WO2012102398A1 - Etoffe non tissée obtenue par fusion-soufflage comportant des fibres ultrafines, procédé et dispositif pour sa production - Google Patents

Etoffe non tissée obtenue par fusion-soufflage comportant des fibres ultrafines, procédé et dispositif pour sa production Download PDF

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Publication number
WO2012102398A1
WO2012102398A1 PCT/JP2012/051887 JP2012051887W WO2012102398A1 WO 2012102398 A1 WO2012102398 A1 WO 2012102398A1 JP 2012051887 W JP2012051887 W JP 2012051887W WO 2012102398 A1 WO2012102398 A1 WO 2012102398A1
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Prior art keywords
nonwoven fabric
suction
blown nonwoven
die
melt blown
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PCT/JP2012/051887
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English (en)
Japanese (ja)
Inventor
智彦 田村
渉 河内
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タピルス株式会社
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Application filed by タピルス株式会社 filed Critical タピルス株式会社
Priority to JP2012554874A priority Critical patent/JP5905400B2/ja
Priority to CN201280006732.0A priority patent/CN103380242B/zh
Publication of WO2012102398A1 publication Critical patent/WO2012102398A1/fr

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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods
    • D01D5/098—Melt spinning methods with simultaneous stretching
    • D01D5/0985—Melt spinning methods with simultaneous stretching by means of a flowing gas (e.g. melt-blowing)

Definitions

  • the present invention is a melt-blown nonwoven fabric made of ultrafine fibers that suppresses entanglement of fibers and adhesion of floating fibers, has a small maximum pore diameter and a small average pore diameter, and is excellent in both fine particle capturing ability and air permeability.
  • the present invention relates to a manufacturing method and an apparatus for manufacturing the same.
  • Melt blown non-woven fabric is made of finer fibers than spunbond non-woven fabric, so it has excellent fine particle capture, is used in liquid filters, air filters, etc., and also has excellent insulation between electrodes and electrolyte retention. It is also used for battery separators.
  • Melt blown non-woven fabric is made of, for example, polyolefin excellent in processability, chemical resistance, etc., but in order to further improve the particulate collection property, the polyolefin fiber is further refined and the maximum pore size and the average pore size are reduced. It has been demanded.
  • Japanese Patent Laid-Open No. 6-25958 discloses a polypropylene ultrafine fiber with a small fiber diameter variation rate, which is obtained by spinning a polypropylene having a melt index of 500 to 2,000 kg / 10 min at a nozzle temperature of 200 to 285 ° C. at a temperature of 230 ° C. and a load of 2.16 kg.
  • a method for producing a meltblown nonwoven fabric made of fibers is disclosed.
  • JP 2002-201560 describes the production of a melt blown nonwoven fabric of ultrafine fibers having an average fiber diameter of 2.0 ⁇ m or less, made of polypropylene having a melt flow rate of 1,200 ⁇ g / 10 min or more and a molecular weight distribution (Mw / Mn) of 2.5 or less.
  • Mw / Mn molecular weight distribution
  • JP-T-2009-534548 has a spinning orifice having a ratio L / D of a length L to a maximum cross-sectional dimension D of 20 or more, and is spun at a very low throughput or a polymer flow rate, so that the diameter is less than 0.5 ⁇ m.
  • a melt blow spinning device for producing a nonwoven fabric made of polypropylene fibers is disclosed. However, when a nonwoven fabric made of ultrafine polypropylene fibers is produced using this apparatus by the melt blow method, fiber entanglement and floating fibers adhere to the resulting nonwoven fabric, resulting in a melt blown excellent in both fine particle capturing and breathability. A nonwoven fabric cannot be obtained.
  • the object of the present invention is to suppress the entanglement of fibers and the adhesion of floating fibers, and even if the basis weight is small, the maximum pore diameter and the average pore diameter are small, and it consists of ultrafine fibers excellent in both fine particle capturing ability and air permeability. It is to provide a melt blown nonwoven fabric, a method for producing the same, and an apparatus for producing the same.
  • the present inventors have (1) the gap between the die and the suction roll, the stretching of the molten polymer is completed, and the vibration of the obtained polymer fiber does not substantially occur. By making it within the range, yarn breakage and entanglement of the polymer fiber are suppressed, and (2) the distance between the outer peripheral surface of the suction roll and the die side end of the suction hood is set on the surface of the obtained melt blown nonwoven fabric. By setting so that the cut fibers can be removed by suction even if they are attached or contacted, even if entanglement of the polymer fibers and floating fibers occur, their adhesion is suppressed, and as a result, the basis weight is small. In addition, the present inventors have found that a melt blown nonwoven fabric composed of ultrafine fibers having a small maximum pore diameter and an average pore diameter and excellent in both fine particle capturing ability and air permeability can be obtained.
  • the method of the present invention comprises: A die having a large number of spinning nozzles having a diameter of 200 ⁇ m or less and air nozzles on both sides thereof, a suction roll provided in the vicinity of the die, and having a porous outer peripheral portion; upstream and downstream of the die Using a melt blow device having a pair of suction hoods provided to cover the suction roll at a position, By stretching the molten polymer discharged from the spinning nozzle with heated air ejected from the air nozzle, and collecting the obtained ultrafine fibers of the polymer on a suction roll, A method for producing a melt blown nonwoven fabric comprising ultrafine fibers having a number average fiber diameter of 1 ⁇ m or less, a fiber diameter distribution (weight average fiber diameter / number average fiber diameter) of 1.3 or less, and a fiber diameter variation rate of 55% or less.
  • the distance between the die and the suction roll is set within a range in which stretching of the molten polymer is completed and vibration of the obtained polymer fiber does not substantially occur
  • the suction roll The distance between the outer peripheral surface of the suction hood and the die side end of the suction hood is set within a range that can be removed by suction even if fibers broken or adhered to the surface of the obtained melt blown nonwoven fabric. .
  • the discharge amount of the molten polymer per spinning nozzle is 50 mg / min or less, and the flow velocity of the heated air is 100 m / sec or more.
  • the ejection amount of the heated air per width is preferably 800 Nm 3 / hr / m or more.
  • the suction amount per width by the suction roll is not less than five times the ejection amount of the heated air, and the total suction amount by the pair of suction hoods and the suction amount by the suction roll (suction amount not converted per width) The ratio is preferably 0.2 to 0.9.
