WO2004076601A1 - 金属加工用水溶性潤滑剤、その使用に適した金属加工方法及び金属加工装置 - Google Patents

金属加工用水溶性潤滑剤、その使用に適した金属加工方法及び金属加工装置 Download PDF

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Publication number
WO2004076601A1
WO2004076601A1 PCT/JP2003/017004 JP0317004W WO2004076601A1 WO 2004076601 A1 WO2004076601 A1 WO 2004076601A1 JP 0317004 W JP0317004 W JP 0317004W WO 2004076601 A1 WO2004076601 A1 WO 2004076601A1
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Prior art keywords
water
metal
working
soluble lubricant
metal working
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PCT/JP2003/017004
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English (en)
French (fr)
Japanese (ja)
Inventor
Keiichi Murata
Atsushi Murakami
Hideo Kanamori
Masato Kaneko
Tahei Okada
Original Assignee
Matsushita Electric Industrial Co., Ltd.
Idemitsu Kosan Co., Ltd.
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Application filed by Matsushita Electric Industrial Co., Ltd., Idemitsu Kosan Co., Ltd. filed Critical Matsushita Electric Industrial Co., Ltd.
Priority to JP2004568784A priority Critical patent/JP4790272B2/ja
Priority to KR1020057012011A priority patent/KR101096993B1/ko
Publication of WO2004076601A1 publication Critical patent/WO2004076601A1/ja

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D22/00Shaping without cutting, by stamping, spinning, or deep-drawing
    • B21D22/02Stamping using rigid devices or tools
    • B21D22/04Stamping using rigid devices or tools for dimpling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21JFORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
    • B21J3/00Lubricating during forging or pressing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23QDETAILS, COMPONENTS, OR ACCESSORIES FOR MACHINE TOOLS, e.g. ARRANGEMENTS FOR COPYING OR CONTROLLING; MACHINE TOOLS IN GENERAL CHARACTERISED BY THE CONSTRUCTION OF PARTICULAR DETAILS OR COMPONENTS; COMBINATIONS OR ASSOCIATIONS OF METAL-WORKING MACHINES, NOT DIRECTED TO A PARTICULAR RESULT
    • B23Q11/00Accessories fitted to machine tools for keeping tools or parts of the machine in good working condition or for cooling work; Safety devices specially combined with or arranged in, or specially adapted for use in connection with, machine tools
    • B23Q11/10Arrangements for cooling or lubricating tools or work
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/16Ethers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/221Six-membered rings containing nitrogen and carbon only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/02Groups 1 or 11
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015Dispersions of solid lubricants
    • C10N2050/02Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating

Definitions

  • the present invention relates to a water-soluble lubricant for metal working, a metal working method and a metal working apparatus suitable for use thereof.
  • the water-soluble cutting oil a composition comprising an alkylene oxide block addition type nonionic surfactant, a carboxylate and water is known (Japanese Patent Application Laid-Open No. 2002-218258).
  • drying performance and processing performance were insufficient.
  • it is necessary to increase the amount of the carboxylic acid salt to be added but this will not only deteriorate the drying property, but also makes it susceptible to putrefaction.
  • the amount of the nonionic surfactant must be increased, and the drying property is further deteriorated.
  • the addition amount is reduced, the processing performance deteriorates, so it was necessary to satisfy the trade-offs.
  • Japanese Patent Application Laid-Open No. 54-91832 discloses a method for manufacturing an inner flame cylinder and an outer flame cylinder of an oil combustor.
  • a method is disclosed in which a stainless steel plate wound in a roll shape is processed while being pulled out, and is annealed and degreased in a conveyor-type continuous drying furnace.
  • a method of manufacturing an aluminum fin with a lubricating film for a heat exchanger using a continuous conveyor processing apparatus including a processing, cutting, and drying furnace process will be described with reference to FIG.
  • the thin metal plate 101 wound into a roll is pulled out from the end and immersed in an oil path 103 containing a conventionally used oil-based lubricant 102.
