WO2008015984A1 - Composition de résine thermoplastique pour scellement de cellule solaire, feuille pour scellement de cellule solaire et cellule solaire - Google Patents
Composition de résine thermoplastique pour scellement de cellule solaire, feuille pour scellement de cellule solaire et cellule solaire Download PDFInfo
- Publication number
- WO2008015984A1 WO2008015984A1 PCT/JP2007/064808 JP2007064808W WO2008015984A1 WO 2008015984 A1 WO2008015984 A1 WO 2008015984A1 JP 2007064808 W JP2007064808 W JP 2007064808W WO 2008015984 A1 WO2008015984 A1 WO 2008015984A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- propylene
- zirconium dichloride
- methylene
- solar cell
- tert
- Prior art date
Links
- 238000007789 sealing Methods 0.000 title claims abstract description 105
- 229920005992 thermoplastic resin Polymers 0.000 title claims abstract description 59
- 239000011342 resin composition Substances 0.000 title claims abstract description 57
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 152
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 140
- 229920001155 polypropylene Polymers 0.000 claims abstract description 95
- 229920001577 copolymer Polymers 0.000 claims abstract description 59
- 239000004711 α-olefin Substances 0.000 claims abstract description 45
- 238000002844 melting Methods 0.000 claims abstract description 32
- 230000008018 melting Effects 0.000 claims abstract description 32
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims abstract description 30
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims description 51
- 125000004432 carbon atom Chemical group C* 0.000 claims description 43
- 238000004519 manufacturing process Methods 0.000 claims description 24
- 150000001336 alkenes Chemical class 0.000 claims description 18
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 17
- 150000001451 organic peroxides Chemical class 0.000 claims description 14
- 239000007822 coupling agent Substances 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- 229910052738 indium Inorganic materials 0.000 claims description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 3
- 239000000088 plastic resin Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 11
- -1 polypropylene Polymers 0.000 description 324
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 188
- 238000006116 polymerization reaction Methods 0.000 description 125
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 123
- 239000000243 solution Substances 0.000 description 85
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 84
- 229920000642 polymer Polymers 0.000 description 76
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 71
- 150000001875 compounds Chemical class 0.000 description 61
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 48
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 44
- 239000005977 Ethylene Substances 0.000 description 44
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 38
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 36
- 230000015572 biosynthetic process Effects 0.000 description 30
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 30
- 238000003786 synthesis reaction Methods 0.000 description 30
- 238000010521 absorption reaction Methods 0.000 description 28
- 239000003054 catalyst Substances 0.000 description 28
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 26
- 229910052726 zirconium Inorganic materials 0.000 description 26
- 238000012360 testing method Methods 0.000 description 24
- 239000011521 glass Substances 0.000 description 23
- 239000010410 layer Substances 0.000 description 23
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 21
- 230000000704 physical effect Effects 0.000 description 21
- 229910052782 aluminium Inorganic materials 0.000 description 20
- 238000006243 chemical reaction Methods 0.000 description 20
- 235000010210 aluminium Nutrition 0.000 description 19
- 229920005989 resin Polymers 0.000 description 19
- 239000011347 resin Substances 0.000 description 19
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 18
- 239000004743 Polypropylene Substances 0.000 description 18
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 17
- 229910052757 nitrogen Inorganic materials 0.000 description 17
- 150000002430 hydrocarbons Chemical group 0.000 description 16
- 238000005259 measurement Methods 0.000 description 16
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 16
- PYBYTLCPLACXSS-UHFFFAOYSA-L [Cl-].[Cl-].CC1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C)[Zr+2] Chemical compound [Cl-].[Cl-].CC1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C)[Zr+2] PYBYTLCPLACXSS-UHFFFAOYSA-L 0.000 description 15
- 238000011156 evaluation Methods 0.000 description 15
- 239000000178 monomer Substances 0.000 description 14
- 239000011241 protective layer Substances 0.000 description 14
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 14
- QRNCGGQYVYYPBL-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)C1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)[Zr+2] Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)C1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)[Zr+2] QRNCGGQYVYYPBL-UHFFFAOYSA-L 0.000 description 13
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 13
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 13
- 229920001038 ethylene copolymer Polymers 0.000 description 13
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 13
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 13
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 12
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 12
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 12
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 12
- 239000002904 solvent Substances 0.000 description 12
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 11
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 10
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 10
- 238000005481 NMR spectroscopy Methods 0.000 description 10
- 125000005234 alkyl aluminium group Chemical group 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 10
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 10
- 239000007789 gas Substances 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 10
- 239000001257 hydrogen Substances 0.000 description 10
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 9
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical class C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 9
- 238000000434 field desorption mass spectrometry Methods 0.000 description 9
- 150000002500 ions Chemical class 0.000 description 9
- 238000000465 moulding Methods 0.000 description 9
- 239000002685 polymerization catalyst Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 8
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 8
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 8
- 238000004132 cross linking Methods 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 125000001624 naphthyl group Chemical group 0.000 description 8
- 239000012044 organic layer Substances 0.000 description 8
- 238000010248 power generation Methods 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 238000001228 spectrum Methods 0.000 description 8
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- FCLIIKLPCZLTFC-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)(C)C=1C=C(C=2CC3=CC=C(C=C3C2C1)C(C)(C)C)[Zr+2] Chemical compound [Cl-].[Cl-].C(C)(C)(C)C=1C=C(C=2CC3=CC=C(C=C3C2C1)C(C)(C)C)[Zr+2] FCLIIKLPCZLTFC-UHFFFAOYSA-L 0.000 description 7
- 239000002734 clay mineral Substances 0.000 description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 7
- 238000010030 laminating Methods 0.000 description 7
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 7
- 239000012299 nitrogen atmosphere Substances 0.000 description 7
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadecene Natural products CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 7
- 229920006395 saturated elastomer Polymers 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 6
- 239000006087 Silane Coupling Agent Substances 0.000 description 6
- 238000007334 copolymerization reaction Methods 0.000 description 6
- VAMFXQBUQXONLZ-UHFFFAOYSA-N icos-1-ene Chemical compound CCCCCCCCCCCCCCCCCCC=C VAMFXQBUQXONLZ-UHFFFAOYSA-N 0.000 description 6
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 6
- 230000035515 penetration Effects 0.000 description 6
- 239000010703 silicon Substances 0.000 description 6
- 150000003624 transition metals Chemical group 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 5
- 230000002411 adverse Effects 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 125000004429 atom Chemical group 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000470 constituent Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 239000003999 initiator Substances 0.000 description 5
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 5
- 235000019341 magnesium sulphate Nutrition 0.000 description 5
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- UULQKRDYHGYUAL-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC2=C3C(=C4C=5C=CC=CC5CC4=C21)C=CC=C3)[Zr+2] Chemical compound [Cl-].[Cl-].C1(=CC=CC2=C3C(=C4C=5C=CC=CC5CC4=C21)C=CC=C3)[Zr+2] UULQKRDYHGYUAL-UHFFFAOYSA-L 0.000 description 4
- OOCBQQVYRPQXIW-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=C1)C1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)O Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=C1)C1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)O OOCBQQVYRPQXIW-UHFFFAOYSA-L 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 4
- UHOVQNZJYSORNB-MZWXYZOWSA-N benzene-d6 Chemical compound [2H]C1=C([2H])C([2H])=C([2H])C([2H])=C1[2H] UHOVQNZJYSORNB-MZWXYZOWSA-N 0.000 description 4
- 239000004305 biphenyl Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 4
- 230000009477 glass transition Effects 0.000 description 4
- 239000003446 ligand Substances 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 229920001384 propylene homopolymer Polymers 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 4
- 239000011949 solid catalyst Substances 0.000 description 4
- 125000003944 tolyl group Chemical group 0.000 description 4
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 4
- 229940106006 1-eicosene Drugs 0.000 description 3
- FIKTURVKRGQNQD-UHFFFAOYSA-N 1-eicosene Natural products CCCCCCCCCCCCCCCCCC=CC(O)=O FIKTURVKRGQNQD-UHFFFAOYSA-N 0.000 description 3
- 238000005160 1H NMR spectroscopy Methods 0.000 description 3
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- GPXYMAZEPFBHGC-UHFFFAOYSA-L CC(C)(C)C1=C(C)C=C(CC2=C3C=C(C(C)(C)C)C(C)=C2[Zr+2](C2=CCCC2)=C)C3=C1.[Cl-].[Cl-] Chemical compound CC(C)(C)C1=C(C)C=C(CC2=C3C=C(C(C)(C)C)C(C)=C2[Zr+2](C2=CCCC2)=C)C3=C1.[Cl-].[Cl-] GPXYMAZEPFBHGC-UHFFFAOYSA-L 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- PUTGAFLYCXQGPO-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)(C)C1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C(C)(C)C)[Zr+2] Chemical compound [Cl-].[Cl-].C(C)(C)(C)C1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C(C)(C)C)[Zr+2] PUTGAFLYCXQGPO-UHFFFAOYSA-L 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 244000309464 bull Species 0.000 description 3
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 3
- 238000004440 column chromatography Methods 0.000 description 3
- PWAPCRSSMCLZHG-UHFFFAOYSA-N cyclopentylidene Chemical group [C]1CCCC1 PWAPCRSSMCLZHG-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 238000010559 graft polymerization reaction Methods 0.000 description 3
- 229910052735 hafnium Inorganic materials 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 150000002484 inorganic compounds Chemical class 0.000 description 3
- 229910001502 inorganic halide Inorganic materials 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 239000004611 light stabiliser Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 3
- 229920005604 random copolymer Polymers 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- CYSGHNMQYZDMIA-UHFFFAOYSA-N 1,3-Dimethyl-2-imidazolidinon Chemical compound CN1CCN(C)C1=O CYSGHNMQYZDMIA-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- GSMZLBOYBDRGBN-UHFFFAOYSA-N 2-fluoro-2-methylpropane Chemical compound CC(C)(C)F GSMZLBOYBDRGBN-UHFFFAOYSA-N 0.000 description 2
- 125000004179 3-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C(Cl)=C1[H] 0.000 description 2
- FPWNLURCHDRMHC-UHFFFAOYSA-N 4-chlorobiphenyl Chemical group C1=CC(Cl)=CC=C1C1=CC=CC=C1 FPWNLURCHDRMHC-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- YBKCAZWIPLRCFA-UHFFFAOYSA-L CC(C)(C)C(C=C(C(C1)=C2)C(C=C3C(C)(C)C)=C1C([Zr+2](C1=CCCC1)=C)=C3C1=CC=CC=C1)=C2C1=CC=CC=C1.[Cl-].[Cl-] Chemical compound CC(C)(C)C(C=C(C(C1)=C2)C(C=C3C(C)(C)C)=C1C([Zr+2](C1=CCCC1)=C)=C3C1=CC=CC=C1)=C2C1=CC=CC=C1.[Cl-].[Cl-] YBKCAZWIPLRCFA-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RWNKSTSCBHKHTB-UHFFFAOYSA-N Hexachloro-1,3-butadiene Chemical compound ClC(Cl)=C(Cl)C(Cl)=C(Cl)Cl RWNKSTSCBHKHTB-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- YQWWSOBITKQFBP-UHFFFAOYSA-L [Cl-].[Cl-].C=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C)C(C)(C)C)C(C)(C)C)C)C1C=CC=C1 Chemical compound [Cl-].[Cl-].C=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C)C(C)(C)C)C(C)(C)C)C)C1C=CC=C1 YQWWSOBITKQFBP-UHFFFAOYSA-L 0.000 description 2
- GBKWMQIRWIPICW-UHFFFAOYSA-L [Cl-].[Cl-].CC(CC1=C(C=2CC3=CC(=C(C=C3C2C=C1)CC1=CC=CC=C1)C)[Zr+2])C(C)CC1=CC=CC=C1 Chemical compound [Cl-].[Cl-].CC(CC1=C(C=2CC3=CC(=C(C=C3C2C=C1)CC1=CC=CC=C1)C)[Zr+2])C(C)CC1=CC=CC=C1 GBKWMQIRWIPICW-UHFFFAOYSA-L 0.000 description 2
- FNYSKFYSOWLLMF-UHFFFAOYSA-L [Cl-].[Cl-].CC(CC1=C(C=2CC3=CC(=C(C=C3C=2C=C1)C(C)(C)C1=CC=CC=C1)C)[Zr+2])C(C)C(C)(C)C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].CC(CC1=C(C=2CC3=CC(=C(C=C3C=2C=C1)C(C)(C)C1=CC=CC=C1)C)[Zr+2])C(C)C(C)(C)C1=CC=CC=C1 FNYSKFYSOWLLMF-UHFFFAOYSA-L 0.000 description 2
- PVKLOYWYVVWJTO-UHFFFAOYSA-L [Cl-].[Cl-].CC(CC1=C(C=2CC3=CC(=C(C=C3C=2C=C1)C)C)[Zr+2])C(C)C Chemical compound [Cl-].[Cl-].CC(CC1=C(C=2CC3=CC(=C(C=C3C=2C=C1)C)C)[Zr+2])C(C)C PVKLOYWYVVWJTO-UHFFFAOYSA-L 0.000 description 2