  • the temperature of the die and the heated air is preferably (melting point of the polymer) to (melting point of the polymer + 50 ° C.).
  • polypropylene having a melt flow rate (JIS K7210, 230 ° C., load 2,160 kg) at 1,000 to 2,000 kg / 10 minutes.
  • the apparatus of the present invention is a melt blown nonwoven fabric comprising ultrafine fibers having a number average fiber diameter of 1 ⁇ m or less, a fiber diameter distribution (weight average fiber diameter / number average fiber diameter) of 1.3 or less, and a fiber diameter variation rate of 55% or less.
  • An apparatus for manufacturing A die having a large number of spinning nozzles having a diameter of 200 ⁇ m or less and air nozzles on both sides thereof, a suction roll provided in the vicinity of the die, and having a porous outer peripheral portion; upstream and downstream of the die A pair of suction hoods provided so as to cover the suction roll at a position; (a) the distance between the die and the suction roll is such that the obtained polymer is obtained while the stretching of the molten polymer is completed; (B) The distance between the outer peripheral surface of the suction roll and the die side end of the suction hood is a fiber that is broken on the surface of the obtained melt blown nonwoven fabric. It is characterized in that it is set within a range that can be removed by suction even if it adheres or contacts.
  • the distance between the die and the suction roll is preferably 30 to 100 mm.
  • the distance between the outer peripheral surface of the suction roll and the die side end of the suction hood is preferably 10 to 40 mm.
  • the ratio of the half roll surface on the die side of the suction roll covered with the pair of suction hoods is 60 to 90%.
  • the area ratio of the suction region to the outer peripheral surface of the suction roll is preferably 1/6 to 1/3.
  • the spinning nozzles are preferably arranged in a line on the die with a density of 50 or more per inch.
  • the melt blown nonwoven fabric of the present invention is composed of ultrafine fibers having a number average fiber diameter of 1 ⁇ m or less, a fiber diameter distribution (weight average fiber diameter / number average fiber diameter) of 1.3 or less, and a fiber diameter variation rate of 55% or less.
  • the number average fiber diameter of the melt blown nonwoven fabric is preferably 0.7 ⁇ m or less.
  • the average basis weight of the melt blown nonwoven fabric is 12 g / m 2 or less
  • the maximum pore diameter and the average pore diameter determined by the bubble point method are 12 ⁇ m or less and 6 ⁇ m or less, respectively
  • the air permeability (JIS L 1096) is 5 mL / cm. It is preferably 2 / sec or more.
  • the ultrafine fibers are preferably made of polypropylene having a melt flow rate (JIS K7210, 230 ° C., load 2,160 g) of 1,000 to 2,000 g / 10 min.
  • the melt blown nonwoven fabric of the present invention is formed of ultrafine fibers having a small average fiber diameter and a narrow fiber diameter distribution, it has a small maximum pore diameter and average pore diameter even if the basis weight is small. Therefore, it is excellent in both fine particle capturing ability and air permeability, and high fine particle capturing performance can be maintained over a long period of time. Therefore, the nonwoven fabric of the present invention is useful for lightweight and small volume liquid filters, air filters, dust masks, battery separators and the like. Moreover, the nonwoven fabric of this invention can obtain the filter and separator which have high microparticle capture
  • the method for producing the melt blown nonwoven fabric of the present invention and the apparatus used therefor are as follows: (1) The distance between the die and the suction roll is such that the stretching of the molten polymer is completed and the resulting vibration of the polymer fiber substantially occurs. Therefore, the polymer fibers can be prevented from being broken and entangled. (2) The distance between the outer peripheral surface of the suction roll and the die side end of the suction hood is obtained. Since it is set within a range that can be removed by suction even if fibers broken on the surface of the nonwoven fabric adhere to or come into contact with the nonwoven fabric, scattered fibers generated by yarn breakage can be effectively removed, and the average fiber diameter is small. A melt blown nonwoven fabric made of ultrafine fibers having a narrow fiber diameter distribution is obtained.
  • FIG. 2 is an exploded perspective view showing an internal structure of a suction roll in the apparatus of FIG.
  • FIG. 2 is a longitudinal sectional view showing an internal structure of a suction roll in the apparatus of FIG.
  • FIG. 2 is a partial cross-sectional front view showing a part of the apparatus of FIG.
  • FIG. 2 is an enlarged partial sectional view showing the vicinity of a polymer fiber collection site in the apparatus of FIG.
  • FIG. 2 is a cross-sectional view showing an internal structure of a die in the meltblowing apparatus of FIG.
  • FIG. 8 is a partial enlarged cross-sectional view showing a main part of the die of FIG.
  • FIG. 8 is a partial plan view showing one of the grooved plates constituting the spinning nozzle of the die of FIG.
  • FIG. 8 is a partial front view showing an array of spinning nozzles in the die of FIG. It is the schematic which shows the flow of the polymer fiber discharged from the die
  • 2 is a cross-sectional view showing a meltblowing device used in Comparative Example 1.
  • FIG. 5 is a cross-sectional view showing a meltblowing device used in Comparative Example 2.
  • FIG. 1 is a meltblowing device used in Comparative Example 1.
  • Example 6 is a graph showing fiber diameter distributions of melt blown nonwoven fabrics of Examples 1 to 3 and Comparative Example 6. It is a graph which shows the pressure-permeation flow rate curve for calculating
  • the polymer constituting the meltblown nonwoven fabric may be any thermoplastic resin that becomes a meltblown molten polymer.
  • the thermoplastic resin that can be melt blown include polyolefins such as polyethylene and polypropylene, polyesters, polyetheretherketone, polyphenylene sulfide, and polyamides.
  • polyolefin or polyester is preferable, and polyolefin is particularly preferable.
  • polystyrene resin examples include homopolymers of ⁇ -olefins such as propylene, ethylene, butene-1, hexene-1, octene-1, 4-methylpentene-1, or two or more kinds of these ⁇ -olefins, which are random or block A copolymer is mentioned.
  • polypropylene is preferable, and polypropylene having a melt flow rate (MFR) of 1,000 to 2,000 g / 10 min is particularly preferable.
  • MFR melt flow rate
  • the melt-kneading temperature must be increased, and the discharged fibers are easily fused to not only widen the fiber diameter distribution but also to cause fiber breakage.
  • the MFR is more than 2,000 g / 10 min, the fibers may be shortened and the strength of the nonwoven fabric may be insufficient.
