WO2006051664A1 - 赤外線透過性カバー - Google Patents
赤外線透過性カバー Download PDFInfo
- Publication number
- WO2006051664A1 WO2006051664A1 PCT/JP2005/018649 JP2005018649W WO2006051664A1 WO 2006051664 A1 WO2006051664 A1 WO 2006051664A1 JP 2005018649 W JP2005018649 W JP 2005018649W WO 2006051664 A1 WO2006051664 A1 WO 2006051664A1
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- WIPO (PCT)
- Prior art keywords
- cover
- infrared
- base layer
- multilayer film
- dielectric multilayer
- Prior art date
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Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/28—Interference filters
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/28—Interference filters
- G02B5/281—Interference filters designed for the infrared light
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/26—Reflecting filters
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/44—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the coatings, e.g. passivation layer or anti-reflective coating
Definitions
- the present invention relates to an infrared-transparent cover, for example, to a highly decorative infrared-transparent cover attached to an infrared signal port that inputs and outputs infrared signals.
- Infrared signals are used for remote control such as short distance wireless data communication (for example, IrDA standard) between electronic devices, and power-on Z-off and volume change of household electric appliances such as TVs and VTRs.
- short distance wireless data communication for example, IrDA standard
- IrDA standard short distance wireless data communication
- power-on Z-off and volume change of household electric appliances such as TVs and VTRs.
- An infrared signal is received by an infrared light receiving element provided in a receiver or transceiver.
- the infrared light receiving element detects not only an infrared signal but also visible light.
- a black or dark, near infrared transparent resin window plate is attached to the infrared signal port of the conventional receiver or transmitter.
- a black or dark resin window prevents malfunction of the light receiving element due to external light such as visible light. Black or dark resin windows may also be attached to the transmitter's infrared signal port.
- the black or dark resin window has a function to hide the inside of the transmitter, receiver and transceiver as if it were invisible.
- Patent Document 1 Japanese Patent Application Laid-Open No. 2002-226805
- a conventional black or dark resin window board has a force S that does not match the appearance of electronic devices and electrical devices. It was a design limitation to design the equipment to make the black or dark grease window inconspicuous!
- the double-sided pressure-sensitive adhesive sheet described in Patent Document 1 has a dark appearance color that absorbs visible light. For this reason, it has the same disadvantages as the black resin window.
- Manufacturing a resin window panel having an arbitrary appearance color involves adding a coloring agent to a transparent resin plate.
- a coloring agent to a transparent resin plate.
- the resin window for the infrared signal port must be infrared transparent. It has been difficult to produce a resin window with any appearance color while maintaining infrared transparency and shielding against visible light.
- An object of the present invention is to provide an infrared-transparent cover for electronic devices having any appearance color.
- the infrared-transparent cover of the present invention is provided with an infrared-transparent base layer, and a dielectric multilayer film laminated on one surface of the base layer and reflecting infrared light-transparent and visible light. Equipped with
- the present invention further provides an electronic device comprising a housing having an opening, an infrared detection element housed in the housing, and the infrared transparent cover attached to the housing to close the opening. Do.
- the infrared ray transmitting cover is formed by ion-assisted deposition, plasma CVD, or low temperature film formation of a dielectric multilayer film reflecting infrared rays and visible light on one surface of an infrared ray transmitting base layer. Manufacturing process.
- the cover of an embodiment further includes a hard coat-treated undercoating layer laminated between the dielectric multilayer film and the base layer, and the dielectric multilayer film serves as an outer surface of the cover. Function.
- the base layer has a laminated first surface of the dielectric multilayer film and a second surface opposite to the first surface, and the cover is An anti-reflection film laminated on the second surface of the base layer is further provided, and the dielectric multilayer film and the anti-reflection film function as an inner side surface and an outer side surface of the cover, respectively.
- the base layer has two surfaces, and the dielectric multilayer film is laminated on the two surfaces of the base layer.
- the base layer includes a light-scattering textured region formed on at least a portion of the surface.
- the interface between the base layer and the dielectric multilayer film is a curved surface.
- the interface between the base layer and the dielectric multilayer film is a convex surface.
- the cover is attached to an infrared signal port of an electronic device, and the cover is an outer side exposed to the outside of the electronic device, and an inner side disposed inside the electronic device.
- the base layer is colorless and transparent, and has a first surface near the inner side surface of the cover and a second surface near the outer side surface of the cover, and the dielectric multilayer film is the base layer A black layer laminated to the dielectric multi-layer film, the black layer blocking infrared light transmission and blocking transmission of visible light, and the second surface of the base layer And a diffusion layer stacked on the
- the base layer is colorless and transparent, and has a first surface close to the inner surface of the cover and a second surface close to the outer surface of the cover, and the dielectric multilayer film Is laminated on the first surface of the base layer, and the cover is further formed of an information printing layer laminated on the dielectric multilayer film, and an infrared ray transparent or laminated layer on the information printing layer. And a black layer blocking transmission of visible light, and a diffusion layer laminated on the second surface of the base layer.
- the information printing layer is a single layer.
- the base layer is colorless and transparent, and has a first surface close to the inner side surface of the cover and a second surface close to the outer side surface of the cover; An information-printed layer laminated between the first surface of the base layer and the dielectric multilayer film, and a black layer laminated on the dielectric multilayer film for preventing transmission of infrared light and visible light. And a diffusion layer laminated on the second surface of the base layer.
- the information print layer includes a plurality of layers.
- the base layer is an infrared-transparent dark base layer, and has a first surface close to the inner side surface of the cover and a second surface close to the outer side surface of the cover, A dielectric multilayer film is formed on the second surface of the dark base layer, and the cover further includes a protective layer laminated on the dielectric multilayer film.
- the base layer is colorless and transparent, and has a first surface close to the inner side surface of the cover and a second surface close to the outer side surface of the cover, and the dielectric multilayer film A black layer formed on the second surface of the base layer, the cover being laminated on the first surface of the base layer, the black layer being infrared-transparent and blocking transmission of visible light; And a protective layer laminated on the collector multilayer film.
