CN1867318B

CN1867318B - Oily solid cosmetic

Info

Publication number: CN1867318B
Application number: CN2004800297883A
Authority: CN
Inventors: 津原一宽; 水鸟洋一
Original assignee: Kose Corp
Current assignee: Kose Corp
Priority date: 2003-10-15
Filing date: 2004-09-15
Publication date: 2010-10-06
Anticipated expiration: 2024-09-15
Also published as: JP4851187B2; HK1095284A1; WO2005039516A1; CN1867318A; TWI334789B; TW200513266A; KR101097832B1; JPWO2005039516A1; KR20070017471A

Abstract

An oily solid cosmetic characterized by comprising (a) a hydrocarbon wax, (b) a polyglycerol fatty acid ester which is made from a polyglycerol having a degree of polymerization of 7 to 11 and a branched fatty acid having 16 to 20 carbon atoms and which is liquid at room temperature and has a degree of esterification of 65 % or above, and (c) silicic acid anhydride. The oily solid cosmetic is freed from the disadvantages of conventional oil- or fat-base solid cosmetics and is excellent in spreadability in application and soft to the touch. Further, the cosmetic is excellent in the gloss of cosmetic film and moistness and in shape retention and long-term stability.

Description

Oily solid cosmetic

Technical field

The present invention relates to oily solid cosmetic, relate in more detail when smearing extend good, have softish skin sense of touch, the gloss of the film of making up simultaneously, moist sense are excellent, the oily solid cosmetic that shape retention, long-time stability are also good.

Background technology

Oily solid cosmetic is the cosmetic material dosage form that is widely used in lip pomade etc., mainly is made of powder compositions such as solid oil, lard, liquid wet goods oil component and coloring pigment, bright pigment, tax matter powder.In above-mentioned cosmetic material, in order to keep its shape, carried out changing oil component and powder composition combined amount, add firming agent to improve the research of its intensity, be used to improve the research of long-time stability, perhaps attempt giving this cosmetic material various sensations, adjust the research of texture and tone.

For example, known to using the firming agent of ethylene/propene copolymer as oily solid cosmetic, stability can be improved (as patent documentation 1, patent documentation 2).Also known in addition, use mountain acid glycerol three esters to suppress the technology (as patent documentation 3) that form of a stroke or a combination of strokes cosmetic material forms the powder film, many as in the polyglyceryl fatty acid ester (patent documentation 4) of surfactant usually, use the technology (as patent documentation 5) that is used to suppress the diaphoresis phenomenon with mountain acid as the solid polyglyceryl fatty acid ester of main body.

And,, also proposed particular silicone oil and Alathon and/or the combined technology (as patent documentation 6) of copolymer in order to obtain the cosmetic film of homogeneity, flexibility, gloss excellence.

Yet,, particularly do not obtain good moist sense though these technical points you can well imagine high usability, cosmetic persistency, gloss etc. fully do not satisfy institute and produce effect.When using silicone oil, be difficult to satisfy easy diaphoresis under moist sense, the high temperature, thereby the bad problem of long-time stability is arranged.

And except the problems referred to above, recently the quality that requires to the oily solid cosmetic usability changes to some extent, and feels that the smooth usability of easily smearing of hardness compares, and likes more with softish skin sense of touch and experiences the usability that pastes the clothes sense.

But, in the oily solid cosmetic that combines shape in the past by wax and oil preparation because the crystallinity height of wax, so during room temperature and the difference in hardness during high temperature big, what obtain is the oily solid cosmetic of feeling hardness.And, in order to reduce stiff sense, considered to reduce the combined amount of wax, though the method has obtained softish skin sense of touch as far as possible, on the other hand can be because of use fracture continuously, shape retention is poor, produce diaphoresis etc. in time, can't obtain the oily solid cosmetic that long-time stability are satisfied.