  • Lubricant 102 is applied.
  • the oil-based lubricant 102 is supplied from a tank 104 that stores the oil-based lubricant 105 to an oil path 103 via a supply amount control valve 106.
  • the press die 1 07 is provided with a female die 107 a to 107 d for processing, and the press punch 108 is a female die 1 08 for processing. a to 108 d are provided.
  • the thin metal plate is pressed by a pressing die 107 and a pressing punch 108, and then the cutting cutters 109 a and 109 provided on the cutting dies 109 and 110 are formed. It is cut by 10a.
  • the drying oven 1 1 1 is for drying the lubricant applied to the thin metal plate, and is generated by a relatively large-capacity heating means 1 1 2 consisting of a heating flame or heater, and a heating means 1 1 2 It has a blower 113 that applies the heated hot air 113a to a thin metal plate.
  • the present invention has been made in view of the above circumstances, and has excellent processing performance and drying properties, and has a very low environmental load.
  • a water-soluble lubricant for metal processing, and a metal processing method and a metal processing apparatus suitable for its use The purpose is to provide. Disclosure of the invention
  • the gist of the present invention is as follows.
  • a water-soluble lubricant for metal working comprising: 0.01% by mass or more and less than 5% by mass of a salt; (B) 0.05 to 20% by mass of a nonionic surfactant; and water.
  • the metal salt of an organic carboxylic acid is an alkali metal salt or an alkaline earth metal 3.
  • the organic carboxylic acid in the organic carboxylic acid metal salt is one of a linear saturated fatty acid, a linear monoene unsaturated fatty acid and a dibasic acid having a total carbon number of 8 or more of carboxylic acid residues or 4.
  • a metal working method consisting essentially of a step of applying a water-soluble lubricant for metal working to at least one of the front and back of the thin metal sheet, and a step of pressing and Z or cutting the thin metal sheet.
  • the thin metal plate is an aluminum thin plate with a lubricating coating of a fin material for a heat exchanger.
  • Storage section for thin metal drive means for pulling out the thin metal plate, coating means for applying a water-soluble lubricant for metal working on at least one of the front and back of the thin metal plate, press working and / or cutting work
  • a metal working apparatus consisting essentially of working means, wherein the application means controls the supply amount of the water-soluble lubricant for metal working according to any one of the above 1 to 8 to apply the lubricant to a thin metal plate.
  • a metal working apparatus characterized by the above-mentioned.
  • FIG. 1 is a diagram showing a metal working apparatus of the present invention.
  • FIG. 2A is a cross-sectional view of a thin metal plate 1 in a processing step of the present invention
  • FIG. 2B is a detailed cross-sectional view of press working in the present invention
  • FIG. 3 is a perspective view of a thin metal plate that has been subjected to press working and cutting work.
  • FIG. 4 is a diagram showing a conventional metal working apparatus.
  • the water-soluble lubricant for metalworking of the present invention is: (A) weighed into a container having a bottom area of 50 cm 2 , held in a thermostat at 100 ° C, and evaporated until 80% by mass evaporates. Metal salt of organic carboxylic acid having a time of not more than 10 minutes 0.01% by mass to less than 5% by mass, (B) nonionic surfactant 0.05 to 20% by mass, and water Features.
  • the amount of water which is a main component of metal working water-soluble lubricant of the present invention (hereinafter, simply also this that a water-soluble lubricant.) Is a lubricant the basis of the total amount, preferably 8 0-9 9.9 mass 0 / 0 . More preferably 9 0-9 9.9 mass 0/0, It is more preferably from 95 to 99.9% by mass, particularly preferably from 97 to 99.9% by mass. If it is less than 80% by mass, the drying property is poor, and if it exceeds 99.9% by mass, the workability is poor.
  • a metal salt of an organic carboxylic acid which is a component (A) of a water-soluble lubricant, improves lubricity and can be used without any particular limitation.