- the dielectric multilayer film selectively reflects visible light in a specific wavelength range.
- the dielectric multilayer film mainly transmits visible light having a wavelength excluding the specific wavelength range.
- the cover of an embodiment has an appearance color except black.
- FIG. 1 is a cross-sectional view of the infrared transparent cover of the present invention.
- FIG. 2 Explanatory drawing of the Fresnel reflection in the transparent base layer of the cover of FIG.
- FIG. 3 A cross-sectional view of the portable information terminal with the cover of FIG. 1 attached.
- FIG. 5 is a cross-sectional view of the infrared-transparent cover according to the first embodiment of the present invention.
- FIG. 8 Reflection spectrum and transmission spectrum of the cover of Example 2.
- FIG. 9 is a cross-sectional view of an infrared-transparent cover according to a second embodiment of the present invention.
- FIG. 10 A cross-sectional view of an infrared-transparent cover according to a third embodiment of the present invention.
- FIG. 11 A cross-sectional view of an infrared-transparent cover according to a fourth embodiment of the present invention.
- FIG. 12 is a cross-sectional view of an infrared-transparent cover according to a fifth embodiment of the present invention.
- FIG. 13 is a cross-sectional view of the infrared ray permeable cover according to the sixth embodiment of the present invention.
- FIG. 14 The reflection spectrum of the cover of Example 3 which changes according to the incident angle.
- FIG. 15 is a cross-sectional view of the infrared ray permeable cover according to the seventh embodiment of the present invention.
- FIG. 16 Reflection spectrum and transmission spectrum of the dielectric multilayer film of the cover of FIG.
- FIG. 17 Transmission spectrum of the black layer of the cover of FIG.
- FIG. 18 A plan view and a cross-sectional view of an infrared transmitting cover according to an eighth embodiment of the present invention.
- FIG. 19 (a) is a view for explaining the reflected light of the cover of the comparative example.
- (B) is a front view of the cover of a comparative example.
- FIG. 20 Front view of the cover of FIG.
- FIG. 21 is a plan view and a cross-sectional view of an infrared-transparent cover according to a ninth embodiment of the present invention.
- FIG. 22 is a cross-sectional view of the infrared ray permeable cover according to the tenth embodiment of the present invention.
- FIG. 23 is a cross-sectional view of the infrared transmissive cover according to the eleventh embodiment of the present invention.
- FIG. 24 is a perspective view of an electronic device provided with the infrared ray transmitting cover of the present invention.
- FIG. 25 The perspective view of the infrared rays permeable cover of a modification.
- the power bar 1 is attached to a transmitter or receiver that transmits an infrared signal in one direction, and a transceiver that transmits the infrared signal in two directions.
- the "outside surface” and the “inside surface (back surface)" of each layer are respectively attached to the outside and inside of the electronic device. Point to the near surface.
- the upper side of FIG. 1 is the outer surface of the cover 1 and each layer, and the lower side is the inner surface of the cover 1 and each layer.
- the cover 1 has an infrared transmitting base layer 2, and an infrared transmitting and visible light reflecting dielectric multilayer film 3 formed on the outer surface of the base layer 2.
- the outer surface 3a of the dielectric multilayer film 3 is exposed to the outside of the infrared ray signal port.
- the inner surface of the base layer 2 is disposed inside the infrared signal port.
- the outer surface 2b of the base layer 2 and air are used as Fresnel reflection. Approximately 4% of the incident light is reflected at the interface SA of the surface and the interface SB between the inner surface 2a and the air, respectively. Thus, about 92% of the incident light is transmitted through the base layer 2.
- FIG. 3 shows the portable information terminal 4 attached with the cover 1 of FIG.
- the cover 1 is attached to the opening (infrared signal port) 5a formed in the case 5 of the portable information terminal 4 .
- the upper side of FIG. 3 is the outer surface of the cover 1 and each layer, and the lower side is the inner surface of the cover 1 and each layer.
- Part of the incident light IL is reflected by the outer surface of the cover 1 (reflected light ra).
- Part of the incident light IL is reflected by the inner surface of the cover 1 (reflected light rb).
- a part of the incident light IL passes through the cover 1 and is reflected by a component 6 such as a light receiving element provided in the housing 5 (reflected light rc).
- Incident light IL is ambient light such as indoor lighting and sunlight.
- the reflected light m is a reflected light of visible light in a specific wavelength range in the incident light IL.
- Curve 7 in Fig. 4 (a) shows the spectral reflection characteristics of the reflected light m.
- the horizontal and vertical axes in Fig. 4 (a) to (e) indicate the wavelength and reflectance, respectively.
- the reflected light rb is reflected by the interface between the inner side surface 2 a of the base layer 2 and the air, and the light emitted from the outer side surface 3 a of the cover 1 is there.
- Curve 8 in Fig. 4 (b) shows the spectral reflection characteristics of the reflected light rb.
- the reflected light rc is light which is reflected by the component 6 and is emitted from the outer side surface 3 a of the cover 1 among the incident light IL transmitted through the dielectric multilayer film 3 and the base layer 2.
- Curve 9 in Fig. 4 (c) shows the dif- ferential light reflection characteristics of the reflected light rc. In order to simplify the explanation, the spectral reflection characteristics of the surface of part 6 are assumed to be flat and ignored.
- the cover 1 appears in a color (exterior color) according to a combined spectrum of the reflected light ra, the reflected light rb, and the reflected light rc.
- the thick curve 10 in Fig. 4 (d) is a synthetic spectrum of the reflected light ra, the reflected light rb and the reflected light rc, and is the spectral reflection characteristic of the entire cover 1.
- the cover 1 has an appearance color according to the curve 10. From FIG. 4 (d), it can be seen that the contrast ratio of the appearance color of the force bar 1 improves as the intensity (light amount) of the reflected light rb and the reflected light rc decreases.
