WO2007108562A1 - 位相差フィルムおよびその製造方法 - Google Patents
位相差フィルムおよびその製造方法 Download PDFInfo
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- WO2007108562A1 WO2007108562A1 PCT/JP2007/057009 JP2007057009W WO2007108562A1 WO 2007108562 A1 WO2007108562 A1 WO 2007108562A1 JP 2007057009 W JP2007057009 W JP 2007057009W WO 2007108562 A1 WO2007108562 A1 WO 2007108562A1
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- WIPO (PCT)
- Prior art keywords
- film
- stretching
- polypropylene resin
- retardation film
- retardation
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/10—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
- B29C55/12—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
- B29C55/14—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial successively
- B29C55/143—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial successively firstly parallel to the direction of feed and then transversely thereto
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/10—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
- B29C55/12—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
- B29C55/14—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial successively
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/13363—Birefringent elements, e.g. for optical compensation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
- B29K2995/0034—Polarising
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3083—Birefringent or phase retarding elements
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/13363—Birefringent elements, e.g. for optical compensation
- G02F1/133634—Birefringent elements, e.g. for optical compensation the refractive index Nz perpendicular to the element surface being different from in-plane refractive indices Nx and Ny, e.g. biaxial or with normal optical axis
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
- Y10S264/90—Direct application of fluid pressure differential to shape, reshape, i.e. distort, or sustain an article or preform and heat-setting, i.e. crystallizing of stretched or molecularly oriented portion thereof
- Y10S264/901—Heat-setting of stretched or molecularly oriented article formed from planar preform, e.g. sheet, film
Definitions
- the present invention relates to a retardation film made of polypropylene resin and a method for producing the same.
- a liquid crystal display device usually includes a combination of a liquid crystal and a retardation film.
- a retardation film obtained by using a polycarbonate resin or a cyclic olefin-based polymer resin as a film and further stretching the film (for example, Japanese Patent Application Laid-Open Nos. 0-7 2 5 6 7 49 and (See Japanese Patent Laid-Open No. 05-210 8).
- these raw materials are expensive. Therefore, development of a phase difference film made of an inexpensive plastic material is desired.
- Japanese Patent Application Laid-Open No. Sho 60-2504.02 discloses a retardation plate made of a polyolefin resin. According to this document, this retardation plate is manufactured by pulling out the resin extruded from the discharge port of the T-die while cooling it so that it is somewhat stretched.
- a film obtained by such a method of stretching in the longitudinal uniaxial direction has non-uniform orientation in the film width direction and unevenness in retardation or unevenness in thickness in the width direction. Therefore, it is not suitable as a retardation film. Disclosure of the invention
- An object of the present invention is to provide a polypropylene resin phase difference film having high axial accuracy and a uniform phase difference, and a method for producing the same.
- a method for producing a retardation film made of a polypropylene resin comprising subjecting a film made of a polypropylene resin to a longitudinal stretching and a lateral stretching performed sequentially. Stretching is characterized by having the following steps: Provide a method.
- this invention provides the retardation film made from a polypropylene resin obtained by the said method in another side surface.
- the polypropylene resin constituting the retardation film of the present invention is a copolymer of propylene and one or more monomers selected from the group consisting of a propylene homopolymer, ethylene and ⁇ -olefin having 4 to 20 carbon atoms. It is a polymer. Also, a mixture of these may be used.
- ⁇ -olefin examples include 1-butene, 2-methyl-1-propene, 1-pentene, 2-methyl-1-butene, 3-methyl-1-butene, 1-hexene, 2-ethyl-1-butene. , 2, 3-dimethyl-1-butene, 2-methyl-1-pentene, 3-methyl-1-pentene, 4-methyl_1-pentene, 3, 3-dimethyl-1-butene, 1-heptene, 2-methyl-1 Hexene, 2, 3-dimethyl- 1-pentene, 2-ethyl- 1-pentene, 1-year-old kuten, 1-year-old ketene, 3-ethyl-1-hexene, 3-3-dimethyl-1, 1-hexene, 2-propyl-1, 1-heptene 2-methyl-3-ethyl 1-heptene, 2, 3, 4-pentylmethyl 1-pentene, 2-propyl 1-1 1-pentene, 2, 3-jetyl 1-butene, 1-nonene, 1-
- the polypropylene resin is preferably a propylene / ethylene copolymer or a propylene / 1-butene copolymer. Further, when the polypropylene resin is a copolymer of propylene and one or more monomers selected from the group consisting of ethylene and chloroolefin having 4 to 20 carbon atoms, the copolymer is randomly selected. It may be a copolymer or a block copolymer.