  • Organic Power Examples of the organic carboxylic acid in the metal sulfonic acid salt include the following.
  • Linear saturated fatty acids such as nonanoic acid, lauric acid, palmitic acid, stearic acid, behenic acid, etc.
  • Branched saturated fatty acids such as 4-, 4-methyltetradecanoic acid, 2-ethylthiotradecanoic acid, 14-methylheptadecanoic acid, 5-methyloctadecanoic acid, 2-butyloctadecanoic acid, and (3) cis — 2- Nonenic acid, hydrproleic acid, 10-pentadecenoic acid, Linderic acid, 2-tridecenoic acid, 5-tetradecenoic acid, myristrenic acid, cis-6-hexadecenoic acid, trans-9-octadecenoic acid Oleic acid, cis-9-eicosenoic acid, trans-13-linear monoen
  • Polyunsaturated fatty acids (6) acetylenic acids such as taliphosphoric acid, stearolic acid, xymenic acid, (7) alicyclic fatty acids such as malparic acid, hydnocarpic acid, and gorlic acid; (8) savininic acid, jarrapinolic acid (9) linear saturated dibasic acids such as adipic acid, azelaic acid, and sebacic acid; and branched saturated dibasic acids such as 7-ethylhexadecane dicarboxylic acid.
  • acetylenic acids such as taliphosphoric acid, stearolic acid, xymenic acid
  • alicyclic fatty acids such as malparic acid, hydnocarpic acid, and gorlic acid
  • savininic acid, jarrapinolic acid 9 linear saturated dibasic acids such as adipic acid, azelaic acid, and sebacic acid; and
  • Acid dibasic acid examples thereof include polycarboxylic acids (excluding dibasic acids) such as trimellitic acid, pyromellitic acid, and 1,2,3,4-monobutanetetracarboxylic acid.
  • polycarboxylic acids such as trimellitic acid, pyromellitic acid, and 1,2,3,4-monobutanetetracarboxylic acid.
  • linear saturated fatty acids, linear monoene unsaturated fatty acids, and dibasic acids are preferred.
  • the carboxylic acid residue preferably has a total carbon number of 8 or more, more preferably 12 or more, and still more preferably 16 or more. More specifically, one or two or more of straight-chain saturated fatty acids having a total number of carbon atoms of carboxylic acid residues of 8 or more, straight-chain monoene unsaturated fatty acids, and dibasic acids are preferable. In particular, dibasic acids having a total carbon number of 16 or more of carboxylic acid residues are most preferred.
  • the metal of the organic carboxylic acid metal salt is preferably an alkali metal such as lithium, sodium and potassium, and an alkaline earth metal such as magnesium and calcium.
  • the metal organic carboxylate may be used alone or in combination of two or more.
  • the compounding amount of the organic carboxylic acid metal salt is from 0.01% by mass to less than 5% by mass based on the total amount of the lubricant. Preferably it is 0.01 to 3% by mass, more preferably 0.01 to 1.5% by mass. If the content is less than 0.01% by mass, the processability is poor, and if it is more than 5% by mass, the drying property is poor.
  • the water-soluble lubricant for metalworking of the present invention has good drying properties, weighs 1 g in a container having a bottom area of 50 cm 2 , holds it in a thermostat at 100 ° C, and evaporates 80% by mass. It takes less than 10 minutes. This factor is determined by various factors as described above.
  • the water-soluble lubricant of the present invention includes (B) a nonionic surfactant, (C) a decay inhibitor and (C) in order to improve liquid stability (solubilizing performance), rot resistance and corrosion resistance. D) A metal deactivator can be added.
  • the nonionic surfactant of the component (B) is not particularly limited.
  • 2-Echi / Rehexinole Retjjengri Cornole, Dipropylene Gli Cornole examples thereof include glycerin, diethyleneglycol hexenolate ether, and otataethyleneglycolnoerphenyl ether.