  • the lower limit of MFR is preferably 1,200 g / 10 minutes, more preferably 1,300 g / 10 minutes, and the upper limit is preferably 1,800 g / 10 minutes, more preferably 1,700 g / 10 minutes.
  • the MFR of polypropylene is measured at a load of 2.16 kg and a temperature of 230 ° C based on JIS K7210.
  • the weight average molecular weight (Mw) of polypropylene is preferably 1 ⁇ 10 4 to 2 ⁇ 10 5, and more preferably 5 ⁇ 10 4 to 10 ⁇ 10 5 .
  • the molecular weight distribution [weight average molecular weight (Mw) / number average molecular weight (Mn)] of polypropylene is preferably 1.1 to 5, more preferably 1.5 to 4, and most preferably 2 to 3.5.
  • Polypropylene includes propylene homopolymers, or a majority polymerization proportion of propylene and other ⁇ -olefins (ethylene, butene, hexene, 4-methylpentene, octene, etc.), unsaturated carboxylic acids or their derivatives (acrylic acid, maleic anhydride). Acid, etc.), aromatic vinyl monomers (styrene, etc.) and the like, random, block or graft copolymers can be preferably used. These polypropylenes may be used singly or as a mixture of a plurality of types of polymers, or may be used by mixing with polyolefins other than polypropylene.
  • ⁇ -olefins ethylene, butene, hexene, 4-methylpentene, octene, etc.
  • unsaturated carboxylic acids or their derivatives acrylic acid, maleic anhydride. Acid, etc.
  • aromatic vinyl monomers styrene, etc.
  • polyesters examples include polyethylene terephthalate, polybutylene terephthalate, polytrimethylene terephthalate, and the like, and it is desirable that any of these is a main component. Among these, polyethylene terephthalate or polybutylene terephthalate is preferable. When a mixture of a plurality of types of polyester is used, any of the aforementioned polyesters is preferably 50% by weight or more, more preferably 70% by weight or more, and most preferably 90% by weight or more. preferable. A melt blown nonwoven fabric made of polyethylene terephthalate, polybutylene terephthalate or polytrimethylene terephthalate has a relatively high melting point, and therefore has excellent heat resistance and excellent dimensional stability due to heat.
  • Polyamide 3 (nylon 3) (registered trademark), polyamide 4 (nylon 4) (registered trademark), polyamide 6 (nylon 6) (registered trademark), polyamide 6-6 (nylon 6-6) (registered trademark) Trademark), polyamide 12 (nylon 12) (registered trademark), and the like.
  • a crystal nucleating agent In the raw material resin, a crystal nucleating agent, a matting agent, a pigment, a fungicide, an antibacterial agent, a flame retardant, a hydrophilic agent, a light stabilizer and the like may be added within a range not impairing the effects of the present invention.
  • FIGS. 1 to 10 show an example of the melt-blown nonwoven fabric manufacturing apparatus of the present invention.
  • This manufacturing apparatus includes a die 1 for discharging molten polymer in the horizontal direction in the form of ultrafine fibers, a suction roll 2 for collecting ultrafine fibers provided in the vicinity of the die 1, and the die on the outer peripheral surface of the suction roll 2. 1 and a pair of suction hoods (upstream suction hood 3a and downstream suction hood 3b) arranged to cover the suction roll 2 at predetermined positions upstream and downstream of 1.
  • downstream side is the side through which the web of the melt blown nonwoven fabric 4 formed by the ultrafine fibers discharged from the die 1 flows
  • upstream side is the side where the melt blown nonwoven fabric 4 is not formed with respect to the die 1. (Opposite the downstream side).
  • the die 1 has a pair of grooved plates 11a and 11b forming a spinning nozzle 11c, and a plurality of through holes 120 for supplying heated air, and a groove
  • the through-hole 120 communicates with the pair of blocks 12a and 12b that support the attached plates 11a and 11b from both sides, and the air nozzles 15 and 15 that open near the tip of the spinning nozzle 11c via the channels 14 and 14.
  • a pair of air jet blocks 13 and 13 provided on the downstream side of the blocks 12a and 12b.
  • the first block 12a has a plurality of through holes 121 for feeding the molten polymer from an extruder (not shown) to the spinning nozzle 11c.
  • the through-hole 121 of the block 12a through which the molten polymer flows communicates with the opening 111 of the grooved plate 11a through the filter 113.
  • the grooved plate 11a includes a recess 110d having a plurality of flow dividers 112 and a number of parallel semi-cylindrical grooves 110c communicating with the downstream side of the recess 110d.
  • the grooved plate 11b is the same as the grooved plate 11a except that it does not have the opening 111.
  • a molten polypropylene reservoir 11d, a diversion channel and a spinning nozzle 11c are formed by the concave portions 110d and 110d, the flow dividers 112 and 112 and the semi-cylindrical grooves 110c and 110c.
  • the flow rate of the molten polymer to the spinning nozzle 11c can be made uniform by the flow dividers 112 and 112.
  • the diameter D of the spinning nozzle 11c is 200 ⁇ m or less.
  • the diameter D is a diameter of a circle having the same area as the cross section.
  • the diameter D exceeds 200 ⁇ m, it is difficult to make the number average fiber diameter 1 ⁇ m or less.
  • the diameter D is preferably 150 ⁇ m or less, and more preferably 130 ⁇ m or less.
  • the lower limit of the diameter D is technically preferably 50 ⁇ m.
  • the ratio L / D between the length L and the diameter D of the spinning nozzle 11c is preferably 20 or more, more preferably 30 or more, and most preferably 100 to 300 preferable.
  • the density of the spinning nozzle 11c is preferably 50 or more per inch, more preferably 70 or more, and 70 to 300 Most preferred.
  • the gap G of the air nozzle 15 is preferably 0.1 to 1 mm, more preferably 0.2 to 0.8 mm.
  • the total gap TG (the distance between the edges of the air jet blocks 13 and 13) is preferably 0.1 to 2 mm, more preferably 0.4 to 1.5 mm.
  • the suction roll 2 for continuously collecting the ultrafine fibers of the polymer discharged and stretched from the spinning nozzle 11c extends in the axial direction (a) A cylindrical member 21 having an opening 21a and communicating with an exhaust device (not shown), (b) a side plate 201 with a flange (201a) fixed to the rotating shaft 203, and the cylindrical member 21 via a bearing 206a. A porous cylindrical member 22 fixed to a cylindrical supporting portion 202 with supporting flanges (202a, 202b), and (c) a cylindrical mesh member 23 provided on the outer peripheral surface of the porous cylindrical member 22. .
