WO2005039516A1 - 油性固形化粧料 - Google Patents

油性固形化粧料 Download PDF

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Publication number
WO2005039516A1
WO2005039516A1 PCT/JP2004/013420 JP2004013420W WO2005039516A1 WO 2005039516 A1 WO2005039516 A1 WO 2005039516A1 JP 2004013420 W JP2004013420 W JP 2004013420W WO 2005039516 A1 WO2005039516 A1 WO 2005039516A1
Authority
WO
WIPO (PCT)
Prior art keywords
fatty acid
oil
wax
solid cosmetic
cosmetic
Prior art date
Application number
PCT/JP2004/013420
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
Kazuhiro Tsuhara
Youichi Mizutori
Original Assignee
Kose Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kose Corporation filed Critical Kose Corporation
Priority to CN2004800297883A priority Critical patent/CN1867318B/zh
Priority to KR1020067007009A priority patent/KR101097832B1/ko
Priority to JP2005514911A priority patent/JP4851187B2/ja
Priority to HK07102532.4A priority patent/HK1095284B/xx
Publication of WO2005039516A1 publication Critical patent/WO2005039516A1/ja

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures

Definitions

  • the present invention relates to an oily solid cosmetic, and more particularly, it has a soft skin contact that spreads well when applied, and has excellent gloss and moisture feeling of a chemical film and shape retention.
  • the present invention relates to an oily solid cosmetic having good stability over time.
  • Oil-based solid cosmetics are cosmetic dosage forms that are widely used for lipsticks and the like, and are mainly composed of oil components such as solid oil, semi-solid oil, and liquid oil, as well as coloring pigments, brilliant pigments, and body powders. It is composed of body powder components.
  • oil components such as solid oil, semi-solid oil, and liquid oil
  • coloring pigments brilliant pigments
  • body powders It is composed of body powder components.
  • the amount of the oil component and the powder component are changed in order to maintain the shape, the solidifying agent added to increase the strength is examined, There have been attempts to improve the properties of cosmetics by imparting various functionalities to the cosmetics and producing texture and color.
  • an oil-based solid cosmetic product has improved stability by using an ethylene-propylene copolymer as a solidification mass U (for example, Patent Documents 1 and 2).
  • Patent Documents 1 and 2 an oil-based solid cosmetic product has improved stability by using an ethylene-propylene copolymer as a solidification mass U (for example, Patent Documents 1 and 2).
  • Patent Document 3 an ethylene-propylene copolymer
  • Patent Document 4 the polyglycerin fatty acid esters that are often used as a surfactant
  • Patent Document 5 a technique of using a solid polyglycerin fatty acid ester mainly composed of an acid for suppressing a sweating phenomenon
  • Patent Document 1 Japanese Patent No. 2519469
  • Patent Document 2 Japanese Patent No. 3073869
  • Patent Document 3 Japanese Patent Publication No. 7-100645
  • Patent Document 4 Japanese Patent Application Laid-Open No. 7-187947
  • Patent Document 5 JP-A-2002-53420
  • Patent Document 6 Patent No. 2960658 ''
  • the new required quality for oil-based solid cosmetics that is, having a soft skin area that spreads well when applied, and has a glossy and moist feeling of the cosmetic film It has been desired to develop an oil-based solid cosmetic that satisfies quality requirements such as excellent in shape, shape retention, and stability over time.
  • the present inventors have conducted intensive studies to solve the above-mentioned problems. As a result, the present inventors have found that a combination of a hydrocarbon wax and a specific polyglycerin fatty acid ester has a low crystallinity. It was found that a soft gel could be formed, and that smoothness at the time of application, soft skin touch, gloss, moisture, and feeling were obtained. In addition, by further adding a silicic acid anhydride thereto, it is possible to improve the holding power of the oily component without damaging the gel structure. The present inventors have found that an oily solid cosmetic having good shape retention and stability over time, which does not easily cause a sweating phenomenon, can be obtained, and the present invention has been completed.
  • the present invention provides the following components (a) to (c):
  • the fatty acid is a branched fatty acid having 16 to 20 carbon atoms having a glycerin polymerization degree of 7 to 11,
  • Polyglycerol fatty acid esters that are liquid at room temperature with a degree of ester substitution of 65% or more
  • the oil-based solid cosmetic of the present invention is excellent in smoothness at the time of application, is excellent in usability such as soft skin contact, is excellent in luster of a makeup film, lasts a moist feeling, and has shape retention and stability over time. It is good.
