WO2008120444A1 - ＺｎＯバリスター粉末 - Google Patents

ＺｎＯバリスター粉末 Download PDF

Info

Publication number
WO2008120444A1
WO2008120444A1 PCT/JP2008/000446 JP2008000446W WO2008120444A1 WO 2008120444 A1 WO2008120444 A1 WO 2008120444A1 JP 2008000446 W JP2008000446 W JP 2008000446W WO 2008120444 A1 WO2008120444 A1 WO 2008120444A1
Authority
WO
WIPO (PCT)
Prior art keywords
mole
terms
zno
powder
zno varistor
Prior art date
Application number
PCT/JP2008/000446
Other languages
English (en)
French (fr)
Inventor
Hideyasu Ando
Yasunori Kasuga
Original Assignee
Kabushiki Kaisha Toshiba
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kabushiki Kaisha Toshiba filed Critical Kabushiki Kaisha Toshiba
Priority to US12/529,773 priority Critical patent/US8216544B2/en
Priority to CN2008800072036A priority patent/CN101627448B/zh
Priority to EP08720332.9A priority patent/EP2124233B1/en
Publication of WO2008120444A1 publication Critical patent/WO2008120444A1/ja

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01C—RESISTORS
    • H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
    • H01C7/10—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material voltage responsive, i.e. varistors
    • H01C7/105—Varistor cores
    • H01C7/108—Metal oxide
    • H01C7/112—ZnO type
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/453—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zinc, tin, or bismuth oxides or solid solutions thereof with other oxides, e.g. zincates, stannates or bismuthates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/08—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances oxides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]

Landscapes

  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Electromagnetism (AREA)
  • Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Thermistors And Varistors (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Conductive Materials (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

本発明により、動作電圧が高く、電流－電圧非直線抵抗特性に優れたＺｎＯバリスター粉末を得る。本発明のＺｎＯバリスター粉末は、酸化亜鉛（ＺｎＯ）を主成分とし、副成分として少なくともビスマス（Ｂｉ）、コバルト（Ｃｏ）、マンガン（Ｍｎ）、アンチモン（Ｓｂ）、ニッケル（Ｎｉ）、アルミニウム（Ａｌ）をそれぞれＢｉ２Ｏ３、Ｃｏ２Ｏ３、ＭｎＯ、Ｓｂ２Ｏ３、ＮｉＯ、Ａｌ３＋に換算して、Ｂｉ２Ｏ３を０．３～１．５ｍｏｌ％、Ｃｏ２Ｏ３を０．３～２．０ｍｏｌ％、ＭｎＯを０．３～３ｍｏｌ％、Ｓｂ２Ｏ３を０．５～４ｍｏｌ％、ＮｉＯを０．５～４ｍｏｌ％、Ａｌ３＋を０．０００５～０．０２ｍｏｌ％含む。ＺｎＯの含有量が９０ｍｏｌ％以上、かさ密度が２．５ｇ／ｃｃ以上、粒度分布における５０％粒径が２０μｍ～１２０μｍの球状粉末であることが望ましい。
PCT/JP2008/000446 2007-03-05 2008-03-05 ＺｎＯバリスター粉末 WO2008120444A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US12/529,773 US8216544B2 (en) 2007-03-05 2008-03-05 ZnO varistor powder
CN2008800072036A CN101627448B (zh) 2007-03-05 2008-03-05 ZnO非线性电阻粉末
EP08720332.9A EP2124233B1 (en) 2007-03-05 2008-03-05 Zno varistor powder

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007054681A JP5150111B2 (ja) 2007-03-05 2007-03-05 ＺｎＯバリスター粉末
JP2007-054681 2007-03-05

Publications (1)

Publication Number Publication Date
WO2008120444A1 true WO2008120444A1 (ja) 2008-10-09

Family

ID=39808031

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/000446 WO2008120444A1 (ja) 2007-03-05 2008-03-05 ＺｎＯバリスター粉末

Country Status (5)

Country Link
US (1) US8216544B2 (ja)
EP (1) EP2124233B1 (ja)
JP (1) JP5150111B2 (ja)
CN (1) CN101627448B (ja)
WO (1) WO2008120444A1 (ja)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011043207A1 (ja) * 2009-10-07 2011-04-14 堺化学工業株式会社 酸化亜鉛粒子、その製造方法、放熱性フィラー、放熱性樹脂組成物、放熱性グリース及び放熱性塗料組成物
US8399092B2 (en) 2009-10-07 2013-03-19 Sakai Chemical Industry Co., Ltd. Zinc oxide particle having high bulk density, method for producing it, exoergic filler, exoergic resin composition, exoergic grease and exoergic coating composition