- OXKGVRBMFJHEAG-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C=CC(C)(C)C=1C=C2C=3C(=C(C(=C(C3CC2=CC1C)O)C)C(C)(C)C)C1C=CC=C1 Chemical compound [Cl-].[Cl-].[Zr+2].C=CC(C)(C)C=1C=C2C=3C(=C(C(=C(C3CC2=CC1C)O)C)C(C)(C)C)C1C=CC=C1 OXKGVRBMFJHEAG-UHFFFAOYSA-L 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 229920001893 acrylonitrile styrene Polymers 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical compound CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 235000011089 carbon dioxide Nutrition 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- MXOAEAUPQDYUQM-UHFFFAOYSA-N chlorphenesin Chemical group OCC(O)COC1=CC=C(Cl)C=C1 MXOAEAUPQDYUQM-UHFFFAOYSA-N 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229960002944 cyclofenil Drugs 0.000 description 2
- FNIATMYXUPOJRW-UHFFFAOYSA-N cyclohexylidene Chemical group [C]1CCCCC1 FNIATMYXUPOJRW-UHFFFAOYSA-N 0.000 description 2
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000004049 embossing Methods 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 2
- 150000004678 hydrides Chemical class 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000005457 ice water Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 150000008040 ionic compounds Chemical class 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000007348 radical reaction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical class O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- ZIYNWDQDHKSRCE-UHFFFAOYSA-N tricyclohexylalumane Chemical compound C1CCCCC1[Al](C1CCCCC1)C1CCCCC1 ZIYNWDQDHKSRCE-UHFFFAOYSA-N 0.000 description 2
- FVQMJJQUGGVLEP-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOOC(C)(C)C FVQMJJQUGGVLEP-UHFFFAOYSA-N 0.000 description 1
- QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 description 1
- GHPYJLCQYMAXGG-WCCKRBBISA-N (2R)-2-amino-3-(2-boronoethylsulfanyl)propanoic acid hydrochloride Chemical compound Cl.N[C@@H](CSCCB(O)O)C(O)=O GHPYJLCQYMAXGG-WCCKRBBISA-N 0.000 description 1
- BLKRGXCGFRXRNQ-SNAWJCMRSA-N (z)-3-carbonoperoxoyl-4,4-dimethylpent-2-enoic acid Chemical compound OC(=O)/C=C(C(C)(C)C)\C(=O)OO BLKRGXCGFRXRNQ-SNAWJCMRSA-N 0.000 description 1
- HSLFISVKRDQEBY-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)cyclohexane Chemical compound CC(C)(C)OOC1(OOC(C)(C)C)CCCCC1 HSLFISVKRDQEBY-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- USFIDJPWNWZJEX-UHFFFAOYSA-N 1-bromo-3-[(3-bromophenyl)-cyclopenta-2,4-dien-1-ylidenemethyl]benzene Chemical compound BrC=1C=C(C=CC1)C(=C1C=CC=C1)C1=CC(=CC=C1)Br USFIDJPWNWZJEX-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- FXJUTDOWCGGCDL-UHFFFAOYSA-N 1-chloro-4-[(4-chlorophenyl)-cyclopenta-2,4-dien-1-ylidenemethyl]benzene Chemical compound C1=CC(Cl)=CC=C1C(C=1C=CC(Cl)=CC=1)=C1C=CC=C1 FXJUTDOWCGGCDL-UHFFFAOYSA-N 0.000 description 1
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 1
- ZMMYZOSYBMIWIR-UHFFFAOYSA-N 2,2,4-trimethyl-4-(2,4,4-trimethylpentan-2-ylperoxy)pentane Chemical compound CC(C)(C)CC(C)(C)OOC(C)(C)CC(C)(C)C ZMMYZOSYBMIWIR-UHFFFAOYSA-N 0.000 description 1
- SNRYPISWKNTUOS-UHFFFAOYSA-N 2,2-bis(butylperoxy)butane Chemical compound CCCCOOC(C)(CC)OOCCCC SNRYPISWKNTUOS-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- BPRYUXCVCCNUFE-UHFFFAOYSA-N 2,4,6-trimethylphenol Chemical compound CC1=CC(C)=C(O)C(C)=C1 BPRYUXCVCCNUFE-UHFFFAOYSA-N 0.000 description 1
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 1
- JWOACSMESNKGGJ-UHFFFAOYSA-N 2-ethenyl-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)C=C JWOACSMESNKGGJ-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- PHBCDAHASFSLMJ-UHFFFAOYSA-N 2-hydroxybenzotriazole Chemical class C1=CC=CC2=NN(O)N=C21 PHBCDAHASFSLMJ-UHFFFAOYSA-N 0.000 description 1
- VSYZXASVWVQEMR-UHFFFAOYSA-N 2-methylbuta-1,3-dienylalumane Chemical compound CC(=C[AlH2])C=C VSYZXASVWVQEMR-UHFFFAOYSA-N 0.000 description 1
- UVTIZRNEWKAOEM-UHFFFAOYSA-N 2-tert-butylperoxy-2-methylbutane Chemical compound CCC(C)(C)OOC(C)(C)C UVTIZRNEWKAOEM-UHFFFAOYSA-N 0.000 description 1
- BHIDMOXEDVIWII-UHFFFAOYSA-N 3-chloro-1-[(3-chloronaphthalen-1-yl)-cyclopenta-2,4-dien-1-ylidenemethyl]naphthalene Chemical compound C=12C=CC=CC2=CC(Cl)=CC=1C(C=1C2=CC=CC=C2C=C(Cl)C=1)=C1C=CC=C1 BHIDMOXEDVIWII-UHFFFAOYSA-N 0.000 description 1
- NMWSKOLWZZWHPL-UHFFFAOYSA-N 3-chlorobiphenyl Chemical group ClC1=CC=CC(C=2C=CC=CC=2)=C1 NMWSKOLWZZWHPL-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- FCQMPDWPOPCFOS-UHFFFAOYSA-N 3-tert-butylcyclopent-2-en-1-one Chemical compound CC(C)(C)C1=CC(=O)CC1 FCQMPDWPOPCFOS-UHFFFAOYSA-N 0.000 description 1
- OXGOEZHUKDEEKS-UHFFFAOYSA-N 3-tert-butylperoxy-1,1,5-trimethylcyclohexane Chemical compound CC1CC(OOC(C)(C)C)CC(C)(C)C1 OXGOEZHUKDEEKS-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- 125000004800 4-bromophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Br 0.000 description 1
- DDYBAABYDNWVPI-UHFFFAOYSA-N 4-chloronaphthalene-1-carbaldehyde Chemical compound C1=CC=C2C(Cl)=CC=C(C=O)C2=C1 DDYBAABYDNWVPI-UHFFFAOYSA-N 0.000 description 1
- ZKTLLQZEGPAYNW-UHFFFAOYSA-N 5-chloronaphthalene-1-carbaldehyde Chemical compound C1=CC=C2C(Cl)=CC=CC2=C1C=O ZKTLLQZEGPAYNW-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- NHLWSTSBEKWRFI-UHFFFAOYSA-N C(C)(C)(C)C1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C(C)(C)C)O Chemical compound C(C)(C)(C)C1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C(C)(C)C)O NHLWSTSBEKWRFI-UHFFFAOYSA-N 0.000 description 1
- WNKWHILAEFVOEX-UHFFFAOYSA-N C(C)(C)(C)C=1C(=C(C=2CC3=CC=CC=C3C2C1)O)C(C)(C)C Chemical compound C(C)(C)(C)C=1C(=C(C=2CC3=CC=CC=C3C2C1)O)C(C)(C)C WNKWHILAEFVOEX-UHFFFAOYSA-N 0.000 description 1
- CDUJMDNHYLCBJI-UHFFFAOYSA-N C(CCC)[O-].C(CCC)[Al+2].C(CCC)[O-].C(CCC)[O-].C(CCC)[Al+2] Chemical compound C(CCC)[O-].C(CCC)[Al+2].C(CCC)[O-].C(CCC)[O-].C(CCC)[Al+2] CDUJMDNHYLCBJI-UHFFFAOYSA-N 0.000 description 1
- 101150116295 CAT2 gene Proteins 0.000 description 1
- 101100326920 Caenorhabditis elegans ctl-1 gene Proteins 0.000 description 1
- 101100494773 Caenorhabditis elegans ctl-2 gene Proteins 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000723368 Conium Species 0.000 description 1
- 102100025027 E3 ubiquitin-protein ligase TRIM69 Human genes 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DDFFCYDMHCRGHM-UHFFFAOYSA-N FC(C=1C=C(C=CC1)C(=C1CCCC1)C1=CC(=CC=C1)C(F)(F)F)(F)F Chemical compound FC(C=1C=C(C=CC1)C(=C1CCCC1)C1=CC(=CC=C1)C(F)(F)F)(F)F DDFFCYDMHCRGHM-UHFFFAOYSA-N 0.000 description 1
- 101100112369 Fasciola hepatica Cat-1 gene Proteins 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- PGTKVMVZBBZCKQ-UHFFFAOYSA-N Fulvene Chemical compound C=C1C=CC=C1 PGTKVMVZBBZCKQ-UHFFFAOYSA-N 0.000 description 1
- 101000830203 Homo sapiens E3 ubiquitin-protein ligase TRIM69 Proteins 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 101100005271 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) cat-1 gene Proteins 0.000 description 1
- 101100126846 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) katG gene Proteins 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 241000282376 Panthera tigris Species 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052775 Thulium Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- 241000927721 Tritia Species 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- NFLQAYVYYVBUOR-UHFFFAOYSA-N [(4-tert-butyl-2-ethylcyclopenta-2,4-dien-1-ylidene)-phenylmethyl]benzene Chemical compound CCC1=CC(C(C)(C)C)=CC1=C(C=1C=CC=CC=1)C1=CC=CC=C1 NFLQAYVYYVBUOR-UHFFFAOYSA-N 0.000 description 1
- OMNDWULGWVIBMO-UHFFFAOYSA-L [Cl-].[Cl-].BrC1=CC=C(C=C1)C(=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC12)C(C)(C)C)C(C)(C)C)C1=CCCC1)C1=CC=C(C=C1)Br Chemical compound [Cl-].[Cl-].BrC1=CC=C(C=C1)C(=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC12)C(C)(C)C)C(C)(C)C)C1=CCCC1)C1=CC=C(C=C1)Br OMNDWULGWVIBMO-UHFFFAOYSA-L 0.000 description 1
- NMTKZJAVMJIBAH-UHFFFAOYSA-L [Cl-].[Cl-].BrC1=CC=C(C=C1)C(C1=CC=C(C=C1)Br)=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C)C(C)(C)C)C(C)(C)C)C)C1C=CC=C1 Chemical compound [Cl-].[Cl-].BrC1=CC=C(C=C1)C(C1=CC=C(C=C1)Br)=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C)C(C)(C)C)C(C)(C)C)C)C1C=CC=C1 NMTKZJAVMJIBAH-UHFFFAOYSA-L 0.000 description 1
- DMZXFNBMCABUPO-UHFFFAOYSA-L [Cl-].[Cl-].BrC1=CC=C(C=C1)C(C1=CC=C(C=C1)Br)=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1C=CC=C1 Chemical compound [Cl-].[Cl-].BrC1=CC=C(C=C1)C(C1=CC=C(C=C1)Br)=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1C=CC=C1 DMZXFNBMCABUPO-UHFFFAOYSA-L 0.000 description 1
- DJUGGWYVCWXPSZ-UHFFFAOYSA-L [Cl-].[Cl-].BrC=1C=C(C=CC1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C)C(C)(C)C)C(C)(C)C)C)C1=CCCC1)C1=CC(=CC=C1)Br Chemical compound [Cl-].[Cl-].BrC=1C=C(C=CC1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C)C(C)(C)C)C(C)(C)C)C)C1=CCCC1)C1=CC(=CC=C1)Br DJUGGWYVCWXPSZ-UHFFFAOYSA-L 0.000 description 1
- LUTOVZDILFNXCN-UHFFFAOYSA-L [Cl-].[Cl-].BrC=1C=C(C=CC1)C(=[Zr+2](C1=CC(=CC=2C3=CC(=CC=C3CC12)C(C)(C)C)C(C)(C)C)C1=CCCC1)C1=CC(=CC=C1)Br Chemical compound [Cl-].[Cl-].BrC=1C=C(C=CC1)C(=[Zr+2](C1=CC(=CC=2C3=CC(=CC=C3CC12)C(C)(C)C)C(C)(C)C)C1=CCCC1)C1=CC(=CC=C1)Br LUTOVZDILFNXCN-UHFFFAOYSA-L 0.000 description 1
- RHSXRCCGHVDLPN-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)(C)C1=CC=C(C=C1)C(C1=CC=C(C=C1)C(C)(C)C)=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1C=CC=C1 Chemical compound [Cl-].[Cl-].C(C)(C)(C)C1=CC=C(C=C1)C(C1=CC=C(C=C1)C(C)(C)C)=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1C=CC=C1 RHSXRCCGHVDLPN-UHFFFAOYSA-L 0.000 description 1
- YRGVATXRCVHRQQ-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)(C)C1=CC=C(C=C1)C1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C1=CC=C(C=C1)C(C)(C)C)[Zr+2] Chemical compound [Cl-].[Cl-].C(C)(C)(C)C1=CC=C(C=C1)C1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C1=CC=C(C=C1)C(C)(C)C)[Zr+2] YRGVATXRCVHRQQ-UHFFFAOYSA-L 0.000 description 1
- MVHWIFCDSKTNBK-UHFFFAOYSA-L [Cl-].[Cl-].C(C1=CC=CC=C1)C(CC1=CC=CC=C1)=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)C1=CCCC1 Chemical compound [Cl-].[Cl-].C(C1=CC=CC=C1)C(CC1=CC=CC=C1)=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)C1=CCCC1 MVHWIFCDSKTNBK-UHFFFAOYSA-L 0.000 description 1
- UMEJDFNKJFASCJ-UHFFFAOYSA-L [Cl-].[Cl-].C(C1=CC=CC=C1)C(CC1=CC=CC=C1)=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C1=CC(=CC(=C1)C)C)C(C)(C)C)C(C)(C)C)C1=CC(=CC(=C1)C)C)C1=CCCC1 Chemical compound [Cl-].[Cl-].C(C1=CC=CC=C1)C(CC1=CC=CC=C1)=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C1=CC(=CC(=C1)C)C)C(C)(C)C)C(C)(C)C)C1=CC(=CC(=C1)C)C)C1=CCCC1 UMEJDFNKJFASCJ-UHFFFAOYSA-L 0.000 description 1
- CDFQNYRVYHZKBN-UHFFFAOYSA-L [Cl-].[Cl-].C(C1=CC=CC=C1)C(CC1=CC=CC=C1)=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1C=CC=C1 Chemical compound [Cl-].[Cl-].C(C1=CC=CC=C1)C(CC1=CC=CC=C1)=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1C=CC=C1 CDFQNYRVYHZKBN-UHFFFAOYSA-L 0.000 description 1
- MJNVILYWDSVZPG-UHFFFAOYSA-L [Cl-].[Cl-].C(C1=CC=CC=C1)C(CC1=CC=CC=C1)=[Zr+2](C1=C(C=CC=2C3=CC(=C(C=C3CC1=2)C)C1=CC=CC=C1)CC(C(C)C1=CC=CC=C1)C)C1C=CC=C1 Chemical compound [Cl-].[Cl-].C(C1=CC=CC=C1)C(CC1=CC=CC=C1)=[Zr+2](C1=C(C=CC=2C3=CC(=C(C=C3CC1=2)C)C1=CC=CC=C1)CC(C(C)C1=CC=CC=C1)C)C1C=CC=C1 MJNVILYWDSVZPG-UHFFFAOYSA-L 0.000 description 1
- KBQPXRJVAISQHE-UHFFFAOYSA-L [Cl-].[Cl-].C(CCC)C(CCCC)=[Zr+2](C1=C(C=CC=2C3=CC(=C(C=C3CC12)C)C)CC(C(C)C)C)C1=CCCC1 Chemical compound [Cl-].[Cl-].C(CCC)C(CCCC)=[Zr+2](C1=C(C=CC=2C3=CC(=C(C=C3CC12)C)C)CC(C(C)C)C)C1=CCCC1 KBQPXRJVAISQHE-UHFFFAOYSA-L 0.000 description 1
- XUGSZRAMKBQDOU-UHFFFAOYSA-L [Cl-].[Cl-].C(CCC)C(CCCC)=[Zr+2](C1=C(C=CC=2C3=CC(=C(C=C3CC1=2)C)C)CC(C(C)C)C)C1C=CC=C1 Chemical compound [Cl-].[Cl-].C(CCC)C(CCCC)=[Zr+2](C1=C(C=CC=2C3=CC(=C(C=C3CC1=2)C)C)CC(C(C)C)C)C1C=CC=C1 XUGSZRAMKBQDOU-UHFFFAOYSA-L 0.000 description 1
- KHQPLPCTKXCXOQ-UHFFFAOYSA-L [Cl-].[Cl-].C(CCC)C(CCCC)=[Zr+2](C1=C(C=CC=2C3=CC(=C(C=C3CC1=2)C)C1=CC=CC=C1)CC(C(C)C1=CC=CC=C1)C)C1C=CC=C1 Chemical compound [Cl-].[Cl-].C(CCC)C(CCCC)=[Zr+2](C1=C(C=CC=2C3=CC(=C(C=C3CC1=2)C)C1=CC=CC=C1)CC(C(C)C1=CC=CC=C1)C)C1C=CC=C1 KHQPLPCTKXCXOQ-UHFFFAOYSA-L 0.000 description 1
- MEEOOGZTRYEHFA-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=C(C=C1)C(=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1=CC(=CC=C1)C(F)(F)F)C Chemical compound [Cl-].[Cl-].C1(=CC=C(C=C1)C(=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1=CC(=CC=C1)C(F)(F)F)C MEEOOGZTRYEHFA-UHFFFAOYSA-L 0.000 description 1
- SIVPLRGKWFABCD-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC2=CC=CC=C12)C1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C1=CC=CC2=CC=CC=C12)[Zr+2] Chemical compound [Cl-].[Cl-].C1(=CC=CC2=CC=CC=C12)C1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C1=CC=CC2=CC=CC=C12)[Zr+2] SIVPLRGKWFABCD-UHFFFAOYSA-L 0.000 description 1
- ALKOCKBEKNKCSK-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC2=CC=CC=C12)CC(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C)C(C)(C)C)C(C)(C)C)C)C1=CCCC1)CC1=CC=CC2=CC=CC=C12 Chemical compound [Cl-].[Cl-].C1(=CC=CC2=CC=CC=C12)CC(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C)C(C)(C)C)C(C)(C)C)C)C1=CCCC1)CC1=CC=CC2=CC=CC=C12 ALKOCKBEKNKCSK-UHFFFAOYSA-L 0.000 description 1
- TWGFTNFJRGATRN-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)C1=CCCC1)C1=CC(=CC=C1)C(F)(F)F Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)C1=CCCC1)C1=CC(=CC=C1)C(F)(F)F TWGFTNFJRGATRN-UHFFFAOYSA-L 0.000 description 1
- HCGAWMSAYVFJLP-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C)C(C)(C)C)C(C)(C)C)C)C1=CCCC1)C1=CC(=CC=C1)C(F)(F)F Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C)C(C)(C)C)C(C)(C)C)C)C1=CCCC1)C1=CC(=CC=C1)C(F)(F)F HCGAWMSAYVFJLP-UHFFFAOYSA-L 0.000 description 1
- QECHEJCQBYXFAH-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)C(C1=CC=CC=C1)=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC12)C(C)(C)C)C(C)(C)C)C1=CC(CC1CC)C(C)(C)C Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)C(C1=CC=CC=C1)=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC12)C(C)(C)C)C(C)(C)C)C1=CC(CC1CC)C(C)(C)C QECHEJCQBYXFAH-UHFFFAOYSA-L 0.000 description 1
- INJYIDNGDPLTHN-UHFFFAOYSA-L [Cl-].[Cl-].C1(CCCC1)CC(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1=CCCC1)CC1CCCC1 Chemical compound [Cl-].[Cl-].C1(CCCC1)CC(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1=CCCC1)CC1CCCC1 INJYIDNGDPLTHN-UHFFFAOYSA-L 0.000 description 1
- NHXQWLIHDMWHBG-UHFFFAOYSA-L [Cl-].[Cl-].C1(CCCCC1)=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1C=CC=C1 Chemical compound [Cl-].[Cl-].C1(CCCCC1)=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1C=CC=C1 NHXQWLIHDMWHBG-UHFFFAOYSA-L 0.000 description 1
- DBVDAZGUWOXABU-UHFFFAOYSA-L [Cl-].[Cl-].C1(CCCCC1)CC(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C)C(C)(C)C)C(C)(C)C)C)C1C=CC=C1)CC1CCCCC1 Chemical compound [Cl-].[Cl-].C1(CCCCC1)CC(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C)C(C)(C)C)C(C)(C)C)C)C1C=CC=C1)CC1CCCCC1 DBVDAZGUWOXABU-UHFFFAOYSA-L 0.000 description 1
