WO2011108525A1 - 防食剤、端子付き被覆電線およびワイヤーハーネス - Google Patents
防食剤、端子付き被覆電線およびワイヤーハーネス Download PDFInfo
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- WO2011108525A1 WO2011108525A1 PCT/JP2011/054591 JP2011054591W WO2011108525A1 WO 2011108525 A1 WO2011108525 A1 WO 2011108525A1 JP 2011054591 W JP2011054591 W JP 2011054591W WO 2011108525 A1 WO2011108525 A1 WO 2011108525A1
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- electric wire
- terminal
- wire
- anticorrosive agent
- terminal fitting
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R4/00—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation
- H01R4/70—Insulation of connections
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R4/00—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation
- H01R4/10—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation effected solely by twisting, wrapping, bending, crimping, or other permanent deformation
- H01R4/18—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation effected solely by twisting, wrapping, bending, crimping, or other permanent deformation by crimping
- H01R4/183—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation effected solely by twisting, wrapping, bending, crimping, or other permanent deformation by crimping for cylindrical elongated bodies, e.g. cables having circular cross-section
- H01R4/184—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation effected solely by twisting, wrapping, bending, crimping, or other permanent deformation by crimping for cylindrical elongated bodies, e.g. cables having circular cross-section comprising a U-shaped wire-receiving portion
Definitions
- the present invention relates to an anticorrosive agent, a coated electric wire with a terminal, and a wire harness, and more specifically, an anticorrosive agent suitable for anticorrosion of an electrical connection portion between an electric wire conductor and a terminal fitting, and a coated electric wire with a terminal and a wire harness using the same. Is.
- a plurality of such covered electric wires with terminals are bundled to form a wire harness.
- wiring is usually performed in the form of a wire harness.
- Patent Document 1 discloses a technique for injecting grease into a connector in which a terminal fitting connected to a wire conductor is inserted and locked.
- the problem to be solved by the present invention is to provide an anticorrosive capable of exhibiting high anticorrosion performance. Moreover, it is providing the covered electric wire with a terminal using this, and a wire harness.
- the anticorrosive agent according to the present invention is mainly composed of an epoxy resin, and has a viscosity at 25 ° C. measured in accordance with JIS Z8803 in the range of 1000 to 30000 mPa ⁇ s.
- the anticorrosive is applied to the electrical connection portion between the electric wire conductor and the terminal fitting.
- the epoxy resin is preferably a one-part type.
- the gist of the covered electric wire with a terminal according to the present invention is that the electrical connection portion between the electric wire conductor and the terminal fitting is covered with a cured product of the anticorrosive.
- the electric wire conductor includes a strand made of aluminum or an aluminum alloy, and the terminal fitting is made of copper or a copper alloy.
- the gist of the wire harness according to the present invention includes the above-described covered electric wire with terminal.
- the anticorrosive agent according to the present invention contains an epoxy resin as a main component, and has a viscosity at 25 ° C. measured in accordance with JIS Z8803 in the range of 1000 to 30000 mPa ⁇ s. Therefore, it is excellent in applicability compared with grease and can exhibit high anticorrosion performance after curing. Moreover, since the epoxy resin is the main component, the heat resistance after curing is excellent as compared with the case where the thermoplastic resin is the main component.
- the corrosion resistance of the electrical connection portion can be enhanced. Therefore, connection reliability can be improved.
- the epoxy resin is a one-pack type
- a mixing process is not required as compared with a two-pack type, so an anticorrosive agent is applied to the electrical connection portion between the wire conductor and the terminal fitting. This can contribute to an improvement in productivity.
- the corrosion resistance of the electric connection portion is improved and the connection reliability is excellent. Covered electric wire.
- the wire conductor contains a strand made of aluminum or an aluminum alloy and the terminal fitting is made of copper or a copper alloy, since the dissimilar metal connection is made, the effect of the anticorrosive agent of the present invention can be obtained. Can fully demonstrate.
- the wire harness according to the present invention includes the above-mentioned coated electric wire with a terminal excellent in anticorrosion performance. Therefore, for example, it can be suitably routed in an engine room or a part of the indoor environment in a flooded area.
