WO2004009879A1 - Plating device - Google Patents

Plating device Download PDF

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Publication number
WO2004009879A1
WO2004009879A1 PCT/JP2003/009144 JP0309144W WO2004009879A1 WO 2004009879 A1 WO2004009879 A1 WO 2004009879A1 JP 0309144 W JP0309144 W JP 0309144W WO 2004009879 A1 WO2004009879 A1 WO 2004009879A1
Authority
WO
WIPO (PCT)
Prior art keywords
plating
substrate
anode
plating solution
electric field
Prior art date
Application number
PCT/JP2003/009144
Other languages
French (fr)
Japanese (ja)
Inventor
Toshikazu Yajima
Takashi Takemura
Rei Kiumi
Nobutoshi Saito
Fumio Kuriyama
Masaaki Kimura
Original Assignee
Ebara Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ebara Corporation filed Critical Ebara Corporation
Priority to US10/485,350 priority Critical patent/US20040262150A1/en
Priority to JP2004522759A priority patent/JP4434948B2/en
Priority to EP03765327A priority patent/EP1524338A4/en
Publication of WO2004009879A1 publication Critical patent/WO2004009879A1/en
Priority to US12/453,347 priority patent/US20090218231A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/12Process control or regulation
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/001Apparatus specially adapted for electrolytic coating of wafers, e.g. semiconductors or solar cells
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/002Cell separation, e.g. membranes, diaphragms
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/008Current shielding devices
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/12Semiconductors
    • C25D7/123Semiconductors first coated with a seed layer or a conductive layer

Definitions

  • the present invention relates to a plating apparatus for plating a surface of a substrate such as a substrate, particularly a fine wiring groove or hole, a via hole, a through hole, a resist opening provided on a surface of a semiconductor wafer or the like.
  • the present invention relates to a plating device used for forming a plating film on a portion or forming a bump (protruding electrode) on a surface of a semiconductor wafer to be electrically connected to a package electrode or the like.
  • solder for example, in TAB (Tape Automated Bonding) or FC (Flip Chip), gold, copper, solder, or lead-free solder or nickel is applied to a predetermined location (electrode) on the surface of a semiconductor chip on which wiring is formed. It is widely used to form protruding connection electrodes (bumps) by laminating them in multiple layers, and to electrically connect to the package electrodes and TAB electrodes via these bumps. There are various methods for forming the bumps, such as an electroplating method, a vapor deposition method, a printing method, and a ball bump method, but with the increase in the number of IZOs and the finer pitch of semiconductor chips, miniaturization is possible. The electroplating method, whose performance is relatively stable, has been increasingly used.
  • a high-purity metal film (plating film) can be easily obtained, and not only is the deposition rate of the metal film relatively high, but also the thickness of the metal film is relatively easily controlled. It can be carried out.
  • FIG. 37 shows an example of a conventional plating apparatus employing a so-called face-down method.
  • the plating apparatus includes an open plating tank 12 for holding a plating solution 10 therein, and an upper and lower side for detachably holding a substrate W with its surface (covered surface) facing down (face down). It has a movable substrate holder 14.
  • Plating tank 1 2 An anode 16 is disposed horizontally at the bottom, an overflow tank 18 is provided around the top, and a plating solution supply nozzle 20 is connected to the bottom of the plating tank 12.
  • the substrate W held horizontally by the substrate holder 14 is placed at a position to close the opening at the upper end of the plating tank 12, and in this state, the plating solution is supplied from the plating solution supply nozzle 20 to the inside of the plating tank 12.
  • the plating liquid 10 is supplied, and the plating liquid 10 overflows from the top of the plating tank 12 so that the plating liquid 10 comes into contact with the surface of the substrate W held by the substrate holder 14.
  • the anode 16 is connected to the anode of the power supply 24 via the conductor 22a, and the substrate W is connected to the cathode of the power supply 24 via the conductor 22b.
  • metal ions in the plating solution 10 receive electrons from the surface of the substrate W, and the metal is deposited on the surface of the substrate W to form a metal film.
  • the size of the anode 16, the distance between the anode 16 and the substrate W and the potential difference, the supply speed of the plating solution 10 supplied from the plating solution supply nozzle 2, and the like are adjusted. By doing so, the uniformity of the thickness of the metal film formed on the surface of the substrate W can be adjusted to some extent.
  • FIG. 38 shows an example of a conventional plating apparatus employing a so-called dip method.
  • This plating apparatus is composed of a plating tank 12a for holding the plating solution inside, and a substrate W that is sealed in a water-tight manner at its peripheral edge to expose the surface (covered surface) and to be detachably held. It has a flexible substrate holder 14a. Inside the plating tank 12, the anode 16 a is held vertically by the anode holder 26, and the substrate W held by the substrate holder 14 a is arranged at a position facing the anode 16 a. At this time, an adjustment plate (regulation plate) 28 made of a dielectric material having a central hole 28a is arranged between the anode 16a and the substrate W.
  • an adjustment plate (regulation plate) 28 made of a dielectric material having a central hole 28a is arranged between the anode 16a and the substrate W.
  • the anode 16, the substrate W and the adjustment plate 28 are immersed in the plating solution in the plating tank 12 a, and at the same time, the anode 16 a is plated through the conductor 22 a. Attach the substrate W to the anode of the power supply 4 and the cathode of the power supply 2 4 By the connection, the metal is deposited on the surface of the substrate W to form a metal film in the same manner as described above.
  • an adjustment plate 28 having a central hole 28a is arranged between the anode 16a and the substrate W arranged at a position facing the anode 16a.
  • the thickness distribution of the metal film formed on the surface of the substrate W can be adjusted to some extent by adjusting the potential distribution in the plating tank 12 a with the plate 28.