- XTPDTUSPUFRPPB-UHFFFAOYSA-L [Cl-].[Cl-].C=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)C1=CCCC1 Chemical compound [Cl-].[Cl-].C=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)C1=CCCC1 XTPDTUSPUFRPPB-UHFFFAOYSA-L 0.000 description 1
- HZAGIPZYQVBIFN-UHFFFAOYSA-L [Cl-].[Cl-].C=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1C=CC=C1 Chemical compound [Cl-].[Cl-].C=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1C=CC=C1 HZAGIPZYQVBIFN-UHFFFAOYSA-L 0.000 description 1
- QLAYMYIMKPEOBU-UHFFFAOYSA-L [Cl-].[Cl-].C=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1 Chemical compound [Cl-].[Cl-].C=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1 QLAYMYIMKPEOBU-UHFFFAOYSA-L 0.000 description 1
- PEXPGTNMOKDTOU-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC=C(C=C1)C1=C(C=2CC3=CC(=C(C=C3C=2C=C1C(C)(C)C)C(C)(C)C)C1=CC=C(C=C1)C)[Zr+2] Chemical compound [Cl-].[Cl-].CC1=CC=C(C=C1)C1=C(C=2CC3=CC(=C(C=C3C=2C=C1C(C)(C)C)C(C)(C)C)C1=CC=C(C=C1)C)[Zr+2] PEXPGTNMOKDTOU-UHFFFAOYSA-L 0.000 description 1
- OZTISTUFHNFQLA-UHFFFAOYSA-L [Cl-].[Cl-].ClC(C1=CC=C(C=C1)C(=[Zr+2](C1=CC(=CC=2C3=CC(=CC=C3CC12)C(C)(C)C)C(C)(C)C)C1=CCCC1)C1=CC=C(C=C1)C(Cl)(Cl)Cl)(Cl)Cl Chemical compound [Cl-].[Cl-].ClC(C1=CC=C(C=C1)C(=[Zr+2](C1=CC(=CC=2C3=CC(=CC=C3CC12)C(C)(C)C)C(C)(C)C)C1=CCCC1)C1=CC=C(C=C1)C(Cl)(Cl)Cl)(Cl)Cl OZTISTUFHNFQLA-UHFFFAOYSA-L 0.000 description 1
- NIVMGDBVBDGFCY-UHFFFAOYSA-L [Cl-].[Cl-].ClC(C=1C=C(C=CC1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)C1=CCCC1)C1=CC(=CC=C1)C(Cl)(Cl)Cl)(Cl)Cl Chemical compound [Cl-].[Cl-].ClC(C=1C=C(C=CC1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)C1=CCCC1)C1=CC(=CC=C1)C(Cl)(Cl)Cl)(Cl)Cl NIVMGDBVBDGFCY-UHFFFAOYSA-L 0.000 description 1
- AFGLFUQRVZXZMN-UHFFFAOYSA-L [Cl-].[Cl-].ClC(C=1C=C(C=CC=1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C)C(C)(C)C)C(C)(C)C)C)C1C=CC=C1)C1=CC(=CC=C1)C(Cl)(Cl)Cl)(Cl)Cl Chemical compound [Cl-].[Cl-].ClC(C=1C=C(C=CC=1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C)C(C)(C)C)C(C)(C)C)C)C1C=CC=C1)C1=CC(=CC=C1)C(Cl)(Cl)Cl)(Cl)Cl AFGLFUQRVZXZMN-UHFFFAOYSA-L 0.000 description 1
- YZMKPTHABIJYJY-UHFFFAOYSA-L [Cl-].[Cl-].ClC(C=1C=C(C=CC=1)C(C1=CC(=CC=C1)C(Cl)(Cl)Cl)=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)(Cl)Cl Chemical compound [Cl-].[Cl-].ClC(C=1C=C(C=CC=1)C(C1=CC(=CC=C1)C(Cl)(Cl)Cl)=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)(Cl)Cl YZMKPTHABIJYJY-UHFFFAOYSA-L 0.000 description 1
- LVYAWYISIHYLTA-UHFFFAOYSA-L [Cl-].[Cl-].ClC1=CC=C(C2=CC=CC=C12)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C)C(C)(C)C)C(C)(C)C)C)C1C=CC=C1)C1=CC=C(C2=CC=CC=C12)Cl Chemical compound [Cl-].[Cl-].ClC1=CC=C(C2=CC=CC=C12)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C)C(C)(C)C)C(C)(C)C)C)C1C=CC=C1)C1=CC=C(C2=CC=CC=C12)Cl LVYAWYISIHYLTA-UHFFFAOYSA-L 0.000 description 1
- QSXYCYFUDHRSHW-UHFFFAOYSA-L [Cl-].[Cl-].ClC1=CC=C(C2=CC=CC=C12)C(=[Zr+2](C1=CC(=CC=2C3=CC(=CC=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1=CC=C(C2=CC=CC=C12)Cl Chemical compound [Cl-].[Cl-].ClC1=CC=C(C2=CC=CC=C12)C(=[Zr+2](C1=CC(=CC=2C3=CC(=CC=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1=CC=C(C2=CC=CC=C12)Cl QSXYCYFUDHRSHW-UHFFFAOYSA-L 0.000 description 1
- OFENMGKOHFMXPN-UHFFFAOYSA-L [Cl-].[Cl-].ClC1=CC=C(C=C1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C)C(C)(C)C)C(C)(C)C)C)C1=CCCC1)C1=CC=C(C=C1)Cl Chemical compound [Cl-].[Cl-].ClC1=CC=C(C=C1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C)C(C)(C)C)C(C)(C)C)C)C1=CCCC1)C1=CC=C(C=C1)Cl OFENMGKOHFMXPN-UHFFFAOYSA-L 0.000 description 1
- XLHIQUBQGGZSKY-UHFFFAOYSA-L [Cl-].[Cl-].ClC=1C=C(C=CC=1)C=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)C1C=CC=C1 Chemical compound [Cl-].[Cl-].ClC=1C=C(C=CC=1)C=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)C1C=CC=C1 XLHIQUBQGGZSKY-UHFFFAOYSA-L 0.000 description 1
- ZNBOCPZGEXLGGK-UHFFFAOYSA-L [Cl-].[Cl-].ClCC=1C=C(C=C(C1)CCl)C(=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC12)C(C)(C)C)C(C)(C)C)C1=CCCC1)C1=CC(=CC(=C1)CCl)CCl Chemical compound [Cl-].[Cl-].ClCC=1C=C(C=C(C1)CCl)C(=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC12)C(C)(C)C)C(C)(C)C)C1=CCCC1)C1=CC(=CC(=C1)CCl)CCl ZNBOCPZGEXLGGK-UHFFFAOYSA-L 0.000 description 1
- UKLNNIQYWGVZJH-UHFFFAOYSA-L [Cl-].[Cl-].FC(C1=CC=C(C=C1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C)C(C)(C)C)C(C)(C)C)C)C1=CCCC1)C1=CC=C(C=C1)C(F)(F)F)(F)F Chemical compound [Cl-].[Cl-].FC(C1=CC=C(C=C1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C)C(C)(C)C)C(C)(C)C)C)C1=CCCC1)C1=CC=C(C=C1)C(F)(F)F)(F)F UKLNNIQYWGVZJH-UHFFFAOYSA-L 0.000 description 1
- RJCGZSSPEBUPBH-UHFFFAOYSA-L [Cl-].[Cl-].FC(C1=CC=C(C=C1)C(C1=CC=C(C=C1)C(F)(F)F)=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)(F)F Chemical compound [Cl-].[Cl-].FC(C1=CC=C(C=C1)C(C1=CC=C(C=C1)C(F)(F)F)=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)(F)F RJCGZSSPEBUPBH-UHFFFAOYSA-L 0.000 description 1
- MREOKQLKWYDANV-UHFFFAOYSA-L [Cl-].[Cl-].FC(C=1C=C(C=C(C1)C(F)(F)F)C(=[Zr+2](C1=CC=CC2=C3C(=C4C=5C=CC=CC5CC4=C21)C=CC=C3)C3=CCCC3)C3=CC(=CC(=C3)C(F)(F)F)C(F)(F)F)(F)F Chemical compound [Cl-].[Cl-].FC(C=1C=C(C=C(C1)C(F)(F)F)C(=[Zr+2](C1=CC=CC2=C3C(=C4C=5C=CC=CC5CC4=C21)C=CC=C3)C3=CCCC3)C3=CC(=CC(=C3)C(F)(F)F)C(F)(F)F)(F)F MREOKQLKWYDANV-UHFFFAOYSA-L 0.000 description 1
- VSTRYBXJWKFAEM-UHFFFAOYSA-L [Cl-].[Cl-].FC(C=1C=C(C=C(C=1)C(F)(F)F)C(C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)=[Zr+2](C1=CC(=CC=2C3=CC(=CC=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)(F)F Chemical compound [Cl-].[Cl-].FC(C=1C=C(C=C(C=1)C(F)(F)F)C(C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)=[Zr+2](C1=CC(=CC=2C3=CC(=CC=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)(F)F VSTRYBXJWKFAEM-UHFFFAOYSA-L 0.000 description 1
- GAIZCWJSJSQOOP-UHFFFAOYSA-L [Cl-].[Cl-].FC(C=1C=C(C=CC1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C)C(C)(C)C)C(C)(C)C)C)C1=CCCC1)C1=CC(=CC=C1)C(F)(F)F)(F)F Chemical compound [Cl-].[Cl-].FC(C=1C=C(C=CC1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C)C(C)(C)C)C(C)(C)C)C)C1=CCCC1)C1=CC(=CC=C1)C(F)(F)F)(F)F GAIZCWJSJSQOOP-UHFFFAOYSA-L 0.000 description 1
- JUKWPELEXMMWPS-UHFFFAOYSA-L [Cl-].[Cl-].FC(C=1C=C(C=CC1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1=CCCC1)C1=CC(=CC=C1)C(F)(F)F)(F)F Chemical compound [Cl-].[Cl-].FC(C=1C=C(C=CC1)C(=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC12)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1=CCCC1)C1=CC(=CC=C1)C(F)(F)F)(F)F JUKWPELEXMMWPS-UHFFFAOYSA-L 0.000 description 1
- TXYQPHISCXMRGP-UHFFFAOYSA-L [Cl-].[Cl-].FC(C=1C=C(C=CC1)C(=[Zr+2](C1=CC=CC2=C3C(=C4C=5C=CC=CC5CC4=C21)C=CC=C3)C3=CCCC3)C3=CC(=CC=C3)C(F)(F)F)(F)F Chemical compound [Cl-].[Cl-].FC(C=1C=C(C=CC1)C(=[Zr+2](C1=CC=CC2=C3C(=C4C=5C=CC=CC5CC4=C21)C=CC=C3)C3=CCCC3)C3=CC(=CC=C3)C(F)(F)F)(F)F TXYQPHISCXMRGP-UHFFFAOYSA-L 0.000 description 1
- CLLYTLAPZHRHDH-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C(C)(C)(C)C1=C(C=2CC3=CC(=CC=C3C2C=C1)C(C)(C)C)O Chemical compound [Cl-].[Cl-].[Zr+2].C(C)(C)(C)C1=C(C=2CC3=CC(=CC=C3C2C=C1)C(C)(C)C)O CLLYTLAPZHRHDH-UHFFFAOYSA-L 0.000 description 1
- SVIVLIAVEMMKKO-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=C1)C(=CC(C)(C)C1=CC=C2C=3C=C(C(=C(C3CC2=C1)O)C(C)(C)C)C1=CCCC1)C1=CC(=CC=C1)C(F)(F)F Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=C1)C(=CC(C)(C)C1=CC=C2C=3C=C(C(=C(C3CC2=C1)O)C(C)(C)C)C1=CCCC1)C1=CC(=CC=C1)C(F)(F)F SVIVLIAVEMMKKO-UHFFFAOYSA-L 0.000 description 1
- OAYDGIQFQIRLHJ-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=C1)C(=CC(C)(C)C=1C=C2C=3C(=C(C(=C(C3CC2=CC1C1=CC=CC=C1)O)C1=CC=CC=C1)C(C)(C)C)C1=CCCC1)C1=CC=C(C=C1)Cl Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=C1)C(=CC(C)(C)C=1C=C2C=3C(=C(C(=C(C3CC2=CC1C1=CC=CC=C1)O)C1=CC=CC=C1)C(C)(C)C)C1=CCCC1)C1=CC=C(C=C1)Cl OAYDGIQFQIRLHJ-UHFFFAOYSA-L 0.000 description 1
- OGQVBDODZJDUOH-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C=CC(C)(C)C1=C(C=C2C=3C(=C(C(=C(C3CC2=C1)O)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C(C)(C)C Chemical compound [Cl-].[Cl-].[Zr+2].C=CC(C)(C)C1=C(C=C2C=3C(=C(C(=C(C3CC2=C1)O)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C(C)(C)C OGQVBDODZJDUOH-UHFFFAOYSA-L 0.000 description 1
- RLQCRAZPQRNVNG-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].CC=1C=C(C=C(C1)C)C1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C1=CC(=CC(=C1)C)C)O Chemical compound [Cl-].[Cl-].[Zr+2].CC=1C=C(C=C(C1)C)C1=C(C=2CC3=CC(=C(C=C3C2C=C1C(C)(C)C)C(C)(C)C)C1=CC(=CC(=C1)C)C)O RLQCRAZPQRNVNG-UHFFFAOYSA-L 0.000 description 1
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 1
- SZNWCVFYBNVQOI-UHFFFAOYSA-N [O-]CC.C(C)[Al+2].[O-]CC.[O-]CC.C(C)[Al+2] Chemical compound [O-]CC.C(C)[Al+2].[O-]CC.[O-]CC.C(C)[Al+2] SZNWCVFYBNVQOI-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Natural products CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 description 1
- SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- UORVGPXVDQYIDP-BJUDXGSMSA-N borane Chemical class [10BH3] UORVGPXVDQYIDP-BJUDXGSMSA-N 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- XGZGKDQVCBHSGI-UHFFFAOYSA-N butyl(triethoxy)silane Chemical compound CCCC[Si](OCC)(OCC)OCC XGZGKDQVCBHSGI-UHFFFAOYSA-N 0.000 description 1
- SXPLZNMUBFBFIA-UHFFFAOYSA-N butyl(trimethoxy)silane Chemical compound CCCC[Si](OC)(OC)OC SXPLZNMUBFBFIA-UHFFFAOYSA-N 0.000 description 1
- OCFSGVNHPVWWKD-UHFFFAOYSA-N butylaluminum Chemical compound [Al].[CH2]CCC OCFSGVNHPVWWKD-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- UXJMPNOASYSGLG-UHFFFAOYSA-N cyclopenta-2,4-dien-1-ylidenecycloheptane Chemical compound C1CCCCCC1=C1C=CC=C1 UXJMPNOASYSGLG-UHFFFAOYSA-N 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- CDHICTNQMQYRSM-UHFFFAOYSA-N di(propan-2-yl)alumane Chemical compound CC(C)[AlH]C(C)C CDHICTNQMQYRSM-UHFFFAOYSA-N 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- XNKVIGSNRYAOQZ-UHFFFAOYSA-N dibenzofluorene Chemical compound C12=CC=CC=C2C2=CC=CC=C2C2=C1CC1=CC=CC=C12 XNKVIGSNRYAOQZ-UHFFFAOYSA-N 0.000 description 1
- VJRUISVXILMZSL-UHFFFAOYSA-M dibutylalumanylium;chloride Chemical compound CCCC[Al](Cl)CCCC VJRUISVXILMZSL-UHFFFAOYSA-M 0.000 description 1
- VTZJFPSWNQFPCQ-UHFFFAOYSA-N dibutylaluminum Chemical compound CCCC[Al]CCCC VTZJFPSWNQFPCQ-UHFFFAOYSA-N 0.000 description 1
- ZTGOUSAYHCYNCG-UHFFFAOYSA-O dicalcium;sodium;dioxido(oxo)silane;hydron Chemical compound [H+].[Na+].[Ca+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O ZTGOUSAYHCYNCG-UHFFFAOYSA-O 0.000 description 1
- YEMLBLTUNOJCQH-UHFFFAOYSA-N diethoxy(2-methylpropyl)alumane Chemical compound CCO[Al](CC(C)C)OCC YEMLBLTUNOJCQH-UHFFFAOYSA-N 0.000 description 1
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 1
- IPZJQDSFZGZEOY-UHFFFAOYSA-N dimethylmethylene Chemical group C[C]C IPZJQDSFZGZEOY-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- AFSIMBWBBOJPJG-UHFFFAOYSA-N ethenyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC=C AFSIMBWBBOJPJG-UHFFFAOYSA-N 0.000 description 1
- HHFAWKCIHAUFRX-UHFFFAOYSA-N ethoxide Chemical compound CC[O-] HHFAWKCIHAUFRX-UHFFFAOYSA-N 0.000 description 1
- HARQWLDROVMFJE-UHFFFAOYSA-N ethyl 3,3-bis(tert-butylperoxy)butanoate Chemical compound CCOC(=O)CC(C)(OOC(C)(C)C)OOC(C)(C)C HARQWLDROVMFJE-UHFFFAOYSA-N 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000004407 fluoroaryl group Chemical group 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910001504 inorganic chloride Inorganic materials 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229920001580 isotactic polymer Polymers 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000005340 laminated glass Substances 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- NEMYBHYAISOMTI-UHFFFAOYSA-N methanolate;2-methylpropylaluminum(2+) Chemical compound [O-]C.[O-]C.CC(C)C[Al+2] NEMYBHYAISOMTI-UHFFFAOYSA-N 0.000 description 1
- BQBCXNQILNPAPX-UHFFFAOYSA-N methoxy(dimethyl)alumane Chemical compound [O-]C.C[Al+]C BQBCXNQILNPAPX-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- DZCCLNYLUGNUKQ-UHFFFAOYSA-N n-(4-nitrosophenyl)hydroxylamine Chemical compound ONC1=CC=C(N=O)C=C1 DZCCLNYLUGNUKQ-UHFFFAOYSA-N 0.000 description 1
- NLRKCXQQSUWLCH-UHFFFAOYSA-N nitrosobenzene Chemical compound O=NC1=CC=CC=C1 NLRKCXQQSUWLCH-UHFFFAOYSA-N 0.000 description 1
- IXUXXVWBRHSNJQ-UHFFFAOYSA-N nonan-5-ylidenecyclohexane Chemical compound CCCCC(CCCC)=C1CCCCC1 IXUXXVWBRHSNJQ-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 125000005474 octanoate group Chemical group 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229910052884 pectolite Inorganic materials 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical compound C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- XMGMFRIEKMMMSU-UHFFFAOYSA-N phenylmethylbenzene Chemical group C=1C=CC=CC=1[C]C1=CC=CC=C1 XMGMFRIEKMMMSU-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- OBRKWFIGZSMARO-UHFFFAOYSA-N propylalumane Chemical compound [AlH2]CCC OBRKWFIGZSMARO-UHFFFAOYSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003902 salicylic acid esters Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- NDUUEFPGQBSFPV-UHFFFAOYSA-N tri(butan-2-yl)alumane Chemical compound CCC(C)[Al](C(C)CC)C(C)CC NDUUEFPGQBSFPV-UHFFFAOYSA-N 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- OPSWAWSNPREEFQ-UHFFFAOYSA-K triphenoxyalumane Chemical compound [Al+3].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 OPSWAWSNPREEFQ-UHFFFAOYSA-K 0.000 description 1
- PJPPDDJSRORGJA-UHFFFAOYSA-K tris(2,6-ditert-butyl-4-methylphenoxy)alumane Chemical compound [Al+3].CC1=CC(C(C)(C)C)=C([O-])C(C(C)(C)C)=C1.CC1=CC(C(C)(C)C)=C([O-])C(C(C)(C)C)=C1.CC1=CC(C(C)(C)C)=C([O-])C(C(C)(C)C)=C1 PJPPDDJSRORGJA-UHFFFAOYSA-K 0.000 description 1
- RTAKQLTYPVIOBZ-UHFFFAOYSA-N tritert-butylalumane Chemical compound CC(C)(C)[Al](C(C)(C)C)C(C)(C)C RTAKQLTYPVIOBZ-UHFFFAOYSA-N 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/10—Peculiar tacticity
- C08L2207/12—Syndiotactic polypropylene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Definitions
- the present invention relates to a solar cell sealing thermoplastic resin composition, a solar cell sealing sheet, and a solar cell, and more specifically, a surface made of a plate or sheet-like material such as glass or plastic.
- a thermoplastic resin composition as a sheet forming material for sealing a solar cell between the material and the back surface material, a solar cell sealing sheet formed from the thermoplastic resin composition, and the sheet Related to solar cells.