- FIG. 2 is a cross-sectional view taken along the line AA in FIG. It is a figure for demonstrating a corrosion test method.
- an anticorrosive agent according to an embodiment of the present invention (hereinafter sometimes referred to as “the anticorrosive agent”) and a covered electric wire with a terminal according to an embodiment of the present invention (hereinafter, referred to as “the present covered electric wire”). ),
- the present wire harness A wire harness according to an embodiment of the present invention (hereinafter, “the present wire harness”) will be described in detail.
- This anticorrosive has an epoxy resin as a main component.
- the epoxy resin may be either one-pack type or two-pack type.
- the mixing process is not required compared to the case of the 2 liquid type, so that the productivity is improved when the anticorrosive agent is applied to the electrical connection portion between the electric wire conductor and the terminal fitting. It is because it can contribute.
- the epoxy resin examples include a bisphenol A type epoxy resin using phenols as a raw material, a bisphenol F type epoxy resin, a bisphenol AD type epoxy resin, an aliphatic epoxy resin using alcohols as a raw material, and amines as a raw material.
- examples thereof include an epoxy resin and an cresol novolac epoxy resin made from o-cresol novolac resin.
- the anticorrosive agent may be composed of an epoxy resin alone, or two or more epoxy resins may be mixed. Furthermore, if necessary, additives, other polymers, and the like may be mixed as long as the physical properties are not impaired.
- the additive is not particularly limited as long as it is an additive generally used for resin molding materials.
- curing agents inorganic fillers, antioxidants, metal deactivators (copper damage inhibitors), UV absorbers, UV masking agents, flame retardant aids, processing aids (lubricants, waxes)
- UV absorbers UV masking agents
- flame retardant aids processing aids (lubricants, waxes)
- processing aids lubricants, waxes
- Carbon other coloring pigments, flexibility imparting materials, impact resistance imparting materials, organic fillers, diluents (solvents, etc.), thixotropic materials, various coupling materials, antifoaming materials, leveling materials, etc. Can be mentioned.
- This anticorrosive is an uncured product, and is cured for the purpose of increasing mechanical strength after application to the wire connection portion or the like.
- the curing method include moisture curing, heat curing, chemical curing, and the like, and are not particularly limited.
- this anticorrosive has a viscosity at 25 ° C. measured in accordance with JIS Z8803 in the range of 1000 to 30000 mPa ⁇ s.
- the viscometer used for the measurement is a rotational viscometer.
- the lower limit of the viscosity is preferably 1500 mPa ⁇ s or more.
- the upper limit of the viscosity is preferably 25000 mPa ⁇ s or less from the viewpoints of productivity, corrosion resistance, and the like.
- This anticorrosive agent can be suitably used for preventing corrosion of, for example, an electrical connection portion between a conductor of a covered wire and a terminal fitting that are routed in a vehicle such as an automobile.
- the present covered electric wire 10 includes a covered electric wire 12 in which an outer periphery of an electric wire conductor 18 is covered with an insulator 20 and a terminal fitting connected to an end of the electric wire conductor 18 of the covered electric wire 12. 14.
- the insulator 20 is peeled off at the end to expose the electric wire conductor 18, and the terminal fitting 14 is connected to the exposed end of the electric wire conductor 18.
- the electric wire conductor 18 is formed of a stranded wire formed by twisting a plurality of strands 18a.
- the stranded wire may be composed of one type of metal strand or may be composed of two or more types of metal strand.
- the twisted wire may contain the strand etc. which consist of organic fibers other than a metal strand.
- the stranded wire may include a reinforcing wire (tension member) that reinforces the covered electric wire.
- Examples of the material for the metal wire include copper, copper alloy, aluminum, aluminum alloy, and materials obtained by applying various platings to these materials.
- Examples of the material of the metal strand as the reinforcing wire include copper alloy, titanium, tungsten, and stainless steel.
- Examples of the organic fiber as the reinforcing wire include Kevlar.
- Examples of the material of the insulator 20 include rubber, polyolefin, PVC, and thermoplastic elastomer. These may be used alone or in combination of two or more.