- a polypropylene resin having a parameter (A) determined by the following resin selection test in the range of 0.07 to 1.0 is preferable.
- An example of a polypropylene resin having a parameter (A) of 0.07 to 1.0 is a propylene random copolymer.
- a 0.1 mm thick film is produced by hot press molding polypropylene resin.
- the resin In the hot press molding, after preheating for 5 minutes the resin with 230 ° C, pressure 2 min retention was raised to 1 00 kg f / cm2 over 3 minutes at the same temperature, then, 30 kg FZC m 2 at 30 ° C Cool for 5 minutes at the same pressure.
- the stress-strain curve (S-S curve) observed when the film is stretched according to JISK-7113 at a temperature at which the tensile test speed is 100 mmZm in and the stress at a strain of 200% is 10 ⁇ lkgZcm 2.
- the tensile test is performed in a thermostatic chamber using a tensile tester equipped with a thermostatic chamber.
- propylene random copolymer examples include a propylene random copolymer obtained by copolymerizing propylene, ethylene, and one or more monomers selected from the group consisting of 4-year-old olefins having 4 to 20 carbon atoms. Can be mentioned.
- refin having 4 to 20 carbon atoms include 1-butene, 2-methyl-1-propene, 1-1-pentene, 2-methyl-1-butene, 3-methyl-1-butene, 1 —Hexene, 2-ethyl-butene, 2,3-dimethyl— 1-butene, 2-methyl-1-pentene, 3-methyl-1-pentene, 4-methyl-1, 1-pentene, 3, 3-dimethyl-1-pentene, 1-1 heptene, 2-methyl-1-hexene, 2, 3 —Dimethyl-1-pentene, 2-ethyl— 1-pentene, 1-octene, 2-ethyl-1-hexene, 3, 3-dimethyl-1-hexene, 2-propyl pill—1-1 heptene, 2-methyl-3 —Ethylu 1-heptene, 2,3,4-trimethyl 1-pentene, 2-propyl 1 1-pentene, 2,3-jetyl 1_butene, 1-nonene
- propylene random copolymer examples include propylene monoethylene random copolymer, propylene-0! -Olefin random copolymer, propylene-ethylene-one-year-old refin random copolymer, and the like. It is done. More specifically, examples of the propylene-hydroolefin random copolymer include propylene 1-1-butene random copolymer, propylene-1-hexene random copolymer, and propylene-1-octene random copolymer.
- propylene-ethylene-one-year-old refin random copolymer examples include, for example, propylene monoethylene mono-1-butene random copolymer, propylene monoethylene-1-hexene random copolymer, propylene monoethylene 1-octene random copolymer, preferably propylene monoethylene random copolymer, propylene mono 1-butene random copolymer, propylene- 1-hexene random copolymer, propylene monoethylene mono 1- Butene random copolymer, propylene-ethylene-1-hexene It is a random copolymer.
- the content of the structural unit derived from the comonomer in the copolymer is preferably more than 0% by weight and 40% by weight or less from the viewpoint of the balance between transparency and heat resistance. More preferably, the content is more than 0% by weight and 20% by weight, more preferably more than 0% by weight and 10% by weight. In the case of a copolymer of two or more types of comonomer and propylene, it is derived from all the monomers contained in the copolymer. The total content of the structural units is preferably in the above range.
