WO2012098408A2 - Improved drying method - Google Patents

Improved drying method Download PDF

Info

Publication number
WO2012098408A2
WO2012098408A2 PCT/GB2012/050121 GB2012050121W WO2012098408A2 WO 2012098408 A2 WO2012098408 A2 WO 2012098408A2 GB 2012050121 W GB2012050121 W GB 2012050121W WO 2012098408 A2 WO2012098408 A2 WO 2012098408A2
Authority
WO
WIPO (PCT)
Prior art keywords
particles
polymeric
drying
polymeric particles
particulate material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2012/050121
Other languages
English (en)
French (fr)
Other versions
WO2012098408A3 (en
Inventor
Stephen Derek Jenkins
Frazer John Kennedy
Stephen Martin Burkinshaw
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xeros Ltd
Original Assignee
Xeros Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to KR1020137021107A priority Critical patent/KR101725174B1/ko
Priority to BR112013018255A priority patent/BR112013018255A2/pt
Priority to HK14100796.0A priority patent/HK1187657B/xx
Priority to JP2013549893A priority patent/JP6066926B2/ja
Priority to AU2012208380A priority patent/AU2012208380B2/en
Priority to EP12701368.8A priority patent/EP2665855B1/en
Priority to DK12701368.8T priority patent/DK2665855T3/en
Priority to CA2823813A priority patent/CA2823813C/en
Application filed by Xeros Ltd filed Critical Xeros Ltd
Priority to US13/980,325 priority patent/US9127882B2/en
Priority to CN201280005596.3A priority patent/CN103443349B/zh
Priority to ES12701368.8T priority patent/ES2542083T3/es
Publication of WO2012098408A2 publication Critical patent/WO2012098408A2/en
Anticipated expiration legal-status Critical
Publication of WO2012098408A3 publication Critical patent/WO2012098408A3/en
Ceased legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F58/00Domestic laundry dryers
    • D06F58/30Drying processes 
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B3/00Drying solid materials or objects by processes involving the application of heat
    • F26B3/02Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B3/00Drying solid materials or objects by processes involving the application of heat
    • F26B3/18Drying solid materials or objects by processes involving the application of heat by conduction, i.e. the heat is conveyed from the heat source, e.g. gas flame, to the materials or objects to be dried by direct contact
    • F26B3/20Drying solid materials or objects by processes involving the application of heat by conduction, i.e. the heat is conveyed from the heat source, e.g. gas flame, to the materials or objects to be dried by direct contact the heat source being a heated surface, e.g. a moving belt or conveyor
    • F26B3/205Drying solid materials or objects by processes involving the application of heat by conduction, i.e. the heat is conveyed from the heat source, e.g. gas flame, to the materials or objects to be dried by direct contact the heat source being a heated surface, e.g. a moving belt or conveyor the materials to be dried covering or being mixed with heated inert particles which may be recycled
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F2103/00Parameters monitored or detected for the control of domestic laundry washing machines, washer-dryers or laundry dryers
    • D06F2103/02Characteristics of laundry or load
    • D06F2103/08Humidity
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F2103/00Parameters monitored or detected for the control of domestic laundry washing machines, washer-dryers or laundry dryers
    • D06F2103/28Air properties
    • D06F2103/34Humidity
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F2103/00Parameters monitored or detected for the control of domestic laundry washing machines, washer-dryers or laundry dryers
    • D06F2103/38Time, e.g. duration
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F2103/00Parameters monitored or detected for the control of domestic laundry washing machines, washer-dryers or laundry dryers
    • D06F2103/44Current or voltage
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F2105/00Systems or parameters controlled or affected by the control systems of washing machines, washer-dryers or laundry dryers
    • D06F2105/46Drum speed; Actuation of motors, e.g. starting or interrupting
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F58/00Domestic laundry dryers
    • D06F58/02Domestic laundry dryers having dryer drums rotating about a horizontal axis
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F58/00Domestic laundry dryers
    • D06F58/20General details of domestic laundry dryers 

