JP4851187B2 - Oily solid cosmetic - Google Patents

Description

  The present invention relates to an oily solid cosmetic, and more specifically, has a good stretch spread at the time of application, has a soft skin area, is excellent in gloss of the cosmetic film, moisturized, and has shape retention and stability over time. It relates to an oily solid cosmetic which is good.

  Oily solid cosmetics are cosmetic dosage forms widely used for lipsticks, etc., mainly oil components such as solid oils, semi-solid oils, liquid oils, and pigments of colored pigments, glitter pigments, and extender powders. It is composed of body components. In the cosmetics described above, in order to maintain the shape, the blending amount of the oil component and the powder component is changed, the investigation of the solidifying agent added to increase the strength, and further the stability over time. Attempts have been made to improve the texture or to give the cosmetics various sensuality and produce a texture and color tone.

  For example, what improved stability by using an ethylene propylene copolymer as a solidification agent of oily solid cosmetics is known (for example, patent documents 1 and patent documents 2). Further, among the technology (for example, Patent Document 3) that suppresses the powdering of pencil-shaped cosmetics using behenic acid triglyceride, and polyglycerin fatty acid ester (Patent Document 4) that is often used as a surfactant, A technique using a solid polyglycerin fatty acid ester mainly composed of an acid to suppress sweating is known (for example, Patent Document 5).

  Furthermore, in order to obtain a decorative film excellent in uniformity, flexibility, and gloss, a technique in which a specific silicone oil is combined with an ethylene homopolymer and / or copolymer has been proposed (for example, Patent Document 6).

  However, with these techniques, although the feeling of use, makeup lasting, gloss, etc. are improved, those that sufficiently satisfy all the effects cannot be obtained, and in particular, a good moist feeling cannot be obtained. When silicone oil is used, it is difficult to satisfactorily obtain a moist feeling, and there is a problem in that stability over time is not good because sweating easily occurs at high temperatures.

  In addition to the above-mentioned problems, recently, the quality required for the feeling of use of oily solid cosmetics has changed, and there is a feeling of adhesion that feels close to the soft skin rather than a light and light feeling that feels firm. It has come to be liked.

However, oily solid cosmetics molded with a combination of conventional waxes and oils have high crystallinity of the wax, so there is a large difference in hardness at room temperature and high temperature, resulting in an oily solid cosmetic that feels hardness. It was. Furthermore, in order to reduce the feeling of hardness, it is conceivable to use a small amount of wax as much as possible. With this method, soft skin can be obtained. It was not possible to obtain an oily solid cosmetic material that was satisfactory in stability over time such as poor performance and sweating over time.
Japanese Patent No. 2519469 Japanese Patent No. 3073869 Japanese Patent Publication No. 7-100635 JP-A-7-187947 JP 2002-53420 A Japanese Patent No. 2960658

  Therefore, not only the above-mentioned problems are solved, but also the new required quality for oily solid cosmetics, that is, the spread at the time of application is good, the skin is soft, and the gloss of the cosmetic film is excellent in moisture, It has been desired to develop an oily solid cosmetic material that satisfies quality requirements such as good shape retention and stability over time.

  Under such circumstances, the present inventors have conducted extensive research to solve the above problems, and as a result, a soft gel with low crystallinity is formed by combining and blending a hydrocarbon wax and a specific polyglycerin fatty acid ester. It was found that smoothness at the time of application, soft skin, gloss and moist feeling can be obtained. Further, by further adding silicic anhydride to this, the retention of the oily component can be improved without breaking the gel structure, sweating phenomenon hardly occurs, shape retention and stability over time are good. The present inventors have found that a certain oily solid cosmetic can be obtained and have completed the present invention.

That is, the present invention provides the following components (a) to (c);
(A) Hydrocarbon wax (b) Polyglycerin fatty acid ester that is liquid at room temperature with a degree of glycerin polymerization of 7 to 11, a fatty acid of 16 to 20 carbon atoms, and an ester substitution degree of 65% or more (c) An oily solid cosmetic comprising silicic anhydride.

