WO2011122391A1 - 含フッ素硬化性樹脂及びそれを用いた活性エネルギー線硬化性組成物 - Google Patents
含フッ素硬化性樹脂及びそれを用いた活性エネルギー線硬化性組成物 Download PDFInfo
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- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
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Definitions
- the present invention relates to a fluorine-containing curable resin that can be used as a fluorine-containing surfactant and a fluorine-containing surface modifier that can impart excellent antifouling properties to the surface of a cured coating film.
- the present invention also relates to an active energy ray-curable composition using the fluorine-containing curable resin, a cured product thereof, and an article having the cured coating film.
- Fluorine-containing surfactants or fluorine-containing surface modifiers are excellent in leveling, wettability, permeability, anti-blocking properties, slipperiness, water / oil repellency, antifouling properties, etc. Widely used in quality materials.
- a cured coating obtained by applying and curing an active energy ray-curable paint containing a fluorine-containing surfactant or fluorine-containing surface modifier (hereinafter simply referred to as “fluorine-containing surfactant”). While the film exhibits excellent antifouling properties, it has fluorine-containing surface activity by heating, humidification, exposure to chemicals such as acid and alkali, cleaning and wiping to remove stains in the manufacturing process of cured coatings. There was a problem that a part of the agent was detached or volatilized from the surface of the cured coating film and the antifouling property of the surface of the cured coating film was lowered.
- the protective film surface is coated with an ultraviolet curable hard coat material to which a fluorine-containing surfactant or the like is added.
- the protective film is subjected to saponification treatment (alkali treatment) for the purpose of imparting adhesiveness to the opposite surface of the hard coat surface to which the hard coat material is applied.
- saponification treatment alkali treatment
- a fluorine-containing surfactant that can withstand a saponification treatment, it has been proposed to polymerize with other materials having a polymerizable functional group and fix it in a cured coating film.
- a copolymer obtained by copolymerizing a monoacrylate having a fluorinated alkyl group and an acrylic monomer having active hydrogen, and then reacting the resulting polymer with an acrylic monomer having an isocyanate group.
- a polymerizable fluorine-containing surfactant having a saturated group has been proposed (see, for example, Patent Document 1).
- This polymerization type fluorine-containing surfactant has a polymerizable group, and when used as an additive to the active energy ray-curable composition, it is bonded to the polymerization component in the composition by a covalent bond and is coated.
- the antifouling property after the saponification treatment is greatly reduced.
- poly (perfluoroalkylene ether) produced from a compound having a (perfluoroalkylene ether) chain and having a di (meth) acryloyl group at both ends in the same manner as the above-described polymerization type fluorine-containing surfactant.
- a polymerization type fluorine-containing surfactant having a chain and an unsaturated group has been proposed (for example, see Patent Document 2).
- the fluorine-containing surfactant having a poly (perfluoroalkylene ether) chain is improved in antifouling property after saponification treatment than the one described in Patent Document 1, but requires a higher level of antifouling property. I was not satisfied.
- the problem to be solved by the present invention is to provide a fluorinated curable resin used as a fluorinated surfactant capable of imparting excellent antifouling properties to the surface of a cured coating film. Moreover, the active energy which can suppress the detachment
- a poly (perfluoroalkylene ether) chain a compound having a styryl group at both ends thereof, and a polymerizable unsaturated monomer having a reactive functional group.
- a fluorine-containing curable resin obtained by reacting a polymer obtained by copolymerizing a polymer with a compound having a functional group reactive with the reactive functional group and a polymerizable unsaturated group.
- the active energy ray-curable composition to be contained has been found to impart excellent antifouling properties to the surface of the cured coating film, and can suppress a decrease in antifouling properties even when saponified, thereby completing the present invention.
- the present invention comprises a compound (A) having a poly (perfluoroalkylene ether) chain and a styryl group at both ends thereof, a hydroxyl group, an isocyanate group, an epoxy group, a carboxyl group, an acid anhydride group, and a carboxylic acid halide group.
- the present invention provides a cured product obtained by applying the fluorine-containing curable resin or active energy ray curable composition to a substrate and irradiating and curing the active energy ray, and the fluorine-containing curable resin or activity.
- the present invention relates to an article having a cured coating film of an energy beam curable composition.
- the fluorine-containing curable resin of the present invention can impart antifouling properties to the substrate surface by applying it alone to a substrate to form a cured coating film.
- the active energy ray-curable composition containing the fluorine-containing curable resin as a fluorine-containing surfactant, when applied to a substrate, has a difference in polarity with other atoms of fluorine atoms.
- the curable resin segregates on the coating film surface, and surface modification that imparts antifouling property or the like only to the coating film surface is possible.
- the fluorine-containing curable resin can be polymerized with other curable components in the active energy ray-curable composition, the fluorine-containing curable resin of the present invention is stronger in the cured coating film. Therefore, volatilization and detachment of the fluorine-containing curable resin or a decomposition product thereof can be suppressed from the surface of the cured coating film even if heat treatment or the like is performed.
- a cured coating film using the fluorine-containing curable resin of the present invention has high resistance to saponification treatment, and can suppress a decrease in antifouling property even when saponification treatment is performed. Therefore, the active energy ray-curable composition using the fluorine-containing curable resin of the present invention is used for a polarizing plate for a liquid crystal display that needs to be imparted with antifouling properties and is subjected to a saponification treatment with an alkali. It is extremely useful as a hard coat material for a TAC film.
- FIG. 1 is an IR spectrum chart of the compound obtained in Synthesis Example 1 and a compound having a styryl group at both ends of the poly (perfluoroalkylene ether) chain.
- FIG. 2 is a chart of the 1 H-NMR spectrum of the compound obtained in Synthesis Example 1 and a compound having a styryl group at both ends of the poly (perfluoroalkylene ether) chain.
- FIG. 3 is a chart of 13 C-NMR spectrum of the compound obtained in Synthesis Example 1 and a compound having a styryl group at both ends thereof.
- FIG. 4 is a GPC chart of the fluorinated curable resin (1) obtained in Example 1.
- FIG. 5 is a GPC chart of the fluorinated curable resin (2) obtained in Example 2.
- the fluorine-containing curable resin of the present invention comprises a poly (perfluoroalkylene ether) chain and a compound (A) having a styryl group at both ends, a hydroxyl group, an isocyanate group, an epoxy group, a carboxyl group, an acid anhydride group and a carboxyl group
- a polymer (P) obtained by copolymerizing, as an essential monomer component, a polymerizable unsaturated monomer (B) having at least one functional group (b) selected from the group consisting of acid halide groups And at least one functional group (c) that is reactive to the functional group (b) and is selected from the group consisting of a hydroxyl group, an isocyanate group, an epoxy group, a carboxyl group, an acid anhydride group, and a carboxylic acid halide group. ) And a compound (C) having a polymerizable unsaturated group.
- the compound (A) having a poly (perfluoroalkylene ether) chain and a styryl group at both ends thereof as a raw material for the fluorine-containing curable resin of the present invention will be described below.
- Examples of the poly (perfluoroalkylene ether) chain of the compound (A) include those having a structure in which a divalent fluorocarbon group having 1 to 3 carbon atoms and oxygen atoms are alternately connected.
- the divalent fluorocarbon group having 1 to 3 carbon atoms may be one kind or a mixture of plural kinds. Specifically, those represented by the following structural formula (a1) may be used. Can be mentioned.
- X is the following structural formulas (a1-1) to (a1-5), and all X in the structural formula (a1) may have the same structure,
- a plurality of structures may be present randomly or in a block shape, and
- n is an integer of 1 or more representing a repeating unit.
- the perfluoromethylene structure represented by the structural formula (a1-1) and the structure are particularly preferable in that the surface of the coating film can be easily wiped off and an excellent antifouling property can be obtained.
- Those coexisting with the perfluoroethylene structure represented by the formula (a1-2) are particularly preferred.
- the abundance ratio between the perfluoromethylene structure represented by the structural formula (a1-1) and the perfluoroethylene structure represented by the structural formula (a1-2) is a molar ratio [structure (a1- The ratio of 1) / structure (a1-2)] is preferably 1/10 to 10/1 from the viewpoint of antifouling properties.
- the value of n in the structural formula (a1) is preferably in the range of 3 to 100, more preferably in the range of 6 to 70.
- the compound (A) has, for example, a poly (perfluoroalkylene ether) chain, a compound (a2) having a hydroxyl group at both ends thereof, and a functional group having reactivity with a hydroxyl group such as a halogenated alkyl group or an isocyanate group. It can be obtained by reacting with styrene (a3).