Definitions

  • the present invention relates to the drying of textile fibres and fabrics in a tumble dryer using a system which utilises only limited quantities of energy, and which reduces drying-related creasing and associated textile fabric damage.
  • the invention provides a method adapted for use in this context.
  • Tumble drying processes are a mainstay of both domestic and industrial textile fabric cleaning procedures and typically involve placing the textiles in a container such as a perforated cylindrical drum which is rotated in alternating clockwise and anticlockwise cycles whilst hot air is introduced into the drum through the perforations.
  • a container such as a perforated cylindrical drum which is rotated in alternating clockwise and anticlockwise cycles whilst hot air is introduced into the drum through the perforations.
  • a combination of the hot air treatment and the mechanical action of the tumbling process causes water to be expelled from the textile materials in order that drying is achieved.
  • Performance levels in the domestic sector generally set the highest standard for an efficient fabric drying process. Energy consumption in industrial tumble drying is usually higher, due to the need for faster cycle times. It is also noteworthy that, overall, tumble drying is significantly less efficient than washing as a component part of the laundry process in either sector.
  • Heating of the circulating air is the principal use of energy in such tumble dryers and the present inventors have therefore sought to effect improvements in the prior art processes by reducing the temperature levels required in such processes.
  • Mechanical action in a conventional, horizontal axis tumble dryer is generated by the forces acting on the fabric through falling and hitting either other fabric or the dryer inner drum surface, whilst the fabric is interacting with the forced hot air flow. This results in release and evaporation of water from within the fabric, and hence drying.
  • alteration of the mechanical action of the process in order to promote more localised release and evaporation of water at the fabric surface has resulted in lower drying temperatures.
  • the present inventors have sought to devise a new approach to the drying problem, which allows the above deficiencies associated with the methods of the prior art to be overcome.
  • the method which is provided eliminates the requirement for the use of high drying temperatures for extended periods of time, but is still capable of providing an efficient means of water removal, so yielding economic and environmental benefits.
  • the method which is provided also promotes fabric care through reduced creasing and fewer requirements for subsequent ironing.
  • WO-A-2007/128962 there is disclosed a method and formulation for cleaning a soiled substrate, the method comprising the treatment of the moistened substrate with a formulation comprising a multiplicity of polymeric particles, wherein the formulation is free of organic solvents.
  • the substrate comprises a textile fibre and the polymeric particles may, for example, comprise particles of polyamides, polyesters, polyalkenes, polyurethanes or their copolymers, but are most preferably in the form of nylon particles.
  • the present invention derives from an appreciation on the part of the inventors that optimum drying performance can be achieved as a result of improved mechanical interaction between substrate and physical media. This can be effected by the use of solid particles in the drying process and is a function of the number, size and mass of the particles and the free volume within the vessel in which the drying operation takes place, in addition to the G force dictated by its speed of rotation.
  • Free volume in this context refers to the space inside the vessel which remains unoccupied by wet substrate or particulate media, and G force is defined on the basis of the centripetal forces which are acting.
  • a method for the drying of a wet substrate comprising treating the substrate with a solid particulate material at ambient or elevated temperature, said treatment being carried out in an apparatus comprising a drum comprising perforated side walls, wherein said drum comprising perforated side walls is rotated so as to facilitate increased mechanical action between said substrate and said particulate material.
  • said drum comprising perforated side walls has a capacity of between 5 and 50 litres for each kg of substrate.
  • said drum is rotated at a speed which generates G forces in the range of from 0.05 to 0.99 G.
  • the drum comprising perforated side walls comprises a rotatably mounted cylindrical cage.
  • said solid particulate material comprises a multiplicity of particles which may be polymeric, non-polymeric or mixtures thereof, and which may be added at a particle to fabric addition level of 0.1 :1 -10:1 by mass.
  • the size of said particles determines the number of particles which are present in a process according to the invention.
  • Each particle may have a smooth or irregular surface structure, can be of solid or hollow construction, and is of such a shape and size to allow for good flowability and intimate contact with the soiled substrate, which typically comprises a textile fabric.
  • a variety of shapes of particles can be used, such as cylindrical, spherical or cuboid; appropriate cross-sectional shapes can be employed including, for example, annular ring, dog-bone and circular. Most preferably, however, said particles comprise cylindrical or spherical particles.
  • Polymeric particles typically have an average density in the range of 0.5-2.5 g/cm 3 , more typically from 0.55-2.0 g/cm 3 , more typically from 0.6-1.9 g/cm 3 .
  • Non- polymeric particles generally have an average density in the range of from 3.5-12.0 g/cm 3 , more typically from 5.0-10.0 g/cm 3 , most typically from 6.0-9.0 g/cm 3 .
  • the average volume of both the non-polymeric and polymeric particles is typically in the range of 5-275 mm 3 , more typically from 8-140 mm 3 , most typically from 10-120 mm 3 .
  • the major cross section axis length, a is typically in the range of from 2.0- 6.0 mm, more typically from 2.2-5.0 mm, most typically from 2.4-4.5 mm
  • the minor cross section axis length, b is typically in the range of from 1.3-5.0 mm, more typically from 1.5-4.0 mm, and most typically from 1.7-3.5 mm (a > b).
  • the length of such particles, h is typically from 1.5-6.0 mm, more typically from 1.7-5.0 mm, and most typically from 2.0-4.5 mm (h/b is typically in the range of from 0.5-10).
  • the typical cross section diameter, d c is in the range of from 1.3-6.0 mm, more typically from 1.5-5.0 mm, and most typically from 1.7-4.5 mm.
  • the typical length, h c of such particles is again from 1.5-6.0 mm, more typically from 1.7-5.0 mm, and most typically from 2.0-4.5 mm (hc/d c is typically in the range of from 0.5-10).
  • the diameter, d s is typically in the range of from 2.0-8.0 mm, more typically in the range of from 2.2-5.5 mm, and most typically from 2.4-5.0 mm.
  • the diameter, d ps is typically in the range of from 2.0-8.0 mm, more typically from 3.0-7.0 mm, and most typically from 4.0-6.5 mm.
  • Polymeric particles may comprise either foamed or unfoamed polymeric materials. Furthermore, the polymeric particles may comprise polymers which are either linear or crosslinked.
  • Preferred polymeric particles comprise polyalkenes such as polyethylene and polypropylene, polyamides, polyesters or polyurethanes.
  • said polymeric particles comprise polyamide or polyester particles, most particularly particles of nylon, polyethylene terephthalate or polybutylene terephthalate.
  • copolymers of the above polymeric materials may be employed for the purposes of the invention.
  • the properties of the polymeric materials may be tailored to individual requirements by the inclusion of monomeric units which confer particular properties on the copolymer.
  • the copolymers may be adapted to attract moisture by comprising monomers which, inter alia, are hydrophilic through being ionically charged or including polar moieties or unsaturated organic groups.
  • Non-polymeric particles may comprise particles of glass, silica, stone, wood, or any of a variety of metals or ceramic materials.
  • Suitable metals include, but are not limited to, zinc, titanium, chromium, manganese, iron, cobalt, nickel, copper, tungsten, aluminium, tin and lead, and alloys thereof.
  • Suitable ceramics include, but are not limited to, alumina, zirconia, tungsten carbide, silicon carbide and silicon nitride. It is seen that non-polymeric particles made from naturally occurring materials (e.g. stone) can have various shapes, depending on their propensity to cleave in different ways during manufacture.
  • said non-polymeric particles may comprise coated non-polymeric particles.
  • said non-polymeric particles may comprise a non-polymeric core material and a shell comprising a coating of a polymeric material.
  • said core may comprise a metal core, typically a steel core, and said shell may comprise a polyamide coating, for example a coating of nylon.
  • the selection of specific particle type (polymeric and non-polymeric) for a given drying operation is particularly important in optimising fabric care.
  • particle size, shape, mass and material must all be considered carefully in respect of the particular substrate which is to be dried, so that particle selection is dependent on the nature of the garments to be dried, i.e. whether they comprise cotton, polyester, polyamide, silk, wool, or any of the other common textile fibres or blends which are commonly in use.
  • G is a function of the drum size and the speed of rotation of the drum and, specifically, is the ratio of the centripetal force generated at the inner surface of the cage to the static weight of the wet substrate.
  • the claimed method additionally provides, on completion of the drying process, for separation and recovery of the particles comprised in the solid particulate material, which are then re-used in subsequent drying procedures.
  • Said rotatably mounted cylindrical cage is comprised in any suitable tumble drying apparatus comprising a housing and access means, allowing access to the interior of said cylindrical cage.
  • said apparatus may comprise:
  • said rotatably mounted cylindrical cage comprises a drum comprising perforated side walls, wherein up to 60% of the surface area of said side walls comprises perforations, and said perforations comprise holes having a diameter of no greater than 25.0 mm.
  • Said drying process also comprises the introduction of either ambient or heated air into said drum comprising perforated side walls. If said air is heated, this is achieved by means of any commercially available air heater and circulated using a fan so as to achieve a temperature of between 5° and 120°C, preferably between 10° and 90°C, most preferably between 20° and 80°C in the apparatus.
  • the temperature of ambient air is dependent on the surroundings in which the drying process is running, but this can typically vary from 5-20°C.
  • drying operations according to the invention are typically carried out at temperatures which are 20°C lower than with prior art processes, whilst achieving equivalent drying performance for the same time of treatment.
  • Figure 1 is a diagrammatic representation of particles which are employed in the method of the invention.
  • Figure 2 is a graphical representation of the efficiency of the drying process according to an embodiment of the invention.
  • Figure 3 a graphical representation of the efficiency of the drying process according to a further embodiment of the invention.
  • said access means typically comprises a hinged door mounted in the casing, which may be opened to allow access to the inside of the cylindrical cage, and which may be closed in order to provide a substantially sealed system.
  • the door includes a window.
  • Said rotatably mounted cylindrical cage is mounted horizontally within said housing means. Consequently, in preferred embodiments of the invention, said access means is located in the front of the apparatus, providing a front-loading facility.
  • Rotation of said rotatably mounted cylindrical cage is effected by use of drive means, which typically comprises electrical drive means, in the form of an electric motor. Operation of said drive means is effected by control means which may be programmed by an operative.
  • drive means typically comprises electrical drive means, in the form of an electric motor.
  • control means which may be programmed by an operative.
  • Said rotatably mounted cylindrical cage is of the size which is to be found in most domestic or industrial tumble driers, and may have a capacity in the region of 50 to 7000 litres.
  • a typical capacity for a domestic machine would be in the region of 80 to 140 litres and, for an industrial machine, this range would typically be from 170 to 2000 litres.
  • Said rotatably mounted cylindrical cage is located within a first upper chamber of said housing means and beneath said first upper chamber is located a second lower chamber which functions as a collection chamber for said solid particulate material.
  • Said housing means is connected to standard plumbing features, thereby providing recirculation means, for returning said solid particulate material from said lower chamber, and delivery means, by virtue of which said solid particulate material may be returned to said cylindrical cage.
  • said apparatus additionally comprises means for circulating air within said housing means, and for adjusting the temperature therein.
  • Said means may typically include, for example, a recirculating fan and an air heater.
  • sensing means may also be provided for determining the temperature and humidity levels within the apparatus, and for communicating this information to the control means.
  • Said apparatus comprises recirculation means, thereby facilitating recirculation of said solid particulate material from said lower chamber to said rotatably mounted cylindrical cage, for re-use in drying operations.
  • said recirculation means comprises ducting connecting said second chamber and said rotatably mounted cylindrical cage.
  • said ducting comprises control means, adapted to control entry of said solid particulate material into said cylindrical cage.
  • said control means comprises a valve located in feeder means, preferably in the form of a feed tube attached to the apex of a receptor vessel located above, and connected to the interior of, said cylindrical cage.
  • Recirculation of solid particulate matter from said lower chamber to said rotatably mounted cylindrical cage is achieved by the use of pumping means comprised in said recirculation means, wherein said pumping means are adapted to deliver said solid particulate matter to said control means, adapted to control the re-entry of said solid particulate matter into said rotatably mounted cylindrical cage.
  • said recirculation means comprises a vacuum pumping system.
