WO2011122658A1 - 水処理装置 - Google Patents
水処理装置 Download PDFInfo
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- WO2011122658A1 WO2011122658A1 PCT/JP2011/058003 JP2011058003W WO2011122658A1 WO 2011122658 A1 WO2011122658 A1 WO 2011122658A1 JP 2011058003 W JP2011058003 W JP 2011058003W WO 2011122658 A1 WO2011122658 A1 WO 2011122658A1
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- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 2
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
- B01D21/28—Mechanical auxiliary equipment for acceleration of sedimentation, e.g. by vibrators or the like
- B01D21/286—Means for gentle agitation for enhancing flocculation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/24—Treatment of water, waste water, or sewage by flotation
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
- B01D21/01—Separation of suspended solid particles from liquids by sedimentation using flocculating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
- B01D21/02—Settling tanks with single outlets for the separated liquid
- B01D21/08—Settling tanks with single outlets for the separated liquid provided with flocculating compartments
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/442—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by nanofiltration
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
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- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/06—Controlling or monitoring parameters in water treatment pH
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/02—Odour removal or prevention of malodour
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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- C02F2303/08—Corrosion inhibition
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/12—Prevention of foaming
Definitions
- the present invention adds a flocculant to water to be treated such as industrial water, city water, well water, river water, lake water, and factory wastewater, and then agglomerates for solid-liquid separation treatment such as filtration or membrane separation treatment. It relates to a water treatment device.
- an agglomerate is coarsened by using an open type, that is, an agglomeration tank in which the water to be treated is open to the atmosphere.
- liquid supply means such as a pump is required when supplying the water to be treated to the apparatus for processing, and the floc is destroyed by this pump or the like, so that clear treated water is difficult to obtain.
- Patent Document 4 describes a sealing type agglomeration process in which water to be treated is held in a state where the water to be treated is not opened to the atmosphere.
- a device for stirring in an open type agglomeration tank having a stirrer is provided, and a flock may be broken by a pump or the like.
- an object of the present invention is to provide a water treatment apparatus that performs solid-liquid separation treatment after agglomeration treatment and can reliably obtain clear treated water.
- the aspect of the present invention that solves the above-mentioned problems is a mixing treatment means having a mixing tank that forms flocs by mixing the flocculant added to the treatment water and the treatment water, and is discharged from the mixing treatment means.
- a cylindrical agglomeration tank in which the water to be treated is introduced and the treated water is not released to the atmosphere, and the water to be treated is tangential from the lower part of the agglomeration tank so that a swirling flow is generated.
- a coagulation treatment means having a treated water introduction port to be introduced into the coagulation tank, and an untreated water discharge port provided at an upper part of the coagulation tank to discharge the treatment water from the upper part of the coagulation tank, and discharged from the coagulation treatment means.
- a solid-liquid separation processing unit for introducing the water to be treated into a solid-liquid separation process.
- the treated water discharge port may be provided so as to discharge the treated water in a tangential direction from the upper part of the coagulation tank.
- the solid-liquid separation processing means is a filtration processing means in which a filtration body having a string-like turbidity trapping portion is filled in a filtration tank so that the porosity of the filtration portion when water passes is 50 to 95%. It is preferable that
- the mixing treatment means keeps the treated water in a state that is not released to the atmosphere.
- the treated water is introduced from the mixing treatment means to the aggregating treatment means in a state where the treated water is not opened to the atmosphere, and the treated water is sent. It is preferable that the liquid feeding means for liquid is provided in the preceding stage of the mixing treatment means.
- a swirling flow is generated in a mixing treatment means for mixing flocculant and treated water to form flocs such as turbidity, and a cylindrical flocculating tank that keeps the treated water that has been mixed and treated not to be released to the atmosphere.
- a water treatment apparatus having a coagulation treatment means for introducing flocs into the flocs and a solid-liquid separation treatment means for introducing the coagulated water to be treated in a state that is not released to the atmosphere and performing a solid-liquid separation treatment.
- the coarse floc formed by the treatment means can be transferred to the subsequent solid-liquid separation treatment means without using a liquid feed means such as a pump, and the destruction of the coarse floc can be suppressed, so that clear treated water is obtained. It becomes a water treatment device that can.
- the water treatment apparatus of the present invention is a water treatment apparatus that performs a solid-liquid separation process such as a precipitation process, a pressure flotation process, a filtration process, and a membrane separation process after adding a flocculant to the water to be treated and performing a coagulation process.
- a solid-liquid separation process such as a precipitation process, a pressure flotation process, a filtration process, and a membrane separation process after adding a flocculant to the water to be treated and performing a coagulation process.
- water to be treated examples include water containing a humic acid / fulvic acid organic substance, a biological metabolite such as sugar produced by algae, or a synthetic chemical substance such as a surfactant, specifically, industrial water. , City water, well water, river water, lake water, factory wastewater (particularly, biologically treated water obtained by biologically treating wastewater from a factory) and the like.