- ethylene butyl acetate copolymer (abbreviated as EVA) containing organic peroxide is generally used.
- EVA has a problem of insufficient heat resistance, such as thermal deformation at the environmental temperature where solar cell modules with low melting points are used.
- the heat resistance of the solar cell sealing sheet is expressed by forming a crosslinked structure in
- a known sheet forming method capable of forming a polyolefin is used for the production of a solar cell sealing sheet.
- an organic peroxide is blended as described above, decomposition of the organic peroxide is prevented.
- molding at low temperatures is forced, and high-speed productivity is hindered.
- Patent Document 1 JP 2000-91611 A
- a particularly important point to be improved is the heat laminating process in the production of solar cells (solar cell element (power generation module), solar cell encapsulating sheet, and glass and back sheet being superposed and heated. It was found that the solar cell encapsulating sheet may become cloudy and its transparency may be impaired when the step of bonding or fusing each other is performed at a low temperature.
- An object of the present invention is to solve the above-mentioned problems in a solar cell sealing sheet.
- the present invention does not generate decomposition gas that adversely affects solar cell elements, and is crosslinked.
- Solar cells that have good heat resistance, flexibility, transparency, mechanical strength, and solar cell sealing ability, can be heat-laminated in a wide temperature range, and have excellent power module sealing properties Sealing sheet and such solar cell sealing sheet The purpose is to provide materials used in the manufacture of!
- thermoplastic resin composition for sealing solar cells of the present invention comprises:
- the total amount with B) is 100 parts by weight.
- the MFR force determined at 16 kg load is in the range of 0.0;! To l OOg / 10 minutes, and at least one of the following requirements (b-1) or (b-2) Satisfy;
- (b-2) Containing structural units derived from propylene in an amount of 55 to 90 mol%, ⁇ -olefin (excluding propylene) power of 2 to 20 carbon atoms, and at least one kind of olefin selected from The structural unit derived from indium is 10 to 45 mol% (however, the total of the structural unit derived from propylene and the structural unit derived from ⁇ -olefin (excluding propylene) having 2 to 20 carbon atoms is 100 mol%.
- the intrinsic viscosity [7]] (dL / g) measured in 135 ° C decalin and the MFR (g / 10min, 230 ° C, 2.16kg load)
- the solar cell encapsulating plastic resin composition comprises the coupling agent (X) with respect to a total of 100 parts by weight of the propylene-based polymer (A) and the propylene-based copolymer (B). , 0.01 ⁇ ; Contains 10 parts by weight! /, May! /.
- the propylene polymer (A) examples include a isotactic propylene polymer (A-1) and a syndiotactic propylene polymer (A-2).
- the second solar cell sealing resin composition of the present invention comprises (A) 0 to 70 parts by weight of a propylene-based polymer that satisfies the following requirement (a), and (B) the following requirement (b): 30 to 100 parts by weight of the propylene-based copolymer (the total amount of (A) and (B) is 100 parts by weight) and the coupling agent (X) Characterized by heat treatment in the presence
- the MFR force determined at 16 kg load is in the range of 0.0;! To l OOg / 10 minutes, and at least one of the following requirements (b-1) or (b-2) Satisfy;
- (b-2) Containing structural units derived from propylene in an amount of 55 to 90 mol%, ⁇ -olefin (excluding propylene) power of 2 to 20 carbon atoms, and at least one kind of olefin selected from The structural unit derived from indium is 10 to 45 mol% (however, the total of the structural unit derived from propylene and the structural unit derived from ⁇ -olefin (excluding propylene) having 2 to 20 carbon atoms is 100 mol%.
- the intrinsic viscosity [7]] (dL / g) measured in 135 ° C decalin and the MFR (g / 10min, 230 ° C, 2.16kg load)
- the solar cell sealing sheet of the present invention is formed from any of the above-mentioned solar cell sealing thermoplastic resin compositions.
- the solar cell sealing thermoplastic resin composition may not be crosslinked.
- thermoplastic resin compositions for sealing solar cells for the production of a sheet for sealing solar cells.
- thermoplastic resin composition constituting the solar cell sealing sheet may not be crosslinked.
- a solar cell of the present invention includes the solar cell sealing sheet.
- thermoplastic resin composition for sealing a solar cell of the present invention When used, a decomposition gas that adversely affects the solar cell element is not generated, and there is no need to crosslink the composition. , Good heat resistance 'Flexibility, solar cell sealing properties (can be heated and laminated in a wide temperature range) ⁇ Mechanical strength ⁇ Transparent solar cell sealing sheet can be manufactured.
- thermoplastic resin composition for sealing a solar cell of the present invention since the crosslinking of the composition is not particularly required, it is necessary for forming a sheet for sealing a solar cell and manufacturing a solar cell. The time can be greatly shortened, and recycling of solar cells after use becomes easy.
- the white turbidity of the solar cell encapsulating sheet can be improved, and the solar cell encapsulating sheet has good stress absorption. Therefore, the power generation module (solar cell element) can be prevented from cracking.
- FIG. 1 shows an example of a form to which a solar cell sealing sheet is applied.
- FIG. 2 is a schematic view of a sample for a heat resistance test and a glass adhesion test in Examples (for the sake of convenience, each layer is drawn separately).
- FIG. 3 is a schematic diagram of samples for transparency test and appearance evaluation in Examples (for convenience, each layer is drawn separately).
- FIG. 4 is a graph plotting the relationship between MFR and [7]] for a polymer corresponding to component (A) or (B) and a isotactic propylene-based polymer used in the present invention.
- the part surrounded by the bold line indicates the area defined by the requirement (b-2), which is one of the properties of the component (B) used in the present invention.
- b-2 the requirement of the component (B) used in the present invention.
- Like! / Indicates the range.
- thermoplastic resin composition for sealing solar cells of the present invention contains a specific propylene polymer (A).
- the second solar cell sealing thermoplastic resin composition of the present invention comprises a specific propylene polymer ( ⁇ ) 0 to 70 wt% and a specific propylene copolymer ( ⁇ ) 30 to; It is characterized by being obtained by heat-treating 100% by weight and the coupling agent (X) in the presence of an organic peroxide.
- propylene polymer ( ⁇ ) used in the present invention examples include a propylene homopolymer and a copolymer of propylene and at least one ⁇ -olefin having 2 to 20 carbon atoms other than propylene.
- ⁇ -olefin having 2 to 20 carbon atoms other than propylene includes ethylene, 1-butene, 1_pentene, 1-hexene, 4-methyl-1-pentene, 1-octene and 1-decene. , 1-dodecene, 1-tetradecene, 1-hexadecene, ⁇ ⁇ octadecene, ⁇ eicosene, etc. Power of ethylene and ⁇ -olefin having 4 to 10 carbon atoms (1-butene, 1-pentene, 1-hexene) 4-methyl-1-pentene, ⁇ -octene, etc.).
- These ⁇ -olefins may form a block copolymer or a random copolymer with propylene.
- the structural unit derived from these ⁇ -olefins may be contained in the propylene polymer ( ⁇ ) in a proportion of 35 mol% or less, preferably 30 mol% or less.
- the melting point observed in the differential scanning calorimetry of the propylene polymer (A) is 100 ° C or higher, preferably 100 to 160; C, more preferably 110-; C.
- the differential scanning calorimetry is performed as follows, for example. About 5 mg of sample is packed in a special aluminum pan, heated to 320 ° C / min at 30 ° C force, etc. using DSCPyrisl or DSC7 manufactured by Perkin Elma Co., and held at 200 ° C for 5 minutes Then, lower the temperature from 200 ° C to 30 ° C at 10 ° C / min, hold it at 30 ° C for another 5 minutes, and then determine the melting point from the endothermic curve when raising the temperature at 10 ° C / min. Ask. When multiple peaks are detected during DSC measurement, the peak detected on the highest temperature side is defined as the melting point (Tm).
- Tm melting point
- the melt flow rate (MFR) of the propylene polymer (A) measured under the conditions of 230 ° C and a load of 2 ⁇ 16 kg in accordance with ASTM D 1238 is from 0.01 to 10 lOOOg / 10 Min, preferably 0.05 to 10; desirably 10OOmin / 10 min.
- the structure of the propylene-based polymer (A) is selected in consideration of the compatibility with the propylene-based copolymer (B), as will be described later, both of the isotactic structure and the syndiotactic structure. Touch with force S.
- isotactic propylene polymer (A-1) which is one of the forms of the propylene polymer (A) will be described in detail below.
- These can be selected according to the physical properties required for the solar cell encapsulating sheet, and can be used in combination with two or more different melting points or rigidity.
- the isotacticity of the isotactic propylene polymer (A-1) measured by the NMR method There is no particular restriction on the fraction of the octpentad (mmmm fraction), but it is usually 90% or more, preferably 95% or more.
- the isotactic pentad fraction (mmmm fraction) is measured and calculated by the method described in JP-A-2003-147135.
- Such a isotactic propylene-based polymer (A-1) is, for example, a Ziegler comprising a solid catalyst component containing magnesium, titanium, halogen and an electron donor as essential components, an organoaluminum compound, and an electron donor. It can be produced by polymerization of propylene or copolymerization of propylene and other ⁇ -olefins in a catalyst system or a meta-octane catalyst system using a meta-octacene compound as a component of the catalyst.
- the syndiotactic propylene polymer ( ⁇ -2) is derived from a constituent unit of 90 mol% to 100 mol% derived from propylene and one or more selected from ethylene and ⁇ -olefin having 4 to 20 carbon atoms.
- the constituent unit is Omol% to 10 mol% (however, the total of both is 100 mol%).
- the ⁇ -olefin having 4 to 20 carbon atoms includes ethylene, 1-butene, 3-methyl-1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, 1-octene, 1-decene. 1-dedecene, 1-tetradecene, 1-hexadecene, 1-octadecene, 1 eicosene, etc.
- the syndiotactic propylene polymer ( ⁇ -2) is usually derived from 90 to 100 mol% of structural units derived from propylene and an ⁇ -olefin power having 4 to 20 carbon atoms.
- This is a propylene polymer containing Omol% to 9 mol% of structural units derived from 20 ⁇ -olefins (provided that the total is 100 mol%).
- the syndiotactic propylene polymer (A-2) preferably satisfies the following requirements [1] and [2]. [1]: The syndiotactic pentad fraction ( ⁇ fraction) measured by 13 C—NMR is 85% or more.
- Tm The melting point (Tm) determined by differential scanning calorimetry (hereinafter referred to as “DSC”) is 100 ° C or higher.
- the polymer (A-2) having a ⁇ fraction in this range has moldability, heat resistance, Excellent transparency and rigidity, and good properties as crystalline polypropylene!
- a polymer (A-2) having a ⁇ fraction in this range can be produced.
- the upper limit of the rrrr fraction is not particularly limited, but is 100% or less, and usually 99% or less, for example.
- This syndiotactic pentad fraction (rrrr fraction) is measured as follows.
- the rrrr fraction is expressed as ⁇ (absorption intensity derived from the methyl group of the third unit at the site where five propylene units are syndiotactically bonded) and Pw (propylene unit) in the 13 C-NMR spectrum. (Absorption intensity derived from all the methyl groups) in accordance with the following formula (1).
- NMR measurement is performed as follows, for example. That is, 0.35 g of sample is dissolved by heating in 2. Oml of hexachlorobutadiene. After filtering this solution through a glass filter (G2), add 0.5 ml of deuterated benzene and insert it into an NMR tube with an inner diameter of 10 mm. Then, 13 C-NMR measurement is performed at 120 ° C using a JEOL GX-500 type NMR measurement device. The number of integrations shall be 10,000 times or more.
- the upper limit of the melting point (Tm) is not particularly limited, but is usually 170 ° C, for example.
- the upper limit of the heat of fusion ( ⁇ ) is not particularly limited, but is usually 120 mJ / mg, for example.
- the differential scanning calorimetry is performed, for example, as follows. About 5 mg of sample is packed in a special aluminum pan, heated to 320 ° C / min at 30 ° C force, etc. using DSCPyrisl or DSC7 manufactured by Perkin Elma Co., and held at 200 ° C for 5 minutes Then, lower the temperature from 200 ° C to 30 ° C at 10 ° C / min, hold it at 30 ° C for another 5 minutes, and then determine the melting point from the endothermic curve when raising the temperature at 10 ° C / min. Ask. When multiple peaks are detected during DSC measurement, the peak detected on the highest temperature side is defined as the melting point (Tm).
- Tm melting point
- the polymer (A-2) having a melting point (Tm) within this range is preferable because it is excellent in moldability, heat resistance and mechanical properties, and has good properties as crystalline polypropylene.
- a polymer (A-2) having a melting point (Tm) within this range can be produced by using a catalyst system as described later and setting the polymerization conditions as described later.
- the syndiotactic propylene polymer (A-2) of the present invention has the above-mentioned requirements [1] and [1]
- the amount of n-decane soluble part is 1% by weight or less.
- the amount of the n-decane soluble part of the syndiotactic propylene polymer (A-2) is 1% or less, preferably 0.8 wt% or less, more preferably 0.6 ⁇ 6 wt% or less.
- the amount of the n-decane soluble part is an index closely related to the blocking property of the syndiotactic propylene polymer or a molded product obtained from the polymer, and usually the amount of the n-decane soluble part is small! /,! / This means that the amount of low crystalline component is small.
- the syndiotactic propylene polymer (A-2) that also satisfies the requirement [3] has very good anti-blocking properties.
- the syndiotactic propylene polymer (A-2) of the present invention preferably satisfies the following requirements [a] to [d].
- Tension elastic modulus is in the range of 150-2000MPa.
- the tensile strength at break is 15 MPa or more.
- Needle penetration temperature is 100 ° C or higher.
- the tensile elastic modulus of the syndiotactic propylene polymer (A-2) is in the range of 150 MPa to 2,000 MPa, preferably 300 MPa to 1800 MPa, more preferably 500 MPa to 1500 MPa.
- the tensile elastic modulus is a value measured by the following procedure.
- a JIS No. 3 dumbbell is punched out from a 1 mm thick press sheet in accordance with JIS K6301 and used as an evaluation sample.
- For measurement for example, using an Instron l23 Instron tensile tester, measure the tensile elastic modulus at 23 ° C with a span interval of 30 mm and a tensile speed of 30 mm / min, and adopt the average of three measurements. To do.
- the tensile elastic modulus is in this range.
- the syndiotactic propylene polymer (A-2) is preferable because it is excellent in mechanical properties and strength and has good properties as a crystalline polypropylene.
- a polymer (A-2) having a tensile elastic modulus in this range can be produced by setting a polymerization condition as described later using a catalyst system as described later.
- the tensile breaking strength of the syndiotactic propylene polymer (A-2) of the present invention is in the range of 15 MPa or more, preferably 18 MPa or more, more preferably 20 MPa or more, and further preferably 3 OMPa or more.
- the tensile strength at break is a value measured by the following procedure.
- a JIS No. 3 dumbbell is punched from a 1 mm thick press sheet and used as an evaluation sample.
- the tensile strength at break was measured at 23 ° C with a span of 30 mm and a tensile speed of 30 mm / min. Measure and adopt the average of 3 measurements.
- tension breaking strength in this range is preferable because of its good properties as a crystalline polypropylene.
- a polymer (A-2) having a tensile strength at break in this range can be produced by setting a polymerization condition as described later using a catalyst system as described later.
- the internal haze of the syndiotactic propylene polymer (A-2) is 50% or less, preferably 45% or less.
- the value of the internal haze is the value when the internal haze is measured with a digital turbidimeter "NDH-20D" manufactured by Nippon Denshoku Industries Co., Ltd. using a press sheet test piece having a thickness of 1 mm. This is the average of two measurements.
- the syndiotactic propylene polymer (A-2) having an internal haze in this range is preferable because of its excellent transparency and good properties as crystalline polypropylene.
- a polymer (A-2) having an internal haze in this range can be produced by using a catalyst system as described later and setting the polymerization conditions as described later.
- the needle penetration temperature of the syndiotactic propylene polymer (A-2) is 100 ° C or higher, more preferably 115 ° C or higher.
- the needle penetration temperature (sometimes called the softening point required by TMA measurement) can be measured as follows.
- the syndiotactic propylene polymer (A-2) having a needle penetration temperature within this range is preferable because of its excellent heat resistance and good properties as crystalline polypropylene.
- a polymer (A-2) having a needle penetration temperature within this range can be produced by setting a polymerization condition as described later using a catalyst system as described later.
- (L-2) a compound (also referred to as “component (L-2)” in the present specification) that forms an ion pair by reacting with the above-mentioned bridged metaguchicene compound (K), and
- (L-3) At least one or more compounds selected from organoaluminum compounds (in the present specification! / And also “component (L-3)”! /, U)) (in this specification! /
- a polymerization catalyst (cat_l) comprising “component (L)” and a polymerization catalyst (cat-2) in which the catalyst (cat-1) is supported on a particulate carrier is suitable.
- the catalyst is not limited to the catalyst as long as the polymer to be produced satisfies the requirements of the propylene polymer (A) component.
- RR 2 , R 3 and R 4 are selected from a hydrogen atom, a hydrocarbon group and a silicon-containing group, and R 2 and R 3 are bonded to each other to form a ring.
- R 5 , R 6 , R 8, R 9 , R u and R 12 are selected from hydrogen, a hydrocarbon group and a silicon-containing group, and the two groups of R 7 and R 1Q are hydrogen atoms.
- one or more adjacent group combinations selected from R 12 the adjacent groups may be bonded to each other to form a ring.
- R 17 and R 18 are a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, or a silicon atom-containing group, and substituents that may be the same or different from each other are bonded to each other to form a ring. Forming Good.
- M is Ti, Zr or Hf
- Y is carbon
- Q is the same or different from a halogen, a hydrocarbon group, an anion ligand, and a neutral ligand capable of coordinating with a lone pair of electrons. Selected in different combinations, j is an integer from;!
- component (K) satisfying this definition are shown below:
- dibenzylmethylene (cyclopentagenyl (2,7-di (2,4,6-trimethylphenol))-3,6-di tert-butylfluorenyl) zirconium dichloride
- Dibenzylmethylene (cyclopentadienyl) (2,7-diphenyl-3,6-di tert-butylfluorenyl) zirconium dichloride
- dibenzylmethylene (cyclopentaenyl) (2,3,6,7-tetratert-butylfluorenyl) zirconium dichloride
- Dibenzylmethylene (cyclopentagenyl) (2,7-di (4-methylphenyl) -3,6-di tert-
- R 11 is an aryl group such as a phenyl group, a tolyl group, a t-butylphenyl group, a dimethylphenyl group, a trimethylenophenyl group, a biphenyl group, or the like.
