WO2011069556A1 - Installation de détection d'encrassement et procédé de détection d'encrassement - Google Patents

Installation de détection d'encrassement et procédé de détection d'encrassement Download PDF

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Publication number
WO2011069556A1
WO2011069556A1 PCT/EP2009/066923 EP2009066923W WO2011069556A1 WO 2011069556 A1 WO2011069556 A1 WO 2011069556A1 EP 2009066923 W EP2009066923 W EP 2009066923W WO 2011069556 A1 WO2011069556 A1 WO 2011069556A1
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WO
WIPO (PCT)
Prior art keywords
fouling
fluid
measuring
parameter
conductivity
Prior art date
Application number
PCT/EP2009/066923
Other languages
English (en)
Inventor
Claudia Caussin De Schneck
Hartmut Forster
Karl Helminger
Ralf Krack
Robert Najman
Original Assignee
Ecolab Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ecolab Inc. filed Critical Ecolab Inc.
Priority to ES09775173.9T priority Critical patent/ES2539303T3/es
Priority to PL09775173T priority patent/PL2510343T3/pl
Priority to NZ600225A priority patent/NZ600225A/en
Priority to MX2012006447A priority patent/MX2012006447A/es
Priority to EP09775173.9A priority patent/EP2510343B1/fr
Priority to PCT/EP2009/066923 priority patent/WO2011069556A1/fr
Priority to US13/513,261 priority patent/US8970829B2/en
Priority to AU2009356474A priority patent/AU2009356474B2/en
Priority to CA2782197A priority patent/CA2782197C/fr
Priority to JP2012542369A priority patent/JP5612700B2/ja
Priority to BR112012016022-2A priority patent/BR112012016022B1/pt
Priority to DK09775173.9T priority patent/DK2510343T3/en
Priority to CN200980162831.6A priority patent/CN102652258B/zh
Publication of WO2011069556A1 publication Critical patent/WO2011069556A1/fr

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Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01—Arrangements or apparatus for facilitating the optical investigation
    • G01N21/15—Preventing contamination of the components of the optical system or obstruction of the light path
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/10—Testing of membranes or membrane apparatus; Detecting or repairing leaks
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N17/00—Investigating resistance of materials to the weather, to corrosion, or to light
    • G01N17/008—Monitoring fouling
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
    • G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
    • G01N27/06—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a liquid
    • G01N27/08—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a liquid which is flowing continuously
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01—Arrangements or apparatus for facilitating the optical investigation
    • G01N21/15—Preventing contamination of the components of the optical system or obstruction of the light path
    • G01N2021/155—Monitoring cleanness of window, lens, or other parts
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01—Arrangements or apparatus for facilitating the optical investigation
    • G01N21/15—Preventing contamination of the components of the optical system or obstruction of the light path
    • G01N2021/155—Monitoring cleanness of window, lens, or other parts
    • G01N2021/157—Monitoring by optical means

Definitions

  • the invention refers to a fouling detection setup and a method for determining the amount of fouling of surfaces of fluid treating devices and/or internal functional components of such devices, which are exposed to said fluid and are subjected to fouling.
  • Fouling detection setups and methods are useful for monitoring the amount of fouling of surfaces of such fluid treating devices and/or internal functional components, e.g. heat-transfer surfaces and also for monitoring the cleaning procedure of such fluid treating devices and/or internal functional components of such devices which is commonly called CIP (Cleaning In Place).
  • CIP Cosmetic In Place
  • a method and apparatus for testing the efficiency of a cleaning procedure for a filter in a filtering system is known from US 20050000894 A1 . After the cleaning procedure, the system is pressurized and a decay in pressure over a
  • An apparatus for measuring a fouling resistance of the heat transfer from a heat- transfer surface and a cleanliness factor of a heat-transfer surface, which is capable of online monitoring a build up degree of deposits is known from US 5992505A.
  • the apparatus uses the given length of a given wire wound inside the heat-transfer surface for measuring an average temperature of the heat-transfer surface and an inlet/outlet portion water temperature measuring member for measuring the temperature of the inlet/outlet portions of the apparatus.
  • Another apparatus for online measuring the fouling of a fluid treating device including a heat exchanger is known from US4766553A.
  • the apparatus calculates the heat-transfer coefficient as a function of the inlet/outlet temperatures, flow rate, area, and specific heat of the heat exchanger.
  • the actual heat-transfer coefficient is compared with a nominal or original heat-transfer coefficient to determine if any deterioration in the coefficients has occurred which reflects the fouling of the heat exchanger.
  • fouling detection devices can only detect fouling with respect to the operating parameters of the fluid treating device and/or internal functional components thereof itself, for example by measuring the internal pressure, heat transfer, or flow rate of the system.