- the humic substance refers to a corrosive substance generated by the decomposition of plants and the like into microorganisms, and includes humic acid, and the water containing the humic substance is derived from humic substance and / or humic substance. It has a soluble COD component, suspended matter and chromaticity component.
- FIGS. 1 to 3 are examples of the water treatment apparatus of the present invention.
- 1 is a schematic system diagram of the water treatment apparatus
- FIG. 2 is a top view (FIG. 2 (a)) and a side view (FIG. 2 (b)) of the aggregating treatment means of the water treatment apparatus
- FIG. 3 is a water treatment. It is a mixing processing means and an agglomeration processing means which the apparatus has.
- the water treatment apparatus 1 of the present invention includes a mixing treatment means 3 having a mixing tank that mixes a flocculant added to water to be treated (raw water) and the water to be treated to form a floc.
- the coagulation treatment means 4 into which the water to be treated discharged from the mixing treatment means 3 is introduced, and the solid-liquid separation treatment means 5 for subjecting the water to be treated discharged from the coagulation treatment means 4 to solid-liquid separation treatment.
- a flocculant introducing means 6 for adding a flocculant to the water to be treated is provided in the preceding stage of the mixing treatment means 3.
- the flocculant is not limited, and flocs (aggregates) are formed by coagulation or aggregation of suspended substances (turbidity), colloidal components, soluble COD (chemical oxygen demand) components, etc. contained in the water to be treated.
- inorganic flocculants such as aluminum salts and iron salts such as polyaluminum chloride (PAC), polymer flocculants, and aquagel C which is a cationic polymer gel made of MT Aquapolymer, and so on.
- PAC polyaluminum chloride
- aquagel C which is a cationic polymer gel made of MT Aquapolymer, and so on.
- particles made of a cationic polymer that is substantially insoluble in water and these can be used alone or in combination.
- a pump P1 is provided in front of the mixing treatment means 3 as a liquid feeding means for feeding the water to be treated. Further, a pump is provided between the mixing treatment means 3 and the aggregation treatment means 4. P2 is provided. And from the coagulation process means 4 to the solid-liquid separation process means 5, it connects with piping as shown by the arrow of FIG. 1 so that to-be-processed water may be passed in the state which is not open
- the state in which the pressure is not released to the atmosphere means a state in which the pressure supplied by the pump 2 or the like provided in the previous stage of the aggregating treatment means 4 (pressure for supplying the water to be treated) can be maintained, that is, almost no pressure is supplied to the atmosphere. It means that it is a sealed type that does not escape.
- the aggregating treatment means 4 divides the water to be treated in the agglomerating tank 11 so as to generate a swirling flow as indicated by an arrow and a cylindrical agglomerating tank 11 into which the water to be treated is introduced.
- a treated water introduction port 12 for introducing the treated water into the coagulation tank 11 in the tangential direction from the lower part and a treated water discharge port 13 for discharging the treated water from the upper part of the coagulating tank 11 in the tangential direction. Since the to-be-treated water inlet 12 is provided in the lower part of the coagulation tank 11 and the to-be-treated water discharge port 13 is provided in the upper part of the coagulation tank 11, the generated swirl flow is an upward flow.
- the agglomeration tank 11 has a shape in which the top and bottom surfaces of a hollow cylinder are covered with a lid, and the introduced treated water is kept in a state where it is not released to the atmosphere, that is, a sealed type. .
- the aggregating treatment means 4 has a treated water discharge port 13 for discharging the treated water from the upper part of the agglomeration tank 11 in the tangential direction. 13 should just be what is provided in the upper part of the coagulation tank 11, and can discharge to-be-processed water from the upper part of the coagulation tank 11. For example, as shown in FIG.
- Aggregation processing means 4B having 4A is a top view of the aggregation processing means 4A
- FIG. 4B is a side view of the aggregation processing means 4A
- FIG. 4C is a schematic diagram of the aggregation processing means 4A
- FIG. 4D is an aggregation processing.
- 4B is a top view of the means 4B
- FIG. 4E is a side view of the aggregation processing means 4B
- FIG. 4F is a schematic diagram of the aggregation processing means 4B.
- the radius of the to-be-treated water introduction port 12 is within +2 m above, and the center position of the cross section in the water flow direction of the to-be-treated water discharge port 13 is within +2 m of the radius of the to-be-treated water discharge port 13 from the ceiling of the coagulation tank And it is sufficient.
- the amount of water to be treated, the residence time, and the G value are not particularly limited.
- the amount of water to be treated has an initial flow rate (flow velocity at the treated water inlet): 0.5 to 2.0 [m / S], residence time: 0.1 to 10 minutes, preferably 2 to 5 minutes, and agglomeration tank average G value: 20 to 200 [1 / s].
- the mixing treatment means 3 is a mixing tank 16 in which, for example, treated water is introduced and the upper part is opened, and the flocculant and the treated water are mixed by stirring the treated water.
- the solid-liquid separation processing means 5 is not particularly limited as long as it can perform solid-liquid separation processing for removing flocs such as turbidity, such as precipitation processing, pressurized flotation processing, filtration processing, membrane separation processing, and the like.