  The oily solid cosmetic of the present invention is excellent in smoothness at the time of application, has excellent usability such as soft skin, gloss of the cosmetic film, persistence of moisture, and good shape retention and stability over time It is.

  Examples of the hydrocarbon wax used as the component (a) in the present invention include paraffin wax, ceresin wax, montan wax, microcrystalline wax, ethylene / propylene copolymer, polyethylene wax, Fischer-Tropsch wax, and the like. Of these, synthetic hydrocarbon waxes such as ethylene / propylene copolymer, polyethylene wax, and Fischer-Tropsch wax are preferred. The ethylene / propylene copolymer preferably has a molecular weight in the range of 500 to 700, and more preferably has a melting point in the range of 80 to 110 ° C. from the viewpoint of shape retention.

  Examples of such commercially available ethylene / propylene copolymer include Petrolite EP-700 (manufactured by Baker Petrolite) and the like, and examples of commercially available polyethylene waxes are PERFORMOLENE 500, PERFORMALENE 655, PERFORMALENE 725, and PERFORMALENE 850 (manufactured by Baker Petrolite). Examples of commercially available Fischer-Tropsch waxes include CIREBELLE108 (manufactured by CIREBELLE).

  The content of the component (a) in the oily solid cosmetic of the present invention is preferably 0.1 to 20% by mass (hereinafter, simply referred to as “%”) in the total composition, and more preferably 2 to 15%. . When contained in this range, the feeling in use and stability over time are good, the gloss is excellent, and the shape retention is further improved.

  In addition, the component (b) of the present invention is a polyglycerol fatty acid ester having a glycerol polymerization degree of 7 to 11, a fatty acid being a branched fatty acid having 16 to 20 carbon atoms, and a liquid state at room temperature with an ester substitution degree of 65% or more. It is.

  The degree of polymerization of glycerin constituting the polyglycerin in this polyglycerin fatty acid ester is 7 to 11 as described above, and 10 of these (decaglycerin) are preferred. The polyglycerin may be polymerized to form a ring, but is preferably a polymer of glycerin chained.

  Furthermore, the constituent fatty acid of the polyglycerol fatty acid ester is a branched fatty acid having 16 to 20 carbon atoms as described above, and among them, isostearic acid having 18 carbon atoms obtained by extraction from a plant is more preferable.

  Further, the degree of ester substitution of the polyglycerol fatty acid ester is 65% or more as described above, and preferably 75% or more. In addition, in this invention, ester substitution degree means the ratio of the hydroxyl group esterified with a fatty acid among all the esterifiable groups of polyglycerol.

  Examples of such commercially available polyglycerin fatty acid esters include NIKKOL Decaglyn 10-IS (manufactured by Nikko Chemicals), S-face IS-1009P (manufactured by Sakamoto Pharmaceutical Co., Ltd.), and the like. it can.

  The content of the component (b) in the oily solid cosmetic of the present invention is preferably 0.1 to 50%, and more preferably 1 to 35%. When contained in this range, the feeling in use and the stability over time are good and the gloss is excellent.

Furthermore, the silicic anhydride used as the component (c) in the oily solid cosmetic of the present invention is generally used in cosmetics, and has an amorphous structure, a hydrophobic treatment, or a crystal structure. Either may be sufficient. Of these silicic anhydrides, preferred are those having a specific surface area of 100 m ² / g or more.

  Examples of such commercially available silicic acid products include AEROSIL200, AEROSIL300, AEROSIL380S, AEROSIL R972, AEROSIL R974, AEROSIL R976S (manufactured by AEROSIL Japan) and the like.

  The content of the component (c) in the oily solid cosmetic of the present invention is preferably 0.1 to 5%, more preferably 0.5 to 3%. When contained in this range, the feeling in use and the stability over time are good and the gloss is excellent.

  For preparing the oily solid cosmetic of the present invention, for example, the component (a) and the component (b) are heated and dissolved at about 110 to 120 ° C., and then the component (c) is added and mixed uniformly. Further heating, defoaming, pouring into a mold, filling, cooling and molding.