  • those having a total carbon number of 15 or less are preferable, those having a total carbon number of 12 or less are more preferable, and those having a total carbon number of 10 or less are further preferable.
  • ethylene glycol hexyl ether (total carbon number: 10) and dipropylene glycol (total carbon number: 6) are particularly preferred.
  • the compounding amount is 0.05 to 20% by mass, preferably 0.05 to 10% by mass, more preferably 0.05 to 5% by mass, particularly preferably 0.1 to 5% by mass, based on the total amount of the lubricant. 0 to 1% by mass. If the amount is less than 0.05% by mass, the effect of dispersing other additives is small, and if it exceeds 20% by mass, the effect is small for the amount, and it is economically disadvantageous and the drying property is deteriorated.
  • the putrefaction inhibitor of the component (C) there is no particular limitation on the putrefaction inhibitor of the component (C), and various ones can be used. Specifically, 2,4-dihydroxybenzoic acid anilide compound; mercaptoamide carboxylic acid or a salt thereof; thiazolidine compound such as dimethylthiazolidin, methylthiazolidine, thiazolidine; polyethyleneimine; 2-phosphonobutane 1-, 2-, 4-tricarboxylic acid or a salt thereof; 1-hydroxylcylidene-1,1-diphosphonic acid or a salt thereof; tri-n-butyl-1-n-hexadecyl-phosphonium, tri-tri-n-hexadecyl-phosphonium; n-Butyl-1-n-dodecyl-phosphonium, tetraxhydrohydroxymethyl-phosphonium or a salt thereof; N- (2-hydroxexetil) piperazine; hexahydro_1,
  • N- (2-hydroxyxethyl) pidazine and amines are particularly preferred.
  • One type of component may be used alone, or two or more types may be used in combination.
  • the compounding amount is 0.01 to 10% by mass, preferably 0.01 to 2% by mass, and more preferably 0.01 to 0.6% by mass, based on the total amount of the lubricant. If the amount is less than 0.01% by mass, the effect of rot resistance is small. If the amount exceeds 10% by mass, the effect is small for the amount, and it is economically disadvantageous, and the drying property is deteriorated.
  • the metal deactivator of the component (D) is used to prevent the metal from coming into contact with corrosive substances by adsorbing on the metal surface.
  • the metal deactivator that can be used is not particularly limited, but may be benzotriazole; potassium benzotriazole; 3-aminotriazole, 4-aminotriazole, 2,5-diaminotriazole, or 3-mercapto.
  • Triazole compounds such as triazole and 3-amino-5-triazole; thiazole compounds such as 2-mercaptothiazole and 2-aminothiazole; and imidazole compounds such as 2-mercaptoimidazole and 2-mercaptoimidazole. Can be mentioned. Of these, triazole compounds are particularly preferred.
  • the component (D) one type may be used alone, or two or more types may be used in combination.
  • the amount thereof, in lubricants total amount, 0.0 1-1 0% by weight, preferably 0.0 to 2 mass 0/0, more preferably 0.0 1 to 0.6 wt% . 0.01 mass. If it is less than / 0 , the effect of the protection is small, and if it exceeds 10% by mass, the effect is small for the amount and it is economically disadvantageous, and the drying property is also deteriorated.
  • water-soluble lubricant for metal working of the present invention various additives such as an antioxidant, an antifoaming agent, an antioxidant, a viscosity index improver, and the like, as long as the object of the present invention is not impaired,
  • a pour point depressant or the like can be appropriately contained alone or in combination of two or more.
  • the antioxidant for example, alkylated diphenylamine, Phenyl- ⁇ -naphthylamine, alkylated mono-naphthylamine, etc., amine-based, 2,6-di-t-butynole- ⁇ -phenylene, such as cresol-one, and sulfur-based, etc.
  • the antifoaming agent include dimethylpolysiloxane and fluoroether.
  • the antioxidant include carboxylic acid-based antioxidants, carboxylate ester-based antioxidants, and perchloric alkaline earth metal salts.