- Examples of the compound (a2) include the following general formulas (a2-1) and (a2-2). In the following structural formulas, “—PFPE—” represents the poly (perfluoroalkylene ether) chain.
- any of a chlorine atom, a bromine atom, and an iodine atom can be used as the halogen atom of the halogenated alkyl group of the styrene (a3).
- the alkyl group preferably has 1 to 6 carbon atoms, and may be linear or branched.
- a chloromethyl group is preferable from the viewpoint of reactivity with the compound (a2) and availability.
- the styrene (a3) may have a substituent other than a functional group having reactivity with a hydroxyl group such as a vinyl group, the halogenated alkyl group, or an isocyanate group in an aromatic ring.
- the positional relationship between the vinyl group and the functional group having reactivity with a hydroxyl group such as a halogenated alkyl group or an isocyanate group may be any of the ortho, meta, and para positions. A para-position is preferable from the viewpoint of high polymerizability in production.
- the compound (A) is a homogeneous solution of a poly (perfluoroalkylene ether) chain, a compound (a2) having a hydroxyl group at both ends and a styrene (a3) having a halogenated alkyl group in the presence or absence of a solvent. And at a suitable temperature, a catalyst may be added as necessary, and a base may be added dropwise to react.
- Examples of the solvent used in the reaction of the compound (a2) and the styrene (a3) include a polar solvent and a two-phase solvent including an organic phase and an aqueous phase.
- Examples of the polar solvent include benzene, toluene, diethyl ether, tetrahydrofuran, diisopropyl ether, dimethyl sulfoxide, 1,3-bis (trifluoromethyl) benzene, 1,4-bis (trifluoromethyl) benzene, and the like.
- Examples of the solvent used in the organic phase include benzene, toluene, diethyl ether, diisopropyl ether, cyclohexane, 1,3-bis (trifluoromethyl) benzene, 1,4-bis (trifluoromethyl) benzene, dimethyl sulfoxide, and the like. It is done.
- Examples of the base used in the production of the compound (A) include alkali metal hydroxides such as sodium hydroxide and potassium hydroxide, alkali metal hydrides such as sodium hydride and potassium hydride, lithium, sodium and potassium And alkali metals such as triethylamine. These bases can also be used as an aqueous solution having an appropriate concentration.
- the amount of the base is preferably used in the range of 1.05 to 5 mol% with respect to the poly (perfluoroalkylene ether) chain and the hydroxyl group of the compound (a2) having hydroxyl groups at both ends thereof.
- Examples of the catalyst used in the production of the compound (A) include various onium salts, such as tetra-n-butylammonium bromide, tetra-n-butylammonium hydrogen sulfate, benzyltrimethylammonium chloride, tricaprylmethyl.
- Quaternary ammonium compounds such as ammonium chloride; quaternary phosphonium compounds such as tetra-n-butylphosphonium bromide, benzyltriphenylphosphonium chloride, tetraphenylphosphonium chloride, tetraphenylphosphonium bromide; tertiary sulfonium compounds such as benzyltetramethylenesulfonium bromide Etc.
- These catalysts can be used alone or in combination of two or more.
- the amount of the catalyst used is preferably in the range of 1 to 50 mol%, more preferably in the range of 3 to 30 mol% with respect to the amount of styrene (a3).
- the reaction temperature is preferably in the range of 0 to 150 ° C., but is preferably 80 ° C. or lower in the presence of a polymerization inhibitor in order to prevent polymerization reaction of raw materials and products.
- a polymerization inhibitor include phenol polymerization inhibitors such as p-methoxyphenol and 2,4-dimethyl-6-t-butylphenol, and carbamic acid metal salt polymerization inhibitors such as copper dimethyldithiocarbamate. . These polymerization inhibitors can be used alone or in combination of two or more.
- the amount of the polymerization inhibitor used is based on the total amount of the poly (perfluoroalkylene ether) chain, the compound (a2) having a hydroxyl group at both ends thereof, and the styrene (a3) having the halogenated alkyl group. It is preferably used in the range of 10 to 1,000 ppm.
- the end point of the reaction is determined to be the end of the reaction by disappearance of the peak derived from the hydroxyl group of the compound (a2) by, for example, IR spectrum measurement or 1 H-NMR spectrum measurement, and the reaction time is usually in the range of 2 to 50 hours. It is preferable that
- the compound (A) obtained by the above production method can be obtained in a high yield by performing removal of the generated salt, removal of the solvent used, recovery of unreacted raw materials, etc. by a known recovery and purification method. It can be of high purity. For example, after the produced salt is separated by filtration from the reaction solution, the filtrate is washed with water and separated to separate the product. Next, the separated product is washed with an organic solvent such as methanol and separated to separate the product, and then the remaining organic solvent is distilled off and concentrated to easily obtain the desired product.
- an organic solvent such as methanol
- the compound (A) include the following general formulas (A-1) to (A-4). Further, the compound (A) includes two or more compounds having different poly (perfluoroalkylene ether) chain lengths or different divalent organic groups connecting the poly (perfluoroalkylene ether) chain and the styryl group. You may use together.
- the polymerizable unsaturated monomer (B) can be easily converted into a high molecular weight polymer by an ordinary radical polymerization method.
- the reaction is performed by bulk polymerization, solution polymerization, suspension polymerization, Known methods such as emulsion polymerization can be used.
- the radical polymerization reaction can be performed by simple heating or irradiation with ultraviolet rays, but can be quickly started by adding a radical initiator.
- the functional group (b) of the polymerizable unsaturated monomer (B) is at least one selected from the group consisting of a hydroxyl group, an isocyanate group, an epoxy group, a carboxyl group, an acid anhydride group, and a carboxylic acid halide group. is there.
- the polymerizable unsaturated monomer (B) having these functional groups (b) may be used alone or in combination of two or more different functional groups (b). You can also.
- the polymerizable unsaturated group of the monomer (B) is preferably a carbon-carbon unsaturated double bond having radical polymerizability, and more specifically, a vinyl group, (meth) acryloyl group, maleimide. A (meth) acryloyl group is more preferable from the viewpoint of easy polymerization.
- (meth) acrylate refers to one or both of methacrylate and acrylate
- (meth) acryloyl group refers to one or both of methacryloyl group and acryloyl group
- (( “Meth) acrylic acid” refers to one or both of methacrylic acid and acrylic acid.
- polymerizable unsaturated monomer (B) examples include 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate, 2-hydroxybutyl (meth) ) Acrylate, 4-hydroxybutyl (meth) acrylate, 1,4-cyclohexanedimethanol mono (meth) acrylate, N- (2-hydroxyethyl) (meth) acrylamide, glycerin mono (meth) acrylate, polyethylene glycol mono (meth) ) Acrylate, polypropylene glycol mono (meth) acrylate, 2-hydroxy-3-phenoxypropyl (meth) acrylate, 2- (meth) acryloyloxyethyl-2-hydroxyethyl phthalate, lactone having a hydroxyl group at the terminal Unsaturated monomers having a hydroxyl group such as a functional (meth) acrylate; 2- (meth) acrylate
- the method for producing the polymer (P) is a radical polymerization initiator in the organic solvent with the compound (A) and the monomer (B) and, if necessary, other polymerizable unsaturated monomers. And a method of copolymerization in the presence of.
- the organic solvent used here ketones, esters, amides, sulfoxides, ethers, hydrocarbons, and fluorine-based solvents are preferable.
- These organic solvents are appropriately selected in consideration of the boiling point, compatibility with the raw material or polymer, and polymerizability. Moreover, since the compound (A) is particularly excellent in compatibility with an organic solvent, it is almost soluble in the organic solvent described above.
- radical polymerization initiator examples include acetyl peroxide, cumyl peroxide, t-butyl peroxide, propionyl peroxide, benzoyl peroxide, 2-chlorobenzoyl peroxide, 3-chlorobenzoyl peroxide, 4-hydroxy peroxide.
- chain transfer agent such as lauryl mercaptan, 2-mercaptoethanol, thioglycerol, ethylthioglycolic acid, octylthioglycolic acid or the like can be used as necessary.
- the fluorine-containing curable resin of the present invention is obtained.
- the functional group (c) of the compound (C) is selected from the group consisting of a hydroxyl group, an isocyanate group, an epoxy group, a carboxyl group, and a carboxylic acid halide group that is reactive with the functional group (b). At least one kind.
