WO2009144912A1 - 有機elディスプレイおよびその製造方法 - Google Patents
有機elディスプレイおよびその製造方法 Download PDFInfo
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- WO2009144912A1 WO2009144912A1 PCT/JP2009/002300 JP2009002300W WO2009144912A1 WO 2009144912 A1 WO2009144912 A1 WO 2009144912A1 JP 2009002300 W JP2009002300 W JP 2009002300W WO 2009144912 A1 WO2009144912 A1 WO 2009144912A1
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- line
- bank
- ink
- organic light
- light emitting
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Images
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/12—Deposition of organic active material using liquid deposition, e.g. spin coating
- H10K71/13—Deposition of organic active material using liquid deposition, e.g. spin coating using printing techniques, e.g. ink-jet printing or screen printing
- H10K71/135—Deposition of organic active material using liquid deposition, e.g. spin coating using printing techniques, e.g. ink-jet printing or screen printing using ink-jet printing
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/122—Pixel-defining structures or layers, e.g. banks
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/30—Devices specially adapted for multicolour light emission
- H10K59/35—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
Definitions
- the present invention relates to a method for manufacturing an organic EL display.
- the present invention relates to a method for manufacturing an organic EL display in which an organic light emitting layer is formed by a coating method (more specifically, an ink jet method).
- Organic EL displays can be roughly classified into the following two types according to the method of forming the organic light emitting layer.
- One is a method of forming an organic light emitting layer by vapor deposition, and is used when the organic light emitting layer is made of a low molecular organic material.
- the other is a method of forming an organic light emitting layer by a solvent coating method, and is often used when the organic light emitting layer is made of a high molecular organic material as well as a low molecular organic material.
- an ink droplet containing an organic light emitting material is ejected to a pixel region of a display substrate by using an ink jet apparatus to form an organic light emitting layer.
- an ink jet apparatus to form an organic light emitting layer.
- the ejected droplets contain an organic light emitting material and a solvent.
- the inkjet apparatus has an inkjet head having two or more nozzles, and ejects ink from the nozzles while controlling the positional relationship between the nozzles of the inkjet head and the display substrate. It is known that there are variations in the size of droplets ejected from nozzles of an inkjet head (see Patent Document 2). Patent Document 2 reports a technique for improving film uniformity within a pixel region by landing a plurality of droplets on one pixel region and adjusting the landing position of each droplet.
- the pixel area of the display substrate from which droplets are discharged is often defined by a partition called a bank. This is so that the ejected ink stays position-selectively in the pixel area.
- the plurality of pixels are arranged on the substrate in rows for each color (RGB) to form a stripe pattern.
- RGB color
- One of the methods for ejecting droplets onto a display substrate having a bank partitioning pixels is a method for ejecting droplets while scanning the inkjet head of the inkjet device in a direction perpendicular to the longitudinal direction of the stripe.
- Known see Patent Documents 4 to 6).
- Another method for ejecting droplets onto a display substrate having a bank partitioning each pixel is an inkjet head of an inkjet apparatus that scans in a direction perpendicular to the longitudinal direction of the stripe, and the longitudinal direction of the stripe.
- a method of applying droplets in combination with an inkjet head of an inkjet apparatus that scans in a direction is known (see Patent Document 7).
- the bank may define a line-shaped region including pixels of the same color (for example, R: red, G: green, B: blue) arranged in a row among pixels arranged in a stripe shape.
- a bank that defines a line-shaped region may be referred to as a line-shaped bank. That is, an R, G, or B organic light emitting layer is formed for each region defined by the line bank (hereinafter also referred to as “line region”).
- the inkjet head 120 of the inkjet apparatus is disposed above (or below) the line direction of the line bank 111 of the display substrate 100 (at this time, preferably the line direction of the line bank 111 and the arrangement direction of the nozzles 121) And so that they are vertical) 2) While relatively moving the inkjet head 120 in parallel with the line direction of the line bank 111 (that is, while transporting the substrate 100 in the direction of the arrow), 3) An organic light emitting layer was formed by discharging droplets from the nozzle 121 to the line region 110 defined by the line bank 111.
- the ink to be applied to one line area is prevented from entering the adjacent line area by mistake. That is, in the color display, for example, a line region in which an R organic light emitting layer is formed, a line region in which a G organic light emitting layer is formed, and a line region in which a B organic light emitting layer is formed are repeatedly arranged. The stripe pattern. Therefore, it is necessary to reliably prevent the ink containing the organic light emitting material from leaking to the adjacent line region and causing color mixing. Therefore, ink is ejected while the inkjet head is relatively moved in parallel with the line direction of the line bank.
- droplets are always ejected from the same nozzle in one line area defined by the line bank.
- a nozzle that supplies (discharges) droplets is set for each region defined by the line bank.
- the amount of ink supplied varies slightly for each region defined by the line bank.
- the thickness of the formed organic light emitting layer is also different; when the thickness of the organic light emitting layer is different, the light emission amount, light emission intensity, and light emission wavelength are different.
- the light emission amount, light emission intensity, and light emission wavelength are different for each region defined by the line-shaped bank, a person visually recognizes as stripes when driven as a display.
- the thickness of the organic light emitting layer is not uniform for each line even if the nozzle of the ink jet head is not uniform. It aims at suppressing becoming. As a result, an organic EL display having a high image quality free from stripes is manufactured. Furthermore, the preferable aspect of this invention aims at providing the manufacturing method of the high quality organic electroluminescent display by which color mixing was suppressed.
- the first of the present invention relates to a method for producing an organic EL display shown below.
- a display substrate having a substrate, two or more line banks arranged on the substrate and parallel to each other, and two or more pixel regions arranged in a line region defined by the line banks is prepared.
- a method for producing an organic EL display comprising:
- the second of the present invention relates to the organic EL display shown below.
- a substrate a plurality of line banks disposed on the substrate and parallel to each other, two or more pixel regions disposed in a line region defined by the line banks, and a line region including the pixel region
- An organic EL display having a line-shaped organic light emitting layer disposed thereon,
- An organic EL display in which a contact height between the line-shaped organic light emitting layer and the line-shaped bank is constant in a line direction.
- the height of the contact point between the line-shaped organic light-emitting layer and the line-shaped bank disposed in the line region disposed at one end of the substrate having two or more line regions is The organic EL display according to [7], which is lower than a contact height between the line-shaped organic light-emitting layer disposed in the line region disposed at the other end and the line-shaped bank.