Patent documentation 1: Japan is No. 2519469 communique of special permission specially

Patent documentation 2: No. 3073869 communique of Japan's special permission

Patent documentation 3: the special fair 7-100645 communique of Japan

Patent documentation 4: Japanese kokai publication hei 7-187947 communique

Patent documentation 5: TOHKEMY 2002-53420 communique

Patent documentation 6: No. 2960658 communique of Japan's special permission

Summary of the invention

The problem that invention will solve

Therefore, wish to develop following oily solid cosmetic, the problems referred to above have promptly not only been eliminated, also satisfy the new quality that requires to oily solid cosmetic, just in good, the softish skin sense of touch of ductility that has when smearing, also satisfy the gloss of cosmetic film, moist sense is excellent, the quality requirements that shape retention, long-time stability are good etc.

The means that are used to deal with problems

In view of the foregoing, the inventor etc. have carried out further investigation repeatedly in order to solve above-mentioned problem, found that: by chloroflo and specific polyglyceryl fatty acid ester is combined, mix, the low softish gel of crystallinity can be formed, the smooth feeling when smearing, softish skin sense of touch, gloss, moist sense can be accessed.And, by further mixing silicic acid anhydride on this basis, can when not destroying above-mentioned gel structure, improve the retentivity of oiliness composition, can access and be difficult to take place the good oily solid cosmetic of diaphoresis phenomenon, shape retention and long-time stability, and then finish the present invention.

That is, the present invention is an oily solid cosmetic, it is characterized in that: contain following composition (a)-(c),

(a) chloroflo;

(b) the glycerol polymerization degree is that 7-11, fatty acid are that branched chain fatty acid, the ester substitution value of carbon number 16-20 is to be liquid polyglyceryl fatty acid ester more than 65%, under the room temperature;

(c) silicic acid anhydride.

The invention effect

The slickness excellence of oily solid cosmetic of the present invention when smearing, the usability of so-called softish skin sense of touch of while, the persistence excellence of the gloss of cosmetic film, moist sense, shape retention and long-time stability are also good.

The specific embodiment that carries out an invention

The chloroflo that uses as composition (a) among the present invention, can enumerate paraffin, ceresin, montan wax, microwax, ethylene/propene copolymer, Tissuemat E, Fischer-Tropsch wax etc., wherein more preferably synthesize ethylene/propene copolymer, Tissuemat E, the Fischer-Tropsch wax of chloroflo.From the advantage of shape retention, the molecular weight of preferred especially this ethylene/propene copolymer is in the 500-700 scope, and more preferred its fusing point is 80-110 ℃ scope.

Commercially available product as this ethylene/propene copolymer, can enumerate ペトロライト EP-700 (production of Baker Petrolite company) etc., commercially available product as Tissuemat E, can enumerate PERFORMALENE500, PERFORMALENE655, PERFORMALENE725, PERFORMALENE850 (production of Baker Petrolite company) etc., as the commercially available product that obtains wax in the Fischer-Tropsch building-up process, can enumerate CIREBELLE108 (production of CIREBELLE company) etc.

The content of composition in the oily solid cosmetic of the present invention (a) is preferably 0.1-20% quality (following only be designated as " % ") in total the composition, more preferably 2-15%.Contain in this scope, then usability, long-time stability are good, the gloss excellence, and shape retention further improves simultaneously.

Composition of the present invention (b) is that the glycerol polymerization degree is that 7-11, fatty acid are that branched chain fatty acid, the ester substitution value of carbon number 16-20 is to be liquid polyglyceryl fatty acid ester more than 65%, under the room temperature.

The glycerol polymerization degree that constitutes polyglycereol in this polyglyceryl fatty acid ester is above-mentioned 7-11, but wherein preferred degree of polymerization is 10 material (ten glycerol).In addition, this polyglycereol also polymerizable forms ring, but preferably glycerine aggregates into chain.

And, the formation fatty acid of polyglyceryl fatty acid ester such as above-mentioned be the branched chain fatty acid of carbon number 16-20, wherein more preferably from plant, extract the isostearic acid of the carbon number 18 that obtains.

In addition, the ester substitution value of polyglyceryl fatty acid ester is above-mentioned more than 65%, preferred more than 75%.In the present invention, but so-called ester substitution value is meant in all hydroxyls of the esterification of polyglycereol, with the ratio of fatty acid-esterified hydroxyl.