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110081548A1 (en) * 2009-10-07 2011-04-07 Sakai Chemical Industry Co., Ltd. Zinc oxide particle, method for producing it, exoergic filler, exoergic resin composition, exoergic grease and exoergic coating composition
WO2011136010A1 (ja) 2010-04-26 2011-11-03 堺化学工業株式会社 フィラー粒子、樹脂組成物、グリース及び塗料組成物
JP5617410B2 (ja) * 2010-07-23 2014-11-05 堺化学工業株式会社 酸化亜鉛粒子、樹脂組成物、グリース、塗料組成物及び化粧料
US8435427B2 (en) * 2010-08-26 2013-05-07 3M Innovative Properties Company Compositions having non-linear current-voltage characteristics
US20130216834A1 (en) 2010-09-13 2013-08-22 Sakai Chemical Industry Co., Ltd, Zinc oxide particles and cosmetic
JP5269064B2 (ja) * 2010-12-28 2013-08-21 株式会社東芝 非直線抵抗材料
JP5998328B2 (ja) * 2012-04-04 2016-09-28 音羽電機工業株式会社 非線形抵抗素子
JP5998329B2 (ja) * 2012-04-04 2016-09-28 音羽電機工業株式会社 非線形抵抗素子
JP6355492B2 (ja) * 2013-10-03 2018-07-11 アルパッド株式会社 複合樹脂及び電子デバイス
JP2016134605A (ja) * 2015-01-22 2016-07-25 株式会社東芝 複合樹脂及び電子デバイス
SG10201501241PA (en) * 2015-02-17 2016-09-29 Hitachi Critical Facilities Prot Pte Ltd A Varistor and Production Method Thereof
DE102016104990A1 (de) * 2016-03-17 2017-09-21 Epcos Ag Keramikmaterial, Varistor und Verfahren zum Herstellen des Keramikmaterials und des Varistors
JP6810590B2 (ja) * 2016-12-07 2021-01-06 Koa株式会社 酸化亜鉛バリスタおよびその製造方法
CN106747406A (zh) * 2017-02-14 2017-05-31 爱普科斯电子元器件(珠海保税区)有限公司 无铅高绝缘陶瓷涂层氧化锌避雷器阀片及其制备方法
CN107099093A (zh) * 2017-04-25 2017-08-29 晶锋集团股份有限公司 一种应用于电缆终端结构的聚丙烯‑三元乙丙橡胶护套管复合材料及其制备方法
CN107043535A (zh) * 2017-04-25 2017-08-15 晶锋集团股份有限公司 一种铋、锰、钴、铌掺杂的氧化锌‑聚酰亚胺复合薄膜及其制备方法
JP7169776B2 (ja) * 2018-06-06 2022-11-11 Koa株式会社 酸化亜鉛バリスタおよびその製造方法
WO2020149034A1 (ja) 2019-01-16 2020-07-23 パナソニックＩｐマネジメント株式会社 バリスタ集合体
JPWO2020170545A1 (ja) 2019-02-22 2020-08-27
CN114269710A (zh) * 2019-08-15 2022-04-01 杰富意矿物股份有限公司 氧化锌烧结体制作用氧化锌粉末及氧化锌烧结体以及它们的制造方法
CN112010644A (zh) * 2020-09-07 2020-12-01 广西新未来信息产业股份有限公司 一种能量型超高梯度氧化锌压敏电阻制造方法
CN114360829A (zh) * 2021-11-30 2022-04-15 南京先正电子股份有限公司 一种大通流容量耐潮湿电表压敏电阻器及其制备方法
CN114438464B (zh) * 2022-01-26 2023-01-31 中国科学院上海硅酸盐研究所 一种无Bi、Pr、V的氧化锌基压敏薄膜材料及其制备方法

Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04245601A (ja) * 1991-01-31 1992-09-02 Ngk Insulators Ltd 電圧非直線抵抗体
JPH04245602A (ja) * 1991-01-31 1992-09-02 Ngk Insulators Ltd 電圧非直線抵抗体
JPH04253302A (ja) * 1991-01-29 1992-09-09 Ngk Insulators Ltd 電圧非直線抵抗体
JPH05258920A (ja) * 1992-03-16 1993-10-08 Ngk Insulators Ltd 電圧非直線抵抗体の製造方法
JPH07249505A (ja) * 1994-03-08 1995-09-26 Ngk Insulators Ltd 電圧非直線抵抗体の製造方法
JPH0831615A (ja) * 1994-07-19 1996-02-02 Mitsubishi Electric Corp 電圧非直線抵抗体およびその製造方法
JPH08115805A (ja) * 1994-10-17 1996-05-07 Mitsubishi Electric Corp 電圧非直線抵抗体およびその製造方法
JPH10308303A (ja) * 1998-05-22 1998-11-17 Mitsubishi Electric Corp 電圧非直線抵抗体およびその製造方法
JPH11340009A (ja) * 1998-05-25 1999-12-10 Toshiba Corp 非直線抵抗体
JP2000503454A (ja) 1996-01-16 2000-03-21 レイケム・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング 電気応力の制御
JP2001233668A (ja) * 2000-02-24 2001-08-28 Mitsubishi Electric Corp 電圧非直線抵抗体及びそれを用いた避雷器
JP2001307909A (ja) * 2000-04-25 2001-11-02 Toshiba Corp 電流−電圧非直線抵抗体
JP2004522259A (ja) 2001-02-09 2004-07-22 タイコ・エレクトロニクス・レイケム・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング 電気絶縁体、電気応用制御材料、電気装置、設備
JP2005348596A (ja) 2004-06-04 2005-12-15 Abb Technology Ag ガス密閉型のサージ・アレスタのための動作部分
JP2007329178A (ja) * 2006-06-06 2007-12-20 Toshiba Corp 電流−電圧非直線抵抗体および避雷器
JP2007329175A (ja) * 2006-06-06 2007-12-20 Toshiba Corp 電流−電圧非直線抵抗体および避雷器
JP2007329174A (ja) * 2006-06-06 2007-12-20 Toshiba Corp 電流−電圧非直線抵抗体および避雷器

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6442803A (en) * 1987-08-11 1989-02-15 Ngk Insulators Ltd Voltage-dependent nonlinear resistor
JP2552309B2 (ja) * 1987-11-12 1996-11-13 株式会社明電舎 非直線抵抗体
FR2703349B1 (fr) * 1993-04-01 1995-06-09 France Pharmacie Centrale Poudre d'oxyde de zinc dopé, procédé de fabrication et céramique obtenue à partir de ladite poudre.
CA2211813A1 (fr) * 1997-08-13 1999-02-13 Sabin Boily Varistances a base de poudres nanocristallines produites par broyage mecanique intense

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04253302A (ja) * 1991-01-29 1992-09-09 Ngk Insulators Ltd 電圧非直線抵抗体
JPH04245602A (ja) * 1991-01-31 1992-09-02 Ngk Insulators Ltd 電圧非直線抵抗体
JPH04245601A (ja) * 1991-01-31 1992-09-02 Ngk Insulators Ltd 電圧非直線抵抗体
JPH05258920A (ja) * 1992-03-16 1993-10-08 Ngk Insulators Ltd 電圧非直線抵抗体の製造方法
JPH07249505A (ja) * 1994-03-08 1995-09-26 Ngk Insulators Ltd 電圧非直線抵抗体の製造方法
JPH0831615A (ja) * 1994-07-19 1996-02-02 Mitsubishi Electric Corp 電圧非直線抵抗体およびその製造方法
JPH08115805A (ja) * 1994-10-17 1996-05-07 Mitsubishi Electric Corp 電圧非直線抵抗体およびその製造方法
JP2000503454A (ja) 1996-01-16 2000-03-21 レイケム・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング 電気応力の制御
JPH10308303A (ja) * 1998-05-22 1998-11-17 Mitsubishi Electric Corp 電圧非直線抵抗体およびその製造方法
JPH11340009A (ja) * 1998-05-25 1999-12-10 Toshiba Corp 非直線抵抗体
JP2001233668A (ja) * 2000-02-24 2001-08-28 Mitsubishi Electric Corp 電圧非直線抵抗体及びそれを用いた避雷器
JP2001307909A (ja) * 2000-04-25 2001-11-02 Toshiba Corp 電流−電圧非直線抵抗体
JP2004522259A (ja) 2001-02-09 2004-07-22 タイコ・エレクトロニクス・レイケム・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング 電気絶縁体、電気応用制御材料、電気装置、設備
JP2005348596A (ja) 2004-06-04 2005-12-15 Abb Technology Ag ガス密閉型のサージ・アレスタのための動作部分
JP2007329178A (ja) * 2006-06-06 2007-12-20 Toshiba Corp 電流−電圧非直線抵抗体および避雷器
JP2007329175A (ja) * 2006-06-06 2007-12-20 Toshiba Corp 電流−電圧非直線抵抗体および避雷器
JP2007329174A (ja) * 2006-06-06 2007-12-20 Toshiba Corp 電流−電圧非直線抵抗体および避雷器

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
STRUMPLER ET AL.: "Smart Varistor Composites", PROCEED. 8TH CIMTEC CERAMIC CONGRESS & FORUM NEW MATERIAL SYMPOSIUM, pages 15 - 22