- the method of the present invention it is possible to suppress variations in the thickness of the organic light emitting layer for each line region even though the organic light emitting layer is formed on the display substrate having the line bank by the inkjet method. Therefore, an organic EL display free from luminance unevenness can be obtained. Furthermore, according to the preferred method of the present invention, a high-quality organic EL display in which color mixing is suppressed can be obtained.
- FIG. 2A is a diagram illustrating an arrangement state of the organic light emitting layer.
- FIG. 2B is a diagram illustrating an arrangement state of a line bank and a pixel region. It is a figure which shows a mode that the organic light emitting layer is apply
- ⁇ is a plot when the surface tension of the coated region is 20 dyn / cm; ⁇ is the surface tension of the coated region is 30 dyn / cm; ⁇ is a plot when the surface tension of the coated region is 40 dyn / cm. It is a figure which shows the cross section perpendicular
- the organic EL display manufactured according to the present invention has two or more line banks arranged in parallel to each other.
- the line bank may be a forward taper type or a reverse taper type, but is preferably a forward taper type.
- the material of the first bank is arbitrary as long as it is insulative, but is preferably an insulating resin (polyimide or the like).
- the wettability may be lowered by fluorinating the surface of the line bank with fluorine-based gas plasma or the like.
- the line direction of the line bank is arbitrary, but is usually parallel to the short axis direction of the display or parallel to the long axis direction.
- the organic light emitting layer is arranged in a line in a region (line region) sandwiched between adjacent line banks.
- FIG. 2A shows a state in which the organic light emitting layer is exposed by omitting the cathode electrode of the organic EL display.
- an R organic light emitting layer 15R, a G organic light emitting layer 15G, or a B organic light emitting layer 15B is formed in each line region 12, and these are repeatedly arranged (striped pattern). Configure).
- the thickness of the organic light emitting layer is preferably about 50 to 100 nm (for example, 60 nm).
- FIG. 2B shows a state in which the pixel region 13 is exposed by further removing the organic light emitting layers 15R, 15G, and 15B.
- two or more pixel regions 13 are arranged in a line in the line region 12.
- the pixel regions 13 are not partitioned independently so as to prevent the movement of the liquid, but are connected to each other through the gap 17 so that the liquid can move. That is, the ink ejected to the line area 12 can freely move in the line area 12.
- each pixel electrode (usually an anode electrode) is arranged in each pixel region 13.
- the anode electrode is arranged independently for each pixel region when the active method is adopted, and is arranged in a stripe shape when the passive method is adopted.
- the anode electrode When bottom emission is adopted, the anode electrode must be a transparent electrode and may be an ITO electrode or the like.
- the anode electrode is preferably a reflective electrode, and may be a silver electrode or a silver-palladium-copper alloy (also referred to as APC) electrode.
- the active method is adopted, the anode electrode is connected to the drain electrode of the TFT.
- a hole transport layer or an electron blocking layer may be disposed on the anode electrode.
- the hole transport layer is a layer made of a hole transport material.
- the material of the hole transport layer may be an oxide such as WO x (tungsten oxide), MoO x (molybdenum oxide), VO x (vanadium oxide), or a combination thereof.
- the hole transport material can be poly (3,4-ethylenedioxythiophene) doped with polyethylene sulfonic acid (referred to as PEDOT-PSS) or a derivative thereof (such as a copolymer).
- the thickness of the hole transport layer is usually from 10 nm to 100 nm and can be about 30 nm.
- the electron blocking layer has a role of blocking the transport of electrons to the hole transport layer and a role of efficiently transporting holes to the organic light emitting layer, and is a layer made of, for example, a polyaniline material.
- the thickness of the electron blocking layer is typically 10 nm or more and 100 nm or less, and may be about 40 nm.
- the organic light emitting layer is disposed over the entire line region including two or more pixel regions arranged in a row. That is, the organic light emitting layer extends over two or more pixel regions arranged in a line.
- the method for manufacturing an organic light emitting display panel according to the present invention includes 1) a step of preparing a display substrate (see FIG. 2B) before the organic light emitting layer is formed, and 2) a step of placing an inkjet head beside the prepared display substrate. 3) Applying an ink containing an organic light emitting material by inkjet to form an organic light emitting layer.
- the display substrate before forming the organic light emitting layer is, for example, the substrate shown in FIG. 2B, and is disposed in the substrate, a plurality of line banks parallel to each other, and a line region sandwiched between the line banks. Includes multiple pixel regions.
- the pixel region 13 at this time for example, the anode electrode is exposed, the hole injection / transport layer is exposed, or the electron block layer is exposed.
- a plurality of nozzles are arranged in a row on the ink jet head arranged on the side of the substrate.
- the head is supplied with ink containing an organic light emitting material, and the ink is ejected as droplets from the nozzle.
- the organic light-emitting material contained in the ink is preferably a polymer-based light-emitting material.
- the polymer-based light-emitting material include polyphenylene vinylene (PPV) and its derivatives, polyacetylene and its derivatives. Derivatives, Polyphenylene and its derivatives, Polyparaphenyleneethylene and its derivatives, Poly3-hexylthiophene (P3HT) and its derivatives, Polyfluorene (PF) )) And derivatives thereof.
- the inkjet head is disposed on the side of the line bank with respect to the line direction, and more specifically, on the side of the end of the plurality of line banks with respect to the line direction.
- the arrangement direction of the arranged inkjet nozzles and the line direction of the linear bank of the substrate may be parallel (see FIG. 3).
- the nozzles 21 (21-1 to 21-n) arranged in the inkjet head 20 from the nozzle 21-1 at one end to the nozzle 21-n at the other end. Is preferably equal to or longer than the length of the line region 12 of the substrate 10 in the line direction. This is because the ink can be applied to the entire line region 12 at the same time. Further, when the arrangement direction of the nozzles 21 of the inkjet head 20 is inclined with respect to the line direction of the line region 12, the “component in the line direction of the distance from the nozzle 21-1 to the nozzle 21-n” The length of the line region 12 is preferably equal to or longer than the length in the line direction.
- the inkjet head 20 may be arranged to be inclined with respect to the line direction. Thereby, the landing pitch in one line region can be reduced, and the time required for leveling can be shortened.
- the inkjet head 20 is tilted, a time difference occurs in the landing of droplets in the same line region. For this reason, the ink droplets that have landed first are dried to increase the viscosity before the last ink droplet lands, and the leveling after the droplets are connected is hindered. Therefore, as shown in FIG. 3C, each of the plurality of inkjet heads (20-1 to 20-6) may be arranged to be inclined with respect to the line direction.