- cover 1 in which the inner surface 2a of the base layer 2 is painted black by applying the infrared ray transmitting visible light absorbing dark paint to the inner surface 2a of the base layer 2, the light reaching the inner surface 2a is It is absorbed by the paint.
- the intensities of the reflected light rb and the reflected light rc from the inner side surface 2a are approximately zero, and the appearance color of the cover 1 is substantially determined according to the color of the reflected light m at the outer side surface 3a.
- cover 1 has an appearance color with a large contrast ratio as shown by curve 7 in FIG. 4 (a), and if reflected light ra is green, cover 1 has a green color with a large appearance color contrast ratio. It looks like
- the cover 1 looks like an inconspicuous color with a small appearance color contrast ratio.
- a curve 11 of FIG. 4 (e) shows a spectral distribution of the transmitted light emitted from the inner side surface 2a through the dielectric multilayer 3 and the base layer 2 in the incident light IL.
- the infrared signal E 1 output from another electronic device passes through the cover 1.
- an infrared signal E 2 generated by a light emitting element such as an infrared light emitting diode housed in the housing 5 passes through the cover 1.
- the infrared signal E 2 is incident on the inner side surface 2 a of the cover 1 and emitted from the outer side surface 3 a of the cover 1.
- the reflection of the incident light IL at the interface between the inner surface 2 a of the base layer 2 and the air is referred to as “with back surface reflection”.
- the fact that the incident light IL is not reflected at the interface and the reflected light rb is negligibly small is referred to as "no back surface reflection”.
- the portable information terminal 22 as an electronic device uses an infrared signal (for example, an infrared ray having a wavelength near 850 nm) to perform information transfer and information exchange with other electronic devices in a tableless manner. It has a transceiver. Infrared communication is performed, for example, in accordance with the IrDA standard.
- the cover 21 closes an opening (infrared signal port) 22 a formed in the housing of the portable information terminal 22.
- the lower side of FIG. 5 is the outer surface of the cover 21 and each layer, and the upper side is the inner surface of the cover 21 and each layer.
- the cover 21 is provided with an infrared transmitting base layer 23 and an infrared transmitting and visible light reflective dielectric multilayer film 24 formed on the outer surface of the base layer 23.
- the base layer 23 is made of, for example, a resin material such as polycarbonate and acrylic resin. Resins other than polycarbonate and acrylic resin may be used as long as they have transparency to infrared rays. The following is an example of the base layer 23.
- a colorless and transparent material which is a semi-transparent layer having a satin finish (matted outer surface or inner surface).
- Dispersed milky white layer of scattering material scattering particles
- a colorless and transparent material which is a layer formed by forming an opaque layer by applying or printing an infrared-transparent dark paint on the inner surface thereof
- the layer of (1) is used as the base layer 23.
- the dielectric multilayer film 24 is formed by alternately laminating a thin film made of a low refractive material and a thin film made of a high refractive index material.
- thin film materials are two or three metal compounds selected from metal oxides and metal fluorides.
- the dielectric multilayer film 24 has infrared transparency.
- the dielectric multilayer film 24 has spectral reflection characteristics in the visible range, which reflects light of a desired color such as blue or yellow.
- infrared transparency means the property of transmitting infrared rays with high transmittance.
- the transceiver of the portable information terminal 22 has a light emitting element 25 such as an infrared light emitting diode for generating and outputting an infrared signal, a light receiving element 26 for receiving infrared light, and an infrared ray transmitting property attached to the infrared signal port. And a cover 21.
- the light emitting element 25 and the light receiving element 26 are disposed close to the back surface 23 a of the base layer 23 of the force bar 21. Description and illustration of a focusing optical system that may be placed in front of a light emitting / receiving element, and a composite element that emits and receives light with one element are omitted.
- Infrared signal 30 emitted from light emitting element 25 passes through cover 21 and is emitted to the outside.
- the infrared signal 30 corresponds to the infrared signal E2 of FIG.
- An infrared ray signal 31 incident from the outside passes through the cover 21 and is received by the light receiving element 26.
- the infrared signal 31 corresponds to the infrared signal E1 of FIG.
- a portion of the visible light 32 incident on the cover 21 is reflected by the dielectric multilayer film 24 and emitted to the outside as a reflected light 33.
- the visible light 32 and the reflected light 33 correspond to the incident light IL and the reflected light ra shown in FIG. 3, respectively.
- the remaining part of the visible light 32 passes through the dielectric multilayer film 24 and the base layer 23, a part of which is reflected by the back surface 23a of the base layer 23 and is emitted to the outside of the cover 21 as reflected light rb shown in FIG. Be done.
- the cover 21 includes an infrared transmitting base layer 23 and an infrared transmitting and visible light reflective dielectric multilayer film 24 laminated on the outer surface of the base layer 23. Visible region of dielectric multilayer film 24 By appropriately selecting the spectral reflection characteristics of the above, the dielectric multilayer film 24 can reflect light having a color adjusted to a desired color while maintaining infrared transparency. A cover 21 having an optional appearance color can be obtained while maintaining the infrared transparency. Therefore, the cover 21 has an excellent design and can improve the freedom of design of the electronic device.
- the cover 21 attached to the housing of the electronic device has a desired decorative effect.
- the dielectric multilayer film 24 has spectral reflection characteristics of reflecting light of a desired color while maintaining the transparency of infrared light.
- the cover 21 has an appearance color (color of reflected light) according to the combined spectral characteristics of the dielectric multilayer film 24 and the base layer 23 with respect to visible light.
- the cover 21 is a dielectric multilayer film 24. It has a mixed appearance color of a strongly reflected blue reflected light, a weak component other than blue (red and green) reflected by the back surface 23a of the base layer 23, and the reflected light.
- the cover 21 has an excellent design, and can improve the freedom of design of the electronic device.