- the filtration device 20 has a string-like (fibrous) filter body that captures flocs formed of turbidity and the like contained in the water to be treated and a flocculant.
- the pH is adjusted with caustic soda, slaked lime or sulfuric acid when adding the flocculant to the water to be treated, and finally the suspension is flocked with an organic polymer flocculant. You can do that. Moreover, you may use an organic coagulant together as needed.
- the membrane separation treatment include microfiltration membranes (MF membranes), ultrafiltration membranes (UF membranes), nanofiltration membranes (NF membranes), and reverse osmosis membranes (RO membranes).
- the flocculant is introduced into the pipe through which the water to be treated (raw water) stored in the raw water tank 2 flows by the flocculant introducing means 6, and the flocculant is introduced into the water to be treated. Added. And the to-be-processed water to which the flocculant was added is introduce
- the to-be-processed water stored by the temporary storage tank 18 is liquid-fed by the pump P2, and from the to-be-processed water inlet 12 provided in the tangential direction at the lower part of the aggregation tank 11 of the aggregation processing means 4, a coagulation tank 11 is introduced into the lower part.
- a swirling flow as shown by the arrow in FIG.
- the flocs formed by the mixing treatment means 3 are relatively gently stirred and coarsened, reach the treated water discharge port 13 while rising, and are discharged from the treated water discharge port 13. .
- the process for coarsening the flocs is called agglomeration process.
- the agglomeration tank 11 is not provided with other members such as a partition plate, an inner tube, and a stirrer inside, so that the swirling flow of the water to be treated is inhibited. Absent. Therefore, it is possible to prevent the floc from colliding with the member and miniaturizing it, and the floc can be satisfactorily coarsened. And since the aggregation tank 11 is not provided with any members inside, of course, maintenance is easy, and manufacturing costs and operating costs can be suppressed.
- the water flow in the downward flow causes a short path, so the agglomeration efficiency is deteriorated, and if the water flows in the horizontal direction, the flow of water becomes uneven and the floc may be destroyed.
- the agglomeration tank 11 has a cylindrical shape whose upper surface and bottom surface are covered with a lid, the introduced water to be treated is not open to the atmosphere, and the pressure of the pump P2 is the treated water discharge port 13. It is also maintained in the treated water discharged from the water.
- the treated water discharged from the treated water discharge port 13 after being agglomerated is passed through a pipe connecting the treated water discharge port 13 and the solid-liquid separation processing means 5.
- the pressure of the pump P ⁇ b> 2 is also maintained in the water to be treated discharged from the treated water discharge port 13.
- a pipe is provided so that the water to be treated is passed from the flocculation processing means 4 to the solid-liquid separation processing means 5 without being released to the atmosphere, that is, the treated water discharge port of the flocculation processing means 4. 13 and the inlet for introducing the water to be treated into the solid-liquid separation processing means 5 are connected by a pipe.
- the water to be treated is solid even without providing a liquid feeding means such as a pump for passing the water to be treated in the solid-liquid separation treatment means 5 between the aggregation treatment means 4 and the solid-liquid separation treatment means 5.
- the liquid is fed to the liquid separation processing means 5. Therefore, since the breakage of the floc coarsened by the liquid feeding means such as a pump can be prevented, the floc can be satisfactorily removed by the solid-liquid separation processing means 5, and clear treated water is obtained with certainty. be able to.
- the aggregation treatment when it is necessary to provide a liquid feeding means such as a pump for passing water to be treated to the solid-liquid separation processing means 5 between the aggregation processing means 4 and the solid-liquid separation processing means 5, for example, the aggregation treatment
- a liquid feeding means such as a pump for passing water to be treated to the solid-liquid separation processing means 5 between the aggregation processing means 4 and the solid-liquid separation processing means 5, for example, the aggregation treatment
- the water treatment device in which the upper part of the coagulation tank of the means is open and the water to be treated is open to the atmosphere, or the water to be treated is open to the atmosphere between the coagulation treatment means and the solid-liquid separation treatment means In such a water treatment apparatus that allows water to flow, the use of the liquid feeding means such as the pump destroys the flocs that have been coarsened by the coagulation treatment, thereby miniaturizing the flocs.
- the water treatment apparatus 1 in which the water to be treated is not released to the atmosphere is sent between the coagulation treatment means 4 itself and the coagulation treatment means 4 and the solid-liquid separation treatment means 5.
- the mixing treatment means 3 also keeps the treated water in a state that is not released to the atmosphere, and the water treatment introduced from the mixing treatment means 3 to the aggregating treatment means 4 in a state where the treated water is not opened to the atmosphere. It is good also as an apparatus.
- a flocculant introduction means 6 for adding a flocculant to the water to be treated is provided in the preceding stage of the mixing treatment means 3A.
- the same devices as those in FIGS. 1 to 3 are denoted by the same reference numerals, and the description of the same devices and the like is omitted.
- the mixing treatment means 3 ⁇ / b> A has two line mixers connected in series, and the water to be treated is held in a state where it is not released to the atmosphere.
- the number of line mixers is not limited.