  • fouling detection occurs at a time, at which the operating parameters of the fluid treating device are already strongly deteriorated, which may lead to damage of functional components and may overrun the system.
  • previously mentioned systems require multiple sensors, which increases the instability or failure of such systems.
  • the fouling detection setup according to the present invention comprising at least one first sensor, which comprises means for measuring the electrical conductive conductivity and/or optical transparency of said fluid including at least one sensitive area that is located nearby or within said surfaces of the fluid treating devices and/or internal functional components of such devices, and wherein said area is at least temporarily exposed to the fluid.
  • a fouling detection setup according to the present invention can be used for fouling, scaling, and/or cleaning control of fluid treating devices that may include functional components, such as for example drain lines, UHT- (Ultra High
  • the operator of any fluid treating device can easily see when his installation needs to be cleaned and when each cleaning step can be ended.
  • optimum runtimes are possible, which may lead to optimum process costs due to the easy to use and robust measuring system.
  • fluid treating devices may be tanks, pipes, containers, ducts, circulation systems, or any combination thereof. These fluid treating devices include one or more of internal functional components, which according to various embodiments of present invention may be heat-transfer surfaces, evaporators, homogenizers, mixing apparatus, mixing machines, or any combination thereof.
  • said surfaces of said fluid treating devices and/or internal functional components thereof are exposed to said fluid and are subjected to fouling. They may include surfaces of internal functional components of such fluid treating devices. Said surfaces, that are under consideration, are subjected to fouling and may, therefore, be only temporarily exposed to the fluid, since after a certain amount of time, a layer of fouling may completely cover the respective surface.
  • said first sensor comprises an area that is located nearby or within said exposed surfaces. Therefore, similar to said exposed surfaces, said area of the sensor may be at least temporarily exposed to said fluid and is also subjected to fouling. Being located nearby or within said exposed surfaces, the amount of fouling of said area of the sensor represents the amount of fouling of said surfaces.
  • said means for measuring the conductive conductivity and/or optical transparency preferably comprise said area.
  • every said first sensor may comprise means for measuring a physical parameter, as for example the conductive conductivity and/or optical transparency.
  • Said physical parameter should generally be independent of the amount of fouling of any surface of the fluid treating devices.
  • said means for measuring said parameter are realized in such a way, that the measurement of the physical parameter with said means does show a strong dependence on the amount of fouling of these surfaces.
  • the measurement of the physical parameter with measurement means according to present invention results in a different value of the measured physical parameter, compared to the value of said physical parameter, that is obtained when the system is in its clean state.
  • any sensor that may be used within a fouling detection setup according to the invention, may originally be designed to measure any arbitrary physical parameter, but when measuring said physical parameter, the value that is being delivered by said sensor strongly deteriorates in case of fouling of said sensor.
  • a sensor comprises an area, that is subjected to fouling and wherein the fouling of said area is reason for said deterioration of said value.
  • the area can be located nearby or within said exposed surfaces, that are under consideration, in order to have an accurate measure for the fouling of those exposed surfaces.
  • any change in electrical conductive conductivity and/or optical transparency that is measured with said at least one first sensor is a measure for the extend of fouling of said surfaces.
  • the area of said measuring sensor may comprise at least one first electrically conductive surface, which may be used as a first electrode.
  • the sensor may further comprise means for measuring the conductive conductivity between said first electrically conductive surface and a second electrically conductive surface, wherein this second conductive surface is at least temporarily exposed to said fluid. Said second electrically conductive surface may then be used as a second electrode.
  • the area of said sensor also comprises said second electrically conductive surface, however being located separate from said first electrically conductive surface.
  • the second electrically conductive surface may be embodied in any conductive component of the fluid treating devices, if there is any, or any other second electrically conductive surface external to said area of the measurement sensor, however being especially designed for usage as a second electrode of the measuring means.
  • said second electrically conductive surface may be less strongly subjected to fouling compared to the exposed surfaces, but it is also within the scope of the invention, if said second electrically conductive surface is not at all subjected to fouling, or is similarly subjected to fouling as said exposed surfaces.
  • Any other geometry for measuring the conductive conductivity is generally possible, if only the measuring setup for measuring the conductive conductivity of the fluid shows a deterioration of the measurement result, that depends on the amount of fouling.
  • a possible embodiment of the electrical conductivity sensor which may
  • This specific electrical conductivity sensor is able to detect conductivity values in between 0 to 20 mS/cm and also includes a temperature measuring device.
