon oil of component (C) can be used alone or in combination of two or more, and its content is preferably 5 to 20%, more preferably 3 to 15%. preferable. If it is this range, the oily hair cosmetics which suppressed the feeling of squeak at the time of application | coating and suppressed the stickiness of the finish can be obtained.

Although the following are illustrated as a nonionic surfactant of the component (D) HLB3-9 used for the oil-based hair cosmetics of this invention, for example, It is not limited to this.
Polyoxyethylene (hereinafter referred to as “POE”) cetyl ether (polyoxyethylene addition mole number 3 (hereinafter referred to as “(POE3)”)), POE cetyl ether (POE5), POE oleyl ether (POE3), POE oleyl ether (POE6), POE stearyl ether (POE6), POE stearyl ether (POE8), POE lauryl ether (POE3), POE isocetyl ether (POE5), POE isostearyl ether (POE5), POE octyldodecyl ether (POE5), POE POE alkyl ethers such as decylpentadecyl ether (POE10), POE behenyl ether (POE10), POE decyltetradecyl ether (POE5), POE cholesteryl ether (POE5), PO Nonylphenyl ether (POE5), POE alkylphenyl ethers such as POE octylphenyl ether (POE5), stearic acid POE stearyl ether (POE12), stearic acid POE lauryl ether (POE5), stearic acid POE lauryl ether (POE15), isostearic acid POE alkyl ethers of stearic acid such as POE lauryl ether (POE10), ethylene glycol diethylene glycol / polyethylene glycol (POE8), ethylene glycol diethylene glycol / polyethylene glycol (POE12), monostearic acid ethylene glycol / polyethylene glycol (POE5), distearic acid Ethylene glycol / polyethylene glycol (POE12), ethylene glycol dioleate Fatty acid ethylene glycol / polyethylene glycol such as polyethylene glycol (POE12), polyethylene glycol isostearate (POE6), polyethylene glycol diisostearate (POE12), polyethylene glycol monooleate (POE6), etc., POE glyceryl isostearate (POE5), POE glyceryl isostearate (POE6), fatty acid POE glyceryl such as POE glyceryl isostearate (POE8), triisostearate POE glyceryl (POE20), trioleate POE glyceryl (POE20), triisostearate POE glyceryl (POE7) ) Tri-fatty acid such as POE glyceryl, POE trimyristate trimethylolpro POE trifatty acid trimethylolpropane such as bread (POE20), POE triisostearic acid trimethylolpropane (POE20), POE triisostearic acid trimethylolpropane (POE25), POE triisostearic acid trimethylolpropane (POE30), POE hydrogenated castor oil (POE5), POE hydrogenated castor oil (POE20), lauric acid POE hydrogenated castor oil (POE20), isostearic acid POE hydrogenated castor oil (POE20), isostearic acid POE hydrogenated castor oil (POE30), isostearic acid POE hydrogenated castor oil (POE40) ), POE hydrogenated castor oil such as isostearic acid POE hydrogenated castor oil (POE50), and derivatives thereof, POE glycerin monostearate (POE5), monoisostearyl Sorbitan, self-emulsifying glyceryl monostearate, diglyceryl monostearate, cetostearyl glucoside, glyceryl oleate, glyceryl dioleate, trioleate glyceryl, sorbitan oleate, glyceryl isostearate, include polyglyceryl diisostearate, and the like. Of these, diglyceryl monostearate, cetostearyl glucoside, glyceryl oleate, glyceryl dioleate, glyceryl trioleate, sorbitan oleate, glyceryl isostearate, and polyglyceryl diisostearate are particularly preferred. It is.

  In the oily hair cosmetic composition of the present invention, the nonionic surfactant of component (D) HLB 3-9 can be used alone or in combination of two or more, and its content is preferably 0.05-1%, 0.1 to 0.5% is more preferable. If it is this range, stickiness can be suppressed and the oil-based hair cosmetics which were excellent in stability without phase separation etc. can be obtained.