  • the cylindrical member 21 Since the cylindrical member 21 is connected to the rotary shaft 203 via the bearing 205b, it remains fixed even if the shaft 203 rotates.
  • the rotating shaft 203 is rotatably supported by a bearing 205a provided on the support 210, and a pulley 204 driven by a motor (not shown) is fixed to an outer end portion thereof.
  • the cylindrical support portion 202 is rotatably supported by a bearing 206b provided on the support body 211 on the outer peripheral surface of the flange 202b.
  • a part 220 of the cylindrical member 21 is provided with means 220 for fixing it at a predetermined circumferential position.
  • the porous cylindrical member 22 and the cylindrical mesh member 23 provided on the outer peripheral surface thereof rotate integrally to continuously collect the ultrafine fibers of the polymer discharged and stretched from the spinning nozzle 11c. Then, a melt blown nonwoven fabric 4 is formed.
  • the diameter of the suction hole 22a (see FIG. 2) of the porous cylindrical member 22 is preferably 3 to 20 mm, More preferably, it is 5 to 15 mm, and the porosity of the porous cylindrical member 22 is preferably 30 to 70%, more preferably 40 to 60%.
  • the porous cylindrical member 22 is preferably a cylindrical body made of a metal plate such as stainless steel having a large number of punch holes from the viewpoint of air permeability and mechanical strength.
  • the cylindrical mesh member 23 is preferably made of a fiber of a high melting point heat resistant resin (nylon or the like).
  • the opening 21a of the cylindrical member 21 has a slight space between the inner surface of the porous cylindrical member 22 and the other portion of the opening 21a.
  • a pair of partition plates 21b and 21c for partitioning the space is fixed.
  • a space surrounded by the opening 21a, the pair of partition plates 21b and 21c, and the porous cylindrical member 22 communicates with the inside of the cylindrical member 21 to form a suction area SA.
  • the die 1 is preferably positioned so that the ultrafine fibers collide with the suction roll 2 near the upstream end of the suction area SA. Further, it is preferable to adjust the discharge direction of the die 1 so that the ultrafine fibers are substantially perpendicular to the outer peripheral surface of the suction roll 2.
  • the central angle ⁇ constituting the suction area SA is preferably 60 to 120 °, more preferably 80 to 100 °. That is, the area ratio of the suction area SA to the outer peripheral surface of the suction roll 2 is preferably 1/6 to 1/3, and more preferably 2/9 to 5/18. When the central angle ⁇ is less than 60 °, the suction area SA is too narrow, and it is difficult to stably manufacture the nonwoven fabric 4. On the other hand, if the central angle ⁇ exceeds 120 °, the suction area SA is too wide and the suction force with respect to the nonwoven fabric 4 is insufficient.
  • the diameter of the suction roll 2 is preferably 30 to 150 cm, and more preferably 50 to 100 cm.
  • the distance d 1 between the die 1 and the outer peripheral surface of the suction roll 2 is within the range where the stretching of the molten polymer is completed and the vibration of the obtained fiber does not substantially occur. Needed (see Figure 5). As shown in FIG. 11, the molten polymer discharged from the spinning nozzle 11c of the die 1 is stretched and vibrates when a predetermined distance (d max ) is exceeded. This is presumably because the high-speed heated air flow becomes turbulent due to friction with the surrounding air.
  • melt blown non-woven fabric composed of fibers with a thickness of several ⁇ m or more, even if entanglement due to turbulent flow occurs, it does not cause a big problem in performance, but in the case of extremely fine fibers with a number average fiber diameter of 1 ⁇ m or less, the entanglement once occurred
  • generated, and not only the maximum pore diameter of a melt blown nonwoven fabric will become large, but it will become easy to produce the scattering fiber by thread breakage. Therefore, after the completion of the stretching of the molten polymer, it is necessary to collect the ultrafine fibers of the polymer on the suction roll 2 within a range in which vibration does not substantially occur.
  • the range d max in which vibration does not substantially occur is usually about 150 mm or less.
  • spacing d 1 is preferably less 100 mm and the outer circumferential surface of the suction roll 2 and, more preferably less 90 mm, or less and most preferably 70 mm.
  • the lower limit of the distance d 1 is preferably 30 mm, and more preferably 40 mm. When the distance d 1 is less than 30 mm, the stretching is insufficient and the resin is not sufficiently cooled, so that a resin lump is easily generated.
  • the suction hoods 3 a and 3 b are provided on the side (downstream side) on which the web of the melt-blown nonwoven fabric 4 formed by the ultrafine fibers discharged from the die 1 flows and on the die 1. On the other hand, it is provided on both sides of the side where the melt blown nonwoven fabric 4 is not formed (upstream side). Since the floating fibers may move downward (upstream side) on the airflow, the floating fibers can be efficiently removed by providing the suction hood 3b on the upstream side.
  • the suction hoods 3a and 3b are provided on one side of the hood main body portions 31a and 31b having the bottom opening portions 35a and 35b along the outer peripheral surface of the suction roll 2 and the hood main body portions 31a and 31b, and are exhausted through a duct. And pipe portions 32a and 32b having openings 33a and 33b connected to each other.
  • the suction hood 3a on the downstream side is a portion where the melt blown nonwoven fabric 4 is peeled off from the suction roll 2 and taken out from a predetermined position on the downstream side of the die 1 (in FIG. (Upper part) is preferably provided so as to cover the suction area SA as much as possible.
  • the upstream suction hood 3b is preferably provided symmetrically with respect to the downstream suction hood 3a and the die 1. As shown in FIG.
  • the suction hood 3a, the roll outer area covered by 3b and S 1 and S 2, the suction hoods 3a, between 3b, suction hoods 3a, the roll outer area not covered by 3b S 3 and when the sum of these areas (S 1 + S 2 + S 3) for the suction hood 3a, the total area covered by 3b (S 1 + S 2) the ratio of (roll coverage (S 1 + S 2) / (S 1 + S 2 + S 3 )) is preferably 60 to 90%, more preferably 70 to 85%. If the roll coverage is less than 60%, the suction of floating fibers is insufficient.