  • every other conductive conductivity sensor with at least one exposed measuring electrode which according to the invention corresponds to the first electrically conductive surface included in the area of the measuring sensor, may be included in said means for measuring the conductive conductivity of the fluid.
  • a sensor even has a larger detection range for conductivities in between 0 to 100 mS/cm for example.
  • the sensor for measuring the conductive conductivity may be specified accordingly.
  • the fouling detection setup can be used to detect the amount of fouling of surfaces of fluid treating devices and/or internal function components of such devices, wherein in consecutive product cycles the fluid treating device may be used for different fluids.
  • the intrinsic conductivity of the fluid which generally can be measured with the fouling detection setup when the fluid treating device is in its clean state, may be different for every other fluid.
  • the fouling detection setup may comprise different conductivity measuring sensors, wherein every sensor may have a different measurement range and possibly also a varying accuracy.
  • the fouling detection setup comprises means to detect whether the measured conductivity is within the range of values, for which the sensor is specified for and means to choose in between various sensors.
  • the fouling detection setup comprises at least one sensor for measuring the optical transparency of the fluid, said area of said measuring sensor may comprise at least one optically
  • the sensor may further comprise means for measuring the optical transparency and/or the amount of scattering of the light that may be emitted into said fluid.
  • those means may comprise at least one light source and an optical detector, wherein said light source may emit light through said transparent window into said fluid and the optical detector may detect light which is scattered into said detector because of scattering effects within said fluid and possibly also within the fouling of said exposed surfaces.
  • the optical detector is mounted right next to the light emitting device, whereas within another embodiment the detector is mounted spatially separated from the light detection device, behind a second transparent window.
  • said measurement window of the sensor may be subjected to fouling, which as a result decreases the transparency of said optical window.
  • the light emitting device is for example a laser, a light bulb, or a light emitting diode (LED).
  • the preferred center wavelength for the light emitting device is in the range of the optical spectrum in which the fluid is generally transparent, but wherein any fouling is semi-transparent and/or absorbing.
  • a possible implementation such a sensor for measuring the optical transparency of the fluid is realized by usage of a commercially available light detecting and/or light absorbing sensor, such as the near infrared absorption sensor HS 16-N manufactured by Optec.
  • the fouling detection setup according to such an embodiment may include light reflecting means, such as for example mirrors.
  • the fouling detection setup in another preferred embodiment may further comprise a second sensor, which is located at a position, where the measured signal of the physical parameter does not deteriorate over time or may deteriorate over time much slower than the measured signal of the first sensor does.
  • Said second sensor may comprise means for measuring the optical transparency and/or electrical conductivity of said fluid including at least one sensitive area, that is at least temporarily subjected to the fluid and that is positioned such, that it is either not subjected to fouling or is only subjected to fouling with an amount that is less than the fouling of said exposed surfaces of said fluid treating devices and/or internal functional components thereof.
  • the area of the second sensor is subjected to fouling that is less than half of the amount of the fouling of said exposed surfaces of said fluid treating devices and/or internal functional components thereof.
  • the fouling detection setup further comprises multiple of said first and/or second sensors and may also include means for calculating an average value of the measured values of multiple sensors.
  • the fouling detection setup may comprise means for choosing one or the other signal of multiple of said first and/or second sensors for further processing, depending on the specifications of those sensors and/or deviating measurement values, which might indicate failure of the respective sensor.
  • the fouling detection setup may further comprise at least one out of the following devices: a temperature measuring device, an inductive conductivity measuring device, a computation device, a data storage device, a visualization device, and/or any other output generating device, e.g. a display, data interface, and/or some analog signal.
  • a temperature measuring device may be used for normalizing the measured electric conductivity and/or transparency with respect to temperature.
  • the temperature measuring device is included within the sensor for measuring the electric conductivity and/or transparency of the fluid.
  • the temperature measuring device is located such, that the temperature of the fluid at the position of the first and/or second sensor is determined indirectly, possibly by calculating means that use some implemented predefined temperature gradient for calculating the temperature at the respective location.
  • the fouling detection setup may further comprise an inductive conductivity measuring device for measuring the electrical conductivity without being affected by fouling of said exposed surfaces.
  • the measured value is generally independent of any fouling of the sensor and implemented in a fouling detection setup of present invention may serve as a reference value for the measured conductive conductivity.
  • the fouling detection setup comprises at least one of said first sensors and at least one inductive conductivity measuring device.
  • a fouling detection setup according to the invention may further comprise means for determining a fouling parameter S by calculating the difference of the value measured with the inductive conductivity measuring device and the value measured with the conductive conductivity measuring device.
  • a fouling detection setup, that also comprises an inductive conductivity measuring device may be especially advantageous for arranging the fouling detection setup locally at only one position within and/or nearby said exposed surfaces.