  • FIG. 39 shows another example of a conventional plating apparatus employing a so-called dip method.
  • the difference of this plating device from that shown in Fig. 38 is that a ring-shaped pseudo cathode (pseudo electrode) 30 is provided without an adjustment plate, and the pseudo cathode 30 is arranged around the substrate W.
  • the substrate W is held in the substrate holder 14a, and further, during the plating process, the pseudo cathode 30 is connected to the cathode of the power supply 24 via the conductor 22c.
  • There are.
  • the uniformity of the thickness of the metal film formed on the surface of the substrate W can be improved by adjusting the potential of the pseudo cathode 30.
  • the potential distribution is improved by an adjustment plate with a central hole in the center, although the uniformity of the film thickness distribution of the metal film over the entire surface can be improved to some extent, as shown in FIG. 40C, the film thickness of the metal film P becomes thicker and wavy at the central portion and the peripheral portion of the substrate W. There is a tendency that a metal film P having an appropriate film thickness distribution is formed. Furthermore, when plating is performed with the plating apparatus shown in Fig. 39, not only is it difficult to adjust the voltage of the pseudo electrode (pseudo cathode), but it is also necessary to remove the metal film attached to the surface of the pseudo electrode. This operation becomes quite complicated.
  • the surface potential distribution formed on the substrate surface tends to increase the film thickness at the periphery of the substrate, which is the power receiving portion, and the film pressure distribution on the substrate surface tends to be U-shaped (see FIG. 4).
  • this is one of the major factors that impair the film thickness uniformity.
  • adjustment plates are used to adjust the supply of metal ions to the substrate surface, that is, to adjust the flow of the plating solution, and to control and adjust the potential distribution on the substrate surface and the electric field in the plating tank. Or a method using a pseudo electrode.
  • Adjustment of the plating solution flow and adjustment by the adjustment plate is performed by collecting metal ions and electric fields at the center of the substrate and raising the plating film at the center of the substrate, thereby forming the film thickness of the plating film over the entire surface of the substrate.
  • This method adjusts the distribution to a W-shape to minimize film thickness fluctuations from the average film thickness (see Fig. 40C). Therefore, the adjustment of the plating solution flow and the position of the adjustment plate-the selection of the center hole size and the fine adjustment have a very important effect on the film thickness uniformity, and the film thickness uniformity is adjusted (tuned). It depends very much on the condition.
  • the potential distribution only on the substrate surface is originally spread to the area including the pseudo electrode on the outer periphery of the substrate, and the rise in the thickness of the power receiving portion is brought close to the pseudo electrode to make the potential distribution extremely uniform on the substrate surface.
  • the film thickness is obtained.
  • a method equivalent to the method using the pseudo electrode there is a method in which a pattern near the periphery of the substrate is used as a "disposal chip" to serve as a pseudo electrode.
  • the voltage adjustment affects the film thickness uniformity, and the operation becomes complicated because it is necessary to periodically remove the metal film (plating film) attached to the pseudo electrode.
  • the pattern near the peripheral edge in the substrate is used as a dummy electrode so as to serve as a pseudo electrode, the number of effective chips per substrate decreases, which leads to a decrease in productivity.
  • the above methods of deviation and deviation also result in adjusting the film thickness distribution to obtain a uniform film thickness distribution. Therefore, by positively controlling and adjusting the electric field in the plating tank formed between the anode and the plating object, which is a power source, the potential distribution on the surface of the plating object is controlled and improved. Therefore, the present invention does not cancel and improve the film thickness distribution of the plating film, which tends to be essentially U-shaped. Disclosure of the invention
  • the present invention has been made in view of the above circumstances, and has a relatively simple device configuration, and does not require complicated operation methods and settings, and is more uniform over the entire covering body.
  • An object is to provide a plating apparatus capable of forming a metal film (plating film) having a thickness.
  • a plating apparatus of the present invention comprises: a plating tank for holding a plating solution; an anode immersed in the plating solution in the plating tank; and an anode and the anode.
  • An adjusting plate provided between the cladding bodies arranged to face each other, and a plating power supply for energizing and plating between the anode and the cladding body; Is provided so as to block the plating liquid held in the plating tank between the anode side and the covering body side, and is provided with a through-hole group including a large number of through-holes therein.
  • the electric field leaks through a large number of through holes provided inside the adjusting plate installed in the plating tank, and the leaked electric field is spread evenly, so that the electric potential distribution over the entire surface of the covering body is reduced.
  • the in-plane uniformity of the metal film formed on the covering body can be further improved.
  • the plating solution is affected by the flow of the plating solution. Nonuniformity in the thickness of the metal film formed on the substrate can be prevented.
  • the through-hole group includes a plurality of elongated holes that extend linearly or arcuately in one direction in a slit shape.
  • the width of the long hole is, for example, 0.5 to 20 mm, preferably about 1 to 15 mm, and the length is determined by the shape of the covering body.
  • the through-hole group includes a plurality of cross holes extending in a cross shape in the vertical and horizontal directions.
  • the through-hole group is characterized by being composed of an arbitrary combination of a plurality of pores, a plurality of holes having different diameters, or a slit-shaped elongated hole.
  • productivity can be improved by forming a through-hole group with a combination of a plurality of pores or a plurality of holes having different diameters.
  • the diameter of the pores and further the small holes is, for example, 1 to 2 Omm, preferably about 2 to 10 mm
  • the diameter of the large holes (center hole) is, for example, It is 50 to 300111111, preferably about 30 to 10 Omm.
  • the through-hole group is formed in a region substantially similar to the plated body over substantially the entire region of the adjustment plate facing the adhered body.
  • a stirring mechanism is provided between the to-be-coated body and the adjusting plate to stir the holding liquid held in the toning tank.