- the mixing processing means 3A, the aggregating processing means 4 and the solid-liquid separation processing means are sequentially connected by piping, and from the mixing processing means 3A to the solid-liquid separation processing means via the aggregating processing means 4, The water is passed through without being released to the atmosphere.
- the liquid feeding means is provided in the preceding stage of the mixing processing means 3A. Only the pump P1 is sufficient. Therefore, the cost and maintenance by providing a plurality of pumps can be reduced.
- a line mixer is preferable from the viewpoint of a small installation area, for example, line mixing in which piping is extended and residence time is extended may be used.
- the flocculant is added to the water to be treated before being introduced into the mixing treatment means 3, but the flocculant is added to the mixing treatment means 3 into which the water to be treated is introduced, that is, the mixing tank 16. You may make it do.
- a plurality of mixing tanks and line mixers may be provided, and different types of flocculants may be added to each mixing tank and line mixer.
- a water treatment apparatus configured to add a different type of flocculant to each line mixer, that is, to pass water through the line mixer each time a different type of flocculant is added will be described with reference to FIG.
- raw water tank 2 in which treated water (raw water) is stored mixing treatment means 3B, mixed treatment means 3B ′ into which treated water discharged from mixing treatment means 3B is introduced, It has a coagulation treatment means 4 into which the water to be treated discharged from the mixing treatment means 3B ′ is introduced, and a solid-liquid separation treatment means 5 for subjecting the water to be treated discharged from the aggregation treatment means 4 to a solid-liquid separation treatment.
- an inorganic flocculant introduction means 6A for adding an inorganic flocculant to the water to be treated is provided in the previous stage of the mixing treatment means 3B, and a polymer flocculant is added to the water to be treated in the previous stage of the mixing treatment means 3B ′.
- Polymer flocculant introduction means 6B is provided.
- the pH adjuster introduction means 7 which introduces a pH adjuster into to-be-processed water is provided in the upstream of the mixing process means 3B.
- the mixing treatment means 3B and the mixing treatment means 3B ′ have the same structure in which three line mixers are connected in series, and the water to be treated is held in a state where it is not released to the atmosphere. is there.
- the number of line mixers is not limited.
- the mixing processing means 3B, the mixing processing means 3B ′, the aggregating processing means 4 and the solid-liquid separation processing means 5 are sequentially connected by a pipe, and the mixing processing means 3B passes through the mixing processing means 3B ′ and the aggregating processing means 4.
- the water to be treated is passed through to the solid-liquid separation treatment means 5 without being released to the atmosphere.
- the liquid feeding means is provided in the preceding stage of the mixing processing means 3B. Only the pump P1 is sufficient. Therefore, the cost and maintenance by providing a plurality of pumps can be reduced.
- the polymer flocculant which is a different kind of flocculant is added and treated by the mixing treatment means 3B ′.
- a floc is formed by a soluble COD component or the like, and a larger floc is formed by this floc and the polymer flocculant, and is coarsened by a swirling flow.
- a water treatment apparatus comprised so that it may flow in order to a line mixer and the coagulation process means 4 whenever a different kind of coagulant
- the raw water tank 2 in which the treated water (raw water) is stored, the mixing treatment means 3B, and the treated water discharged from the mixing treatment means 3B are introduced.
- Coagulation treatment means 4 mixing treatment means 3 B ′ into which treated water discharged from the aggregation treatment means 4 is introduced, and aggregation treatment means 4 ′ into which treated water discharged from the mixing treatment means 3 B ′ is introduced.
- solid-liquid separation processing means 5 for performing solid-liquid separation processing on the water to be treated discharged from the aggregation processing means 4 ′.
- the aggregation processing means 4 and the aggregation processing means 4 ′ have the same structure.
- an inorganic flocculant introduction means 6A for adding an inorganic flocculant to the water to be treated is provided in the previous stage of the mixing treatment means 3B, and a polymer flocculant is added to the water to be treated in the previous stage of the mixing treatment means 3B ′.
- Polymer flocculant introduction means 6B is provided.
- the pH adjuster introduction means 7 which introduces a pH adjuster into to-be-processed water is provided in the upstream of the mixing process means 3B.
- the same devices as those in FIGS. 1 to 6 are denoted by the same reference numerals, and the description of the same devices and the like is omitted.
- the mixing treatment means 3B and the mixing treatment means 3B ′ have the same structure in which three line mixers are connected in series, and the water to be treated is held in a state where it is not released to the atmosphere. is there.
- the number of line mixers is not limited.
- the mixing processing unit 3B, the aggregation processing unit 4, the mixing processing unit 3B ′, the aggregation processing unit 4 ′, and the solid-liquid separation processing unit 5 are sequentially connected by a pipe, and from the mixing processing unit 3B, the aggregation processing unit 4, The water to be treated is passed through the mixed treatment means 3B ′ and the aggregation treatment means 4 ′ to the solid-liquid separation treatment means 5 without being released to the atmosphere.
