PL2049253T3 - Zintegrowany sposób obejmujący uwodornianie za pomocą katalizatorów rutenowych i ich regenerację - Google Patents
Zintegrowany sposób obejmujący uwodornianie za pomocą katalizatorów rutenowych i ich regeneracjęInfo
- Publication number
- PL2049253T3 PL2049253T3 PL07787686T PL07787686T PL2049253T3 PL 2049253 T3 PL2049253 T3 PL 2049253T3 PL 07787686 T PL07787686 T PL 07787686T PL 07787686 T PL07787686 T PL 07787686T PL 2049253 T3 PL2049253 T3 PL 2049253T3
- Authority
- PL
- Poland
- Prior art keywords
- regneration
- dehydration
- integrated process
- ruthenium catalysts
- ruthenium
- Prior art date
Links
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 230000018044 dehydration Effects 0.000 title 1
- 238000006297 dehydration reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 229910052707 ruthenium Inorganic materials 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/462—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/303—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/392—Metal surface area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/396—Distribution of the active metal ingredient
- B01J35/397—Egg shell like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/51—Spheres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/46—Ruthenium, rhodium, osmium or iridium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/8995—Catalyst and recycle considerations
- Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06118206 | 2006-07-31 | ||
PCT/EP2007/057428 WO2008015103A2 (de) | 2006-07-31 | 2007-07-18 | Verfahren zur regenerierung von für die hydrierung geeigneten rutheniumkatalysatoren |
EP07787686.0A EP2049253B1 (de) | 2006-07-31 | 2007-07-18 | integriertes VERFAHREN bestehend aus Hydrierung mit RUTHENIUMKATALYSATOREN und REGENERIERUNG derselben |
Publications (1)
Publication Number | Publication Date |
---|---|
PL2049253T3 true PL2049253T3 (pl) | 2020-03-31 |
Family
ID=38596286
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PL07787686T PL2049253T3 (pl) | 2006-07-31 | 2007-07-18 | Zintegrowany sposób obejmujący uwodornianie za pomocą katalizatorów rutenowych i ich regenerację |
Country Status (7)
Country | Link |
---|---|
US (1) | US8895791B2 (pl) |
EP (1) | EP2049253B1 (pl) |
KR (1) | KR101414317B1 (pl) |
CN (1) | CN101522300B (pl) |
ES (1) | ES2759627T3 (pl) |
PL (1) | PL2049253T3 (pl) |
WO (1) | WO2008015103A2 (pl) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8895791B2 (en) | 2006-07-31 | 2014-11-25 | Basf Se | Method of regenerating ruthenium catalysts suitable for hydrogenation |
CN101722058B (zh) * | 2008-10-22 | 2012-08-08 | 中国石油天然气股份有限公司 | 一种烯烃歧化铼基负载催化剂的再生方法 |
KR102079160B1 (ko) | 2009-12-10 | 2020-02-19 | 더 리젠츠 오브 더 유니버시티 오브 캘리포니아 | 아밀로이드 결합제 |
US20110144398A1 (en) * | 2009-12-11 | 2011-06-16 | Basf Se | Process for regenerating a ruthenium-containing supported hydrogenation catalyst |
EP2512658A2 (de) | 2009-12-15 | 2012-10-24 | Basf Se | Katalysator und verfahren zur hydrierung von aromaten |
US9180437B2 (en) * | 2012-05-10 | 2015-11-10 | Korea Institute Of Science And Technology | Method of preparing magnesium oxide structure with meso-macro pores |
CN103816923B (zh) * | 2012-11-16 | 2016-01-20 | 万华化学集团股份有限公司 | 一种钌加氢催化剂再生的方法 |