- the time until the droplets are connected in the entire line region can be further shortened.
- the ink discharged from all the nozzles is leveled in the line region, so that the variation in the film thickness can be suppressed.
- it is not always necessary to apply the ink corresponding to the desired film thickness in one scan and the application to the entire line region 12 may be completed by repeating the scan a plurality of times.
- the viscosity of the ink applied in the previous scan increases, and leveling at the connection portion with the ink applied in the subsequent scan may be suppressed. For this reason, when a solvent that easily evaporates, such as an ink of an organic light emitting material, is used, it is desirable to apply to the entire line region in one scan.
- the pitch between the nozzles 21 arranged in a line on the inkjet head 20 is preferably 10 ⁇ m to 50 ⁇ m, and preferably about 20 ⁇ m, for example. This is because the ink ejected from the nozzles 21 is connected to each other at the landing point. Further, the amount of droplets ejected from the nozzle 21 is preferably 1 pl to 15 pl, for example 3 pl.
- the height of the gap 17 between the pixel regions is set to be somewhat higher than the height of the pixel region 13.
- the difference in height is not so large, and the coating film immediately after coating covers the gap 17 so as not to hinder leveling.
- the ink material is effectively used by concentrating the ink in the pixel region 13 in the drying process while realizing leveling.
- the inkjet head 20 is moved relative to the display substrate 10 in the direction perpendicular to the line direction of the line-shaped bank 11 of the display substrate 10.
- the inkjet head 20 may be moved, the substrate 10 may be conveyed, or both may be moved.
- the relative movement of the inkjet head 20 when the nozzle 21 of the inkjet head 20 reaches one of the line regions 12 (see FIG. 4), ink droplets are ejected from the nozzle 21.
- the amount of ink applied is 100 to 500 pl per pixel.
- a plurality of droplets may be ejected from one nozzle to one pixel, thereby supplying a necessary amount of ink.
- the ejected ink droplets land on the line area 12. As described above, there are two or more pixel regions 13 in the line region 12, but a droplet that has landed on one pixel region can move (wet spread) to an adjacent pixel region. Since it can move between the pixel regions, the thickness of the entire coating film formed in the line region 12 is made uniform (see FIG. 10).
- the amount of liquid droplets ejected from the nozzles 21 of the inkjet head 20 may vary from nozzle to nozzle.
- the thickness of the coating film is made uniform (leveling) in the line region 12, even if there is a difference in the amount of droplets from the nozzle 21, the coating film in the line region 12 is formed. It becomes uniform.
- the inkjet head 20 When ejection of ink droplets onto one line region 12 is completed, the inkjet head 20 is further moved relative to the nozzle 21 of the inkjet head 20 to the next line region 12 where ink droplets are to be ejected. (See FIG. 5). Normally, the R ink, the G ink, and the B ink are applied in different scans, so that ink droplets are ejected every three line regions. When the nozzle 21 reaches the desired line area 12, the ink droplet is ejected again to land on the line area 12. By repeating this, ink is applied to all the line regions 12 to which the ink is to be applied (see FIG. 6).
- the line direction of the line bank of the organic EL display of the present invention may be parallel to the short axis direction of the display, or may be parallel to the long axis direction. If the line direction of the line bank is parallel to the minor axis, the scanning inkjet head can be downsized. Further, even if slight light emission unevenness occurs due to nozzle variation, the light emission unevenness is not noticeable because it is light unevenness in a small area. On the other hand, if the line direction of the line bank is parallel to the major axis, the scanning distance of the inkjet head is shortened, so that the application can be completed in a short time, the productivity is improved, and the drying unevenness during the application is reduced. Can be suppressed.
- the relative movement speed for example, the conveyance speed of the substrate
- the relative movement speed is lowered to ensure that the liquid droplets ejected from the nozzle land on the line area.
- the relative movement speed when discharging droplets is preferably 50 mm / s to 300 mm / s; the relative movement speed when droplets are not discharged (preferably Is not particularly limited, but is, for example, 400 mm / s or more.
- the line region 12 is unevenly distributed in front of the substrate transport direction (backward in the moving direction of the inkjet head), and the ink The droplet 14 may be landed.
- the ink that is unevenly distributed in the front of the substrate transport direction naturally spreads backward in the transport direction by the wind pressure generated by the transport of the substrate, and can form the coating film 16 (FIG. 8C).
- the substrate after coating, the substrate itself may be tilted so that the front in the substrate transport direction is up.
- the surface tension (wetting property) of the line bank 11 may be used.
- the surface of the bank 12 in the bank line-shaped bank 11a in the transport direction (see the arrow) of the substrate 10 and the region 12 side of the line bank 11b in the transport direction of the substrate 10 If the wettability of the surface is the same, the ink droplets that have landed forward in the substrate transport direction do not spread uniformly, and the thickness of the organic light emitting layer 15 is difficult to be uniform as shown in FIG. 9B. .
- the area closer to the area 12 side of the line-shaped bank 11 a in front of the substrate transport direction is located behind the substrate transport direction. If the wettability of the surface 30 on the region 12 side of the line-shaped bank 11b is made high, the ink can spread over the entire line region 12 even if ink droplets are landed in front of the substrate transport direction. As a result, as shown in FIG. 9D, the organic light emitting layer 15 having a uniform film thickness is obtained.
- the standby After the ink is ejected to the line region (including a plurality of pixel regions), it is preferable to wait until the thickness of the ink coating film becomes uniform (leveling), and then remove the solvent of the ink. .
- the standby may be left in the air or in an inert gas atmosphere.
- the waiting time mainly depends on the viscosity of the ink and the surface tension of the ink with respect to the applied area.
- the viscosity of the ink containing the organic light emitting material applied by the ink jet apparatus is about 5 to 20 cps.
- the surface tension of the ink with respect to the area to be applied is 20 to 40 dyn / cm.
- FIG. 10 A state in which the coating film 16 having a variation of ⁇ 100% is formed in this region is defined as an initial state (FIG. 10A).
- the vertical axis represents the time (seconds) required for leveling; the horizontal axis represents the viscosity (cps) of the ink constituting the coating film.
- the plot of ⁇ is when the surface tension of the coated area is 20 dyn / cm; the plot of ⁇ is when the surface tension of the coated area is 30 dyn / cm; the plot of ⁇ is when the surface tension of the coated area is 40 dyn / cm The results are shown.
- the waiting time may be affected by the evaporation of the solvent from the coating film, so it is adjusted according to the actual conditions.