As the commercially available product of above-mentioned polyglyceryl fatty acid ester, can enumerate NIKKOL Decaglyn10-IS (Japanese ケミカ Le ズ company produce), S-Off エイス IS-1009P (production of this pharmaceutical industries of slope company) etc., all can use.

The content of composition in the oily solid cosmetic of the present invention (b) is preferably 0.1-50%, preferred especially 1-35%.Contain in this scope, then usability, long-time stability are good, the gloss excellence.

And then the silicic acid anhydride that uses as composition (c) in the oily solid cosmetic of the present invention is to be generally used for making up material in the material, can be the material of impalpable structure, the material of handling through hydrophobization or the arbitrary forms such as material with crystalline texture.In this silicic acid anhydride,, can enumerate specific surface area at 100m as preference ²The material that/g is above.

As the commercially available product of this silicic acid anhydride, as enumerating AEROSIL200, AEROSIL300, AEROSIL380S, AEROSIL R972, AEROSIL R974, AEROSIL R976S (Japanese AEROSIL company produce) etc.

The content of composition in the oily solid cosmetic of the present invention (c) is preferably 0.1-5%, preferred especially 0.5-3%.Contain in this scope, then usability, long-time stability are good, the gloss excellence.

About the preparation of oily solid cosmetic of the present invention, as can with composition (a) and composition (b) after 110-120 ℃ of left and right sides heating for dissolving, adding composition (c) uniform mixing.And then after the heating, deaeration, flow into mould and fill, can be shaped after the cooling.

In the oily solid cosmetic of the present invention, except mentioned component (a)-(c), can also mix suitable any composition as required in the scope of not damaging effect of the present invention.Example as this any composition; can enumerate the oiliness composition that is used to give wettability effect; be used to give sensation adjustment, painted etc. powder; be used to give the surfactant of pigment-dispersing, the lasting effect of making up; fiber; UV absorbent, wetting agent, epithelium forms agent, anti-fading agent, antioxidant, defoamer, beauty treatment composition, antiseptic, essence etc. and is mixed in other composition of making up in expecting usually.

In above-mentioned any composition, as the oiliness composition, no matter be the character of the origin of vegetable oil, animal oil, synthetic wet goods and solid oil, lard, liquid oil, volatility wet goods, can enumerate hydro carbons, oils, wax class, hydrogenated oils, ester oil class, fatty acid, higher alcohols, silicone oil, fluorine is oils, lanolin derivative class, oil-base gel agent class etc.

Specifically; can enumerate liquid paraffin; squalane; hydro carbons such as vaseline; haze tallow; olive oil; castor bean oil; refined mink fat; macadimia nut wet goods oils; Apis cerana Fabricius; Brazil wax; candelilla wax; wax classes such as spermaceti; the malic acid diisopstearate; isooctyl acid hexadecane ester; isopropyl myristate; isopropyl palmitate; myristic acid octyl group dodecane ester; tricaprylin; two isostearic acid polyglycerin ester; three isostearic acids, two glyceride; three mountain acid glycerides; two sad DOPCP; cholesterol aliphatic ester; N-lauroyl-L-glutamic acid two (cholesteryl docosyl octyl group dodecyl) ester; jojoba oil; esters such as rosin acid pentaerythritol ester; stearic acid; lauric acid; myristic acid; mountain acid; iso stearate; fatty acids such as oleic acid; stearyl alcohol; spermol; lauric acid; oleyl alcohol; isooctadecanol; senior alcohols such as mountain alcohol; dimethyl polysiloxane; methyl phenyl silicone; decamethylcyclopentasiloxane; octamethylcy-clotetrasiloxane; polyether-modified organopolysiloxane; polyoxyalkylene alkyl methyl polysiloxanes methyl polysiloxane copolymer; alkoxy-modified polysiloxanes; fluorine modification organopolysiloxanes etc. are silicone based; perfluoro decane; PFO; fluorine such as PFPE are the oil preparation class; lanoline; the acetic acid lanoline; the lanolin fatty acid isopropyl ester; lanolin derivatives such as lanolin alcohol, dextrin fatty acid ester; sucrose fatty acid ester; the starch fatty acid ester; the 12-hydroxy stearic acid; the isostearic acid ammonium; oil-base gel agent classes such as calcium stearate etc.