  • cleaned garments containing residual moisture are first placed into said rotatably mounted cylindrical cage.
  • the cylindrical cage is caused to rotate and ambient or heated air is introduced via the perforations in the cage before the solid particulate material is added.
  • water is caused to be removed from the garments by evaporation and a quantity of the solid particulate material falls through the perforations in the cage and into the second chamber of the apparatus.
  • the solid particulate material is re-circulated via the recirculation means such that it is returned, in a manner controlled by said control means, to the cylindrical cage for continuation of the drying operation. This process of continuous circulation of the solid particulate material occurs throughout the drying operation until drying is completed.
  • the solid particulate material which exits through the perforations in the walls of said rotatably mounted cylindrical cage and into said second chamber is carried to the top side of said rotatably mounted cylindrical cage, wherein it is caused, by means of gravity and operation of the control means, to fall back into said cage, thereby to continue the drying operation.
  • pumping of fresh and recycled solid particulate material proceeds at a rate sufficient to maintain approximately the same level of material in said rotatably mounted cylindrical cage throughout the drying operation, and to ensure that the ratio of particulate material to substrate stays substantially constant until the cycle has been completed.
  • any remaining solid particulate material on said at least one substrate may be easily removed by shaking the at least one substrate. If necessary, however, further remaining solid particulate material may be removed by suction means, preferably comprising a vacuum wand.
  • Said rotatably mounted cylindrical cage more preferably has a volume of between 5 and 50 litres for each kg of fabric in the load. Preferred rates of rotation of said rotatably mounted cylindrical cage are sufficient to give G forces of between 0.05 and 0.99 G. Typically the drying process and the subsequent separation of the particles from the fabric are both carried out within this G range. After separation, the particles are recovered for use in subsequent drying procedures.
  • said apparatus operates in conjunction with wet substrates and drying media comprising a solid particulate material, which is most preferably in the form of a multiplicity of particles which may be polymeric, non-polymeric, or mixtures of both polymeric and non-polymeric particles. All particles may be solid or hollow in their structure and the polymeric particles may be foamed or unfoamed and linear or crosslinked. These particles are required to be efficiently circulated to promote optimum performance and the apparatus, therefore, preferably includes circulation means.
  • the inner surface of the cylindrical side walls of said rotatably mounted cylindrical cage preferably comprises a multiplicity of spaced apart elongated protrusions affixed essentially perpendicularly to said inner surface.
  • said protrusions additionally comprise air amplifiers which are typically driven pneumatically and are adapted so as to promote circulation of a current of heated air within said cage.
  • said apparatus comprises from 3 to 10, most preferably 4, of said protrusions, which are commonly referred to as lifters.
  • the method of the invention may be applied to the drying of any of a wide range of substrates including, for example, plastics materials, leather, metal or wood.
  • said method is principally applied to the drying of wet substrates comprising textile fibres and fabrics, and has been shown to be particularly successful in achieving efficient drying of textile fabrics which may, for example, comprise either natural fibres, such as cotton, or man-made and synthetic textile fibres, for example nylon 6,6, polyester, cellulose acetate, or fibre blends thereof.
  • the solid particulate material comprises a multiplicity of particles which may be polymeric, non-polymeric, or mixtures thereof.
  • Typical polymeric particles may comprise polyamide or polyester particles, most particularly particles of nylon, polyethylene terephthalate or polybutylene terephthalate, or copolymers thereof, most preferably in the form of beads, which may be solid or hollow in their structure.
  • the polymers may be foamed or unfoamed, and may be linear or crosslinked.
  • Various nylon or polyester homo- or co-polymers may be used including, but not limited to, Nylon 6, Nylon 6,6, polyethylene terephthalate and polybutylene terephthalate.
  • the nylon comprises Nylon 6,6 homopolymer having a molecular weight in the region of from 5000 to 30000 Daltons, preferably from 10000 to 20000 Daltons, most preferably from 15000 to 16000 Daltons.
  • the polyester will typically have a molecular weight corresponding to an intrinsic viscosity measurement in the range of from 0.3-1.5 dl/g as measured by a solution technique such as ASTM D-4603.
  • Suitable non-polymeric particles may comprise particles of glass, silica, stone, wood, or any of a variety of metals or ceramic materials.
  • Suitable metals include, but are not limited to, zinc, titanium, chromium, manganese, iron, cobalt, nickel, copper, tungsten, aluminium, tin and lead, and alloys thereof.
  • Suitable ceramics include, but are not limited to, alumina, zirconia, tungsten carbide, silicon carbide and silicon nitride. It is seen that non-polymeric particles made from naturally occurring materials (e.g. stone) can have various shapes, depending on their propensity to cleave in different ways during manufacture.
  • Said solid particulate cleaning material may be comprised entirely of polymeric particles or entirely of non-polymeric particles, or may comprise mixtures of both types of particles.
  • the ratio of polymeric particles to non-polymeric particles may be anywhere from 99.9%:0.1% to 0.1%:99.9% w/w.
  • the ratio of solid particulate material to substrate is generally in the range of from 0.1 :1 to 10:1 w/w, preferably in the region of from 1.0:1 to 7:1 w/w, with particularly favourable results being achieved using polymeric particles at a ratio of between 3:1 and 5:1 w/w, and especially at around 4:1 w/w.
  • polymeric particles at a ratio of between 3:1 and 5:1 w/w, and especially at around 4:1 w/w.
  • 20 g of polymeric particles would be employed in one embodiment of the invention.
  • the ratio of solid particulate material to substrate is maintained at a substantially constant level throughout the drying cycle.
  • the method of the present invention may be used for either small or large scale batchwise processes and finds application in both domestic and industrial drying processes.
  • the method of the invention finds particular application in the drying of textile fabrics.
  • the conditions employed in such a system do, however, allow the use of significantly reduced temperatures from those which typically apply to the conventional tumble drying of textile fabrics and, as a consequence, offer significant environmental and economic benefits.
  • typical procedures and conditions for the drying cycle require that fabrics are generally treated according to the method of the invention at, for example, temperatures of between 20 and 80°C for a duration of between 5 and 55 minutes. Thereafter, additional time is required for the completion of the particle separation stage of the overall process, so that the total duration of the entire cycle is typically in the region of 1 hour.
  • the method of the invention also shows benefits in terms of reducing drying- related fabric damage.
  • fabric creasing readily occurs in conventional tumble drying, and this acts to concentrate the stresses from the mechanical action of the drying process at each crease, resulting in localised fabric damage.
  • Prevention of such fabric damage (or fabric care) is of primary concern to the domestic consumer and industrial user.
  • the addition of particles according to the method of the invention effectively reduces creasing in the process by acting as a pinning layer on the fabric surface in order to help prevent the folding action.
  • the particles also inhibit interaction between separate pieces of fabric in the drying process by acting as a separation or spacing layer, thereby reducing entanglement which is another major cause of localised fabric damage.
  • mechanical action is still present but, critically, this is much more uniformly distributed as a result of the action of the particles. It is the localised aspect of the damage that determines the lifetime of a garment under multiple drying processes.
  • the method of the present invention provides for enhanced performance in comparison with the methods of the prior art under equivalent energy conditions; alternatively, equivalent drying performance may be achieved at lower levels of energy, together with reduced fabric damage.
  • the solid particulate material is continually falling out of the rotatably mounted cylindrical cage through its perforations, and is being recycled and added, together with fresh material, via the control means. This process may either be controlled manually, or operated automatically.
  • the rate of exit of the solid particulate material from the rotatably mounted cylindrical cage is essentially controlled by means of its specific design.
  • the key parameters in this regard include the size of the perforations, the number of perforations, the arrangement of the perforations within the cage and the G force (or rotational speed) which is employed.
  • the perforations should be sized so as to be at least the size of the largest dimension of the particles comprised in the solid particulate material, in order that these particles are able to exit from the cage.
  • optimum separation of particles from fabric is achieved when the perforations are sized at around 1-3 times the largest particle dimension which, typically, results in perforations having a diameter of between 2.0 and 25.0 mm.
  • a rotatably mounted cylindrical cage would be drilled so that only around 34% of the surface area of the cylindrical walls of the cage comprises perforations. Whilst restricting air flow, this allows for greater retention of solid particulate material in the drying load.
  • the perforations may be banded in stripes or distributed evenly over the cylindrical walls of the rotatably mounted cylindrical cage, or could even be exclusively located, for example, in one half of the cage.
  • Conventional commercial vented tumble dryers e.g. DanubeTM - Model Number TD2005/10E
  • Conventional commercial vented tumble dryers typically have perforations of 6.5 mm diameter, and these are drilled at maximum areal density, such that they are distributed closely packed (1 mm apart) over the cylindrical cage wall. This equates to some 56% of the surface area of the cylindrical walls of the cage comprising perforations which ensures good air flow through the drying load, and this cage geometry is also found to be suitable for the successful performance of the method of the present invention.
  • the rate of exit of the solid particulate material from the rotatably mounted cylindrical cage is also affected by the speed of rotation of said cage, with higher rotation speeds increasing the G force, although at G > 1 the fabric adheres to the sides of the cage and prevents exit of the particulate material.
  • slower rotational speeds have been found to provide optimum results in this regard, as they allow the particles to fall from the fabric and through the perforations as the fabric opens out more during tumbling.
  • Rotational speeds resulting in a G force of ⁇ 1 are therefore required ( ⁇ 42 rpm in a 98 cm diameter cage, for example).
  • the G force (or rotational speed) is also controlled so as to maximise the beneficial effect of the mechanical action of the particulate material on the substrate, and the most suitable G is generally found to be in the region of 0.9 G (e.g. 40 rpm in a 98 cm diameter cage).
  • the method of the invention has been shown to be successful in the removal of particulate material from the dried substrate after processing and tests with cylindrical polyester particles, and nylon particles comprising either Nylon 6 or Nylon 6,6 polymer, have indicated particle removal efficacy such that on average ⁇ 5 particles per garment remain in the load at the end of the particle separation cycle. Generally, this can be further reduced to an average of ⁇ 2 particles per garment and, in optimised cases wherein a 20 minute separation cycle is employed, complete removal of particles is typically achieved.
  • the method of the invention is believed to comprise the mechanical action of the particles against a cloth so as to liberate the moisture trapped between fibres, and the pick up of this moisture on the particle surface, wherein rapid evaporation occurs of the thin film of water which is formed.
  • Certain polymeric particles also have the ability to absorb moisture to a larger extent (Nylon 6 and Nylon 6,6 being examples). It may be the case, therefore, that some such absorption is also contributing to the drying mechanism.
  • a drying procedure was carried out by adding a solid particulate material comprising 4 kg of Nylon 6,6 particles (DuPont Zytel ® 101 NC010) to a mesh bag with 1 kg (dry mass) of a cloth substrate, which had been wetted with 10°C water. Details of the particles are set out in Table 1 and an illustration of these cylindrical particles is provided in Figure 1.
  • the substrate was made up of the same type of article in each case (cotton pillowcases). This bag was then loaded into a conventional commercial vented tumble dryer (DanubeTM - Model Number TD 2005/10E). The dryer was set to rotate at 48 rpm which, with a drum diameter of 74 cm, resulted in a centripetal force on the bag and its contents of 0.95 G. The dryer operating temperature was set to 20°, 30°, 40°, or 60°C for individual separate drying tests, and repeat experiments were performed without particles present (i.e. fabric only) to act as controls. The heat up rate programmed into the dryer was 2.0°C/min.
  • Table 3 and Figure 3 provide a comparative illustration of the drying efficacy which is achieved when heated particles are employed. These data effectively provide an illustration of the benefits associated with heat retention in the particles for a subsequent drying process.
  • the particles were pre-heated in a separate tumble dryer to 60°C (measured by an in-situ remote temperature recorder) in order to simulate heated particles from a previous cycle.
  • These hot particles were then quickly added to the mesh bag with wet cloth as before, and tumbled in the DanubeTM dryer at 20°C (the test denoted 'Particles 60°C/Dryer 20°C). As previously therefore, this was effectively ambient temperature with the heaters in the dryer switched off. With heated particles, the drying efficiency increased to 0.48% water removed/minute, vs. the test from Example 1 with the particles at 20°C, which gave only 0.28% water/min.