  • examples of the hydrocarbon wax used as the component (a) include paraffin wax, ceresin wax, montan wax, microcrystalline wax, ethylene 'propylene copolymer, polyethylene wax, Fischer-Tropsch wax and the like.
  • synthetic hydrocarbon waxes such as ethylene'propylene copolymer, polyethylene wax, and fish'yatropsch wax are preferred.
  • the ethylene 'propylene copolymer having a molecular weight in the range of 500 to 700 is particularly preferred, and the one having a melting point in the range of 80 to 110 ° C is particularly preferred from the viewpoint of shape retention.
  • Examples of commercially available ethylene propylene copolymers include Petrolite EP-700 (manufactured by Baker Petrolite), and commercially available polyethylene waxes include PER F ⁇ RMALENE500, PERF ⁇ RMALENE655, and PERFORMALENE725. , PER FORMALENE850 (manufactured by Baker Petrolite) and the like, and commercial products of Fischer-Tropsch wax include CIREBELLE108 (manufactured by CIREBELLE).
  • the content of the component (a) in the oil-based solid cosmetic of the present invention is 0.:! In particular, 2 to 15% is more preferable, in which % 20% by mass (hereinafter simply referred to as “%”) is preferable. In this range When contained, the feeling of use and the stability over time are good, the gloss is excellent, and the shape retention is further improved.
  • the component (b) of the present invention is a branched fatty acid having a degree of polymerization of glycerin of 7 to 11 and a fatty acid of 16 to 20 carbon atoms and a degree of ester substitution of 65% or more, which is liquid at room temperature.
  • Glycerin is a fatty acid ester.
  • the degree of polymerization of glycerin constituting polyglycerin is 7 to 11 as described above. Of these forces, 10 (decaglycerin) is preferable. Further, the polyglycerin may be polymerized to form a ring, but is preferably one in which glycerin is polymerized in a chain. '
  • constituent fatty acids of the polyglycerin fatty acid ester have 16 to 2 carbon atoms as described above.
  • a power S which is a branched fatty acid of 0, and among them, isostearic acid having 18 carbon atoms obtained by extraction from a plant is more preferable.
  • the degree of ester substitution of the polyglycerol fatty acid esterol is 65% or more as described above, and is preferably 75% or more.
  • the degree of ester substitution refers to a ratio of hydroxyl groups esterified with a fatty acid, among all the hydroxyl groups that can be esterified in polyglycerin. ⁇
  • Examples of commercially available polyglycerin fatty acid esters as described above include NIKKOL Decagly n 10-IS (manufactured by Nikko Chemicals Co., Ltd.) and S-face IS-1009P (manufactured by Sakamoto Pharmaceutical Co., Ltd.). Can be used. '
  • the content of the component (b) in the oily solid cosmetic of the present invention is preferably 0.1 to 50%, and particularly preferably 1 to 35%. When it is contained in this range, the feeling in use and the stability over time are good, and the gloss is excellent.
  • the silicic anhydride used as the component (c) in the oily solid cosmetic of the present invention is commonly used in cosmetics, and has an amorphous structure, a hydrophobicized one, or Any of those having a crystal structure is acceptable.
  • these silicic anhydrides preferred are those having a specific surface area of 100 m 2 Zg or more.
  • the content of the component (c) in the oily solid cosmetic of the present invention is preferably from 0.1 to 5%, particularly preferably from 0.5 to 3%. When it is contained in this range, the feeling in use and the stability over time are good, and the gloss is excellent.
  • the oil-based solid cosmetic preparation of the present invention is prepared by, for example, dissolving the component (a) and the component (b) by heating at about 110 to 12 ° C, adding the component (c), and mixing them uniformly. I do. After further heating, defoaming, it may be poured into a mold, filled, cooled and molded.
  • the oil-based solid cosmetic of the present invention does not impair the effects of the present invention depending on the purpose, depending on the purpose!
  • optional components can be blended.
  • optional components include an oily component for imparting a moisturizing effect, a powder for imparting texture control and coloring, a surfactant for imparting pigment dispersibility and a cosmetic holding effect,
  • Other components that are usually blended in cosmetics such as fibers, ultraviolet absorbers, humectants, film-forming agents, anti-fading agents, antioxidants, defoamers, cosmetic ingredients, preservatives, and fragrances can be mentioned.
  • the oily component includes hydrocarbons, irrespective of the origin of animal oil, vegetable oil, synthetic oil, etc., and solid oil, semi-solid oil, liquid oil, volatile oil, etc.
  • examples include oils and fats, waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine-based oils, lanolin derivatives, oily gelling agents, and the like.