- the solvent is removed from the leveled coating film in a high temperature environment or a reduced pressure environment for the entire display substrate (drying process). Thereby, an organic light emitting layer is formed. In this way, an organic light emitting layer with high thickness uniformity is formed in each line region, and variations in the thickness of the organic light emitting layer for each line region are reduced.
- an electron injecting and transporting layer After forming the organic light emitting layer, an electron injecting and transporting layer, a counter electrode (generally a cathode electrode), etc. are laminated to form an organic electroluminescent device, and a sealing film or a glass substrate is further arranged to display the display. To manufacture.
- the material of the cathode electrode layer differs depending on whether it is a bottom emission type or a top emission type.
- the cathode electrode In the case of the top emission type, since the cathode electrode needs to be transparent, it is preferable to form an ITO electrode or an IZO electrode.
- a buffer layer or the like is preferably formed between the organic light emitting layer and the cathode electrode layer.
- the cathode electrode does not need to be transparent, and an electrode made of any material may be used.
- the cathode electrode only needs to be formed on the organic light emitting layer disposed in each pixel region, but may be formed so as to cover all the pixels included in one line region.
- the cathode electrode is usually formed by sputtering or vapor deposition. Furthermore, the cathode electrode may not be separated for each line region. In other words, if the anode electrode is controlled independently for each pixel electrode as in the active matrix type, the TFT element that drives the pixel electrode is independent, so that the cathode electrode can be shared by a plurality of line regions. it can.
- the organic EL display panel of the present invention may be sealed by providing a cover material on the surface on which the cathode electrode is further formed.
- the cover material prevents entry of moisture and oxygen.
- the organic EL display panel of the present invention can be manufactured by the above-described method, but may have a structural feature in the relationship between the organic light emitting layer applied and formed in the line region and the line bank.
- the first feature of the organic EL display panel of the present invention is that the height of the contact point between the organic light emitting layer disposed in each line region and the line bank is constant in the line direction.
- the thickness of the organic light emitting layer 15 is constant in the line direction. That is, the cross section at AA (FIG. 12-2) and the cross section at BB (FIG. 12) of the organic light emitting layer 15 formed in each line region (line region X, Y, or Z) in FIG. -3) and the cross section taken along the line CC (FIG. 12-4) are substantially the same; the contact height between the organic light emitting layer 15 and the line bank 111 is constant in the line direction.
- the constant height means that the difference between the minimum height and the maximum height is within 20%, preferably within 10% of the film thickness at the pixel center of the organic light emitting layer. This is because according to the method of the present invention, there is no significant difference in the drying environment of the coating liquid in one line region.
- the organic light emitting layer formed by providing the coating solution along the line direction of the line bank has a height of the contact point between the organic light emitting layer and the line bank in one line region.
- the cross section (FIG. 13-3) and the cross section at C′-C ′ (FIG. 13-4) are not constant, and the variation becomes large.
- the cross section at A ′ rides on the side of the right bank 111; the cross section at C ′ does not run on the side of the bank 111.
- the coating liquid is provided along the line direction, such a variation occurs because a large difference occurs in the drying environment of the coating liquid in one line region.
- An organic EL display panel having a bank may gradually deteriorate in long-term use.
- One of the causes of this deterioration is considered to be that the effluent from the bank acts on the organic light emitting layer.
- the effluent from the bank is, for example, an organic substance containing moisture and hydroxyl groups. It is considered that the degree of deterioration of the organic light emitting layer due to the effluent from the bank is affected by the positional relationship between the organic light emitting layer and the bank.
- the distance between adjacent pixels in each line area is very short. Therefore, if a difference occurs in the degree of deterioration of the pixel and a difference in light emission characteristics, it is easy to visually recognize the light emission unevenness of the display.
- the height of the contact between the organic light emitting layer and the line bank can be constant for each line region. Accordingly, the degree of long-term deterioration of the organic light emitting elements included in one line region can be the same. Therefore, uneven light emission of the display can be suppressed even with long-term use.
- the second feature of the organic EL display panel according to the present invention is that the height of the contact point between the organic light emitting layer formed in the line region arranged at one end of the display panel and the line bank is the other of the display panel. It is higher than the height of the contact of the organic light emitting layer formed in the line area
- the drying rate of the coating solution applied to the line region X at the end (right side) where coating of the substrate 100 is started is fast, and the organic light emitting layer 15 formed by drying is It tends to swell on the side surface of the bank 111 (see FIGS. 12-2 to 12-4).
- the drying speed of the coating liquid applied to the line region Z at the end (left side) opposite to the side on which the coating of the substrate 100 is started is slow, the formed organic light emitting layer 15 It is hard to get excited.
- the film thickness profile of the organic light-emitting layer of each pixel not only affects the light emission characteristics, but the heat generation characteristics may be different even if the film thickness profile is not visible as the light emission characteristics. .
- the organic light emitting layer 15 formed in the line region X arranged at one end (the side where coating is started) in FIG. 12A tends to have a large film thickness distribution. Therefore, the amount of heat generated by the organic light emitting element in the line region X is relatively large.
- the organic light emitting layer 15 formed in the line region Z disposed at the other end of the display panel has a suppressed film thickness distribution, the amount of heat generated by the organic light emitting element 15 in the line region Z is relatively small. Become.
- the can sealing structure is a structure in which a sealing can is placed on a display substrate on which an organic light emitting element is formed to protect the organic light emitting element from the external environment.
- heat tends to stay inside the sealed can, but if a heat flow is generated inside the sealed can, the heat distribution is made uniform by convection.
- moisture and oxygen gas existing inside the sealing can move due to the flow of heat, if an adsorbent that adsorbs moisture and oxygen gas is placed downstream of the flow, moisture and oxygen can be efficiently Oxygen gas can also be removed.
- the third feature of the organic EL display of the present invention is that the film thickness profiles in the line direction of the organic light emitting layers formed in the respective line regions are similar to each other. That is, as shown in FIG. 14A, all the organic light emitting layers 15 formed in the line region are relatively thick at one position (G) in the line direction; In H), it becomes relatively thin (see FIGS. 14-2 to 14-4).
- 14-2 is a sectional view taken along the line DD of FIG. 14-1;
- FIG. 14-3 is a sectional view taken along the line EE of FIG. 14-1;
- the nozzle size of the inkjet head varies and is not necessarily constant.
- the coating method of the present invention droplets are simultaneously dropped onto one entire line area, and the thickness of the coating film is made uniform (leveling), so the thickness of the organic light emitting layer is uniform over the entire line area. It becomes.
