WO2010071241A3 - 樹脂組成物およびそれを用いた多層構造体 - Google Patents

樹脂組成物およびそれを用いた多層構造体 Download PDF

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WO2010071241A3
WO2010071241A3 PCT/JP2010/054029 JP2010054029W WO2010071241A3 WO 2010071241 A3 WO2010071241 A3 WO 2010071241A3 JP 2010054029 W JP2010054029 W JP 2010054029W WO 2010071241 A3 WO2010071241 A3 WO 2010071241A3
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vinyl acetate
ethylene
polyolefin
acetate copolymer
mass
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PCT/JP2010/054029
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English (en)
French (fr)
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WO2010071241A2 (ja
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修 風藤
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株式会社クラレ
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Priority to EP10722902.3A priority Critical patent/EP2407508B1/en
Priority to CN2010800112948A priority patent/CN102348749A/zh
Priority to JP2010543034A priority patent/JP5730582B2/ja
Priority to ES10722902.3T priority patent/ES2531705T3/es
Priority to AU2010203002A priority patent/AU2010203002B2/en
Priority to US13/256,110 priority patent/US20120009431A1/en
Publication of WO2010071241A2 publication Critical patent/WO2010071241A2/ja
Publication of WO2010071241A3 publication Critical patent/WO2010071241A3/ja

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B19/00—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853—Vinylacetate
    • C08L23/0861—Saponified vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02—Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514—Oriented
    • B32B2307/518—Oriented bi-axially
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
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    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B32B2307/70—Other properties
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    • C08K5/01—Hydrocarbons
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
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    • C08K5/098—Metal salts of carboxylic acids
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
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    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31928—Ester, halide or nitrile of addition polymer

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)

Abstract

　ポリオレフィン（Ａ）、エチレン含有量２０～６５モル％、酢酸ビニル単位のケン化度９６％以上であるエチレン－酢酸ビニル共重合体ケン化物（Ｂ）、炭素数８～２２の高級脂肪酸金属塩（Ｃ）、および沸点２０℃以上の共役ポリエン化合物（Ｄ）を含有し、かつポリオレフィン（Ａ）とエチレン－酢酸ビニル共重合体ケン化物（Ｂ）の質量比（Ａ：Ｂ）が、６０：４０～９９．９：０．１であり、かつ、高級脂肪酸金属塩（Ｃ）をポリオレフィン（Ａ）とエチレン－酢酸ビニル共重合体ケン化物（Ｂ）の合計量１００質量部に対して０．０００１～１０質量部の範囲で、共役ポリエン化合物（Ｄ）をポリオレフィン（Ａ）とエチレン－酢酸ビニル共重合体ケン化物（Ｂ）の合計量１００質量部に対して０．０００００１～１質量部の範囲で含有する樹脂組成物。これにより、ミクロな領域における凝集物の生成が抑制され、ＥＶＯＨの分散性が改良される。そして、その凝集物に起因した流動異常による成形物表面の波模様の発生などの外観不良発生が抑制され、外観美麗な成形物が得られる。
PCT/JP2010/054029 2009-03-11 2010-03-10 樹脂組成物およびそれを用いた多層構造体 WO2010071241A2 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP10722902.3A EP2407508B1 (en) 2009-03-11 2010-03-10 Resin composition and multilayered structure using the same
CN2010800112948A CN102348749A (zh) 2009-03-11 2010-03-10 树脂组合物及使用其而成的多层结构体
JP2010543034A JP5730582B2 (ja) 2009-03-11 2010-03-10 樹脂組成物およびそれを用いた多層構造体
ES10722902.3T ES2531705T3 (es) 2009-03-11 2010-03-10 Composición de resina y estructura multicapa que la utiliza
AU2010203002A AU2010203002B2 (en) 2009-03-11 2010-03-10 Resin composition and multilayered structure using the same
US13/256,110 US20120009431A1 (en) 2009-03-11 2010-03-10 Resin composition and multilayered structure using the same

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JP2009058076 2009-03-11
JP2009-058076 2009-03-11

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US (1) US20120009431A1 (ja)
EP (1) EP2407508B1 (ja)
JP (1) JP5730582B2 (ja)
KR (1) KR101652742B1 (ja)
CN (2) CN104004248B (ja)
AU (1) AU2010203002B2 (ja)
ES (1) ES2531705T3 (ja)
WO (1) WO2010071241A2 (ja)

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JP6703753B2 (ja) * 2015-11-13 2020-06-03 三菱ケミカル株式会社 エチレン−ビニルエステル系共重合体ケン化物ペレット及びその製造方法
WO2017142745A1 (en) 2016-02-17 2017-08-24 The Curators Of The University Of Missouri Fabrication of multilayer nanograting structures
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TWI810170B (zh) * 2016-12-29 2023-08-01 日商可樂麗股份有限公司 樹脂組成物及其用途
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EP3715414B1 (en) * 2017-11-22 2023-04-26 Mitsubishi Chemical Corporation Resin composition, melt-forming material, multilayer structure, and liquid packaging material
WO2019103074A1 (ja) * 2017-11-22 2019-05-31 日本合成化学工業株式会社 樹脂組成物、溶融成形用材料、多層構造体および熱水殺菌用包装材料
TWI795472B (zh) * 2017-11-22 2023-03-11 日商三菱化學股份有限公司 樹脂組成物、熔融成形用材料、多層結構體及液體包裝用材料
CN112292408B (zh) 2018-04-17 2022-11-22 株式会社可乐丽 乙烯-乙烯醇共聚物、其制造方法及其用途
KR101926155B1 (ko) 2018-05-21 2018-12-07 주식회사 두본 폴리우레탄 섬유 제조용 펠렛 조성물 및 이를 이용하여 변색성이 낮고 해사성이 우수한 폴리우레탄 섬유를 제조하는 방법
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JPH0372542A (ja) * 1989-05-30 1991-03-27 Kuraray Co Ltd 樹脂組成物およびそれを用いた多層構造体
JPH0971620A (ja) * 1995-06-26 1997-03-18 Kuraray Co Ltd 酢酸ビニル系重合体の製法、酢酸ビニル系重合体ケン化物の製法および樹脂組成物
JPH101570A (ja) * 1996-06-17 1998-01-06 Nippon Synthetic Chem Ind Co Ltd:The 樹脂組成物およびその製造法、用途

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EP2407508B1 (en) 2014-12-17
JPWO2010071241A1 (ja) 2012-05-31
KR101652742B1 (ko) 2016-09-01
CN104004248A (zh) 2014-08-27
EP2407508A4 (en) 2012-08-08
CN104004248B (zh) 2017-08-04
EP2407508A2 (en) 2012-01-18
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CN102348749A (zh) 2012-02-08
AU2010203002B2 (en) 2013-03-21
US20120009431A1 (en) 2012-01-12

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