- the functional group (b) is a hydroxyl group
- the functional group (c) includes an isocyanate group, an epoxy group, a carboxyl group, an acid anhydride group, and a carboxylic acid halide group
- the functional group (b) In the case of an isocyanate group, a hydroxyl group is exemplified as the functional group (c).
- the functional group (b) is an epoxy group
- a hydroxyl group, a carboxyl group, and an acid anhydride group are present as the functional group (c).
- the functional group (b) is a carboxyl group
- examples of the functional group (c) include a hydroxyl group and an epoxy group.
- the functional group (b) is a carboxylic acid halide group
- examples of the group (c) include a hydroxyl group. These may be a combination of a plurality of functional groups as long as the reaction is not hindered.
- the compound (C) include 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate, 2-hydroxybutyl (meth) acrylate, 4-hydroxy Butyl (meth) acrylate, 1,4-cyclohexanedimethanol mono (meth) acrylate, N- (2-hydroxyethyl) (meth) acrylamide, glycerin mono (meth) acrylate, polyethylene glycol mono (meth) acrylate, polypropylene glycol mono (Meth) acrylate, 2-hydroxy-3-phenoxypropyl (meth) acrylate, 2- (meth) acryloyloxyethyl-2-hydroxyethyl phthalate, lactone modified with a hydroxyl group at the terminal (meth) Unsaturated monomer having a hydroxyl group such as acrylate; 2- (meth) acryloyloxyethyl isocyanate,
- unsaturated monomers having a hydroxyl group and a plurality of polymerizable unsaturated groups such as 2-hydroxy-3-acryloyloxypropyl methacrylate, pentaerythritol triacrylate, and dipentaerythritol pentaacrylate can also be used.
- 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 3-hydroxypropyl acrylate, 2-hydroxybutyl acrylate, 4-hydroxybutyl acrylate, 1,4- Cyclohexanedimethanol monoacrylate, N- (2-hydroxyethyl) acrylamide, 2-acryloyloxyethyl isocyanate, 4-hydroxybutyl acrylate glycidyl ether and acrylic acid are preferred.
- the method of reacting the polymer (P) with the functional group (c) having reactivity with respect to the functional group (b) and the compound (C) having a polymerizable unsaturated group is the same as in the compound (C).
- the reaction may be carried out under conditions where the polymerizable unsaturated group is not polymerized.
- the reaction is preferably carried out by adjusting the temperature condition in the range of 30 to 120 ° C. This reaction is preferably carried out in the presence of a catalyst or a polymerization inhibitor, and if necessary in the presence of an organic solvent.
- the functional group (b) is a hydroxyl group and the functional group (c) is an isocyanate group
- the functional group (b) is an isocyanate group
- the functional group (c) is a hydroxyl group.
- p-methoxyphenol, hydroquinone, 2,6-di-t-butyl-4-methylphenol or the like is used as a polymerization inhibitor
- a method in which zinc octylate or the like is used and the reaction temperature is in the range of 20 to 150 ° C., particularly in the range of 40 to 120 ° C., is preferable.
- the functional group (b) is an epoxy group and the functional group (c) is a carboxyl group
- the functional group (b) is a carboxyl group
- the functional group (c) is an epoxy group.
- p-methoxyphenol, hydroquinone, 2,6-di-t-butyl-4-methylphenol or the like is used as a polymerization inhibitor
- tertiary amines such as triethylamine, chloride, etc. are used as an esterification reaction catalyst.
- a reaction temperature 80 to 130 ° C., particularly 100 to 120 ° C. It is preferable to make it react with.
- the organic solvent used in the above reaction is preferably ketones, esters, amides, sulfoxides, ethers, hydrocarbons, or fluorine-based solvents, specifically acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, acetic acid.
- the fluorine-containing curable resin of the present invention obtained as described above can prevent gelation during production and can impart excellent antifouling properties to the cured coating film, so that its number average molecular weight (Mn) is 1,
- Mn number average molecular weight
- the range is preferably from 000 to 20,000, more preferably from 1,500 to 10,000.
- the weight average molecular weight (Mw) is preferably in the range of 3,000 to 80,000, and more preferably in the range of 4,000 to 50,000.
- the number average molecular weight (Mn) and the weight average molecular weight (Mw) are values converted to polystyrene based on gel permeation chromatography (hereinafter abbreviated as “GPC”) measurement.
- GPC gel permeation chromatography
- the fluorine content in the fluorine-containing curable resin of the present invention is preferably in the range of 2 to 50% by mass, since both antifouling properties and compatibility with other components can be achieved.
- the range of 40% by mass is more preferable, and the range of 10 to 35% by mass is more preferable.
- the fluorine content in the fluorine-containing radical polymerizable copolymer of the present invention is a value calculated from the mass ratio of fluorine atoms with respect to the total amount of raw materials used.
- the fluorine-containing curable resin of the present invention can be used as a main component of the active energy ray curable composition itself, but has an extremely excellent surface modification performance, and therefore the active energy ray curable composition.
- a fluorine-containing surfactant to be added to the coating film By using it as a fluorine-containing surfactant to be added to the coating film, excellent antifouling properties can be imparted to the cured coating film.
- the active energy ray-curable composition of the present invention is a blend of the fluorine-containing curable resin of the present invention.
- the main component thereof is the active energy ray-curable resin (D) or active energy ray-curable property.
- the active energy ray curable resin (D) and the active energy ray curable monomer (E) may be used alone or in combination. It doesn't matter.
- the fluorine-containing curable resin of the present invention is preferably used as a fluorine-containing surfactant in the active energy ray-curable composition.
- the active energy ray-curable resin (D) is a urethane (meth) acrylate resin, an unsaturated polyester resin, an epoxy (meth) acrylate resin, a polyester (meth) acrylate resin, an acrylic (meth) acrylate resin, or a resin having a maleimide group.
- a urethane (meth) acrylate resin is particularly preferable from the viewpoint of transparency and low shrinkage.
- the urethane (meth) acrylate resin used here is a resin having a urethane bond and a (meth) acryloyl group obtained by reacting an aliphatic polyisocyanate compound or an aromatic polyisocyanate compound with a (meth) acrylate compound having a hydroxyl group. Is mentioned.
- Examples of the aliphatic polyisocyanate compound include tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate, heptamethylene diisocyanate, octamethylene diisocyanate, decamethylene diisocyanate, 2-methyl-1,5-pentane diisocyanate, 3-methyl- 1,5-pentane diisocyanate, dodecamethylene diisocyanate, 2-methylpentamethylene diisocyanate, 2,2,4-trimethylhexamethylene diisocyanate, 2,4,4-trimethylhexamethylene diisocyanate, isophorone diisocyanate, norbornane diisocyanate, hydrogenated diphenylmethane diisocyanate , Hydrogenated tolylene diisocyanate, hydrogenated xylylene Diisocyanate, hydrogenated tetramethylxylylene diisocyanate, cyclohexyl diisocyanate
- examples of the acrylate compound having a hydroxyl group include 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 2-hydroxybutyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, Monohydric alcohol mono (meth) acrylates such as 5-pentanediol mono (meth) acrylate, 1,6-hexanediol mono (meth) acrylate, neopentyl glycol mono (meth) acrylate, hydroxypivalate neopentyl glycol mono (meth) acrylate (Meth) acrylate; trimethylolpropane di (meth) acrylate, ethoxylated trimethylolpropane (meth) acrylate, propoxylated trimethylolpropane di (meth) acrylate, glycerin di (meth) Mono- or di (meth) acrylates of trivalent alcohol
- a compound having a group, or a polyfunctional (meth) acrylate having a hydroxyl group obtained by modifying the compound with ⁇ -caprolactone; dipropylene glycol mono (meth) acrylate, diethylene glycol mono (meth) acrylate, (Meth) acrylate compounds having an oxyalkylene chain such as propylene glycol mono (meth) acrylate and polyethylene glycol mono (meth) acrylate; polyethylene glycol-polypropylene glycol mono (meth) acrylate, polyoxybutylene-polyoxypropylene mono (meth) (Meth) acrylate compounds having block structure oxyalkylene chains such as acrylate; random structures such as poly (ethylene glycol-tetramethylene glycol) mono (meth) acrylate and poly (propylene glycol-tetramethylene glycol) mono (meth) acrylate And (meth) acrylate compounds having an oxyalkylene chain.