- the dielectric multilayer film 24 designed to reduce the Fresnel reflection of the base layer 23 to near infrared light is laminated on the base layer 23, the transmissivity of near infrared rays is improved compared to the case of the base layer 23 alone. Do.
- the dielectric multilayer film 24 also has the same anti-reflection effect as the anti-reflection film on the infrared signals 30, 31.
- the dielectric multilayer film 24 itself reduces the reflection of the infrared signals 30, 31 at the outer side surface (the interface SA in FIG. 2) of the substrate 23 by about 4%. Accordingly, the loss of the infrared signals 30, 31 due to the reflection on the outer surface of the substrate 23 is reduced.
- Example 1 The cover of Example 1 will be described with reference to FIG. 6, FIG. 7, Table 1, and Table 2.
- the cover of Example 1 has the same layer structure as the cover 21 shown in FIG. 5, and has a base layer 23 made of acrylic resin and a dielectric multilayer film that has infrared transparency and reflects blue light 24.
- the dielectric multi-layer film 24 is an eight layer in which a film material (ZrO) of a high refractive index material and a film material (SiO 2) of a low refractive index material are alternately laminated on the outer surface of the base layer 23 made of acrylic resin. Composed of thin film layers Be The dielectric multilayer film 24 reflects light having a central wavelength c.
- the central wavelength c is related to the color of the reflected light, ie the color of the cover.
- the eight layers constituting the dielectric multilayer film 24 of Example 1 are designed to reflect light having a center wavelength c of 495 nm, that is, blue light.
- Example 1 Blue reflection, central wavelength; l c: 495 nm, number of dielectric multilayer films: 8
- FIG. 6 shows the spectral reflection characteristics and the spectral transmission characteristics of the dielectric multilayer film 24 in Example 1.
- a curve 40 shows the spectral reflection characteristic (reflectance R) in the case of “without back surface reflection”.
- Curve 41 shows the spectral transmission characteristic (transmission factor T) in the case of “without back surface reflection”.
- a curve 42 shows the spectral reflection characteristic (reflectance R) in the case of “with back surface reflection”.
- a curve 43 shows the spectral transmission characteristic (reflectance T) in the case of “with back surface reflection”.
- Curves 40 and 42 indicate that the reflectance of infrared rays around 900 m m is very low and the transmittance of the infrared rays is very low in both cases of “without back surface reflection” and “with back surface reflection”. Show that! In both cases of “no back surface reflection” and “with back surface reflection”, the transmittance of light in the wavelength region where the reflectance of light in the wavelength region around 500 nm (blue light) is as high as about 70% is 30 It shows that it is about%. This reflectance can be adjusted appropriately.
- FIG. 7 is a chromaticity diagram of the xy Y color system. Y in Table 2 indicates the brightness of the reflected light.
- the dielectric multilayer film 24 has a function to transmit near infrared light (infrared light) around 900 nm at about 100%, high! /, Transmittance, and light around 495 nm for visible light ( It has a function to reflect blue light at a reflectance of about 70%.
- the cover of Example 1 provided with the dielectric multilayer film 24 has a blue appearance color (reflected light) while maintaining the transparency of infrared light.
- the cover of Example 2 has the same structure as the cover 21 of FIG. 5, and comprises a base layer 23 made of acrylic resin and a dielectric multilayer film 24 that reflects yellow light.
- the dielectric multilayer film 24 is a seven-layer thin film in which a film material of high refractive index material (ZrO 2) and a film of low refractive index material (SiO 2) are alternately laminated.
- the central wavelength c of the dielectric multilayer film 24 is set to the wavelength of reflected yellow light (600 nm).
- Example 2 Yellow reflection, center wavelength band c: 600 nm, number of dielectric multilayer films: 7
- a curve 50 shows the spectral reflection characteristic (reflectance R) in the case of “without back surface reflection”.
- a curve 51 shows the spectral transmission characteristic (transmission factor T) in the case of “without back surface reflection”.
- a curve 52 shows the spectral reflection characteristic (reflectance R) in the case of “with back surface reflection”.
- a curve 53 shows the spectral transmission characteristic (transmittance T) in the case of “with back surface reflection”.
- Curves 50 and 52 in FIG. 8 indicate that the reflectance of infrared light near 900 nm is very low and the transmittance of infrared light is extremely high for both “without back surface reflection” and “with back surface reflection”.
- the reflectance for light in the wavelength range around 600 nm is as high as about 70% in all cases of “high”, “no back reflection” and “with back reflection”. It shows that the transmissivity of area light is about 30%.
- Table 4 shows chromaticity coordinate values of reflected light of the dielectric multilayer film 24 in the second embodiment.
- the color of the reflected light of the dielectric multilayer film 24 can be divided from the chromaticity coordinate values (x, y) and the xy chromaticity diagram shown in FIG.
- the dielectric multilayer film 24 has a function to transmit near infrared light (infrared light) near 900 nm at almost 100% with high V and transmittance, and light around 600 nm for visible light (yellow Light) with a reflectivity of approximately 70%. Therefore, the cover of Example 2 provided with the dielectric multilayer film 24 has a yellow appearance color while maintaining infrared transparency.
- FIG. 9 An infrared transmitting cover 21A according to a second embodiment of the present invention will be described with reference to FIG.
- the lower side of FIG. 9 is the outer surface of the cover 21A and each layer, and the upper side is the inner surface of the cover 21A and each layer.
- the cover 21 A differs from the cover 21 of the first embodiment in that the cover 21 A is different from the cover 21 of the first embodiment in that the base treatment layer 27 hard-coated is provided between the dielectric multilayer film 24 and the base layer 23 in the first embodiment. It is
- the base layer 23 is coated with the base treatment layer 27 to be hard-coated, and the dielectric multilayer film 24 is formed on the base treatment layer 27.
- the dielectric multilayer film 24 is also prevented from peeling off the base layer 23, and the surface hardness of the base layer 23 is also improved, and the durability of the cover 21 A is improved.
- FIG. 10 An infrared transmitting cover 21B according to a third embodiment of the present invention will be described with reference to FIG.