  • the stirring mechanism is preferably a paddle-type stirring mechanism having a paddle that reciprocates in parallel with the covering body.
  • the plating solution is agitated with a paddle that reciprocates in parallel with the object to be covered, so that sufficient force is applied to the plating solution, such as force S, which prevents the flow of the plating solution from becoming directional. It can be uniformly supplied to the attached body.
  • the anode and the adjustment plate are arranged in a vertical direction. It is characterized by being installed in. As a result, an installation device having a small installation area and excellent maintainability can be provided.
  • Another plating apparatus of the present invention includes a plating tank for holding a plating solution, an anode installed by being immersed in a plating solution in the plating tank, and disposed so as to face the anode and the anode.
  • An adjusting plate installed between the anode and the body to be plated; and a plating power source for performing plating by energizing between the anode and the body to be adhered.
  • the plating solution is installed so as to block the plating solution held therein between the anode side and the covering body side, and is provided with a plating solution flow path through which the plating solution flows while uniformly passing the electric field.
  • the mounting device is characterized in that:
  • the length of the plating solution flow path is appropriately set depending on the shape of the plating tank, the distance between the anode and the covering object, etc., but is generally 10 to 9 Omm, preferably 20 to 7 Omm. It is set to 5 mm, more preferably 30 to 60 mm.
  • the plating liquid flow path is formed on the inner peripheral surface of a cylindrical body or a rectangular block.
  • the structure can be simplified.
  • a plurality of through-holes having a size to prevent electric field leakage are provided in the peripheral wall of the cylindrical body. This prevents the electric field from leaking and allows the plating solution to flow through the through-holes formed in the peripheral wall of the cylindrical body, thereby causing a bias in the concentration of the plating solution inside and outside the cylindrical body. Can be prevented.
  • Examples of the shape of the through hole include a long hole of a pore-slit shape, a cross hole extending vertically and horizontally, and a combination thereof.
  • the plating tank has a stirring mechanism for stirring the pouring liquid.
  • the plating solution is agitated during the plating process so that the concentration of the plating solution containing various metal ions and various additives in the plating bath becomes uniform in the plating bath, and the plating solution has a uniform concentration.
  • the stirring mechanism is preferably a paddle-type stirring mechanism having a paddle that reciprocates in parallel with the covering body.
  • the stirring mechanism may be a plating solution spraying type stirring mechanism having a plurality of plating solution spray nozzles for spraying a plating solution toward a direction of the body to be covered.
  • the plating solution in the plating tank is agitated to make the concentration of the plating solution uniform and, at the same time, the plating on the body to be plated.
  • the plating liquid flow path may be provided inside the adjustment plate integrally with the adjustment plate.
  • a thick plate may be used as the adjusting plate, and a through hole may be provided inside the adjusting plate so that the through hole serves as a liquid flow path.
  • Still another plating apparatus of the present invention includes: a plating tank that holds a plating solution; an anode that is installed by being immersed in a plating solution in the plating tank; and an anode that is disposed to face the anode.
  • a plating solution held in the plating tank is installed between the anode body and the body to be adhered between the anode body and the body to be adhered.
  • An adjusting plate provided with a plating solution flow path to be circulated; a plating power supply for conducting plating between the anode and the body to be plated; and an end of the plating solution flow path on the side of the body to be plated.
  • an electric field adjusting ring for adjusting an electric field at an outer peripheral portion of the object to be plated.
  • the electric field formed between the anode and the cladding body can be more uniformly spread over the entire surface of the cladding body.
  • the shape of the electric field adjustment ring is appropriately set depending on the plating tank, the shape of the body to be covered, the distance between the anode and the body to be covered, etc., and the width is generally 1 to 2 O mm, Preferably, it is set to 3 to 17 mm, more preferably to 5 to 15 mm.
  • the gap between the electric field adjusting ring and the covering body is generally set to 0.5 to 30 mm, preferably 1 to 15 mm, and more preferably 1.5 to 6 mm.
  • the plating liquid flow path is formed on an inner peripheral surface of a tubular body, and the electric field adjusting ring is connected to a covered body side end of the tubular body. ing.
  • the plating liquid flow path is formed on an inner peripheral surface of the cylindrical body, and the electric field adjusting ring is arranged separately from the cylindrical body at an end of the cylindrical body to be adhered to the body. You can.
  • the tubular body and the electric field adjusting ring are separated from each other, so that the range of options can be expanded.
  • the plating liquid flow path may be formed on an inner peripheral surface of a tubular body, and the electric field adjusting ring may be formed on an end face of the tubular body facing the covered body. Thereby, the number of parts can be reduced.
  • FIG. 1 is an overall layout diagram of a plating apparatus equipped with a plating apparatus according to an embodiment of the present invention.
  • FIG. 2 is a schematic diagram of a transport robot provided in a plating space of the plating apparatus shown in FIG.
  • FIG. 3 is a schematic sectional view of a plating apparatus provided in the plating apparatus shown in FIG.
  • FIG. 4 is a schematic perspective view of a main part of the plating apparatus shown in FIG.
  • FIG. 5 is a plan view of an adjustment plate provided in the plating apparatus shown in FIG.
  • FIG. 6 is a diagram schematically showing a state of a metal film when a metal film (plating film) is formed by the plating apparatus shown in FIG.
  • FIG. 7A to 7E show a process of forming bumps (protruding electrodes) on a substrate in the order of steps. It is sectional drawing shown in FIG.
  • FIG. 8 is a plan view showing another example of the adjustment plate.
  • FIG. 9 is a plan view showing still another example of the adjustment plate.
  • FIG. 10 is a plan view showing still another example of the adjustment plate.
  • FIG. 11 is a plan view showing still another example of the adjustment plate.