In addition, as the powder composition, to shapes such as spherical, tabular, needle-likes, particle diameters such as smoke-like, microgranule, pigment-level, grain structures such as porous matter, atresia matter etc. are not particularly limited, and can enumerate inorganic powder class, light powdery type, organic dust class, dye powder class, metal dust class, composite powder class etc.

Specifically; can enumerate titanium oxide; zinc oxide; cerium oxide; white inorganic pigments such as barium sulfate; ferrum oxide; white carbon black; chromium oxide; chromic oxide gel; Prussian blue; coloured inorganic pigment such as ultramarine; Talcum; white mica; phlogopite; rubellan; biotite; synthetic mica; sericite; synthetic sericite; Kaolin; carborundum; bentonite; Montmorillonitum; aluminium oxide; magnesium oxide; zirconium oxide; stibium oxide; kieselguhr; aluminium silicate; Magnesiumaluminumsilicate; calcium silicates; barium silicate; magnesium silicate; calcium carbonate; magnesium carbonate; hydroxyapatite; white such as boron nitride is composed the matter powder; the Muscovitum of titanium dioxide lining; the bismuth oxychloride of titanium dioxide lining; the ferrum oxide mica titanium; the mica titanium of Prussian blue processing; the mica titanium that carmine is handled; bismuth oxychloride; light powder such as guanin; polyamide-based resin; polyethylene-based resin; polyacrylate is a resin; polyester based resin; fluorine resin; cellulose-based resin; polystyrene resin; copolymer resins such as copolymer in cinnamic acrylic ester; polypropylene-based resin; organic siliconresin; organic polymer resin powder such as polyurethane resin; zinc stearate; organic low molecular powder such as N-acyl group resin; starch; the silk powder; natural organic dust such as cellulose powder; red No. 201; red No. 202; red No. 205; red No. 226; red No. 228; orange No. 203; orange No. 204; blue No. 404; wait the organic pigment powder yellow No. 401; red No. 3; red No. 104; red No. 106; orange No. 205; yellow No. 4; yellow No. 5; green No. 3; wait zirconium blue No. 1; organic pigment powder or aluminium powders such as barium or aluminum pigment color lake; bronze; metal dusts such as argentum powder; the mica titanium that particulate oxide is titanium coated; the mica titanium of particulate oxide zinc lining; the mica titanium of barium sulfate lining; the silicon dioxide that contains titanium oxide; the silicon dioxide that contains zinc oxide; the composite powders such as glass powder of titanium oxide lining; polyethylene terephthalate aluminum epoxy laminate powder; polyethylene terephthalate polyolefin layer press mold powder; the ラメ agent of polyethylene terephthalate polymethyl methacrylate layers press mold powder etc.; these powder can use more than a kind or 2 kinds, and can use the material of compoundization.What these powder can use fluorine based compound, silicon-type chemical compound, metallic soap, lecithin, hydrolecithin, collagen, hydrocarbon, higher fatty acids, higher alcohol, ester, wax, wax, surfactant etc. implements surface treatment more than a kind or 2 kinds.

As surfactant,, can enumerate nonionic surfactant, anionic surfactant, cationic surfactant, amphoteric surfactant etc. so long as the surfactant of expecting that is generally used for making up gets final product.

In this surfactant, as nonionic surfactant, as can enumerate fatty acid glyceride with and the aklylene glycol addition product, the aklylene glycol addition product of polyglyceryl fatty acid ester, methyl glycol fatty acid ester and aklylene glycol addition product thereof, sorbitan fatty acid ester and aklylene glycol addition product thereof, the fatty acid ester of Sorbitol and aklylene glycol addition product thereof, the poly alkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl, the glycerol alkyl ether, the polyoxyethylene groups alkyl phenyl ether, polyoxyethylene hydrogenated Oleum Ricini, the aklylene glycol addition product of lanoline, the polyoxyalkylene modified organic silicon, the alkyl co-modified organosilicon of polyoxyalkylene etc.