- the lower side of FIG. 10 is the outer surface of the cover 21B and each layer, and the upper side is the inner surface of the cover 21B and each layer.
- the cover 21 B of the second embodiment includes a dielectric multilayer film 24 laminated on the inner side surface of the base layer 23.
- the reflection of infrared rays at both interfaces of the base layer 23 is reduced by about 4% (total of about 8%) by the antireflective film 28 and the dielectric multilayer film 24. Therefore, the loss of the infrared signal can be reduced.
- the cover 21B has a clearer appearance color and can enhance the decoration of the infrared signal port.
- the cover 21B can enhance the decoration of the infrared signal port for a long time.
- FIG. 11 An infrared transmitting cover 21C according to a fourth embodiment of the present invention will be described with reference to FIG.
- the lower side of FIG. 11 is the outer surface of the cover 21C and each layer, and the upper side is the inner surface of the cover 21C and each layer.
- the cover 21 C includes a dielectric multilayer film 24 stacked on the outer surface of the base layer 23 and a dielectric multilayer film 29 stacked on the inner surface of the base layer 23.
- the cover 21C has an appearance color of a composite color of the color of the reflected light 33 reflected by the dielectric multilayer film 24 and the color of the reflected light 33 3 ′ reflected at the interface between the dielectric multilayer film 29 and the base layer 23.
- the outer dielectric multilayer film 24 is designed to reflect blue light 33 while having infrared transparency, and to reflect yellow light 33 ′ while having infrared transparency.
- the inner dielectric multilayer film 29 can be designed.
- the cover 21 C has a mixed appearance color of blue and yellow, and has excellent design and high! Decorative effect.
- the base layer that transmits infrared rays and blocks visible light can be formed from a resin material in which a material that blocks light in a specific wavelength range, such as an absorbent, a paint, or an ink, is kneaded.
- a dielectric thin film layer may be formed on the inner surface of the base layer to reflect light in the visible full wavelength range and unwanted infrared wavelength range on the specific short wavelength side to block those light beams. so Can. In this case, it is possible to block the light of the wavelength adjusted easily and precisely with high accuracy as compared with mixing the material for blocking the light.
- FIG. 12 An infrared signal transmissive cover 21D according to a fifth embodiment of the present invention will be described with reference to FIG.
- the lower side of FIG. 12 is the outer surface of the cover 21D and each layer, and the upper side is the inner surface of the cover 21D and each layer.
- a ground glass surface (a textured area) 23 A for scattering light rays is formed on part or all of the outer surface of the transparent base layer 23 made of acrylic resin.
- the other configuration is the same as that of the first embodiment.
- the textured area 23A scatters the infrared rays and reduces the directivity of the infrared rays, but the cover 21
- the light receiving element 26 is disposed close to the base layer 23 inside D, it can be used limitedly.
- the textured region 23A produces scattered light of whitish translucent color (milky white) when observed in a visible light castle.
- the cover 21D has the color of the reflected light of the dielectric multilayer film 24 and the matte area 2
- the base layer 23 has a translucent appearance like a ground glass. Therefore, when the cover 21D is attached to the electronic device, the inside of the electronic device can not be seen.
- the cover 21D can be attached to an infrared receiving port of a home electric appliance such as a TV or a VTR.
- a home electric appliance such as a TV or a VTR.
- an infrared signal (infrared in the wavelength range for remote control) for remotely controlling the power on / off and volume control of the home appliance is received by the home appliance through the power bar 21D.
- FIG. 13 An infrared transmitting cover 21E according to a sixth embodiment of the present invention will be described with reference to FIG.
- the upper side of FIG. 13 is the outer surface of the cover 21E and each layer, and the lower side is the inner surface of the cover 21E and each layer.
- the cover 21 E is laminated on the base layer 60 having a curved outer surface and the outer surface of the base layer 60. And a dielectric multilayer film 61.
- An example of base layer 60 is a semi-cylindrical or dome having a convex outer surface.
- the appearance color of the cover 21E differs depending on the viewing angle. For example, when the angle of the incident light IL with respect to the normal of the cover 21E is 0 °, the color of the reflected light raO (0 degree reflection) reflected by the outer surface of the dielectric multilayer film 61 and the incident angle of 20 ° The color of the reflected light ra20 (20 degrees reflection) in the case and the color of the reflected light ra40 (40 degrees reflection) in the case of an incident angle of 40 ° are different from each other. Therefore, the cover 21E looks iridescent and has a sense of luxury.
- Example 3 of the cover 21E of the sixth embodiment will be described with reference to FIG. 14, FIG. 7, Table 5 and Table 6.
- the cover 21E of Example 3 has the same structure as the cover of Example 2 shown in Table 2 except that the base layer has a curved surface. Therefore, the cover 21E of Example 3 has infrared transparency and reflects yellow light.
- Example 3 Yellow reflection, center wavelength ⁇ c: 600 nm, number of dielectric multilayer films: 7
- FIG. 14 shows the spectral reflection characteristics of the cover 21E of the third embodiment.
- Curve 70 shows the spectral reflectance spectrum of the reflected light raO at 0 degree reflection.
- Curve 71 is the spectral response of the 20-degree reflected light ra20 Indicates a shooting spectrum.
- Curve 72 shows the spectral reflectance spectrum of the reflected light ra40 with a 40 degree reflection. In all cases, there is no back surface reflection.
- Table 6 shows chromaticity coordinate values representing colors of the reflected light raO, ra20, and ra40 of Example 3. All In the case of "no back surface reflection". From the chromaticity coordinate values (x, y) and the xy chromaticity diagram shown in FIG. 7, the chromaticity represented by the chromaticity coordinate values, that is, the color of the reflected light of the dielectric multilayer film 24 can be known.
