WO2009031216A1 - シクロヘキセンの分離及び製造方法 - Google Patents

シクロヘキセンの分離及び製造方法 Download PDF

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Publication number
WO2009031216A1
WO2009031216A1 PCT/JP2007/067330 JP2007067330W WO2009031216A1 WO 2009031216 A1 WO2009031216 A1 WO 2009031216A1 JP 2007067330 W JP2007067330 W JP 2007067330W WO 2009031216 A1 WO2009031216 A1 WO 2009031216A1
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WO
WIPO (PCT)
Prior art keywords
cyclohexene
extraction solvent
production process
solvent purification
purification column
Prior art date
Application number
PCT/JP2007/067330
Other languages
English (en)
French (fr)
Inventor
Masakazu Ban
Original Assignee
Asahi Kasei Chemicals Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Kasei Chemicals Corporation filed Critical Asahi Kasei Chemicals Corporation
Priority to DE112007003647.8T priority Critical patent/DE112007003647B4/de
Priority to JP2009531054A priority patent/JP5498165B2/ja
Priority to CN2007801005227A priority patent/CN101796001B/zh
Priority to US12/676,250 priority patent/US8237005B2/en
Priority to KR1020107004179A priority patent/KR101093958B1/ko
Priority to PCT/JP2007/067330 priority patent/WO2009031216A1/ja
Priority to TW096133341A priority patent/TWI337600B/zh
Publication of WO2009031216A1 publication Critical patent/WO2009031216A1/ja

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/04—Purification; Separation; Use of additives by distillation
    • C07C7/05—Purification; Separation; Use of additives by distillation with the aid of auxiliary compounds
    • C07C7/08—Purification; Separation; Use of additives by distillation with the aid of auxiliary compounds by extractive distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/04—Purification; Separation; Use of additives by distillation
    • C07C7/05—Purification; Separation; Use of additives by distillation with the aid of auxiliary compounds
    • C07C7/06—Purification; Separation; Use of additives by distillation with the aid of auxiliary compounds by azeotropic distillation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

　（ａ）シクロヘキセン、シクロヘキサン及びベンゼンを含む混合溶液を、Ｎ，Ｎ－ジメチルアセトアミドを抽剤として蒸留分離する工程、及び（ｂ）前記工程（ａ）により、前記混合溶液からシクロヘキセン、シクロヘキサン及びベンゼンが分離された第１の塔底液の少なくとも一部を抽剤精製塔に供給し、酢酸シクロヘキシルとＮ，Ｎ－ジメチルアセトアミドとの共沸混合物を前記抽剤精製塔の塔頂から系外に抜出すと共に、前記抽剤精製塔の第２の塔底液を工程（ａ）にリサイクルする工程を含む、シクロヘキセンの分離方法を提供する。
PCT/JP2007/067330 2007-09-05 2007-09-05 シクロヘキセンの分離及び製造方法 WO2009031216A1 (ja)

Priority Applications (7)

Application Number Priority Date Filing Date Title
DE112007003647.8T DE112007003647B4 (de) 2007-09-05 2007-09-05 Verfahren zur Trennung und Herstellung von Cyclohexen
JP2009531054A JP5498165B2 (ja) 2007-09-05 2007-09-05 シクロヘキセンの分離及び製造方法
CN2007801005227A CN101796001B (zh) 2007-09-05 2007-09-05 环己烯的分离和制造方法
US12/676,250 US8237005B2 (en) 2007-09-05 2007-09-05 Method for separating and producing cyclohexene
KR1020107004179A KR101093958B1 (ko) 2007-09-05 2007-09-05 시클로헥센의 분리 및 제조 방법
PCT/JP2007/067330 WO2009031216A1 (ja) 2007-09-05 2007-09-05 シクロヘキセンの分離及び製造方法
TW096133341A TWI337600B (en) 2007-09-05 2007-09-06 A method for separating and manufacturing cyclohexene

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2007/067330 WO2009031216A1 (ja) 2007-09-05 2007-09-05 シクロヘキセンの分離及び製造方法

Publications (1)

Publication Number Publication Date
WO2009031216A1 true WO2009031216A1 (ja) 2009-03-12

