WO2005084799A1 - Catalyst carrier and catalyst composition, processes for their preparation and their use - Google Patents

Catalyst carrier and catalyst composition, processes for their preparation and their use Download PDF

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Publication number
WO2005084799A1
WO2005084799A1 PCT/EP2005/050866 EP2005050866W WO2005084799A1 WO 2005084799 A1 WO2005084799 A1 WO 2005084799A1 EP 2005050866 W EP2005050866 W EP 2005050866W WO 2005084799 A1 WO2005084799 A1 WO 2005084799A1
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
carrier
range
acid
present
Prior art date
Application number
PCT/EP2005/050866
Other languages
English (en)
French (fr)
Inventor
Edward Julius Creyghton
Laurent Georges Huve
Cornelis Ouwehand
Johannes Anthonius Robert Van Veen
Original Assignee
Shell Internationale Research Maatschappij B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij B.V. filed Critical Shell Internationale Research Maatschappij B.V.
Priority to CA002558172A priority Critical patent/CA2558172A1/en
Priority to JP2007501276A priority patent/JP2007526119A/ja
Priority to EP05716843A priority patent/EP1735094A1/de
Priority to BRPI0508276-5A priority patent/BRPI0508276A/pt
Publication of WO2005084799A1 publication Critical patent/WO2005084799A1/en
Priority to ZA2006/06951A priority patent/ZA200606951B/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm

Definitions

  • the form is very suitably a conventional TRILOBE, twisted trilobe, or quadrilobe form (Trilobe is a trade mark) .
  • the form may usefully be a shaped trilobe as described in International patent publication WO 03/013725.
  • hydrocarbonaceous feedstocks useful in the present process can vary within a wide boiling range. They include atmospheric gas oils; coker gas oils; vacuum gas oils; deasphalted oils; fractions, eg gas oils and waxes, obtained from a Fischer-Tropsch synthesis process, long and short residues, catalytically cracked cycle oils, thermally or catalytically cracked gas oils, and syncrudes, optionally originating from tar sand, shale oils, residue upgrading processes and biomass .
  • the space velocity is in the range from 0.1 to 10, particularly from 0.2 to 8, and preferably from 0.5 to 5 kg.l ⁇ l.h ⁇ l.
  • the ratio of hydrogen gas to feedstock (total gas rate or the gas/feed ratio) used in the present process will generally be in the range from 100 to 5000 Nl/kg, but is preferably in the range from 200 to 3000 Nl/kg, more preferably 250 to 2000 Nl/Kg.
  • the hydrocracking process of the present invention may be used to particularly advantageous effect in single-stage hydrocracking, wherein it gives a good efficiency of conversion even on exposure to feedstocks comprising nitrogen and sulphur-containing contaminants.
  • One application of single-stage hydrocracking is the production of middle distillate fractions.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
PCT/EP2005/050866 2004-03-03 2005-03-01 Catalyst carrier and catalyst composition, processes for their preparation and their use WO2005084799A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CA002558172A CA2558172A1 (en) 2004-03-03 2005-03-01 Catalyst carrier and catalyst composition, processes for their preparation and their use
JP2007501276A JP2007526119A (ja) 2004-03-03 2005-03-01 触媒担体と触媒組成物、それらの調製方法およびそれらの使用方法
EP05716843A EP1735094A1 (de) 2004-03-03 2005-03-01 Katalysatorträger und katalysatorzusammensetzung, herstellungsverfahren dafür und verwendung davon
BRPI0508276-5A BRPI0508276A (pt) 2004-03-03 2005-03-01 suporte catalìtico conformado, processo para a preparação de um suporte catalìtico, composição catalìtica, processos para a preparação de uma composição catalìtica e de hidrocraqueamento, e, uso de uma composição catalìtica
ZA2006/06951A ZA200606951B (en) 2004-03-03 2006-08-18 Catalyst carrier and catalyst composition processes for their preparation and their use

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP04251241 2004-03-03
EP04251241.8 2004-03-03

Publications (1)

Publication Number Publication Date
WO2005084799A1 true WO2005084799A1 (en) 2005-09-15

Family

ID=34896131

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2005/050866 WO2005084799A1 (en) 2004-03-03 2005-03-01 Catalyst carrier and catalyst composition, processes for their preparation and their use

Country Status (11)