- the cover 21E has an appearance color that varies depending on the viewing angle, while maintaining the transmittance to infrared light near 900 nm close to 100%. Specifically, the color of the reflected light changes continuously to a slightly greenish yellow as the angle of the incident light IL is 0 ° or 40 °. Turn By this change in appearance color, the cover 21 can have an improved sense of quality and an excellent design, and can improve the degree of freedom in the design of the electronic device.
- the optical characteristics of the cover 21E change depending on the incident angle also in the wavelength region of the infrared signal. However, as shown in FIG. 14, the change in optical characteristics in the infrared region is slight, and the transmittance to the infrared signals El and E2 does not substantially decrease.
- FIG. 15 An infrared transmitting cover 21F according to a seventh embodiment of the present invention will be described with reference to FIG.
- the lower side of FIG. 15 is the outer surface of the cover 21F and each layer, and the upper side is the inner surface of the cover 21F and each layer.
- the cover 21 F is formed on the inner surface of the transparent base layer 23 having infrared ray permeability and visible light permeability, the dielectric multilayer film 24 formed on the inner surface of the base layer 23, and the dielectric multilayer film 24. It comprises a black layer 91 having infrared transparency and blocking transmission of visible light, and a diffusion layer 90 formed on the outer surface of the transparent base layer 23.
- a curve 92 in FIG. 16 shows the spectral transmission characteristics of the dielectric multilayer film 24.
- the dielectric multilayer film 24 has high transmittance to blue, red and infrared light.
- the force bar 21F including the dielectric multilayer film 24 reflects yellow light (see curve 93).
- a curve 94 in FIG. 17 shows the spectral transmission characteristics of the black layer 91.
- One wavelength range of the infrared signal is shown in FIG. 16 and FIG.
- the diffusion layer 90 prevents the black layer 91 from being observed through the dielectric multilayer film 24.
- the diffusion layer 90 suppresses reflection, averages incident light from the outside, and scatters reflected light from the dielectric multilayer film 24.
- visible light that is reflected by the dielectric multilayer film 24 and directed to the observer is relatively increased. Therefore, the reflected light power S of the dielectric multilayer film 24 can be easily seen outside the cover 21F, and in the present embodiment, the force bar 21F can have a clear appearance color (yellow).
- Diffusion layer 90 is formed by, for example, the outer surface of transparent base layer 23 as shown in the textured area 23A of FIG. It may be a roughened layer by physical or chemical treatment in contact with it, or it may be a layer laminated by printing or coating on the outer surface of the base layer 23.
- the transparent base layer 23 is made of a resin such as an acrylic resin having low adhesion to the dielectric multilayer film 24, a hard coat-treated undercoating layer is laminated on the inner surface of the base layer 23. It is also good.
- diffusion layer 90 has the function of scattering the reflected light of dielectric multilayer film 24.
- the black layer 91 is observed. Therefore, the cover 21F does not look dark and has a clear appearance color (yellow reflection color) according to the color of the reflected light of the dielectric multilayer film 24.
- FIG. 18 is a plan view of the cover 21G and a cross-sectional view of the cover 21G along line C-C.
- the lower side of FIG. 18 is the outer surface of the cover 21G and each layer, and the upper side is the inner surface of the cover 21G and each layer.
- the cover 21 ⁇ / b> G includes a transparent base layer 23 having an infrared ray transmitting property and a visible light transmitting property, a dielectric multilayer film 24 formed on the inner side surface of the base layer 23, and an infrared ray transmitting layer formed on the inner side surface of the dielectric multilayer film 24.
- Layer 91 which has the property of blocking the transmission of visible light
- a diffusion layer 90 formed on the outer surface of the transparent base layer 23, and an information printing layer formed between the dielectric multilayer film 24 and the black layer 91.
- the information print layer 95 prints information such as characters, images and patterns.
- the other configuration is the same as the cover 21F of FIG.
- FIG. 18 shows the B character 112 printed with white ink.
- the characters 112 are actually printed on the inner surface of the dielectric multilayer film 24 in reverse (mirror image). Print out the images and patterns.
- the transparent base layer 23 is made of a resin such as an acrylic resin having low adhesion to the dielectric multilayer film 24, a hard coat-treated undercoating layer is laminated on the inner surface of the base layer 23. It is also good.
- the permeability of the dielectric multilayer film 24 to visible light is adjusted so that information such as characters, images and patterns formed on the information printing layer 95 can be viewed on the outside of the cover 21G.
- the layer configuration of the dielectric multilayer film 24 is adjusted such that the dielectric multilayer film 24 selectively allows transmission of visible light in a specific wavelength range.
- the viewer of the cover 21G can see the yellow background area 111 by the reflected light of the dielectric multilayer film 24 and the white B character 112 in the background area 111. Therefore, the cover 21G has an excellent design, and can improve the freedom of design of the electronic device.
- diffusion layer 90 has the function of scattering the reflected light of dielectric multilayer film 24.
- the visible light reflected by the dielectric multilayer film 24 toward the viewer is relatively increased, and the external force of the cover 21G is also a clear appearance color according to the color of the reflected light of the dielectric multilayer film 24 (yellow While the black layer 91 is observed, the As shown in FIG. 19 a, the cover 100 of the comparative example without the diffusion layer is disposed on the front of the dark object 105, the light source 106 is disposed diagonally in front of the cover 100, and the observer 107 is on the front of the cover 100.
- the black layer 91 is observed by the observer through the semitransparent dielectric multilayer film 24 which is not disturbed by the reflected light of the dielectric multilayer film 24. Also, the light beam scattered by the information print layer 95 is observed by the observer 107. Therefore, as shown in FIG. 19b, to the observer of the cover 100 of the comparative example, white characters 102 are visible in the dark background area 101, and the reflection color of the dielectric multilayer film 24 is hardly visible.
- the amount of haze (cloudiness value) of the diffusion layer 90 is determined to such an extent that the decrease in the visibility of the characters 112 is not impaired.
- the cover 21G can display information such as characters, images and patterns in a clear colored background area (in this example, a yellow reflected color).