  • hydrocarbons such as liquid paraffin, squalane, petrolatum, etc.
  • oils and fats such as mocro, olive oil, castor oil, mink oil, madame nut oil, beeswax, carnauba wax
  • Waxes such as delila wax and gay wax, diisostearyl malate, cetyl isooctanate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, polyglyceryl diisostearate, diglyceryl triisostearate, glyceryl tribehenate
  • Fluorinated oils lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, dextrin fatty acid ester, sucrose fatty acid ester, starch fatty acid ester, 12-hydrazine Kishisutearin acid, aluminum isostearate, oily gelling agents such as calcium stearic phosphate and the like.
  • the powder component is not particularly limited by shapes such as spherical, plate-like, and needle-like, fume-like, fine particle, particle size such as pigment grade, and particle structure such as porous and nonporous. , Inorganic powders, brilliant powders, organic powders, pigment powders, metal powders, composite powders and the like.
  • Specific examples include white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, and barium sulfate; and colored inorganic pigments such as iron oxide, carbon black, chromium oxide, chromium hydroxide, navy blue, and ultramarine blue.
  • White powder titanium dioxide coated mica, titanium dioxide coated oxychloride bismuth, iron oxide mica titanium, Blue-treated mica titanium, carmine-treated mica titanium, brilliant powders such as oxy-salt bismuth, fish scale foil, polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, fluorine resin, cellulose resin, Polystyrene resin Moonlight, copolymer resin such as styrene-acrylic copolymer, organic polymer resin powder such as polypropylene resin, silicone resin, urethane resin, zinc stearate, N-acid / resin resin, etc. Natural organic powders such as organic low molecular weight powder, starch, silk powder, cellulose powder
  • Organic pigment powders such as zirconium, barium or aluminum lake, and metal powders such as aluminum-powder powder, gold powder and silver powder, fine titanium oxide coated mica titanium, fine zinc oxide coated mica titanium, barium sulfate coated
  • Composite powders such as titanium mica, silicon dioxide containing titanium oxide, silicon dioxide containing zinc oxide, glass powder coated with titanium oxide, polyethylene terephthalate; aluminum / epoxy laminated powder; polyethylene terephthalate; polyolefin laminated film powder; polyethylene terephthalate poly Laminating agents and the like of the powder of methyl methacrylate film can be used, and one or more of these powders can be used. According, also be used as further complexed I spoon.
  • These powders may be one or more of fluorine compounds, silicone compounds, metal stones, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes, surfactants, etc.
  • the surface treatment may be performed by using two or more kinds. .
  • surfactant surfactant any surfactant commonly used in cosmetics may be used.
  • Nonionic surfactants anionic surfactants, cationic surfactants, amphoteric surfactants Agents and the like.
  • nonionic surfactants include, for example, glycerin fatty acid ester and its alkylene glycol adduct, boliglycerin fatty acid ester azylene glycol adduct, propylene glycol fatty acid ester and its alkylene glycol Recall adducts, sorbitan fatty acid esters and their alkylene glycol adducts, sorbitol fatty acid esters and their alkylene glycol adducts, polyalkylene glycol fatty acid esters, sucrose fatty acid esters, polyoxyalkylene alkyl esters, glycerin alkyl ethers, polyoxy Ethylene alkyl fuel ether, polyoxyethylene hydrogenated castor oil, alkylene glycol adduct of lanolin, polyoxyalkylene-modified silicone, polyoxy Ruki alkylene alkyl co-modified silicones are exemplified up.
  • ayuonic surfactant examples include fatty acids such as stearic acid and lauric acid, and inorganic and organic salts thereof, alkylbenzene sulfate, alkyl sulfonate, and C —Olefin sulfonate, dialkyl sulfosuccinate, a-sulfonyl fatty acid salt, asinolemethyl taurine salt, N-methyl-N-alkyl taurine salt, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl ferrate Resulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl phenyl ether phosphate, N-acyl amino acid salt, N-acyl-N-alkyl amino acid salt, 0-alkyl substituted malic acid Salts, alkyl sulfosuccinates and the like.
  • fatty acids such as stearic acid and lauric acid
  • Examples of the cationic surfactant include an alkylamine salt, a polyamine and a alkanolamine fatty acid derivative, an alkyl quaternary ammonium salt, and a cyclic quaternary ammonium salt.
  • amphoteric surfactant there are carboxylic acid type, betaine type, carboxylic acid type, sulfate type, sulfonic acid type and phosphate type, and those which are safe for the human body are used. It can.