- the melt flow rate (MFR) of polypropylene resin is usually 0.1 to 200 g / 10 min as measured at a temperature of 230 ° C and a load of 21.18 N in accordance with JIS K7210, preferably 0 5-50 gZl 0 minutes.
- the molecular weight distribution of the polypropylene-based polymer is defined by the ratio of the weight average molecular weight Mw to the number average molecular weight Mn, and is usually 1-20.
- Mn and Mw are measured by GPC using o-dichlorobenzene at 140 ° C as the solvent and polystyrene as the standard sample.
- the melting point of the polypropylene resin is usually 120 to 170 ° C.
- the melting point is defined as the temperature at which the highest peak appears in the melting curve measured with a differential scanning calorimeter (DSC).
- DSC differential scanning calorimeter
- a method for producing a polypropylene resin one or more selected from the group consisting of a method of homopolymerizing propylene using a known polymerization catalyst, or an ⁇ -aged refin having 4 to 20 carbon atoms. And a method of copolymerizing the monomer and propylene.
- T i — Mg-based catalyst comprising a solid catalyst component containing magnesium, titanium and halogen as essential components
- the catalyst system used for the production of the propylene polymer is a combination of an organic aluminum compound and an electron donating compound with a solid catalyst component containing magnesium, titanium and octalogen as essential components.
- Catalytic systems are most commonly used.
- the organoaluminum compound preferably includes triethylaluminum, triisobutylaluminum, a mixture of triethylaluminum and jetylaluminum chloride, and tetraethyldialumoxane.
- solid catalyst components containing magnesium, titanium, and octalogen as essential components include, for example, Japanese Patent Application Laid-Open Nos. Sho 6 1-2 186 60, Japanese Patent Sho 6 1-287 904, Examples include catalyst systems described in Kaihei 7-2 1 60 1 7 and the like.
- the metallocene catalyst include catalyst systems described in Japanese Patent No. 2 5 8 7 2 51, Japanese Patent No. 2 6 2 7 6 6 9, and Japanese Patent No. 2 6 6 8 7 3 2. .
- Polymerization methods used for the production of polypropylene resins include hexane, heptane, octane, decane, cyclohexane, methylcyclohexane, benzene, toluene, solvents using inert solvents typified by hydrocarbon compounds such as xylene. Examples thereof include a polymerization method, a bulk polymerization method using a liquid monomer as a solvent, a gas phase polymerization method performed in a gas monomer, and the bulk polymerization method or the gas phase polymerization method is preferable. These polymerization methods may be a batch method or a continuous method.
- the stereoregularity of the polypropylene resin may be any of isotactic, syndiotactic and atactic forms.
- the polypropylene resin is preferably a syndiotactic or isotactic propylene polymer from the viewpoint of heat resistance.
- the polypropylene resin may be a blend of two or more types of polypropylene polymers having different molecular weights, proportions of structural units derived from propylene, etc., or may contain polymers and additives other than polypropylene polymers as appropriate. Good.
- additives that the polypropylene resin can contain include antioxidants, ultraviolet absorbers, antistatic agents, lubricants, nucleating agents, antifogging agents, and antiblocking agents.
- Antioxidants include phenolic antioxidants, phosphorus antioxidants, sulfur antioxidants, hindered amine antioxidants (HA LS), and phenolic and phosphorus antioxidants in one molecule. Examples include a composite type antioxidant having a mechanism and a unit.
- UV absorber examples include UV absorbers such as 2-hydroxybenzophenone and hydroxytriazole, and UV blockers such as benzoate.
- antistatic agent examples include a polymer type, an oligomer type, and a monomer type.
- the lubricant examples include higher fatty acid amides such as gallic acid amide and oleic acid amide, higher fatty acids such as stearic acid, and metal salts thereof.
- the nucleating agent examples include a sorbitol nucleating agent, an organic phosphate nucleating agent, and a polymer nucleating agent such as polypinylcycloalkane.
- antiblocking agent inorganic or organic fine particles having a spherical shape or a shape close thereto can be used. Each of the above additives may be used in combination.