  • the total area (S 1 + S 2 + S 3 ) is preferably set so as to occupy a half circumference of the suction roll 2. Accordingly, the outer peripheral area S 3 facing the die 1 without being covered by the suction hoods 3a and 3b is preferably 10 to 40%, more preferably 15 to 30% of the area of the half circumference of the suction roll 2.
  • the suction hoods 3a, 3b are arranged so that the die 1 and the suction hoods 3a, 3b are at an appropriate interval. Are arranged, and the floating fibers can be effectively removed while suppressing the disturbance of the fiber flow 41.
  • the distance between the bottom openings 35a, 35b of the suction hoods 3a, 3b and the outer peripheral surface of the suction roll 2 is substantially constant as a whole.
  • the distance between the suction hoods 3a, 3b and the outer peripheral surface of the suction roll 2 is an interval at which at least at the die 1 side end portions 311a, 311b, the fibers can be removed by suction even if the broken fiber adheres to or contacts the surface of the melt blown nonwoven fabric 4. d Must be set to 2 .
  • the distance d 2 is the distance between the end portions 311 a and 311 b of the suction hoods 3 a and 3 b and the outer peripheral surface of the suction roll 2.
  • the distance d 2 is preferably 10 to 40 mm, and more preferably 15 to 35 mm.
  • the distance d 2 is less than 10 mm, sufficient air does not flow into the suction hoods 3a and 3b, and the removal of floating fibers is insufficient.
  • the distance d 2 is greater than 40 mm, the flow rate of the air flowing into the suction hoods 3a and 3b is too slow, and the floating fibers adhering to or contacting the surface of the melt blown nonwoven fabric 4 cannot be sufficiently removed.
  • the distance between the suction hood 3a and the outer peripheral surface of the suction roll 2 and the distance between the suction hood 3b and the outer peripheral surface of the suction roll 2 may be the same or different.
  • Each suction hood 3a, 3b is not limited to the shape shown in FIG. 1, and pipe portions 34a, 34b connected to an exhaust device (not shown) are further connected in the vicinity of the collection site of the fiber stream 41 as shown in FIG. You may have.
  • the suction hood 3a, 3b are arranged so that the appropriate role coverage, so that the suction hood 3a of the air inlet, a gap d 2 between 3b and the suction roll 2 a suitable distance
  • the suction hoods 3a and 3b arranged in the slab it is possible to effectively remove the suspended fibers while suppressing the disturbance of the fiber flow 41, and thus a melt blown nonwoven fabric made of ultrafine fibers having a small average fiber diameter and a narrow fiber diameter distribution.
  • the method of the present invention for producing a melt blown nonwoven fabric using the above-mentioned apparatus comprises The melted polymer discharged from the spinning nozzle 11c is stretched by heated air ejected from the air nozzles 15 and 15, and the resulting polymer ultrafine fibers are collected on a suction roll, whereby the number average fiber diameter is 1 ⁇ m.
  • the fiber diameter distribution (weight average fiber diameter / number average fiber diameter) is 1.3 or less, a method for producing a melt blown nonwoven fabric composed of ultrafine fibers having a fiber diameter variation rate of 55% or less, (1) By setting the distance between the die 1 and the suction roll 2 within a range where the stretching of the molten polymer is completed and vibration of the obtained polymer fiber does not substantially occur, tangle was suppressed, (2) the outer peripheral surface and the suction hood 3a of the suction roll 2, the die-side end 311a of 3b, and distance d 2 between 311b, fibers yarn breakage on the surface of the melt-blown nonwoven fabric obtained is adhered or It is characterized in that it is set so that it can be removed by suction even if it comes into contact.
  • the obtained melt-blown nonwoven fabric may be subjected to a calendar treatment, a charging treatment, a hydrophilization treatment or the like as necessary.
  • the melt-kneading temperature of the polymer is preferably (melting point of the polymer) to (melting point of the polymer + 280 ° C.).
  • the melt kneading temperature is preferably 160 to 440 ° C, more preferably 170 to 420 ° C.
  • the molten polymer is discharged from a large number of spinning nozzles 11c, and heated air is ejected from the nozzles 15 and 15 to form ultrafine fibers of the polymer.
  • the temperature of the die 1 and the heated air is preferably (the melting point of the polymer) to (the melting point of the polymer + 50 ° C.).
  • the temperature of the die 1 and heated air is preferably 160 to 220 ° C, more preferably 170 to 210 ° C. If the temperature of the die 1 and the heated air is less than the melting point of the polymer, the polymer is rapidly solidified immediately after being discharged from the spinning nozzle 11c, so that stretching is insufficient.
  • the melting point of the polymer exceeds + 50 ° C., the formed polymer ultrafine fiber is easily fused, and the variation in fiber diameter increases.
  • the discharge amount of the molten polymer per spinning nozzle 11c is preferably 50 mg / min or less, more preferably 30 mg / min or less, and most preferably 10 mg / min or less.
  • the lower limit of the discharge amount of the molten polymer is preferably 1 mg / min.
  • the flow velocity of the heated air is preferably 100 m / second or more, more preferably 150 to 300 m / second.
  • the ejection amount of heated air per width is preferably 800 Nm 3 / hr / m or more, more preferably 1,000 to 2,000 Nm 3 / hr / m.
  • the suction amount of the suction roll 2 per width can be appropriately adjusted according to the desired physical properties of the melt blown nonwoven fabric 4, but in order to suppress the fusion of single fibers, an air nozzle 5 or more times the ejection amount per width from 15, 15 is preferable, 10 times or more is more preferable, and 12 times or more is most preferable. If the suction amount of the suction roll 2 is set to 5 times or more of the ejection amount of the heated air, most of the heated air is sucked into the suction roll 2 through the suction hole 22a of the porous cylindrical member 22, and the fiber flow is disturbed. Can be suppressed.
  • the suction amount of the suction roll 2 per width is preferably 10,000 Nm 3 / hr / m or more, and more preferably 15,000 to 25,000 Nm 3 / hr / m.
  • the upper limit of the suction amount of the suction roll 2 is not particularly limited, but is practically 50 times the ejection amount of heated air.
  • the ratio between the total suction amount of the suction hoods 3a and 3b and the suction amount of the suction roll 2 is preferably 0.2 to 0.9. Within the range of the suction amount ratio, most of the heated air flows into the suction area SA to prevent disturbance of the fiber flow, while flowing the remainder of the heated air and the surrounding air into the suction hoods 3a and 3b. Thus, not only the scattered fibers can be removed, but also the floating fibers adhering to or contacting the melt blown nonwoven fabric 4 can be effectively removed.