- the liquid feeding means is provided in the preceding stage of the mixing processing means 3B. Only the pump P1 is sufficient. Therefore, the cost and maintenance by providing a plurality of pumps can be reduced. Moreover, the water to be treated to which the inorganic flocculant has been added is sequentially treated by the mixing treatment means 3B and the flocculant treatment means 4, and then the water to be treated to which the polymer flocculant which is a different type of flocculant is added is sequentially mixed.
- flocs are formed by the inorganic flocculant, turbidity, soluble COD components, etc., and are coarsened by the swirling flow.
- a larger floc is formed with the molecular flocculant and coarsened by the swirling flow.
- the solid-liquid separation process means 5 is a filtration process means, and has a fibrous filter body.
- a filtration body having a string-like (fibrous) turbidity trapping portion is filled in a filtration tank so that the porosity of the filtration portion when water passes is 50 to 95%.
- a specific example of such a filtration means is a filtration device shown in FIG. 8 is a cross-sectional view showing the configuration of the filtration device, and FIG. 9 is an enlarged view of the main part of FIG.
- the filtration device 20 includes a cylindrical filtration tank 21 through which water to be treated is passed, and a filter body 22 that captures turbidity in the water to be treated.
- the filter body 22 includes a core member 23 connected to both ends of the filtration tank 21 in the water flow direction, and a string-like turbidity capturing unit 24.
- a circular plate 26 made of resin or the like provided with a plurality of holes to allow water to be treated containing flocs formed of turbidity or the like to flow freely is provided at both ends of the filtration tank 21 in the water flow direction.
- the both ends of the core member 23 are fixed to the center of each plate 26.
- the turbidity capturing part 24 is provided so that a part of the turbidity capturing part 24 is knitted and fixed to the core member 23 and a so-called loop-shaped part that is not fixed spreads radially toward the inner wall surface of the filtration tank 21.
- the filter body 22 spreads over the entire filtration tank 21.
- the string-like turbidity catching portion 24 is a loop of a long rectangle (tape), and as shown in the enlarged view of the string-like turbidity catching portion 24 in FIG.
- a plurality of slits 25 that do not reach are provided. By providing the slit 25 in this manner, the trapping effect of turbidity and the like is improved.
- the filter body 22 is placed in the filtration tank 21 so that the porosity of the filtration part when the water to be treated is passed is 50 to 95%, preferably 60 to 90%, more preferably 50 to 80%. Filled.
- the porosity is a value obtained from the following formula.
- the filtration unit is a region where turbidity or the like of the water to be treated is captured by the filter body 22, that is, the inner wall surface of the filtration tank 21 is used as a side surface and both ends of the filter body 22 in the water passage direction when passing water are thick.
- the layer filled with the turbidity trapping portion 24 of the filter body 22 as both ends in the direction refers to a portion excluding the portion that does not contribute to filtration (the portion of the core material 23 in FIG. 8).
- a filtration part uses the inner wall surface of the filtration tank 21 as a side surface, and the turbidity of the filter body 22 makes the water flow direction both ends of the filter body 22 at the time of water flow the both ends of the thickness direction.
- Porosity (%) [(volume of filtration part ⁇ volume of turbidity trapping part) / volume of filtration part] ⁇ 100
- the water to be treated passes between the string-like turbid traps 24 and between the slits 25 provided in the turbid trap 24, and in that case Turbidity and the like contained in the treated water are trapped by the string-like turbidity capturing unit 24 and the slit 25, and the treated water from which the turbidity has been removed is discharged from the filtration tank 21.
- the filter body 22 is filled so that the porosity of the filtration part at the time of water flow is 50 to 95%, the water flow is not hindered and traps such as turbidity are also good.
- the water to be treated introduced into the filtration device 20 is well turbid in the filtration device 20 because the coarse flocs formed by turbidity and the flocculant are prevented from being destroyed. The quality etc. can be trapped.
- the filter body 22 by filling the filter body 22 so that the porosity of the filtration part during water passage is 50 to 95%, water passage is not hindered and trapping of turbidity and the like is improved.
- occlusion of the apparatus 20 can be suppressed and there exists an effect that clear treated water is obtained. If the porosity is higher than 95%, the water flow becomes good and it becomes easy to filter at high speed, but the turbidity of the treated water becomes remarkably high, and if it is lower than 50%, the trap of turbidity is good. However, the water flow is insufficient, and the filtration device and the membrane separation processing means provided in the latter stage as necessary are clogged, and the differential pressure increase rate is remarkably increased.
- the filtration operation is performed at a high speed of 100 m / h or more, or the water to be treated is treated with high turbidity (for example, 20 degrees or more), the turbidity of the treated water is increased, or the apparatus is blocked.
- the filtration device 20 filled with the filter body 22 so that the porosity is 50 to 95% even if the water to be treated has high speed operation or high turbidity, Clogging can be suppressed and clear treated water can be obtained.
- blockage can be suppressed and clear treated water can be obtained.
- the turbidity trapping part 24 is filled up to the vicinity of both ends of the filtration tank 21 in the water flow direction. It is preferable to fill up to the vicinity of the inner wall surface.