  • the total content of these optional additives is preferably 10% by mass or less, more preferably 5% by mass or less, based on the total amount of the lubricant.
  • the amount of the water-soluble lubricant to be applied is in the range of 3 cc to 12 cc for a thin metal plate having a lubricating film on the surface area of 1 square meter of the thin metal plate. In the case of a thin metal plate not provided on the surface, the range is preferably 3 cc to 35 cc.
  • the coating amount is less than 3 cc, the lubricity required for each process cannot be obtained, and the risk of cracking of the thin metal plate in press working increases.
  • the applied amount is larger than 12 cc or 35 cc, drying is not easy, and the equipment for the drying process may be large.
  • the dilution ratio for diluting the raw material of the water-soluble lubricant with water is in the range of 30 to 200 in the case of a thin metal plate having a lubricating coating on the surface. In the case of a metal plate, the range of 30 to 100 is preferable.
  • the dilution ratio is less than 30, a high-concentration water-soluble lubricant will be used, and it will not be easily dried, which may require a large-scale equipment for the drying process. If the dilution ratio is more than 100 or 200, The lubricity required for working cannot be obtained, and the possibility of cracking of the thin metal plate during press working increases.
  • the amount and concentration of the water-soluble lubricant, and the water-soluble lubricant applied to the thin metal plate depends on the type of the thin metal plate, the presence or absence of a surface lubricating film, the hardness, and the thickness. Therefore, it is preferable to select an optimal amount or concentration of lubricating oil, whereby good lubricating performance can be exhibited without using a wasteful water-soluble lubricant, and costs can be reduced.
  • FIG. 1 is a view showing a metal working apparatus of the present invention. In this apparatus, each of the steps of press working, cutting work, and drying proceeds from left to right in FIG.
  • the thin metal plate 1 wound into a roll is drawn out by an arbitrary method and introduced into the coating chamber 2.
  • the water-soluble lubricant preparation machine 8 mixes a raw material of the water-soluble lubricant and tap water to prepare a water-soluble lubricant 9 at an arbitrary concentration and temporarily stores the same.
  • the water-soluble lubricant 9 is supplied into the coating chamber 2 via a control valve 10 for controlling the spray amount.
  • the process of diluting the water-soluble lubricant raw material with water is performed on or near the same site as the pressing and cutting process of the thin metal plate. Can be handled as raw materials, and the weight, volume, and inventory of lubricants managed during the distribution and storage stages can be reduced, and costs can be reduced. In addition, by performing the dilution process immediately before the pressing and cutting processes, the processing of bubbles generated and grown by dilution is achieved. The labor can be reduced.
  • a mist-like water-soluble lubricant 4 is jetted from a spray nozzle 3, and the inside of the coating chamber 2 is filled with an atmosphere of the mist-like water-soluble lubricant 4. Then, when the thin metal plate 1 is introduced into the atmosphere of the mist-like lubricant 4, the mist-like water-soluble lubricant 4 is formed on the surface of the thin metal plate 1 with the lubricating coating layer remaining. Attached and applied evenly. At this time, the spray nozzle 3 is installed so as to spray with the back facing the thin metal plate 1 passing through the inside of the coating chamber 2. This is because the water-soluble lubricant 4 is sprayed directly on the thin metal plate 1 to prevent the water-soluble lubricating coating layer (not shown) on the surface of the thin metal plate 1 from melting and peeling off. .
  • the surface of the thin metal plate is evenly lubricated with a minimum amount of the water-soluble lubricant. The cost of the water-soluble lubricant can be reduced.
  • the excess water-soluble lubricant 4 a provided in the coating chamber 2 is temporarily stored in a lubricant reservoir 5, and when a predetermined amount is accumulated, is applied through a drain pipe 7 provided with a discharge control pulp 6. Exhausted from room 2.