  • the ratio is more preferably 0.3 to 0.6.
  • the total suction amount of the suction hoods 3a and 3b is preferably 1,000 to 10,000 Nm 3 / hr, and more preferably 2,000 to 5,000 Nm 3 / hr.
  • Rotational speed of the suction roll 2 is preferably 1 to 20 mm / min, more preferably 3 to 15 mm / min.
  • the suction roll 2 may be at room temperature, but may be heated as necessary.
  • Calendar treatment step When the obtained melt-blown nonwoven fabric is subjected to a calendar treatment, not only the mechanical strength is improved, but also the pore diameter is reduced.
  • the calendar treatment can be performed at room temperature.
  • the calendering pressure is preferably 1 to 10 MPa, more preferably 3 to 7 MPa.
  • the melt blown nonwoven fabric can be made into a laminated product by performing a laminating process such as a calendar process.
  • a laminating process such as a calendar process.
  • the melt blown nonwoven fabric is made of polyolefin ultrafine fibers
  • a laminated product in which a decrease in pore diameter is suppressed can be obtained by performing a calendar treatment at room temperature.
  • Conventional non-woven fabrics made of fibers with an average fiber diameter of more than 1 ⁇ m will be peeled off when they are laminated (calendered) at room temperature. Therefore, the fiber is crushed, the pore size is reduced, and the permeability is extremely reduced.
  • the nonwoven fabric made of the ultrafine fiber of the present invention is anchored even when laminated at room temperature.
  • the melt-blown nonwoven fabric may be subjected to a charging treatment such as a corona discharge treatment.
  • the charged nonwoven fabric has a charge amount of about 10 ⁇ 11 to 10 ⁇ 7 coulomb / cm 2 and can electrostatically collect fine particles.
  • the meltblown nonwoven fabric may be subjected to a hydrophilic treatment.
  • the hydrophilization treatment can be performed by monomer grafting, surfactant treatment or the like. In the case of the surfactant treatment, a nonionic surfactant is preferable.
  • melt blown nonwoven fabric of the present invention has the following physical properties. In addition, each physical property was measured by the method as described in the column of an Example.
  • the melt blown nonwoven fabric has a small average pore diameter and a maximum pore diameter, and a high air permeability, and is excellent in fine particle capturing performance.
  • the number average fiber diameter is preferably 0.7 ⁇ m or less, more preferably 0.3 to 0.7 ⁇ m.
  • Weight average fiber diameter of 0.8 ⁇ m or less When the weight average fiber diameter is 0.8 ⁇ m or less, the melt blown nonwoven fabric has a small average pore diameter and a maximum pore diameter, and a high air permeability, and is excellent in fine particle capturing performance.
  • the weight average fiber diameter is preferably 0.3 to 0.8 ⁇ m.
  • Fiber diameter distribution of 1.3 or less (weight average fiber diameter / number average fiber diameter)
  • the meltblown nonwoven fabric has a small average pore diameter and a maximum pore diameter, and is excellent in fine particle capturing performance even if the basis weight is small.
  • the fiber diameter distribution is preferably 1.05 to 1.25.
  • the melt blown nonwoven fabric has a small average pore diameter and a maximum pore diameter, and is excellent in fine particle capturing performance even if the basis weight is small.
  • the fiber diameter fluctuation rate is preferably 50% or less, and more preferably 45% or less.
  • the average pore diameter is preferably 5.5 ⁇ m or less, and more preferably 5 ⁇ m or less.
  • the maximum pore diameter is preferably 10 ⁇ m or less, more preferably 8 ⁇ m or less.
  • Air permeability of 5 mL / cm 2 / sec or more When the air permeability is less than 5 mL / cm 2 / sec, the melt blown nonwoven fabric is clogged quickly.
  • the air permeability is preferably 5 to 30 mL / cm 2 / sec. On the other hand, when the air permeability exceeds 30 mL / cm 2 / sec, the particulate collection efficiency is low.
  • the average basis weight is preferably 1 to 12 g / m 2, more preferably 2 to 10 g / m 2, and most preferably 3 to 9 g / m 2 .
  • the basis weight fluctuation rate of 5% or less When the basis weight fluctuation rate exceeds 5%, the maximum pore diameter is large and the air permeability is not uniform.
  • the basis weight fluctuation rate is preferably 4% or less.
  • Average film thickness of 0.05 to 0.5 mm Melt blown nonwoven fabric having an average film thickness of 0.05 to 0.5 mm is suitable for a filter.
  • filling rate 80-99% porosity
  • the filling rate is preferably 2 to 10%.
  • Tensile strength at break of 1-15 N / 50 mm width (longitudinal direction)
  • a meltblown nonwoven fabric having a longitudinal tensile breaking strength of 1 to 15 N / 50 mm width is suitable for a filter.
  • the tensile strength at break is preferably 1.2 to 13 N / 50 mm width.
  • Fine particle collection rate of 90% or more A fine particle collection rate of 90% or more is suitable for use as a filter.
  • the fine particle collection rate is preferably 95% or more.
  • Example 1 Polypropylene PP prepared using a metallocene polymerization catalyst [MFR (JIS K7210, 2.16 kg, 230 ° C): 1,550 g / 10 min, weight average molecular weight (Mw): 7 ⁇ 10 4 , molecular weight distribution (Mw / Mn) : 2.5, melting point: 155 ° C.], using the apparatus shown in FIGS. 1 to 10, a melt blown nonwoven fabric having a width of 300 mm was produced under the conditions shown in Table 1.
  • the suction hoods 3a and 3b are arranged symmetrically upstream and downstream of the die 1 so that (S 1 + S 2 + S 3 ) in FIG.
  • Example 2 A meltblown nonwoven fabric was produced in the same manner as in Example 1 except that the total gap TG was 0.7 mm (see Table 1).
  • Example 3 A melt blown nonwoven fabric was produced in the same manner as in Example 1 except that the polypropylene discharge amount per spinning nozzle was 6.7 mg / min and the rotation speed of the suction roll was 7.2 m / min (see Table 1).
  • Example 4 Suction hood 3a, by changing the size of 3b, i.e. in FIG. 6, S 3 is evenly reduced only S 1 and S 2 without changing rolls coverage [(S 1 + S 2) / ( A melt blown nonwoven fabric was produced in the same manner as in Example 1 except that S 1 + S 2 + S 3 ) ⁇ 100] was changed to 60% (see Table 1).