As the anionic surfactant as enumerating stearic acid; fatty acid and their inorganic salt and organic salts such as lauric acid, alkyl sulfate; alkylsulfonate; alpha-alkene sulfonate; the dialkyl group thio succinate; α-alpha-sulfonated fatty hydrochlorate; acyl methyl taurine salt; N-methyl-N-alkyltaurate; the polyoxyethylene groups alkyl ether sulfate; polyoxyethylene groups alkyl phenyl ether sulfate; alkylphosphonic; the polyoxyethylene groups alkyl ether phosphate; polyoxyethylene groups alkyl phenyl ether phosphate; N-acyl amino hydrochlorate; N-acyl group-N-alkylaminoacid salts; adjacent alkyl replaces malate; alkyl-thio-succinate etc.

As cationic surfactant as enumerating alkylamine salt, polyamines and alkanolamine derivative of fatty acid, alkyl quaternary ammonium salts, ring type quaternary ammonium salt etc.

As the material of amphoteric surfactant, so long as just can use to the material of human body safety as the carboxylic acid type that can enumerate amino acid pattern or betaine type, sulfuric acid ester type, sulfonic acid type, phosphate type.For example, soybean phospholipid, N, N-dimethyl-N-alkyl-N-carboxymethyl ammonium betanin, N, N-dialkyl amido alkylen carboxylic acids, N, N, N-trialkyl-N-sulfo group alkylidene ammonium betanin, N, N-dialkyl group-N, two (polyoxyethylene sulphuric acid) the ammonium betanins of N-, 2-alkyl-1-ethoxy-1-carboxymethyl imidazoline Betanin etc.

In addition, can enumerate synthetic fibers such as nylon, polyester, polyolefin as fiber, staple fibres such as artificial silk, natural fibers such as cellulose, semisynthetic fibres such as acetate silk etc.In addition, only otherwise influencing effect of the present invention also can use the material of handling these fibers by common oil preparation, silicone oil, fluorine compounds, surfactant etc.

As UV absorbent as enumerating benzophenone, PABA system, cinnamic acid system, salicylic acid system, the 4-tert-butyl group-4 '-methoxy dibenzoyl methane, oxybenzone etc.

On the other hand, as the wettability effect that is used to adjust oily solid cosmetic of the present invention and sense of touch and blended composition, as enumerating water soluble polymer, protein, mucopolysaccharide, collagen, elastin laminin, keratin, water composition etc.

Wherein, can enumerate natural series materials such as guar gum, sodium chondroitin sulfate, hyaluronic acid, arabic gum, carrageenin as water soluble polymer, methylcellulose, hydroxyethyl-cellulose, carboxymethyl cellulose etc. are semi-synthetic to be material, and CVP Carbopol ETD2050 etc. are synthetic to be material.

As water composition, so long as the composition in water and the water soluble gets final product, can use any material, except water can be enumerated propylene glycol, 1, glycolss such as 3-butanediol, dipropylene glycol, glycerols such as glycerol, two glycerol, polyglycereol, plant extraction liquids such as the aqueous solution of Aloe vulgaris, Hamamelis virginiana, Radix Hamamelidis Mollis, Fructus Cucumidis sativi, Fructus Citri Limoniae, Garden lavender, Flos Rosae Rugosae.

As enumerating alpha-tocopherol, ascorbic acid etc., vitamins, antiinflammatory, crude drug etc. can be enumerated as antioxidant, p-Hydroxybenzoate, phenyl phenol etc. can be enumerated as antiseptic as the beauty treatment composition.

The oily solid cosmetic of the present invention that more than illustrated can be made cosmetic material that color make-up uses, cosmetic skin-care material, hair cosmetic material etc., also can make different shape, goods form according to purpose.Shape can be enumerated strip, ware shape, lip pencil etc., can enumerate lip pomade, lip gloss, lip gloss, cream base, rouge, eye shadow, informer, eyebrow pencil, eye cream, pomade etc. as the goods form.Particularly make up and expect to have showed significant effect as lip, therefore preferred.