  • the press die 11 has a female die 11 a to 11 d for processing
  • the punch 12 has a female die 12 a to 12 d for processing. Is provided.
  • the thin metal plate is pressed by a press die 11 and a press punch 12. In the press working, the thin metal plate advances by one row of the female mold 11 a-lid or os mold 12 a-l 2 d each time the press machine performs one press operation, and the total After four small steps, the pressing process is completed.
  • the water-soluble lubricant shower 13 sprays and applies the water-soluble lubricant 14 to a thin metal plate in the form of droplets.
  • Water-soluble lubricant 1 4 is water-soluble lubricant preparation It is supplied from the machine 8 through the shower volume control pulp 15.
  • the water-soluble lubricant 14 sprayed from the lubricant shower 13 is applied directly to the surface of the thin metal plate after the pressing process.
  • the reason that the water-soluble lubricant 14 is directly applied to the surface of the thin metal plate is that the necessity of providing a lubricating coating layer on the surface of the thin metal plate is lower in cutting than in pressing. This is because equipment such as the coating chamber 2 for creating an atmosphere of a mist-like water-soluble lubricant is not required.
  • the excess water-soluble lubricant 14 a is temporarily stored in a lubricant reservoir 16, and is discharged through a drain pipe 7 provided with a discharge control valve 6 when a predetermined amount is accumulated.
  • the application of the water-soluble lubricant is performed immediately before the press working, as a pre-process of the cutting work, or at the same time as the above-mentioned processing, and the minimum amount of the water-soluble lubricant is applied at the optimum time. Can be added without drying, and the cost of the water-soluble lubricant can be reduced.
  • the cutting dies 17 and 18 are provided with cutting cutters 17a and 18a, respectively, and the thin metal plate is cut by the cutting cutters 17a and 18a.
  • the air blower 19 for the air blower blows through the nozzle 20 to dry the water-soluble lubricants 4 and 14 on the surface of the pressed and cut thin metal plate.
  • the drying may be performed at a temperature slightly higher than the ambient temperature by using a small-capacity heat source or the like as necessary.
  • water-soluble lubricants can be dried by natural drying, if air-drying of the thin metal plate after pressing and cutting is possible, air blow No equipment is needed for the drying process using a blower 19 or the like. However, an existing drying oven or a drying oven with a large capacity heat source may be used to greatly reduce the drying time. .
  • FIG. 2 (a) is a cross-sectional view of the thin metal plate 1 in the process of processing the thin metal plate 1 by the above-mentioned female dies 11a to 1d and the dies 12a to 12d for press working. is there.
  • a thin metal plate 1 is formed into a spherical shape by forming, step I, a hole 1a is formed by piercing, and a collar lb is provided.Step II, and the collar 1b is extended by eye ing III, The end portion lc of the collar 1b is wrapped around the outside by a flaring process in the order of steps IV to IV.
  • the load on the working tool is large, especially the stress applied to the point A shown in Fig. 2 (b) is the largest.
  • the press die 11 and the punch 12 as tools may be damaged. Therefore, it is important to optimize lubrication during the above series of press working.
  • Water-soluble lubricant 4 is applied by mist spraying to improve lubricity, and after lubrication before cutting, water-soluble The emphasis is on applying the agent 14 to remove foreign matter such as cutting powder.
  • the pressing tool is preferably made of a cemented carbide containing at least cobalt or nickel as a binder (binding phase metal), and the water-soluble lubricant elutes binder (bonding phase metal) from the pressing tool. It is preferred that the inhibitor that inhibits the dissolution is dissolved.
  • FIG. 3 is a perspective view of the thin metal plate after the pressing step and the cutting step.
  • 1a is the hole pierced
  • lb is the eye.
  • lc is the end of collar 1b that has been rolled out.
  • the mode of processing an aluminum plate has been described.
  • the present invention may be applied to a steel plate and a copper plate, and can be applied to any press or cutting of a metal having a thin thickness and requiring a water-soluble lubricant. Can be suitable.