  • the fouling detection setup may further comprise a computation device for calculating a fouling parameter S.
  • all sensors and/or measuring devices of the fouling detection setup may be connected to an analog/digital (A/D-) converter, which converts the analog signal of the sensors and/or measuring devices into a digital value.
  • the digital signal may be further transferred to said computation device.
  • the fouling detection setup may further comprise a data storage device for saving the measured values of the sensors and/or measuring devices and/or for saving any calculated fouling parameter S.
  • the fouling detection setup may further comprise a visualization device for visualizing the fouling parameter S and/or the measured data over time and/or for the output of automated recommendations preferably with regard to cleaning requirements of the fluid treating devices and/or internal functional components thereof.
  • the computation device may further include routines for calculating a fouling parameter S and for analyzing said fouling parameter S according to the method that is specified in the claims and/or the following description.
  • routines for calculating a fouling parameter S and for analyzing said fouling parameter S according to the method that is specified in the claims and/or the following description.
  • the features of said fouling detection setup may be specified in such a way, that they allow to accomplish said method.
  • a method for determining the amount of fouling of surfaces of fluid treating devices and/or internal functional components of such devices exposed to said fluid includes the steps of: measuring the electrical conductive conductivity Q and/or optical transparency T of said fluid at locations which are chosen such that they are nearby or within said exposed surfaces and wherein a change in electrical conductive conductivity and/or optical transparency represents a measure for the extend of fouling of said exposed surfaces, determining a fouling parameter S, and analysis of said fouling parameter S, preferably by comparison of said fouling parameter S with a predefined reference value, preferably a fluid dependent predefined reference value.
  • the measuring of the electrical conductive conductivity Q and/or optical transparency T of said fluid is preferably performed such, that the means for measuring the electrical conductive conductivity Q and/or optical transparency T continuously remain at said locations within at least one product cycle of the fluid treating devices.
  • a product cycle is defined as the time period between two cleaning procedures of the fluid treating devices and/or internal function components thereof.
  • said means for measuring the electrical conductive conductivity and/or optical transparency are preferably as much exposed to the fluid, as said surfaces. Any change of the measured electrical conductive conductivity Q and/or optical transparency T within said product cycle represents a measure for the extend of fouling of said exposed surfaces according to the invention.
  • the step of determining a fouling parameter S can be performed in various ways.
  • the fouling parameter S directly equals the measured value (Q,T), that was measured in the measuring step.
  • the measured value may be normalized with a predefined conversion coefficients C.
  • the step of determining a fouling parameter S may further include a step of calculating the difference and/or relative difference of the measured value (Q,T) and a pre-defined reference value, which preferably corresponds to the value of said physical parameter (Qo,T 0 ), which may be measured when the system is in its clean state. Accordingly, said reference value is generally fluid dependent. Said difference between the measured value and said reference value may then be interpreted as a measure for the amount of fouling of said surfaces and, therefore, may be considered as fouling parameter S.
  • the fouling parameter S is above some predefined threshold value (QT,T t ), which may dependent on the fluid and/or fluid treating device, the step of analyzing said fouling parameter may result in a corresponding cleaning advise.
  • the measuring step further includes measuring the electrical conductive conductivity Q' and/or optical transparency T of said fluid at locations that are chosen because they are particularly unaffected by fouling. These locations may be remote to said exposed surfaces that are under consideration, preferably upstream with respect to any internal functional component of said fluid treating devices.
  • the measured signal (Q',T') obtained from said locations, that are unaffected by fouling may be used as a continuous reference value in such a way, that the difference (Q-Q', T-T') and/or relative difference ((Q-Q')/Q, (T-T')/T) between the measured value at locations subjected to fouling (Q,T) and at locations that are particularly unaffected by fouling (Q',T) is used as a measure for the amount of fouling of the exposed surfaces.
  • the step of determining a fouling parameter S may then further include the step of calculating said difference, in order to associate the corresponding result with the fouling parameter S.
  • the method may further include a step of measuring the electrical inductive conductivity Q in d of said fluid.
  • the location for measuring the electrical inductive conductivity is arbitrary, and may be performed at a position, that is close to said exposed surfaces, preferably at the same position where the conductive conductivity is being measured.
  • the advantage of measuring the inductive conductivity Q in d is given by the fact, that generally its value is
  • determining a fouling parameter S may further include the step of calculating the difference (Q-Qind) and/or relative difference (Q-C Q) between the measured value Q that is obtained when measuring the conductive conductivity at a position that is subjected to fouling and when measuring the electrical inductive
  • the measuring step may also include measuring the temperature of the fluid. Preferably the temperature is being measured at the same locations, where the conductivity (Q,Q ⁇ Qind) and/or optical transparency ( ⁇ , ⁇ ') of the fluid is being measured.