Oily solid cosmetic of the present invention flowed in the metal ware be shaped, when using flow graph (productions of レオテ Star Network company) (diameter 1.5mm, 2cm/ minute) mensuration pin to go into load, the pin under preferred 45 ℃ is gone into pin under load and 35 ℃, and to go into the difference of load be below the 75g.By satisfying this condition, can manifest the effect of softish skin sense of touch especially.

Embodiment

Below enumerate embodiment and describe the present invention in detail.But the present invention is not limited by these embodiment.

Embodiment 1

Stick lip balm:

By prescription shown in the table 1, make the present invention product 1-11 and the stick lip balm of product 1-4 relatively.To each stick lip balm of gained, the gloss of usability (ductility, softish skin sense of touch), cosmetic film, moist sense are estimated by sensory evaluation standard described later.In addition, at high temperature take care of lip pomade, estimate shape retention, long-time stability.Comprehensive this results are shown in table 1.

* 1: ペトロライト EP-700 (production of Baker Petrolite company)

* 2:PERFORMALENE500 (production of Baker Petrolite company)

* 3:CIREBELLE108 (production of CIREBELLE company)

* 4:S-Off エイ IS-1009P (production of this pharmaceutical industries of slope company)

* 5: the glycerol polymerization degree is that the ester substitution value of 10, behenic acids is the polyglyceryl fatty acid ester more than 90%

* 6: the glycerol polymerization degree is 4, the ester substitution value of isostearic acid is the polyglyceryl fatty acid ester more than 80%

* 7:AEROSIL R976S (Japanese AEROSIL company produce)

* 8:5% perfluoralkyl phosphate diethanolamine salt is handled

* the 9:3% dimethyl polysiloxane is handled

(manufacture method)

A. behind 110-120 ℃ of heating and melting composition (1)-(13), add composition (14)-(20), uniform mixing.

B. in A, add composition (21)-(24) uniform mixing.

C. add in B that composition (25) heats, after the deaeration, flow into that mould is filled, cooling forms.

(evaluation)

1, sensory evaluation

20 people by the specialized review group carry out use test to (1) ductility, (2) soft skin sense of touch, (3) cosmetic film gloss, (4) moist sense, each one of Review Team provides scoring by the evaluation that following absolute evaluation carried out for 7 stages, calculate the meansigma methods of each sample by each all member's of Review Team overall score, judge by following 4 phase judgement standards.

(absolute evaluation)

(scoring): (evaluation)

6: very good

5: good

4: better

3: common

2: relatively poor

1: poor

0: non-constant

(4 phase judgement standard)

(scoring meansigma methods): (evaluation)

Greater than 5 minutes: very good (◎)

Greater than 3 minutes and be less than or equal to 5 fens: good (zero)

Greater than 1 but be less than or equal to 3 points: better (△)

Be less than or equal to 1 point: bad (*)

2, shape retention

Lip pomade is taken out from container, 1 week of traverse in 50 ℃ of temperature chambers, observe the state after 1 week, never change to and fracture, with ◎-* 4 stages judge.

(state): (judgement)

Do not change: ◎

Have a bit crooked but it doesn't matter: zero

Bending is difficult to use: △

Serious crooked or fracture: *

3, long-time stability

In 50 ℃ of temperature chambers, placed 1 month, and observed the state after 1 month, never change to diaphoresis carry out ◎-* the judgement in 4 stages.

(state): (judgement)

Do not change: ◎

Some diaphoresis are arranged: zero

Diaphoresis: △

As seen significantly diaphoresis: *

As shown in Table 1, the stick lip balm of the present invention's product, shape retention, long-time stability excellence, and the usability when smearing (extend, softish skin sense of touch), cosmetic film gloss, moist sense are good.