Landscapes

  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Drying Of Solid Materials (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatment Of Fiber Materials (AREA)
PCT/GB2012/050121 2011-01-19 2012-01-19 Improved drying method Ceased WO2012098408A2 (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
DK12701368.8T DK2665855T3 (en) 2011-01-19 2012-01-19 IMPROVED drying method
HK14100796.0A HK1187657B (en) 2011-01-19 2012-01-19 Improved drying method
JP2013549893A JP6066926B2 (ja) 2011-01-19 2012-01-19 改良された乾燥方法
AU2012208380A AU2012208380B2 (en) 2011-01-19 2012-01-19 Improved drying method
EP12701368.8A EP2665855B1 (en) 2011-01-19 2012-01-19 Improved drying method
CA2823813A CA2823813C (en) 2011-01-19 2012-01-19 Method for drying a wet substrate using perforated drum and particulate material
US13/980,325 US9127882B2 (en) 2011-01-19 2012-01-19 Drying method
KR1020137021107A KR101725174B1 (ko) 2011-01-19 2012-01-19 개선된 건조 방법
BR112013018255A BR112013018255A2 (pt) 2011-01-19 2012-01-19 método de secagem aperfeiçoado
CN201280005596.3A CN103443349B (zh) 2011-01-19 2012-01-19 改善的干燥方法
ES12701368.8T ES2542083T3 (es) 2011-01-19 2012-01-19 Método de secado mejorado

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1100918.0 2011-01-19
GBGB1100918.0A GB201100918D0 (en) 2011-01-19 2011-01-19 Improved drying method

Publications (2)

Publication Number Publication Date
WO2012098408A2 true WO2012098408A2 (en) 2012-07-26
WO2012098408A3 WO2012098408A3 (en) 2013-07-25

Family

ID=43736674

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2012/050121 Ceased WO2012098408A2 (en) 2011-01-19 2012-01-19 Improved drying method

Country Status (13)

Country Link
US (1) US9127882B2 (https=)
EP (1) EP2665855B1 (https=)
JP (1) JP6066926B2 (https=)
KR (1) KR101725174B1 (https=)
CN (1) CN103443349B (https=)
AU (1) AU2012208380B2 (https=)
BR (1) BR112013018255A2 (https=)
CA (1) CA2823813C (https=)
DK (1) DK2665855T3 (https=)
ES (1) ES2542083T3 (https=)
GB (1) GB201100918D0 (https=)
TW (1) TWI561785B (https=)
WO (1) WO2012098408A2 (https=)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014147390A1 (en) * 2013-03-20 2014-09-25 Xeros Limited Improved drying apparatus and method
WO2014147389A1 (en) * 2013-03-20 2014-09-25 Xeros Limited Improved cleaning apparatus and method
WO2014147391A1 (en) * 2013-03-20 2014-09-25 Xeros Limited New cleaning apparatus and method
WO2014170226A1 (en) 2013-04-17 2014-10-23 Crown Packaging Technology Inc Can production process
US9121000B2 (en) 2010-09-14 2015-09-01 Xeros Limited Cleaning method
US9127882B2 (en) 2011-01-19 2015-09-08 Xeros Limited Drying method
US9523169B2 (en) 2013-11-25 2016-12-20 Xeros Limited Cleaning apparatus and method
US9803307B2 (en) 2011-01-14 2017-10-31 Xeros Limited Cleaning method
US10081900B2 (en) 2013-11-08 2018-09-25 Xeros Limited Cleaning method including use of solid particles
US10494590B2 (en) 2012-07-06 2019-12-03 Xeros Limited Cleaning material
GB2562534B (en) * 2017-05-19 2022-06-22 Cares Laboratory Ltd Improvements to drying textiles

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0607047D0 (en) 2006-04-07 2006-05-17 Univ Leeds Novel cleaning method
GB201006076D0 (en) 2010-04-12 2010-05-26 Xeros Ltd Novel cleaning apparatus and method
CN102154801B (zh) 2011-01-11 2016-08-17 海尔集团公司 节水滚筒洗衣机及洗衣方法
CN102828379B (zh) 2011-06-15 2016-01-06 海尔集团公司 使用聚合物固体颗粒的洗涤方法
EP2972035B1 (en) 2013-03-15 2020-07-22 Usnr, Llc Multi-pass lumber kiln
NZ711551A (en) * 2013-03-15 2016-11-25 Usnr Llc Unidirectional multi-path lumber kilns
GB201306607D0 (en) 2013-04-11 2013-05-29 Xeros Ltd Method for treating an animal substrate
US9470455B2 (en) * 2014-08-11 2016-10-18 Weyerhaeuser Nr Company Sorting green lumber
GB201417487D0 (en) 2014-10-03 2014-11-19 Xeros Ltd Method for treating an animal substrate
GB201418007D0 (en) 2014-10-10 2014-11-26 Xeros Ltd Animal skin substrate Treatment apparatus and method
GB201418006D0 (en) 2014-10-10 2014-11-26 Xeros Ltd Animal skin substrate treatment apparatus and method
GB201421293D0 (en) 2014-12-01 2015-01-14 Xeros Ltd New cleaning method, apparatus and use
GB201513346D0 (en) 2015-07-29 2015-09-09 Xeros Ltd Cleaning method, apparatus and use
CN109312413A (zh) 2016-04-13 2019-02-05 塞罗斯有限公司 使用固体颗粒材料处理的方法及其设备
AR108127A1 (es) 2016-04-13 2018-07-18 Xeros Ltd Método y aparato de tratamiento de pieles de animales
GB201704736D0 (en) 2017-03-24 2017-05-10 Xeros Ltd Treatment apparatus and method
TWI756475B (zh) * 2017-10-06 2022-03-01 日商東京威力科創股份有限公司 抑制粒子產生之方法及真空裝置
EP3727639B1 (en) 2017-12-19 2023-06-14 Xeros Limited Filter for a treatment apparatus
GB201811569D0 (en) 2018-07-13 2018-08-29 Xeros Ltd Apparatus and method for treating subsrtate with solid particles
GB201811568D0 (en) 2018-07-13 2018-08-29 Xeros Ltd Apparatus and method for treating a substrate with solid particles

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4055248A (en) 1974-12-17 1977-10-25 The Procter & Gamble Company Fabric treating compositions and articles
WO2007128962A1 (en) 2006-04-07 2007-11-15 University Of Leeds Novel cleaning method