  • the step of determining a fouling parameter S may then comprise a normalization of the measured conductivity (Q,Q ⁇ Qind) and/or optical transparency ( ⁇ , ⁇ ') with respect to temperature. This normalization can be performed according to a linear relationship between conductivity and/or optical transparency and temperature, or any other predefined functional relationship, which preferably is chosen with respect to the fluid.
  • the steps of measuring, determining a fouling parameter, and analyzing said fouling parameter are performed simultaneously with any operation of the fluid treating devices and/or functional components thereof.
  • the step of measuring and/or determining a fouling parameter is repeated for an arbitrary number of times before the remaining steps are performed.
  • all steps are done repeatedly after predefined time intervals At.
  • fouling of said exposed surfaces can be monitored online.
  • the step of determining the fouling parameter S may include calculating the fouling parameter S as a function of the measured values of the electrical conductivity (Q,Q ⁇ Qind) and/or optical transparency ( ⁇ , ⁇ ').
  • this function is linear with respect to the measured values, however it may also be any kind of polynomial of order N with pre-defined conversion coefficients C,.
  • these conversion coefficients C are chosen according to the respective sensor that is being used within the measuring step.
  • the conversion coefficients C may be determined within some previously performed calibration step.
  • the step of determining said fouling parameter S further includes saving the fouling parameter S with respective data acquisition and/or data storage means and/or the step of analysing said fouling parameter S includes retrieving a set of previous fouling parameters from the data storage means and visualizing said set of fouling parameters. Analysing said fouling parameter may, however, be also realized by comparing the fouling parameter S with some predefined threshold value ST. In case the fouling parameter S is larger than said threshold value ST, the method may further include a step of notifying the user of the fluid treating devices and/or internal functions thereof.
  • the step of analyzing said fouling parameter S may also include calculating a second parameter S', which is a measure for the change over time of the fouling parameter S, preferably by numerically calculating the first derivative f(S) of the fouling parameter S and comparing this second parameter S' with some other predefined threshold value S'T-
  • the step of analysing results in indicating the necessity for cleaning, when the magnitude of parameter S' is smaller than said predefined threshold value S'T-
  • the fluid is a mixture containing a suspension and/or emulsion.
  • the fluid is a mixture mostly containing milk.
  • the fluid treating device with internal functional components may be for example an UHT line. High temperatures may cause a denaturation of the milk, which may be the cause for fouling of the surfaces of the UHT-line, that are downstream of the heat generating element.
  • any other type of fluid may be treated within the fluid treating device and choosing any kind of preferred fluid does not restrict the present invention in any way.
  • a further alternative of present method may include a step of measuring the conductive conductivity and/or optical transparency at various locations within the fluid treating devices and/or functional components thereof and/or at different times, preferably integer fragments of said time interval At.
  • An additional step of calculating an average value may increase the accuracy of the determination of the fouling parameter S.
  • the determining step of the fouling parameter S may be performed by taking an average value.
  • Figure 1 is a schematic view of a fluid treating device with internal functional components, including a fouling detection setup according to the invention.
  • Figure 2 is a schematic view of the surfaces of the fluid treating device and internal functional components thereof as they are arranged in the streaming direction of the fluid, including a fouling detection setup, according to the invention.
  • FIG. 5 is a flow chart of four various alternatives of the method accord
  • a fluid treating device (2) for pasteurizing a fluid, preferably some mixture containing milk, is shown schematically.
  • the product circuit (12) of the fluid treating device (2) contains an UHT line, which comprises pipes and tanks and two heat exchangers (37) for heating the fluid (6), which according to the preceding description are representing said internal functional components of the fluid treating device (12).
  • the product circuit (12) has an inlet portion for feeding the fluid (6) into the product circuit (12) and an outlet portion for withdrawal of fluid (6).
  • the fluid first passes through a first heat exchanger (37), for preheating the fluid (6) by thermodynamic contact with those portions of the fluid (6) that have already passed most parts of the product circuit (12) and are just before exiting the product circuit (12) through the outlet portion.
  • the fluid After being preheated in the first heat exchanger (37), the fluid is being guided through a pipe into a second heat exchanger (37), where it is being heated to high temperatures by thermodynamic contact with an external water circuit (38).
  • the water in the external water circuit (38) has been heated by passage through a third heat exchanger (41 ), which is driven by steam and/or some electrically powered heat source (39).
  • the heat source also includes an electrical output, which may serve as a measure for the temperature of the water circuit.