  • examples of the fiber include synthetic fibers such as nylon, polyester, and polyolefin, artificial fibers such as rayon, natural fibers such as cellulose, and synthetic fibers such as acetate human silk. These fibers may be those treated with a general oil, silicone oil, a fluorine compound, a surfactant or the like as long as the effects of the present invention are not impaired.
  • ultraviolet absorber examples include benzophenone-based, iBA-based, cinnamic acid-based, salicylic acid-based, 4_tert_butyl-4-methoxydibenzoylmethane, oxybenzone, and the like.
  • components to be mixed for the purpose of adjusting the moisturizing effect and feel of the oil-based solid cosmetic of the present invention include, for example, water-soluble polymers, proteins, mucopolysaccharides, collagen, elastin, keratin and the like.
  • Aqueous components and the like can be mentioned.
  • examples of the water-soluble polymer include natural ones such as guar gum, sodium chondroitin sulfate, hyaluronic acid, gum arabic, and carrageenan, and synthetic ones such as methylcellulose, hydroxyethylcellulose, and carboxymethylcellulose. Synthetic polymers such as carboxyvinyl polymers can be mentioned.
  • the aqueous component may be any component soluble in water and water.
  • glycols such as propylene glycol, 1,3-butylene glycol, and dipropylene glycolone may be used.
  • glycerols such as glycerin, diglycerin and polyglycerin, and plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender and rose.
  • antioxidants for example, ⁇ -tocopherol and ascorbic acid
  • cosmetic ingredients for example, as vitamins, anti-inflammatory agents, crude drugs, etc .
  • preservatives for example, ⁇ -oxybenzoic acid Esters, phenoxyethanol and the like.
  • the oil-based solid cosmetic of the present invention described above can be used as a makeup cosmetic, a skin care cosmetic, a hair cosmetic, and the like, and can be formed into various shapes and product forms depending on purposes. Examples include sticks, dishes, and pencils, and examples of products include lipstick, lip darros, lip balm, foundation, lipstick, eye color, eye liner, eyebrow, eye cream, and hair wax. Can be In particular, lip cosmetics have a remarkable effect and are preferred.
  • stick-shaped lipsticks of the present invention products 1 to 11 and comparative products 1 to 4 were produced Built.
  • the feeling of use extended and spread, soft skin contact
  • the gloss of the makeup film was evaluated according to the self-evaluation criteria.
  • the lipstick was stored at a high temperature, and the shape retention and the stability over time were evaluated. Table 1 also shows the results.
  • Components (1) to (; 13) are heated and dissolved at 110 to 120 ° C, and then components (14) to (20) are mixed together and uniformly mixed.
  • the stick-like lipstick of the product of the present invention is excellent in shape retention and stability over time, and has a feeling of use at the time of application (expansion, soft skin contact), gloss of a cosmetic film, The feeling of moisture was good.
  • Comparative Example 1 a product satisfying the stability over time was not obtained, and decaglycerin behen was used instead of the component (b). Comparative products 2 and 3 containing acid ester and tetraglycerin lysostearate did not provide satisfactory moistness, and comparative product 4 containing no component (c) was particularly stable over time. Satisfaction in terms of sex could not be obtained.
  • the dish-shaped eyeshadow obtained in this example had a smooth feeling in use, was excellent in gloss of the decorative film, had no perspiration, and had good stability over time.
  • the lip balm obtained in this example has a soft skin feel and a smooth feeling of use.
  • UV absorber (shear oil)
  • B is filled and molded into a product.
  • the pencil eyeliner obtained in this example had a soft skin feel, a smooth feeling of use, was excellent in luster, and had good stability over time.
  • Components (1) to (9) are uniformly dissolved at 100 ° C.
  • the oily solid foundation obtained in this example had a soft skin feel, a smooth feeling of use, excellent luster, and good stability over time.
  • Components (1) to (10) are uniformly dissolved at 100 ° C.
  • the oil-based solid eye color obtained in this example has a soft skin feel, a smooth feeling of use, excellent gloss, and good stability over time. .
  • the hair wax obtained in this example had a soft and smooth feel on hair, was excellent in moist feeling, and had good shape retention and regeneration.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)
PCT/JP2004/013420 2003-10-15 2004-09-15 油性固形化粧料 WO2005039516A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2004800297883A CN1867318B (zh) 2003-10-15 2004-09-15 油性固体化妆料
KR1020067007009A KR101097832B1 (ko) 2003-10-15 2004-09-15 유성 고형 화장료
JP2005514911A JP4851187B2 (ja) 2003-10-15 2004-09-15 油性固形化粧料
HK07102532.4A HK1095284B (en) 2003-10-15 2004-09-15 Oily solid cosmetic