  In the oily hair cosmetic composition of the present invention, the continuous phase is an oily component and does not contain water or even if it contains less than 1%. Although it is preferably in an anhydrous form, in addition to the above components (A) to (D), the components used in normal hair cosmetics are aqueous and non-aqueous in a qualitative and quantitative range that does not impair the effects of the present invention. You may contain without distinction. For example, oily components such as hydrocarbon oils other than components (A) and (B), ester oils, silicone oils, animal oils, vegetable oils, mineral oils, volatile oils other than components (C), and interfaces other than components (D) Activators, polyhydric alcohols, chelating agents, fungicides, powders, antioxidants, viscosity modifiers, astringents, antidandruff agents, UV absorbers, coloring agents such as dyes and pigments, perfumes, and beauty such as vitamins Components and aerosol propellants can be included as appropriate.

  The oily component other than the essential components that can be blended in the oily hair cosmetic of the present invention is not particularly limited as long as it is an oily component that can be usually used in cosmetics. However, solid hydrocarbon oils and waxes, silicone oils, Oily components such as fats and oils, higher alcohols and fatty acids can be used. For example, paraffin wax, Fischer-Tropsch wax, synthetic hydrocarbon wax, ethylene propylene copolymer, microcrystalline wax, ceresin wax, solid hydrocarbon oil such as ozokerite, wax such as beeswax, carnauba wax, candelilla wax, gay wax , Dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, polyether-modified polysiloxane, polyoxyalkylene-alkylmethylpolysiloxane-methylpolysiloxane copolymer, alkoxy-modified polysiloxane, alkyl Modified polysiloxane, cross-linked organopolysiloxane, fluorine-modified polysiloxane, amino-modified polysiloxane, glycerin-modified Silicone oil such as xanthan, higher alkoxy-modified silicone, higher fatty acid-modified silicone, lanolin, liquid lanolin, reduced lanolin, lanolin alcohol, hard lanolin, lanolin acetate, lanolin derivatives such as lanolin fatty acid isopropyl, lauryl alcohol, myristyl alcohol, palmityl alcohol Higher alcohols such as stearyl alcohol, behenyl alcohol, oleyl alcohol, isostearyl alcohol, hexyl decanol, octyldodecanol, cetostearyl alcohol, cholesterol, phytosterol, lanosterol, monostearyl glycerin ether (batyl alcohol), beef tallow, cured beef tallow, Hardened oil, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, doco Hexaenoic acid (DHA), fatty acids such as isostearic acid and the like, can be selected and used these one or more suitably.

In the oily hair cosmetic composition of the present invention, a silicone oil having a polysiloxane skeleton, for example, a silicone oil such as dimethylpolysiloxane or methylphenylpolysiloxane having a viscosity at 25 ° C. of 1 to 100,000 mm ² / S, or If a cyclic silicone oil such as decamethylcyclopentasiloxane or octamethylcyclotetrasiloxane is contained, a squeaky feeling or artificial smoothness will be felt as an uncomfortable feeling. Therefore, the silicone oil content is preferably less than 1%.