- urethanization catalysts that can be used here include amines such as pyridine, pyrrole, triethylamine, diethylamine, and dibutylamine, phosphines such as triphenylphosphine and triethylphosphine, dibutyltin dilaurate, octyltin trilaurate, and octyl.
- organotin compounds such as tin diacetate, dibutyltin diacetate, and tin octylate, and organometallic compounds such as zinc octylate.
- urethane acrylate resins those obtained by reacting an aliphatic polyisocyanate compound with a (meth) acrylate compound having a hydroxyl group are excellent in transparency of the cured coating film and have good sensitivity to active energy rays. It is preferable from the viewpoint of excellent curability.
- the unsaturated polyester resin is a curable resin obtained by polycondensation of ⁇ , ⁇ -unsaturated dibasic acid or its acid anhydride, aromatic saturated dibasic acid or its acid anhydride, and glycols.
- ⁇ , ⁇ -unsaturated dibasic acid or its acid anhydride include maleic acid, maleic anhydride, fumaric acid, itaconic acid, citraconic acid, chloromaleic acid, and esters thereof.
- aromatic saturated dibasic acid or acid anhydride thereof phthalic acid, phthalic anhydride, isophthalic acid, terephthalic acid, nitrophthalic acid, tetrahydrophthalic anhydride, endomethylenetetrahydrophthalic anhydride, halogenated phthalic anhydride and these Examples include esters.
- the aliphatic or alicyclic saturated dibasic acid include oxalic acid, malonic acid, succinic acid, adipic acid, sebacic acid, azelaic acid, glutaric acid, hexahydrophthalic anhydride, and esters thereof.
- glycols include ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, 1,3-butanediol, 1,4-butanediol, 2-methylpropane-1,3-diol, neopentyl glycol, triethylene glycol, Examples include tetraethylene glycol, 1,5-pentanediol, 1,6-hexanediol, bisphenol A, hydrogenated bisphenol A, ethylene glycol carbonate, 2,2-di- (4-hydroxypropoxydiphenyl) propane, etc.
- oxides such as ethylene oxide and propylene oxide can be used in the same manner.
- epoxy vinyl ester resin (meth) acrylic acid is reacted with an epoxy group of an epoxy resin such as a bisphenol A type epoxy resin, a bisphenol F type epoxy resin, a phenol novolac type epoxy resin, or a cresol novolak type epoxy resin. What is obtained is mentioned.
- an epoxy resin such as a bisphenol A type epoxy resin, a bisphenol F type epoxy resin, a phenol novolac type epoxy resin, or a cresol novolak type epoxy resin. What is obtained is mentioned.
- the resin having a maleimide group includes a bifunctional maleimide urethane compound obtained by urethanizing N-hydroxyethylmaleimide and isophorone diisocyanate, and a bifunctional maleimide ester compound obtained by esterifying maleimide acetic acid and polytetramethylene glycol.
- Examples thereof include tetrafunctional maleimide ester compounds obtained by esterification of maleimidocaproic acid and a tetraethylene oxide adduct of pentaerythritol, and polyfunctional maleimide ester compounds obtained by esterification of maleimide acetic acid and a polyhydric alcohol compound.
- These active energy ray-curable resins (F) can be used alone or in combination of two or more.
- Examples of the active energy ray-curable monomer (E) include ethylene glycol di (meth) acrylate, diethylene glycol di (meth) acrylate, triethylene glycol di (meth) acrylate, and a number average molecular weight in the range of 150 to 1,000.
- trimethylolpropane tri (meth) acrylate pentaerythritol tri (meth) acrylate, dipentaerythritol hexa (meth) acrylate, pentaerythritol tetra
- a trifunctional or higher polyfunctional (meth) acrylate such as (meth) acrylate is preferred.
- active energy ray-curable monomers (E) can be used alone or in combination of two or more.
- the amount used thereof is the active energy ray-curable resin (D) and the active energy ray.
- the amount is preferably in the range of 0.01 to 10 parts by mass, more preferably in the range of 0.1 to 5 parts by mass with respect to 100 parts by mass in total of the curable monomer (E). If the amount of the fluorine-containing curable resin of the present invention is in this range, the leveling property, water / oil repellency and antifouling property can be made sufficient, and the hardness and transparency after curing of the composition can be achieved. Can also be sufficient.
- the fluorine-containing curable resin or active energy ray-curable composition of the present invention can be formed into a cured coating film by irradiating active energy rays after being applied to a substrate.
- the active energy rays refer to ionizing radiation such as ultraviolet rays, electron beams, ⁇ rays, ⁇ rays, and ⁇ rays.
- a photopolymerization initiator (F) is added to the fluorine-containing curable resin or active energy ray curable composition to improve curability. It is preferable. Further, if necessary, a photosensitizer can be further added to improve curability.
- ionizing radiation such as electron beam, ⁇ -ray, ⁇ -ray, and ⁇ -ray
- F) or a photosensitizer need not be added.
- Examples of the photopolymerization initiator (F) include intramolecular cleavage type photopolymerization initiators and hydrogen abstraction type photopolymerization initiators.
- Examples of the intramolecular cleavage type photopolymerization initiator include diethoxyacetophenone, 2-hydroxy-2-methyl-1-phenylpropan-1-one, benzyldimethyl ketal, 1- (4-isopropylphenyl) -2-hydroxy.
- Acetophenone compounds such as propan-1-one, 2-benzyl-2-dimethylamino-1- (4-morpholinophenyl) butanone; benzoins such as benzoin, benzoin methyl ether, benzoin isopropyl ether; 2, 4, 6 -Trimethylbenzoin diphenylphosphine Kishido, bis (2,4,6-trimethylbenzoyl) acyl phosphine oxide-based compounds such as triphenylphosphine oxide; benzyl, and methyl phenylglyoxylate ester.
- examples of the hydrogen abstraction type photopolymerization initiator include benzophenone, methyl 4-phenylbenzophenone o-benzoylbenzoate, 4,4′-dichlorobenzophenone, hydroxybenzophenone, 4-benzoyl-4′-methyl-diphenyl sulfide.
- Benzophenone compounds such as acrylated benzophenone, 3,3 ′, 4,4′-tetra (t-butylperoxycarbonyl) benzophenone, 3,3′-dimethyl-4-methoxybenzophenone; 2-isopropylthioxanthone, 2,4 -Thioxanthone compounds such as dimethylthioxanthone, 2,4-diethylthioxanthone, 2,4-dichlorothioxanthone; Aminobenzophenone compounds such as Michler-ketone, 4,4'-diethylaminobenzophenone; -2-chloro acridone, 2-ethyl anthraquinone, 9,10-phenanthrenequinone, camphorquinone, and the like.
- the compatibility with the active energy ray curable resin (D) and the active energy ray curable monomer (E) in the active energy ray curable composition is excellent. Therefore, 1-hydroxycyclohexyl phenyl ketone and benzophenone are preferable, and 1-hydroxycyclohexyl phenyl ketone is particularly preferable.
- These photopolymerization initiators (F) can be used alone or in combination of two or more.
- the photosensitizer examples include amines such as aliphatic amines and aromatic amines, ureas such as o-tolylthiourea, sodium diethyldithiophosphate, s-benzylisothiouronium-p-toluenesulfonate, and the like. And sulfur compounds.
- photopolymerization initiators and photosensitizers are preferably used in an amount of 0.01 to 20 parts by weight, preferably 0.1 to 15 parts by weight, per 100 parts by weight of the nonvolatile component in the active energy ray-curable composition. Part is more preferable, and 0.3 to 7 parts by mass is even more preferable.
- the active energy ray-curable composition of the present invention is not limited to the effects of the present invention, depending on the purpose of use, characteristics, etc.
- Various compounding materials for the purpose of adjusting coating properties and coating film properties such as various organic solvents, acrylic resins, phenol resins, polyester resins, polystyrene resins, urethane resins, urea resins, melamine resins, alkyd resins, epoxy resins,
- Various resins such as polyamide resin, polycarbonate resin, petroleum resin, fluororesin, various organic or inorganic particles such as PTFE (polytetrafluoroethylene), polyethylene, polypropylene, carbon, titanium oxide, alumina, copper, silica fine particles, polymerization start Agent, polymerization inhibitor, antistatic agent, antifoaming agent, viscosity modifier, light stabilizer, weather stabilizer, Stabilizers, antioxidants, rust inhibitors, slip agents, waxes, gloss modifiers, mold release agents, compatibilizers, conduct
- the organic solvent is useful for appropriately adjusting the solution viscosity of the active energy ray-curable composition of the present invention.