Country Link
US (1) US20050197249A1 (de)
EP (1) EP1735094A1 (de)
JP (1) JP2007526119A (de)
KR (1) KR20070004776A (de)
CN (1) CN100428995C (de)
BR (1) BRPI0508276A (de)
CA (1) CA2558172A1 (de)
RU (1) RU2366505C2 (de)
UA (1) UA91016C2 (de)
WO (1) WO2005084799A1 (de)
ZA (1) ZA200606951B (de)

Cited By (7)

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EP1584373A2 (de) * 2004-03-12 2005-10-12 Chevron Oronite Company LLC Zeolith Y Katalysator für die Alkylierung von aromatischen Kohlenwasserstoffen
WO2010126955A1 (en) 2009-04-29 2010-11-04 Pq Corporation Zeolite y
WO2010124935A1 (en) 2009-04-29 2010-11-04 Shell Internationale Research Maatschappij B.V. Hydrocracking catalyst
US8877671B2 (en) 2005-12-14 2014-11-04 Advanced Refining Technologies Llc Method of making hydroprocessing catalyst
US9272971B2 (en) 2012-02-28 2016-03-01 Sekisui Chemical Co., Ltd. Catalyst for C2 oxygenate synthesis, device for manufacturing C2 oxygenate, and method for manufacturing C2 oxygenate
CN107469870A (zh) * 2017-08-29 2017-12-15 淄博齐茂催化剂有限公司 一种调节孔结构的催化剂的制备方法
FR3130640A1 (fr) 2021-12-21 2023-06-23 IFP Energies Nouvelles Catalyseur comprenant un support à base de matrice silico-aluminique et de zéolithe, sa préparation et procédé d’hydrocraquage de charges hydrocarbonées

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US7169291B1 (en) * 2003-12-31 2007-01-30 Uop Llc Selective hydrocracking process using beta zeolite
US7507844B2 (en) * 2005-05-09 2009-03-24 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Nanometer scale restructuring of alumina carrier surface and catalysts for the production of alkene oxides
US7585405B2 (en) * 2005-11-04 2009-09-08 Uop Llc Hydrocracking catalyst containing beta and Y zeolites, and process for its use to make jet fuel or distillate
US7510645B2 (en) * 2005-11-04 2009-03-31 Uop Llc Hydrocracking catalyst containing beta and Y zeolites, and process for its use to produce naphtha
CN101489668B (zh) * 2006-06-20 2013-03-13 国际壳牌研究有限公司 含贵金属的耐硫芳烃加氢催化剂及其制备方法和应用
US20080011649A1 (en) * 2006-07-17 2008-01-17 Li Wang Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate
US20080011647A1 (en) * 2006-07-17 2008-01-17 Li Wang Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate
US20080011648A1 (en) * 2006-07-17 2008-01-17 Li Wang Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate
CN101815577A (zh) * 2007-08-27 2010-08-25 国际壳牌研究有限公司 芳烃加氢催化剂及其制备和使用方法
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US9187702B2 (en) * 2009-07-01 2015-11-17 Chevron U.S.A. Inc. Hydroprocessing catalyst and method of making the same
JP5547923B2 (ja) * 2009-08-03 2014-07-16 出光興産株式会社 重質油水素化分解触媒及びそれを用いた重質油の水素化処理方法
CN103889573B (zh) 2011-10-24 2016-08-24 道达尔炼油法国 用于制备加氢转化催化剂的方法、由此获得的催化剂及其在加氢转化方法中的用途
CN104105542B (zh) * 2011-12-23 2017-02-22 国际壳牌研究有限公司 制备加氢裂化催化剂组合物的方法
KR101885247B1 (ko) * 2012-07-26 2018-08-03 삼성전자주식회사 Ｃｏ２ 개질용 촉매, 그 제조 방법, 및 ｃｏ２ 개질 방법
RU2640804C2 (ru) * 2012-09-17 2018-01-18 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ получения катализатора гидрокрекинга
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US20150159095A1 (en) * 2013-12-09 2015-06-11 Bi-Zeng Zhan Method for making a middle distillate
US10138428B2 (en) * 2014-05-08 2018-11-27 Reliance Industries Limited Catalyst assisted conversion of biomass to bio-oil
US20160121312A1 (en) * 2014-10-31 2016-05-05 Chevron U.S.A. Inc. Middle distillate hydrocracking catalyst containing highly nanoporous stabilized y zeolite
US20160121313A1 (en) * 2014-10-31 2016-05-05 Chevron U.S.A. Inc. Middle distillate hydrocracking catalyst containing highly a stabilized y zeolite with enhanced acid site distribution
US10183282B2 (en) * 2015-01-22 2019-01-22 Chevron U.S.A. Inc. Noble metal zeolite catalyst for second-stage hydrocracking
US10183286B2 (en) * 2015-08-11 2019-01-22 Chevron U.S.A. Inc. Noble metal zeolite catalyst for second-stage hydrocracking to make middle distillate
CN107344107B (zh) * 2016-05-05 2019-10-15 中国石油化工股份有限公司 一种加氢改质催化剂及其制备方法
RU2633965C1 (ru) * 2016-10-19 2017-10-20 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) Способ приготовления катализатора гидрокрекинга углеводородного сырья
US20190126227A1 (en) * 2017-10-30 2019-05-02 Saudi Arabian Oil Company Catalyst loading method to disperse heat in hydroconversion reactor
WO2020119754A1 (zh) 2018-12-13 2020-06-18 中国石油化工股份有限公司 一种加氢裂化催化剂及其制备方法和应用