- the thickness of the organic light-emitting layer reflects the variation in nozzle size, variation in nozzle temperature, variation in the drying state of the nozzle, etc., as long as the emission characteristics are not affected. Occurs.
- the thickness distribution in the line direction of the organic light emitting layer in any line region is similar (FIGS. 14-2 to 14-). 4). That is, the position of the thickest part or the thinnest part of the organic light emitting layer in each line region matches in the line direction or falls within the range of 2 to 8 times the nozzle pitch. Therefore, even when stress is applied so that the display warps in the line direction (bends about an axis perpendicular to the line direction), the deformation in the thickness direction of each line region matches, resulting in damage to the organic light emitting layer. Is suppressed.
- the film thickness profile in the line direction of the organic light-emitting layer 15 formed by supplying the coating solution along the line direction of the line-shaped bank is different for each line region.
- 15-2 is the D′-D ′ cross section of FIG. 15-1
- FIG. 15-3 is the E′-E ′ cross section of FIG. 15-1
- -1 is the F′-F ′ cross section (FIG. 15-4), but the film thickness profile of any organic light emitting layer 15 is also different.
- the organic EL display panel can be a flexible display (for example, a roll display or a foldable display).
- a method of using the flexible display for example, it is conceivable to bend it with the line direction of the line bank as an axis.
- the thickness profile of the organic light emitting layer in one line region is specifically different from the thickness profile of the organic light emitting layer in the other line region when bent along the line direction, The organic light emitting layer is easily destroyed.
- the method of applying along the line direction of the line bank since the organic light emitting layer having a different thickness profile may be formed due to the nozzle variation of the ink jet, the entire organic light emitting layer is destroyed. . As a result, the quality as a display cannot be ensured.
- the coating liquid applied to the line region is made uniform, so that it is difficult to form organic light emitting layers having different thickness profiles.
- the thickness profile in the line direction of the organic light emitting layer in each line region is similar. Therefore, a portion having a specific thickness of the organic light emitting layer can be formed along a line perpendicular to the line direction, but is not easily broken by bending with the line direction as an axis.
- the line bank of the organic EL display of the present invention may be formed by a photolithography method, or may be formed by a printing method.
- Examples of the printing method include a gravure offset printing method.
- a bank material for example, a resin material
- a cylinder is transferred to a substrate 100, whereby the line bank 111 is formed.
- the line banks 111 formed by the printing method have the same shape precisely in the line direction. That is, the shape variation in the line direction is the same for any line bank 111.
- the variation of the line bank is less likely to be reflected in the shape profile of the organic light emitting layer due to the leveling of the coating liquid.
- the variation of the line bank is not improved. Not only is it easily reflected in the shape profile; there is a possibility that the variation in the nozzles of the inkjet head and the shape variation in the line direction of the line bank synergize.
- the organic EL display panel of the present invention may be provided with a color filter for each pixel in order to increase color purity.
- the color filter is composed of a colored layer disposed between adjacent line banks. Even when the colored layer of the color filter is formed by an ink jet method, unevenness in the color filter may occur due to variations in the nozzles of the ink jet head. Therefore, as in the present invention, when the organic light emitting layer is formed by providing a coating solution along the direction perpendicular to the line direction of the line bank, the color filter is applied along the line direction of the line bank. Preferably, it is formed by providing a liquid. This is in order to suppress synergies between the mutual variations.
- the colored layer of the color filter may be continuously applied along the line region with a dispenser or the like. Also in this case, it is preferable to apply and form the organic light emitting layer in the vertical direction of the line bank so that the mutual variations do not synergize.
- the cathode electrode of the organic EL display of the present invention may be formed by sputtering.
- ITO which is a transparent electrode
- the sputtering film formation can be performed, for example, by a magnetron sputtering apparatus, and a member for which a cathode electrode is to be formed (a display substrate on which an organic light emitting element having no cathode electrode formed thereon) is conveyed and passed through the sputtering region. . Since the environment of the sputtering region is not necessarily uniform (there is variation), a slight unevenness can occur in the film obtained by sputtering along the transport direction.
- the cathode electrode is formed by sputtering as shown in FIG.
- the cathode electrodes of all organic light emitting pixels may be made conductive.
- the coverage is increased and the deposited cathode is prevented from being thinned or cut in the bank portion, and the cathode electrode Conductivity can be increased.
- the organic EL display of the present invention may have a sealing resin layer for sealing the organic light emitting element formed on the substrate.
- a sealing resin is applied to a display substrate on which the organic light emitting element is formed; a sealing substrate (glass substrate) is superposed on and adhered to the display substrate.
- the sealing resin may be filled in the gap between the sealing substrate and the sealing substrate.
- the organic light emitting layer of the organic EL display of the present invention is formed by providing the coating liquid along the direction perpendicular to the line direction of the line-shaped bank, and therefore, uneven stripes in the line direction are unlikely to occur. Therefore, uneven light emission due to the unevenness of the sealing resin described above can be suppressed.
- the organic light emitting layer formed by providing the coating solution along the line direction of the line-shaped bank is likely to generate stripes in the line direction. Therefore, there is a possibility that uneven light emission may be emphasized in synergy with the above-described sealing resin stripe unevenness.
- the production method of the present invention provides a high-quality organic EL display free from stripes.