The surfactant that can be contained in the oily hair cosmetic of the present invention is not particularly limited as long as it is a surfactant that can be usually used in cosmetics, and is a nonionic surfactant other than the component (D), anionic surfactant. Agents, cationic surfactants, amphoteric surfactants and the like can be used.
More specifically, nonionic surfactants include, for example, POE alkyl ether, fatty acid glyceryl, POE fatty acid glyceryl, fatty acid polyglyceryl, propylene glycol fatty acid ester, sorbitan fatty acid ester, POE sorbitan fatty acid ester, POE sorbitol fatty acid ester, poly Examples include alkylene glycol fatty acid ester, sucrose fatty acid ester, glycerin alkyl ether, POE alkyl phenyl ether, POE hydrogenated castor oil, polyoxyalkylene-modified silicone, polyoxyalkylene alkyl co-modified silicone, and the like. Can be appropriately selected and used.
Examples of the anionic surfactant include fatty acids such as stearic acid and lauric acid and their inorganic and organic salts, alkylbenzene sulfate, alkyl sulfonate, α-olefin sulfonate, dialkyl sulfosuccinate, α- Sulfonated fatty acid salt, acylmethyl taurine salt, N-methyl-N-alkyl taurine salt, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkylphenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, poly Examples thereof include oxyethylene alkylphenyl ether phosphate, N-acyl amino acid salt, N-acyl-N-alkyl amino acid salt, o-alkyl substituted malate, alkyl sulfosuccinate, and the like. Can be selected and used as appropriate .
Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, cyclic quaternary ammonium salts, and the like. Can be used.
Examples of amphoteric surfactants include amino acid type and betaine type carboxylic acid type, sulfate ester type, sulfonic acid type, and phosphate ester type, such as soybean phospholipid, N, N-dimethyl-N-alkyl- N-carboxymethylammonium betaine, N, N-dialkylaminoalkylene carboxylic acid, N, N, N-trialkyl-N-sulfoalkylene ammonium betaine, N, N-dialkyl-N, N-bis (polyoxyethylene sulfate) ) Ammonium betaine, 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine, and the like can be used, and one or more of these can be appropriately selected and used.

  As the powder that can be contained in the oily hair cosmetic composition of the present invention, if it is a powder that can be usually used in cosmetics, the shape of a sphere, plate, needle, etc., the shape of fumes, fine particles, pigment grade, etc. There are no particular restrictions depending on the particle structure such as porous and nonporous, and inorganic powders, glitter powders, organic powders, pigment powders, metal powders, composite powders, etc. Can be used. Specifically, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide and barium sulfate, colored inorganic pigments such as iron oxide, carbon black, chromium oxide, chromium hydroxide, bitumen and ultramarine, talc, muscovite, gold Mica, red mica, biotite, synthetic mica, sericite (sericite), synthetic sericite, kaolin, silicon carbide, bentonite, smectite, aluminum oxide, magnesium oxide, zirconium oxide, antimony oxide, diatomaceous earth, aluminum silicate , Magnesium Metasilicate, Calcium Silicate, Barium Silicate, Magnesium Silicate, Calcium Carbonate, Magnesium Carbonate, Hydroxyapatite, Boron Nitride Powder, Titanium Dioxide Coated Mica, Titanium Dioxide Coated Bismuth Oxychloride, Iron Oxide Mica titanium, bitumen treated mica titanium, mosquito Bright powder such as min-treated mica titanium, bismuth oxychloride, fish scale foil, polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, fluorine resin, cellulose resin, polystyrene resin, styrene-acrylic Copolymer resins such as copolymers, organic polymer resin powders such as polypropylene resins, silicone resins and urethane resins, organic low molecular weight powders such as zinc stearate and N-acyl lysine, starch, silk powder, cellulose powder, etc. Natural organic powder, red 201, red 202, red 205, red 226, red 228, orange 203, orange 204, blue 404, yellow 401, etc., organic pigment powder, red 3 No., Red No. 104, Red No. 106, Orange No. 205, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 1, etc. , Organic pigment powder such as barium or aluminum lake or metal powder such as aluminum powder, gold powder, silver powder, fine particle titanium oxide coated mica titanium, fine particle zinc oxide coated mica titanium, barium sulfate coated mica titanium, titanium dioxide containing silicon dioxide , Zinc oxide-containing composite powders, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder lame agent, etc. Alternatively, two or more kinds can be appropriately selected and used. These powders may be one or two of fluorine compound, silicone compound, metal soap, lecithin, hydrogenated lecithin, collagen, hydrocarbon, higher fatty acid, higher alcohol, ester, wax, wax, surfactant and the like. Surface treatment may be performed using seeds or more.