  In addition to the above components (a) to (c), an appropriate optional component can be blended in the oily solid cosmetic of the present invention within a range that does not impair the effects of the present invention. Examples of such optional components include oily components for imparting a moisture effect, powders for imparting feel adjustment and coloring, surfactants for imparting pigment dispersibility and makeup-holding effects, fibers Other ingredients that are usually blended in cosmetics such as ultraviolet absorbers, humectants, film forming agents, anti-fading agents, antioxidants, antifoaming agents, cosmetic ingredients, preservatives, and fragrances.

  Among the above-mentioned optional components, as oily components, hydrocarbons, fats and oils, regardless of the origin, such as animal oil, vegetable oil, synthetic oil, and properties such as solid oil, semi-solid oil, liquid oil, volatile oil, etc. Examples thereof include waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorinated oils, lanolin derivatives, and oily gelling agents.

  Specifically, hydrocarbons such as liquid paraffin, squalane and petrolatum, oils and fats such as mole, olive oil, castor oil, mink oil, macadamian nut oil, beeswax, carnauba wax, candelilla wax, gay wax, etc. Wax, diisostearyl malate, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, polyglyceryl diisostearate, diglyceryl triisostearate, glyceryl tribehenate, neopentyl glycol dioctanoate , Cholesterol fatty acid esters, N-lauroyl-L-glutamate di (cholesteryl, behenyl, octyldodecyl), jojoba oil, esters such as rosin acid pentaerythritol, stear Acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid and other fatty acids, stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol and other higher alcohols, dimethylpolysiloxane, methyl Phenylpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, polyether-modified organopolysiloxane, polyoxyalkylene / alkylmethylpolysiloxane / methylpolysiloxane copolymer, alkoxy-modified polysiloxane, fluorine-modified organopolysiloxane, etc. Silicones, fluorinated oils such as perfluorodecane, perfluorooctane, perfluoropolyether, lanolin, lanolin acetate Isopropyl lanolate, lanolin derivatives such as lanolin alcohols, dextrin fatty acid esters, sucrose fatty acid esters, starch fatty acid esters, 12-hydroxystearic acid, aluminum isostearate, oily gelling agents such as calcium stearate.

  In addition, the powder component is not particularly limited by the shape of a sphere, plate, needle, etc., the particle size of fumes, fine particles, pigment grade, etc., the particle structure of porous, nonporous, etc. Body, glitter powder, organic powder, pigment powder, metal powder, composite powder and the like.

  Specific examples include white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide and barium sulfate, colored inorganic pigments such as iron oxide, carbon black, chromium oxide, chromium hydroxide, bitumen and ultramarine, talc and muscovite. , Phlogopite, phlogopite, biotite, synthetic mica, sericite (sericite), synthetic sericite, kaolin, silicon carbide, bentonite, smectite, aluminum oxide, magnesium oxide, zirconium oxide, antimony oxide, diatomaceous earth, silica White body powder such as aluminum silicate, magnesium magnesium silicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, titanium dioxide coated mica, titanium dioxide coated bismuth oxychloride, Iron oxide mica titanium, bitumen treated mica , Carmine-treated mica titanium, bismuth oxychloride, luster powder such as fish scale foil, polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, fluorine resin, cellulose resin, polystyrene resin, styrene -Copolymer resin such as acrylic copolymer, organic polymer resin powder such as polypropylene resin, silicone resin and urethane resin, organic low molecular weight powder such as zinc stearate and N-acyl lysine, starch, silk powder, cellulose Natural organic powders such as powder, organic pigment powders such as red 201, red 202, red 205, red 226, red 228, orange 203, orange 204, blue 404, yellow 401, Red No. 3, Red No. 104, Red No. 106, Orange No. 205, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 1, etc. Organic pigment powder such as conium, barium or aluminum lake or metal powder such as aluminum powder, gold powder, silver powder, fine titanium oxide coated mica titanium, fine zinc oxide coated mica titanium, barium sulfate coated mica titanium, titanium dioxide containing titanium dioxide Composite powder such as silicon, zinc oxide-containing silicon dioxide, titanium oxide coated glass powder, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, lamellar agent of polyethylene terephthalate / polymethyl methacrylate laminated film powder, etc. These powders can be used singly or in combination of two or more, and may be further combined. These powders may be one or two of fluorine compound, silicone compound, metal soap, lecithin, hydrogenated lecithin, collagen, hydrocarbon, higher fatty acid, higher alcohol, ester, wax, wax, surfactant and the like. Surface treatment may be performed using seeds or more.

