WO2011082991A3 - Katalysator und verfahren zur hydrierung von aromaten - Google Patents

Katalysator und verfahren zur hydrierung von aromaten Download PDF

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Publication number
WO2011082991A3
WO2011082991A3 PCT/EP2010/069637 EP2010069637W WO2011082991A3 WO 2011082991 A3 WO2011082991 A3 WO 2011082991A3 EP 2010069637 W EP2010069637 W EP 2010069637W WO 2011082991 A3 WO2011082991 A3 WO 2011082991A3
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WO
WIPO (PCT)
Prior art keywords
hydrogenating
shell catalyst
catalyst
aromates
organic compound
Prior art date
Application number
PCT/EP2010/069637
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English (en)
French (fr)
Other versions
WO2011082991A2 (de
Inventor
Lucia KÖNIGSMANN
Daniela Mirk
Thomas Heidemann
Michael Hesse
Martin Bock
Mario Emmeluth
Jutta Bickelhaupt
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Priority to CN201080063583.2A priority Critical patent/CN102753266B/zh
Priority to EP10792900A priority patent/EP2512658A2/de
Priority to KR1020127018329A priority patent/KR101833077B1/ko
Priority to US13/516,124 priority patent/US9084983B2/en
Priority to JP2012543686A priority patent/JP5745538B2/ja
Publication of WO2011082991A2 publication Critical patent/WO2011082991A2/de
Publication of WO2011082991A3 publication Critical patent/WO2011082991A3/de

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B01J35/31—
    • B01J35/392—
    • B01J35/397—
    • B01J35/615—
    • B01J35/635—
    • B01J35/647—
    • B01J35/66—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C07C209/70—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines
    • C07C209/72—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines by reduction of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/19—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds in six-membered aromatic rings
    • C07C29/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds in six-membered aromatic rings in a non-condensed rings substituted with hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/303—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Abstract

Die vorliegenden Erfindung betrifft einen Schalenkatalysator, enthaltend ein Aktivmetall ausgewählt aus der Gruppe bestehend aus Ruthenium, Rhodium, Palladium, Platin und Mischungen davon, aufgebracht auf ein Trägermaterial enthaltend Siliziumdioxid, wobei das Porenvolumen des Trägermaterials 0,6 bis 1,0 ml/g, bestimmt durch Hg- Porosimetrie, beträgt, die BET-Oberfläche 280 bis 500 m2/g beträgt, und mindestens 90% der vorhandenen Poren einen Durchmesser von 6 bis 12 nm aufweisen, ein Verfahren zur Herstellung dieses Schalenkatalysators, ein Verfahren zur Hydrierung einer organischen Verbindung, die mindestens eine hydrierbare Gruppe enthält unter Verwendung des Schalenkatalysators, sowie die Verwendung des Schalenkatalysators zur Hydrierung einer organischen Verbindung.
PCT/EP2010/069637 2009-12-15 2010-12-14 Katalysator und verfahren zur hydrierung von aromaten WO2011082991A2 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN201080063583.2A CN102753266B (zh) 2009-12-15 2010-12-14 用于氢化芳族化合物的催化剂和方法
EP10792900A EP2512658A2 (de) 2009-12-15 2010-12-14 Katalysator und verfahren zur hydrierung von aromaten
KR1020127018329A KR101833077B1 (ko) 2009-12-15 2010-12-14 방향족 화합물의 수소화를 위한 촉매 및 방법
US13/516,124 US9084983B2 (en) 2009-12-15 2010-12-14 Catalyst and process for hydrogenating aromatics
JP2012543686A JP5745538B2 (ja) 2009-12-15 2010-12-14 芳香族化合物水素化用触媒とその方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09179201 2009-12-15
EP09179201.0 2009-12-15

Publications (2)

Publication Number Publication Date
WO2011082991A2 WO2011082991A2 (de) 2011-07-14
WO2011082991A3 true WO2011082991A3 (de) 2012-05-03

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2010/069637 WO2011082991A2 (de) 2009-12-15 2010-12-14 Katalysator und verfahren zur hydrierung von aromaten

Country Status (6)

Country Link
US (1) US9084983B2 (de)
EP (1) EP2512658A2 (de)
JP (1) JP5745538B2 (de)
KR (1) KR101833077B1 (de)
CN (1) CN102753266B (de)
WO (1) WO2011082991A2 (de)

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