- the retardation film of the present invention is produced by stretching a raw film made of polypropylene resin under the conditions described above.
- the raw film it is preferable to use an optically homogeneous non-oriented film or a non-oriented film. Specifically, it is preferable to use a film having an in-plane retardation of 30 nm or less.
- the method for producing the raw film include a solvent casting method and an extrusion molding method. In the former method, a solution in which a thermoplastic resin is dissolved in an organic solvent is cast on a substrate such as a biaxially stretched polyester film having releasability by a die coater, and then dried to remove the organic solvent. A method of forming a film on a substrate.
- the film formed on the base material by such a method is peeled off from the base material and used as a cocoon original film.
- the latter method is a method in which a thermoplastic resin is melt-kneaded in an extruder, then extruded from a T die, brought into contact with a roll and taken out while being cooled and solidified to obtain a film.
- the polypropylene resin film produced by this method is used as it is in the method of the present invention as a raw film. Extrusion molding from the viewpoint of raw film production costs The method is preferred.
- the melt extruded from the die is cooled and solidified by using a casting roll and an air chamber, or by using a casting roll and an evening roll.
- a casting roll and an air chamber or by using a casting roll and an evening roll.
- Examples thereof include a method of pinching and a method of pressing between a casting roll and a metal endless belt provided so as to be pressed against the casting roll along its circumferential direction.
- the surface temperature of the casting roll used is preferably 0 to 30 ° C. in order to obtain a retardation film having better transparency.
- the touch roll is an outer cylinder made of a rubber roll or a metal endless belt that can be elastically deformed. And a roll made of an elastic body that can be elastically deformed inside the outer cylinder, and a roll having a structure in which a space between the outer cylinder and the elastic roll is filled with a temperature adjusting medium. I like it.
- the support is preferably a biaxially stretched film made of a thermoplastic resin having a thickness of 5 to 50 m.
- the endless belt is formed of the casting roll. It is preferably held by a plurality of rolls arranged in the circumferential direction in parallel with the casting roll. More preferably, the endless bell rod is held by two rolls having a diameter of 100 to 300 mm, and the thickness of the endless belt is 100 to 500 m.
- a phase difference film made of polypropylene resin can be obtained by sequentially performing longitudinal stretching and lateral stretching of the raw film obtained by the above method or the like. Stretching may be performed in the transverse direction after the longitudinal stretching is performed first, or may be performed in the longitudinal direction after the lateral stretching is performed first.
- Examples of the longitudinal stretching method include a method of stretching a raw film by a difference in rotational speed between two or more rolls, and a long span stretching method.
- the long span stretching method is a method of stretching by using a longitudinal stretching machine having two pairs of nip rolls and an oven between them and heating the raw film in the oven by a difference in rotational speed between the two pairs of nip rolls. . Since a retardation film having high optical uniformity can be obtained, the long span longitudinal stretching method is preferred. It is particularly preferable to use an air floating oven.
- the air-floating type oven has a structure in which hot air can be blown from both the upper nozzle and the lower nozzle onto both sides of the original film when the original film is introduced into the oven.
- the stretching temperature for this combination (that is, the temperature of the atmosphere in the oven) is preferably 90 ° C. or higher and not higher than the melting point of the polypropylene resin. If the oven is divided into two or more zones, the temperature settings for each zone may be the same or different.
- the longitudinal draw ratio is not limited, it is usually 1.0;! To 2 times, and a retardation film that is superior in optical uniformity can be obtained, so that it should be 1.0 5 to 1.8 times. It is preferable.
- Transverse stretching has the following steps.
- a tenter method is an example of a typical transverse stretching method.
- the tenter method is a method in which a raw film, which is fixed at both ends in the film width direction with a chuck, is stretched in an oven with the chuck interval widened.
- the oven temperature of the zone that performs the preheating process, the zone that performs the stretching process, and the zone that performs the heat setting process is used.
- the pre-heating step for transverse stretching is a step that is installed before the step of stretching the film in the width direction, and is a step of heating the film to a temperature high enough to stretch the film.