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Abstract
Description
1)インクジェット装置のインクジェットヘッド120を、ディスプレイ基板100のライン状バンク111のライン方向に対する上部(または下部)に配置し(このとき好ましくは、ライン状バンク111のライン方向と、ノズル121の配列方向とが垂直になるように配置し)、
2)インクジェットヘッド120をライン状バンク111のライン方向と平行に相対移動させながら(つまり、基板100を矢印方向に搬送しながら)、
3)ライン状バンク111で規定されたライン領域110に、ノズル121から液滴を吐出して、有機発光層を形成していた。
[1]基板と、前記基板に配置され、互いに平行な2以上のライン状バンクと、前記ライン状バンクで規定されたライン領域に配置された2以上のピクセル領域と、を有するディスプレイ基板を準備するステップと、
所定のピッチで、列状に配列された2以上のノズルを有し、有機発光材料を含有するインクを供給されるインクジェットヘッドを、前記ライン状バンクのライン方向に対する側部に配置するステップと、
前記インクジェットヘッドを、前記ライン状バンクのライン方向に対して垂直方向に相対移動させて、前記ライン状バンクで規定されたライン領域毎に、前記インクを前記ノズルから吐出して塗布するステップと、
を含む、有機ELディスプレイの製造方法。
[3] 前記インクジェットヘッドに配置されたノズルのうち、一方の端にあるノズルから、もう一方の端にあるノズルまでの距離は、基板のライン領域のライン方向の長さと同じか、またはそれ以上である、[1]に記載の製造方法。
前記ノズルから、前記ライン状バンクで規定されたライン領域に前記インクを吐出している間の前記相対移動速度は、前記インクを吐出していない間の前記相対移動速度よりも低い、[1]に記載の製造方法。
[5]前記ノズルから吐出されたインクは、前記ライン状バンクで規定されたライン領域のうち、前記インクジェットヘッドに対する前記ディスプレイ基板の移動方向の前方に偏って着弾する、[1]に記載の製造方法。
[6]前記領域を規定する、互いに隣接するライン状バンクのうち、
前記インクジェットヘッドに対する前記ディスプレイ基板の移動方向の前方のライン状バンクの、前記領域側の表面のぬれ性は、前記インクジェットヘッドに対する前記ディスプレイ基板の移動方向の後方のライン状バンクの、前記領域側のぬれ性よりも低い、[1]に記載の製造方法。
[7]基板と、前記基板に配置され、互いに平行な複数のライン状バンクと、前記ライン状バンクで規定されたライン領域に配置された2以上のピクセル領域と、前記ピクセル領域を含むライン領域上に配置されたライン状の有機発光層と、を有する有機ELディスプレイであって、
前記ライン状の有機発光層と前記ライン状バンクとの接点の高さは、ライン方向に一定である、有機ELディスプレイ。
[8]前記ライン領域を2以上有し、前記基板の一方の端部に配置されたライン領域に配置されたライン状の有機発光層とライン状バンクとの接点の高さは、前記基板の他方の端部に配置されたライン領域に配置されたライン状の有機発光層とライン状バンクとの接点の高さよりも低い、[7]に記載の有機ELディスプレイ。
前述のように、ライン領域毎に順にインクを供給すると、ライン領域毎の塗膜厚のばらつきが低減される一方で、隣接するライン領域に誤ってインクが混入するリスクが高まる。隣接するライン領域にインクが混入すると、混色が発生して、ディスプレイとしての画質を著しく低下させる。特に、生産性を上げるために、インクジェットヘッドと基板との相対移動速度を上げると、混色の発生率が高まる。つまり図7Aに示されるように、相対移動速度が低い場合には、より確実に所望のライン領域12内に液滴が着弾するが;図7Bおよび図7Cに示されるように、相対移動速度が上がるにつれて、液滴の着弾領域が移動方向に広がるとともに、所望のライン領域12内に着弾させることも困難になる場合がある(図7C参照)。
ライン領域(複数のピクセル領域を含む)にインクが吐出された後に、インクの塗膜の厚さが均一化(レベリング)されるまで待機して、その後に、インクの溶媒を除去することが好ましい。待機は、具体的には、大気中または不活性ガス雰囲気中にて放置すればよい。
110 ライン領域
111 ライン状バンク
120 インクジェットヘッド
121 ノズル
10 基板
11 ライン状バンク
12 ライン領域
13 ピクセル領域
14 インクの液滴
15,15R,15G,15B 有機発光層
16 塗膜
17 ギャップ
20 インクジェットヘッド
21 ノズル
200 版胴
300 スパッタ領域
Claims (8)
- 基板と、前記基板に配置され、互いに平行な2以上のライン状バンクと、前記ライン状バンクで規定されたライン領域に配置された2以上のピクセル領域と、を有するディスプレイ基板を準備するステップと、
所定のピッチで、列状に配列された2以上のノズルを有し、有機発光材料を含有するインクを供給されるインクジェットヘッドを、前記ライン状バンクのライン方向に対する側部に配置するステップと、
前記インクジェットヘッドを、前記ライン状バンクのライン方向に対して垂直方向に相対移動させて、前記ライン状バンクで規定されたライン領域毎に、前記インクを前記ノズルから吐出して塗布するステップと、
を含む、有機ELディスプレイの製造方法。 - ライン状バンクで規定されたライン領域に塗布されたインクが、均一になるまで待機したのち、インクに含まれる溶媒を乾燥させるステップ、をさらに含む、請求項1に記載の製造方法。
- 前記インクジェットヘッドに配置されたノズルのうち、一方の端にあるノズルから、もう一方の端にあるノズルまでの距離は、基板のライン領域のライン方向の長さと同じか、またはそれ以上である、請求項1に記載の製造方法。
- 前記インクジェットヘッドを、前記ライン状バンクのライン方向に対して垂直方向に相対移動させる速度は一定でなく、
前記ノズルから、前記ライン状バンクで規定されたライン領域に前記インクを吐出している間の前記相対移動速度は、前記インクを吐出していない間の前記相対移動速度よりも低い、請求項1に記載の製造方法。 - 前記ノズルから吐出されたインクは、前記ライン状バンクで規定されたライン領域のうち、前記インクジェットヘッドに対する前記ディスプレイ基板の移動方向の前方に偏って着弾する、請求項1に記載の製造方法。
- 前記領域を規定する、互いに隣接するライン状バンクのうち、
前記インクジェットヘッドに対する前記ディスプレイ基板の移動方向の前方のライン状バンクの、前記領域側の表面のぬれ性は、前記インクジェットヘッドに対する前記ディスプレイ基板の移動方向の後方のライン状バンクの、前記領域側のぬれ性よりも低い、請求項1に記載の製造方法。 - 基板と、前記基板に配置され、互いに平行な複数のライン状バンクと、前記ライン状バンクで規定されたライン領域に配置された2以上のピクセル領域と、前記ピクセル領域を含むライン領域上に配置されたライン状の有機発光層と、を有する有機ELディスプレイであって、
前記ライン状の有機発光層と前記ライン状バンクとの接点の高さは、ライン方向に一定である、有機ELディスプレイ。 - 前記ライン領域を2以上有し、
前記基板の一方の端部に配置されたライン領域に配置されたライン状の有機発光層とライン状バンクとの接点の高さは、前記基板の他方の端部に配置されたライン領域に配置されたライン状の有機発光層とライン状バンクとの接点の高さよりも低い、
請求項7に記載の有機ELディスプレイ。
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2014185529A1 (ja) * | 2013-05-17 | 2014-11-20 | 住友化学株式会社 | 有機el素子、及び、有機el素子の製造方法 |
US20140363911A1 (en) * | 2011-12-15 | 2014-12-11 | Panasonic Corporation | Method for producing organic el display panel |
WO2015072063A1 (ja) * | 2013-11-12 | 2015-05-21 | 株式会社Joled | 有機el表示パネルとその製造方法及び有機el表示装置 |
JP2021056039A (ja) * | 2019-09-27 | 2021-04-08 | パナソニックIpマネジメント株式会社 | インクジェット印刷装置、それを用いて製造されたデバイス、塗膜形成ムラ検出方法、及びデバイスの製造方法 |
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Publication number | Priority date | Publication date | Assignee | Title |
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WO2010143360A1 (ja) * | 2009-06-11 | 2010-12-16 | パナソニック株式会社 | 有機elディスプレイ |