Family Cites Families (129)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2970464A (en) 1958-12-19 1961-02-07 Gen Electric Combination washer and dryer with improved clothes receptacle
US3119773A (en) 1960-10-10 1964-01-28 Whirlpool Co Pivoting deflector water balance system for centrifugal extractor apparatus
US3321843A (en) 1964-07-10 1967-05-30 Singer Co Laundering machines
US3333344A (en) * 1965-11-22 1967-08-01 Phillips Petroleum Co Rotary dryer
GB1256064A (en) 1967-10-26 1971-12-08 Iws Nominee Co Ltd Continuous scouring process
DE1900002A1 (de) 1969-01-02 1970-07-30 Henkel & Cie Gmbh Wasch- und Reinigungsmittel
GB1297316A (https=) 1969-09-29 1972-11-22
US3650673A (en) * 1969-11-24 1972-03-21 Gen Electric Dry wash fabric cleaning method and apparatus
US3647354A (en) 1969-11-24 1972-03-07 Gen Electric Fabric-treating method
GB1379742A (en) 1971-03-25 1975-01-08 Neil & Spencer Ltd Dry cleaning
US3805406A (en) * 1971-09-03 1974-04-23 A Castonoli Interchangeable path drying apparatus
DE2501464A1 (de) 1974-01-29 1975-07-31 Procter & Gamble Bleichverfahren
US4188807A (en) 1975-12-04 1980-02-19 Bosch-Siemens Hausgerate Gmbh Automatic washing machine for textiles having separate containers for washing substances, meters and common pre-mix channel for metered substances
DE2819233A1 (de) 1978-05-02 1979-11-15 Henkel Kgaa Verfahren und vorrichtung zum maschinellen waschen und reinigen
AU544392B2 (en) 1979-04-02 1985-05-23 Gs Development Ab Cleaning machine
US4493783A (en) 1981-04-20 1985-01-15 Alcon Laboratories, Inc. Cleaning agent for optical surfaces
US4434067A (en) 1981-07-27 1984-02-28 Milliken Research Corporation Powdered cleaning composition
DE3210976C2 (de) 1982-03-25 1984-11-29 Alu Plast Aluminium-Plastik Recycling GmbH, 5440 Mayen Waschvorrichtung und Verfahren zum Waschen von Kunststoffkleinteilen
FR2525645A1 (fr) 1982-04-23 1983-10-28 Thomson Brandt Lave-linge a faible consommation en eau
JPS5948078A (ja) 1982-09-14 1984-03-19 Matsushita Electric Works Ltd 固定化酵素の製法
SE8301624D0 (sv) 1983-03-24 1983-03-24 Carl Goran Christer Mosell Sett vid rengoringsmaskin
US4655952A (en) 1984-03-02 1987-04-07 Vorwerk & Co. Interholding Gmbh Detergent and method for producing the same
GB8418566D0 (en) 1984-07-20 1984-08-22 Unilever Plc Fabric cleaning compositions
US4575887A (en) 1984-08-29 1986-03-18 Viramontes Julio C Method for abrading fabric garments
JPS62224289A (ja) 1986-03-25 1987-10-02 Agency Of Ind Science & Technol 固定化酵素及びその製造方法
US4750227A (en) 1986-10-28 1988-06-14 Dexter Chemical Corporation Abrasive structures and methods for abrading fabrics
US4809854A (en) 1987-01-12 1989-03-07 Nelmor Co., Inc. Flotation apparatus for reclaiming bonded, two-resin articles
US4839969A (en) * 1988-02-26 1989-06-20 Permian Research Corporation Drying method and apparatus
JPH01285188A (ja) 1988-05-12 1989-11-16 S T Chem Co Ltd リパーゼ固定ポリアクリル酸系材料およびその利用
JPH0257295A (ja) 1988-08-23 1990-02-27 Yoshikatsu Kotaki 洗濯機
CA1284407C (en) 1988-11-18 1991-05-28 Kent Dickinson Method for dry carpet cleaning
JP3021490B2 (ja) * 1989-11-20 2000-03-15 大日本印刷株式会社 カード
US4951366A (en) 1989-02-07 1990-08-28 Geller George R Method for modifying fabrics to produce varied effects
FR2666101B1 (fr) 1990-08-23 1994-10-14 Sylvie Dameron Procede et dispositif pour le lavage d'objets a l'aide d'une machine a laver a tambour rotatif.
JP2696593B2 (ja) 1990-08-24 1998-01-14 新東工業株式会社 食器洗浄方法
GB9023006D0 (en) 1990-10-23 1990-12-05 Bp Chem Int Ltd Bleach activators
JPH04241165A (ja) 1991-01-07 1992-08-28 Rakutou Kasei Kogyo Kk 染色天然繊維材料にストーン・ウオッシュ様外観を付与する処理方法
SE469507B (sv) 1991-03-01 1993-07-19 Viptop Ab Granuldiskmaskin innefattande en skiljevaegg med ett svaengbart nedre parti foer separering av granuler ur rengoeringsvaetskan
JPH0531297A (ja) * 1991-08-01 1993-02-09 Matsushita Electric Ind Co Ltd 衣類乾燥方法
US5503840A (en) 1991-08-09 1996-04-02 E. I. Du Pont De Nemours And Company Antimicrobial compositions, process for preparing the same and use
SE9201117D0 (sv) 1992-04-08 1992-04-08 Svemo Mekaniska Ab Anordning foer diskmaskiner
SE500315C2 (sv) 1992-04-24 1994-05-30 Pw System Ab Rengöringsmaskin för behandling av gods med vätska och granuler
US5305533A (en) * 1993-01-27 1994-04-26 Alexander Donald J Combined direct and indirect rotary dryer with reclaimer
JPH06240297A (ja) 1993-02-16 1994-08-30 Toray Ind Inc 酵素固定化洗浄用助剤
DE4324624B4 (de) 1993-07-22 2004-06-17 Hamann, Hans-Jörg Vorrichtung zur Oberflächenbehandlung von Textilien
US5993839A (en) 1994-05-09 1999-11-30 Phoenix Medical Technology, Inc. Antimicrobial gloves and a method of manufacture thereof
DE19505921A1 (de) 1995-02-21 1996-08-22 Andreas Kiehne Waschmittel für eine Waschmaschine und Verfahren zu dessen Herstellung
WO1996030581A1 (en) 1995-03-30 1996-10-03 The Procter & Gamble Company Dry cleaning article
US5547476A (en) 1995-03-30 1996-08-20 The Procter & Gamble Company Dry cleaning process
US5605491A (en) 1995-06-02 1997-02-25 Church & Dwight Co., Inc. Blast media with defoamers
BR9608977A (pt) 1995-06-22 1999-06-29 Reckitt & Colman Inc Composição para pré-tratamento de manchas processo para o tratramento de uma mancha sobre um roupa ou têxtil e kit para limpeza doméstica a seco
IL120617A (en) 1996-05-17 1999-12-31 Rohm & Haas Method for removing liquid contaminants from a surface
BR9612636A (pt) 1996-06-05 1999-07-20 Rainer Clover Inibição de crescimento bacteriano
US5925195A (en) 1996-07-25 1999-07-20 King; Paul Portable dip cleaning system
GB9703813D0 (en) * 1997-02-24 1997-04-16 Ici Plc Dyeing of textiles
US20070151312A1 (en) * 2005-12-30 2007-07-05 Bruce Beihoff C Modular fabric revitalizing system
ES2196763T3 (es) * 1998-02-03 2003-12-16 Tencel Ltd Procedimiento para el teñido y acabado de generos celulosicos.
US6280301B1 (en) 1998-04-17 2001-08-28 National Conveyor Corp. Granule dishwashing apparatus and method of use
BR9916438A (pt) 1998-12-22 2001-09-04 Firmenich & Cie Polimetilsilsesquioxano poroso, processo de preparação de um polimetilsilsesquioxano poroso sob forma de pó, utilização de um polimetilsilsesquioxano e composição perfumante ou perfumada
GB9913549D0 (en) 1999-06-10 1999-08-11 Unilever Plc Detergent compositions
DE50011759D1 (de) 1999-07-09 2006-01-05 Henkel Kgaa Wasch- oder reinigungsmittel-portion
US7097715B1 (en) * 2000-10-11 2006-08-29 R. R. Street Co. Inc. Cleaning system utilizing an organic cleaning solvent and a pressurized fluid solvent
JP2001137600A (ja) * 1999-11-12 2001-05-22 Abe Jimusho:Kk 衣類乾燥機の乾燥促進具
CA2325620C (en) 1999-11-15 2004-05-11 The Procter & Gamble Company Bleach-containing non-aqueous detergent formulated to control dye transfer and sudsing in high efficiency washing machines