- aryl group such as a phenyl group, a tolyl group, a t-butylphenyl group, a dimethylphenyl group, a trimethylenophenyl group, a biphenyl group, or the like.
- it is preferably used because it gives a syndiotactic propylene polymer exhibiting a strength S as a substituted aryl group and a high melting point.
- the above-mentioned bridged metaguchicene compound (K) can be produced by a known method, and the production method is not particularly limited.
- Known production methods include, for example, the production methods described in W 02001/27124 and WO 2004/087775 by the present applicant.
- meta-orthene compounds can be used alone or in combination of two or more.
- the polymerization catalyst component (U is (L-1) an organoaluminum compound, (L-2) a compound that forms an ion pair by reacting with the cross-linked meta-orthocene compound ( ⁇ ), and (L -3) It is selected from at least one compound selected from organoaluminum compounds, and the catalyst in the production of the polymer ( ⁇ -2) is further composed of (C) particulate carrier, if necessary.
- each component will be described in detail.
- R is independently a hydrocarbon group having 1 to 10 carbon atoms, and ⁇ is an integer of 2 or more.
- R represents a hydrocarbon group having 1 to 10 carbon atoms, and ⁇ represents an integer of 2 or more.
- a methylaluminoxane in which R is a methyl group, n is 3 or more, and preferably 10 or more is used.
- These aluminoxanes can be mixed with some organoaluminum compounds!
- organoaluminum compound (L-1) examples include modified methylaluminoxane as shown in [4] below.
- R represents a hydrocarbon group having! To 10 carbon atoms, each independently m, and n represents an integer of 2 or more.
- This modified methylaluminoxane is prepared using trimethylaluminum and an alkylaluminum other than trimethylaluminum.
- a compound [4] is generally called MMAO.
- Such MMAO can be prepared by the method described in US4960878, for example, or a commercially available product can be used as it is.
- JP-A-1-501950 discloses a compound (L-2) (hereinafter sometimes abbreviated as “ionic compound”) that forms an ion pair by reacting with the bridged meta-octene compound (K).
- L-2 hereinafter sometimes abbreviated as “ionic compound”
- ionic compound that forms an ion pair by reacting with the bridged meta-octene compound (K).
- Examples include Lewis acids, ionic compounds, borane compounds and carborane compounds described in Japanese Patent Publications and US5321106.
- the power S can include heteropoly compounds and isopoly compounds.
- organoaluminum compound (L-3) that forms the olefin polymerization catalyst
- organoaluminum compound (L-3) that forms the olefin polymerization catalyst
- R a and R b represent a hydrocarbon group having 1 to 15, preferably 1 to 4 carbon atoms which may be the same or different from each other,
- X represents a halogen atom
- m Is 0 ⁇ m ⁇ 3, n is 0 ⁇ n ⁇ 3, p is 0 ⁇ p ⁇ 3, q is a number 0 ⁇ q ⁇ 3, and m + n + p + q 3).
- tri-n-alkylaluminums such as trimethylaluminum, triethylaluminum, tri-n-butylaluminum, trihexanolenoreminium, trioctylaluminum;
- Tri-branched alkyl aluminums such as triisopropylaluminum, triisobutylaluminum, trisec-butylaluminum, tritert-butylaluminum, tri-2-methylbutylaluminum, tri-3-methylhexylaluminum, tri-2-ethylhexylaluminum ;
- Tricyclohexylaluminum such as tricyclohexylaluminum, tricyclootatylaluminum
- Trif Trilinole Noreminicum such as Ninore Noreminicum, Tritorinole Noreminicum; Dialkylaluminum hydrides such as Diisopropylaluminum hydride, Diisobutylaluminum hydride;
- Alkenyl aluminum such as isoprenyl aluminum
- Alkyl aluminum alkoxides such as isobutyl aluminum methoxide and isobutyl aluminum ethoxide;
- Dialkylaluminum alkoxides such as dimethylaluminum methoxide, jetylaluminum ethoxide, dibutylaluminum butyloxide; alkylaluminum sesquioxides such as ethylaluminum sesquiethoxide and butylaluminum sesquibutoxide;
- Alkyl aluminum aryloxides such as jetyl aluminum phenoxide, jetyl aluminum (2,6-di-t-butyl-4-methyl phenoxide);
- Dialkylaluminum halides such as dimethylaluminum chloride, jetylaluminum chloride, dibutylaluminum chloride, jetylaluminum bromide, diisobutylaluminum chloride;
- Ethylaluminum sesquik lid butylaluminum sesquik lid, ethylaluminum Alkylaluminum sesquihalides such as dium sesquibromide;
- Partially halogenated alkylaluminums such as alkylaluminum dihalides such as ethylaluminum dichloride;
- Dialkylaluminum dihydrides such as jetylaluminum hydride and dibutylaluminum hydride;
- alkylaluminum dihydrides such as ethyl aluminum dihydride, propylaluminum dihydride;
- Partially alkoxylated and halogenated alkynolealuminum such as ethylaluminum ethoxychloride, butylaluminum butoxychloride, ethylminium ethoxybromide
- trimethylaluminum and triisobutylaluminum are preferably used as the (A-3) organoaluminum compound.
- the catalyst for producing the polymer (A-2) includes (K) a crosslinked metacene compound represented by the general formula [1], and (L) (L-1) organoaluminum. Necessary with at least one compound selected from an oxy compound, (L-2) a compound that forms an ion pair by reacting with the above-mentioned bridged meta-cyclocene compound (K), and (L-3) an organic aluminum compound.
- Use carrier (C) according to the conditions.
- the carrier (C) (also referred to herein as “component (C)”) is an inorganic or organic compound, and is a granular or particulate solid. Of these, porous oxides, inorganic chlorides, clays, clay minerals or ion-exchange layered compounds are preferred as the inorganic compounds.
- the porous oxide specifically, SiO, Al 2 O, MgO, ZrO, TiO, BO, CaO, ZnO, BaO, T ⁇ and the like, or a composite or mixture containing these, for example, natural or Synthetic zeolite, SiO 2 —MgO, SiO 2 —Al 2 O, SiO 2 —TiO 2 , SiO 2 —VO, SiO 2 —Cr 0 3 , Si0 2 —Ti0 2 —MgO, and the like can be used. Of these, those containing Si02 and / or Al 2 O as the main component are preferable.
- the inorganic oxide contains a small amount of Na 2 CO 3, K 2 CO 3, CaCO, MgCO, Na 2 SO,
- Carbonic acid such as Al (SO), BaSO, KNO, Mg (NO), Al (NO), Na 0, K 0, Li O
- It may contain salt, sulfate, nitrate and oxide components.
- MgCl, MgBr, MnCl, MnBr, etc. are used as the inorganic halide.
- the inorganic halide may be used as it is, or may be used after being pulverized by a ball mill or a vibration mill.
- the clay is usually composed mainly of clay minerals.
- the ion-exchangeable layered compound is a compound having a crystal structure in which the surfaces constituted by ionic bonds are weak and / or stacked in parallel by the bonding force, and the ions contained therein can be exchanged. It is.
- Most clay minerals are ion-exchangeable layered compounds.
- these clays, clay minerals, and ion-exchange layered compounds are not limited to natural ones, and artificial synthetic materials can also be used.
- Examples of clays, clay minerals or ion-exchangeable layered compounds include clays, clay minerals, and ionic crystalline compounds having a layered crystal structure such as hexagonal close packing type, antimony type, CdCl type, and Cdl type. can do.
- the ion-exchangeable layered compound may be a layered compound in a state where the layers are expanded by exchanging the exchangeable ions between the layers with other large and bulky ions using the ion-exchange property.
- Preferred are clays or clay minerals, and particularly preferred are montmorillonite, vermiculite, pectolite, teniolite and synthetic mica.
- Examples of the organic compound include granular or fine particle solids having a particle size force of ⁇ 300 m and a particle size of 10 to 300111.
- a (co) polymer or burcyclohexane produced mainly from ⁇ -olefin having 2 to 14 carbon atoms such as ethylene, propylene, 1-butene, 4-methyl-1-pentene, etc.
- examples thereof include (co) polymers produced from styrene as a main component, and modified products thereof.
- an organic compound component (D) such as alcohols, phenolic compounds, carboxylic acids, phosphorus compounds, and sulfonates as required (in this specification! /
- component (D) can also be included.
- At least two or more of the catalyst components may be in contact with each other in advance.
- the component (C) is a solid catalyst component in which the component (K) is supported, and the component (C) has the component (K
- the component (the solid catalyst component on which U is supported may be further supported on the prepolymerized solid catalyst component on which olefin is prepolymerized.
- the polymerization can be carried out by V or deviation of a liquid phase polymerization method such as solution polymerization or suspension polymerization or a gas phase polymerization method.
- a liquid phase polymerization method such as solution polymerization or suspension polymerization or a gas phase polymerization method.
- the inert hydrocarbon medium used in liquid phase polymerization include propane, butane, pentane, hexane, heptane, octane, decane, dodecane, and kerosene; Alicyclic hydrocarbons such as pentane, cyclohexane and methylcyclopentane; aromatic hydrocarbons such as benzene, toluene and xylene; halogenated hydrocarbons such as ethylene chloride, chlorobenzene and dichloromethane or mixtures thereof It is also possible to use olefin itself as a solvent.
- Component (Ll) is a molar ratio of component (Ll) to all transition metal atoms (L) in component (K) [(L-1) / M] force usually 0.01 to 5000, preferably Is used in such an amount as 0.05-2000.
- the component (L-2) has a molar ratio [(L-2) / M] of the component (L-2) and the transition metal atom (M) in the component (K) usually:!
- Component (L-3) has a molar ratio ((L-3) / M) of aluminum atoms in component (L-3) to all transition metals (M) in component (K) of usually 10 to
- the amount used is 5000, preferably 20 to 2000.
- the component (D) has a molar ratio [(D) / (L-1)] of usually 0.01 to 10, preferably 0.00.
- the molar ratio (D) / (L-2)] is usually from 0.01 to 10; preferably 0
- the molar ratio [(D) / (L-3)] is usually 0.0; It is preferably used in an amount such that 0.005 to;
- the polymerization temperature of olefin using such an olefin polymerization catalyst is usually in the range of -50 to + 200 ° C, preferably 0 to 170 ° C.
- the polymerization pressure is usually from normal pressure to lOMPa gauge pressure, preferably from normal pressure to 5 MPa gauge pressure, and the polymerization reaction can be carried out in any of batch, semi-continuous and continuous methods. it can. It is also possible to carry out the polymerization in two or more stages with different reaction conditions.
- the molecular weight of the resulting olefin polymer can also be controlled by the presence of hydrogen in the polymerization system or by changing the polymerization temperature. Furthermore, it can be adjusted by the amount of component (L) used. When hydrogen is added, the amount is suitably from 0.001 to 100 NL per kg of olefin.
- the propylene-based copolymer (B) used in the present invention satisfies the following requirement (b).
- the MFR force determined at 16kg load is in the range of 0.0;! To lOOg / 10 minutes, and at least one of the following requirements (b-1) or (b-2) Fulfill;
- (b-2) structure derived from 55 to 90 mol constitutional units derived from propylene 0/0 (provided that propylene from electrically Charles structural units and 2-20 carbon ⁇ - Orefuin (excluding propylene)
- the component unit is derived from at least one olefin selected from ⁇ -olefins (excluding propylene) having 2 to 20 carbon atoms.
- the intrinsic viscosity [7]] (dL / g) measured in 135 ° C decalin and the MFR (g / 10 min, 230 ° C, 2.16 kg load) Relational expression:
- the melt flow rate (MFR; ASTM D-1238, 230 ° C, 2.16 kg load) of the propylene copolymer (B) is 0.0;! To 50 g / 10 min, preferably 0.0; ! ⁇ 30dl / g.
- the propylene-based copolymer (B) satisfies at least one of the requirements (b-1) and (b-2).
- the syndiotactic triad fraction (rr fraction, triato syndiotacticity) measured by 13 C-NMR of the propylene copolymer (B) is 60% or more, preferably 70% or more More preferably, it is 75% or more. When the rr fraction is in this range, the stress absorbing performance of the solar cell sealing sheet is exhibited, which is preferable.
- the rr fraction is Prr in the 13 C-NMR spectrum (absorption intensity derived from the methyl group of the second unit at the site where 3 units of propylene units are continuously syndiotactically bonded) and Pw (propylene unit). (Absorption intensity derived from all the methyl groups) is obtained by the following formula (2).
- absorption derived from mr absorption derived from at least both syndiotactic bonds and isotactic bonds among 3 units of propylene units, used to determine Pmr (absorption intensity)
- absorption derived from rr Absence derived from the methyl group of the second unit at the site where 3 units of propylene units are syndiotactically linked, used to determine Prr (absorption intensity)
- absorption derived from mm used to determine the Pmm (absorption intensity), absorption derived from the second unit methyl group at the site where 3 units of propylene units are consecutively isotactically bonded
- the value obtained according to the method for obtaining the “syndiotacticity parameter (SP value)” described above is 60% or more, preferably 65% or more, more preferably 70% or more. Is desirable. In other words, in the calculation of the rr value,
- Absorption derived from the second unit methyl group at the site of syndiotactic bonding, used for determination of Prr (absorption intensity)), or mm-derived absorption (3 units of propylene units in succession) If the absorption derived from the second group methyl group at the tick-bonded site, the intensity used to determine Pmm (absorption intensity)), and the absorption derived from the comonomer overlap, the contribution of the comonomer component is subtracted. It is.
- NMR measurement is performed, for example, as follows.
- Propylene-based copolymer (B) is present in an amount of 55 to 90 mole 0/0 constitutional units derived from propylene, structure derived from having 2 to 20 carbon atoms ⁇ - Orefuin (excluding propylene) single Containing 10 to 45 mol% of the position.
- Constituent units derived from wherein propylene, total of constituent units derived from having 2 to 20 carbon atoms ⁇ - Orefuin (excluding propylene) is 1 00 mole 0/0.
- ⁇ -olefins having 2 to 20 carbon atoms include ethylene, 3-methyl-1-butene, 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, 1-octene, 1-decene, 1-dedecene, 1-tetradecene, 1-hexadecene, 1-octadecene, 1 eicosene, etc.
- Particularly preferred are ethylene, 1-butene, 1-hexene, 4-methyl-1 pentene, and 1-octene.
- the propylene copolymer (B) preferably has an observed melting point of less than 100 ° C or no melting point in differential scanning calorimetry (DSC)! /.
- the fact that the melting point is not observed means that in the range of 150 to 200 ° C, no crystal melting peak with a crystal melting heat quantity of lj / g or more is observed. Details of the melting point measurement conditions are as described in the Examples section below.
- the intrinsic viscosity [7] of the propylene copolymer (B) measured in 135 ° C decalin is 0.;
- the degree of crystallinity of this propylene copolymer (B) measured by X-ray diffraction is preferably 20% or less, more preferably 0 to 15%.
- This propylene-based copolymer (B) has a single glass transition temperature, and the glass transition temperature (Tg) obtained by differential scanning calorimetry (DSC) is usually 50 ° C. ⁇ ; 10 ° C, preferably — in the range of 40 ° C to 0 ° C, more preferably in the range of 35 ° C to 0 ° C.
- the propylene copolymer (B) has excellent cold resistance and low temperature characteristics when the glass transition temperature (Tg) is within the above range. It is preferable because it exhibits stress absorption performance.
- the differential scanning calorimetry is performed, for example, as follows. Sample lO.OOmg is packed in a special aluminum pan, heated at 200 ° C / min from 30 ° C to 200 ° C using DSCRDC220 manufactured by Seiko Instruments Inc., and held at 200 ° C for 5 minutes After that, from the endothermic curve when the temperature was lowered to 200 ° C, La 100 ° C at 10 ° C / min, held at 100 ° C for another 5 minutes, and then heated at 10 ° C / min The glass transition temperature (Tg) is determined.
- the molecular weight distribution (Mw / Mn, converted to polystyrene, Mw: weight average molecular weight, Mn: number average molecular weight) of the propylene-based copolymer (B) measured by GPC is preferably 3.5 or less. Preferably it is 3.0 or less, More preferably, it is 2.5 or less.
- a part of the propylene-based copolymer (B) as described above may be graft-modified with a polar monomer.
- the polar monomer include a hydroxyl group-containing ethylenically unsaturated compound, an amino group-containing ethylenically unsaturated compound, an epoxy group-containing ethylenically unsaturated compound, an aromatic bull compound, an unsaturated carboxylic acid or a derivative thereof, and bull.
- examples include ester compounds and butyl chloride.
- the modified propylene copolymer (B) is obtained by graft polymerization of a polar monomer to the propylene copolymer (B) as described above.
- the polar monomer is usually used for 100 parts by weight of the propylene copolymer (B);! To 100 parts by weight. It is preferably used in an amount of 5 to 80 parts by weight.
- This graft polymerization is usually carried out in the presence of a radical initiator.
- a radical initiator an organic peroxide or an azo compound can be used.
- the radical initiator can be used by directly mixing it with the propylene-based copolymer (B) and the polar monomer. It can also be used by dissolving it in a small amount of an organic solvent.
- the organic solvent is not particularly limited as long as it is an organic solvent that can dissolve the radical initiator, and it can be used with a force S.
- graft polymerization of a polar monomer to the propylene-based copolymer (B) may be performed in the presence of a reducing substance.
- a reducing substance When reducing substances are used, the force S can be improved to improve the grafting amount of polar monomers.
- Graft modification of the propylene-based copolymer (B) with a polar monomer can be performed by a conventionally known method.
- the propylene-based copolymer (B) is dissolved in an organic solvent, and then the polar monomer and the radical are used.
- an initiator or the like By adding an initiator or the like to the solution and reacting them at a temperature of 70 to 200 ° C, preferably 80 to 190 ° C, for 0.5 to 15 hours, preferably 1 to 10 hours. You can use fi urging power S.