- the preheating temperature in the preheating step means the temperature of the atmosphere in the zone where the oven preheating step is performed, and is a temperature equal to or higher than the melting point of the polypropylene resin of the stretched film.
- the preheating temperature greatly affects the axial accuracy of the obtained retardation film, and a uniform retardation cannot be achieved in the obtained retardation film at a preheating temperature lower than the melting point.
- the preheat step residence time of the stretched film is preferably 30 to 120 seconds. If the residence time in this preheating process is less than 30 seconds, stress is dispersed when the film is stretched in the stretching process, which adversely affects the uniformity of the axis and retardation of the retardation film. In addition, if the residence time exceeds 120 seconds, the film may be exposed to heat more than necessary, causing the film to partially melt and sag.
- the preheating step residence time is more preferably 30 to 60 seconds.
- the stretching process of transverse stretching is a process of stretching the film in the width direction.
- the stretching temperature in this stretching process (which means the temperature of the atmosphere in the zone where the oven stretching process is performed) is lower than the preheating temperature.
- the stretching temperature is preferably 5 to 20 ° C lower than the preheating temperature in the preheating step, and more preferably 7 to 15 ° C lower.
- the heat setting process of transverse stretching means that the film width is maintained at the end of the stretching process.
- the film is passed through an atmosphere of a predetermined temperature in an oven.
- the heat setting temperature is from 5 ° C lower than the stretching temperature in the stretching process to 3 Ot: higher than the stretching temperature. It is preferable to be within a range up to a degree.
- the transverse stretching step may further include a thermal relaxation step.
- this step is usually performed between a stretching zone and a heat setting zone, and is performed in a heat relaxation zone where the temperature can be set independently of other zones.
- thermal relaxation is performed by stretching the film to a predetermined width in the stretching process and then reducing the chuck interval by a few percent (usually 0.5-7%) to remove useless strain. Done.
- the in-plane retardation Rc is usually 30 to 300 nm.
- the in-plane retardation Ro is 40 to 70 nm and the thickness direction retardation R th is 90 to 230 nm.
- the thickness of the retardation film is usually 10 to 100 m, preferably 10 to 60 m.
- a retardation film having a desired retardation can be obtained by controlling the stretching ratio at the time of producing the retardation film and the thickness of the retardation film to be produced.
- the retardation film manufactured by the above method has a difference between the maximum and minimum retardation values within the film plane (500 mm width x 500 mm length region) of 1 O nm or less.
- the optical axis is one. More + 1. It is the following, and is a retardation film having high optical uniformity.
- the retardation film of the present invention is laminated with various polarizing plates, liquid crystal layers, and the like, and is preferably used as a liquid crystal display device such as a mobile phone, a personal digital assistant (PDA), a personal computer, and a large TV.
- the liquid crystal display device (LCD) that uses the retardation film of the present invention in a laminated state includes an optically compensated bend (OCB) mode, a vertical alignment (VA) mode, a lateral electric field (In-Plane Switching).
- I PS I PS
- Thin F i 1 thin film transistor Yuichi
- TFT m tran sistor
- TN twisted nematic
- STN super twisted nematic
- a liquid crystal display device has a polarizing plate arranged on both sides of a liquid crystal cell having two substrates and a liquid crystal layer sandwiched between them, and is arranged on the outer side (back side) of one of them.
- the retardation film of the present invention can be disposed between the back side polarizing plate and the liquid crystal cell and / or between the front side polarizing plate and the liquid crystal cell via an adhesive.
- the polarizing plate is usually configured to be sandwiched by two protective films such as triacetyl cellulose (TAC) film via an adhesive to protect a polarizing film made of polyvinyl alcohol.
- TAC triacetyl cellulose
- This retardation film is bonded to the polarizing film with an adhesive instead of the front side polarizing plate and the protective film on the liquid crystal cell side of the Z or back side polarizing plate, so that the optical compensation film (retardation film) and It is also possible to play the role of both protective films.
- a polypropylene resin was hot press molded to produce a 0.1 mm thick film.