- the film thickness can be adjusted. It becomes easy.
- the organic solvent that can be used here include aromatic hydrocarbons such as toluene and xylene; alcohols such as methanol, ethanol, isopropanol and t-butanol; esters such as ethyl acetate and propylene glycol monomethyl ether acetate; methyl ethyl ketone, Examples thereof include ketones such as methyl isobutyl ketone and cyclohexanone. These solvents can be used alone or in combination of two or more.
- the amount of the organic solvent to be used varies depending on the intended use and the intended film thickness and viscosity, but is preferably in the range of 0.5 to 4 times the mass of the total mass of the curing component.
- the active energy ray for curing the active energy ray-curable composition of the present invention is an ionizing radiation such as an ultraviolet ray, an electron beam, an ⁇ ray, a ⁇ ray, and a ⁇ ray.
- an ionizing radiation such as an ultraviolet ray, an electron beam, an ⁇ ray, a ⁇ ray, and a ⁇ ray.
- a curing device for example, a germicidal lamp, an ultraviolet fluorescent lamp, a carbon arc, a xenon lamp, a high-pressure mercury lamp for copying, a medium or high-pressure mercury lamp, an ultra-high pressure mercury lamp, an electrodeless lamp, a metal halide lamp, natural light, etc.
- the electron beam include ultraviolet rays, a scanning type, and a curtain type electron beam accelerator.
- ultraviolet rays are particularly preferable, and ultraviolet rays are preferably irradiated in an inert gas atmosphere such as nitrogen gas in order to avoid curing inhibition due to oxygen or the like. Further, if necessary, heat may be used as an energy source and heat treatment may be performed after curing with ultraviolet rays.
- the application method of the active energy ray-curable composition of the present invention varies depending on the application.
- the cured coating film of the fluorine-containing curable resin of the present invention has excellent antifouling properties (ink repellency, fingerprint resistance, etc.), scratch resistance, etc. It is possible to impart antifouling property, scratch resistance, etc. Moreover, since the fluorine-containing curable resin of the present invention can add leveling properties to the coating material by adding it as a fluorine-containing surfactant to the coating material, the active energy ray-curable composition of the present invention. Has high leveling properties.
- Examples of articles that can be imparted with antifouling properties (ink repellency, fingerprint resistance, etc.) using the fluorine-containing curable resin or active energy ray-curable composition of the present invention include polarization of liquid crystal displays (LCD) such as TAC films.
- LCD liquid crystal displays
- Film for plates Various display screens such as plasma display (PDP) and organic EL display; Touch panel; Case or screen of electronic terminal such as mobile phone; Transparent protection for color filter for liquid crystal display (hereinafter referred to as “CF”) Film: Organic insulating film for liquid crystal TFT array; Ink-jet ink for forming electronic circuit; Optical recording medium such as CD, DVD, Blu-ray disc; Transfer film for insert mold (IMD, IMF); Rubber for OA equipment such as copier and printer Roller; Glass surface of the reading part of OA equipment such as copiers and scanners; Optical lenses such as LA, video camera, glasses, etc .; windshields of watches such as watches, glass surfaces; windows of various vehicles such as automobiles and railway vehicles; cover glasses or films for solar cells; various building materials such as decorative panels; Glass; woodworking materials such as furniture, artificial and synthetic leather, various plastic molded products such as housings for home appliances, FRP bathtubs, and the like.
- CF Transparent protection for color filter for liquid crystal display
- antifouling properties can be imparted to the article surfaces.
- TAC Hard coating material for polarizing plate film of LCD such as film, anti-glare (AG: anti-glare) coating material or anti-reflection (LR) coating material; hard coating material for various display screens such as plasma display and organic EL display (PDP) Hard coat material for touch panel; color resist, printing ink, inkjet ink or paint for forming each pixel of RGB used in CF; black resist, printing ink, inkjet ink or paint for black matrix of CF; plasma Resin composition for pixel partition walls of displays (PDP), organic EL displays, etc.
- PDP plasma display and organic EL display
- Coating materials for electronic terminals such as mobile phones or hard coating materials; hard coating materials for mobile phone screens; transparent protective film coatings that protect the CF surface; coatings for organic insulating films of liquid crystal TFT arrays; Ink-jet inks; Hard coating materials for optical recording media such as CDs, DVDs, Blu-ray discs; Hard coating materials for transfer films for insert molds (IMD, IMF); Coating materials for rubber rollers for OA equipment such as copying machines and printers; Glass coating material for reading parts of OA equipment such as copy machines and scanners; Optical lens coating materials for cameras, video cameras, glasses, etc .; Windshields for watches such as watches, glass coating materials; Various types of automobiles, railway vehicles, etc.
- a prism sheet that is a backlight member of an LCD or Examples thereof include a diffusion sheet. Further, by adding the fluorine-containing curable resin of the present invention to the prism sheet or the diffusion sheet coating material, the leveling property of the coating material is improved and the coating film of the coating material is scratch resistant (scratch resistance). And antifouling property can be provided.
- optical fiber cladding materials As other applications in which the fluorine-containing curable resin or the active energy ray-curable composition of the present invention can be used, optical fiber cladding materials, waveguides, liquid crystal panel sealing materials, various optical sealing materials, optical Adhesives and the like.
- the active energy ray-curable composition of the present invention when used as an antiglare coating material among coating materials for protective films for polarizing plates for LCDs, among the above-described compositions, silica fine particles, acrylic resin fine particles, polystyrene resin Excellent anti-glare properties by blending inorganic or organic fine particles such as fine particles at a ratio of 0.1 to 0.5 times the total mass of the curing component in the active energy ray-curable composition of the present invention. Since it becomes a thing, it is preferable.
- the fluorine-containing curable resin or the active energy ray-curable composition of the present invention is used for an antiglare coating material for a protective film of a polarizing plate for LCD, a mold having an uneven surface shape is formed before the coating material is cured. After the contact, the active energy ray is irradiated from the side opposite to the mold and cured, and the surface of the coating layer can be embossed to apply an antiglare property.
- the measurement method of IR spectrum and NMR spectrum of the obtained poly (perfluoroalkylene ether) chain and a compound having a styryl group at both ends thereof, and the measurement conditions of GPC of the fluorinated curable resin are as follows. .
- X represents a perfluoromethylene group and a perfluoroethylene group, and an average of 7 perfluoromethylene groups and an average of 8 perfluoroethylene groups per molecule.
- FIG. 1 shows a chart of IR spectrum
- FIG. 2 shows a chart of 1 H-NMR spectrum
- FIG. 3 shows a chart of 13 C-NMR spectrum.
- X represents a perfluoromethylene group and a perfluoroethylene group, and an average of 7 perfluoromethylene groups and an average of 8 perfluoroethylene groups per molecule.
- X represents a perfluoromethylene group and a perfluoroethylene group, and an average of 19 perfluoromethylene groups and an average of 19 perfluoroethylene groups per molecule.
- X represents a perfluoromethylene group and a perfluoroethylene group, and an average of 19 perfluoromethylene groups and an average of 19 perfluoroethylene groups per molecule.
- the mixture is stirred at 10 ° C. for 1 hour, heated to 30 ° C. for 1 hour, then heated to 50 ° C. and stirred for 10 hours, and acrylic acid is measured by gas chromatography. The disappearance of chloride was confirmed.
- 80 parts by mass of ion-exchanged water was mixed and stirred, and then left to stand to separate and remove the aqueous layer, and washing was repeated 3 times.
- compound (A ′) having a poly (perfluoroalkylene ether) chain represented by the following formula (A ′) and an acryloyl group at both ends thereof. For short).
- X represents a perfluoromethylene group and a perfluoroethylene group, and an average of 7 perfluoromethylene groups and an average of 8 perfluoroethylene groups per molecule.
- Example 1 A glass flask equipped with a stirrer, thermometer, condenser, and dropping device was charged with 80 parts by mass of methyl isobutyl ketone as a solvent and heated to 105 ° C. while stirring under a nitrogen stream. Next, a monomer solution in which 20 parts by mass of the compound (A-1-1) obtained in Synthesis Example 1 was dissolved in 20 parts by mass of methyl isobutyl ketone, and 38.4 parts by mass of 2-hydroxyethyl methacrylate were 38 parts by mass of methyl isobutyl ketone.
- a methyl isobutyl ketone solution containing 50% by mass of the fluorine curable resin (1) was obtained.