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011043207A1 (ja) * 2009-10-07 2011-04-14 堺化学工業株式会社 酸化亜鉛粒子、その製造方法、放熱性フィラー、放熱性樹脂組成物、放熱性グリース及び放熱性塗料組成物
JP4771027B2 (ja) * 2009-10-07 2011-09-14 堺化学工業株式会社 酸化亜鉛粒子、その製造方法、放熱性フィラー、放熱性樹脂組成物、放熱性グリース及び放熱性塗料組成物
CN102227377A (zh) * 2009-10-07 2011-10-26 堺化学工业株式会社 氧化锌颗粒、其制造方法、散热性填料、散热性树脂组合物、散热性脂膏和散热性涂料组合物
EP2409952A1 (en) * 2009-10-07 2012-01-25 Sakai Chemical Industry Co., Ltd. Zinc oxide particles, process for production of the particles, heat-dissipating filler, heat-dissipating resin composition, heat-dissipating grease, and heat-dissipating coating composition
EP2409952A4 (en) * 2009-10-07 2012-05-23 Sakai Chemical Industry Co ZINC OXIDE PARTICLES, METHOD FOR PRODUCING THESE PARTICLES, HEAT WASHING OF THE FILLER, HEAT-WASTE RESIN COMPOSITION, HEAT-WASTE GREASING GREASE, AND HEAT-DAMPING COATING COMPOSITION
US8399092B2 (en) 2009-10-07 2013-03-19 Sakai Chemical Industry Co., Ltd. Zinc oxide particle having high bulk density, method for producing it, exoergic filler, exoergic resin composition, exoergic grease and exoergic coating composition
CN102227377B (zh) * 2009-10-07 2014-01-01 堺化学工业株式会社 氧化锌颗粒、其制造方法、散热性填料、散热性树脂组合物、散热性脂膏和散热性涂料组合物

Also Published As

Publication number Publication date
EP2124233B1 (en) 2019-05-15
EP2124233A4 (en) 2018-03-28
CN101627448A (zh) 2010-01-13
US20100136337A1 (en) 2010-06-03
JP5150111B2 (ja) 2013-02-20
CN101627448B (zh) 2011-08-31
JP2008218749A (ja) 2008-09-18
US8216544B2 (en) 2012-07-10
EP2124233A1 (en) 2009-11-25

Similar Documents

Publication Publication Date Title
WO2008120444A1 (ja) ＺｎＯバリスター粉末
WO2014090584A8 (en) Bimodal lithium transition metal based oxide powder for use in a rechargeable battery
CN106986393B (zh) 高电压型钴酸锂及其制备方法
JP2015181118A5 (ja)
JP2019003955A5 (ja)
JP2011040734A (ja) 酸化亜鉛バリスタを作製するための２つの独立した処理手順を介して酸化亜鉛バリスタを製造するプロセス
WO2012039563A3 (ko) 리튬 망간계 산화물을 포함하는 양극 활물질 및 비수 전해질 이차전지
EP4354526A3 (en) Positive electrode material for lithium secondary battery, and positive electrode for lithium secondary battery, and lithium secondary battery including the same
JPS6365740B2 (ja)
JPH11340009A (ja) 非直線抵抗体
RU2011101578A (ru) Электродная проволока с перовскитным покрытием
EP2194541A3 (en) Current-voltage non-linear resistor and method of manufacture thereof
CA2699462A1 (en) Noncrystalline composite alkali metal titanate composition and friction material
EP2660901A1 (en) Flat primary battery, negative electrode mixture for flat primary battery, and method for manufacturing flat primary battery
US20050034633A1 (en) Flux compositions for sintering Ni-Zn ferrite material
EP1542298A4 (en) PRIMARY CELL WITH POSITIVE ELECTRODE MATERIAL IN COMPOUND BASED ON NICKEL
US10233123B2 (en) Varistor compositions and multilayer varistor
Zhang et al. Effect of ZnMn 2 O 4 thickness on its resistive switching characteristics
JPS621202A (ja) 電圧非直線抵抗体
JPS5821806B2 (ja) 焼結型電圧非直線抵抗体
JP2943367B2 (ja) 電圧非直線抵抗体の製造方法
JP2985559B2 (ja) バリスタ
JPH02133904A (ja) バリスタ用電極材料及びそれを用いたバリスタ
KR0153126B1 (ko) 전압 비직선 저항체 및 그 제조방법
JP3415249B2 (ja) 非直線抵抗体

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200880007203.6

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08720332

Country of ref document: EP

Kind code of ref document: A1

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
WWE Wipo information: entry into national phase

Ref document number: 2008720332

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 12529773

Country of ref document: US