US6235705B1 (en) 2000-02-15 2001-05-22 Bath & Body Works, Inc. Dryer pearls
ES2184725T3 (es) 2000-07-13 2003-04-16 Oreal Composicion cosmetica de limpieza espumante.
US20020058595A1 (en) * 2000-07-27 2002-05-16 The Procter & Gamble Company Process and a device for deodorizing and/or fragrancing an environment
GB2365648A (en) * 2000-08-07 2002-02-20 Dentpark Ltd Colour correction in image processing
AR031181A1 (es) 2000-11-24 2003-09-10 Unilever Nv Composiciones de limpieza
DE10128894A1 (de) 2001-06-15 2002-12-19 Basf Ag Verfahren zur schmutzablösungsfördernden Behandlung von Oberflächen textiler und nicht-textiler Materialien
FR2826548B1 (fr) 2001-06-28 2007-01-19 Rhodianyl Particule comprenant une matrice et au moins un agent bioactif, son procede de preparation et ses applications
US6780205B2 (en) * 2001-08-21 2004-08-24 E. I. Du Pont De Nemours And Company Vat acid dyeing of textile fibers
EP1443885B1 (en) 2001-11-02 2015-01-21 The Procter & Gamble Company Composition containing a cationic polymer and water insoluble solid material
DE10163331A1 (de) 2001-12-21 2003-07-10 Henkel Kgaa Trägerfixierte Bleichkatalysatorkomplexverbindungen geeignet als Katalysatoren für Persauerstoffverbindungen
US20050204477A1 (en) 2004-03-22 2005-09-22 Casella Victor M Fabric treatment for stain release
DE10215522A1 (de) 2002-04-09 2003-10-30 Basf Ag Kationisch modifizierte anionische Polyurethandispersionen
EP1371718A1 (en) 2002-06-14 2003-12-17 Rohm And Haas Company Polymeric nanoparticle formulations and their use as fabric care additives
WO2004001120A1 (en) 2002-06-24 2003-12-31 Imperial Chemical Industries Plc Method for cleaning textiles
US7528102B2 (en) 2002-08-09 2009-05-05 Henkel Kgaa Fragrance release system
DE10247289A1 (de) 2002-10-10 2004-04-22 Symrise Gmbh & Co. Kg Riechstoffhaltige feste Reinigungsmittel
CN100409831C (zh) 2003-01-27 2008-08-13 宝洁公司 包含不规则形状颗粒和球状颗粒的个人清洁组合物
JP2004238602A (ja) 2003-02-07 2004-08-26 Iwata Kokogyo Kk 洗濯石およびそれを用いた洗濯小袋、および洗濯機の付着黴の除去方法
CN1654617A (zh) 2004-02-10 2005-08-17 捷时雅株式会社 清洗用组合物和半导体基板的清洗方法及半导体装置的制造方法
US20050183208A1 (en) 2004-02-20 2005-08-25 The Procter & Gamble Company Dual mode laundry apparatus and method using the same
US7494512B2 (en) 2004-02-20 2009-02-24 Brown Steven E Compositions and methods for cleaning textile substrates
EP1618970A1 (en) 2004-07-22 2006-01-25 Linde Aktiengesellschaft Carbon dioxide cleaning method
US7605116B2 (en) 2004-08-11 2009-10-20 The Procter & Gamble Company Highly water-soluble solid laundry detergent composition that forms a clear wash liquor upon dissolution in water
GB0422533D0 (en) * 2004-10-11 2004-11-10 Univ Leeds Non-aqueous treatment method
CN2789299Y (zh) 2005-04-05 2006-06-21 苏州三星电子有限公司 一体化的全自动洗衣机
US20060287212A1 (en) 2005-06-02 2006-12-21 Novozymes A/S Blends of inactive particles and active particles
DE102005026522B4 (de) 2005-06-08 2007-04-05 Henkel Kgaa Verstärkung der Reinigungsleistung von Waschmitteln durch Polymer
US8258066B2 (en) 2005-12-12 2012-09-04 Milliken & Company Cleaning device
US20070270327A1 (en) * 2006-05-22 2007-11-22 The Procter & Gamble Company Dryer-added fabric care articles imparting fabric feel benefits
EP2148919A1 (en) 2007-04-25 2010-02-03 Reckitt Benckiser N.V. Composition
JP5631205B2 (ja) 2007-06-11 2014-11-26 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 抗菌性ポリオレフィン及びポリエステル組成物
DE102007037984A1 (de) 2007-08-10 2009-02-12 Leibniz-Institut für Plasmaforschung und Technologie e.V. Verfahren zur Textilreinigung und Desinfektion mittels Plasma und Plasmaschleuse
US7637129B2 (en) 2007-10-04 2009-12-29 Sheng-Ming Wang Air jet pressurized clothes washing machine
KR101461950B1 (ko) 2008-04-30 2014-11-14 엘지전자 주식회사 세탁기
GB0724644D0 (en) 2007-12-19 2008-01-30 Harman Technology Ltd Polymer compositions
US7781387B2 (en) 2008-01-22 2010-08-24 Access Business Group International, Llc. Automatic phosphate-free dishwashing detergent providing improved spotting and filming performance
DE102008009462A1 (de) 2008-02-15 2009-08-20 Henkel Ag & Co. Kgaa Wasch- und Reinigungsmittel mit porösen Polyamidpartikeln
WO2009112296A1 (en) 2008-03-14 2009-09-17 Unilever Plc Laundry treatment compositions
SE0850054A1 (sv) 2008-10-24 2010-04-25 Gs Dev Ab Granul för diskmaskiner
GB0902619D0 (en) 2009-02-17 2009-04-01 Xeros Ltd Cleaning apparatus
GB0907943D0 (en) 2009-05-08 2009-06-24 Xeros Ltd Novel cleaning method
US20100281928A1 (en) 2009-05-08 2010-11-11 Actervis Gmbh Washer friendly laundry ball
CN101886321A (zh) 2009-05-11 2010-11-17 海尔集团公司 洗涤方法
GB0908642D0 (en) 2009-05-20 2009-06-24 Reckitt Benckiser Nv Composition
GB0909362D0 (en) 2009-06-01 2009-07-15 Reckitt Benckiser Nv Composition
ES2393252T3 (es) 2009-08-03 2012-12-19 Dsm Ip Assets B.V. Material antimicrobiano para la esterilización de agua que comprende un vehículo poliamídico y nanopartículas de plata elemental
DE102009046170A1 (de) 2009-10-29 2011-05-05 Henkel Ag & Co. Kgaa Waschen mit Polymerkörpern
GB0920565D0 (en) 2009-11-24 2010-01-06 Xeros Ltd Improved cleaning apparatus
GB201002245D0 (en) 2010-02-10 2010-03-31 Xeros Ltd Improved cleaning apparatus and method
GB201006076D0 (en) 2010-04-12 2010-05-26 Xeros Ltd Novel cleaning apparatus and method
GB201015276D0 (en) 2010-09-14 2010-10-27 Xeros Ltd Polymer treatment method
GB201015277D0 (en) 2010-09-14 2010-10-27 Xeros Ltd Novel cleaning method
GB201018318D0 (en) 2010-10-29 2010-12-15 Xeros Ltd Improved cleaning method
WO2012084619A1 (en) 2010-12-24 2012-06-28 Unilever Nv Flocculation process and device
GB201100627D0 (en) 2011-01-14 2011-03-02 Xeros Ltd Improved cleaning method
GB201100918D0 (en) * 2011-01-19 2011-03-02 Xeros Ltd Improved drying method
US20130316430A1 (en) 2011-02-01 2013-11-28 Maharshi Dayanand University Polyvinyl chloride surface co-immobilized with enzymes and uses thereof
CN202500017U (zh) 2012-02-22 2012-10-24 青岛海尔模具有限公司 一种洗衣机的视窗装置及使用该视窗装置的洗衣机
GB201212098D0 (en) 2012-07-06 2012-08-22 Xeros Ltd New cleaning material
GB201212096D0 (en) 2012-07-06 2012-08-22 Xeros Ltd Improved cleaning formulation and method
GB201216101D0 (en) 2012-09-10 2012-10-24 Xeros Ltd Improved cleaning apparatus and method
GB201317557D0 (en) 2013-10-03 2013-11-20 Xeros Ltd Improved cleaning apparatus and method
GB201317558D0 (en) 2013-10-03 2013-11-20 Xeros Ltd Cleaning apparatus
GB201319782D0 (en) 2013-11-08 2013-12-25 Xeros Ltd Cleaning method and apparatus
GB201320784D0 (en) 2013-11-25 2014-01-08 Xeros Ltd Improved cleaning Apparatus and method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4055248A (en) 1974-12-17 1977-10-25 The Procter & Gamble Company Fabric treating compositions and articles
WO2007128962A1 (en) 2006-04-07 2007-11-15 University Of Leeds Novel cleaning method