- GPC polystyrene equivalent molecular weight
- Example 2 A glass flask equipped with a stirrer, thermometer, condenser, and dropping device was charged with 58 parts by mass of methyl isobutyl ketone as a solvent and heated to 105 ° C. while stirring under a nitrogen stream. Next, a monomer solution obtained by dissolving 36 parts by mass of the compound (A-1-1) obtained in Synthesis Example 1 in 20 parts by mass of methyl isobutyl ketone, 30.7 parts by mass of 2-hydroxyethyl methacrylate, and 25.
- dripping liquids Three types of dripping liquids: a monomer solution dissolved in 7 parts by mass and a polymerization initiator solution in which 10 parts by mass of t-butylperoxy-2-ethylhexanoate as a radical polymerization initiator was dissolved in 20 parts by mass of methyl isobutyl ketone.
- a monomer solution dissolved in 7 parts by mass
- a polymerization initiator solution in which 10 parts by mass of t-butylperoxy-2-ethylhexanoate as a radical polymerization initiator was dissolved in 20 parts by mass of methyl isobutyl ketone.
- a methyl isobutyl ketone solution containing 50% by mass of the fluorine curable resin (2) was obtained.
- GPC polystyrene equivalent molecular weight
- Example 3 A glass flask equipped with a stirrer, a thermometer, a condenser, and a dropping device was charged with 73.1 parts by mass of 1,3-bis (trifluoromethyl) benzene as a solvent, and stirred at 105 ° C. while stirring under a nitrogen stream. The temperature rose.
- Example 4 A glass flask equipped with a stirrer, thermometer, condenser, and dropping device was charged with 58.5 parts by mass of 1,3-bis (trifluoromethyl) benzene as a solvent, and stirred at 105 ° C. under a nitrogen stream. The temperature rose.
- a methyl ethyl ketone solution containing 50% by mass of the fluorine curable resin (6) was obtained.
- GPC polystyrene equivalent molecular weight
- Examples 5 to 8 and Comparative Examples 3 to 5 The fluorinated curable resin solutions (1) to (5) obtained in Examples 1 and 2 and Comparative Examples 1 and 2 as the fluorinated surfactant were added to 268 parts by mass of the base resin composition obtained above. An amount of 1 part by mass was added and mixed uniformly to obtain an active energy ray-curable composition. Next, this active energy ray-curable composition was treated with a bar coater No. 13 was applied to a polyethylene terephthalate (PET) film having a thickness of 188 ⁇ m, and then placed in a dryer at 60 ° C. for 5 minutes to volatilize the solvent.
- PET polyethylene terephthalate
- the dried coating film was cured by irradiating with ultraviolet rays (UV) with an ultraviolet curing device (in a nitrogen atmosphere, a high pressure mercury lamp, an ultraviolet irradiation amount of 2 kJ / m 2 ), and Examples 5 to 8 and Comparative Examples 3 to 4 were cured.
- a coated film was prepared.
- the coating film was similarly produced about only the base resin composition of the active energy ray curable composition, without adding anything, and it was set as the comparative example 5.
- the antifouling property of the coated surface of the coated film obtained above was evaluated from the following contact angle of water and n-dodecane, antifouling property, and the number of repeated wiping off of dirt.
- the dirt wiping property was evaluated according to the following criteria from the result of the number of times of wiping and removing the dirt measured as described above.
- the cured coating films of the active energy ray-curable compositions of Examples 5 to 8 to which the fluorine-containing curable resins (1) to (4) of the present invention obtained in Examples 1 to 4 were added were water and n- It was found that the contact angle of dodecane was high, and the contact angle did not decrease greatly even after alkali treatment. In addition, the anti-smudge property of felt pen inks is high for both black and blue inks, and since the decrease in anti-smudge property is suppressed even after alkaline treatment, it has a high anti-smudge property against any stains. In addition, it has been found that it has stable antifouling performance even when it comes into contact with chemicals such as alkali. Furthermore, the dirt wiping property was also high, and in particular, the sample of Example 6 was found to have a very excellent dirt wiping property with the number of times of wiping off the dirt exceeding 20 times.
- Comparative Example 3 using the fluorine-containing curable resin (5) having a perfluoroalkyl group introduced in place of the poly (perfluoroalkylene ether) chain produced in Comparative Example 1 has a water contact angle of less than 100 °. It was found that the water repellency was insufficient. Further, the anti-smudge property was good for the blue ink, but the black ink was found to have a problem that the anti-smudge property was greatly lowered after the alkali treatment. Further, it was found that the dirt wiping property was low and it was difficult to wipe off the dirt repeatedly.