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US8211782B2 (en) * | 2009-10-23 | 2012-07-03 | Palo Alto Research Center Incorporated | Printed material constrained by well structures |
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JP5677315B2 (ja) * | 2010-10-15 | 2015-02-25 | パナソニック株式会社 | 有機発光パネルとその製造方法、および有機表示装置 |
JPWO2012098577A1 (ja) | 2011-01-19 | 2014-06-09 | パナソニック株式会社 | 有機発光素子の製造方法、有機表示パネル、有機発光装置、機能層の形成方法、インク、基板、有機発光素子、有機表示装置、および、インクジェット装置 |
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US9082732B2 (en) | 2011-12-28 | 2015-07-14 | Joled Inc. | Organic EL display panel and method for manufacturing same |
US8728858B2 (en) * | 2012-08-27 | 2014-05-20 | Universal Display Corporation | Multi-nozzle organic vapor jet printing |
KR20140033671A (ko) * | 2012-09-10 | 2014-03-19 | 삼성디스플레이 주식회사 | 유기발광 표시장치 및 그 제조 방법 |
KR102003768B1 (ko) * | 2012-11-13 | 2019-07-26 | 삼성디스플레이 주식회사 | 기상 증착 장치 및 유기 발광 표시 장치 제조 방법 |
JP6167540B2 (ja) * | 2013-02-05 | 2017-07-26 | セイコーエプソン株式会社 | 吸引装置、吸引方法、吐出装置 |
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CN104299968B (zh) * | 2014-09-22 | 2017-04-26 | 京东方科技集团股份有限公司 | 电致发光器件及其制造方法、显示基板和显示装置 |
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KR20210142031A (ko) | 2020-05-14 | 2021-11-24 | 삼성디스플레이 주식회사 | 표시 장치 |
KR20220014383A (ko) | 2020-07-24 | 2022-02-07 | 삼성디스플레이 주식회사 | 잉크젯 분사방법, 잉크젯 분사장치 및 이를 이용한 표시패널 제조방법 |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003208979A (ja) * | 2002-01-15 | 2003-07-25 | Casio Comput Co Ltd | Elパネル製造方法、elディスプレイ及び液滴噴射装置 |
JP2003266669A (ja) | 2002-03-18 | 2003-09-24 | Seiko Epson Corp | 液滴吐出装置とその描画方法、およびデバイス製造装置とデバイス製造方法並びにデバイス |
JP2004071222A (ja) * | 2002-08-02 | 2004-03-04 | Seiko Epson Corp | 材料の配置方法、膜形成装置、電子装置及びその製造方法、電気光学装置及びその製造方法、並びに電子機器 |
JP2004090621A (ja) * | 2002-07-08 | 2004-03-25 | Canon Inc | 液体吐出装置および方法、表示装置用パネルの製造装置及び製造方法 |
JP2004362818A (ja) | 2003-06-02 | 2004-12-24 | Seiko Epson Corp | 薄膜パターンの製造方法、有機電界発光素子の製造方法、カラーフィルタの製造方法、プラズマディスプレイパネルの製造方法、液晶表示パネルの製造方法及び電子機器 |
US7091660B2 (en) | 2003-01-22 | 2006-08-15 | Samsung Sdi Co., Ltd. | Polymer organic light emitting diode |
JP2007080545A (ja) | 2005-09-09 | 2007-03-29 | Toshiba Matsushita Display Technology Co Ltd | 有機el表示装置の製造方法 |
JP2008015309A (ja) | 2006-07-07 | 2008-01-24 | Toppan Printing Co Ltd | 光学素子の製造方法、カラーフィルタの製造方法及び有機エレクトロルミネッセンス素子の製造方法。 |
JP2008108570A (ja) | 2006-10-25 | 2008-05-08 | Sharp Corp | 表示装置用基板の製造方法、表示装置の製造方法、及び、吐出装置 |
JP2008141291A (ja) | 2006-11-30 | 2008-06-19 | Nippon Dempa Kogyo Co Ltd | マイクロ波フィルタ及び高周波振動子 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4075425B2 (ja) * | 2002-03-20 | 2008-04-16 | セイコーエプソン株式会社 | 有機el装置、有機el装置の製造方法、有機el装置の製造装置、及び電子機器 |
US7111755B2 (en) * | 2002-07-08 | 2006-09-26 | Canon Kabushiki Kaisha | Liquid discharge method and apparatus and display device panel manufacturing method and apparatus |
JP4311084B2 (ja) * | 2003-06-02 | 2009-08-12 | セイコーエプソン株式会社 | 薄膜パターンの製造方法、有機電界発光素子の製造方法、カラーフィルタの製造方法、プラズマディスプレイパネルの製造方法、液晶表示パネルの製造方法 |
JP2005056614A (ja) * | 2003-08-07 | 2005-03-03 | Sharp Corp | 有機エレクトロルミネッセンス素子の製造装置及びその製造方法 |
US20090160325A1 (en) * | 2003-12-16 | 2009-06-25 | Panasonic Corporation | Organic electroluminescent device and method for manufacturing the same |
US7785718B2 (en) * | 2003-12-16 | 2010-08-31 | Panasonic Corporation | Organic electroluminescent device and method for manufacturing the same |
JP4595387B2 (ja) * | 2004-05-27 | 2010-12-08 | セイコーエプソン株式会社 | 液滴吐出装置、液滴吐出方法、カラーフィルタ基板の製造方法、電気光学装置の製造方法 |
JP3925525B2 (ja) * | 2004-10-01 | 2007-06-06 | セイコーエプソン株式会社 | 液滴吐出装置、パネルの製造方法、画像表示装置および電子機器 |
JP2006139932A (ja) * | 2004-11-10 | 2006-06-01 | Pentax Corp | 有機エレクトロルミネセンス素子、および有機エレクトロルミネセンス素子の製造方法 |
JP4935152B2 (ja) * | 2005-06-24 | 2012-05-23 | セイコーエプソン株式会社 | 液滴吐出方法 |
JP2007188862A (ja) * | 2005-12-13 | 2007-07-26 | Canon Inc | 有機el発光装置およびその製造方法 |
JP2007234232A (ja) * | 2006-02-27 | 2007-09-13 | Hitachi Displays Ltd | 画像表示装置 |
US20070241665A1 (en) * | 2006-04-12 | 2007-10-18 | Matsushita Electric Industrial Co., Ltd. | Organic electroluminescent element, and manufacturing method thereof, as well as display device and exposure apparatus using the same |