  • Example 5 Example 1 except that the sizes of the suction hoods 3a and 3b were changed, that is, in FIG. 6, only S 1 and S 2 were uniformly increased without changing S 3 and the roll coverage was set to 85%. In the same manner, a melt blown nonwoven fabric was produced (see Table 1).
  • Example 6 Using a die with a spinning nozzle length L of 3 mm, a diameter D of 0.1 mm, L / D of 30, a number of spinning nozzles of 1,001 and a total gap TG of 0.5 mm, a melt kneading temperature of 400 °C, the discharge rate of polypropylene per spinning nozzle is 22.5 mg / min, the flow rate and the jet rate of heated air are 225 m / sec and 1,650 Nm 3 / hr / m, respectively, and the ratio of roll suction rate / heated air jet rate Was 11.8, the distance d 1 between the die and the suction roll was 90 mm, and the rotational speed of the suction roll was 11.0 m / min, and a melt blown nonwoven fabric was produced in the same manner as in Example 1 (see Table 1) .
  • Example 7 A melt blown nonwoven fabric was produced in the same manner as in Example 6 except that L / D was 50 and the amount of polypropylene discharged per spinning nozzle was 5.6 mg / min (see Table 1).
  • Example 8 A melt blown nonwoven fabric was prepared in the same manner as in Example 1 except that the hood suction amount was 2,400 Nm 3 / hr and the hood suction amount / roll suction amount ratio was 0.38 (see Table 1).
  • Example 9 A melt blown nonwoven fabric was prepared in the same manner as in Example 1 except that the hood suction amount was 3,600 Nm 3 / hr and the hood suction amount / roll suction amount ratio was 0.58 (see Table 1).
  • Example 10 A melt blown nonwoven fabric in the same manner as in Example 1 except that polypropylene (MFR: 1,200 g / 10 min, weight average molecular weight: 74,000, molecular weight distribution: 3.4, melting point: 158 ° C.) prepared using a metallocene polymerization catalyst was used. (See Table 1).
  • Example 11 The meltblown nonwoven fabric of Example 1 was subjected to corona discharge treatment (applied voltage: 17 kV) (see Table 1).
  • Example 12 The melt blown nonwoven fabric of Example 1 was calendered (pressure: 5 MPa) at room temperature (see Table 1).
  • Example 13 In the same manner the die end of the suction hood and the Example 1 except that the distance d 2 was 30 mm between the suction roll outer surface, to produce a melt-blown nonwoven fabric (see Table 1).
  • Comparative Example 1 As shown in FIG. 13, only on the downstream side of the die 1 of the suction roll 2, using a device provided with a suction hood 301, the suction amount is 6,000 Nm 3 / hr, and the ratio of the hood suction amount / roll suction amount is 0.96.
  • a melt-blown nonwoven fabric was produced in the same manner as in Example 1 except that (see Table 1).
  • the length of the suction hood 301 in the web traveling direction was 700 mm.
  • Comparative Example 2 As shown in FIG. 14, a meltblown nonwoven fabric was prepared in the same manner as in Example 1 except that an apparatus having suction hoods 302a and 302b joined to the die 1 so as to cover the entire fiber flow 41 was used (Table 1). reference).
  • Comparative Example 3 The distance d 1 between the die and the suction roll in the same manner as in Example 1 except that the 0.99 mm, to prepare a melt blown nonwoven fabric (see Table 1).
  • Comparative Example 4 In the same manner the die end of the suction hood and the Example 1 except that the distance d 2 was 5 mm between the suction roll outer surface, to produce a melt-blown nonwoven fabric (see Table 1).
  • Comparative Example 5 The distance d 2 of the die-side end portion of the suction hood and the suction roll outer surface in the same manner as in Example 1 except that the 50 mm, to prepare a melt blown nonwoven fabric (see Table 1).
  • Comparative Example 6 A commercially available polypropylene melt blown nonwoven fabric (trade name “SYNTEX nano”, manufactured by Mitsui Chemicals, Inc.) was used.
  • the average film thickness is obtained by measuring and averaging the film thickness at three locations (50 mm, 150 mm and 250 mm from the edge) with the dial thickness gauge in the width direction of the meltblown nonwoven fabric. It was.
  • Average basis weight is obtained by measuring and averaging the mass (g) of water equilibrium at 10 ° C. and 100 mm ⁇ 100 mm test pieces of melt blown nonwoven fabric at a temperature of 23 ° C. and a humidity of 50%. Asked.
  • Unit weight variation rate (standard deviation of unit weight) / (average unit basis weight) ⁇ 100.
  • the number-average fiber diameter was determined by measuring the fiber diameters up to the order of 0.1 ⁇ m and averaging them for 10 of 10 arbitrary positions from an electron micrograph of the melt-blown nonwoven fabric.
  • FIG. 15 shows the fiber diameter distribution of the melt blown nonwoven fabrics of Examples 1 to 3 and Comparative Example 6.
  • Fiber diameter distribution weight average fiber diameter / number average fiber diameter.
  • Fiber diameter variation rate (%) (standard deviation of fiber diameter / number average fiber diameter) ⁇ 100.
  • Average pore diameter and maximum pore diameter were measured by the bubble point method (ASTM F316-86, JIS K3832) shown below.
  • ASTM F316-86 JIS K3832
  • the pressure P 1 when the air began to permeate the dry test piece was determined, the dry flow curve shown in FIG. 16 was created, and then the half dry flow curve with a permeate flow rate of 1/2 was created.
  • the average pore diameter D AV was determined by the following equation from the pressure P cross at the intersection of the half dry flow curve and the wet flow curve.
  • D AV 4 ⁇ cos ⁇ / (P cross -P 1 ) [Where ⁇ is the surface tension of the solvent, and ⁇ is the contact angle of the solvent with respect to polypropylene. ]
  • Air permeability was measured on a 100 mm x 100 mm melt blown nonwoven fabric test piece according to JIS L 1096 using a Frazier type tester.
  • Filling ratio (%) [average basis weight (g / m 2 ) / average film thickness (m) / resin density (g / m 3 )] ⁇ 100.
  • Tensile strength at break The tensile strength at break in the longitudinal direction at the time of production was measured according to JIS L 1085 for a strip-shaped meltblown nonwoven fabric test piece having a width of 50 mm.