- Various additives may be appropriately added to the material of the insulator 20. Examples of the additive include a flame retardant, a filler, a colorant and the like.
- the terminal fitting 14 includes a tab-like connection portion 14c connected to the counterpart terminal, a wire barrel 14a that extends from the proximal end of the connection portion 14c, and that crimps the end of the wire conductor 18 of the covered wire 12, and a wire An insulation barrel 14b that extends from the barrel 14a and crimps the insulator 20 at the end of the covered wire 12 is provided.
- Examples of the material (base material) of the terminal fitting 14 include various commonly used copper alloys, copper, and the like. A part (for example, a contact) or the entire surface of the terminal fitting 14 may be plated with various metals such as tin, nickel, and gold.
- the wire conductor 18 In the electrical connection portion between the wire conductor 18 and the terminal fitting 14 at the wire terminal, a part of the wire conductor 18 is exposed.
- the exposed portion of the coated electric wire 10 is covered with the anticorrosive agent.
- the anticorrosive coating film 16 covers the boundary between the proximal end of the connecting portion 14c of the terminal fitting 14 and the distal end of the electric wire conductor 18 to the proximal end of the connecting portion 14c, and
- the insulator 20 is covered up to the insulator 20 across the boundary between the modulation barrel 14b and the insulator 20.
- the anticorrosive to be used can be selected from the above physical property range in consideration of the combination of the material of the electric wire conductor 18 and the material of the terminal fitting 14.
- the thickness of the anticorrosive coating film 16 may be appropriately adjusted, but is preferably in the range of 0.01 mm to 0.1 mm. If the coating film 16 is too thick, it is difficult to insert the terminal fitting 14 into the connector. Moreover, when the thickness of the coating film 16 is too thin, an anticorrosion effect will fall easily.
- the anticorrosive is formed by crimping the terminal fitting 14 at the wire end to connect the wire conductor 18 and the terminal fitting 14, and then the surface of the connection portion between the wire conductor 18 and the terminal fitting 14, that is, the surface of the insulator 20 at the end. And the surface of the insulation barrel 14b, the surface of the wire barrel 14a, the exposed surface of the wire conductor 18, and the base end surface of the connecting portion 14c. Thereby, the coating film 16 is formed on the surface of the connection portion between the wire conductor 18 and the terminal fitting 14.
- the coating film 16 is also applied to the back side of the tab-like connecting portion 14c protruding from the wire barrel 14a of the terminal fitting 14, and the back side of the wire barrel 14a and the insulation barrel 14b. It may be formed.
- the anticorrosive coating film 16 is cured for the purpose of increasing the mechanical strength after application to the wire connection portion.
- the curing method include moisture curing, heat curing, chemical curing, and the like, and are not particularly limited.
- the anticorrosive is solidified after curing, it can be fixed in a place where it has been applied over a long period of time, as well as having no risk of stickiness during handling. Therefore, the anticorrosion effect can be maintained over a long period of time.
- the present wire harness is formed by bundling a plurality of covered electric wires with terminals including the main covered electric wire 10.
- a part of the covered electric wire included in the harness may be the main covered electric wire 10, or all may be the main covered electric wire 10.
- the plurality of covered electric wires may be bundled by tape winding, or may be covered by an external part such as a round tube, a corrugated tube, or a protector.
- This wire harness is suitable for being routed in a vehicle such as an automobile, and is particularly suitable for being routed in an engine room or a vehicle in a wet area.
- a wire harness is wired in such a place, it will become easy to generate
- FIG. According to this wire harness, generation
- the polyvinyl chloride composition obtained above was 0.28 mm thick around a conductor (cross-sectional area 0.75 mm) made of an aluminum alloy twisted wire in which seven aluminum alloy wires were twisted together. And extrusion coated. This produced the covered electric wire (PVC electric wire).
- Example 1 1-pack epoxy resin (A) [manufactured by ThreeBond Co., Ltd., “2212C”, viscosity at 25 ° C. 25000 mPa ⁇ s, curing condition 80 ° C. ⁇ 30 minutes] (Example 2)
- 1-pack epoxy resin (B) [manufactured by ThreeBond Co., Ltd., “2212”, viscosity at 25 ° C. 13000 mPa ⁇ s, curing condition 90 ° C. ⁇ 30 minutes]
- Example 3 1-pack epoxy resin (C) [manufactured by ThreeBond Co., Ltd., “2210”, viscosity at 25 ° C.
