WO2011071060A1 - Article enduit de résine produit par formation de film humide, et procédé de production correspondant - Google Patents

Article enduit de résine produit par formation de film humide, et procédé de production correspondant Download PDF

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Publication number
WO2011071060A1
WO2011071060A1 PCT/JP2010/071967 JP2010071967W WO2011071060A1 WO 2011071060 A1 WO2011071060 A1 WO 2011071060A1 JP 2010071967 W JP2010071967 W JP 2010071967W WO 2011071060 A1 WO2011071060 A1 WO 2011071060A1
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WO
WIPO (PCT)
Prior art keywords
resin
film formation
wet film
wet
glove
Prior art date
Application number
PCT/JP2010/071967
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English (en)
Japanese (ja)
Inventor
古賀信義
堀川翔平
Original Assignee
株式会社東和コーポレーション
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社東和コーポレーション filed Critical 株式会社東和コーポレーション
Publication of WO2011071060A1 publication Critical patent/WO2011071060A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/02—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a matt or rough surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/40—Distributing applied liquids or other fluent materials by members moving relatively to surface
    • B05D1/42—Distributing applied liquids or other fluent materials by members moving relatively to surface by non-rotary members
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
    • B29C41/14—Dipping a core
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • D06N3/0093—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin by applying resin powders; by sintering
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00—Gloves
    • A41D19/015—Protective gloves
    • A41D19/01547—Protective gloves with grip improving means
    • A41D19/01558—Protective gloves with grip improving means using a layer of grip improving material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B29C2059/028—Incorporating particles by impact in the surface, e.g. using fluid jets or explosive forces to implant particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/48—Wearing apparel
    • B29L2031/4842—Outerwear
    • B29L2031/4864—Gloves
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/10—Particulate form, e.g. powder, granule
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2207/00—Treatments by energy or chemical effects
    • D06N2207/06—Treatments by energy or chemical effects using liquids, e.g. water
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/10—Properties of the materials having mechanical properties
    • D06N2209/106—Roughness, anti-slip, abrasiveness
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/10—Clothing
    • D06N2211/103—Gloves