- the information printing layer 95 is a printed single layer of information such as bright characters, images and patterns. Following the information printing layer 95 is easy. Therefore, the power bar 21 G that displays information such as the character 112 can be easily manufactured.
- the cover 21 G having the appearance including the clear colored background area 111 and the characters 112 has an excellent design and can improve the design freedom of the electronic device.
- FIG. 21 shows a plan view of the cover 21H and a cross-sectional view of the cover 21H along the line D--D.
- the difference between the cover 21 H and the cover 21 G shown in FIG. 18 is that the dielectric multilayer film 24 and the information print layer 95 are interchanged.
- the lower side of FIG. 21 is the outer surface of the cover 21H and each layer, and the upper side is the inner surface of the cover 21H and each layer.
- the cover 21 H includes a transparent base layer 23, an information printing layer 95 formed on the inner side surface of the transparent base layer 23, a dielectric multilayer film 24 laminated on the transparent base layer 23 and the information printing layer 95, and a dielectric multilayer film 24. And a diffusion layer 90 formed on the outer surface of the base layer 23.
- An example of the information printing layer 95 is a single layer including information such as characters, images and patterns printed directly on the inner surface of the base layer 23.
- the cover 21H has an excellent design, and can improve the freedom of design of the electronic device.
- the haze amount (cloudiness value) of the diffusion layer 90 is determined to such an extent that the decrease in the visibility of the characters 112 is not impaired.
- the cover 21H can display information such as characters, images and patterns in a clear colored background area (in this example, a yellow reflected color).
- the information printing layer 95 is a printed single layer of information such as bright characters, images and patterns. Following the information printing layer 95 is easy. It is easy to change the color of the information printing layer 95 or use multiple colors. Therefore, the cover 21H for displaying information such as the characters 112 can be easily manufactured.
- the cover 21 H having an appearance including the clear colored background area 111 and the characters 112 has an excellent design, and can improve the design freedom of the electronic device.
- FIG. 22 An infrared-transparent cover 211 according to a tenth embodiment of the present invention will be described with reference to FIG.
- the lower side of FIG. 22 is the outer surface of the cover 211 and each layer, and the upper side is the inner surface of the cover 211 and each layer.
- the cover 211 has a dark-colored and infrared-transparent base layer 23 B, a dielectric multilayer film 24 formed on the outer surface of the base layer 23 B, and a protective layer 96 formed on the outer surface of the dielectric multilayer film 24. Prepare for.
- the protective layer 96 may be formed by spraying, dipping, sputtering, vacuum evaporation or the like, which has both antifouling properties and sliding properties, such as hardening by hard coating, water repellent coating and the like. Can.
- the protective layer 96 can improve the slipperiness and stain resistance of the outer surface of the cover 211.
- the protective layer 96 formed by vacuum evaporation of an organosilicon-based water repellent is preferable because it has a very thin and uniform thickness.
- the infrared transmitting dark base layer 23 B is made of a resin such as acrylic resin having low adhesion to the dielectric multilayer film 24, a base treatment layer hard coated on the outer surface of the base layer 23 B is laminated. Good luck.
- the protective layer 96 prevents deterioration of the dielectric multilayer film 24 due to abrasion, sebum, etc., the durability of the cover 211 is improved.
- the vacuum evaporation method can form, for example, a thin protective layer 96 of 10 nm or less. Therefore
- the influence of the protective layer 96 on the generation of interference color and the spectral characteristics of the dielectric multilayer film 24 is extremely small.
- FIG. 23 An infrared transmitting cover 21J according to an eleventh embodiment of the present invention will be described with reference to FIG.
- the lower side of FIG. 23 is the outer surface of the cover 21J and each layer, and the upper side is the inner surface of the cover 21J and each layer.
- the difference between the cover 21 J and the cover 211 of FIG. 22 is that the transparent base layer 23 is used instead of the infrared transparent dark base layer 23 B, and the inner surface of the transparent base layer 23 is infrared transparent and acceptable. It is a point that a black layer 91 is formed to block transmission of an optical ray! Other configurations and effects are the same as the cover 211 of FIG.
- a method of manufacturing the cover 21 according to the first embodiment will be described as an example. This manufacturing method is applicable to manufacturing covers other than the cover 21 of the first embodiment. This manufacturing method has a softening point It is suitable for the manufacture of covers comprising a relatively low material base layer which is formed relatively low.
- the method of manufacturing the infrared transmissive cover includes the following steps.
- An infrared-transmissive and visible-light-reflective dielectric multilayer film 24 is formed on the outer surface of the infrared-transmissive base layer 23 by a low-temperature film formation technique.
- the low temperature deposition technique is a technique for forming a thin film by maintaining the base layer at a temperature below the softening point. Examples of low temperature deposition techniques are IAD (ion-assisted deposition), plasma CVD, and sputtering (sputtering).
- Resin materials such as polycarbonate and acrylic resin used for the base layer 23 have a low softening temperature.
- the base layer 23 is generally heated to 200 ° C. to 300 ° C. Therefore, it is difficult to form the dielectric multilayer film 24 on the base layer 23 made of a low softening point material such as resin by the usual vacuum evaporation method.
- the dielectric multilayer film 24 is formed on the outer surface of the base layer 23 by a low temperature deposition technique such as IAD (ion-assisted deposition), plasma CVD, or sputtering (sputtering), so the softening point temperature is low.
- a dielectric multilayer film 24 having desired spectral characteristics can be formed on the base layer 23 made of a resin material.
- FIG. 24 shows a portable information terminal 80 as an electronic device.
- the portable information terminal 80 includes a housing attached with an infrared ray transparent cover 81, an operation key 82, and a display unit 83.
- the cover 81 has the structure described in the above embodiment and examples.
- the following effects can be obtained.
- the portable information terminal 80 is provided with an infrared transmitting cover 81 capable of obtaining an arbitrary appearance color.
- an infrared transmitting cover 81 capable of obtaining an arbitrary appearance color.