- Example 4 1-pack epoxy resin (D) [Ajinomoto Fine Techno Co., Ltd., “Plain Set AE-400”, viscosity at 25 ° C. 10000 mPa ⁇ s, curing conditions 80 ° C. ⁇ 30 minutes] (Example 5)
- 1-pack epoxy resin (E) [Ajinomoto Fine Techno Co., Ltd., “Plain Set AE-15”, viscosity 2000 mPa ⁇ s at 25 ° C., curing condition 80 ° C.
- Example 6 Two-component epoxy resin (F) [Taoka Chemical Industries, Ltd., “Technodyne AH6021W”, viscosity 15000 mPa ⁇ s at 25 ° C., curing condition 80 ° C. ⁇ 60 minutes] (Comparative Example 1) 1-pack epoxy resin (a) [manufactured by ThreeBond Co., Ltd., “2212E”, viscosity at 25 ° C. 35000 mPa ⁇ s, curing condition 90 ° C.
- each of the prepared covered electric wires with terminals 1 is connected to the + electrode of the 12V power supply 2, and the pure copper plate 3 (width 1 cm ⁇ length 2 cm ⁇ thickness 1 mm) is connected to the ⁇ electrode of the 12V power supply 2,
- the electric connection part of the electric wire conductor and terminal metal fitting of the covered electric wire 1 with a terminal, and the pure copper plate 3 were immersed in 300cc NaCl5% aqueous solution 4, and it supplied with electricity at 12V for 2 minutes.
- ICP emission analysis of NaCl 5% aqueous solution 4 was performed, and the amount of aluminum ions eluted from the wire conductor of the covered wire 1 with terminals was measured.
- the case where the elution amount was less than 0.1 ppm was designated as “ ⁇ ”
- the case where the elution amount was 0.1 ppm or more was designated as “x”.
- Table 1 summarizes the viscosity and evaluation results at 25 ° C. measured in accordance with JIS Z8803 of the anticorrosives according to Examples and Comparative Examples.
- the viscosity of the anticorrosive according to the comparative example is outside the scope of the present invention. Therefore, it is inferior to anticorrosion performance. This is presumed that although the anticorrosive agent was in close contact without being peeled off from the electrical connection portion, the resin did not sufficiently penetrate into the wire connection portion, so that sufficient anticorrosion performance could not be exhibited.
- the anticorrosive agent according to the present invention has a viscosity within the range defined by the present invention. Therefore, it is sufficiently adhered to the electrical connection portion and can exhibit excellent anticorrosion performance. This is presumably because the viscosity of the anticorrosive was within a specific range, so that the resin penetrated sufficiently into the wire connection part.
- a male terminal having a tab-shaped connecting portion 14c is shown as the terminal fitting 14, but the present invention is not limited to this.
- it may be a female terminal that can be fitted with a male terminal, or a tuning fork terminal.
- the terminal metal fitting 14 may be crimped only by the wire barrel 14a without having the insulation barrel 14b.
- the connection method between the electric wire conductor 12 and the terminal fitting 14 is not limited to crimping by a barrel, and may be a method such as pressure resistance welding, ultrasonic welding, or soldering.
- the conductor 18 which consists of a twisted wire is shown, the conductor 18 may be a single core wire.