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2003354504 2003-10-15
JP2003-354504 2003-10-15

Publications (1)

Publication Number Publication Date
WO2005039516A1 true WO2005039516A1 (ja) 2005-05-06

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PCT/JP2004/013420 WO2005039516A1 (ja) 2003-10-15 2004-09-15 油性固形化粧料

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JP (1) JP4851187B2 (enrdf_load_stackoverflow)
KR (1) KR101097832B1 (enrdf_load_stackoverflow)
CN (1) CN1867318B (enrdf_load_stackoverflow)
TW (1) TW200513266A (enrdf_load_stackoverflow)
WO (1) WO2005039516A1 (enrdf_load_stackoverflow)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007102125A3 (en) * 2006-03-06 2008-01-03 Procter & Gamble Lipophilic personal care composition
JP2008048989A (ja) * 2006-08-25 2008-03-06 Key Tranding Co Ltd メークアップ化粧料の処方管理システム
JP2008247831A (ja) * 2007-03-30 2008-10-16 Kose Corp 油性化粧料
FR2968979A1 (fr) * 2010-12-21 2012-06-22 Oreal Composition cosmetique sous forme de produit coule
JP2012152598A (ja) * 2012-04-23 2012-08-16 Key Tranding Co Ltd メークアップ化粧料の処方管理システム
JP5255749B2 (ja) * 2003-09-05 2013-08-07 阪本薬品工業株式会社 化粧品用抱水性油性原料及び化粧品
JP2014162788A (ja) * 2013-02-28 2014-09-08 Milbon Co Ltd 整髪料
JP2015193607A (ja) * 2014-03-28 2015-11-05 株式会社コーセー 油性固形化粧料
JP2018012647A (ja) * 2016-07-19 2018-01-25 ホーユー株式会社 油性整髪料組成物
JP2018168128A (ja) * 2017-03-30 2018-11-01 株式会社コーセー 口唇化粧料
WO2020039917A1 (ja) * 2018-08-18 2020-02-27 ジェイオーコスメティックス株式会社 油性固形化粧料
JP2020186179A (ja) * 2019-05-10 2020-11-19 東色ピグメント株式会社 スティック状油性固型化粧料
WO2022264968A1 (ja) * 2021-06-14 2022-12-22 株式会社コーセー 油性化粧料

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JP6918489B2 (ja) * 2015-12-29 2021-08-11 株式会社コーセー スティック状油性固形化粧料
CN106137795B (zh) * 2016-08-15 2020-04-17 广州澳希亚实业有限公司 一种抑制润唇膏出汗及兼顾修复唇部损伤的组合物
KR102610442B1 (ko) * 2016-09-30 2023-12-06 (주)아모레퍼시픽 입술 화장료 조성물
TW201836586A (zh) * 2017-03-30 2018-10-16 日商高級醇工業股份有限公司 固體預混合化妝材料

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JPH09176088A (ja) * 1995-12-25 1997-07-08 Pola Chem Ind Inc ポリグリセリンヘテロポリ脂肪酸エステル及びそれを含有する組成物
JPH101413A (ja) * 1996-06-11 1998-01-06 Noevir Co Ltd 化粧料
JP2002053420A (ja) * 2000-08-10 2002-02-19 Naris Cosmetics Co Ltd 油性固形化粧料
JP2004026771A (ja) * 2002-06-28 2004-01-29 Sakamoto Yakuhin Kogyo Co Ltd エステル化生成物及びこれを含有する化粧料
JP2004137214A (ja) * 2002-10-18 2004-05-13 Noevir Co Ltd 口唇用化粧料

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Publication number Priority date Publication date Assignee Title
JPS5872510A (ja) * 1981-10-23 1983-04-30 Nippon Saafuakutanto Kogyo Kk 化粧料
JPH09176088A (ja) * 1995-12-25 1997-07-08 Pola Chem Ind Inc ポリグリセリンヘテロポリ脂肪酸エステル及びそれを含有する組成物
JPH101413A (ja) * 1996-06-11 1998-01-06 Noevir Co Ltd 化粧料
JP2002053420A (ja) * 2000-08-10 2002-02-19 Naris Cosmetics Co Ltd 油性固形化粧料
JP2004026771A (ja) * 2002-06-28 2004-01-29 Sakamoto Yakuhin Kogyo Co Ltd エステル化生成物及びこれを含有する化粧料
JP2004137214A (ja) * 2002-10-18 2004-05-13 Noevir Co Ltd 口唇用化粧料

Cited By (15)

* Cited by examiner, † Cited by third party
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JP5255749B2 (ja) * 2003-09-05 2013-08-07 阪本薬品工業株式会社 化粧品用抱水性油性原料及び化粧品
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HK1095284A1 (zh) 2007-05-04
TW200513266A (en) 2005-04-16
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TWI334789B (enrdf_load_stackoverflow) 2010-12-21

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