  Furthermore, the surfactant may be a surfactant generally used in cosmetics, and examples thereof include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants.

  Among these surfactants, examples of nonionic surfactants include glycerin fatty acid esters and alkylene glycol adducts thereof, polyglycerin fatty acid ester alkylene glycol adducts, propylene glycol fatty acid esters and alkylene glycol adducts thereof, and sorbitan fatty acids. Esters and alkylene glycol adducts thereof, fatty acid esters of sorbitol and alkylene glycol adducts thereof, polyalkylene glycol fatty acid esters, sucrose fatty acid esters, polyoxyalkylene alkyl ethers, glycerin alkyl ethers, polyoxyethylene alkylphenyl ethers, polyoxyethylene cured Castor oil, lanolin alkylene glycol adduct, polyoxyalkylene modified silicone, polyoxyalkylene Alkyl co-modified silicone, and the like.

Examples of the anionic surfactant include fatty acids such as stearic acid and lauric acid and their inorganic and organic salts, alkylbenzene sulfate, alkyl sulfonate, α-olefin sulfonate, dialkyl sulfosuccinate, α- Sulfonated fatty acid salt, acylmethyl taurine salt, N-methyl-N-alkyl taurine salt, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkylphenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, poly Examples thereof include oxyethylene alkylphenyl ether phosphate, N-acyl amino acid salt, N-acyl-N-alkyl amino acid salt, o-alkyl substituted malate, alkyl sulfosuccinate and the like.
Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, and cyclic quaternary ammonium salts.

  Examples of amphoteric surfactants include amino acid type and betaine type carboxylic acid types, sulfate ester types, sulfonic acid types, and phosphate ester types, and those that are safe for the human body can be used. For example, soybean phospholipid, N, N-dimethyl-N-alkyl-N-carboxylmethyl ammonium betaine, N, N-dialkylaminoalkylene carboxylic acid, N, N, N-trialkyl-N-sulfoalkylene ammonium betaine, N, N-dialkyl-N, N-bis (polyoxyethylene sulfate) ammonium betaine, 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine and the like can be mentioned.

  Furthermore, examples of the fibers include synthetic fibers such as nylon, polyester, and polyolefin, artificial fibers such as rayon, natural fibers such as cellulose, and semisynthetic fibers such as acetate artificial silk. In addition, those fibers treated with a general oil agent, silicone oil, fluorine compound, surfactant or the like can be used as long as the effects of the present invention are not hindered.

  Examples of the ultraviolet absorber include benzophenone series, PABA series, cinnamic acid series, salicylic acid series, 4-tert-butyl-4'-methoxydibenzoylmethane, and oxybenzone.

  On the other hand, examples of the components to be blended for the purpose of adjusting the moisture effect and feel of the oily solid cosmetic of the present invention include water-soluble polymers, proteins, mucopolysaccharides, collagen, elastin, keratin and aqueous components. .

  Among these, as water-soluble polymers, natural products such as guar gum, sodium chondroitin sulfate, hyaluronic acid, gum arabic, and carrageenan, semisynthetic materials such as methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, carboxyvinyl polymer, etc. Synthetic ones can be mentioned.

  The aqueous component may be any water or water-soluble component. In addition to water, for example, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol, glycerin, di- Examples include glycerols such as glycerin and polyglycerin, and plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender and rose.

  Further, examples of the antioxidant include α-tocopherol and ascorbic acid, examples of the cosmetic component include vitamins, anti-inflammatory agents, herbal medicines, and examples of the antiseptic include p-oxybenzoate ester and phenoxyethanol.