Family

ID=40428539

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2007/067330 WO2009031216A1 (ja) 2007-09-05 2007-09-05 シクロヘキセンの分離及び製造方法

Country Status (7)

Country Link
US (1) US8237005B2 (ja)
JP (1) JP5498165B2 (ja)
KR (1) KR101093958B1 (ja)
CN (1) CN101796001B (ja)
DE (1) DE112007003647B4 (ja)
TW (1) TWI337600B (ja)
WO (1) WO2009031216A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013008637A1 (ja) * 2011-07-12 2013-01-17 旭化成ケミカルズ株式会社 シクロヘキサノール、シクロヘキサノールの製造方法及びアジピン酸の製造方法
CN107226770A (zh) * 2016-03-24 2017-10-03 中国石油化工股份有限公司 一种蒸馏方法及一种乙酸环己酯的生产方法和一种环己醇的生产方法
CN112661593A (zh) * 2021-02-05 2021-04-16 郑州轻工业大学 一种含离子液体混合溶剂萃取精馏分离苯、环己烯和环己烷的方法

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102134177A (zh) * 2011-02-28 2011-07-27 河北民海化工有限公司 一种萃取精馏分离环己烷和环己烯的方法
CN102617262B (zh) * 2012-02-23 2014-04-09 蓝仁水 一种环己烷-环己烯-苯分离的节能工艺方法
CN103880598B (zh) * 2012-12-20 2016-04-27 中国石油化工股份有限公司 一种联产环己醇和乙醇的方法及装置
CN103880599B (zh) * 2012-12-20 2016-03-23 中国石油化工股份有限公司 一种联产环己醇和乙醇的方法及装置
CN103664528B (zh) * 2012-09-18 2016-05-25 中国石油化工股份有限公司 一种生产环己醇的方法
CN103910603B (zh) * 2013-01-05 2015-08-26 中国石油化工股份有限公司 一种联产环己醇和乙醇的方法
CN103910602A (zh) * 2013-01-05 2014-07-09 中国石油化工股份有限公司 一种生产环己醇的方法
US9561991B2 (en) 2012-09-18 2017-02-07 China Petroleum & Chemical Corporation Process and apparatus for co-producing cyclohexanol and alkanol
CN103232342B (zh) * 2013-04-18 2014-12-10 湖南长岭石化科技开发有限公司 一种由甲苯制备乙酸甲基环己酯的方法
CN103214365B (zh) * 2013-04-18 2015-04-08 湖南长岭石化科技开发有限公司 一种由苯生产乙酸环己酯的方法
CN108083966B (zh) * 2017-12-27 2021-01-12 中国天辰工程有限公司 一种共沸精馏分离环己烯和1,3-环己二烯的方法
CN108358808B (zh) * 2018-02-28 2020-09-08 中国天辰工程有限公司 一种回收环己酮装置废油中二甲基乙酰胺的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52144649A (en) * 1976-05-26 1977-12-02 Toray Ind Inc Separation and purification of cyclohexene
JPS58164524A (ja) * 1982-03-25 1983-09-29 Asahi Chem Ind Co Ltd シクロヘキセンを分離する方法
JPH01135730A (ja) * 1987-11-24 1989-05-29 Asahi Chem Ind Co Ltd 混合溶剤によるシクロヘキセンの分離方法
JPH11228472A (ja) * 1998-02-17 1999-08-24 Mitsubishi Chemical Corp 高純度シクロヘキサノールの製造方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
EP0040016B1 (en) 1980-05-13 1984-09-12 Imperial Chemical Industries Plc Zeolite nu-3
EP0054364B1 (en) 1980-12-11 1985-04-24 Imperial Chemical Industries Plc Zeolites
DE3169606D1 (en) 1980-12-17 1985-05-02 Ici Plc Zeolites
EP0065400B1 (en) 1981-05-20 1986-03-05 Imperial Chemical Industries Plc Zeolites
JPS57200218A (en) 1981-05-20 1982-12-08 Ici Ltd Novel synthetic zeolite substance
JPS58110419A (ja) 1981-12-21 1983-07-01 Teijin Yuka Kk 結晶性アルミノシリケ−トゼオライト及びその製造方法
EP0113116B1 (en) 1982-12-30 1985-12-04 Asahi Kasei Kogyo Kabushiki Kaisha A crystalline aluminosilicate, a process for producing the same, and a catalyst comprising the crystalline aluminosilicate
JPS59128210A (ja) 1982-12-30 1984-07-24 Asahi Chem Ind Co Ltd 結晶性アルミノシリケ−ト、その製造方法及びそのアルミノシリケ−トから成るモノアルキルベンゼンのアルキル化用触媒
JP2844098B2 (ja) 1989-12-20 1999-01-06 旭化成工業株式会社 Ｚｓｍ―５微粒子体の製造法
JPH0763902B2 (ja) 1990-06-04 1995-07-12 積水化学工業株式会社 密封リング装着装置
US5069756A (en) * 1990-11-26 1991-12-03 Lloyd Berg Separation of cyclohexane from cyclohexene by azeotropic or extractive distillation
JPH0930994A (ja) 1995-07-17 1997-02-04 Mitsubishi Chem Corp シクロヘキセンの分離方法
JPH09169669A (ja) 1995-10-20 1997-06-30 Mitsubishi Chem Corp シクロヘキセンの分離方法
EP0769484B1 (en) 1995-10-20 2001-06-13 Mitsubishi Chemical Corporation Method for separating cyclohexene
JPH09165348A (ja) * 1995-12-15 1997-06-24 Mitsubishi Chem Corp シクロヘキセンの分離方法
JP4008527B2 (ja) 1997-04-02 2007-11-14 旭化成ケミカルズ株式会社 シクロオレフィンとシクロアルカンの製造方法
DE10056685A1 (de) * 2000-11-15 2002-06-06 Max Planck Gesellschaft Verfahren zur Abtrennung von mindestens einer reaktiven Komponente aus flüssigen Stoffgemischen und Vorrichtung zur Durchführung dieses Verfahrens