- Comparative Example 4 using a fluorine-containing curable resin (6) made from a compound having an acryloyl group at both ends of the poly (perfluoroalkylene ether) chain produced in Comparative Example 2 is a contact between water and n-dodecane. Although the angle is high, it has been found that there is a problem that the contact angle greatly decreases after alkali treatment. In addition, the anti-smudge property was good for blue ink, but for black ink, it was found that the anti-smudge property was greatly reduced after alkali treatment.
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Abstract
Description
測定装置:東ソー株式会社製「HLC-8220 GPC」、
カラム:東ソー株式会社製ガードカラム「HHR-H」(6.0mmI.D.×4cm)
+東ソー株式会社製「TSK-GEL GMHHR-N」(7.8mmI.D.×30cm)
+東ソー株式会社製「TSK-GEL GMHHR-N」(7.8mmI.D.×30cm)
+東ソー株式会社製「TSK-GEL GMHHR-N」(7.8mmI.D.×30cm)
+東ソー株式会社製「TSK-GEL GMHHR-N」(7.8mmI.D.×30cm)
検出器:ELSD(オルテック製「ELSD2000」)
データ処理:東ソー株式会社製「GPC-8020モデルIIデータ解析バージョン4.30」
測定条件:カラム温度 40℃
展開溶媒 テトラヒドロフラン(THF)
流速 1.0ml/分
試料:樹脂固形分換算で1.0質量%のテトラヒドロフラン溶液をマイクロフィルターでろ過したもの(5μl)。
標準試料:前記「GPC-8020モデルIIデータ解析バージョン4.30」の測定マニュアルに準拠して、分子量が既知の下記の単分散ポリスチレンを用いた。
東ソー株式会社製「A-500」
東ソー株式会社製「A-1000」
東ソー株式会社製「A-2500」
東ソー株式会社製「A-5000」
東ソー株式会社製「F-1」
東ソー株式会社製「F-2」
東ソー株式会社製「F-4」
東ソー株式会社製「F-10」
東ソー株式会社製「F-20」
東ソー株式会社製「F-40」
東ソー株式会社製「F-80」
東ソー株式会社製「F-128」
東ソー株式会社製「F-288」
東ソー株式会社製「F-550」
株式会社島津製作所製「IRPrestige-21」の測定装置を用いて、試料溶液をKBr板に極少量滴下して溶剤を乾燥後、測定を行った。
日本電子株式会社製「AL-400」を用いて、試料のアセトン-d6溶液を分析して化合物の構造解析を行った。
測定装置:東ソー株式会社製「HLC-8220 GPC」、
カラム:東ソー株式会社製ガードカラム「HHR-H」(6.0mmI.D.×4cm)
+東ソー株式会社製「TSK-GEL GMHHR-N」(7.8mmI.D.×30cm)
+東ソー株式会社製「TSK-GEL GMHHR-N」(7.8mmI.D.×30cm)
+東ソー株式会社製「TSK-GEL GMHHR-N」(7.8mmI.D.×30cm)
+東ソー株式会社製「TSK-GEL GMHHR-N」(7.8mmI.D.×30cm)
検出器:ELSD(オルテック製「ELSD2000」)
データ処理:東ソー株式会社製「GPC-8020モデルIIデータ解析バージョン4.30」
測定条件:カラム温度 40℃
展開溶媒 テトラヒドロフラン(THF)
流速 1.0ml/分
試料:樹脂固形分換算で1.0質量%のテトラヒドロフラン溶液をマイクロフィルターでろ過したもの(5μl)。
標準試料:前記「GPC-8020モデルIIデータ解析バージョン4.30」の測定マニュアルに準拠して、分子量が既知の下記の単分散ポリスチレンを用いた。
東ソー株式会社製「A-500」
東ソー株式会社製「A-1000」
東ソー株式会社製「A-2500」
東ソー株式会社製「A-5000」
東ソー株式会社製「F-1」
東ソー株式会社製「F-2」
東ソー株式会社製「F-4」
東ソー株式会社製「F-10」
東ソー株式会社製「F-20」
東ソー株式会社製「F-40」
東ソー株式会社製「F-80」
東ソー株式会社製「F-128」
東ソー株式会社製「F-288」
東ソー株式会社製「F-550」
撹拌装置、温度計、冷却管、滴下装置を備えたガラスフラスコに、下記式(a2-1-1)で表される両末端に水酸基を有するパーフルオロポリエーテル化合物200質量部、p-クロロメチルスチレン123.4質量部、p-メトキシフェノール0.06質量部、ベンジルトリエチルアンモニウムクロライドの50質量%水溶液32.3質量部及びヨウ化カリウム1.35質量部を仕込んだ。次いで、空気気流下にて攪拌を開始し、フラスコ内温度を45℃に昇温させ、水酸化ナトリウムの49質量%水溶液9.2質量部を2時間かけて滴下した。滴下終了後、60℃まで昇温し、1時間攪拌させた。この後、水酸化ナトリウムの49質量%水溶液37.1質量部を4時間かけて滴下した後、さらに15時間反応した。
撹拌装置、温度計、冷却管、滴下装置を備えたガラスフラスコに、下記式(a2-1-1)で表される両末端に水酸基を有するパーフルオロポリエーテル化合物150質量部、p-クロロメチルスチレン68質量部、p-メトキシフェノール0.05質量部、ベンジルトリエチルアンモニウムクロライドの50質量%水溶液44質量部及びヨウ化カリウム0.12質量部を仕込んだ。次いで、空気気流下にて攪拌を開始し、フラスコ内温度を45℃に昇温させ、水酸化ナトリウムの49質量%水溶液1.3質量部を2時間かけて滴下した。滴下終了後、60℃まで昇温し、1時間攪拌させた。この後、水酸化ナトリウムの49質量%水溶液11.5質量部を4時間かけて滴下した後、さらに15時間反応した。
撹拌装置、温度計、冷却管、滴下装置を備えたガラスフラスコに、上記式(a2-1-1)で表される両末端に水酸基を有するパーフルオロポリエーテル化合物20質量部、溶媒としてジイソプロピルエーテル20質量部、重合禁止剤としてp-メトキシフェノール0.02質量部及び中和剤としてトリエチルアミン3.1質量部を仕込み、空気気流下にて攪拌を開始し、フラスコ内を10℃に保ちながらアクリル酸クロライド2.7質量部を1時間かけて滴下した。滴下終了後、10℃で1時間攪拌し、昇温して30℃で1時間攪拌した後、50℃に昇温して10時間攪拌することにより反応を行い、ガスクロマトグラフィー測定にてアクリル酸クロライドの消失が確認された。次いで、溶媒としてジイソプロピルエーテル40質量部を追加した後、イオン交換水80質量部を混合して攪拌してから静置し水層を分離させて取り除く方法による洗浄を3回繰り返した。次いで、重合禁止剤としてp-メトキシフェノール0.02質量部を添加し、脱水剤として硫酸マグネシウム8質量部を添加して1日間静置することで完全に脱水した後、脱水剤を濾別した。
撹拌装置、温度計、冷却管、滴下装置を備えたガラスフラスコに、溶媒としてメチルイソブチルケトン80質量部を仕込み、窒素気流下にて攪拌しながら105℃に昇温した。次いで、合成例1で得られた化合物(A-1-1)20質量部をメチルイソブチルケトン20質量部に溶解したモノマー溶液と、2-ヒドロキシエチルメタクリレート38.4質量部をメチルイソブチルケトン38質量部に溶解したモノマー溶液と、ラジカル重合開始剤としてt-ブチルペルオキシ-2-エチルヘキサノエート8.8質量部をメチルイソブチルケトン26質量部に溶解した重合開始剤溶液との3種類の滴下液をそれぞれ別々の滴下装置にセットし、フラスコ内を105℃に保ちながら同時に2時間かけて滴下した。滴下終了後、105℃で10時間攪拌した後、減圧下で溶媒の一部を留去することによって、重合体(P-1)を得た。
撹拌装置、温度計、冷却管、滴下装置を備えたガラスフラスコに、溶媒としてメチルイソブチルケトン58質量部を仕込み、窒素気流下にて攪拌しながら105℃に昇温した。次いで、合成例1で得られた化合物(A-1-1)36質量部をメチルイソブチルケトン20質量部に溶解したモノマー溶液と、2-ヒドロキシエチルメタクリレート30.7質量部をメチルイソブチルケトン25.7質量部に溶解したモノマー溶液と、ラジカル重合開始剤としてt-ブチルペルオキシ-2-エチルヘキサノエート10質量部をメチルイソブチルケトン20質量部に溶解した重合開始剤溶液との3種類の滴下液をそれぞれ別々の滴下装置にセットし、フラスコ内を105℃に保ちながら同時に2時間かけて滴下した。滴下終了後、105℃で10時間攪拌した後、減圧下で溶媒の一部を留去することによって、重合体(P-2)を得た。
撹拌装置、温度計、冷却管、滴下装置を備えたガラスフラスコに、溶媒として1,3-ビス(トリフルオロメチル)ベンゼン73.1質量部を仕込み、窒素気流下にて攪拌しながら105℃に昇温した。次いで、合成例2で得られた単量体(A-1-2)41.8質量部と、2-ヒドロキシエチルメタクリレート80質量部と、ラジカル重合開始剤としてt-ブチルペルオキシ-2-エチルヘキサノエート18.3質量部を1,3-ビス(トリフルオロメチル)ベンゼン153.1質量部に溶解した重合開始剤溶液との3種類の滴下液をそれぞれ別々の滴下装置にセットし、フラスコ内を105℃に保ちながら同時に2時間かけて滴下した。滴下終了後、105℃で10時間攪拌することによって、重合体(P-3)の溶液を得た。
撹拌装置、温度計、冷却管、滴下装置を備えたガラスフラスコに、溶媒として1,3-ビス(トリフルオロメチル)ベンゼン58.5質量部を仕込み、窒素気流下にて攪拌しながら105℃に昇温した。次いで、合成例1で得られた単量体(A-1-1)10質量部及び合成例2で得られた単量体(A-1-2)10質量部の混合物と、2-ヒドロキシエチルメタクリレート38.4質量部と、ラジカル重合開始剤としてt-ブチルペルオキシ-2-エチルヘキサノエート8.8質量部を1,3-ビス(トリフルオロメチル)ベンゼン50質量部に溶解した重合開始剤溶液との3種類の滴下液をそれぞれ別々の滴下装置にセットし、フラスコ内を105℃に保ちながら同時に2時間かけて滴下した。滴下終了後、105℃で10時間攪拌することによって、重合体(P-4)の溶液を得た。