  The oily solid cosmetic of the present invention described above can be a makeup cosmetic, a skin care cosmetic, a hair cosmetic, or the like, and can have various shapes and product forms depending on the purpose. Shapes include sticks, dishes, pencils, etc. Product forms include lipstick, lip gloss, lip balm, foundation, blusher, eye color, eyeliner, eyebrow, eye cream, hair wax, etc. It is done. In particular, it is preferable to use lip cosmetics because the effects are remarkable.

  In addition, the oil-based solid cosmetic of the present invention has a penetration load at a temperature of 45 ° C. when measured by using a rheometer (manufactured by Rheotech Co., Ltd.) (diameter 1.5 mm, 2 cm / min). The difference between the penetration load value and the penetration load value at 35 ° C. is desirably 75 g or less. By satisfying such a condition, the effect per soft skin is particularly remarkable.

  Hereinafter, the present invention will be described in detail with reference to examples. Note that these do not limit the present invention.

Example 1
Sticky lipstick:
According to the formulation shown in Table 1, the stick-shaped lipsticks of the present invention products 1 to 11 and the comparison products 1 to 4 were produced. About each obtained stick-shaped lipstick, the feeling of use (elongation spread and soft skin), gloss of a cosmetic film, and a moist feeling were evaluated by sensory evaluation criteria mentioned later. Moreover, the lipstick was stored at a high temperature, and shape retention and stability over time were evaluated. The results are also shown in Table 1.

* 1: Petrolite EP-700 (manufactured by Baker Petrolite)
* 2: PERFORMALENE 500 (manufactured by Baker Petrolite)
* 3: CIREBELLE108 (CIREBELLE)
* 4: S-face IS-1009P (Sakamoto Pharmaceutical Co., Ltd.)
* 5: Polyglycerin fatty acid ester with a degree of polymerization of glycerin of 10 and an ester substitution degree of behenic acid of 90% or more * 6: A polyglycene with a degree of polymerization of glycerin of 4 and an ester substitution degree of isostearic acid of 80% Fatty acid ester * 7: AEROSIL R976S (manufactured by AEROSIL, Japan)
* 8: 5% treatment with perfluoroalkyl phosphate diethanolamine salt * 9: 3% treatment with dimethylpolysiloxane

(Production method)
A. After components (1) to (13) are heated and dissolved at 110 to 120 ° C., components (14) to (20) are added and mixed uniformly.
B. Add components (21) to (24) to A and mix uniformly.
C. Ingredient (25) is added to B and heated, and after defoaming, poured into a mold, filled, cooled and molded.

(Evaluation)
1. Sensory evaluation (b) The spread of (b), (b) soft skin gloss (c) gloss of the cosmetic film, and (d) moist feeling were tested by 20 professional panelists. The evaluation was made into 7 grades and given a score, and the average value was calculated from the total score of all the panels for each sample, and judged according to the following 4 grade criteria.

(Absolute evaluation)
(Score): (Evaluation)
6: very good 5: good 4: moderately good 3: normal 2: moderately bad 1: bad 0: very bad

(4 step criteria)
(Average score): (Judgment)
More than 5 points: Very good (◎)
3 points to 5 points or less: Good (○)
More than 1 point and 3 points or less: Somewhat bad (△)
1 point or less: Defect (x)

2. Shape retention The lipstick is drawn out from the container, placed in a 50 ° C. thermostatic bath for 1 week, observed after 1 week, and from what does not change until it breaks. Judged in 4 stages.

(State): (Judgment)
No change: ◎
Slightly bent but not interested: ○
Bent and difficult to use: △
Pretty bent or broken: ×

3. Stability over time It was installed in a thermostatic bath at 50 ° C. for 1 month, and the state after 1 month was observed.

(State): (Judgment)
No change: ◎
Slightly sweating: ○
Sweating: △
Significant sweating: ×

  As is apparent from Table 1, the stick-shaped lipstick of the present invention has excellent shape retention and stability over time, and also has a feeling of use (elongation, soft skin) at the time of application, gloss of the cosmetic film, and moisture. It was good.