- a modified propylene copolymer (B) can also be produced by reacting the propylene copolymer (B) with a polar monomer in the absence of a solvent using an extruder or the like. This reaction is usually carried out at a temperature equal to or higher than the melting point of the propylene copolymer (B), specifically at a temperature of 120 to 250 ° C., usually 0.5 to 10 minutes.
- the modified amount of the modified propylene copolymer (B) thus obtained (the amount of the polar monomer graft) is usually 0.! To 50% by weight when the modified product is 100% by weight. , Preferably 0.2 to 30% by weight, more preferably 0.2 to 10% by weight.
- the solar cell sealing thermoplastic resin composition of the present invention When the modified propylene-based copolymer (B) is contained in the solar cell sealing thermoplastic resin composition of the present invention, the solar cell sealing thermoplastic resin composition and other resins It has excellent adhesion and compatibility, and may improve the wettability of the solar cell sealing sheet surface.
- the propylene-based copolymer (B) used in the present invention is:
- ( ⁇ -2) a compound that forms an ion pair by reacting with the bridged meta-orthocene compound ( ⁇ ) (also referred to as “component ( ⁇ -2)” in this specification), and
- the ability to produce more S The ability to be produced The polymer is not limited to the catalyst as long as the polymer to be produced satisfies the requirements of the propylene-based copolymer (B).
- R 8 , R 9 and R 12 are atoms or groups selected from a hydrogen atom, a hydrocarbon group and a silicon-containing group, and each may be the same or different.
- R 6 and R U are the same atom or the same group selected from a hydrogen atom, a hydrocarbon group, and a silicon-containing group,
- R 7 and R 1Q are the same atom or the same group selected from a hydrogen atom, a hydrocarbon group, and a silicon-containing group,
- R 2 and R 3 may combine with each other to form a ring.
- Adjacent groups among R 5 to R 12 may be bonded to each other to form a ring.
- R 13 and R 14 are each an aryleno group having 6 to 18 carbon atoms, an alkyl group having! To 40 carbon atoms, an alkyl group having 6 to 40 carbon atoms, a fluoroaryl group having 6 to 20 carbon atoms, carbon Fluoroalkyl group having 7 to 40 carbon atoms, chloroaryl group having 6 to 20 carbon atoms, chloroaryl group having 7 to 40 carbon atoms, bromoaryl group having 6 to 20 carbon atoms, 7 to 40 carbon atoms It is selected from bromoalkyl aryl groups, C 6-20 iodine aryl groups and C 7-40 iodine alkyl aryl groups, which may be the same or different.
- At least one of R 13 and R 14 is an aryl group having 7 to 18 carbon atoms, a chloroaor having 6 to 20 carbon atoms Reel group, 7 to 40 carbon black alkyl group, 6 to 20 bromo aryl group, 7 to 40 bromoalkyl group, 6 to 20 carbon aryl group, 7 carbon atoms Selected from ⁇ 40 alkylalkylene groups and 7-40 carbon fluoroalkylene groups,
- M is Ti, Zr or Hf
- Y is carbon or silicon
- Q is the same or different combination of halogen, hydrocarbon group, neutral having 10 or less carbon atoms, conjugated or nonconjugated gen, anion ligand, and neutral ligand capable of coordinating with a lone pair of electrons.
- j is an integer from! ).
- bridged metaguchicene compound represented by the general formula [11] are shown below, but the scope of the present invention is not particularly limited by this.
- otatamethyloctahydrodibenzofunoleolene refers to the structure represented by Formula [12]
- otatamethyltetrahydridocyclopentafluorene refers to the structure represented by Formula [13]
- dibenzofluorene refers to the formula [12] 14].
- the bridged meta-octene compound ( ⁇ ) the meta-cene compound described in International Publication No. 2004-087775 can also be used.
- the above-mentioned bridged metaguchicene compound ( ⁇ ) can be produced by referring to a known method.
- the power S can be cited as WO04 / 029062 by the present applicant.
- meta-orthene compounds as described above may be used alone or in combination of two or more.
- At least two or more of the catalyst components may be in contact with each other in advance.
- Ingredient (gamma) is per liter of the reaction volume, typically 10 9 ⁇ ; 10- 1 mol, preferably 10- 8 ⁇ ; used in such an amount that 10 to 2 mol.
- Component ( ⁇ -1) is a molar ratio [(11_1) / M] force of component (II-1) to all transition metal atoms (M) in component ( ⁇ ), usually 0.0; It is used in an amount of ⁇ 5,000, preferably 0.05 to 2,000.
- Component ( ⁇ -2) usually has a molar ratio [(II-2) / M] of the aluminum atoms in component ( ⁇ -2) and all transition metals (M) in component ( ⁇ ); It is used in an amount of ⁇ 1,000, preferably 1 to 500.
- Component ( ⁇ -3) has a molar ratio (( ⁇ -3) / ⁇ ) of component ( ⁇ -3) to transition metal atom ( ⁇ ) in component (a) of usually 1 to 10,000, The amount is preferably 1 to 5,000.
- the propylene-based copolymer (B) is at least selected from propylene and ⁇ -olefin having 2 to 20 carbon atoms (excluding propylene) in the presence of the above-mentioned catalyst for olefin polymerization. It is usually obtained by copolymerizing one type of olefin in the liquid phase. At this time, a hydrocarbon solvent is generally used, but a-olefin may be used as a solvent.
- hydrocarbon medium examples include aliphatic hydrocarbons such as propane, butane, pentane, hexane, heptane, octane, decane, dodecane, and kerosene; alicyclic groups such as cyclopentane, cyclohexane, and methylcyclopentane.
- Hydrocarbons Aromatic hydrocarbons such as benzene, toluene, xylene, but not limited to these. Copolymerization can be performed either batchwise or continuously.
- Examples of ⁇ -olefins that can be used for polymerization that is, those that can be polymerized, include, for example, ethylene, 1-butene, 1-pentene, 3-methyl-1-butene, 1-pentene, 1-hexene, 4-methyl 1- Examples include pentene, 3-methyl 1-pentene, 1-octene, 1-decene, 1-dedecene, 1-tetradecene, 1-hexadecene, 1-octadecene, 1-eicosene.
- ⁇ -olefin can be used alone or in combination of two or more.
- the concentration of the metalocene compound in the polymerization system is usually from 0.000005 to; Is used in an amount of 0.0001-0.50 mm mono.
- reaction time (average residence time when copolymerization is carried out in a continuous process) varies depending on conditions such as catalyst concentration and polymerization temperature. Usually 5 minutes to 3 hours, preferably 10 minutes ⁇ 1.5 hours.
- the propylene and the ⁇ -olefin (excluding propylene) force having 2 to 20 carbon atoms, and at least one olefin selected from the above are the propylene-based copolymers ( ⁇ ) having the specific composition as described above. Are each supplied to the polymerization system in such an amount that can be obtained. In the copolymerization, a molecular weight regulator such as hydrogen can also be used.
- a propylene-based olefin copolymer ( ⁇ ) is usually obtained as a polymerization solution containing it. This polymerization solution is a conventional method. To obtain a propylene-based copolymer (B).
- the copolymerization reaction is usually performed at a temperature of 40-200 ° C, preferably 40 ° C-; 180 ° C, more preferably 50 ° C-; 150 ° C, with a pressure of 0. Exceeding ⁇ 10Mpa, preferably 0.5 ⁇ ;! OMpa, more preferably 0.5-7Mpa.
- propylene-based copolymer (B) examples include the following propylene “butene” ethylene copolymers (B-1) and propylene “ethylene copolymers (B-2)”.
- the propylene / butene / ethylene copolymer (B-1) is composed of 55 to 90 mol%, preferably 55 to 87 mol% of a structural unit derived from propylene in the propylene-based copolymer (B). structural units derived from butene 3-43 mol%, preferably 10 to 30 mol%, of 2 to 42 mol of constituent units derived from ethylene 0/0, preferably contains 3 to 35 mole 0/0 .
- the propylene / butene / ethylene copolymer (B-1) having such a composition has good compatibility with the isotactic propylene-based polymer (A-1).
- the propylene-ethylene copolymer (B-2) is an amount of 55 to 90 mol%, preferably 60 to 85 mol% of the structural unit derived from propylene in the propylene-based copolymer (B) described above. amount, 10 to 45 mol constitutional units derived from ethylene 0/0, preferably those containing an amount of 15 to 40 molar%.
- the propylene / ethylene copolymer (B-2) having such a composition has good compatibility with the syndiotactic propylene polymer (A-2).
- the solar cell encapsulating sheet of the present invention (hereinafter also simply referred to as “sheet”) contains the propylene polymer (A) and the propylene polymer (B) in the following amounts.
- a thermoplastic resin composition hereinafter also simply referred to as “thermoplastic resin composition”
- the solar cell sealing sheet is obtained with good moldability. It is preferable at the point from which the heat resistance of a solar cell sealing sheet, transparency, and a softness
- thermoplastic resin composition for sealing solar cells of the present invention As specific examples of the thermoplastic resin composition for sealing solar cells of the present invention,
- thermoplastic resin composition 1 comprising a isotactic propylene-based polymer (A-1) and a propylene 'butene' ethylene copolymer (B-1);
- thermoplastic resin composition 2 comprising a syndiotactic propylene-based polymer (A-2) and a propylene-ethylene copolymer (B-2);
- thermoplastic resin composition 3 comprising a syndiotactic propylene polymer (A-2) and a propylene-butene-ethylene copolymer (B-1);
- thermoplastic resin composition 3 is particularly excellent in both heat resistance and transparency after heat lamination.
- the thermoplastic resin composition for sealing a solar cell of the present invention includes an adhesion promotion for improving the adhesion of the solar cell sealing sheet of the present invention formed from the composition to glass, plastic, and the like.
- a coupling agent (X) can be further blended.
- the coupling agent (X) a layer containing the solar cell sealing thermoplastic resin composition of the present invention (that is, a solar cell sealing sheet) and a polar group-containing resin or an inorganic compound such as a metal are used. Any force that can be used without particular limitation as long as it can improve the adhesion with other layers contained in an amount of 50% by weight or more.
- Silane, titanate, and chromium coupling agents are preferably used.
- a system coupling agent (silane coupling agent) is preferably used.
- silane coupling agent known ones can be used, and there is no particular limitation. Specific examples include butyltriethoxysilane, butyltrimethoxysilane, burtris (/ 3-methoxy-ethoxy). Runs can be used.
- the compounding amount of the silane coupling agent is 0.01 to 10 parts by weight, preferably 0. 0 to 100 parts by weight in total of the propylene polymer (A) and the propylene polymer (B). ! ⁇ 3 parts by weight.
- the coupling agent and the thermoplastic resin composition are subjected to a heat treatment such as melt-kneading in the presence of an organic peroxide to cause a coupling reaction of the coupling agent with the thermoplastic resin composition. Is possible.
- the blending amount of the coupling agent is desirably about 0.;! To about 5 parts by weight with respect to 100 parts by weight in total of the propylene polymer (A) and the propylene polymer (B).
- the solar cell sealing sheet formed from the silane-grafted thermoplastic resin composition is also a solar cell formed from the thermoplastic resin composition in which a silane coupling agent is blended with glass and plastic. Adhesiveness equivalent to or better than the battery sealing sheet.
- thermoplastic resin composition of the present invention may be blended in the thermoplastic resin composition of the present invention as necessary.
- radical reaction aid examples include sulfur, P-quinone dioxime, ⁇ , ⁇ '-dibenzoyl quinone dioxime, ⁇ -methyl- ⁇ -4-dinitrosaniline, nitrosobenzene, diphenol.
- Peroxy auxiliaries such as nildanidine, trimethylolpropane-N, N, -m-phenylenedimaleimide; or dibutenebenzene, triarylcyanurate (TAC), triallyl isocyanurate (TAIC) from the standpoint of reaction efficiency preferable.
- polyfunctional methacrylate monomers such as ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, trimethylolpropane trimethacrylate, arylmethacrylate, butyl butyrate, vinyl stearate
- polyfunctional methacrylate monomers such as ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, trimethylolpropane trimethacrylate, arylmethacrylate, butyl butyrate, vinyl stearate
- multifunctional burmonomers such as ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, trimethylolpropane trimethacrylate, arylmethacrylate, butyl butyrate, vinyl stearate
- multifunctional burmonomers such as ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, polyethylene glyco
- triallyl cyanurate (TAC) and triallyl isocyanurate (TAIC) are preferable from the viewpoint of reaction efficiency.
- the above auxiliary agent has a weight ratio [(auxiliary agent) / (organic peroxide)] of 1 / It is desirable to use in an amount of 30 to 20/1, preferably 1/20 to 10/1.
- an organic peroxide is used, it is preferably used so as not to be “crosslinked” as described below.
- the amount of the organic peroxide is preferably 0.001 to 5 parts by weight, more preferably 0.0;! To 3 parts by weight with respect to 100 parts by weight of the total of (A) and (B).
- thermoplastic resin composition of the present invention and the solar cell sealing sheet comprising the same may be cross-linked, but are preferably not cross-linked, that is, non-cross-linked from the viewpoint of sheet recycling. Masle.
- crosslinked means that at least a part of the polymer contained in the thermoplastic resin composition or the solar cell sealing sheet is crosslinked, and the force or the composition is also present.
- the boiling xylene insoluble content in the total organic matter contained in the sheet is 0.1% by weight or less, or a melt flow rate measured at 230 ° C and a load of 2 ⁇ 16 kg in accordance with ASTM D 1238 ( MFR) is 0.04g / 10min or less.
- organic peroxide for grafting known ones can be used, and there is no particular limitation. Specifically, dilauroyl peroxide, 1, 1, 3, 3-tetramethylbutyl peroxide is used. -2-ethylhexanoate, dibenzoyl peroxide, t-amylperoxy-2-ethenohexanoate, t-butylperoxy-2-ethylhexanoate, t-butylenoperoxyisobutyrate, t-butylperoxymaleic acid 1,1-di (t-amylveroxy) -3,3,5-trimethylcyclohexane, 1, ⁇ -di (t-amylveroxy) cyclohexane, t-amylperoxyisononanoe K t-a Milperoxy normal octoate, 1,,!
- thermoplastic resin composition for sealing a solar cell of the present invention and the composition formed therefrom.
- the solar cell encapsulating sheet may be blended with various other additives as long as the object of the present invention is not impaired.
- additives include UV absorbers, light stabilizers, antioxidants, heat stabilizers, antistatic agents, and anti-slip agents for preventing deterioration of solar cell sealing sheets due to ultraviolet rays in sunlight.
- ultraviolet absorbers include 2-hydroxy-4methoxybenzophenone, 2--2-dihydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4-carboxybenzophenone Benzophenones such as 2-hydroxy-4-N-otatoxybenzophenone; 2- (2-hydroxy-3,5-di-1-butylphenenole) benzotriazole, 2- (2-hydroxy- Benzotriazoles such as 5-methylphenol) benzotriazole; salicylic acid ester UV absorbers such as phenylsulcylate and p-octylphenylsulcylate are used.
- a hindered amine light stabilizer is used as the light stabilizer.
- antioxidant a hindered phenol-based or phosphite-based antioxidant is used.
- the melt flow rate (MFR) measured at 230 ° C and a load of 2.16 kg in accordance with ASTM D 1238 of the thermoplastic resin composition for sealing solar cells of the present invention is usually 0 ⁇ 05. —100 g / 10 min, preferred ⁇ is 0.2 to 600 g / 10 min, more preferred ⁇ is 0.3 to 200 g / 10 min.
- the solar cell sealing thermoplastic resin composition of the present invention has a maximum peak of the melting point (Tm, ° C) at 100 ° C or higher in the endothermic curve in differential scanning calorimetry (DSC),
- the heat of fusion is preferably in the range of 1 to 40 J / g, and more preferably in the range of 3 to 35 J / g.
- the maximum endothermic peak (melting point) of the thermoplastic resin composition for sealing a solar cell of the present invention is 100 ° C or higher, preferably 110 ° C or higher, more preferably 120 ° C or higher.
- thermoplastic resin composition for sealing a solar cell of the present invention may be blended with other resins, rubbers, inorganic fillers and the like as long as the object of the present invention is not impaired.
- thermoplastic resin composition for sealing a solar cell of the present invention may be blended with other resins, rubbers, inorganic fillers and the like as long as the object of the present invention is not impaired.
- petroleum resin When blended, the stress absorption property of the solar cell sealing sheet is further improved near room temperature.
- the thickness of the solar cell sealing sheet of the present invention is not particularly limited, but it is usually preferably in the range of 0.1 mm to 3 mm. If it is smaller than lmm, the glass and solar cells are likely to be damaged in the heating laminating process in the production of solar cells, and if it is larger than 3 mm, the light transmittance of the sheet decreases. The amount of photovoltaic power generation may decrease.
- the solar cell sealing sheet of the present invention is not particularly limited, but may be formed by known extrusion molding (cast molding, extrusion sheet molding, inflation molding, injection molding, etc.), compression molding, calendar molding, or the like. It can be produced by molding the solar cell sealing thermoplastic resin composition of the invention.
- embossing the sheets prevents blocking of the sheets, and the embossing becomes a cushion for the laminated glass and solar cell element (power generation module). Preferred in terms of preventing damage.
- a layer made of a thermoplastic resin other than the solar cell sealing thermoplastic resin composition of the present invention may be laminated on one side or both sides thereof.
- the solar cell sealing sheet of the present invention is laminated on one side and / or both sides of the solar cell element, and if necessary, what is the solar cell element side of the laminated solar cell sealing sheet? It can utilize for a solar cell by laminating
- Fig. 1 shows an example of the form of a solar cell to which a solar cell sealing sheet is applied.
- the method for producing the solar cell is not particularly limited.
- the surface protective layer, the solar cell element, and the solar cell sealing sheet of the present invention are laminated in a desired order, and then vacuum suction or the like is performed.
- the method of laminating by heating is mentioned.
- the surface protective layer is not particularly limited as long as it can protect a layer formed of a solar cell and a solar cell sealing sheet and does not impair the object of the present invention.
- Known materials can be used.