Abstract
Description
本防食剤は、エポキシ樹脂を主成分とする。上記エポキシ樹脂は、1液形、2液形のいずれであっても良い。1液形である場合には2液形である場合に比較して混合工程が不要になるので、電線導体と端子金具との電気接続部等に防食剤を適用する場合における生産性の向上に寄与することができるからである。
次に、本被覆電線について説明する。
本ワイヤーハーネスは、上記本被覆電線10を含む複数本の端子付き被覆電線を束ねたものからなる。本ワイヤーハーネスにおいては、ハーネス中に含まれる被覆電線のうちの一部が本被覆電線10であっても良いし、全てが本被覆電線10であっても良い。
ポリ塩化ビニル(重合度1300)100質量部に対して、可塑剤としてジイソノニルフタレート40質量部、充填剤として重炭酸カルシウム20質量部、安定剤としてカルシウム亜鉛系安定剤5質量部をオープンロールにより180℃で混合し、ペレタイザーにてペレット状に成形することにより、ポリ塩化ビニル組成物を調製した。
上記作製した被覆電線の端末を皮剥して電線導体を露出させた後、自動車用として汎用されている黄銅製のオス形状の圧着端子金具(タブ幅0.64mm)を被覆電線の端末に加締め圧着した。
1液エポキシ樹脂(A)[スリーボンド(株)製、「2212C」、25℃における粘度25000mPa・s、硬化条件80℃×30分]
(実施例2)
1液エポキシ樹脂(B)[スリーボンド(株)製、「2212」、25℃における粘度13000mPa・s、硬化条件90℃×30分]
(実施例3)
1液エポキシ樹脂(C)[スリーボンド(株)製、「2210」、25℃における粘度8000mPa・s、硬化条件90℃×30分]
(実施例4)
1液エポキシ樹脂(D)[味の素ファインテクノ(株)製、「プレーンセットAE-400」、25℃における粘度10000mPa・s、硬化条件80℃×30分]
(実施例5)
1液エポキシ樹脂(E)[味の素ファインテクノ(株)製、「プレーンセットAE-15」、25℃における粘度2000mPa・s、硬化条件80℃×30分]
(実施例6)
2液エポキシ樹脂(F)[田岡化学工業(株)製、「テクノダインAH6021W」、25℃における粘度15000mPa・s、硬化条件80℃×60分]
(比較例1)
1液エポキシ樹脂(a)[スリーボンド(株)製、「2212E」、25℃における粘度35000mPa・s、硬化条件90℃×30分]
(比較例2)
1液エポキシ樹脂(b)[味の素ファインテクノ(株)製、「プレーンセットAE-901B」、25℃における粘度60000mPa・s、硬化条件60℃×30分]
(比較例3)
2液エポキシ樹脂(c)[田岡化学工業(株)製、「テクノダインAH3051K」、25℃における粘度35000mPa・s、硬化条件100℃×30分]
各種の防食剤を塗布した端子付き被覆電線を用い、防食剤の剥がれ、防食性能の評価を以下のようにして行った。
各防食剤を塗布、硬化後、爪で引っ掻き、防食剤が剥がれなかったものを「○」とし、剥がれたものを「×」とした。なお、剥がれがある場合には、明らかに防食性能に劣る。そのため、以下の防食性能評価の前に試験を行ったものである。
図3に示すように、作製した各端子付き被覆電線1を12V電源2の+極につなぐとともに、純銅板3(幅1cm×長さ2cm×厚み1mm)を12V電源2の-極につなぎ、端子付き被覆電線1の電線導体と端子金具との電気接続部および純銅板3を300ccのNaCl5%水溶液4に浸漬し、12Vで2分間通電した。通電後、NaCl5%水溶液4のICP発光分析を行ない、端子付き被覆電線1の電線導体からのアルミニウムイオンの溶出量を測定した。溶出量が0.1ppm未満であった場合を「○」とし、溶出量が0.1ppm以上であった場合を「×」とした。
Claims (6)
- エポキシ樹脂を主成分とし、
JIS Z8803に準拠して測定される25℃での粘度が1000~30000mPa・sの範囲内にあることを特徴とする防食剤。 - 電線導体と端子金具との電気接続部に適用されることを特徴とする請求項1に記載の防食剤。
- 前記エポキシ樹脂は、1液形であることを特徴とする請求項1または2に記載の防食剤。
- 請求項1から3のいずれか1項に記載の防食剤の硬化物により、電線導体と端子金具との電気接続部が覆われていることを特徴とする端子付き被覆電線。
- 前記電線導体は、アルミニウムまたはアルミニウム合金よりなる素線を含有してなり、前記端子金具は、銅または銅合金よりなることを特徴とする請求項4に記載の端子付き被覆電線。
- 請求項4または5に記載の端子付き被覆電線を含むことを特徴とするワイヤーハーネス。
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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CN2011800123415A CN103097585A (zh) | 2010-03-04 | 2011-03-01 | 防腐蚀剂、具有端子的包覆电线和线束 |
DE112011100782T DE112011100782T5 (de) | 2010-03-04 | 2011-03-01 | Korrosionsschutzmittel, beschichtete elektrische Leitung mit Anschluss und Kabelstrang |