撹拌装置、温度計、冷却管、滴下装置を備えたガラスフラスコに、溶媒としてメチルイソブチルケトン69質量部を仕込み、窒素気流下にて攪拌しながら105℃に昇温した。次いで、下記式(Y-1)で表されるフッ素化アルキル基含有アクリレート40質量部及び2-ヒドロキシエチルメタクリレート28.8質量部をメチルイソブチルケトン69質量部に溶解したモノマー溶液137.8質量部と、ラジカル重合開始剤としてt-ブチルペルオキシ-2-エチルヘキサノエート3.4質量部をメチルイソブチルケトン22.5質量部に溶解した重合開始剤溶液25.9質量部との2種類の滴下液をそれぞれ別々の滴下装置にセットし、フラスコ内を105℃に保ちながら同時に3時間かけて滴下した。滴下終了後、105℃で10時間攪拌し、重合体を得た。
撹拌装置、温度計、冷却管、滴下装置を備えたガラスフラスコに、溶媒としてメチルイソブチルケトン63質量部を仕込み、窒素気流下にて攪拌しながら105℃に昇温した。次いで、合成例2で得られたポリ(パーフルオロアルキレンエーテル)鎖とその両末端にアクリロイル基を有する化合物(A’)21.5質量部と、2-ヒドロキシエチルメタクリレート41.3質量部と、ラジカル重合開始剤としてt-ブチルペルオキシ-2-エチルヘキサノエート9.4質量部をメチルイソブチルケトン126質量部に溶解した重合開始剤溶液135.4質量部との3種類の滴下液をそれぞれ別々の滴下装置にセットし、フラスコ内を105℃に保ちながら同時に2時間かけて滴下した。滴下終了後、105℃で10時間攪拌した後、減圧下で溶媒の一部を留去することによって、重合体を得た。
HEMA:2-ヒドロキシエチルメタクリレート
AOI:2-アクリロイルオキシエチルイソシアネート
紫外線硬化性ウレタンアクリレート樹脂(DIC株式会社製「ユニディック17-806」;樹脂分80質量%の酢酸ブチル溶液)125質量部、光重合開始剤として1-ヒドロキシシクロヘキシルフェニルケトン(チバスペシャリティーケミカルズ社製「イルガキュア184」)5質量部、溶剤としてトルエン54質量部、2-プロパノール28質量部、酢酸エチル28質量部、プロピレングリコールモノメチルエーテル28質量部を混合し溶解させて、活性エネルギー線硬化性組成物のベース樹脂組成物を得た。
上記で得られたベース樹脂組成物268質量部に、含フッ素界面活性剤として実施例1~2及び比較例1~2で得られた含フッ素硬化性樹脂溶液(1)~(5)を樹脂分として1質量部となる量を加えて均一に混合して、活性エネルギー線硬化性組成物を得た。次いで、この活性エネルギー線硬化性組成物をバーコーターNo.13を用いて、厚さ188μmのポリエチレンテレフタレート(PET)フィルムに塗布した後、60℃の乾燥機に5分間入れて溶剤を揮発させた。次に、乾燥した塗膜に紫外線硬化装置(窒素雰囲気下、高圧水銀灯、紫外線照射量2kJ/m2)で紫外線(UV)を照射して硬化させ、実施例5~8及び比較例3~4として塗工フィルムを作製した。また、何も添加せずに活性エネルギー線硬化性組成物のベース樹脂組成物のみについても同様に塗工フィルムを作製して比較例5とした。
上記で得られた塗工フィルムの塗工表面の防汚性を、下記の水及びn-ドデカンの接触角、汚れ付着防止性及び汚れ拭き取り繰り返し回数から評価した。
塗工フィルムの塗工表面について、接触角測定装置(協和界面科学株式会社製「MODEL CA-W150」)を用いて、水及びn-ドデカンの接触角を測定した。
塗工フィルムの塗工表面に、フェルトペン(寺西化学工業株式会社製「マジックインキ大型黒色」又は「マジックインキ大型青色」)で線を描き、その黒色インク又は青色インクの付着状態を目視で観察することで汚れ付着防止性の評価を行った。なお、評価基準は下記の通りである。
AA:防汚性が最も良好で、インクが玉状にはじくもの。
A:インクが玉状にはじかず、線状のはじきが生じるもの(線幅がフェルトペンのペン先の幅の50%未満)。
B:インクの線状のはじきが生じ、線幅がフェルトペンのペン先の幅の50%以上100%未満であったもの。
C:インクがまったくはじかずに表面にきれいに描けてしまうもの。
上記の汚れ付着防止性の試験後、付着した黒色インクを荷重1kgにてティッシュペーパーですべて拭き取った後、再度塗工フィルムの塗工表面の同じ場所にフェルトペンで線を描き、付着したインクをティッシュペーパーですべて拭き取ることを繰り返し行い、インクが塗膜表面ではじかなくなるまでに付着したインクをティッシュペーパーで拭き取った回数を汚れ拭き取り除去回数として測定した。
上記で測定した汚れ拭き取り除去回数の結果から、汚れ拭き取り性を下記の基準にて評価した。
A:5回以上のインクの拭き取り除去ができたもの。
B:5回未満のインクの拭き取り除去ができたもの。
C:1回もインクの拭き取り除去できなかったもの。
上記で得られた塗工フィルムを70℃の強アルカリ水溶液(2mol/lの水酸化カリウム水溶液)に1分間浸漬処理した後、純水で洗浄し、100℃で3分乾燥させた後、室温で放冷した塗工フィルムについても、上記と同様の方法で塗工表面に対する水及びn-ドデカンの接触角、汚れ付着防止性を評価した。
Claims (4)
- ポリ(パーフルオロアルキレンエーテル)鎖とその両末端にスチリル基を有する化合物(A)と、水酸基、イソシアネート基、エポキシ基、カルボキシル基、酸無水物基及びカルボン酸ハライド基からなる群から選ばれる少なくとも1つの官能基(b)を有する重合性不飽和単量体(B)とを必須の単量体成分として共重合させて得られる重合体(P)に、前記官能基(b)に対して反応性を有し、かつ水酸基、イソシアネート基、エポキシ基、カルボキシル基、酸無水物基及びカルボン酸ハライド基からなる群から選ばれる少なくとも1つの官能基(c)及び重合性不飽和基を有する化合物(C)を反応させて得られるものであることを特徴とする含フッ素硬化性樹脂。
- 請求項1記載の含フッ素硬化性樹脂、及び、活性エネルギー線硬化性樹脂(D)又は活性エネルギー線硬化性単量体(E)を含有することを特徴とする活性エネルギー線硬化性組成物。
- 請求項1記載の含フッ素硬化性樹脂又は請求項2記載の活性エネルギー線硬化性組成物を、基材に塗布し、活性エネルギー線を照射して硬化させてなることを特徴とする硬化物。
- 請求項1記載の含フッ素硬化性樹脂又は請求項2記載の活性エネルギー線硬化性組成物の硬化塗膜を有することを特徴とする物品。
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CN201180017097.1A CN102834421B (zh) | 2010-03-31 | 2011-03-22 | 含氟固化性树脂及使用其的活性能量线固化性组合物 |
KR1020127007193A KR101732391B1 (ko) | 2010-03-31 | 2011-03-22 | 함불소 경화성 수지 및 그것을 사용한 활성 에너지선 경화성 조성물 |
US13/635,372 US8716361B2 (en) | 2010-03-31 | 2011-03-22 | Curable fluorine-containing resin and active-energy-ray-curable composition including the same |
JP2011522339A JP4873107B2 (ja) | 2010-03-31 | 2011-03-22 | 含フッ素硬化性樹脂及びそれを用いた活性エネルギー線硬化性組成物 |
EP20110762623 EP2554554B1 (en) | 2010-03-31 | 2011-03-22 | Curable fluorine-containing resin and active energy ray curable composition using same |
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JP2014065865A (ja) * | 2012-09-27 | 2014-04-17 | Dic Corp | 重合性樹脂、カラーフィルター画素形成用組成物、カラーフィルター、液晶表示装置及び有機el表示装置。 |
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JPWO2018123463A1 (ja) * | 2016-12-26 | 2019-04-18 | Dic株式会社 | 含フッ素活性エネルギー線硬化型樹脂、界面活性剤、活性エネルギー線硬化型樹脂組成物及び硬化塗膜 |
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KR102186446B1 (ko) * | 2016-12-26 | 2020-12-04 | 디아이씨 가부시끼가이샤 | 함불소 활성 에너지선 경화형 수지, 계면활성제, 활성 에너지선 경화형 수지 조성물 및 경화 도막 |
US11326069B2 (en) | 2016-12-26 | 2022-05-10 | Dic Corporation | Fluorine-containing active energy ray curable resin, surfactant, active energy ray curable resin composition, and cured film |
CN110691822A (zh) * | 2017-06-02 | 2020-01-14 | 三菱电机株式会社 | 涂料膜、涂料组合物及具有该涂料膜的物品 |
JPWO2020017251A1 (ja) * | 2018-07-19 | 2020-07-27 | Dic株式会社 | 活性エネルギー線硬化性組成物、その硬化膜及び反射防止フィルム |
JP7082146B2 (ja) | 2018-07-19 | 2022-06-07 | Dic株式会社 | 活性エネルギー線硬化性組成物、その硬化膜及び反射防止フィルム |
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KR20130018638A (ko) | 2013-02-25 |
CN102834421B (zh) | 2014-09-24 |
CN102834421A (zh) | 2012-12-19 |
EP2554554B1 (en) | 2015-04-29 |
TWI589612B (zh) | 2017-07-01 |
US20130012647A1 (en) | 2013-01-10 |
US8716361B2 (en) | 2014-05-06 |
JP4873107B2 (ja) | 2012-02-08 |
TW201141891A (en) | 2011-12-01 |
JPWO2011122391A1 (ja) | 2013-07-08 |
KR101732391B1 (ko) | 2017-05-04 |
EP2554554A1 (en) | 2013-02-06 |
EP2554554A4 (en) | 2014-07-09 |
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