WO2009066639A1 - ナトリウム・マンガン複合金属酸化物およびその製造方法、ならびにナトリウム二次電池 - Google Patents

ナトリウム・マンガン複合金属酸化物およびその製造方法、ならびにナトリウム二次電池 Download PDF

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Publication number
WO2009066639A1
WO2009066639A1 PCT/JP2008/070877 JP2008070877W WO2009066639A1 WO 2009066639 A1 WO2009066639 A1 WO 2009066639A1 JP 2008070877 W JP2008070877 W JP 2008070877W WO 2009066639 A1 WO2009066639 A1 WO 2009066639A1
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Prior art keywords
sodium
metal oxide
complex metal
secondary battery
manganese complex
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PCT/JP2008/070877
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English (en)
French (fr)
Inventor
Masami Makidera
Taketsugu Yamamoto
Satoru Kuze
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Sumitomo Chemical Company, Limited
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Publication date
Application filed by Sumitomo Chemical Company, Limited filed Critical Sumitomo Chemical Company, Limited
Priority to US12/743,971 priority Critical patent/US20100266900A1/en
Publication of WO2009066639A1 publication Critical patent/WO2009066639A1/ja

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Manganates manganites or permanganates
    • C01G45/1221—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof
    • C01G45/1228—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof of the type [MnO2]n-, e.g. LiMnO2, Li[MxMn1-x]O2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/76—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by a space-group or by other symmetry indications
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/411—Organic material
    • H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
    • H01M50/417—Polyolefins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/411—Organic material
    • H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
    • H01M50/423—Polyamide resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Cell Separators (AREA)

Abstract

　本発明では、稀少金属の使用量を減少させつつ、二次電池の正極活物質としての優れた性能を有する複合金属酸化物、ならびに優れた性能を有するナトリウム二次電池用正極およびナトリウム二次電池を提供する。ナトリウムのマンガンに対するモル比（Ｎａ／Ｍｎ）が０．４以上０．７以下になる量の炭酸ナトリウム（Ｎａ２ＣＯ３）と三酸化二マンガン（Ｍｎ２Ｏ３）とを含有する材料を、８５０°C以上の温度で焼成する工程を含むことを特徴とする、ナトリウム・マンガン複合金属酸化物の製造方法、ならびにこの方法によって製造されるナトリウム・マンガン複合金属酸化物とする。また、このナトリウム・マンガン複合金属酸化物を有するナトリウム二次電池用正極およびナトリウム二次電池とする。
PCT/JP2008/070877 2007-11-22 2008-11-17 ナトリウム・マンガン複合金属酸化物およびその製造方法、ならびにナトリウム二次電池 WO2009066639A1 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US12/743,971 US20100266900A1 (en) 2007-11-22 2008-11-17 Sodium-manganese mixed metal oxide, production method thereof and sodium secondary battery

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007303490A JP2009129702A (ja) 2007-11-22 2007-11-22 ナトリウム・マンガン複合金属酸化物およびその製造方法、ならびにナトリウム二次電池
JP2007-303490 2007-11-22

Publications (1)

Publication Number Publication Date
WO2009066639A1 true WO2009066639A1 (ja) 2009-05-28

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PCT/JP2008/070877 WO2009066639A1 (ja) 2007-11-22 2008-11-17 ナトリウム・マンガン複合金属酸化物およびその製造方法、ならびにナトリウム二次電池

Country Status (4)

Country Link
US (1) US20100266900A1 (ja)
JP (1) JP2009129702A (ja)
TW (1) TW200941803A (ja)
WO (1) WO2009066639A1 (ja)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109565037A (zh) * 2016-07-18 2019-04-02 宁德时代新能源科技股份有限公司 钠离子电池极片，其制备方法及含有该极片的钠离子电池
CN114604896A (zh) * 2022-03-25 2022-06-10 中南大学 一种MXene复合改性的二元锰基钠电前驱体及其制备方法

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CN102511106A (zh) * 2009-09-28 2012-06-20 住友电气工业株式会社 电池和能量系统
JP5874328B2 (ja) 2010-11-29 2016-03-02 住友化学株式会社 電極合剤ペースト、電極および非水電解質二次電池
WO2012111681A1 (ja) * 2011-02-15 2012-08-23 住友化学株式会社 ナトリウム二次電池電極およびナトリウム二次電池
KR101580731B1 (ko) * 2011-05-02 2015-12-28 도요타지도샤가부시키가이샤 비수 전해질 2차 전지
JP6109467B2 (ja) * 2011-06-28 2017-04-05 日産自動車株式会社 耐熱絶縁層付セパレータ
FR2977723B1 (fr) 2011-07-04 2013-08-16 Univ Picardie Matiere active d'electrode pour une batterie aux ions sodium
US20150333325A1 (en) 2012-11-19 2015-11-19 Iucf-Hyu(Industry-University Cooperation Foundation Hanyang University) Manufacturing method of positive active material precursor for sodium rechargeable batteries, positive active material precursor for sodium rechargeable batteries made by the same, and manufacturing method of positive active material for sodium rechargeable batteries, positive active material for sodium rechargeable batteries made by the same
WO2014077663A1 (ko) * 2012-11-19 2014-05-22 한양대학교 산학협력단 나트륨 이차전지용 양극활물질 및 이의 제조 방법
CN103840149A (zh) * 2012-11-27 2014-06-04 中国科学院物理研究所 钠离子二次电池及其用的层状含锰氧化物活性物质、正极和活性物质的制备方法
KR101613435B1 (ko) * 2014-11-26 2016-04-20 한국생산기술연구원 전극제조를 위한 Na0.44MnO2 나노로드의 제조방법 및 이를 이용한 수계 나트륨 이차전지의 제조방법
US9966629B2 (en) 2015-02-03 2018-05-08 Samsung Electronics Co., Ltd. Sodium-conducting solid electrolyte
WO2017179917A1 (ko) * 2016-04-12 2017-10-19 세종대학교산학협력단 나트륨계 전극 활물질 및 이를 포함하는 이차전지
WO2019039639A1 (ko) * 2017-08-23 2019-02-28 전자부품연구원 나트륨이온전지용 양극활물질 및 그의 제조 방법

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JP2006216508A (ja) * 2005-02-07 2006-08-17 Sanyo Electric Co Ltd 非水電解質二次電池
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JP2006216508A (ja) * 2005-02-07 2006-08-17 Sanyo Electric Co Ltd 非水電解質二次電池
WO2006101243A1 (ja) * 2005-03-23 2006-09-28 Dupont Teijin Advanced Papers (Japan) Ltd. 複合体シート、その製造方法およびそれを用いた電気電子部品
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Cited By (4)

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Publication number Priority date Publication date Assignee Title
CN109565037A (zh) * 2016-07-18 2019-04-02 宁德时代新能源科技股份有限公司 钠离子电池极片，其制备方法及含有该极片的钠离子电池
CN109565037B (zh) * 2016-07-18 2022-03-08 宁德时代新能源科技股份有限公司 钠离子电池极片，其制备方法及含有该极片的钠离子电池
CN114604896A (zh) * 2022-03-25 2022-06-10 中南大学 一种MXene复合改性的二元锰基钠电前驱体及其制备方法
CN114604896B (zh) * 2022-03-25 2023-03-10 中南大学 一种MXene复合改性的二元锰基钠电前驱体及其制备方法

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JP2009129702A (ja) 2009-06-11
US20100266900A1 (en) 2010-10-21
TW200941803A (en) 2009-10-01

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