Definitions

  • the present invention relates to a resin film product by wet film formation having a resin having a non-slip portion on the surface and a method for producing the same.
  • the surface area is increased by forming the second concave portion due to the bubbles on the inner surface of the first concave portion due to the granular material, and the anti-slip effect can be exhibited.
  • the current situation is only for natural and synthetic resin emulsions.
  • the present invention has been made in order to solve the above problems, and by removing the solid powder at the same time as solidifying the surface, a resin film product having an excellent anti-slip property even in a resin for wet film formation, and a method for producing the same The purpose is to provide.
  • the surface of the fiber dough is coated with a resin to be wet-formed, and a powdered solid is adhered, and then the resin is wet-filmed and simultaneously removed to remove the powdered solid.
  • a resin film product by wet film formation is characterized in that a plurality of cavities having a shape smaller than the uneven surface is formed inside a resin to be wet-formed and formed with a plurality of uneven surfaces.
  • the invention according to claim 2 is the resin film product by wet film formation according to claim 1, wherein the resin for wet film formation is a urethane resin.
  • the invention according to claim 3 is the resin film product by wet film formation according to claim 1 or 2, wherein the powdered solid is a water-soluble powder.
  • the invention described in claim 4 is characterized in that the wet film-forming resin is formed on the front surface and / or the back surface of the fiber fabric. It is a resin film product by film formation.
  • the invention described in claim 5 includes a step of coating a fiber fabric with a resin to be wet-formed, a step of attaching a powdered solid to the resin, and removing the powdered solid at the same time that the resin is wet-formed.
  • the invention according to claim 6 is the method for producing a resin film product by wet film formation according to claim 5, wherein the resin for wet film formation is a urethane resin.
  • the invention described in claim 7 is the method for producing a resin film product by wet film formation according to claim 5 or 6, wherein the powdered solid is a water-soluble powder.
  • the invention according to claim 8 is characterized in that the resin for wet film formation is formed on the surface and / or the back surface of the fiber fabric. This is a method for producing a resin film product by film formation.
  • the present invention has the following effects. That is, (1) In the inventions according to claims 1 and 5, the surface area is increased due to the uneven surface of the powdery solid on the surface and the resin part wet-formed, and an excellent anti-slip effect can be exhibited. In addition, the wet-deposited resin part has a sponge-like structure that exhibits excellent flexibility, excellent breathability, excellent heat insulation and heat retention, excellent sound and vibration resistance, and excellent soft touch. can do.
  • the resin for wet film formation is a urethane resin, it can be designed to have flexibility depending on the molecular weight and the type of raw material.
  • the resin for wet film formation is formed on the surface and / or the back surface of the fiber fabric, the resin is formed on the surface of the glove, for example. It can function as an anti-slip against the object to be grasped, and by forming a resin film on the back surface, it is possible to prevent the hand and the glove from slipping when grasping with a strong force through the glove. .
  • the resin film product by wet film formation in the present embodiment is coated with a resin to be wet film-formed on a fiber fabric, attached with a powdered solid, and then removed by removing the powdered solid simultaneously with the wet film formation. It is characterized in that an uneven surface is formed on the surface.
  • the resin for wet film formation may be any resin that can be used by dissolving in a water-soluble solvent, and includes known resins such as urethane resin, nylon resin, vinyl chloride resin, and acrylic resin, and preferably has a molecular weight of 5 ⁇ 130,000 urethane resin is good. Moreover, what mixed these may be used.
  • water-soluble solvent examples include DMAA (dimethylacetamide), MEK (methyl ethyl ketone), etc., preferably DMF (dimethylformamide).
  • a powdery solid is attached to an unsolidified resin and the powdered solid is immediately removed.
  • the powdered solid is particularly preferably water-soluble, for example, metal salts such as sodium chloride, sodium bicarbonate, sodium carbonate, calcium nitrate, sodium phosphate, calcium carbonate, sugars such as granulated sugar, Examples thereof include organic acids such as citric acid and ascorbic acid.
  • the inner diameter of the concave portion can be controlled by the particle size of the powdered solid used.
  • the powdery solid was attached and dried and solidified, and then the powdered solid was removed.
  • it is dried and solidified, it is difficult to remove the powdery solid, and there is a problem that the inside is solidified and a sponge is not formed.
  • the subject of the present invention is a resin film product by wet film formation.
  • resin film products by wet film formation include gloves, socks, mats, cushions, rugs, burgloose, cushions, pillow covers, bags, shoulder straps for bags, packing belts, etc.
  • Various anti-slip materials can be mentioned.
  • a fluffy feel is obtained and the touch is good, it can be used for inner surface processing and the like.
  • the wet-formed resin part has a sponge structure, it has breathability, heat insulation / heat insulation, soundproofing / vibration resistance, and can be applied to various fields.
  • the resin for wet film formation may be provided on the entire surface of the glove or may be provided partially.
  • the resin for wet film formation can be formed on the front and back surfaces of the fiber fabric.
  • the resin for wet film formation can be formed on the front and back surfaces of the fiber fabric. For example, by forming a wet film-forming resin on the inner peripheral surface of the glove, it is possible to prevent the hand and the glove from slipping when gripped with a strong force through the glove.
  • ⁇ A glove base such as a knitted fabric or a woven fabric is attached to a glove mold, and a wet urethane resin is applied to adhere a powdered solid.
  • the powdered solid is a water-soluble powder, which is immediately immersed in water to remove the water-soluble solvent and the powdery solid at the same time. Then, the gloves are made by sufficiently drying.
  • Example 1 In this embodiment, a case of creating gloves will be described.
  • the little finger part, the ring finger part, the middle finger part, the index finger part are knitted in order, and the four torso parts are knitted continuously to these four finger parts, and then the thumb part is