  • FIG. 12 is a plan view showing still another example of the adjustment plate.
  • FIG. 13 is a plan view showing still another example of the adjustment plate.
  • FIG. 14 is a plan view showing still another example of the adjustment plate.
  • FIG. 15 is a plan view showing still another example of the adjustment plate.
  • FIG. 16 is a plan view showing still another example of the adjustment plate.
  • FIG. 17 is a plan view showing still another example of the adjustment plate.
  • FIG. 18 is a plan view showing still another example of the adjustment plate.
  • FIG. 19 is a plan view showing still another example of the adjustment plate.
  • FIG. 20 is a schematic sectional view showing a plating apparatus according to another embodiment of the present invention.
  • FIG. 21A is a perspective view showing an adjustment plate and a cylindrical body provided in the plating apparatus shown in FIG.
  • FIG. 21B is a front view of FIG. 21A.
  • FIG. 22 is a diagram schematically showing a state of the metal film when a metal film (plating film) is formed by the plating apparatus shown in FIG.
  • FIG. 23 is a schematic sectional view showing a plating apparatus according to still another embodiment of the present invention.
  • FIG. 24A is a perspective view showing still another example of the adjusting plate and the cylindrical body.
  • FIG. 24B is a front view of FIG. 24A.
  • FIG. 25A is a perspective view showing another example of the adjusting plate and the cylindrical body.
  • FIG. 25B is a front view of FIG. 25A.
  • FIG. 26A is a perspective view showing still another example of the adjusting plate and the cylindrical body.
  • FIG. 26B is a front view of FIG. 26A.
  • FIG. 27A is a perspective view showing still another example of the adjusting plate and the cylindrical body.
  • FIG. 27B is a front view of FIG. 27A.
  • FIG. 28 is a schematic sectional view showing a plating apparatus according to still another embodiment of the present invention.
  • FIG. 29A is a perspective view showing an adjustment plate, a cylindrical body, and an electric field adjustment ring provided in the plating apparatus shown in FIG.
  • FIG. 29B is a front view of FIG. 29A.
  • FIG. 30 is a diagram schematically showing a state of the metal film when a metal film (plating film) is formed by the plating apparatus shown in FIG.
  • FIG. 31 is a schematic sectional view showing a plating apparatus according to still another embodiment of the present invention.
  • FIG. 32A is a perspective view showing another example of the adjusting plate, the cylindrical body, and the electric field adjusting ring.
  • FIG. 32B is a front view of FIG. 32A.
  • FIG. 33A is a perspective view showing still another example of the adjusting plate, the cylindrical body, and the electric field adjusting ring.
  • FIG. 33B is a front view of FIG. 33A.
  • FIG. 34A is a perspective view showing still another example of the adjusting plate, the cylindrical body, and the electric field adjusting ring.
  • FIG. 34B is a front view of FIG. 34A.
  • FIG. 35A is a perspective view showing still another example of the adjusting plate, the cylindrical body, and the electric field adjusting ring.
  • FIG. 35B is a front view of FIG. 35A.
  • FIG. 36 is a schematic sectional view showing a plating apparatus according to still another embodiment of the present invention.
  • FIG. 37 is a schematic sectional view showing an example of a conventional plating apparatus.
  • FIG. 38 is a schematic perspective view showing another example of the conventional plating apparatus.
  • FIG. 39 is a schematic perspective view showing still another example of the conventional plating apparatus.
  • FIGS. 4OA to 40C are diagrams schematically showing different states of a metal film (plated film) formed by a conventional plating apparatus.
  • FIG. 1 is an overall layout diagram of a plating apparatus equipped with a plating apparatus according to an embodiment of the present invention.
  • This plating treatment equipment automatically and continuously performs all the plating processes of the pre-treatment of the substrate, the plating treatment and the post-treatment of the plating, and the inside of the equipment frame 110 with the exterior panel attached.
  • a substrate attaching / detaching table 162 as a substrate transfer section for attaching / detaching the substrate to / from each substrate holder 160 is provided.
  • a load / unload port 120 for mounting a substrate cassette containing substrates is connected to the clean space 114, and an operation panel 122 is provided for the device frame 110. ing.
  • an aligner 122 that aligns the orientation of the board, such as the orientation flat and the notch, in a predetermined direction, and a board that cleans the plated board and spins it by rotating it at a high speed.
  • Apparatus 124 and pretreatment of the substrate in this example, by spraying pure water on the surface of the substrate (the surface to be covered), the substrate surface is washed with pure water and wetted with pure water.
  • each of these processing units that is, the aligner 122, the cleaning / drying unit 124, and the pre-processing unit 126 is located substantially at the center, and each of these processing units 122, 124, 1 26, a first transfer robot 128 for transferring and transferring a substrate between the substrate loading / unloading port 120 and the substrate cassette mounted on the load / unload port 120 is provided.
  • the aligner 1 2 2, the cleaning / drying device 1 2 4, and the pre-processing device 1 2 6 placed in the clean space 1 1 4 hold the substrate in a horizontal position with the surface facing upward and process it.
  • the transfer robot 128 transfers and transfers the substrate while holding the substrate in a horizontal posture with the surface facing upward.
  • a stop force 1 64 for storing and temporarily placing the substrate holder 160, for example, the electric resistance of the surface of the seed layer formed on the surface of the substrate.
  • One of the second transfer robots 174a transfers the substrate holder 160 between the substrate attaching / detaching table 162 and the stock force 164, and the other second transfer robot 174b controls the stocker 1
  • the substrate holder 160 is transferred between the activation device 166, the first washing device 168a, the plating device 170, the second washing device 168b, and the blowing device 172.
  • the second transfer robots 174a and 174b include a vertically extending body 178, a vertically movable body 178, and a rotatable shaft.