The ultraviolet absorbent that can be contained in the oily hair cosmetic composition of the present invention is not particularly limited as long as it is an ultraviolet absorbent that can be usually used in cosmetics. For example, benzophenone series, paraaminobenzoic acid series, paramethoxycinnamic acid 2 -Cinnamic acid type such as ethylhexyl, salicylic acid type, 4-tert-butyl-4'-methoxydibenzoylmethane and the like.
Examples of the polyhydric alcohol include glycols such as propylene glycol, 1,3-butylene glycol, and dipropylene glycol, and glycerols such as glycerin, diglycerin, and polyglycerin.
Examples of antioxidants include α-tocopherol and ascorbic acid, and cosmetic ingredients include vitamins, anti-inflammatory agents, proteins, mucopolysaccharides, collagen, elastin, keratin, hyaluronic acid, aloe vera, witch hazel, hamamelis, cucumber, Examples of antiseptics such as plant extracts such as lemon, lavender and rose, herbal medicines, and the like include p-oxybenzoic acid ester, phenoxyethanol, ethylhexylglycerin, and 1,2-alkanediols.

The oily hair cosmetic composition of the present invention can be produced by a conventional method, and can be made into liquid oil, gel, wax, multi-layer hair oil, pomade, tic, etc. It can be a hair spray, foam aerosol or the like.

  EXAMPLES Next, although an Example demonstrates this invention in detail, this invention is not limited at all by these.

Examples 1-11 and Comparative Examples 1-10: Oily hair cosmetics (hair oil)
Hair oils were prepared according to the formulations shown in Tables 1 and 2 and the following production method. "A. No bunch", "b. No stickiness", "c. Natural finger feeling (no creaking)", And “d. Appearance properties” were evaluated. When increasing or decreasing the specific component amount, correction was performed by decreasing or increasing the other components at the same ratio so that the total amount of the components (1) to (9) was an approximate value.
“D. Appearance properties” are the stability over time after each hair oil is stored in a constant temperature bath at 50 ° C. for one week, ◯ for uniformly dissolved properties, Δ for turbidity, and those with separation or precipitation. It determined with x, and about other a-c, it evaluated by the evaluation method and determination criteria shown below. The evaluation results of a to d are also shown in Tables 1 and 2.

(Production method)
Ingredients (1) to (13) were uniformly mixed at room temperature to obtain a hair oil.

[Evaluation method (sensory evaluation)]
After washing the hair with a commercially available shampoo by a panel of 10 sensory testers and making it semi-dry with a dryer, take an appropriate amount of the hair oil of the present invention product and the comparative product, and adjust to the hair. About the evaluation items a to c below, Sensory evaluation was performed in 7 steps using the absolute evaluation criteria of (1), and the average value of the scores of the implemented product and the comparative product was further determined using the 4-step criteria of (2).
(Evaluation item)
a. Lack of bunch; b. No stickiness c. Natural finger feeling (no creaking)

(1) Absolute evaluation standard score: Evaluation 6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad

(2) Four-stage criteria Criteria average value: Judgment Over 5 points: ◎
Over 3.5 points and below 5 points: ○
Over 2.5 points and below 3.5 points: △
2 points or less: ×

As is apparent from the results of Tables 1 and 2, the hair oils of Examples 1 to 11 were “no bundle feeling”, “no stickiness”, “natural finger feeling (no creaking)”, and “ It was an oily hair cosmetic excellent in all “appearance properties”.
On the other hand, Comparative Example 1 containing more than 80% of the component (A) is inferior in “no stickiness” and “natural feeling of fingering” and contains less than 30% of the component (A). No. 2 was inferior in “no sense of bundle” and “natural feeling of fingering”. Comparative Example 3 containing no component (A) and containing triglycerides having different fatty acid compositions was particularly inferior in “no stickiness”. Comparative Example 4 containing more than 50% of component (B) is inferior in "no bundle feeling", and Comparative product 5 containing less than 10% of component (B) is inferior in "natural feeling of fingering" Met. The comparative example 6 which did not contain a component (B) and contained liquid paraffin exceeding a kinematic viscosity of 100 mm ² / S was particularly inferior in “no bundle feeling”. Comparative Example 7 containing more than 20% of component (C) is inferior in “natural feeling of fingering”, and Comparative Example 8 containing less than 5% of component (C) is inferior in “no stickiness”. there were. Further, Comparative Example 9 containing more than 1% of the component (D) was inferior in “non-stickiness”, and Comparative Example 10 containing less than 0.05% of the component (D) caused phase separation over time. "Appearance property" was inferior even compared with.