- the volume of the filtration part does not fluctuate between passing water to be treated and other states such as backwashing or stopping filtration, which will be described later, and the volume fluctuation rate of the filtration part is 30%. Hereinafter, it is preferably 10% or less. By setting it as such a range, a filtration apparatus can be made compact.
- the size of the filtration tank 21 is, for example, a cylindrical shape, the diameter can be 100 to 1000 mm and the height can be 200 to 1000 mm.
- the filter tank 21 is filled with a plurality of filter bodies 21 or the turbidity trapping portion 24 of the filter body 22 is enlarged, for example. What is necessary is just to make it the porosity of the filtration part at the time of water to be 50 to 95%.
- the core material 23 and the suspended matter capturing part 24 synthetic resins such as polypropylene, polyester, and nylon can be cited.
- the core material 23 may be provided with strength by knitting synthetic fibers such as polypropylene, polyester, and nylon in the manufacturing process.
- the filter body 22 which spreads radially by twisting the metal after arranging the turbidity catching parts 24 evenly after using the wire made of a metal coated with SUS or resin that is not corroded like a torsion brush. It is good. By improving the strength of the core member 23 in this manner, the core member 23 is not bent, and the end of the filter body 22 can be easily fixed, so that the replacement work of the filter body 22 is facilitated.
- the thickness is 0.05 to 2 mm
- the width is 1 to 50 mm
- the distance may be about 10 to 500 mm, preferably about 0.3 to 2 mm in thickness, 1 to 20 mm in width, and about 50 to 200 mm in length.
- the cylindrical filtration tank 21 in FIG. 8 it does not need to be a cylinder shape,
- transmit water, ie, what is necessary is just hollow,
- the shape which provided the cavity in the prism may be sufficient.
- the both ends of the core material 23 were fixed to the plate 26, it is not limited to this, For example, you may make it fix only one end of a core material.
- the end portion of the core member 23 can be fixed.
- a rod-shaped member may be disposed on the end surface of the filtration tank 21 and the end portion of the core member 23 may be fixed.
- each turbidity trapping part 24 is provided to protrude from the core member 23, but the present invention is not limited to this.
- One end of each turbidity trapping part may be fixed to the core material.
- acquisition part 24 was made into square, there is no limitation in particular, For example, circular shape may be sufficient.
- the length of each turbidity trapping part may be the same or different.
- the material of the turbidity capturing part 24 is one type, but it may be two or more types.
- acquisition part may be plural or single, and does not need to provide.
- the core material 23 may not be provided, and the filter body 22 including only the turbidity trapping part may be used.
- the filter body 22 is preferably present in the filtration tank 21 substantially uniformly, It is preferable to fix the capturing part at a predetermined position of the filtration tank.
- Such a mixing process, agglomeration process, and solid-liquid separation process provide clear treated water, but may further have a deionization process such as an ion exchange process. Thereby, pure water or ultrapure water can be obtained. Moreover, you may further perform the refinement
- Example 1 As water to be treated (raw water), industrial water (turbidity of 5 to 7 degrees) was treated with a water treatment apparatus shown in FIG.
- the water treatment apparatus used will be specifically described in detail. It has a mixing treatment means 3A in which two line mixers are connected, a coagulation treatment means 4 shown in FIG. 2, and a filtration device 20 shown in FIG.
- a water treatment apparatus in which a pump P1 is provided only in the front stage of the mixing treatment means 3A, and the mixing treatment means 3A and the coagulation treatment means 4 are held in a state where the water to be treated is not released to the atmosphere.
- the treatment means 3A, the flocculation treatment means 4 and the filtration device 20 are sequentially connected by piping, and the water to be treated is not released to the atmosphere from the mixing treatment means 3A through the flocculation treatment means 4 to the filtration device 20.
- the water is passed through.
- the conditions for each processing means are described below.
- ⁇ Mixing treatment means Poly-aluminum chloride in front of the first line mixer in the direction of water flow of the water to be treated is made by mixing two series 1 / 2-N50-171-1 line mixers manufactured by Noritake Company in series. (PAC: 10 wt% as Al 2 O 3 ) is added at 60 mg / L to the water to be treated, and the residence time from the first line mixer outlet to the second line mixer inlet is about 10 seconds, Immediately before the second line mixer, 4 mg / L of amphoteric polymer flocculant (Kurita Kogyo Co., Ltd., Krivest E851) was added to the water to be treated.
- PAC 10 wt% as Al 2 O 3
- Filter tank size acrylic cylindrical column having a diameter of 200 mm and a height of 500 mm
- Filter body Filter body 22 comprising a core material 23 and a string-like turbidity capturing part 24.
- the core material has a volume of 250 mL, and the thickness of each turbidity trap 24 is 0.5 mm, the width is 2 mm, and the length (the distance from the core material when the water to be treated is passed) is 100 mm.