- the base layers 23, 60 may be any of (1) to (5) described above.
- the cover can be given an appearance color according to the choice of base layer.
- the transparent base layer 23 of the first to fourth embodiments and the transparent base layer 60 of the sixth embodiment may be changed to a milky white base layer.
- the color of reflected light from the dielectric multilayer film 24 (dielectric multilayer film 61 in the sixth embodiment) (reflected color) is added with the color of reflected light from the milky white base layer (milky white). can get.
- a pearl-like lustrous texture can be obtained and a high-class feeling can be imparted.
- the base layer 23 of the first to fourth embodiments and the base layer 60 of the sixth embodiment may be changed to the (4) dark base layer or (5) opaque base layer described above.
- the color (reflected color) of the reflected light by the dielectric multilayer film 24 (the dielectric multilayer film 61 in the sixth embodiment) can be made clearer, and the infrared transparency in the state of being attached to the electronic device It also has the effect of hiding the inside of the cover.
- the inner surface of the base layer 23 may be textured instead of the outer surface of the transparent base layer 23 being textured. Also in this case, the effect of the fifth embodiment is maintained.
- a resin material such as polycarbonate having a low soft softening point temperature or an acrylic resin is used as the base layer 23, and the low temperature film forming technology A dielectric multilayer film 24 was formed on the surface 23.
- the base layer is made of a high soft melting point material such as glass
- the dielectric multilayer film may be formed on the base layer by a method other than the low temperature film forming technique, for example, a normal vacuum evaporation method. it can.
- the dielectric multilayer film 24 of Example 1 shown in Table 1 is a laminate of eight thin films configured to obtain a blue appearance color.
- the dielectric multilayer film 24 may be formed by laminating eight thin films so as to obtain an appearance color other than blue, for example, a yellow appearance color.
- the number of thin films is not limited to eight.
- the dielectric multilayer films 24 of Examples 2 and 3 shown in Tables 3 and 5 are a laminate of seven thin films configured to obtain a yellow appearance color.
- the dielectric multilayer film 24 may be formed by laminating seven thin films so as to obtain an appearance color other than yellow, for example, a blue appearance color.
- the number of thin films is not limited to seven.
- the information printing layer 95 may be composed of a plurality of printed layers of characters, images and patterns.
- the cover of each embodiment is not limited to a flat plate and a curved plate, and can have various shapes.
- the shape of the cover can be modified to match the appearance of the electronic device.
- a cover 21K shown in FIG. 25 is a three-dimensional cap having a side wall. Cover 21 K may also be equipped with mounting claws for engaging electronic devices.
- the deposition material such as ZrO.sub.2, SiO.sub.
- each layer can be appropriately changed according to the desired appearance color of the cover.
- the cover can have an appearance color such as blue, light blue, green, yellow, pink, red, and silver.
- the infrared transparent cover of the present invention is not limited to the portable information terminal 80, but is various electronic devices such as desktop computers, notebook computers, digital cameras, etc., and it is possible to use electronic devices provided with an infrared transparent cover. It is applicable.
- the cover of the present invention can be used for a surveillance camera using an image sensor such as a CCD and a CMOS.
- a surveillance camera detects near infrared rays. It is desirable that surveillance cameras be installed in stores without prominence. Therefore, the surveillance camera can be housed and used in a housing having a photographing window attached with the cover of the present invention.
- a calculator, a watch and a power generation device are known as electronic devices provided with a solar cell.
- Such electronic devices are relatively wide and include a light receiving surface of a light receiving area.
- the light of the main emission radio wave length received by the light receiving surface enters a solar cell disposed in the housing of the electronic device.
- the decorativeness of the light receiving surface can be improved by attaching the cover of the present invention to the light receiving surface.
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
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CN200580038563.9A CN101057341B (zh) | 2004-11-12 | 2005-10-07 | 红外线透射盖子 |
EP05790663A EP1837920B8 (en) | 2004-11-12 | 2005-10-07 | Infrared-transmitting cover |
US11/667,568 US20080316594A1 (en) | 2004-11-12 | 2005-10-07 | Infrared-Transmitting Cover |
KR1020077011684A KR101158821B1 (ko) | 2004-11-12 | 2005-10-07 | 적외선 투과성 커버 |
AT05790663T ATE547811T1 (de) | 2004-11-12 | 2005-10-07 | Infrarotsendende abdeckung |
US13/670,127 US20130063810A1 (en) | 2004-11-04 | 2012-11-06 | Infrared-transmitting cover |
Applications Claiming Priority (4)
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JP2004-328906 | 2004-11-04 | ||
JP2004328906 | 2004-11-12 | ||
JP2005-117090 | 2005-04-14 | ||
JP2005117090A JP4122010B2 (ja) | 2004-11-12 | 2005-04-14 | 赤外線受発光部 |
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US13/670,127 Continuation-In-Part US20130063810A1 (en) | 2004-11-04 | 2012-11-06 | Infrared-transmitting cover |
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WO2006051664A1 true WO2006051664A1 (ja) | 2006-05-18 |
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US (1) | US20080316594A1 (ja) |
EP (1) | EP1837920B8 (ja) |
JP (1) | JP4122010B2 (ja) |
KR (1) | KR101158821B1 (ja) |
AT (1) | ATE547811T1 (ja) |
WO (1) | WO2006051664A1 (ja) |
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Also Published As
Publication number | Publication date |
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US20080316594A1 (en) | 2008-12-25 |
EP1837920A1 (en) | 2007-09-26 |
KR20070084497A (ko) | 2007-08-24 |
JP4122010B2 (ja) | 2008-07-23 |
KR101158821B1 (ko) | 2012-07-03 |
EP1837920B1 (en) | 2012-02-29 |
EP1837920A4 (en) | 2009-03-18 |
ATE547811T1 (de) | 2012-03-15 |
EP1837920B8 (en) | 2012-04-18 |
JP2006165493A (ja) | 2006-06-22 |
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