Example 12: Oily hair cosmetic (hair wax)
(Ingredient) (%)
1. 1. Petrolatum remaining amount Dimethyl distearyl ammonium hectorite 5
3. Propylene glycol 8
4). Methylparaben 0.2
5. Rice bran oil 30
6). Liquid paraffin 10
7). Fischer-Tropsch wax (Note 4) 3
8). Microcrystalline wax 5
9. Polyglyceryl diisostearate 0.5
10. Dibutylhydroxytoluene 0.1
11. Talc 5
12 Hydrogenated polyisobutene 5
13. Fragrance 0.1
14 2-Ethylhexyl paramethoxycinnamate 0.5
(Note 4) CIREBELLE 108 (manufactured by CIREBELLE)
(Production method)
A: Ingredients 1 to 4 are heated and mixed uniformly.
B: Components 5 to 10 are uniformly mixed with A.
C: Component 11 is added to B and dispersed uniformly.
D: Components 12 to 14 were added to C and mixed uniformly, and then filled into a container to obtain a hair wax.

The hair wax of Example 12 was evaluated according to Example 1. As a result, the hair wax was an oily hair cosmetic excellent in all of non-stickiness, natural fingering feeling and appearance properties.

Example 13: Hair oil mist (component) (%)
1. Hydrogenated polyisobutene 20
2. Sesame oil 30
3. Sorbitan sesquioleate 0.8
4). 4. Diglyceryl triisostearate remaining amount Methylphenyl polysiloxane 0.5
6). Liquid paraffin 10
7). Methylsiloxane network polymer 0.3
8). Silylation-treated silicic acid 0.1
9. 2-Ethylhexyl paramethoxycinnamate 0.2
10. Dibutylhydroxytoluene 0.1
11. Phenoxyethanol 0.2
12 Lauroyl glutamate di (phytosteryl / octyldodecyl 0.1
13. Fragrance 0.2
(Production method)
A: Components 1 to 13 are mixed and dissolved uniformly.
B: A was used as an aerosol stock solution, and the aerosol can was filled so that the mass ratio of A to the propellant (liquefied petroleum gas) was 6: 4 to obtain a hair oil mist.

The hair oil mist of Example 13 was evaluated according to Example 1. As a result, the oily hair cosmetic was excellent in all of the feelings of bunch, non-stickiness, natural fingering feeling, and appearance properties (before aerosol filling). Met.

  The present invention has no squeaky feeling or stickiness when applied, and is excellent in smoothness, suppleness, and natural fingering after use, and is useful as an oily hair cosmetic.

Claims (3)

The following components (A) to (D);
(A) 30-80 mass% of triglycerides whose fatty acid composition is 20-60% linoleic acid and 20-60% oleic acid
(B) Nonvolatile hydrocarbon oil having a kinematic viscosity at 37.8 ° C. of 10 to 100 mm ² / S 10 to 50% by mass
(C) Volatile hydrocarbon oil having a boiling point of 300 ° C. or less 5 to 20% by mass
(D) HLB3-9 nonionic surfactant 0.05-1 mass%
Oily hair cosmetics containing   The oily hair cosmetic according to claim 1, wherein the triglyceride of component (A) is one or more of rice bran oil, corn oil and sesame oil.   The oily hair cosmetic composition according to claim 1 or 2, wherein the silicone oil content is less than 1% by mass.