WO2008096798A1 - 熱収縮性フィルム、並びにこの熱収縮性フィルムを用いた成形品、熱収縮性ラベル、およびこの成形品を用いた、またはこのラベルを装着した容器 - Google Patents

熱収縮性フィルム、並びにこの熱収縮性フィルムを用いた成形品、熱収縮性ラベル、およびこの成形品を用いた、またはこのラベルを装着した容器 Download PDF

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Publication number
WO2008096798A1
WO2008096798A1 PCT/JP2008/051975 JP2008051975W WO2008096798A1 WO 2008096798 A1 WO2008096798 A1 WO 2008096798A1 JP 2008051975 W JP2008051975 W JP 2008051975W WO 2008096798 A1 WO2008096798 A1 WO 2008096798A1
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WIPO (PCT)
Prior art keywords
resin
thermally shrinkable
shrinkable film
molded article
film
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Application number
PCT/JP2008/051975
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English (en)
French (fr)
Inventor
Takashi Hiruma
Takeyoshi Yamada
Takatoshi Muta
Original Assignee
Mitsubishi Plastics, Inc.
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Publication date
Priority claimed from JP2007079960A external-priority patent/JP5301783B2/ja
Application filed by Mitsubishi Plastics, Inc. filed Critical Mitsubishi Plastics, Inc.
Priority to KR1020097017995A priority Critical patent/KR101444490B1/ko
Priority to US12/525,884 priority patent/US8420193B2/en
Priority to EP20080710871 priority patent/EP2123699B1/en
Publication of WO2008096798A1 publication Critical patent/WO2008096798A1/ja
Priority to US13/777,033 priority patent/US9206312B2/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B53/00Shrinking wrappers, containers, or container covers during or after packaging
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/04Polyesters derived from hydroxy carboxylic acids, e.g. lactones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10Homopolymers or copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10Homopolymers or copolymers of propene
    • C08J2423/14Copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/06Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2453/00Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1328Shrinkable or shrunk [e.g., due to heat, solvent, volatile agent, restraint removal, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1328Shrinkable or shrunk [e.g., due to heat, solvent, volatile agent, restraint removal, etc.]
    • Y10T428/1331Single layer [continuous layer]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31786Of polyester [e.g., alkyd, etc.]
    • Y10T428/31797Next to addition polymer from unsaturated monomers

Abstract

ポリ乳酸系樹脂とポリオレフィン系樹脂又は軟質アクリル系樹脂とを主成分として含有し、ポリ乳酸系樹脂とポリオレフィン系樹脂又は軟質アクリル系樹脂との質量比が95/5~50/50である混合樹脂で構成し、上記ポリ乳酸系樹脂が、D-乳酸とL-乳酸との共重合体又はこの共重合体の混合樹脂であり、D-乳酸とL-乳酸のD/L比が、3/97~15/85又は85/15~97/3とし、上記ポリオレフィン系樹脂又は軟質アクリル系樹脂の振動周波数10Hz、歪み0.1%の条件で測定したときの20°Cの貯蔵弾性率(E’)を100MPa以下とし、少なくとも一方向に延伸され、かつ80°C温水中に10秒間浸漬したときのフィルムの主収縮方向の熱収縮率が20%以上とすることで、環境に対する負荷が低く、熱収縮特性、耐衝撃性、透明性、機械的特性、および収縮仕上がり性に優れ、収縮包装、収縮結束包装や収縮ラベル等の用途に適した熱収縮性フィルムを得る。
PCT/JP2008/051975 2007-02-06 2008-02-06 熱収縮性フィルム、並びにこの熱収縮性フィルムを用いた成形品、熱収縮性ラベル、およびこの成形品を用いた、またはこのラベルを装着した容器 WO2008096798A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
KR1020097017995A KR101444490B1 (ko) 2007-02-06 2008-02-06 열수축성 필름 및 이 열수축성 필름을 이용한 성형품, 열수축성 라벨, 및 이 성형품을 이용하거나 또는 이 라벨을 장착한 용기
US12/525,884 US8420193B2 (en) 2007-02-06 2008-02-06 Heat-shrinkable film, molded product and heat-shrinkable label employing the film, and container employing the molded product or having the label fitted thereon
EP20080710871 EP2123699B1 (en) 2007-02-06 2008-02-06 Thermally shrinkable film, molded article and thermally shrinkable label both using the thermally shrinkable film, and container using the molded article or having the label attached thereon
US13/777,033 US9206312B2 (en) 2007-02-06 2013-02-26 Heat-shrinkable film, molded product and heat-shrinkable label employing the film, and container employing the molded product or having the label fitted thereon

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007-026670 2007-02-06
JP2007026670 2007-02-06
JP2007079960A JP5301783B2 (ja) 2007-03-26 2007-03-26 熱収縮性フィルム、並びにこの熱収縮性フィルムを用いた成形品、熱収縮性ラベル、及びこの成形品を用いた、又はこのラベルを装着した容器
JP2007-079960 2007-03-26