- the porosity of the filtration part water volume obtained by subtracting the volume of the core material 23 from the volume inside the filtration tank 21) at the time of passing water is 60%. And the both ends of the core material 23 of the filter body 22 are being fixed by the plate arrange
- LV 250m / h
- the coagulation treatment means has a coagulation tank and a stirrer, and the water to be treated is held open to the atmosphere, and the treatment water is fed between the coagulation treatment means and the filtration device.
- the same operation as in Example 1 was performed except that a pump was provided.
- the residence time of the aggregation treatment means of Comparative Example 1 is 10 minutes, and the stirring speed is 30 rpm.
- Example 1 and Comparative Example 1 have substantially the same floc diameter in the coagulation tank, but the treated water discharged from the filtration device is significantly clearer in Example 1. It was.
- Example 1 flocs were coarsened in the coagulation tank, and the coarsened flocs were introduced into the filtration device without being destroyed by a pump or the like, so that very clear water was obtained as compared with Comparative Example 1. It is presumed that On the other hand, in Comparative Example 1 in which it was necessary to provide a pump for feeding the liquid between the flocculation tank and the filtration device, the water to be treated introduced into the filtration device was destroyed and the floc was broken to become fine. It is presumed that they could not be captured.
- the reference example which shows the effect of the filtration apparatus 20 below is shown.
- industrial water with a turbidity of 20 degrees was treated at LV 200 m / h for 1 week using a water treatment device 30 shown in FIG.
- the water treatment apparatus 30 introduces an inorganic flocculant into the reaction tank 31 from a reaction tank 31 into which water to be treated (raw water) is introduced and an inorganic flocculant tank 32 in which the inorganic flocculant is held.
- An inorganic flocculant introduction means 33 comprising a pump or the like, a chemical introduction means 35 comprising a pump or the like for introducing a chemical from the chemical tank 34 holding the polymer flocculant into the reaction tank 31, and a stirrer 36 in the reaction tank 31. 8 and the filtration device 20 of FIG. 8 into which the water to be treated which has been subjected to agglomeration treatment by stirring is introduced.
- the filter body used for the filtration apparatus 20 consists of the core material 23 and the string-like turbidity capture
- the core material 23 has a volume of 250 mL, and the thickness of each turbidity trap 24 is 0.5 mm, width 2 mm, and length (distance from the core material when the water to be treated is passed) is 100 mm. It is knitted into a core material in a loop shape, and changes the knitting density of the turbidity trapping portion 24 to change the filtration portion during passage of water (subtracting the volume of the core material 23 from the volume inside the filtration tank 21 ) Were produced, and water treatment was carried out using each filter.
- the filter bodies were 30, 40, 50, 60, 70, 80, 90, 95, and 98%.
- the volume change rate of the filtration part was approximately 0% when the treated water was passed and at other times.
- the size of the filtration tank 21 is 200 mm in diameter and 500 mm in height.
- Clivest E851 (manufactured by Kurita Kogyo) was added.
- Table 2 shows the results of measuring the turbidity of the treated water discharged from the filtration device (treated water turbidity) and the differential pressure increase rate (differential pressure increase rate) of the filtration device.