  On the other hand, comparative product 1 in which component (a) was not blended was not particularly satisfactory in terms of stability over time, and instead of component (b), decaglycerin behenic acid ester, tetraglycerin isostearic acid In comparison products 2 and 3 containing an ester, a satisfactory product is not obtained in terms of moist feeling, and in comparison product 4 in which the component (c) is not blended, a product that is particularly satisfactory in terms of stability over time is obtained. I couldn't.

Example 2
Dish eye shadow:
(Ingredient) (%)
1. Ethylene / propylene copolymer * 1 2
2. Carnauba wax 2
3. Ceresin wax 2
4). Dextrin fatty acid ester 1
5). Silica anhydride * 10 1
6). Polyglycerin fatty acid ester * 11 20
7). Propylene glycol dicaprate 10
8). 8. Diglyceryl tetraisostearate remaining amount UV absorber (oxybenzone) 0.1
10. Antioxidant (Vitamin E) 0.1
11. Mica titanium 10
12 Iron oxide-treated mica 10
13. Polyethylene terephthalate / aluminum
Epoxy laminated powder 3
14 Titanium oxide coated glass powder 3
15. Red 226 0.5
16. Red iron oxide 2
* 10: AEROSIL380S (manufactured by AEROSIL Japan)
* 11: Degree of esterification of isostearic acid with a degree of polymerization of glycerin of 10.
Polyglycene fatty acid ester with a saponification of 80% or more

(Production method)
A. After components (1) to (10) are uniformly heated, mixed and dissolved, components (11) to (16) are added and mixed uniformly.
B. Fill A to make a product.
The dish-shaped eye shadow obtained in this example had a smooth feeling of use, was excellent in gloss of the decorative film, had no sweating, and had good stability over time.

Example 3
Lip balm:
(Ingredient) (%)
1. Polyethylene wax * 12 5
2. Ozoquelite wax 5
3. Fischer-Tropsch wax * 3 5
4). Beeswax 3
5). Carnauba wax 3
6). Polyglycerin fatty acid ester * 13 20
7). Vaseline 10
8). UV absorber (shear fat) 0.1
9. Antioxidant (Vitamin E) 0.1
10. 10. remaining amount of glyceryl trioctanoate Silicic anhydride * 14 0.5
* 12: PERFORMALENE 655 (Baker Petrolit
e)
* 13: Degree of esterification of isopalmitic acid with a degree of polymerization of glycerin of 10.
Is 70% or more polyglycene fatty acid ester * 14: AEROSIL R972 (manufactured by AEROSIL, Japan)

(Production method)
A. Ingredients (1) to (10) are uniformly heated, mixed and dissolved. Add component (11) and mix evenly.
B. A is filled and molded into a product.
The lip balm obtained in this example was soft and soft, had a smooth feeling of use, was excellent in moisture, and had good shape retention.

Example 4
Pencil eyeliner:
(Ingredient) (%)
1. Ethylene / propylene copolymer * 1 5
2. Stearic acid 15
3. Owl 5
4). Beeswax 2
5). Carnauba wax 2
6). Polyglycerin fatty acid ester * 4 10
7). 7. Squalane remaining amount UV absorber (shear fat) 0.1
9. Antioxidant (Vitamin E) 0.1
10. Black iron oxide 40
11. Black iron oxide coated mica titanium 5
12 Silicic anhydride * 15 1
* 15: AEROSIL300 (manufactured by AEROSIL Japan)

(Production method)
A. Ingredients (1) to (9) are uniformly heated, mixed and dissolved.
B. Add components (10) to (12) to A and disperse uniformly.
C. B is filled and molded into a product.
The pencil eyeliner obtained in this example was soft and soft, had a smooth feeling of use, was excellent in gloss, and had good stability over time.