KR101905165B1 (ko) | 2015-04-01 | 2018-10-05 | 한화케미칼 주식회사 | 프탈레이트 화합물의 수소화 촉매의 재생 방법 |
CN107282045B (zh) * | 2016-04-12 | 2020-05-05 | 中国石油化工股份有限公司 | 用于制备1,4-环己烷二甲醇的催化剂 |
US10995057B2 (en) * | 2016-09-08 | 2021-05-04 | Basf Se | Method for hydrogenating nitriles in the presence of a ruthenium catalyst carried on ZrO2 |
CN112169847A (zh) * | 2020-09-25 | 2021-01-05 | 南京大学 | 一种钌基催化剂活化再生方法及其应用 |
EP4015079A1 (de) * | 2020-12-18 | 2022-06-22 | Evonik Operations GmbH | Verfahren zur regenerierung von hydrierkatalysatoren |
US11918989B2 (en) * | 2020-12-18 | 2024-03-05 | Evonik Operations Gmbh | Process for regeneration of hydrogenation catalysts |
CN114602463B (zh) * | 2022-04-13 | 2023-12-05 | 宏业生物科技股份有限公司 | 一种对羟基苯甲酸乙酯加氢催化剂及其制备方法 |
Family Cites Families (35)
Publication number | Priority date | Publication date | Assignee | Title |
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US2757128A (en) | 1951-04-27 | 1956-07-31 | Exxon Research Engineering Co | Low pressure hydrogenation and hydrogen regeneration of the catalyst |
GB799396A (en) | 1954-05-07 | 1958-08-06 | Engelhard Ind Inc | Improvements in or relating to methods of hydrogenation |
US2898387A (en) | 1955-07-29 | 1959-08-04 | Sinclair Refining Co | Process for the hydrogenation of hydrocarbons |
FR1504433A (fr) * | 1965-11-17 | 1967-12-08 | Inst Francais Du Petrole | Procédé perfectionné de réactivation applicable aux catalyseurs d'hydrogénation |
FR1592093A (pl) | 1968-02-29 | 1970-05-11 | ||
GB1361811A (en) | 1970-11-06 | 1974-07-30 | Texaco Development Corp | Catalysts and the use thereof |
US3851004A (en) | 1973-09-27 | 1974-11-26 | Union Carbide Corp | Hydrocarbon alkylation process using catalyst regeneration |
US4322315A (en) * | 1980-04-25 | 1982-03-30 | Phillips Petroleum Company | Regeneration of a ruthenium containing hydrogenation catalyst |
US4331557A (en) | 1980-05-22 | 1982-05-25 | Phillips Petroleum Company | Regeneration of ruthenium-containing catalyst |
JP2634828B2 (ja) | 1987-12-16 | 1997-07-30 | 旭化成工業株式会社 | 芳香族化合物の部分核水素化方法 |
JP2886563B2 (ja) | 1989-08-07 | 1999-04-26 | 旭化成工業株式会社 | ルテニウム触媒の活性回復方法 |
GB9117948D0 (en) | 1991-08-20 | 1991-10-09 | Shell Int Research | Process for the activation of a catalyst |
JPH07178341A (ja) | 1993-12-24 | 1995-07-18 | Mitsubishi Chem Corp | ルテニウム触媒の再生方法 |
DE4428018A1 (de) * | 1994-08-08 | 1996-02-15 | Bayer Ag | Verfahren zur Herstellung von aromatischen Aminen |
US5817589A (en) * | 1996-04-02 | 1998-10-06 | Intevep, S.A. | Regeneration of catalyst comprising flushing with inert gas followed by flushing with hydrogen |
DE69632873T2 (de) * | 1995-11-01 | 2005-07-14 | Asahi Kasei Kabushiki Kaisha | Methode zur reaktivierung eines rutheniumkatalysators |
DE19624485A1 (de) | 1996-06-19 | 1998-01-02 | Basf Ag | Verfahren zur Hydrierung einer aromatischen Verbindung in Gegenwart eines geträgerten Rutheniumkatalysators |
US6248924B1 (en) | 1996-06-19 | 2001-06-19 | Basf Aktiengesellschaft | Process for reacting an organic compound in the presence of a supported ruthenium catalyst |
DE19756913A1 (de) | 1997-12-19 | 1999-06-24 | Basf Ag | Verfahren zur Hydrierung von Benzendicarbonsäureestern unter Verwendung eines Makroporen aufweisenden Katalysators |