- the turbidity of the treated water was determined by a transmitted light measurement method using a kaolin standard solution, and the differential pressure increase rate of the filtration device was determined by the pressure difference between the inlet and the outlet.
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Abstract
Description
空隙率(%)=[(濾過部の体積-濁質捕捉部の体積)/濾過部の体積]×100
被処理水(原水)として、工業用水(濁度5~7度)を、図5に示す水処理装置で処理した。用いた水処理装置について具体的に詳述すると、ラインミキサーを2個連結した混合処理手段3A、図2に示す凝集処理手段4及び図8に示す濾過装置20を順に有し、送液手段として混合処理手段3Aの前段のみにポンプP1が設けられている水処理装置であって、混合処理手段3A及び凝集処理手段4は被処理水が大気に開放されない状態で保持されるものであり、混合処理手段3A、凝集処理手段4及び濾過装置20は順に配管で繋がれており、混合処理手段3Aから凝集処理手段4を経由して濾過装置20に至るまで、被処理水が大気に開放されない状態で通水されるものである。なお、以下に各処理手段の条件を記載する。
ノリタケカンパニー製の型式1/2-N50-171-1のラインミキサーを2個直列に連接したものを混合処理手段とし、被処理水の通水方向の1番目のラインミキサーの前でポリ塩化アルミニウム(PAC:10重量%as Al2O3)を被処理水に対して60mg/L添加しこの1番目のラインミキサー出口から2番目のラインミキサー入口までの滞留時間を10秒程度とし、また、2番目のラインミキサー直前で両性高分子凝集剤(栗田工業株式会社製、クリベストE851)を被処理水に対して4mg/L添加した。
凝集槽の大きさ:内径100mm×高さ510mm
被処理水導入口の位置:通水方向断面の中心位置が凝集槽の底から上方に半径+20mm
被処理水排出口の位置:通水方向断面の中心位置が凝集槽の天井部(上面)から下方に半径+20mm
被処理水の通水量:初期流速(被処理水導入口流速)1.33[m/s]
被処理水の滞留時間:1分
撹拌速度(旋回流の回転速度):20~30rpm
凝集槽平均G値:121.07[1/s]
濾過槽の大きさ:直径200mm、高さ500mmのアクリル製の筒状カラム
濾過体:芯材23及び紐状の濁質捕捉部24からなる濾過体22。芯材は体積250mLで、各濁質捕捉部24の厚さは0.5mm、幅2mm、長さ(被処理水を通水した際の芯材からの距離)100mmとなるようループ状に編みこんだものであり、通水時の濾過部(濾過槽21内部の体積から芯材23の体積を引いたもの)の空隙率は60%である。そして、濾過体22の芯材23の両端が、上下に配置されたプレートによって固定されている。
LV=250m/h
凝集処理手段を、凝集槽と撹拌機を有し被処理水が大気に開放された状態で保持されるものとし、凝集処理手段と濾過装置との間に、被処理水を送液するためのポンプを設けた以外は、実施例1と同様の操作を行った。なお、比較例1の凝集処理手段の滞留時間は10分、撹拌速度は30rpmである。
(濾過装置の空隙率と差圧上昇及び処理水濁度の関係)
被処理水(原水)として、濁度20度の工業用水を図11に示す水処理装置30を用いて、LV200m/hで1週間処理した。水処理装置30は、図11に示すように、被処理水(原水)が導入される反応槽31と、無機凝集剤が保持される無機凝集剤槽32から反応槽31に無機凝集剤を導入するポンプ等からなる無機凝集剤導入手段33と、高分子凝集剤が保持される薬品槽34から反応槽31に薬品を導入するポンプ等からなる薬品導入手段35と、反応槽31で撹拌機36で撹拌することにより凝集処理した被処理水が導入される図8の濾過装置20とを具備するものである。また、濾過装置20に用いた濾過体は、図8に示すように芯材23及び紐状の濁質捕捉部24からなり、濾過槽21の通水方向両端のプレート26にそれぞれ両端が固定されている。そして、芯材23は体積250mLで、各濁質捕捉部24の厚さは、0.5mm、幅2mm、長さ(被処理水を通水した際の芯材からの距離)100mmとなるようループ状に芯材に編みこんだものであり、濁質捕捉部24の編込み密度を変化させて、通水時の濾過部(濾過槽21内部の体積から芯材23の体積を引いたもの)の空隙率が、30、40、50、60、70、80、90、95、98%の濾過体を作製し、各濾過体を用いて水処理した。なお、芯材は両端で固定しているため、被処理水通水時とその他の時とでは濾過部の体積変化率はほぼ0%であった。また、濾過槽21の大きさは、直径200mm、高さ500mmである。また、凝集剤として、被処理水に対して30mg/Lのポリ塩化アルミニウム(PAC:10重量% as Al2O3)及び被処理水に対して0.7mg/Lの両性の高分子凝集剤クリベストE851(栗田工業製)を添加した。濾過装置から排出された処理水の濁度(処理水濁度)及び濾過装置の差圧上昇速度(差圧上昇速度)を測定した結果を表2に示す。なお、処理水の濁度はカオリン標準液を用いた透過光測定方法により求め、濾過装置の差圧上昇速度は入口と出口の圧力差で求めた。
Claims (4)
- 被処理水に添加された凝集剤と被処理水とを混合してフロックを形成する混合槽を有する混合処理手段と、
前記混合処理手段から排出される被処理水が導入されると共に被処理水が大気に開放されない状態に保たれる円筒形状の凝集槽、旋回流が発生するように被処理水を前記凝集槽の下部から接線方向に前記凝集槽に導入する被処理水導入口、及び、前記凝集槽の上部に設けられ被処理水を前記凝集槽の上部から排出する被処理水排出口を有する凝集処理手段と、
前記凝集処理手段から排出される被処理水が大気に開放されない状態で前記凝集処理手段から導入され、被処理水を固液分離処理する固液分離処理手段と、を有することを特徴とする水処理装置。 - 前記被処理水排出口は、被処理水を前記凝集槽の上部から接線方向に排出するように設けられていることを特徴とする請求項1に記載の水処理装置。
- 前記固液分離処理手段が、紐状の濁質捕捉部を有する濾過体が通水時の濾過部の空隙率が50~95%になるように濾過槽に充填されている濾過処理手段であることを特徴とする請求項1または2に記載の水処理装置。
- 前記混合処理手段は被処理水を大気に開放されない状態に保つものであり、被処理水が大気に開放されない状態で前記混合処理手段から前記凝集処理手段に導入され、被処理水を送液する送液手段が前記混合処理手段の前段に設けられていることを特徴とする請求項1~3のいずれかに記載の水処理装置。
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JP2012508359A JP5843071B2 (ja) | 2010-03-30 | 2011-03-30 | 水処理装置 |
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TWI508766B (zh) | 2015-11-21 |
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SG182742A1 (en) | 2012-08-30 |
CN102781847B (zh) | 2014-08-27 |
US20120305468A1 (en) | 2012-12-06 |
CN102781847A (zh) | 2012-11-14 |
KR20130012009A (ko) | 2013-01-30 |
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