- Specific examples of the material of the surface protective layer include glass, polyethylene resin, polypropylene resin, cyclic polyolefin resin, AS (acrylonitrile-styrene) resin, ABS (acrylonitrile-butadiene-styrene) resin, polychlorinated bur resin, vinyl chloride resin, Polyester resins such as fluorine resins, polyethylene terephthalate, polyethylene naphthalate, etc., phenol resins, polyacrylic resins, polyamide resins such as various nylons, polyimide resins, polyamide-imide resins, polyurethane resins, cellulose resins, silicone resins Resins, polycarbonate resins and the like can be mentioned. Different resins may be used by mixing (blending) these resins, but different resins may be used by stack
- an inorganic / organic composite film on which an inorganic oxide or the like is vapor-deposited can be preferably used as the surface protective layer in order to improve the normality of gas / water.
- the surface protective layer and the solar cell encapsulating sheet (layer) of the present invention are a laminate composed of a plurality of layers, between these layers.
- a layer made of a known adhesive or adhesive resin may be provided.
- one of the two surface protective layers may have a light-shielding property or a light-reflective property. If it is a laminate comprising these layers, at least one of these layers may have a light shielding property or a light reflecting property. Examples of a method for imparting light shielding properties to a certain layer include a method of forming the layer with a resin in which a pigment (for example, titanium white, etc.) is blended and kneaded.
- the surface protective layer is a multilayer
- a method of forming the layer with a resin in which one of the layers is blended with, for example, a pigment (for example, titanium phosphate) is kneaded.
- One of the surface protective layers may be a layer made of a metal foil, for example, an aluminum foil.
- This reaction solution was extracted with jetyl ether, the organic layer was washed with 1N hydrochloric acid, saturated aqueous sodium hydrogen carbonate solution and saturated brine, and the separated organic phase was dried over anhydrous magnesium sulfate, and then magnesium sulfate was filtered off. The solvent of the filtrate was distilled off under reduced pressure with a rotary evaporator. Purification was performed on a silica gel column to obtain the desired product (yield 3.37 g, yield 57%). The target product was identified by 1 H-NMR.
- This reaction solution was extracted with jetyl ether, the organic layer was washed with 1N hydrochloric acid, saturated aqueous sodium hydrogen carbonate solution and saturated brine, and the separated organic phase was dried over anhydrous magnesium sulfate, and then magnesium sulfate was filtered off.
- the solvent of the filtrate was distilled off under reduced pressure using a rotary evaporator. After purification on a silica gel column, recrystallization was performed with toluene to obtain the desired product (yield 0.714 g, yield 17%).
- the target product was identified by 1 H-NMR and FD-MS spectra.
- Propylene was continuously supplied in an amount of 65 kg / h while maintaining a gas phase concentration of 57 mol% in the reaction vessel of hydrogen, and polymerization was carried out at 25 ° C for 4 hours, followed by a small amount of diethylene glycol monoisopropyl. Ether was added to stop the polymerization. The obtained polymer was washed with 1.8 m 3 of heptane and dried under reduced pressure at 80 ° C. for 15 hours. As a result, 100 kg of polymer was obtained.
- di (p-chlorophenyl) methylene (cyclopentageninole) (Otamethinoleoctahydrodibenzofunenolenenole) dinolecodichloride and methylaluminoxane in toluene (Tosohichi Finechem)
- cyclopentageninole Otamethinoleoctahydrodibenzofunenolenenole
- the isotactic triad fraction (mm fraction) can be measured using the method described in WO 2004-087775 pamphlet, page 21, line 7 to page 26, line 6.)
- a toluene solution containing aluminum atom and zirconium atomic energy S, aluminum atom / zirconium atom 300/1 (molar ratio), and then the amount of zirconium atom contained in the toluene solution is 0.002 mmol ( Therefore, the amount of aluminum atom (containing 0.6 mmol) was sampled and added to the polymerization vessel. Polymerization was carried out for 20 minutes with ethylene at an internal temperature of 65 ° C and an internal pressure of 0.78 MPa, and 20 mL of methanol was added. The polymerization was stopped by adding. After depressurization, the polymer was precipitated from the polymerization solution in 2 L of methanol and dried under vacuum at 130 ° C. for 12 hours. The obtained polymer was 60.4 g.
- the physical properties of the EVA used are as follows:
- silane coupling agent (X) 3-methacryloxypropyltrimethoxysilane (VMM S) (trade name: SZ-6030, manufactured by Toray Dow Coung) was used.
- (Y) Organic vortex oxide
- a dialkyl type peroxide (trade name: Perhexa 25 ⁇ ( ⁇ 25 ⁇ ), manufactured by NOF Corporation) was used.
- TAIC Triallyl isocyanurate
- the DSC exothermic endothermic curve was obtained, and the temperature at the maximum melting peak position at the time of temperature rise was defined as Tm.
- the sample is packed in an aluminum pan, (i) heated to 200 ° C at 100 ° C / min and held at 200 ° C for 5 minutes, then (ii) at 150 ° C at 10 ° C / min. (Iii) The temperature was raised to 200 ° C. at 10 ° C./min. This is the thermodynamic melting point (Tm) of the endothermic peak observed in (iii).
- the sample was packed in an aluminum pan, heated to 200 ° C at 100 ° C / min, held at 200 ° C for 5 minutes, and then cooled to -150 ° C at 10 ° C / min. Next, it was obtained from the exothermic / endothermic curve when the temperature was raised at 10 ° C / min.
- GPC gel permeation chromatography
- Mw weight average molecular weight
- Mn number average molecular weight
- Mw / Mn molecular weight distribution
- the density was measured according to the method described in ASTM D1505.
- thermoplastic resin composition iPP (a- l) 20 parts by weight, PBER (b— 1) 80 parts by weight, VMM S 0.5 parts by weight, PH25B 0.09 parts by weight, and M-60 0.02 parts by weight
- the portion was kneaded (190 ° C, 3 min, 40 rpm) with Labo Plus® Mill (manufactured by Toyo Seiki) to obtain a thermoplastic resin composition.
- thermoplastic resin composition was covered by a press molding machine (190 ° C, heated for 7 minutes and then cooled) to form a 500 m-thick press sheet (sealing sheet sun) as a solar cell sealing sheet. Pull) and a 2 mm thick press sheet (for MFR, flexibility, heat resistance and stress absorption evaluation).
- a 300 Hm thick aluminum plate used as a pseudo module is sandwiched between two sealing sheet samples, and a glass plate with a thickness of 3 mm is provided on one surface of the sealing sheet.
- White plate heat-treated glass manufactured by Asahi Glass Kinki Building Materials Co., Ltd.
- white PET film Limirror (registered trademark) (S 10 type)
- Toray Industries, Inc. Made by heating and laminating them under the conditions of 160 ° C, 10 min, 1 atm to prepare a sample for heat resistance test and a sample for glass adhesion test.
- the glass having a thickness of 3 mm, the sealing sheet sample, and the thickness 50
- the evaluation criteria are as follows.
- the sample for heat resistance test was held in an oven at 90 ° C. with a tilt of 60 ° with respect to the horizontal for 1000 hours to evaluate whether or not the pseudo module flowed.
- the adhesive strength (N / m) between the thermoplastic resin (solar cell sealing sheet) and glass was evaluated.
- thermoplastic resin was prepared in the same manner as in Example 1 except that iPP (a-1) and PBER (b-1) were changed to 20 parts by weight of sPP (a-2) and 80 parts by weight of PER (b-2).
- a composition was prepared, a press sheet and various test samples were prepared, and the solar cell sealing sheet was evaluated. Table 2 shows the evaluation results.
- thermoplastic resin composition was prepared in the same manner as in Example 1 except that 20 parts by weight of iPP (a-1) was changed to 20 parts by weight of sPP (a-2), and a press sheet and various test samples were prepared. And a solar cell sealing sheet was evaluated. Table 2 shows the evaluation results.
- thermoplastic resin composition was prepared in the same manner as in Example 1 except that 80 parts by weight was changed to 1 to 8 £ 1 ⁇ (80 parts by weight. Samples for solar cell sealing were evaluated.
- Table 2 shows the evaluation results.
- thermoplastic resin composition 100 parts by weight of EVA, 0.5 part by weight of VMMS, 0.09 part by weight of PH25B, and 0.02 part by weight of M-60 were kneaded (110 ° C, 3min, 40rpm) in a lab plast mill (manufactured by Toyo Seiki). Thus, a thermoplastic resin composition was obtained.
- thermoplastic resin composition was processed by a press molding machine (heated at 160 ° C for 10 minutes and then cooled) to produce a 2 mm thick press sheet (for MFR, flexibility and stress absorption evaluation). The evaluation was performed in the same manner as in Example 1. Table 2 shows the evaluation results.
- thermoplastic resin composition was processed by a press molding machine (heated at 140 ° C for 10 minutes and then cooled) to prepare a 500 ⁇ m-thick press sheet (sealing sheet sample).
- Various test samples were prepared in the same manner as in Example 1 except that this sealing sheet sample was used, and the solar cell sealing sheet was evaluated in the same manner as in Example 1. Table 2 shows the evaluation results.
- FIG. 4 shows the above-mentioned iPP (a-l), sPP (a-2) PBER (b-1) and PER (b-2), and the following polymers (AA- ;!) to The relationship between MFR and [7]] of (AA-5), (BB— ;!) to (BB-8) and isotactic polymer (DD-1) (DD-8) is shown.
- the organic layer was washed with a saturated aqueous sodium hydrogen carbonate solution, water, and a saturated aqueous sodium chloride solution. After drying with magnesium sulfate, the solvent was distilled off. Thereafter, the residue was purified by column chromatography to obtain 4.2 g of a white solid. The yield was 53%. Identification was performed by FD mass spectrometry spectrum (FD-MS). The measurement results are shown below.
- the reaction solution was sufficiently cooled in a dry ice / methanol bath, and 0.39 g of zirconium tetrachloride (1.68 mmol) was added. After stirring for 48 hours while gradually returning to room temperature, the solvent was distilled off under reduced pressure. The slurry was reslurried with hexane and filtered through a glass filter filled with diatomaceous earth. The brown solid on the filter was extracted with a small amount of dichloromethane and filtered. The obtained hexane solution and dichloromethane solution were respectively distilled off under reduced pressure.
- the orange solid was washed with a small amount of pentane and jetyl ether, and dried under reduced pressure to obtain 140 mg (0.186 mmol) of the target compound as an orange solid.
- Identification was performed with NMR spectrum and FD-mass spectrometry spectrum. The measurement results are shown below.
- a glass autoclave with a volume of 500 ml that had been thoroughly purged with nitrogen was charged with 250 ml of toluene, propylene was circulated in an amount of 150 liters / hour, and kept at 25 ° C. for 20 minutes.
- the amount of zirconium atoms contained in the toluene solution in an amount of 0 ⁇ OOlmmol (and hence the amount of aluminum atoms contained in 0.3 mmo 1) is sampled and added to the polymerization vessel.
- Polymerization was carried out for 10 minutes while maintaining the pressure at 1.37 MPa with ethylene, and 20 ml of methanol was added to terminate the polymerization.
- the polymer was precipitated from the polymerization solution in 4 L of methanol and dried under vacuum at 130 ° C. for 12 hours.
- Table 4 shows the measured physical properties of the obtained polymer. The rr value was 75%.
- di (p-chlorophenyl) methylene (cyclopentageninole) (Otamethinoleoctahydrodibenzofunenolenenole) dinolecodichloride and methylaluminoxane in toluene (Tosohichi Finechem)
- cyclopentageninole Otamethinoleoctahydrodibenzofunenolenenole
- di (p-chlorophenyl) methylene (cyclopentageninole) (Otamethinoleoctahydrodibenzofunenolenenole) dinolecodichloride and methylaluminoxane in toluene (Tosohichi Finechem)
- cyclopentageninole Otamethinoleoctahydrodibenzofunenolenenole
- di (p-chlorophenyl) methylene (cyclopentageninole) (Otamethinoleoctahydrodibenzofunenolenenole) dinolecodichloride and methylaluminoxane in toluene (Tosohichi Finechem)
- cyclopentageninole Otamethinoleoctahydrodibenzofunenolenenole
- di (p-chlorophenyl) methylene (cyclopentadienyl) (otatamethyloctahydrodibenzofluorenore) zirconium dichloride and a solution of methylaluminoxane in toluene (Tosohichi, Finechem) and To prepare a toluene solution containing aluminum atoms and zirconium atomic energy at a ratio of aluminum atoms / zirconium atoms 300/1 (molar ratio).
- diphenylmethylene (3-tert-butyl-5-ethylcyclopentaenyl) (2,7-di-tert-butylfluorenyl) zirconium dichloride synthesized in Catalyst Synthesis Example 4 and toluene of methylaluminoxane were used.
- an amount containing 0.001 mmol of zirconium atoms (and therefore 0.3 mmol of aluminum atoms) is sampled and added to the polymerization vessel, and the internal temperature is set to 55 ° C and the internal pressure is set. Polymerization was continued for 25 minutes while maintaining ethylene at 75 MPa, and 20 ml of methanol was added to terminate the polymerization.
- Table 6 shows the physical properties of the propylene polymers (DD-1) to (DD-8).
- the solar cell sealing sheet of the present invention has excellent heat resistance even when it is not crosslinked.