- the resin is preheated at 230 ° C for 5 minutes, then the pressure is increased to 100 kg f Zcm2 over 3 minutes at the same temperature and held for 2 minutes, and then 30 kg fZcm 2 at 30 ° C. Cooled for 5 minutes.
- Stress-strain curve (S-S) observed when the film is stretched according to JIS K-7113 at a temperature at which the tensile test speed is 100 mmZm in and the stress at 200% strain is 10 ⁇ lkg / cm 2.
- the parameter (A) was obtained by Equation (3).
- the tensile test is equipped with a thermostatic bath. The bow I tension test was performed in the thermostat using a test apparatus.
- a sheet having a thickness of 0.5 mm was formed by hot press molding a polypropylene resin.
- the propylene polymer is preheated in a hot press machine at 230 ° C for 5 minutes, then the pressure is increased to 50 kg ⁇ / cm2 over 3 minutes, the pressure is maintained for 2 minutes, and then 30 ° C, 30 It was pressed to cool at 5 kg / cm 2 for 5 minutes.
- a melting curve was prepared by heating from 50 ° C to 180 ° C at a heating rate of 5 ° C / min. In this melting curve, the temperature (° C) showing the highest endothermic peak was determined, and this was taken as the melting point (Tm) of the propylene resin.
- the melt rate was measured according to JI S K7210 at a temperature of 230 ° C and a load of 21.18 N.
- Propylene 'Ethylene copolymer was subjected to IR spectrum measurement described on page 616 of the Polymer Analysis Handbook (published by Kinokuniya Shoten in 1995), and the constituent units derived from ethylene in the copolymer were measured. The content was determined.
- a 1 g sample of a polypropylene resin was completely dissolved in 100 ml of boiling xylene, then the temperature was lowered to 20 ° C. and left at that temperature for 4 hours. Then, precipitate and filter by filtration The solid produced by distilling off xylene from the filtrate was dried at 70 ° C under reduced pressure. The percentage of the weight of the residue obtained by drying with respect to the weight of the sample (1 g) was defined as the 20 ° C. xylene-soluble component amount (CXS) of the propylene-based resin.
- CXS xylene-soluble component amount
- the in-plane retardation was measured in a 500 mn x 500 mm long region of the retardation film using a phase difference measurement device (Koji BRA—CCD, manufactured by Oji Scientific Instruments).
- the thickness direction retardation R th was measured at the central portion of the retardation film using a retardation measuring device (manufactured by Oji Scientific Instruments, KOBRA-WPR).
- the angle of the optical axis was measured at intervals of 20 mm over a 500 mm wide range of the retardation film.
- the extruded molten polypropylene resin is composed of a 400 mm ⁇ casting roll adjusted to 12 ° C, an outer cylinder made of a metal sleeve adjusted to 12 ° C, and an elastic roll inside it.
- a polypropylene resin film having a thickness of 200 m was obtained by being sandwiched and cooled with a torch roll.
- the air gap was 115 mm, and the distance that the molten polypropylene resin was sandwiched between the casting roll and the evening roll was 20 mm.
- the obtained polypropylene resin film was introduced into a long span longitudinal stretching machine having an air floating type oven between two nip rolls for longitudinal stretching. The air-floating oven was divided into two zones, and each zone was 1.5 m long.
- draw ratio 1.5 times.
- the thickness of the longitudinally stretched film was 170 m
- the average value of the in-plane retardation Ro was 1290 nm
- the thickness direction retardation R th was 720 nm.
- this longitudinally stretched film was subjected to transverse stretching by the Tenyu method to obtain a retardation film.
- R 0 , R th and optical axis accuracy of the obtained retardation film were measured.
- the average value of Ro is 70 nm
- the difference between the maximum and minimum values of Ro is 6 nm
- Rth is 200 nm
- the angle of the optical axis is not less than 0.5 ° and not more than 0.5 °
- the phase difference The film had high optical uniformity.