Example 5
Oily solid foundation:
(Ingredient) (%)
1. Candelilla wax 5
2. Microcrystalline wax 10
3. Ceresin 2
4). Polyglycerin fatty acid ester * 11 10
5). Volatile silicone 15
6). Silicone resin * 16 3
7). N-lauroyl-L-glutamic acid di
(Cholesteryl, behenyl, octyldodecyl) 2
8). 8. Tri (capryl / capric acid) glyceride remaining amount Stearyl-modified acrylate silicone * 17 10
10. Fine particle titanium oxide 1
11. Fine zinc oxide 1
12 Titanium oxide 8
13. Barium sulfate 2
14 Sericite 15
15. Bengala 1.0
16. Yellow iron oxide 2.0
17. Black iron oxide 0.5
18. Silicic anhydride * 18 1.5
19. Aloe extract appropriate amount 20. Perfume appropriate amount * 16: Silicone KF-7312J (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 17: KP-561 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 18: AEROSIL200 (made by AEROSIL Japan)

(Production method)
A. Ingredients (1) to (9) are uniformly dissolved at 100 ° C.
B. Add components (10) to (20) to A and disperse uniformly.
C. B was poured into a metal pan and solidified by cooling to obtain a foundation.
The oil-based solid foundation obtained in this example was soft and soft, had a smooth feeling of use, was excellent in gloss, and had good stability over time.

Example 6
Oily solid eye shadow:
(Ingredient) (%)
1. Microcrystalline wax 5
2. Ceresin wax 10
3. Diglyceryl triisostearate 4
4). Vaseline 5
5). Silicone resin * 19 2
6). Volatile silicone 5
7). Polyglycerin fatty acid ester * 4 5
8). 8. Squalane remaining amount Propylene glycol caprate 15
10. Stearyl-modified acrylate silicone * 17 15
11. Spherical nylon powder 5
12 Silicone-treated talc 10
13. Red No. 202 0.5
14 Blue No. 404 1
15. Silicone-treated titanium oxide 2
16. Carboxyvinyl polymer 2
17. Silicic anhydride * 15 0.5
18. Collagen aqueous solution appropriate amount 19. Perfume appropriate amount * 19: Silicon KF-9021 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A. Ingredients (1) to (10) are uniformly dissolved at 100 ° C.
B. Add components (11) to (19) to A and mix and disperse uniformly.
C. B was poured into a metal pan and cooled and solidified to obtain an oily eye shadow.
The oily solid eye color obtained in this example was soft and soft, had a smooth feeling of use, was excellent in gloss, and had good temporal stability.

Example 7
Hair wax:
(Ingredient) (%)
1. Ethylene / propylene copolymer * 1 10
2. Owl 20
3. Lanolin 10
4). Beeswax 10
5). Neopentyl glycol dioctanoate 5
6). Polyglycerin fatty acid ester * 11 5
7). Vaseline 5
8). UV absorber (shear fat) 0.1
9. Antioxidant (Vitamin E) 0.1
10. 10. Diglyceryl triisostearate remaining amount Silicic anhydride * 7 1

(Production method)
A. Ingredients (1) to (10) are uniformly heated, mixed and dissolved. Add component (11) and mix evenly.
B. A is filled and molded into a product.
The hair wax obtained in this example was soft to the hair, had a smooth feeling of use, was excellent in moisture, and had good shape retention.

Claims (3)

The following components (a) to (c);
(A) One or more hydrocarbon waxes selected from paraffin wax, ceresin wax, montan wax, microcrystalline wax, ethylene / propylene copolymer, polyethylene wax, Fischer-Tropsch wax (b) Degree of glycerol polymerization of 7 to 11 And a polyglycerin fatty acid ester that is liquid at room temperature with a degree of ester substitution of 65% or more and (c) silicic acid anhydride. .   The compounding amount of the component (a) is 0.1 to 20% by mass, the compounding amount of the component (b) is 0.1 to 50% by mass, and the compounding amount of the component (c) is 0.1 to 5% by mass. The oily solid cosmetic according to claim 1.   The oily solid cosmetic according to claim 1 or 2, wherein the oily solid cosmetic is a lip cosmetic.