  • the application of the water-soluble lubricant 4 before press working was performed in the form of a mist spray. Since there is no need to consider the dissolution of the layer, the water-soluble lubricant may be applied before pressing by a method of directly immersing the thin metal plate in the water-soluble lubricant or a method of spraying directly in the form of a spray. .
  • the water-soluble lubricants 4 and 14 are applied immediately before the press working and immediately before the cutting work, but the material of the metal sheet, the working area, the complexity of the working, the presence or absence of the surface lubricating coating and the like.
  • the adjustment of the application amount and the concentration of the water-soluble lubricant can be arbitrarily set in each of the steps before, during, before, and during the cutting. By doing so, it is possible to maximize the lubricating effect according to each metal, and it is possible to manage the application of the minimum necessary water-soluble lubricant in each process, so that the lubricant Costs can be reduced.
  • the metal processing apparatus includes: a thin metal storage unit; a driving unit that pulls out the thin metal plate; an application unit that applies a water-soluble lubricant for metal processing to at least one of the front and back surfaces of the thin metal plate; Or a metal working apparatus essentially consisting of a processing means for performing a cutting process, wherein the application means controls a supply amount of the metal working water-soluble lubricant according to any one of claims 1 to 8,
  • This is a metal working apparatus characterized in that it is applied to a thin metal plate.
  • the apparatus of the present invention may be any apparatus that can be used for the metal working method described above.
  • the application means should be provided immediately before the processing means for pressing and / or cutting.Furthermore, depending on the purpose of drying at a temperature around room temperature or for a short time, drying at a high temperature of about 150 ° C. It may have a drying means using an oven.
  • the coefficient of friction was determined by the Bowden test.
  • Test material bare material (friction test 1) and K S175, pole: S U J 2 (3/16 inch) (friction test 2)
  • the degree of spoilage was determined from the number of viable bacteria after one week using an easy cult.
  • Bare material 20 ⁇ 50 was immersed in a sample of 30 cc, kept at 60 for 3 days, and observed for corrosion.
  • the water-soluble lubricant for metal working of the present invention is a water-soluble lubricant which has excellent processing performance and drying properties and has an extremely low environmental load, and is suitable as a water-based lubricant for the above-mentioned metal working method and metal working equipment.
  • Can be used for The environmental load is extremely low because of the water-soluble lubricant, and the waste lubricant can be treated without reusing the extra lubricant, so that the water-soluble lubricant can be used stably without changing the composition. There are various effects such as easy handling.
  • the water-soluble lubricant is applied to at least one of the front and back of the thin metal plate in the pressing or cutting of the thin metal plate.
  • the load can be reduced.
  • a water-soluble lubricant having excellent drying properties is used, the drying time can be reduced by appropriately using a drying means such as a blowing means in the drying step and the draining step.
  • the use of a water-soluble lubricant eliminates the possibility of ignition by a lubricating liquid, so that a drying device can be provided close to a press machine, and the line of the device can be shortened.
  • the water-soluble lubricant is sprayed in a mist form or in a spray form to form a thin metal plate.
  • the thin metal plate surface can be evenly lubricated with a minimum amount of water-soluble lubricant.