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9550966B2 (en) 2010-09-14 2017-01-24 Xeros Limited Cleaning method
US9121000B2 (en) 2010-09-14 2015-09-01 Xeros Limited Cleaning method
US9803307B2 (en) 2011-01-14 2017-10-31 Xeros Limited Cleaning method
US9127882B2 (en) 2011-01-19 2015-09-08 Xeros Limited Drying method
US10494590B2 (en) 2012-07-06 2019-12-03 Xeros Limited Cleaning material
CN105143544B (zh) * 2013-03-20 2017-12-05 塞罗斯有限公司 改进的清洗设备及方法
WO2014147389A1 (en) * 2013-03-20 2014-09-25 Xeros Limited Improved cleaning apparatus and method
JP2016516501A (ja) * 2013-03-20 2016-06-09 ゼロス・リミテツド 改善された洗浄機および洗浄法
JP2016518886A (ja) * 2013-03-20 2016-06-30 ゼロス・リミテツド 改善された乾燥機および乾燥方法
US10597814B2 (en) 2013-03-20 2020-03-24 Xeros Limited Drying apparatus and method
CN105143544A (zh) * 2013-03-20 2015-12-09 塞罗斯有限公司 改进的清洗设备及方法
WO2014147391A1 (en) * 2013-03-20 2014-09-25 Xeros Limited New cleaning apparatus and method
WO2014147390A1 (en) * 2013-03-20 2014-09-25 Xeros Limited Improved drying apparatus and method
US9850619B2 (en) 2013-03-20 2017-12-26 Xeros Limited Cleaning apparatus and method
EP3293305A1 (en) 2013-03-20 2018-03-14 Xeros Limited Improved drying apparatus and method
US9932700B2 (en) 2013-03-20 2018-04-03 Xeros Limited Cleaning apparatus and method
JP2018099525A (ja) * 2013-03-20 2018-06-28 ゼロス・リミテツド 改善された乾燥機および乾燥方法
US10017895B2 (en) 2013-03-20 2018-07-10 Xeros Limited Drying apparatus and method
WO2014170226A1 (en) 2013-04-17 2014-10-23 Crown Packaging Technology Inc Can production process
US10081900B2 (en) 2013-11-08 2018-09-25 Xeros Limited Cleaning method including use of solid particles
US9523169B2 (en) 2013-11-25 2016-12-20 Xeros Limited Cleaning apparatus and method
GB2562534B (en) * 2017-05-19 2022-06-22 Cares Laboratory Ltd Improvements to drying textiles
EP3635167B1 (en) * 2017-05-19 2023-06-07 Cares Laboratory Limited Improvements to drying textiles
EP4241648A3 (en) * 2017-05-19 2023-10-11 Cares Laboratory Limited Improvements to drying textiles