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US12/525,884 A-371-Of-International US8420193B2 (en) 2007-02-06 2008-02-06 Heat-shrinkable film, molded product and heat-shrinkable label employing the film, and container employing the molded product or having the label fitted thereon
US13/777,033 Division US9206312B2 (en) 2007-02-06 2013-02-26 Heat-shrinkable film, molded product and heat-shrinkable label employing the film, and container employing the molded product or having the label fitted thereon

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WO2008096798A1 true WO2008096798A1 (ja) 2008-08-14

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PCT/JP2008/051975 WO2008096798A1 (ja) 2007-02-06 2008-02-06 熱収縮性フィルム、並びにこの熱収縮性フィルムを用いた成形品、熱収縮性ラベル、およびこの成形品を用いた、またはこのラベルを装着した容器

Country Status (5)

Country Link
US (2) US8420193B2 (ja)
EP (1) EP2123699B1 (ja)
KR (1) KR101444490B1 (ja)
TW (1) TWI406888B (ja)
WO (1) WO2008096798A1 (ja)

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JP2010180338A (ja) * 2009-02-06 2010-08-19 Achilles Corp 花卉包装用ポリ乳酸系フィルム
WO2010143318A1 (ja) * 2009-06-12 2010-12-16 東洋紡績株式会社 空洞含有熱収縮性ポリエステル系フィルム及びその製造方法

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TWI411535B (zh) * 2005-11-30 2013-10-11 Mitsubishi Plastics Inc 聚烯烴系熱收縮性薄膜,暨使用該薄膜之成形品、熱收縮性標籤及容器
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WO2008149995A1 (ja) * 2007-06-06 2008-12-11 Mitsubishi Plastics, Inc. ポリ乳酸系樹脂組成物、ポリ乳酸系フィルム、並びに該フィルムを用いた成形品、延伸フィルム、熱収縮性ラベル、及び該ラベルを装着した容器
RU2480487C2 (ru) * 2007-11-21 2013-04-27 Мицубиси Полиэстэ Филм, Инк. Полиэфирная пленка, обладающая потенциальной способностью к сжатию, и способ ее изготовления
US10753023B2 (en) 2010-08-13 2020-08-25 Kimberly-Clark Worldwide, Inc. Toughened polylactic acid fibers
US20120142854A1 (en) * 2010-12-07 2012-06-07 Bonset America Corporation Poly(Lactic Acid) Shrink Film
DE102011121243A1 (de) * 2011-12-19 2013-06-20 Huhtamaki Films Germany Gmbh & Co. Kg Eine aus biologisch abbaubaren Polymerenaufgebaute Kunststoff-Blasfolie
US8980964B2 (en) 2012-02-10 2015-03-17 Kimberly-Clark Worldwide, Inc. Renewable polyester film having a low modulus and high tensile elongation
US8975305B2 (en) 2012-02-10 2015-03-10 Kimberly-Clark Worldwide, Inc. Rigid renewable polyester compositions having a high impact strength and tensile elongation
US9040598B2 (en) 2012-02-10 2015-05-26 Kimberly-Clark Worldwide, Inc. Renewable polyester compositions having a low density
US8637130B2 (en) * 2012-02-10 2014-01-28 Kimberly-Clark Worldwide, Inc. Molded parts containing a polylactic acid composition
US10858762B2 (en) 2012-02-10 2020-12-08 Kimberly-Clark Worldwide, Inc. Renewable polyester fibers having a low density
US10329393B2 (en) 2012-12-12 2019-06-25 Eastman Chemical Company Copolysters plasticized with polymeric plasticizer for shrink film applications
US9617414B2 (en) 2013-06-20 2017-04-11 Saudi Basic Industries Corporation Polymer composition
JP5854180B1 (ja) * 2014-03-28 2016-02-09 東レ株式会社 二軸配向ポリプロピレンフィルム
KR101924475B1 (ko) 2014-08-13 2018-12-03 토요 세이칸 가부시키가이샤 폴리 유산 조성물 및 해당 조성물을 이용하여 성형되는 연신 성형 보틀
KR101642194B1 (ko) * 2014-10-13 2016-07-22 박윤희 수축 필름 및 이를 이용한 수축 포장 방법
AU2015353887B2 (en) 2014-11-26 2019-07-04 Kimberly-Clark Worldwide, Inc. Annealed porous polyolefin material
US10240009B2 (en) * 2015-03-02 2019-03-26 Fina Technology, Inc. Composites of polyethylene and polylactic acid
WO2020263496A1 (en) * 2019-06-28 2020-12-30 Rohm And Haas Company Reactive acrylic polyolefin blends
CN113429910B (zh) * 2021-07-12 2022-06-14 浙江精华科技有限公司 一种酸奶包装杯标签用胶及其生产方法

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US8420193B2 (en) 2013-04-16
US20130164468A1 (en) 2013-06-27
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