  • the fiber glove 11 is formed by knitting, knitting the five torso parts so as to be continuous with the thumb part and the four torso parts, and finally knitting the sleeve part.
  • the glove making mold 14 is covered with a fiber glove 11 and immersed in the polyurethane solution 12 filled in the filling tank 16 to adhere the polyurethane solution 12.
  • the polyurethane solution 12 is attached to the entire palm portion of the fiber glove 11. After pulling up from the polyurethane solution 12, the excess solution is removed by hanging it down with the fingertips of the gloves down.
  • Polyurethane solution 12 is necessary for forming a wet film-forming urethane resin film, 100 parts by weight of a polyurethane film for wet film formation (solid content 30%), 200 parts by weight of N, N'-dimethylformamide, 1 part by weight of a cell conditioner. Prepare by mixing chemicals according to the conditions.
  • the viscosity of the polyurethane resin for wet film formation is preferably 50 to 500 centipoise.
  • a powdered solid such as salt is adhered to the polyurethane solution 12 portion adhered to the fiber glove 11. That is, in a state where the glove making mold 14 is covered with the fiber glove 11, the water-soluble powder 15 is sprinkled from above to adhere the water-soluble powder 15 to the surface portion of the polyurethane resin portion 13.
  • the thickness of the polyurethane resin portion 13 to be wet-formed is preferably 0.1 mm to 2 mm. If the thickness is less than 0.1 mm, the protection of the glove body is lacking because the resin film is thin. However, since the wet film formation is performed, the film is soaked in the glove fabric, and therefore, when the glove fabric is thick, the thickness may be 1 mm or more.
  • the fiber glove 11 is immediately immersed in the water 20 as shown in FIG.
  • the polyurethane resin portion 13 is gelled by the substitution action of dimethylformamide as a solvent and water 20.
  • a cavity 18 having a predetermined size is generated in the polyurethane resin portion 13 by the substitution action of dimethylformamide and water 20.
  • the cavities 18 have different sizes and are formed so that a plurality of the cavities 18 are continuous.
  • the size of the cavity 18 can be adjusted by an additive that adjusts the hydrophilicity. If the additive is increased, the cavity 18 can be formed larger. That is, by adding a large amount of the above additives, the water absorption of the water 20 increases, the substitution of dimethylformamide with the water 20 is activated, and the cavity becomes large. However, when the cavity becomes large, the structure becomes sparse and the strength becomes weak. For example, the size of the cavity is approximately several tens of ⁇ m or less.
  • the surface 19 of the polyurethane resin portion 13 is formed flat at first glance by a substitution action of dimethylformamide and water 20 at first glance. In this manner, a sponge-like polyurethane resin portion 13 can be formed on the surface of the fiber glove 11.
  • a concave portion 17 is formed in the melted portion, and the polyurethane resin portion 13 is easily formed by the concave portion 17. Unevenness can be formed on the surface. Moreover, a plurality of cavities 18 are formed uniformly and continuously on the inner surface of the recess 17.
  • the wet solution when natural rubber is used, the wet solution may be melted out when the gelatinized without drying is applied to the water 20, but the polyurethane solution 12 which is a resin for wet film formation is used. In such a case, the wet solution does not dissolve even when it is applied to the water 20, and the coated polyurethane solution 12 does not move from the glove body.
  • the completed fiber glove 11 is obtained by coating a fiber cloth with a resin for wet film formation, and obtains a resin film product by wet film formation having a sponge shape and unevenness on the surface.
  • the surface area is increased and an excellent anti-slip effect can be exhibited.
  • the structure becomes sponge-like, and can exhibit excellent flexibility, excellent breathability, excellent heat insulation and heat retention, excellent sound and vibration insulation, and excellent soft touch.
  • the resin layer formed by wet film formation in the present invention has a softer and more velvety surface than conventional natural rubber / synthetic resin emulsions, and is suitable for protecting products such as cushioning materials.
  • the reason for this is thought to be that, while the conventional technique dries while shrinking by slowly blowing off moisture, the present invention removes DMF all at once in water, thus forming a fine cavity.
  • cavities are evenly formed on the inner surface of the concavo-convex wall, and a fine structure that cannot be measured with a small size of several tens of ⁇ m or less is formed.
  • the solid content is as high as 30 to 60% in the prior art and the solid content is as low as 5 to 20% in the present invention, it is considered that the difference in the solid content is further influenced.
  • the coating is performed by dipping only once in the polyurethane solution 12 for wet film formation.
  • the sponge-like polyurethane resin portion 13 can be formed on the surface with fewer steps than a conventional product such as natural rubber.
  • Comparative Example 1 in the case of creating gloves will be described.
  • the glove making mold 14 is covered with the fiber glove and dipped in a polyurethane solution to adhere the polyurethane solution. After lifting from the solution, remove excess solution by hanging it down with the fingertips of the gloves down.
  • water-soluble powder is adhered to the polyurethane solution portion adhered to the fiber glove, and dried and solidified at 70 ° C. for 30 minutes. After drying, it is immersed in water 20 to dissolve and remove the water-soluble powder.
  • a glove having irregularities on the surface can be created by drying and releasing from the mold.
  • the polyurethane solution is the same as in Example 1.
  • an excellent anti-slip effect in which a microscopic sponge-like portion due to a cavity formed by wet film formation and irregularities of about several hundred ⁇ m due to powdered solids are combined.
  • the resin film product by wet film formation of the present invention has a large surface area due to surface irregularities, and therefore can be used for fiber fabrics that require a non-slip effect.
  • the resin film product by wet film formation has a sponge-like structure, it can be used for applications that require air permeability, heat insulation / heat insulation, soundproof / vibration resistance / flexibility. Furthermore, it is also suitable for harvesting fruit trees for the purpose of protecting the product.
  • a Urethane gloves 11 Textile gloves (fibrous fabric) 12 Polyurethane solution 13 Polyurethane resin part 14 Glove making mold 15 Water-soluble powder 16 Filling tank 17 Recessed part 18 Cavity 19 Gloves surface (non-slip part) 20 water