  • An arm 180 is provided.
  • the arm 180 is provided with two substrate holder holding portions 182 for freely attaching and detaching and holding the substrate holder 160.
  • the substrate holder 160 is configured to hold the substrate W in a state where the surface is exposed and the peripheral edge is sealed, and the substrate W is freely attached and detached.
  • the stocker 164, the activation processing unit 166, the rinsing unit 168a, 168b and the mounting unit 170 are provided with the outwardly projecting projections 160a provided at both ends of the substrate holder 160.
  • the substrate holder 160 is hung vertically to be supported by being hooked.
  • the activation processing apparatus 166 is provided with two activation processing tanks 183 for holding a chemical solution therein. As shown in FIG. 2, a substrate holder 160 on which a substrate W is mounted is provided.
  • the washing devices 1 668a and 1 668b have two washing tanks 1 84a and 1 8 4 1) each containing pure water inside, and the plating device 1 7 0
  • a plurality of plating tanks 186 each holding a plating solution therein are provided.
  • the substrate holder 160 is mounted together with the substrate W on the pure water in these washing tanks 184a and 184b. By immersing it in water or the plating solution in plating bath 186, it is configured to perform water washing treatment and plating treatment.
  • the blower 1 72 lowered the arm 180 of the second transfer robot 1 74 b holding the substrate holder 160 loaded with the substrate W in a vertical state, and mounted the substrate holder 160
  • the substrate W is configured to be blown by blowing air or an inert gas onto the substrate W to blow off the liquid adhering to the substrate holder 160 and the substrate W to drain the water.
  • each plating tank 1886 of the plating apparatus 17 is configured to hold a plating solution 10 therein, and the substrate holder is contained in the plating solution 10.
  • the periphery is sealed in a water-tight manner, and the substrate W held with the surface (covered surface) exposed is immersed and arranged.
  • an overflow tank 46 for flowing the plating solution 10 which overflows the upper end of the overflow weir 44 of the plating tank 1 86.
  • the flow tank 46 and the plating tank 18 6 are connected by a circulation pipe 48.
  • a circulation pump 50, a constant temperature unit 52, and a filter 54 are provided inside the circulation pipe 48.
  • a circular anode 56 conforming to the shape of the substrate W is held vertically by the anode holder 58, and is vertically installed, and the plating solution 10 is placed in the plating tank 1886.
  • the anode 56 is immersed in this plating solution 10 I have.
  • the inside of the plating tank 186 is partitioned between the anode 56 and the substrate holder 160 to partition the inside of the plating tank 186 into an anode side chamber 40a and a substrate side chamber 40b, and the plating liquid 10 held in the plating tank 186 is supplied to the anode
  • An adjustment plate 60 is installed on the side and the substrate side.
  • a plurality of paddles 62 hanging downward are provided between the substrate holder 160 and the adjustment plate 60, and the paddles 62 are positioned inside the plating solution 10 in the substrate side chamber 40b and held by the substrate holder 160.
  • a paddle-type stirring mechanism 64 that stirs the plating solution in the substrate side chamber 40 b by reciprocating in parallel with the substrate W is disposed.
  • the adjusting plate 60 has, for example, a thickness of about 0.5 to about L Omm and is made of a dielectric material made of PVC, PP, PEEK, PES, HT-PVC, PFA, PTFE, and other resin-based materials. I have. Then, a predetermined area inside the adjustment plate 60, that is, an area facing the surface of the substrate W when the substrate W is held by the substrate holder 160 and arranged at a predetermined plating position in the plating tank 186. A through-hole group 68 including a large number of through-holes 66 is provided in substantially the entire area of the substrate and in a circular region similar to the substrate W.
  • a through hole 66 is formed by a slit-like elongated hole extending linearly in the horizontal direction, and the through hole (elongated hole) 66 is formed in the outer shape of the substrate W.
  • the through-hole group 68 is configured by being arranged linearly and side-by-side in a circular area B along.
  • the width of the through hole (slot) 66 is generally about 0.5 to 20 mm, preferably about 1 to 15 mm, and the length is arbitrary according to the size (diameter) of the substrate W. Is set to
  • a through-hole group 68 including a large number of through-holes 66 is provided inside the adjustment plate 60, and during plating, an electric field leaks through each of the through-holes 66 so that the leaked electric field spreads evenly.
  • the potential distribution over the entire surface (covered surface) of the substrate W can be made more uniform, and the in-plane uniformity of the metal film formed on the surface of the substrate W can be further improved.
  • the flow of the plating solution 10 is reduced. It is possible to prevent the thickness of the metal film formed on the surface of the substrate W from being uneven due to the influence of (return of the plating solution).
  • a through-hole group 68 including a large number of through-holes 66 is formed over substantially the entire region of the adjustment plate 60 facing the surface of the substrate W and in a circular region similar to the substrate W.
  • a metal film having good film thickness uniformity in all directions on the surface of the substrate W can be formed.
  • the plating solution 10 is filled in the plating tank 186 and the plating solution 10 is circulated as described above.
  • the substrate holder 160 holding the substrate W is lowered, and the substrate W is placed at a predetermined position where the substrate W is immersed in the plating liquid 10 in the plating tank 186.
  • the anode 56 is connected to the anode of the power supply 24 via the conductor 22a, and the substrate W is connected to the cathode of the power supply 24 via the conductor 22b.
  • the stirring mechanism 64 By driving the stirring mechanism 64, the paddle 62 is reciprocated along the surface of the substrate W to stir the plating solution 10 in the substrate side chamber 40b. Is deposited to form a metal film.