Relative therewith, there are not the relatively product 1 of blending constituent (a) not enough on long-time stability especially; It is not enough in moist sense to replace composition (b) to mix the relatively product 2,3 of ten Gan You behenic acid esters, four iso stearic acid of glycerine ester; There are not the relatively product 4 of blending constituent (c) on long-time stability, not satisfy especially.

Embodiment 2

Ware shape eye shadow

(composition) (%)

1. ethylene/propene copolymer * 12

2. Brazil wax 2

3. ceresin 2

4. dextrin fatty acid ester 1

5. silicic acid anhydride * 10 1

6. polyglyceryl fatty acid ester * 11 20

7. the didecyl acid propylene glycol ester 10

8. four iso stearates, two glyceride surpluses

9. UV absorbent (oxybenzone) 0.1

10. antioxidant (vitamin E) 0.1

11. mica titanium 10

12. the Muscovitum 10 of iron oxide treatment

13. polyethylene terephthalate aluminum epoxy laminate powder 3

14. the glass powder 3 of titanium oxide lining

15. red No. 226 0.5

16. red iron oxide 2

* 10:AEROSIL380S (Japanese ABROSIL company produce)

* 11: the degree of polymerization of glycerol is 10, the ester substitution value of iso stearate is the polyglyceryl fatty acid ester more than 80%

(manufacture method)

A. with behind composition (1)-(10) even heating mixed dissolution, add composition (11)-(16), uniform mixing.

B. fill A and make goods.

The ware shape eye shadow that obtains in the present embodiment is when having smooth usability, and the gloss excellence of cosmetic film does not have diaphoresis etc., and long-time stability are good.

Embodiment 3

Lip gloss

(composition) (%)

1. Tissuemat E * 12 5

2. ore deposit ceresine 5

3. Fischer-Tropsch wax * 35

4. Apis cerana Fabricius 3

5. Brazil wax 3

6. polyglyceryl fatty acid ester * 13 20

7. vaseline 10

8. UV absorbent (Butyrospermum oils and fats (シア fat)) 0.1

9. antioxidant (vitamin E) 0.1

10. tricaprylin surplus

11. silicic acid anhydride * 14 0.5

* 12:PERFORMALENE655 (production of Baker Petrolite company)

* 13: the degree of polymerization of glycerol is 10, the ester substitution value of different Palmic acid is the polyglyceryl fatty acid ester more than 70%

* 14:AEROSIL R972 (Japanese AEROSIL company produce)

(manufacture method)

A. with behind composition (1)-(10) even heating mixed dissolution, add composition (11)

Uniform mixing.

B. fill shaping A and make goods.

The lip gloss that obtains in the present embodiment is when having soft skin sense of touch, smooth usability, and moist sense is excellent, and shape retention is also good.

Embodiment 4

Eyeliner

(composition) (%)

1. ethylene/propene copolymer * 15

2. stearic acid 15

3. haze tallow 5

4. Apis cerana Fabricius 2

5. Brazil wax 2

6. polyglyceryl fatty acid ester * 4 10

7. squalane surplus

8. UV absorbent (Butyrospermum oils and fats) 0.1

9. antioxidant (vitamin E) 0.1

10. black iron oxide 40

11. the Muscovitum 5 of black iron oxide lining

12. silicic acid anhydride * 15 1

* 15:AEROSIL300 (Japanese AEROSIL company produce)

(manufacture method)

A. with composition (1)-(9) even heating mixed dissolution.

B. composition (10)-(12) are added among the A homodisperse.

C. fill shaping B, make goods.

The eyeliner that obtains in the present embodiment when having soft skin sense of touch, smooth usability, the gloss excellence, long-time stability are good.