Abstract

La présente invention concerne un article enduit de résine produit par formation de film humide, dans lequel un excellent effet antidérapant et une excellente douceur peuvent être conférés à la résine appliquée par formation de film humide. L'article enduit de résine selon l'invention est produit en fixant des particules solides pulvérulentes (15) pendant l'enduction d'un tissu de fibres (11) avec la résine (13) devant être soumise à formation de film humide, puis en éliminant les particules solides pulvérulentes (15) en même temps qu'on procède à la formation de film humide. Il est ainsi possible de former des protubérances et des creux en forme d'éponge sur la surface (19), et de d'obtenir un excellent effet antidérapant et une excellente douceur.
PCT/JP2010/071967 2009-12-09 2010-12-08 Article enduit de résine produit par formation de film humide, et procédé de production correspondant WO2011071060A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2009279656A JP4875138B2 (ja) 2009-12-09 2009-12-09 湿式成膜による樹脂皮膜品及びその製造方法
JP2009-279656 2009-12-09

Publications (1)

Publication Number Publication Date
WO2011071060A1 true WO2011071060A1 (fr) 2011-06-16

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103857305A (zh) * 2011-10-14 2014-06-11 住友橡胶工业株式会社 手套的制造方法
KR101651821B1 (ko) * 2015-07-29 2016-08-29 (주)신성메이저글러브 장갑의 표면처리용 분말 코팅장치

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11229248B2 (en) * 2015-12-02 2022-01-25 Showa Glove Co. Supporting glove and method for manufacturing the supporting glove

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008029703A1 (fr) * 2006-09-04 2008-03-13 Showa Glove Co. Gant
JP4331782B2 (ja) * 2007-03-30 2009-09-16 株式会社東和コーポレーション 樹脂表面の形成方法、表面に異なる大きさの凹状部が混在する物品の製造方法及びその物品、手袋の製造方法及び手袋

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008029703A1 (fr) * 2006-09-04 2008-03-13 Showa Glove Co. Gant
JP4331782B2 (ja) * 2007-03-30 2009-09-16 株式会社東和コーポレーション 樹脂表面の形成方法、表面に異なる大きさの凹状部が混在する物品の製造方法及びその物品、手袋の製造方法及び手袋

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103857305A (zh) * 2011-10-14 2014-06-11 住友橡胶工业株式会社 手套的制造方法
CN103857305B (zh) * 2011-10-14 2015-11-25 住友橡胶工业株式会社 手套的制造方法
KR101651821B1 (ko) * 2015-07-29 2016-08-29 (주)신성메이저글러브 장갑의 표면처리용 분말 코팅장치

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JP2011122261A (ja) 2011-06-23
JP4875138B2 (ja) 2012-02-15

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