  • the electric field leaks through the many through holes 66 provided inside the adjustment plate 60, and the leaked electric field is spread evenly, so that the surface of the substrate W (covering By making the potential distribution over the entire surface (surface) more uniform, it is possible to form a metal film P with higher in-plane uniformity on the surface of the substrate W as shown in FIG. Moreover, by agitating the plating solution 10 between the substrate W and the adjustment plate 60 with the paddle 62 during the plating process, sufficient ions can be removed from the substrate W while losing directionality in the flow of the plating solution. The metal film having a more uniform thickness can be formed more quickly by supplying the material more uniformly to the surface.
  • the plating power source 24 is separated from the substrate W and the anode 56, and the substrate holder 160 is pulled up together with the substrate W, and after performing necessary processing such as washing and rinsing the substrate W. Then, the substrate W after plating is transferred to the next process.
  • a series of bump attachment processing by the plating equipment configured as described above will be described with further reference to FIG. 7A, a seed layer 500 as a power supply layer is formed on the surface, and the height H is, for example, 20 to 120 ⁇ m on the surface of the seed layer 500.
  • a substrate W provided with an opening 502 a having a diameter of, for example, about 20 to 200 / zm at a predetermined position of the resist 502 is placed on the surface thereof. (Substrate facing up), put it in a substrate cassette, and mount this substrate cassette on the load / unload port 120.
  • one substrate W is taken out by the first transfer robot 128, placed on the aligner 122, and the position of the orientation notch is set in a predetermined direction. Match.
  • the substrate W aligned in the direction by the aligner 122 is transferred to the pretreatment device 126 by the first transfer robot 128.
  • pretreatment using pure water as a pretreatment liquid is performed.
  • the substrate holder 160 stored in the vertical position in the stocker 164 is taken out by the second transfer robot 174a, and it is rotated 90 ° and placed in a horizontal state to remove the substrate 1 6 Place two in parallel on 2.
  • the substrate W that has been subjected to the above-described pre-treatment is mounted on the substrate holder 160 mounted on the substrate attaching / detaching table 16 2 with its peripheral edge sealed.
  • the two substrate holders 160 on which the substrate W is mounted are simultaneously held by the second transport robot 1774a, raised, and then transported to the stocker 1664, and rotated 90 °.
  • the substrate holder 160 is set in a vertical state, and then lowered, whereby the two substrate holders 160 are suspended and held (temporarily placed) by the stop force 164. This operation is sequentially repeated, and the substrates are sequentially mounted on the substrate holders 160 accommodated in the stockers 1664, and are sequentially suspended and held (temporarily placed) at predetermined positions of the stockers 1664.
  • the two substrate holders 160, on which the substrates are mounted and temporarily placed at the stocking force 164, are simultaneously held, raised, and then activated.
  • the substrate is immersed in a chemical solution such as sulfuric acid or hydrochloric acid placed in the activation treatment tank 18 3 to etch the oxide film with high electrical resistance on the surface of the seed layer, and clean metal Expose the surface.
  • the substrate holder 160 on which the substrate is mounted is transported to the first rinsing device 168a in the same manner as described above, and the surface of the substrate is rinsed with pure water in the rinsing tank 184a. Wash with water.
  • the substrate holder 160 on which the rinsed substrate is mounted is transferred to the plating apparatus 170 in the same manner as described above, and the plating tank is immersed in the plating solution 10 in the plating tank 186.
  • the surface of the substrate W is plated by suspending and supporting it on 186. Then, after a lapse of a predetermined time, the substrate holder 160 on which the substrate is mounted is again held by the second transfer robot 174b, pulled up from the plating tank 186, and the plating process is completed.
  • the substrate holder 160 is transported to the second washing device 1668b, and is immersed in pure water in the washing tank 1884b to clean the surface of the substrate with pure water. I do. Thereafter, the substrate holder 160 on which the substrate is mounted is conveyed to the blower 172 in the same manner as described above, where an inert gas or air is blown toward the substrate, and the substrate holder 16 Remove the plating solution and water droplets attached to 0. Thereafter, the substrate holder 160 on which the substrate is mounted is returned to a predetermined position of the stocker 164 and suspended and held in the same manner as described above.
  • the second transfer robot 174 b sequentially repeats the above operation, and returns the substrate holder 160 on which the plated substrate is mounted to the predetermined position of the stop force 164 in order, and suspends the substrate holder.
  • the first transfer robot 128 disposed in the cleaning space 114 removes the substrate from the substrate holder 160 placed on the substrate mounting table 162, and cleans the substrate.
  • the substrate held horizontally with its surface facing upwards is washed with pure water or the like by this washing / drying device 124 and spin-dried by high-speed rotation.
  • the substrate cassette mounted on the loading / unloading port 120 at 28 to complete a series of plating processes. This As a result, as shown in FIG. 7B, a substrate W having a plated film 504 grown in the opening 502 a provided in the resist 502 is obtained.
  • the substrate W spin-dried as described above is immersed in a solvent such as acetone at a temperature of 50 to 60 ° C., for example, and a resist 5 on the substrate W is formed as shown in FIG. 7C.
  • a solvent such as acetone
  • FIG. 7D unnecessary seed layer 500 exposed outside after plating is removed.
  • the plating film 504 formed on the substrate W is reflowed to form a bump 506 which is rounded by surface tension as shown in FIG. 7E.
  • the substrate W is subjected to annealing at a temperature of, for example, 100 ° C. or more to remove residual stress in the bumps 506.
  • the transfer of the substrate in the plating space 1 16 is performed by the second transfer robots 17 4 a and 17 4 b arranged in the mounting space 1 16 in the clean space 1 14.
  • the first transfer robot 1 28 arranged in the clean space 114 transfers the substrates of the respective substrates, thereby continuously performing the pre-processing of the substrate, the plating process, and the post-processing of the plating.