  • non-woven fabric (1 m 2 ) calendered (pressure 5 MPa, room temperature)
  • the number of film-like strips [length 1.4 mm or more, aspect ratio (length / width of the thickest part) 5 or more] was visually observed. And counted as the number of floating fibers.
  • the nonwoven fabrics of Examples 1 to 13 are polypropylene fine fibers having a number average fiber diameter of 1 ⁇ m or less, particularly 0.7 ⁇ m or less, a fiber diameter distribution of 1.3 or less, and a fiber diameter fluctuation rate of 55% or less. Since it consists of fibers, the maximum pore diameter and the average pore diameter were small even when the basis weight was small, and the air permeability, tensile breaking strength, fine particle collecting property and appearance were excellent.
  • the melt blown nonwoven fabric of Example 11 subjected to the charging treatment and Example 12 subjected to the calendar treatment exhibited a better particle collecting ability.
  • the melt blown nonwoven fabric of Comparative Example 1 manufactured with an apparatus provided with a suction hood only on the downstream side from the die 1 of the suction roll, the weight average fiber diameter, fiber diameter distribution, fiber diameter fluctuation rate, maximum compared to Examples 1-13
  • the pore diameter, average pore diameter and basis weight fluctuation rate were large, the particulate collection rate was inferior, and there were many floating fibers.
  • the melt blown nonwoven fabric of Comparative Example 2 produced under the condition where the roll coverage was 100% was compared with Examples 1 to 13 in terms of number average fiber diameter, weight average fiber diameter, fiber diameter distribution, fiber diameter fluctuation rate, maximum fineness.
  • the pore diameter, average pore diameter, and basis weight fluctuation rate were large, so that the particulate collection rate was inferior and the resin mass was also large.
  • Comparative Example 2 since the fiber flow was covered with a suction hood, the fiber flow spread and cooling was insufficient, which is considered to be a cause of the above-described deterioration in performance.
  • the melt blown nonwoven fabric of Comparative Example 3 produced under the condition that the distance between the die and the suction roll was over 100 mm was compared with Examples 1 to 13 in number average fiber diameter, weight average fiber diameter, fiber diameter distribution, fiber diameter
  • the fluctuation rate, the maximum pore diameter, the average pore diameter, and the basis weight fluctuation rate were large, so that the particulate collection rate was inferior and there were many floating fibers.
  • the melt blown nonwoven fabric of Comparative Example 4 manufactured under the condition that the distance d 2 between the die side end of the suction hood and the outer peripheral surface of the roll is less than 10 mm has a suction speed by the suction hood as compared with Examples 1 to 13.
  • Strengthening, number average fiber diameter, weight average fiber diameter, fiber diameter distribution, fiber diameter fluctuation rate, maximum pore diameter, average pore diameter and basis weight fluctuation rate are large, so it is inferior in particulate collection rate and also has a lot of resin mass .
  • the melt blown nonwoven fabric of Comparative Example 5 manufactured under the condition that the distance d 2 between the die side end of the suction hood and the outer peripheral surface of the roll was more than 40 mm was compared with Examples 1 to 13 in terms of fiber diameter distribution and fiber diameter fluctuation.
  • the rate and the basis weight fluctuation rate were large, the particle collection rate was inferior, and there were many floating fibers.
  • the commercially available polypropylene melt blown nonwoven fabric (commercial name “SYNTEX nano”, manufactured by Mitsui Chemicals, Inc.) of Comparative Example 6 has an average basis weight, a weight average fiber diameter, a fiber diameter distribution, and a fiber diameter variation rate as compared with Examples 1 to 13.
  • the air permeability was poor.
  • Example 14 A six-layer product having a thickness of 0.1 mm and comprising six ultrafine fiber nonwoven fabrics obtained in Example 1 was prepared by the following procedure by laminating using a calender roll. Two ultrafine fiber nonwoven fabrics obtained in Example 1 were laminated at room temperature with a roll interval of about 0.04 mm to produce a two-layer product (thickness of about 0.08 mm). The four-layer product (thickness: about 0.14 mm) was produced again by the above process, and the four-layer product and the two-layer product were further laminated at room temperature with a roll interval of about 0.08 mm to produce a six-layer product. .
  • Example 15 The 4-layer product and 2-layer product produced in Example 14 were laminated at room temperature with a roll interval of about 0.16 mm in the same manner as in Example 14 to produce a 6-layer product having a thickness of 0.2 mm.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Nonwoven Fabrics (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

L'invention concerne une étoffe non tissée en fibres ultrafines, présentant d'excellentes caractéristiques de piégeage de particules fines et de perméabilité à l'air, obtenue par un procédé de fusion-soufflage utilisant : une filière (1) dotée d'une pluralité de buses de filage ultrafines et une buse à air ; un rouleau tournant (2) à aspiration qui est doté d'une surface périphérique extérieure poreuse et qui aspire par son intérieur ; et une paire de hottes supérieure et inférieure (3a, 3b) d'aspiration recouvrant le rouleau (2) à aspiration. Ledit procédé de fusion-soufflage est caractérisé en ce que : l'intervalle entre la filière (1) et le rouleau (2) à aspiration est réglé de façon à limiter la rupture et la torsion des fibres de polymère, dans une gamme assurant l'étirement d'un polymère fondu tout en supprimant sensiblement les vibrations de la fibre de polymère obtenue ; et les intervalles entre la surface périphérique extérieure du rouleau (2) à aspiration et la section d'extrémité des hottes (3a, 3b) d'aspiration côté filière sont réglés de telle façon que des fibres qui se sont cassées et fixées ou ont adhéré par fusion à la surface de l'étoffe non tissée obtenue par fusion-soufflage puissent être éliminées par aspiration.
PCT/JP2012/051887 2011-01-28 2012-01-27 Etoffe non tissée obtenue par fusion-soufflage comportant des fibres ultrafines, procédé et dispositif pour sa production WO2012102398A1 (fr)

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JP2012554874A JP5905400B2 (ja) 2011-01-28 2012-01-27 極細繊維からなるメルトブロー不織布の製造方法及び極細繊維からなるメルトブロー不織布を製造するための装置
CN201280006732.0A CN103380242B (zh) 2011-01-28 2012-01-27 由极细纤维构成的熔喷无纺布、该熔喷无纺布的制造方法及用于制造该熔喷无纺布的装置

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