US20070290604A1 (en) * | 2006-06-16 | 2007-12-20 | Matsushita Electric Industrial Co., Ltd. | Organic electroluminescent device and method of producing the same |
US7347530B2 (en) * | 2006-06-22 | 2008-03-25 | Orbotech Ltd | Inkjet printing of color filters |
JP2008020517A (ja) * | 2006-07-11 | 2008-01-31 | Dainippon Printing Co Ltd | カラーフィルタ |
US20080012480A1 (en) * | 2006-07-14 | 2008-01-17 | Matsushita Electric Industrial Co., Ltd. | Organic electroluminescent device and method for manufacturing the same |
-
2009
- 2009-05-25 US US12/668,724 patent/US7932109B2/en active Active
- 2009-05-25 WO PCT/JP2009/002300 patent/WO2009144912A1/ja active Application Filing
- 2009-05-25 CN CN2009801000504A patent/CN101766058B/zh active Active
- 2009-05-25 EP EP09754421.7A patent/EP2296442B1/en not_active Not-in-force
- 2009-05-25 KR KR1020107004148A patent/KR101037037B1/ko active IP Right Grant
- 2009-05-25 JP JP2009549732A patent/JP4604131B2/ja active Active
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003208979A (ja) * | 2002-01-15 | 2003-07-25 | Casio Comput Co Ltd | Elパネル製造方法、elディスプレイ及び液滴噴射装置 |
JP2003266669A (ja) | 2002-03-18 | 2003-09-24 | Seiko Epson Corp | 液滴吐出装置とその描画方法、およびデバイス製造装置とデバイス製造方法並びにデバイス |
JP2004090621A (ja) * | 2002-07-08 | 2004-03-25 | Canon Inc | 液体吐出装置および方法、表示装置用パネルの製造装置及び製造方法 |
JP2004071222A (ja) * | 2002-08-02 | 2004-03-04 | Seiko Epson Corp | 材料の配置方法、膜形成装置、電子装置及びその製造方法、電気光学装置及びその製造方法、並びに電子機器 |
US7091660B2 (en) | 2003-01-22 | 2006-08-15 | Samsung Sdi Co., Ltd. | Polymer organic light emitting diode |
JP2004362818A (ja) | 2003-06-02 | 2004-12-24 | Seiko Epson Corp | 薄膜パターンの製造方法、有機電界発光素子の製造方法、カラーフィルタの製造方法、プラズマディスプレイパネルの製造方法、液晶表示パネルの製造方法及び電子機器 |
JP2007080545A (ja) | 2005-09-09 | 2007-03-29 | Toshiba Matsushita Display Technology Co Ltd | 有機el表示装置の製造方法 |
JP2008015309A (ja) | 2006-07-07 | 2008-01-24 | Toppan Printing Co Ltd | 光学素子の製造方法、カラーフィルタの製造方法及び有機エレクトロルミネッセンス素子の製造方法。 |
US20080113282A1 (en) | 2006-07-07 | 2008-05-15 | Toppan Printing Co., Ltd. | Method of manufacturing an optical device, a method of manufacturing a color filter and a method of manufacturing an organic electroluminescence device |
JP2008108570A (ja) | 2006-10-25 | 2008-05-08 | Sharp Corp | 表示装置用基板の製造方法、表示装置の製造方法、及び、吐出装置 |
JP2008141291A (ja) | 2006-11-30 | 2008-06-19 | Nippon Dempa Kogyo Co Ltd | マイクロ波フィルタ及び高周波振動子 |
Non-Patent Citations (1)
Title |
---|
See also references of EP2296442A4 |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20140335639A1 (en) * | 2011-12-15 | 2014-11-13 | Panasonic Corporation | Method for producing organic el display panel |
US20140363911A1 (en) * | 2011-12-15 | 2014-12-11 | Panasonic Corporation | Method for producing organic el display panel |
WO2014185529A1 (ja) * | 2013-05-17 | 2014-11-20 | 住友化学株式会社 | 有機el素子、及び、有機el素子の製造方法 |
CN105229815A (zh) * | 2013-05-17 | 2016-01-06 | 住友化学株式会社 | 有机el元件和有机el元件的制造方法 |
JPWO2014185529A1 (ja) * | 2013-05-17 | 2017-02-23 | 住友化学株式会社 | 有機el素子、及び、有機el素子の製造方法 |
CN105229815B (zh) * | 2013-05-17 | 2017-05-10 | 住友化学株式会社 | 有机el元件和有机el元件的制造方法 |
US9929366B2 (en) | 2013-05-17 | 2018-03-27 | Sumitomo Chemical Company, Limited | Organic EL element, and organic EL element manufacturing method |
WO2015072063A1 (ja) * | 2013-11-12 | 2015-05-21 | 株式会社Joled | 有機el表示パネルとその製造方法及び有機el表示装置 |
JPWO2015072063A1 (ja) * | 2013-11-12 | 2017-03-16 | 株式会社Joled | 有機el表示パネルとその製造方法及び有機el表示装置 |
US9773848B2 (en) | 2013-11-12 | 2017-09-26 | Joled Inc. | Organic EL display panel, production method therefor, and organic EL display device |
JP2021056039A (ja) * | 2019-09-27 | 2021-04-08 | パナソニックIpマネジメント株式会社 | インクジェット印刷装置、それを用いて製造されたデバイス、塗膜形成ムラ検出方法、及びデバイスの製造方法 |
Also Published As
Publication number | Publication date |
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US7932109B2 (en) | 2011-04-26 |
EP2296442A4 (en) | 2011-08-17 |
CN101766058B (zh) | 2012-04-18 |
EP2296442A1 (en) | 2011-03-16 |
JP4604131B2 (ja) | 2010-12-22 |
KR20100047283A (ko) | 2010-05-07 |
CN101766058A (zh) | 2010-06-30 |
KR101037037B1 (ko) | 2011-05-25 |
EP2296442B1 (en) | 2016-08-31 |
JPWO2009144912A1 (ja) | 2011-10-06 |
US20110042691A1 (en) | 2011-02-24 |
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