  • the fluid (6) may cause fouling (5) on the surfaces (3) of the fluid heating device and the heat-exchangers, which are located right at the beginning of the first heat exchanger and downstream of that.
  • the fouling detection setup (1 ) according to the preferred embodiment of present invention as shown in Figure 1 comprises two sensors (7,107) with means for measuring the conductive conductivity of the fluid (9, 109), two temperature measurement devices (3, 130), a sensor for measuring the inductive conductivity of the fluid (13), an analog digital converter (35), and a Personal Computer (PC) (36).
  • the latter includes a computation device (32), a data device (33), and a visualization device (34).
  • the first sensor (7) for measuring the conductive conductivity of the fluid is positioned such, that the area (8) of the sensor, as can be seen in Figure 2 is located within the exposed surfaces (3) of the fluid treating device and heat exchangers thereof, which are subjected to fouling (5).
  • said area (8) of the sensor (7) is also subjected to fouling (5), in such a way that the fouling (5) on this area (8) represents the fouling of the surfaces (3) of the fluid treating device, including those of the heat exchangers.
  • One of the temperature measuring devices (30) is located nearby, in order to measure the temperature of the fluid at the position, where the electrical conductivity of the fluid (6) is being measured.
  • the sensor for measuring the temperature (30) and the sensor (7) for measuring the conductive conductivity of the fluid are schematically shown in Figures 1 and 2 as being separate, however, in a preferred embodiment of the invention both devices can be combined in one single device.
  • the second temperature measuring device (130) and the sensor (7, 107) with means for measuring the conductive conductivity of the fluid (109) are positioned upstream within the fluid treating device with respect to the heat-transfer surfaces (4) within the first and second heat exchangers (37). At this position the fluid is not heated yet, and therefore does not generate any fouling on nearby surfaces of the fluid treating device.
  • the measured conductive conductivity of the sensor (107), which is located upstream to the water chamber for heat transfer (37) generally should remain constant.
  • the measured conductive conductivity of the first sensor (7) changes, because of the fouling (5) of the surfaces (3) of the fluid treating device which are at and/or downstream the heat exchangers (37). The fouling (5) is generated due to the increased
  • the fouling detection setup (1 ) further includes a sensor for measuring the inductive conductivity of the fluid (13).
  • the position of the sensor (13) in this specific embodiment is located downstream the heat exchangers (37), but can be located at any position within the fluid treating device (2).
  • All sensors are connected to an analog/digital- (A D-)converter, which converts the measured values of the sensors into a digital signal.
  • the digital signal is being transferred to a computation device, which according to the present embodiment of the invention is included in a personal computer (36).
  • Any measured value can be visualized by using a visualization device (34), which is connected to the Personal Computer (36), which may also include any computed fouling parameter or any automated recommendations based on a comparison of the fouling parameter with predefined threshold values or reference values.
  • the fluid stream (6) is shown schematically as it passes along various components of the surfaces of the fluid treating device, including internal functional components thereof (3) and the fouling detection setup (1 ) according to a preferred embodiment of the invention, which is shown in Figure 1 .
  • the functional components that are being passed include the heat transfer surfaces (4) of the first and second heat exchanger (37).
  • the fluid first passes the sensor with means for measuring the conductive conductivity of the fluid (109) and the temperature measuring device (130). At the position of those devices the fluid (6) is not yet heated and therefore does not generate any fouling (5) on the surfaces of the fluid treating device.
  • the fluid (6) passes the surfaces of the heat exchangers (4, 37).
  • the fluid (6) is thereby heated and may start to generate fouling (5) on the surfaces (3) of the fluid treating device and the heat exchangers.
  • an additional temperature sensor (30) and a sensor (7) for measuring the conductive conductivity of the fluid has been arranged.
  • Both sensors (7, 107) for measuring the conductive conductivity of the fluid are schematically shown in Figure 2 by comprising an area (8, 108) that is located within the respective surfaces of the fluid treating device (2) and may be subjected to fouling, as it is the case for the sensor (7) downstream of the heat exchangers (4, 37).
  • the sensor (7) further comprises means to measure the electrical conductive conductivity (9, 109) of the fluid, wherein these means are connected to a first electrically conductive surface (10, 1 10) and to a second electrically conductive surface (1 1 , 1 1 1 ), wherein in this specific embodiment of the invention both conductive surfaces (10, 1 10, 1 1 1 , 1 1 ) are located within said area (8, 108) of the sensor (7, 107).
  • the conductive surfaces of the sensor (10, 1 10, 1 1 , 1 1 1 ) are therefore similarly subjected to fouling as the area (8, 108) of the sensor (7, 107).