  • the throughput of the plating equipment is improved, and the load on the auxiliary equipment of the plating equipment is further reduced.
  • the size can be further reduced.
  • a plating apparatus having a small footprint and having a plating tank 186 is used as the plating apparatus 170 for performing the plating process.
  • one of the two washing / drying devices 124 installed may be replaced with a pretreatment device.
  • FIG. 8 to 19 show different examples of the through-hole group including a large number of through-holes in the adjustment plate 60.
  • a through hole 66a is formed by a slit-shaped elongated hole extending linearly in the vertical direction, and the through hole (slot) 66a is formed in a circular area along the outer shape of the substrate W.
  • the through-hole group 68a is configured by arranging them in a straight line and in parallel.
  • Fig. 9 shows the case where a rectangular substrate is used as the substrate W.
  • the through-holes (slots) 66 b are arranged linearly and in parallel in a rectangular area along the outer shape of the substrate W to form a through-hole group 68 b.
  • FIG. 10 shows a plurality of through-holes (slots) 66 c formed of slits extending linearly over almost the entire width of a region of the adjustment plate 60 facing the surface of the substrate W.
  • a hole group 68 c is formed.
  • the through hole (slot) 66 d is placed in a rectangular area along the outer shape of the substrate W as shown in FIG.
  • the through-hole group 68 d may be arranged in parallel. Although not shown, these through holes 66d may extend linearly in the vertical direction.
  • Fig. 12 shows a configuration in which a plurality of through-holes (cross-shaped holes) 66 e composed of cross-shaped holes extending in a cross shape in the vertical and horizontal directions are equally arranged in a circular area to form a through-hole group 68 e. is there. Also in this case, when a rectangular substrate is used as the substrate W, the through hole (cross-shaped hole) 66 f should be placed in the rectangular area along the outer shape of the substrate W as shown in FIG. The holes may be evenly arranged to form a through hole group 6 8 f.
  • Fig. 14 shows a group of 68 g of through-holes in which 66 g of a plurality of through-holes (pores) are evenly distributed in a circular region.
  • the diameter of each through-hole (pore) 66 g is set to 2 mm in this example, and a total of 633 is provided in the example shown.
  • the diameter of the through hole 66 g and the following small holes (peripheral holes) 66 h 2 to 66 h 5 are arbitrarily set, for example, in the range of 1 to 2 O mm. About 0 mm is preferable. In this way, by forming 66 g of the through-holes (pores) into 68 g of the through-hole group, the productivity of the adjusting plate 60 can be improved.
  • Figure 15 shows multiple holes with different diameters, that is, a large-diameter large hole (center hole) 6 6 1 ⁇ located at the center, and the outer periphery of the large hole 6 6 1 ⁇ along the circumferential direction.
  • Plural rows (four rows in the figure) of small holes (peripheral holes) that are arranged and decrease in diameter as they go in the diameter direction 6 6 h 2 to 66 h 5 8 h.
  • the diameter of this large hole (center hole) 66 1 ⁇ is set to 84 mm in this example, but is set arbitrarily in the range of 50 to 30 O mm, for example, to 30 to 10 0 mm. O mm is preferable.
  • the diameter of the small holes (peripheral holes) 6 6 h 2 ⁇ 6 6 h c is, 1 0 mm, 8 mm, 7 mm and 6 mm respectively.
  • 1 6 has a center hole 6 6 ii centrally located, the center hole 6 disposed outside the 6 i, a plurality of rows (in the illustrated five rows) extending in the circumferential direction of the slot 6 6 i 2 a plurality of through holes 66 i consisting of -66 i 6 is obtained by constituting the through hole groups 6 8 i.
  • the diameter of the central hole 66 i ⁇ in this example, is set to 34 mm, the width of the slot 66 i 2 ⁇ 6 6 i 6 is, 2 7mm, 1 8. 5mm, 7 mm, 7 mm, 7 mm Are set respectively.
  • Figure 17 shows a large-diameter large hole (central hole) 66ji located at the center, and a circumferentially extending long hole arranged outside the central hole 66ji along the circumferential direction. 6 6 and j 2, this is located outside of the long hole 66 j 2, small holes (peripheral holes) of a plurality of rows which diameter decreases toward the diameter direction (four rows in the figure) 66 j 3 -66 j
  • a through hole group 68 j is constituted by a plurality of through holes 66 j composed of six .
  • the diameter of the large hole (center hole) 66 ji is 67 mm in this example, the width of the long hole 66 j 2 is 17 mm, and the small hole (peripheral hole) 66 j 3 to 66 j 6
  • the diameters are set at 9mm, 8mm, 7mm and 6mm respectively.
  • Figure 18 shows a large-diameter large hole (central hole) 661 ⁇ located at the center and a plurality of circumferentially extending holes arranged outside the central hole 66k along the circumferential direction.
  • the diameter of the large hole (center hole) 66 ki is 80 mm in this example, the width of the long holes 66 k 2 and 66 k 3 is 7 mm, and the small holes (peripheral holes) 66 k 4 and 66 k 5 The diameters are set at 6 mm and 4 mm, respectively.
  • Fig. 19 shows a large-diameter large hole (center hole) 661i located at the center, and a radially arranged outside the center hole 661i at a predetermined pitch along the circumferential direction. It is obtained by constituting the through hole groups 68 1 by a plurality of through holes 66 1 including a plurality of slit-like long holes 66 1 2 extending linearly in.
  • the width of the long hole 66 1 2 is generally on the order of 0. 5 to 20 m m, is preferably about 1 to 1 5 mm. Also, the length is It is set arbitrarily according to the shape of the body.
  • a through-hole group is formed, thereby providing a plating place and conditions. And so on.
  • the through holes are arranged inside the circular region to form a group of through holes.