- This retardation film is laminated on the back of the VA mode liquid crystal cell in this order from the liquid crystal cell substrate side in the order of adhesive, retardation film, adhesive, and polarizing plate. Laminated in the order of the plates.
- a backlight was installed on the back of this liquid crystal display device, and the viewing angle dependence was evaluated by the degree of light leakage due to the change in viewing angle when the liquid crystal cell was in a black display state with no voltage applied.
- the viewing angle dependency is small, and the viewing angle characteristics of the retardation film are excellent. It was confirmed that the liquid crystal display device in this example had little light leakage in both the front direction and the oblique direction, and excellent viewing angle characteristics.
- Polypropylene resin nobrene W151 was charged into a 9 ⁇ extruder with a cylinder temperature of 250 ° C., melted and kneaded, and extruded from a 1250 mm wide T-die attached to the extruder at an extrusion rate of 100 kgZh.
- the extruded molten polypropylene resin was cooled by a casting roll adjusted to a temperature of 10 ° C. and a single air chamber to obtain a polypropylene resin film having a thickness of 160 m.
- the air gap was 90 mm.
- the obtained polypropylene resin film was introduced into a long span longitudinal stretching machine having an air floating type oven between two sets of nip rolls for longitudinal stretching.
- the air-floating oven was divided into 2 zones, and each zone was 2 m long.
- the thickness of the longitudinally stretched film 1 3 0 rn, Ro is 9 1 0 nm, R th was 5 1 0 nm.
- this longitudinally stretched film was subjected to transverse stretching by the Tenyu method to obtain a retardation film.
- R 0 , Rth and optical axis accuracy of the obtained retardation film were measured.
- the average value of Ro is 70 nm
- the difference between the maximum and minimum values of Ro is 10 nm
- Rth is 120 nm
- the optical axis angle is _0.5. More than +0.5.
- the retardation film had high optical uniformity. This retardation film is laminated on the back of the VA mode liquid crystal cell in this order from the liquid crystal cell substrate side in the order of adhesive, retardation film, adhesive, and polarizing plate, and on the front of the liquid crystal cell, the adhesive and polarizing plate The layers were laminated in this order.
- a backlight was installed on the back of the liquid crystal display device, and the liquid crystal cell was evaluated for viewing angle dependence based on the degree of light leakage due to the change in viewing angle in a black display state where no voltage was applied.
- the viewing angle dependency is small, and the viewing angle characteristics of the retardation film are excellent. It was confirmed that the liquid crystal display device of this example had little light leakage in the front direction and the oblique direction, and excellent viewing angle characteristics.
- a retardation film was produced in the same manner as in Example 1 except that the following transverse stretching conditions were used.
- the transverse stretching conditions were as follows: all temperatures in the preheating zone, stretching zone, and heat setting zone were 13.6 ° C, the line speed was 1 mZ, and the stretching ratio was 3.5 times.
- the in-plane phase difference of the obtained phase difference film is 70 nm, the difference between the maximum and minimum phase differences is 16 nm, and the optical axis angle is not less than 12 ° and not more than + 2 °.
- a product with high optical uniformity could not be obtained.
- Industrial applicability According to the method of the present invention, a polypropylene resin retardation film having high axial accuracy and a uniform retardation can be obtained.
- the retardation film made of a polypropylene resin produced by the method of the present invention is used even for a large-screen liquid crystal display such as a large-sized liquid crystal television, and the retardation and light derived from optical non-uniformity. There is no unevenness of the axis, and the effect of improving the viewing angle dependency is excellent. Furthermore, the liquid crystal display device of the present invention comprising the retardation film having high axial accuracy and uniform retardation has excellent viewing angle characteristics and durability.