  • the sensors are connected to an analog digital converter (35) which is connected to a Personal Computer (36), including a computation device (32), a data device (33), and a visualization device (34).
  • Figure 3 shows a schematic view of the sensor (7) for measuring the conductive conductivity of the fluid along the cutting line in Figure 2.
  • the Figure shows the area (8) of the sensor which is being subjected to fouling (5) and which includes a first electrically conductive surface (10) and a second electrically conductive surface (1 1 ). Both are connected to means for measuring the electrical conductive conductivity (9).
  • Figure 3 shows the course of field lines (40) in between the first (10) and second electrically conductive surface (1 1 ). Depending on the amount of fouling (5) the electrical field lines (40) partially pass through a layer of fouling (5) and the fluid itself.
  • FIG 4 an equivalence circuit diagram is shown for the electrical current in between the first and second conductive surface for every electrical field line (40), which are represented in Figure 3.
  • An equivalent electrical resistance (44) for all remaining field lines is shown schematically.
  • the electrical resistance for every path of current along any one of the field lines can be considered as a series connection of an electrical resistance that depends on the amount of fouling (43) and another resistance (42), representing the electrical resistance of the fluid (6).
  • the equivalent electrical resistance (43) of the fouling layer (5) increases, caused by the increasing thickness of the fouling layer (5).
  • FIG 5 a flow chart of four various alternatives of the method according to this invention is shown.
  • the flow chart graphically demonstrates the steps of the fouling detection method while using the fouling detection setup according to the embodiment, that has been described before. All alternatives, which are shown in Figure 5, start with a measuring step, which includes measuring the electrical conductive conductivity Q, at a location that is subjected to fouling.
  • the measuring step can be performed by utilizing the electrical conductive conductivity sensor (7), which is located downstream of the surfaces of the heat exchangers (37,4).
  • the step of determining a fouling parameter S is realized according to the first alternative, shown in Figure 5 on the very left side.
  • the fouling parameter S is being calculated as the difference between the measured conductive conductivity Qi and a predefined reference value, which according to this alternative is given by the measured conductive conductivity at the beginning of the measurement cycle.
  • the measurement cycle starts at the same time as the product cycle.
  • the conductive conductivity Q 0 is measured in the clean stage of the fluid treatment device and should therefore correspond to the physically anticipated, fluid dependent electrical conductivity of the fluid.
  • the step of analyzing includes checking, if the saturation parameters exceeds a threshold value, which in the affirmative case causes a step of issuing a cleaning advice.
  • the step of measuring, determining and analyzing is being repeated continuously, preferably starting at predefined time intervals At.
  • the index i represents an increasing integer number, which continuously increases with every new
  • the step of measuring further includes measuring the conductive conductivity Q' at a location that is not subjected to fouling.
  • the step of measuring the conductive conductivity Q' can be performed by utilizing the sensor (107) of the fouling detection setup, which is located upstream of any internal functional components.
  • the step of determining a fouling parameter S is performed by calculating the difference between the conductive conductivity Q', which was measured at a location that is not subjected to fouling and the conductive conductivity Q, which was measured at a location that is subjected to fouling.
  • the step of analyzing remains equal to the alternative described before.
  • the third alternative of the method which is schematically shown in Figure 5 is performed such, that the measurement step includes measuring the inductive conductivity Q- md . Since the inductive conductivity is independent of the amount of fouling of any surface within the fluid treating device and/or internal functional components thereof, the advantage of this method is given by the fact, that the measurement of the inductive conductivity can be performed at the same position in which the conductive conductivity was measured.
  • the step of determining a fouling parameter includes calculating the saturation parameter as the difference between a function of the inductive conductivity and a function of the conductive conductivity. These functions might be any kind of polynomial and are specified according to the sensor that was used for measuring the respective value.
  • the polynomial might have been pre-determined specifically for each sensor within a previous calibration step, which is not shown in Figure 5.
  • the saturation parameter S might as well be calculated by directly calculating the difference between the measured inductive and conductive conductivity.
  • the step of measuring further includes measuring the temperature of the fluid at the position in which the inductive conductive and/or the conductive conductivity was measured.
  • the step of determining a fouling parameter now includes the step of normalizing the measured conductivity with respect to temperature.
  • the step of calculating the fouling parameter includes respective functions which also depend on the temperature T next to the measured
  • the 4 th alternative as it is shown in Figure 5, further includes the step of saving all measured values and another step of retrieving old data values, which are being visualized with respective visualizing means.
  • the method according to the invention also includes any other alternative, which might be a combination of those previously described alternatives or any other which is in accordance with the features of the claims.