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52144649A (en) * 1976-05-26 1977-12-02 Toray Ind Inc Separation and purification of cyclohexene
JPS58164524A (ja) * 1982-03-25 1983-09-29 Asahi Chem Ind Co Ltd シクロヘキセンを分離する方法
JPH01135730A (ja) * 1987-11-24 1989-05-29 Asahi Chem Ind Co Ltd 混合溶剤によるシクロヘキセンの分離方法
JPH11228472A (ja) * 1998-02-17 1999-08-24 Mitsubishi Chemical Corp 高純度シクロヘキサノールの製造方法

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013008637A1 (ja) * 2011-07-12 2013-01-17 旭化成ケミカルズ株式会社 シクロヘキサノール、シクロヘキサノールの製造方法及びアジピン酸の製造方法
US9771313B2 (en) 2011-07-12 2017-09-26 Asahi Kasei Chemicals Corporation Cyclohexanol, method for producing cyclohexanol, and method for producing adipic acid
CN107226770A (zh) * 2016-03-24 2017-10-03 中国石油化工股份有限公司 一种蒸馏方法及一种乙酸环己酯的生产方法和一种环己醇的生产方法
CN112661593A (zh) * 2021-02-05 2021-04-16 郑州轻工业大学 一种含离子液体混合溶剂萃取精馏分离苯、环己烯和环己烷的方法
CN112661593B (zh) * 2021-02-05 2023-07-18 郑州轻工业大学 一种含离子液体混合溶剂萃取精馏分离苯、环己烯和环己烷的方法

Also Published As

Publication number Publication date
TWI337600B (en) 2011-02-21
DE112007003647T5 (de) 2010-10-14
CN101796001B (zh) 2013-11-13
US20100197988A1 (en) 2010-08-05
TW200911729A (en) 2009-03-16
KR20100036383A (ko) 2010-04-07
JP5498165B2 (ja) 2014-05-21
US8237005B2 (en) 2012-08-07
KR101093958B1 (ko) 2011-12-15
DE112007003647B4 (de) 2021-06-24
CN101796001A (zh) 2010-08-04
JPWO2009031216A1 (ja) 2010-12-09

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