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- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Nonlinear Science (AREA)
- Mathematical Physics (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Polarising Elements (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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CN2007800097240A CN101432642B (zh) | 2006-03-23 | 2007-03-23 | 相位差薄膜及其制造方法 |
KR1020087025704A KR101324053B1 (ko) | 2006-03-23 | 2007-03-23 | 위상차 필름 및 이의 제조방법 |
US12/293,347 US7744969B2 (en) | 2006-03-23 | 2007-03-23 | Retardation film and method for production thereof |
Applications Claiming Priority (2)
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JP2006080237 | 2006-03-23 | ||
JP2006-080237 | 2006-03-23 |
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WO2007108562A1 true WO2007108562A1 (ja) | 2007-09-27 |
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PCT/JP2007/057009 WO2007108562A1 (ja) | 2006-03-23 | 2007-03-23 | 位相差フィルムおよびその製造方法 |
Country Status (5)
Country | Link |
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US (1) | US7744969B2 (ja) |
KR (1) | KR101324053B1 (ja) |
CN (1) | CN101432642B (ja) |
TW (1) | TWI410322B (ja) |
WO (1) | WO2007108562A1 (ja) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2009051188A1 (ja) * | 2007-10-19 | 2009-04-23 | Dai Nippon Printing Co., Ltd. | 光学フィルム、偏光板及び画像表示装置 |
JP2009093168A (ja) * | 2007-09-21 | 2009-04-30 | Sumitomo Chemical Co Ltd | 位相差フィルムの製造方法 |
JP2009134257A (ja) * | 2007-10-31 | 2009-06-18 | Sumitomo Chemical Co Ltd | 位相差フィルム、およびそれを用いた楕円偏光板 |
GB2456274B (en) * | 2006-11-17 | 2010-11-03 | Dainippon Printing Co Ltd | Optical film, polarizing plate and image display device |
US8277950B2 (en) | 2008-06-12 | 2012-10-02 | Hwaseung Industries Co. Ltd | Retardation film having uniform in-plane phase-difference value and laminated optical film having positive dispersibility in wavelength |
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TWI434109B (zh) * | 2007-03-30 | 2014-04-11 | Sumitomo Chemical Co | A retardation film thin film, a retardation film, and a liquid crystal display device |
JP5120938B2 (ja) * | 2008-03-05 | 2013-01-16 | 住友化学株式会社 | 粘着剤層付位相差フィルム及びそれを用いた楕円偏光板及び液晶表示装置 |
JP5594125B2 (ja) * | 2010-12-21 | 2014-09-24 | 住友化学株式会社 | 位相差フィルムの製造方法 |
TWI450780B (zh) * | 2011-07-07 | 2014-09-01 | Benq Materials Corp | 用於製造相位差薄膜之滾輪的製造方法及使用該滾輪的相位差膜製造方法與相位差膜 |
JP5512624B2 (ja) * | 2011-09-21 | 2014-06-04 | 日本写真印刷株式会社 | 静電容量式タッチセンサ及びこれを備えた表示装置 |
US9221931B2 (en) | 2012-05-15 | 2015-12-29 | Sekisui Chemical Co., Ltd. | Method for producing polypropylene material, and polypropylene material |
JP6418929B2 (ja) * | 2014-12-08 | 2018-11-07 | 日東電工株式会社 | 位相差フィルムの製造方法および積層偏光板の製造方法 |
KR101927432B1 (ko) * | 2015-02-11 | 2018-12-10 | 동우 화인켐 주식회사 | 고내구성 편광판 및 이를 구비한 표시장치 |
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- 2007-03-23 CN CN2007800097240A patent/CN101432642B/zh not_active Expired - Fee Related
- 2007-03-23 WO PCT/JP2007/057009 patent/WO2007108562A1/ja active Application Filing
- 2007-03-23 US US12/293,347 patent/US7744969B2/en not_active Expired - Fee Related
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Also Published As
Publication number | Publication date |
---|---|
CN101432642B (zh) | 2012-05-23 |
US7744969B2 (en) | 2010-06-29 |
KR101324053B1 (ko) | 2013-11-01 |
US20090227756A1 (en) | 2009-09-10 |
TW200806457A (en) | 2008-02-01 |
KR20080111083A (ko) | 2008-12-22 |
TWI410322B (zh) | 2013-10-01 |
CN101432642A (zh) | 2009-05-13 |
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