JP3726504B2 (ja) | 1998-08-11 | 2005-12-14 | 三菱化学株式会社 | 触媒の再生方法及び再生触媒を用いる水素化方法 |
DE19917051A1 (de) | 1999-04-15 | 2000-10-19 | Basf Ag | Verfahren zur Hydrierung von unsubstituierten oder alkylsubstituierten Aromaten unter Verwendung eines Makroporen aufweisenden Katalysators |
DE19927978A1 (de) | 1999-06-18 | 2000-12-21 | Basf Ag | Ausgewählte Cyclohexan-1,3- und 1,4-dicarbonsäureester |
US6869978B2 (en) | 1999-11-17 | 2005-03-22 | Conocophillips Company | Pressure swing catalyst regeneration procedure for Fischer-Tropsch catalyst |
DE10060099A1 (de) * | 2000-12-04 | 2002-06-06 | Basf Ag | Regenerierung eines Dehydrierkatalysators |
DE10128242A1 (de) | 2001-06-11 | 2002-12-12 | Basf Ag | Verfahren zur Hydrierung organischer Verbindungen |
DE10128205A1 (de) | 2001-06-11 | 2002-12-12 | Basf Ag | Ruthenium-Katalysatoren |
DE10135490A1 (de) | 2001-07-20 | 2003-01-30 | Basf Ag | Verfahren zur Hydrierung von aromatischen Verbindungen mit Restgas enthaltendem Wasserstoff |
US6521791B1 (en) | 2001-11-09 | 2003-02-18 | Air Products And Chemicals, Inc. | Process for regenerating a monolith hydrogenation catalytic reactor |
DE10216745A1 (de) | 2002-04-16 | 2003-10-30 | Bayer Ag | Ruthenium-Katalysatoren für die Hydrierung von aromatischen Kohlenwasserstoffen |
DE10249368A1 (de) | 2002-10-23 | 2004-05-06 | Basf Ag | Verfahren zur Regenerierung eines Hydrierkatalysators |
DE10361157A1 (de) | 2003-12-22 | 2005-07-21 | Basf Ag | Ruthenium-Heterogenkatalysator und Verfahren zur Herstellung eines Bisglycidylethers der Formel I |
EP1699557A1 (de) * | 2003-12-22 | 2006-09-13 | Basf Aktiengesellschaft | Ruthenium-heterogenkatalysator, verfahren zur hydrierung einer carbocyclischen aromatischen gruppe und kernhydrierte bisglycidylether der bisphenole a und f |
DE102005029200A1 (de) | 2005-06-22 | 2006-12-28 | Basf Ag | Katalysator und Verfahren zur Hydrierung von hydrierbare Gruppen enthaltenden organischen Verbindungen |
DE602006004279D1 (de) * | 2005-09-09 | 2009-01-29 | Mitsubishi Gas Chemical Co | Verfahren zur Herstellung von Aminoverbindungen mit einem aromatischen Ring unter Verwendung eines Schalenkatalysators |
US8895791B2 (en) | 2006-07-31 | 2014-11-25 | Basf Se | Method of regenerating ruthenium catalysts suitable for hydrogenation |
-
2007
- 2007-07-18 US US12/375,566 patent/US8895791B2/en active Active
- 2007-07-18 KR KR1020097001994A patent/KR101414317B1/ko active IP Right Grant
- 2007-07-18 ES ES07787686T patent/ES2759627T3/es active Active
- 2007-07-18 CN CN2007800363022A patent/CN101522300B/zh active Active
- 2007-07-18 WO PCT/EP2007/057428 patent/WO2008015103A2/de active Application Filing
- 2007-07-18 EP EP07787686.0A patent/EP2049253B1/de not_active Revoked
- 2007-07-18 PL PL07787686T patent/PL2049253T3/pl unknown
Also Published As
Publication number | Publication date |
---|---|
KR101414317B1 (ko) | 2014-07-02 |
EP2049253B1 (de) | 2019-09-11 |
WO2008015103A3 (de) | 2008-04-10 |
KR20090037903A (ko) | 2009-04-16 |
US20090281348A1 (en) | 2009-11-12 |
EP2049253A2 (de) | 2009-04-22 |
CN101522300A (zh) | 2009-09-02 |
ES2759627T3 (es) | 2020-05-11 |
WO2008015103A2 (de) | 2008-02-07 |
US8895791B2 (en) | 2014-11-25 |
CN101522300B (zh) | 2012-10-10 |
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