- good heat resistance can be achieved without generating decomposition gas that adversely affects the solar cell element, and without crosslinking the composition. Flexibility, solar cell sealing (heat laminating at wide temperature range) ⁇ Mechanical strength ⁇ Transparent solar cell sealing sheet can be obtained.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Electromagnetism (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Photovoltaic Devices (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008527733A JP5355087B2 (ja) | 2006-07-31 | 2007-07-27 | 太陽電池封止用熱可塑性樹脂組成物、太陽電池封止用シートおよび太陽電池 |
KR1020097004097A KR101122486B1 (ko) | 2006-07-31 | 2007-07-27 | 태양 전지 밀봉용 열가소성 수지 조성물, 태양 전지 밀봉용시트 및 태양 전지 |
US12/309,602 US8101684B2 (en) | 2006-07-31 | 2007-07-27 | Thermoplastic resin composition for sealing solar cell, sheet for sealing solar cell and solar cell |
EP07791502.3A EP2048194A4 (en) | 2006-07-31 | 2007-07-27 | THERMOPLASTIC RESIN COMPOSITION FOR SOLAR CELL SIDING, SHEET FOR SOLAR CELL SIEFING, AND SOLAR CELL |
CN2007800271904A CN101490168B (zh) | 2006-07-31 | 2007-07-27 | 太阳能电池密封用热塑性树脂组合物、太阳能电池密封用片材及太阳能电池 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006-209266 | 2006-07-31 | ||
JP2006209266 | 2006-07-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008015984A1 true WO2008015984A1 (fr) | 2008-02-07 |
Family
ID=38997163
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2007/064808 WO2008015984A1 (fr) | 2006-07-31 | 2007-07-27 | Composition de résine thermoplastique pour scellement de cellule solaire, feuille pour scellement de cellule solaire et cellule solaire |
Country Status (6)
Country | Link |
---|---|
US (1) | US8101684B2 (ja) |
EP (1) | EP2048194A4 (ja) |
JP (1) | JP5355087B2 (ja) |
KR (1) | KR101122486B1 (ja) |
CN (1) | CN101490168B (ja) |
WO (1) | WO2008015984A1 (ja) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010222455A (ja) * | 2009-03-23 | 2010-10-07 | Mitsui Chemicals Inc | ポリオレフィン系樹脂組成物 |
WO2011096389A1 (ja) | 2010-02-02 | 2011-08-11 | 日本ゼオン株式会社 | 太陽電池素子封止用樹脂組成物及び太陽電池モジュール |
WO2011162324A1 (ja) * | 2010-06-25 | 2011-12-29 | 日本ポリエチレン株式会社 | 太陽電池封止材用樹脂組成物、及びそれを用いた太陽電池封止材と太陽電池モジュール |
WO2012014965A1 (ja) * | 2010-07-28 | 2012-02-02 | 三菱樹脂株式会社 | 太陽電池封止材及びそれを用いて作製された太陽電池モジュール |
WO2012043708A1 (ja) | 2010-09-29 | 2012-04-05 | 日本ゼオン株式会社 | アルコキシシリル基を有するブロック共重合体水素化物及びその利用 |
JP2013229618A (ja) * | 2010-11-02 | 2013-11-07 | Mitsui Chemicals Inc | 太陽電池封止材および太陽電池モジュール |
WO2014077267A1 (ja) | 2012-11-15 | 2014-05-22 | 日本ゼオン株式会社 | 樹脂組成物およびそれからなる成形体 |
US8991039B2 (en) | 2010-09-30 | 2015-03-31 | Dow Global Technologies Llc | Method for manufacturing flexible multilayer electrical articles with improved layer adhesion |
JP2016051772A (ja) * | 2014-08-29 | 2016-04-11 | 三菱樹脂株式会社 | 太陽電池モジュール及びその製造方法 |
JP2016051771A (ja) * | 2014-08-29 | 2016-04-11 | 三菱樹脂株式会社 | 太陽電池ダミーモジュール及びその製造方法 |
JP2016111356A (ja) * | 2014-11-28 | 2016-06-20 | 京セラ株式会社 | 太陽電池モジュールおよび太陽電池モジュールの製造方法 |
KR20230049180A (ko) * | 2021-10-05 | 2023-04-13 | 율촌화학 주식회사 | 무펠렛 합성 수지 태양전지 봉지재 필름 제조방법 및 이로부터 제조된 무펠렛 합성 수지 태양전지 봉지재 필름 |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI391405B (zh) * | 2005-05-18 | 2013-04-01 | Mitsui Chemicals Inc | 丙烯系聚合體、丙烯系聚合體組成物及該等之用途 |
US7863368B2 (en) | 2006-11-17 | 2011-01-04 | Mitsui Chemicals, Inc. | Propylene resin composition, process for producing propylene resin composition, propylene polymer composition, shaped article produced of the propylene resin composition, and electric wire |
CN102217091B (zh) | 2009-07-17 | 2012-11-21 | 三菱树脂株式会社 | 太阳能电池封装材料以及使用该封装材料制作的太阳能电池组件 |
WO2012050093A1 (ja) * | 2010-10-12 | 2012-04-19 | 三菱樹脂株式会社 | 透明性及び防湿性に優れた樹脂組成物、並びに、それを成形してなるシート |
EP2763188A4 (en) * | 2011-09-29 | 2015-05-27 | Sanyo Electric Co | SOLAR CELL MODULE |
US9640676B2 (en) * | 2012-06-29 | 2017-05-02 | Sunpower Corporation | Methods and structures for improving the structural integrity of solar cells |
CN105017637B (zh) * | 2014-04-16 | 2017-08-25 | 中国石化扬子石油化工有限公司 | 一种高透明长支链聚丙烯/弹性体组合物及其制备方法 |
JP6490086B2 (ja) * | 2014-09-10 | 2019-03-27 | 三井化学株式会社 | 潤滑油組成物 |
US20170025991A1 (en) * | 2015-07-23 | 2017-01-26 | Flexwave Co., Ltd. | Portable photovoltaic device |
US11492471B2 (en) | 2016-07-21 | 2022-11-08 | Mitsui Chemicals, Inc. | Polypropylene resin composition and monolayer and multilayer film |
DE102018213627B4 (de) | 2017-08-17 | 2022-03-10 | Armor Solar Power Films Gmbh | Flächenmaterial mit Photovoltaikmodul, Erzeugnis mit einer solchen Flächenmaterial und Verfahren zur Herstellung einer Flächenmaterial |
CN111690086B (zh) * | 2020-06-19 | 2022-11-08 | 浙江大学衢州研究院 | 太阳能电池封装用快速交联型丙烯基聚烯烃的制备方法 |
EP4206294A4 (en) * | 2020-12-17 | 2024-04-24 | Hangzhou First Applied Material Co., Ltd. | ENCAPSULATION COMPOSITION, COMPOSITION, ENCAPSULATION GLUE FILM, ELECTRONIC COMPONENT AND SOLAR CELL ASSEMBLY |
CA3237354A1 (en) * | 2021-11-05 | 2023-05-11 | Exxonmobil Chemical Patents Inc. | Syndiotactic propylene-based ethylene-propylene copolymers |
CN118202023A (zh) | 2021-11-05 | 2024-06-14 | 埃克森美孚化学专利公司 | 聚丙烯粘度改性剂及其润滑油 |
Citations (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01501950A (ja) | 1987-01-30 | 1989-07-06 | エクソン・ケミカル・パテンツ・インク | 触媒、これらの触媒の製法およびこれらの触媒を使用する重合プロセス |
US4960878A (en) | 1988-12-02 | 1990-10-02 | Texas Alkyls, Inc. | Synthesis of methylaluminoxanes |
US5321106A (en) | 1990-07-03 | 1994-06-14 | The Dow Chemical Company | Addition polymerization catalyst with oxidative activation |
JP2000091611A (ja) | 1998-09-17 | 2000-03-31 | Dainippon Printing Co Ltd | 太陽電池のカバーフィルムおよびその製造方法、およびそのカバーフィルムを用いた太陽電池モジュール |
WO2001027124A1 (fr) | 1999-10-08 | 2001-04-19 | Mitsui Chemicals, Inc. | Compose metallocene, son procede de fabrication, catalyseur de polymerisation d'olefine, procede de production de polyolefine et polyolefine |
JP2002097325A (ja) | 2000-09-20 | 2002-04-02 | Mitsui Chemicals Inc | シンジオタクティックポリプロピレン系共重合体組成物および成形体 |
JP2003147135A (ja) | 2001-11-08 | 2003-05-21 | Mitsui Chemicals Inc | ポリプロピレン樹脂組成物 |
WO2004008777A1 (en) | 2002-07-12 | 2004-01-22 | General Instrument Corporation | A method and managing reference frame and field buffers in adaptive frame/field encoding |
WO2004029062A1 (ja) | 2002-09-27 | 2004-04-08 | Mitsui Chemicals, Inc. | オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法 |
JP2004189666A (ja) | 2002-12-11 | 2004-07-08 | Mitsui Chemicals Inc | オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法 |
JP2004210943A (ja) * | 2002-12-27 | 2004-07-29 | Mitsui Chemicals Inc | シンジオタクティックプロピレン系重合体組成物 |
JP2004285318A (ja) * | 2003-01-27 | 2004-10-14 | Mitsui Chemicals Inc | プロピレン系重合体組成物 |
WO2006057361A1 (ja) * | 2004-11-25 | 2006-06-01 | Mitsui Chemicals, Inc. | プロピレン系樹脂組成物およびその用途 |
WO2006070793A1 (ja) * | 2004-12-28 | 2006-07-06 | Du Pont/Mitsui Polychemicals Co. Ltd. | 太陽電池封止材 |
JP2006176600A (ja) * | 2004-12-21 | 2006-07-06 | Mitsui Chemicals Inc | 熱可塑性樹脂組成物、成形体およびその用途 |
JP2006210905A (ja) * | 2004-12-28 | 2006-08-10 | Mitsui Chemical Fabro Inc | 太陽電池封止材 |
WO2006123759A1 (ja) * | 2005-05-18 | 2006-11-23 | Mitsui Chemicals, Inc. | オレフィン重合用触媒、オレフィン重合体の製造方法、プロピレン系共重合体の製造方法、プロピレン重合体、プロピレン系重合体組成物およびこれらの用途 |
WO2007061030A1 (ja) * | 2005-11-25 | 2007-05-31 | Mitsui Chemicals, Inc. | 太陽電池封止材、太陽電池封止用シートおよびそれらを用いた太陽電池モジュール |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW272986B (ja) * | 1993-07-28 | 1996-03-21 | Mitsui Petroleum Chemicals Ind | |
US6632885B2 (en) * | 1999-04-13 | 2003-10-14 | Mitsui Chemicals, Inc. | Soft syndiotactic polypropylene composition and molded product |
US7629416B2 (en) * | 2002-08-12 | 2009-12-08 | Exxonmobil Chemical Patents Inc. | Plasticized polyolefin compositions |
KR20070072586A (ko) * | 2003-01-27 | 2007-07-04 | 미쯔이가가꾸가부시끼가이샤 | 프로필렌계 중합체 조성물 및 그의 용도 |
KR101004338B1 (ko) * | 2003-03-28 | 2010-12-28 | 미쓰이 가가쿠 가부시키가이샤 | 프로필렌/1―부텐 공중합체, 폴리프로필렌 조성물 및 그 용도, 및 폴리프로필렌 복합 필름 |
JP4949019B2 (ja) * | 2004-04-19 | 2012-06-06 | 三井化学株式会社 | α−オレフィン系重合体組成物、該組成物からなる成形体、新規重合体 |
JP4082701B2 (ja) * | 2004-08-20 | 2008-04-30 | 金子農機株式会社 | 溝切機 |
JP2007302853A (ja) * | 2005-05-18 | 2007-11-22 | Mitsui Chemicals Inc | プロピレン系共重合体の製造方法 |
JP5105772B2 (ja) * | 2005-07-25 | 2012-12-26 | 三井化学株式会社 | シンジオタクティックα−オレフィン重合体の製造方法 |
JP5374606B2 (ja) * | 2006-01-20 | 2013-12-25 | 三井化学株式会社 | プロピレン系重合体組成物およびその用途 |
JP5068038B2 (ja) * | 2006-01-20 | 2012-11-07 | 三井化学株式会社 | プロピレン系重合体組成物の製造方法 |
JP4912753B2 (ja) * | 2006-01-20 | 2012-04-11 | 三井化学株式会社 | プロピレン系重合体組成物、該組成物からなる成形体 |
JP5382982B2 (ja) * | 2006-02-24 | 2014-01-08 | 三井化学株式会社 | プロピレン重合体、及び該重合体から得られる成形体 |
US7863368B2 (en) * | 2006-11-17 | 2011-01-04 | Mitsui Chemicals, Inc. | Propylene resin composition, process for producing propylene resin composition, propylene polymer composition, shaped article produced of the propylene resin composition, and electric wire |
CN101578306B (zh) * | 2007-02-15 | 2012-08-08 | 三井化学株式会社 | 丙烯类聚合物、丙烯类聚合物组合物、粒料和粘合剂 |
CN101903463B (zh) * | 2007-12-27 | 2013-03-20 | 三井化学株式会社 | 丙烯类聚合物组合物 |
-
2007
- 2007-07-27 US US12/309,602 patent/US8101684B2/en not_active Expired - Fee Related
- 2007-07-27 CN CN2007800271904A patent/CN101490168B/zh not_active Expired - Fee Related
- 2007-07-27 EP EP07791502.3A patent/EP2048194A4/en not_active Withdrawn
- 2007-07-27 KR KR1020097004097A patent/KR101122486B1/ko not_active IP Right Cessation
- 2007-07-27 JP JP2008527733A patent/JP5355087B2/ja not_active Expired - Fee Related
- 2007-07-27 WO PCT/JP2007/064808 patent/WO2008015984A1/ja active Application Filing
Patent Citations (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01501950A (ja) | 1987-01-30 | 1989-07-06 | エクソン・ケミカル・パテンツ・インク | 触媒、これらの触媒の製法およびこれらの触媒を使用する重合プロセス |
US4960878A (en) | 1988-12-02 | 1990-10-02 | Texas Alkyls, Inc. | Synthesis of methylaluminoxanes |
US5321106A (en) | 1990-07-03 | 1994-06-14 | The Dow Chemical Company | Addition polymerization catalyst with oxidative activation |
JP2000091611A (ja) | 1998-09-17 | 2000-03-31 | Dainippon Printing Co Ltd | 太陽電池のカバーフィルムおよびその製造方法、およびそのカバーフィルムを用いた太陽電池モジュール |
WO2001027124A1 (fr) | 1999-10-08 | 2001-04-19 | Mitsui Chemicals, Inc. | Compose metallocene, son procede de fabrication, catalyseur de polymerisation d'olefine, procede de production de polyolefine et polyolefine |
JP2002097325A (ja) | 2000-09-20 | 2002-04-02 | Mitsui Chemicals Inc | シンジオタクティックポリプロピレン系共重合体組成物および成形体 |
JP2003147135A (ja) | 2001-11-08 | 2003-05-21 | Mitsui Chemicals Inc | ポリプロピレン樹脂組成物 |
WO2004008777A1 (en) | 2002-07-12 | 2004-01-22 | General Instrument Corporation | A method and managing reference frame and field buffers in adaptive frame/field encoding |
WO2004029062A1 (ja) | 2002-09-27 | 2004-04-08 | Mitsui Chemicals, Inc. | オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法 |
JP2004189666A (ja) | 2002-12-11 | 2004-07-08 | Mitsui Chemicals Inc | オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法 |
JP2004210943A (ja) * | 2002-12-27 | 2004-07-29 | Mitsui Chemicals Inc | シンジオタクティックプロピレン系重合体組成物 |
JP2004285318A (ja) * | 2003-01-27 | 2004-10-14 | Mitsui Chemicals Inc | プロピレン系重合体組成物 |
WO2006057361A1 (ja) * | 2004-11-25 | 2006-06-01 | Mitsui Chemicals, Inc. | プロピレン系樹脂組成物およびその用途 |
JP2006176600A (ja) * | 2004-12-21 | 2006-07-06 | Mitsui Chemicals Inc | 熱可塑性樹脂組成物、成形体およびその用途 |
WO2006070793A1 (ja) * | 2004-12-28 | 2006-07-06 | Du Pont/Mitsui Polychemicals Co. Ltd. | 太陽電池封止材 |
JP2006210905A (ja) * | 2004-12-28 | 2006-08-10 | Mitsui Chemical Fabro Inc | 太陽電池封止材 |
WO2006123759A1 (ja) * | 2005-05-18 | 2006-11-23 | Mitsui Chemicals, Inc. | オレフィン重合用触媒、オレフィン重合体の製造方法、プロピレン系共重合体の製造方法、プロピレン重合体、プロピレン系重合体組成物およびこれらの用途 |
WO2007061030A1 (ja) * | 2005-11-25 | 2007-05-31 | Mitsui Chemicals, Inc. | 太陽電池封止材、太陽電池封止用シートおよびそれらを用いた太陽電池モジュール |
Non-Patent Citations (1)
Title |
---|
See also references of EP2048194A4 |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010222455A (ja) * | 2009-03-23 | 2010-10-07 | Mitsui Chemicals Inc | ポリオレフィン系樹脂組成物 |
WO2011096389A1 (ja) | 2010-02-02 | 2011-08-11 | 日本ゼオン株式会社 | 太陽電池素子封止用樹脂組成物及び太陽電池モジュール |
WO2011162324A1 (ja) * | 2010-06-25 | 2011-12-29 | 日本ポリエチレン株式会社 | 太陽電池封止材用樹脂組成物、及びそれを用いた太陽電池封止材と太陽電池モジュール |
US10030085B2 (en) | 2010-06-25 | 2018-07-24 | Japan Polyethylene Corporation | Resin composition for solar cell encapsulant, and solar cell encapsulant and solar cell module using the same |
JP5625060B2 (ja) * | 2010-07-28 | 2014-11-12 | 三菱樹脂株式会社 | 太陽電池封止材及びそれを用いて作製された太陽電池モジュール |
WO2012014965A1 (ja) * | 2010-07-28 | 2012-02-02 | 三菱樹脂株式会社 | 太陽電池封止材及びそれを用いて作製された太陽電池モジュール |
JPWO2012014965A1 (ja) * | 2010-07-28 | 2013-09-12 | 三菱樹脂株式会社 | 太陽電池封止材及びそれを用いて作製された太陽電池モジュール |
US9447272B2 (en) | 2010-07-28 | 2016-09-20 | Dai Nippon Printing Co., Ltd | Solar cell sealing material, and solar cell module prepared by using same |
WO2012043708A1 (ja) | 2010-09-29 | 2012-04-05 | 日本ゼオン株式会社 | アルコキシシリル基を有するブロック共重合体水素化物及びその利用 |
US8991039B2 (en) | 2010-09-30 | 2015-03-31 | Dow Global Technologies Llc | Method for manufacturing flexible multilayer electrical articles with improved layer adhesion |
JP2013229618A (ja) * | 2010-11-02 | 2013-11-07 | Mitsui Chemicals Inc | 太陽電池封止材および太陽電池モジュール |
WO2014077267A1 (ja) | 2012-11-15 | 2014-05-22 | 日本ゼオン株式会社 | 樹脂組成物およびそれからなる成形体 |
US9493688B2 (en) | 2012-11-15 | 2016-11-15 | Zeon Corporation | Resin composition and molded article comprising same |
JP2016051772A (ja) * | 2014-08-29 | 2016-04-11 | 三菱樹脂株式会社 | 太陽電池モジュール及びその製造方法 |
JP2016051771A (ja) * | 2014-08-29 | 2016-04-11 | 三菱樹脂株式会社 | 太陽電池ダミーモジュール及びその製造方法 |
JP2016111356A (ja) * | 2014-11-28 | 2016-06-20 | 京セラ株式会社 | 太陽電池モジュールおよび太陽電池モジュールの製造方法 |
KR20230049180A (ko) * | 2021-10-05 | 2023-04-13 | 율촌화학 주식회사 | 무펠렛 합성 수지 태양전지 봉지재 필름 제조방법 및 이로부터 제조된 무펠렛 합성 수지 태양전지 봉지재 필름 |
KR102594265B1 (ko) * | 2021-10-05 | 2023-10-27 | 율촌화학 주식회사 | 무펠렛 합성 수지 태양전지 봉지재 필름 제조방법 및 이로부터 제조된 무펠렛 합성 수지 태양전지 봉지재 필름 |
Also Published As
Publication number | Publication date |
---|---|
JP5355087B2 (ja) | 2013-11-27 |
JPWO2008015984A1 (ja) | 2009-12-24 |
US8101684B2 (en) | 2012-01-24 |
EP2048194A1 (en) | 2009-04-15 |
EP2048194A4 (en) | 2014-03-26 |
KR101122486B1 (ko) | 2012-04-23 |
US20100000600A1 (en) | 2010-01-07 |
CN101490168A (zh) | 2009-07-22 |
CN101490168B (zh) | 2012-05-23 |
KR20090035023A (ko) | 2009-04-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5355087B2 (ja) | 太陽電池封止用熱可塑性樹脂組成物、太陽電池封止用シートおよび太陽電池 | |
TWI405842B (zh) | 太陽電池密封材與其用途、及聚合體組成物 | |
CN101087842B (zh) | 太阳能电池密封材料 | |
JP5344909B2 (ja) | 熱可塑性樹脂組成物、太陽電池封止用シートおよび太陽電池 | |
CN101138095B (zh) | 太阳能电池密封材料 | |
CN104137277B (zh) | 太阳能电池密封用片组件 | |
JP5774065B2 (ja) | プロピレン系樹脂組成物、プロピレン系樹脂組成物の製造方法、該プロピレン系樹脂組成物からなる成形体および電線 | |
CN102449060B (zh) | 乙烯系树脂组合物、太阳能电池密封材料和使用其的太阳能电池组件 | |
TWI606088B (zh) | 太陽電池封裝材及太陽電池模組 | |
KR101929101B1 (ko) | 태양 전지 밀봉재 및 태양 전지 모듈 | |
JP5444039B2 (ja) | 樹脂組成物、太陽電池封止材及びそれを用いた太陽電池モジュール | |
WO2013186992A1 (ja) | 太陽電池封止材および太陽電池モジュール | |
JP6488817B2 (ja) | 太陽電池封止材用樹脂組成物の製造方法、それを用いた太陽電池封止材及び太陽電池モジュール | |
JP5801733B2 (ja) | 太陽電池封止材および太陽電池モジュール | |
JP6984128B2 (ja) | ポリエチレン樹脂の製造方法並びに当該方法により製造されたポリエチレン樹脂を用いた太陽電池封止材および太陽電池モジュール | |
KR20140064811A (ko) | 봉지재 | |
JP2014208774A (ja) | エチレン系共重合体、並びにそれを用いた太陽電池封止材及び太陽電池モジュール | |
JP6898426B2 (ja) | 樹脂組成物、シート、太陽電池封止材、太陽電池モジュール、太陽電池封止材用シートの製造方法 | |
JP4920379B2 (ja) | プロピレン系樹脂フィルムまたはシート、または該フィルムまたはシートを含んでなる積層体、プロピレン系重合体組成物および該組成物からなるペレット | |
JP2010232457A (ja) | 太陽電池封止材および太陽電池モジュール | |
JP2012214555A (ja) | 樹脂組成物、シート成形物および太陽電池封止材 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200780027190.4 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 07791502 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2008527733 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 12309602 Country of ref document: US |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2007791502 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020097004097 Country of ref document: KR |
|
NENP | Non-entry into the national phase |
Ref country code: RU |