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US20030173256A1 (en) * 2001-06-20 2003-09-18 Takashi Fujikawa Catalyst for hydrogenation treatment of gas oil and method for preparation thereof, and process for hydrogenation treatment of gas oil
FR2863913A1 (fr) * 2003-12-23 2005-06-24 Inst Francais Du Petrole Catalyseur zeolithique,support a base de matrice silico-aluminique et de zeolithe, et procede d'hydrocraquage de charges hydrocarbonees

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EP1584373A3 (de) * 2004-03-12 2006-02-01 Chevron Oronite Company LLC Zeolith Y Katalysator für die Alkylierung von aromatischen Kohlenwasserstoffen
EP2095874A3 (de) * 2004-03-12 2009-10-21 Chevron Oronite Company LLC Zeolith-Y-Alkylierungskatalysatoren
EP1584373A2 (de) * 2004-03-12 2005-10-12 Chevron Oronite Company LLC Zeolith Y Katalysator für die Alkylierung von aromatischen Kohlenwasserstoffen
US8877671B2 (en) 2005-12-14 2014-11-04 Advanced Refining Technologies Llc Method of making hydroprocessing catalyst
US9566572B2 (en) 2005-12-14 2017-02-14 Advanced Refining Technologies Llc Method of making hydroprocessing catalyst
US9248438B2 (en) 2005-12-14 2016-02-02 Advanced Refining Technologies Llc Method of making hydroprocessing catalyst
WO2010124935A1 (en) 2009-04-29 2010-11-04 Shell Internationale Research Maatschappij B.V. Hydrocracking catalyst
US9199228B2 (en) 2009-04-29 2015-12-01 Shell Oil Company Hydrocracking catalyst
RU2487756C1 (ru) * 2009-04-29 2013-07-20 ПиКью КОРПОРЕЙШН Цеолит y
US9308521B2 (en) 2009-04-29 2016-04-12 Pq Corporation Zeolite Y
WO2010126955A1 (en) 2009-04-29 2010-11-04 Pq Corporation Zeolite y
US10610855B2 (en) 2009-04-29 2020-04-07 Shell Oil Company Hydrocracking catalyst
US9272971B2 (en) 2012-02-28 2016-03-01 Sekisui Chemical Co., Ltd. Catalyst for C2 oxygenate synthesis, device for manufacturing C2 oxygenate, and method for manufacturing C2 oxygenate
CN107469870A (zh) * 2017-08-29 2017-12-15 淄博齐茂催化剂有限公司 一种调节孔结构的催化剂的制备方法
FR3130640A1 (fr) 2021-12-21 2023-06-23 IFP Energies Nouvelles Catalyseur comprenant un support à base de matrice silico-aluminique et de zéolithe, sa préparation et procédé d’hydrocraquage de charges hydrocarbonées
WO2023117475A1 (fr) 2021-12-21 2023-06-29 IFP Energies Nouvelles Catalyseur comprenant un support à base de matrice silico-aluminique et de zéolithe, sa préparation et procédé d'hydrocraquage de charges hydrocarbonées

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CA2558172A1 (en) 2005-09-15
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EP1735094A1 (de) 2006-12-27
BRPI0508276A (pt) 2007-08-07
CN100428995C (zh) 2008-10-29
KR20070004776A (ko) 2007-01-09
UA91016C2 (ru) 2010-06-25
US20050197249A1 (en) 2005-09-08
JP2007526119A (ja) 2007-09-13
CN1938088A (zh) 2007-03-28
ZA200606951B (en) 2008-04-30

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