  • the present invention can be applied to the processing of an aluminum thin plate having a lubricating film of a fin material for a heat exchanger, so that a heat exchanger used for an air conditioner or the like can be efficiently manufactured.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Mounting, Exchange, And Manufacturing Of Dies (AREA)
  • Lubricants (AREA)
  • Shaping Metal By Deep-Drawing, Or The Like (AREA)
PCT/JP2003/017004 2002-12-26 2003-12-26 金属加工用水溶性潤滑剤、その使用に適した金属加工方法及び金属加工装置 WO2004076601A1 (ja)

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KR1020057012011A KR101096993B1 (ko) 2002-12-26 2003-12-26 금속 가공용 수용성 윤활제, 그 사용에 적합한 금속 가공방법 및 금속 가공 장치

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WO2006129457A1 (ja) * 2005-06-01 2006-12-07 Nihon Parkerizing Co., Ltd. 固体に対する水系潤滑皮膜処理剤
JP2009013356A (ja) * 2007-07-06 2009-01-22 Idemitsu Kosan Co Ltd 極微量給油式金属加工油組成物
WO2013059473A2 (en) 2011-10-19 2013-04-25 Bioformix Inc. Multifunctional monomers, methods for making multifunctional monomers, polymerizable compositions and products formed therefrom
US8782894B2 (en) 2008-10-10 2014-07-22 Magna Steyr Fahrzeugtechnik Ag & Co. Kg Method for producing and commissioning a transmission with a water-based lubricant, and such a lubricant
JP2015071750A (ja) * 2013-09-04 2015-04-16 三洋化成工業株式会社 金属加工品の製造方法
JP2015196705A (ja) * 2014-03-31 2015-11-09 地方独立行政法人山口県産業技術センター 潤滑剤とそれを用いた金属加工方法

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CN102477353A (zh) * 2010-11-23 2012-05-30 沈阳黎明航空发动机(集团)有限责任公司 一种水基金属加工冷却液及其制备工艺
CN102581184B (zh) * 2012-02-27 2014-10-22 上海明兴开城超音波科技有限公司 一种避免金属零件积炭的锻压前润滑工艺及其生产装置
CN103418657B (zh) * 2013-08-28 2015-09-16 北京科技大学 组合模具板金属连续冲压成形工艺及成形设备
JP6393839B2 (ja) * 2016-05-20 2018-09-19 手島精管株式会社 金属細管の製造方法
CN106312681B (zh) * 2016-09-14 2019-06-14 青岛理工大学 一种基于物理特性的多介质混合高速切削微量润滑雾化系统
CN115820320B (zh) * 2022-11-17 2023-12-22 滁州默尔新材料科技有限公司 一种防裂纹的光学镜头切割用保护液及其制备方法

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WO1995018202A1 (fr) * 1993-12-24 1995-07-06 Castrol Kabushiki Kaisha Lubrifiant utilise pour former des plaques en aluminium et en alliage d'aluminium et plaques en aluminium et en alliage d'aluminium ainsi formees
JPH10180391A (ja) * 1996-12-26 1998-07-07 Nippon Sangyo Kagaku Kenkyusho 穀物粉末を主成分とする懸濁液を用いた材料プレス成形法
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006129457A1 (ja) * 2005-06-01 2006-12-07 Nihon Parkerizing Co., Ltd. 固体に対する水系潤滑皮膜処理剤
JP2009013356A (ja) * 2007-07-06 2009-01-22 Idemitsu Kosan Co Ltd 極微量給油式金属加工油組成物
US8782894B2 (en) 2008-10-10 2014-07-22 Magna Steyr Fahrzeugtechnik Ag & Co. Kg Method for producing and commissioning a transmission with a water-based lubricant, and such a lubricant
WO2013059473A2 (en) 2011-10-19 2013-04-25 Bioformix Inc. Multifunctional monomers, methods for making multifunctional monomers, polymerizable compositions and products formed therefrom
JP2015071750A (ja) * 2013-09-04 2015-04-16 三洋化成工業株式会社 金属加工品の製造方法
JP2015196705A (ja) * 2014-03-31 2015-11-09 地方独立行政法人山口県産業技術センター 潤滑剤とそれを用いた金属加工方法

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KR20050089854A (ko) 2005-09-08
CN101812364B (zh) 2013-07-10
TW200422397A (en) 2004-11-01
CN100582207C (zh) 2010-01-20
CN101812364A (zh) 2010-08-25
JPWO2004076601A1 (ja) 2006-06-08
KR101096993B1 (ko) 2011-12-20
CN1729279A (zh) 2006-02-01
JP4790272B2 (ja) 2011-10-12

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