Also Published As

Publication number Publication date
EP2665855A2 (en) 2013-11-27
US20130305560A1 (en) 2013-11-21
WO2012098408A3 (en) 2013-07-25
CN103443349A (zh) 2013-12-11
CN103443349B (zh) 2016-05-25
BR112013018255A2 (pt) 2016-11-08
CA2823813C (en) 2018-03-06
KR20140044774A (ko) 2014-04-15
DK2665855T3 (en) 2015-06-01
JP2014506487A (ja) 2014-03-17
ES2542083T3 (es) 2015-07-30
GB201100918D0 (en) 2011-03-02
KR101725174B1 (ko) 2017-04-10
HK1187657A1 (zh) 2014-04-11
AU2012208380A1 (en) 2013-08-08
EP2665855B1 (en) 2015-04-29
AU2012208380B2 (en) 2017-03-30
JP6066926B2 (ja) 2017-01-25
US9127882B2 (en) 2015-09-08
TW201233967A (en) 2012-08-16
CA2823813A1 (en) 2012-07-26
TWI561785B (en) 2016-12-11

Similar Documents

Publication Publication Date Title
AU2012208380B2 (en) Improved drying method
US10597814B2 (en) Drying apparatus and method
CN102482839B (zh) 衣物烘干机及洗衣烘干机
CN102482840A (zh) 衣物烘干机及洗衣烘干机
HK1187657B (en) Improved drying method
HK1251026B (en) Improved drying apparatus and method
HK1217981B (en) Improved drying apparatus and method

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12701368

Country of ref document: EP

Kind code of ref document: A2

ENP Entry into the national phase

Ref document number: 2823813

Country of ref document: CA

ENP Entry into the national phase

Ref document number: 2013549893

Country of ref document: JP

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 13980325

Country of ref document: US

ENP Entry into the national phase

Ref document number: 2012208380

Country of ref document: AU

Date of ref document: 20120119

Kind code of ref document: A

ENP Entry into the national phase

Ref document number: 20137021107

Country of ref document: KR

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 2012701368

Country of ref document: EP

REG Reference to national code

Ref country code: BR

Ref legal event code: B01A

Ref document number: 112013018255

Country of ref document: BR

ENP Entry into the national phase

Ref document number: 112013018255

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20130717