US13/581,132 US20130032394A1 (en) | 2010-03-04 | 2011-03-01 | Anticorrosive, coated electric wire with terminal, and wiring harness |
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JP2010-047353 | 2010-03-04 | ||
JP2010047353A JP2011179101A (ja) | 2010-03-04 | 2010-03-04 | 防食剤、端子付き被覆電線およびワイヤーハーネス |
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TWI540590B (zh) * | 2011-05-31 | 2016-07-01 | 住友電木股份有限公司 | 半導體裝置 |
JP2014110151A (ja) * | 2012-12-03 | 2014-06-12 | Auto Network Gijutsu Kenkyusho:Kk | 端子付き被覆電線、ワイヤーハーネス、および防食剤 |
WO2014132685A1 (ja) * | 2013-02-27 | 2014-09-04 | 株式会社オートネットワーク技術研究所 | 端子付き被覆電線および端子付き被覆電線の製造方法 |
JP6056584B2 (ja) | 2013-03-22 | 2017-01-11 | 株式会社オートネットワーク技術研究所 | 端子付き被覆電線、ワイヤーハーネス、及び防食剤 |
DE102013205235A1 (de) * | 2013-03-25 | 2014-09-25 | Tyco Electronics Amp Gmbh | Crimpverbindung |
JP6107620B2 (ja) * | 2013-11-29 | 2017-04-05 | 株式会社オートネットワーク技術研究所 | 端子付き被覆電線及びワイヤーハーネス |
JP6964981B2 (ja) * | 2014-03-07 | 2021-11-10 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェンHenkel AG & Co. KGaA | 光硬化性エポキシ樹脂系 |
JP6354608B2 (ja) * | 2015-01-29 | 2018-07-11 | 株式会社オートネットワーク技術研究所 | 端子付き被覆電線 |
JP6200448B2 (ja) * | 2015-04-20 | 2017-09-20 | 矢崎総業株式会社 | 防食材、端子付き電線及びワイヤーハーネス |
JP6263500B2 (ja) * | 2015-06-12 | 2018-01-17 | 矢崎総業株式会社 | 電線付き端子及びワイヤハーネス |
CN106010089A (zh) * | 2016-05-24 | 2016-10-12 | 怀远县金浩电子科技有限公司 | 一种电动车电池导线防腐涂层及其制备方法 |
CN106099621A (zh) * | 2016-05-30 | 2016-11-09 | 铜陵东晟生态农业科技有限公司 | 端子和线束的连接前处理方法 |
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- 2010-03-04 JP JP2010047353A patent/JP2011179101A/ja active Pending
-
2011
- 2011-03-01 US US13/581,132 patent/US20130032394A1/en not_active Abandoned
- 2011-03-01 DE DE112011100782T patent/DE112011100782T5/de not_active Ceased
- 2011-03-01 CN CN2011800123415A patent/CN103097585A/zh active Pending
- 2011-03-01 WO PCT/JP2011/054591 patent/WO2011108525A1/ja active Application Filing
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JP2001131467A (ja) * | 1999-08-23 | 2001-05-15 | Kansai Paint Co Ltd | エポキシ樹脂塗料組成物 |
JP2007317470A (ja) * | 2006-05-25 | 2007-12-06 | Auto Network Gijutsu Kenkyusho:Kk | 芯線接続部の封止方法 |
JP2009230998A (ja) * | 2008-03-21 | 2009-10-08 | Autonetworks Technologies Ltd | 端子金具付き電線の製造方法及び端子金具付き電線 |
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DE112011100782T5 (de) | 2012-12-20 |
CN103097585A (zh) | 2013-05-08 |
US20130032394A1 (en) | 2013-02-07 |
JP2011179101A (ja) | 2011-09-15 |
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