  • the invention has been described above mainly with reference to a preferred embodiment of the fouling detection setup (1 ). However, other embodiments than the one disclosed above are also possible within the scope of the invention, as defined by the appended patent claims.
  • Heat generating element including electrical supply and output for 40 Electrical field line

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Abstract

L'invention porte sur une installation de détection d'encrassement (1) et sur un procédé de détermination de l'amplitude d'encrassement (5) de surfaces (3) de dispositifs de traitement (2) de fluide (6) et/ou d'éléments fonctionnels internes (4) de tels dispositifs exposés audit fluide et sujets à un encrassement. Les installations et les procédés de détection d'encrassement sont utiles pour la surveillance de l'amplitude d'encrassement d'une surface, par exemple de surfaces d'échange thermique et également pour la surveillance de la procédure de nettoyage de tels dispositifs de traitement de fluide et/ou des éléments fonctionnels internes de tels dispositifs. Selon l'invention, l'installation de détection (1) comprend au moins un premier capteur (7) comportant des moyens (9) de mesure de la transparence optique T et/ou de la conductivité électrique Q dudit fluide (6). Le capteur comprend au moins une zone sensible (8) localisée près desdites surfaces (3) ou à l'intérieur de celles-ci, et ladite zone étant au moins temporairement exposée audit fluide (6).
PCT/EP2009/066923 2009-12-11 2009-12-11 Installation de détection d'encrassement et procédé de détection d'encrassement WO2011069556A1 (fr)

Priority Applications (13)

Application Number Priority Date Filing Date Title
ES09775173.9T ES2539303T3 (es) 2009-12-11 2009-12-11 Instalación de detección de incrustación y método para detectar incrustación
PL09775173T PL2510343T3 (pl) 2009-12-11 2009-12-11 Układ do wykrywania osadu i sposób wykrywania osadu
NZ600225A NZ600225A (en) 2009-12-11 2009-12-11 Fouling detection setup and method to detect fouling
MX2012006447A MX2012006447A (es) 2009-12-11 2009-12-11 Sistema de deteccion de suciedad y metodo para detectar suciedad.
EP09775173.9A EP2510343B1 (fr) 2009-12-11 2009-12-11 Installation de détection d'encrassement et procédé de détection d'encrassement
PCT/EP2009/066923 WO2011069556A1 (fr) 2009-12-11 2009-12-11 Installation de détection d'encrassement et procédé de détection d'encrassement
US13/513,261 US8970829B2 (en) 2009-12-11 2009-12-11 Fouling detection setup and method to detect fouling
AU2009356474A AU2009356474B2 (en) 2009-12-11 2009-12-11 Fouling detection setup and method to detect fouling
CA2782197A CA2782197C (fr) 2009-12-11 2009-12-11 Installation de detection d'encrassement et procede de detection d'encrassement
JP2012542369A JP5612700B2 (ja) 2009-12-11 2009-12-11 ファウリング検出機構及びファウリングを検出する方法
BR112012016022-2A BR112012016022B1 (pt) 2009-12-11 2009-12-11 Instalação de detecção de incrustação e método para a determinação da quantidade de incrustação de superfícies
DK09775173.9T DK2510343T3 (en) 2009-12-11 2009-12-11 Device for detecting soiling and method for detecting soiling
CN200980162831.6A CN102652258B (zh) 2009-12-11 2009-12-11 结垢检测装置和结垢检测方法

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PT3575782T (pt) 2018-05-31 2023-08-23 Univ Del Pais Vasco/Euskal Herriko Unibertsitatea Método e dispositivo para a deteção e monitorização de uma incrustação de superfície
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CN115667835A (zh) * 2020-03-25 2023-01-31 美商戽水车水科技股份有限公司 用于实时直接监测传热表面的表面结污和结垢的方法和装置
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EP2510343B1 (fr) 2015-03-18
PL2510343T3 (pl) 2015-10-30
US8970829B2 (en) 2015-03-03
US20130003048A1 (en) 2013-01-03
EP2510343A1 (fr) 2012-10-17
CN102652258B (zh) 2015-11-25
BR112012016022A2 (pt) 2018-05-29
CA2782197C (fr) 2017-06-20
NZ600225A (en) 2013-12-20
JP2013513784A (ja) 2013-04-22
CA2782197A1 (fr) 2011-06-16
AU2009356474B2 (en) 2015-10-01
CN102652258A (zh) 2012-08-29
AU2009356474A1 (en) 2012-06-14
ES2539303T3 (es) 2015-06-29
JP5612700B2 (ja) 2014-10-22
DK2510343T3 (en) 2015-04-20
BR112012016022B1 (pt) 2019-09-24

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