Embodiment 5

The oily solid cream base

(composition) (%)

1. candelilla wax 5

2. microwax 10

3. ceresin 2

4. polyglyceryl fatty acid ester * 11 10

5. the volatility organosilicon 15

6. organic resin * 16 3

7.N-lauroyl-L-glutamic acid two (cholesteryl docosyl octyl group dodecyl) ester 2

8. three (octyl group is sad) glyceride surplus

9. stearyl modification acrylate organosilicon * 17 10

10. particulate titanium dioxide 1

11. particulate oxide zinc 1

12. titanium oxide 8

13. barium sulfate 2

14. sericite 15

15. iron oxide red 1.0

16. yellow iron oxide 2.0

17. black iron oxide 0.5

18. silicic acid anhydride * 18 1.5

19. Aloe extract is an amount of

20. essence is an amount of

* 16: organosilicon KF-7312J (production of chemical industrial company of SHIN-ETSU HANTOTAI)

* 17:KP-561 (production of chemical industrial company of SHIN-ETSU HANTOTAI)

* 18:AEROSIL200 (Japanese AEROSIL company produce)

(manufacture method)

A. with composition (1)-(9) 100 ℃ of following uniform dissolution.

B. in A, add composition (10)-(20) homodisperse.

B is flowed in the metal ware (golden ware), and cooling curing obtains cream base.

The oily solid cream base that obtains in the present embodiment, when having soft skin sense of touch, smooth usability, gloss excellence, long-time stability are also good.

Embodiment 6

The oily solid eye shadow

(composition) (%)

1. microwax 5

2. ceresin 10

3. three isostearic acids, two glyceride 4

4. vaseline 5

5. organic siliconresin * 19 2

6. the volatility organosilicon 5

7. polyglyceryl fatty acid ester * 45

8. squalane surplus

9. sad propylene glycol ester 15

10. stearyl modification acrylate organosilicon * 17 15

11. spherical nylon powder 5

12. the Talcum 10 that organosilicon is handled

13. red No. 202 0.5

14. blue No. 404 1

15. the titanium oxide 2 that organosilicon is handled

16. CVP Carbopol ETD2050 2

17. silicic acid anhydride * 15 0.5

18. collagenic aqueous solution is an amount of

19. essence is an amount of

* 19: organosilicon KF-9021 (production of chemical industrial company of SHIN-ETSU HANTOTAI)

(manufacture method)

A. with composition (1)-(10) 100 ℃ of following uniform dissolution.

B. add composition (11)-(19) in A, uniform mixing disperses.

B is flowed in the metal ware, and cooling curing obtains eye shadow.

The oily solid eye shadow that obtains in the present embodiment, when having soft skin sense of touch, smooth usability, the gloss excellence, long-time stability are good.

Embodiment 7

Pomade

(composition) (%)

1. ethylene/propene copolymer * 1 10

2. haze tallow 20

3. lanoline 10

4. Apis cerana Fabricius 10

5. two sad DOPCP 5

6. polyglyceryl fatty acid ester * 11 5

7. vaseline 5

8. UV absorbent (Butyrospermum oils and fats) 0.1

9. antioxidant (vitamin E) 0.1

10. three isostearic acids, two glyceride surpluses

11. silicic acid anhydride * 71

(manufacture method)

A. with composition (1)-(10) even heating mixed dissolution.Add composition (11) uniform mixing.

B. fill shaping A and make goods.

The pomade that obtains in the present embodiment has on hair in soft feeling, the smooth usability, and moist sense is excellent, and shape retention is also good.

Claims

1. oily solid cosmetic is characterized in that containing following composition (a)-(c):

(a) chloroflo;

(b) the glycerol polymerization degree is that 7-11, fatty acid are that branched chain fatty acid, the ester substitution value of carbon number 16-20 is to be the polyglyceryl fatty acid ester of liquid more than 65%, under the room temperature;

(c) silicic acid anhydride.

2. the oily solid cosmetic of claim 1 is characterized in that: the combined amount of mentioned component (a) is that the combined amount of 0.1-20% quality, composition (b) is that the combined amount of 0.1-50% quality, composition (c) is the 0.1-5% quality.

3. claim 1 or 2 oily solid cosmetic is characterized in that: this oily solid cosmetic is a lip with the material of making up.

4. claim 1 or 2 oily solid cosmetic, it is characterized in that: chloroflo is the material that is selected from ethylene/propene copolymer, Tissuemat E or Fischer-Tropsch wax more than a kind or 2 kinds.