  • a rectangular substrate is used as the substrate.
  • these through holes may be arranged in a rectangular area along the outer shape of the substrate to form a through hole group.
  • the electric field leaks through a large number of through-holes provided inside the adjustment plate installed in the plating tank, and the leaked electric field is uniformly spread, so that the covering is performed.
  • the potential distribution over the entire surface of the attached body more uniform, the in-plane uniformity of the metal film formed on the attached body can be further improved.
  • the plating solution is affected by the flow of the plating solution, and Nonuniformity in the thickness of the formed metal film can be prevented.
  • FIG. 20 shows a plating apparatus 170a according to another embodiment of the present invention
  • FIG. 21 shows an adjusting plate and a cylindrical body forming a plating liquid flow path used in the plating apparatus 170a.
  • the adjusting plate 60 has a thickness of, for example, about 0.5 to 1 Omm and a substrate held by a substrate holder 160 at the center thereof.
  • a central hole 60a having an inner diameter D facing the outer diameter of the substrate W and facing the W is used.
  • a cylindrical body 200 equal to the inner diameter D of the cylindrical body 200 is connected concentrically and continuously, whereby the plating solution flow path through which the plating solution 10 flows through the inner peripheral surface of the cylindrical body 200 while allowing the electric field to pass uniformly. This is the point that formed 200a.
  • This cylindrical body 200 is made of a dielectric material made of, for example, PVC, PP, PEEK, PES, HT-PVC, PFA, PTFE, and other resin-based materials, similarly to the adjustment plate 60. Other configurations are the same as those shown in FIGS. is there.
  • the central hole of the adjusting plate 60 and the inner diameter D of the cylindrical body 200 are generally equal to the outer diameter of the surface of the substrate W to be plated (the outer diameter of the surface to be covered) ⁇ 10 mm.
  • the diameter is set to about ⁇ 5 mm, which is equal to the outer diameter of the covering surface, and more preferably, about ⁇ 1 mm, which is equal to the outer diameter of the covering surface.
  • the length L of the cylindrical body 200 is appropriately determined by the shape of the plating tank 1886, the distance between the anode 56 and the substrate W, etc.1S In general, 10 to 90 mm, preferably , 20 to 75 mm, more preferably 30 to 60 mm.
  • the electric field formed between the anode 56 and the substrate W in the plating tank 1886 is arranged along the liquid flow path 200a, that is, the inside of the cylindrical body 200 is formed by the cylindrical body.
  • the distortion and bias of the electric field are adjusted and corrected, and the potential distribution over the entire surface of the substrate W is made more uniform, as shown in Fig. 22.
  • the metal film P As described above, on the surface of the substrate W, it is possible to form the metal film P with slightly increased in-plane uniformity, although the film thickness is slightly increased at the edge of the substrate W.
  • the thickness of the adjusting plate 60 is generally as thin as about 0.5 to 10 mm with only the adjusting plate 60 having the central hole 60a therein.
  • the regulation of the electric field formed between the anode 56 and the substrate W by the adjustment plate 60 alone is insufficient, causing distortion and bias in the electric field, especially the film thickness at the edge of the substrate that is the power receiving part.
  • by restricting the passage of an electric field over the length L of the cylindrical body 200 such an adverse effect can be prevented and the in-plane surface of the metal film can be prevented. Uniformity can be improved.
  • a plurality of paddles 6 hanging down between the cylindrical body 200 and the substrate W held by the substrate holder 160 are provided.
  • a paddle-type stirring mechanism 64 equipped with a paddle-type stirring mechanism 64 is disposed.
  • the paddle-type stirring mechanism 64 is driven to reciprocate the paddle 62 along the surface of the substrate W, and the substrate side chamber 40 b
  • a sufficient ion is supplied more evenly to the surface of the substrate W while the direction of the plating solution flow is lost, and a metal film having a more uniform film thickness is more quickly formed. It can be formed quickly.
  • FIG. 23 shows a plating apparatus 17 Ob according to still another embodiment of the present invention.
  • the difference from the example shown in FIGS. 21 and 22 of this plating device 170 b is that a paddle-type stirring mechanism 6 is provided between the cylindrical body 200 and the substrate W held by the substrate holder 160. 4 in that a plating solution jetting type stirring mechanism 202 is provided instead of 4.
  • the plating liquid injection type stirring mechanism 202 is formed of, for example, a ring-shaped pipe, communicates with the circulation pipe 48, and is immersed in the plating liquid 10 of the plating tank 1886.
  • Attached solution supply pipe 204 and this plating liquid supply pipe 204 are attached at predetermined positions along the circumferential direction, and are directed to substrate W holding plating solution 10 with substrate holder 16 °. And a plurality of plating liquid jet nozzles 206 for jetting. Then, the plating solution 10 sent with the driving of the pump 50 is supplied to the plating solution supply pipe 204, and is sprayed from the plating solution spray nozzle 206 toward the substrate, so that the plating tank 1. It is introduced into 86, and overflows at the upper end of the overflow weir 44 to circulate.
  • the plating solution 10 in the plating tank 186 is stirred to make the plating solution concentration uniform.
  • the components of the plating liquid 10 are sufficiently supplied to the substrate W, and a metal film having a more uniform film thickness can be formed more quickly.
  • a force is shown in which the cylindrical body 200 is connected to the surface of the adjustment plate 60 on the substrate W side.
  • a fitting hole is formed in the adjustment plate 60.
  • a cylindrical body 200 having an inner diameter D and a length of 200 b and having a liquid flow path 200 a was fitted in the fitting hole 60 b, and a cylindrical body was provided.
  • the cylindrical body 200 may be held at a predetermined position along the length direction of 200. As a result, even when the distance between the adjusting plate 60 and the “Donore 62” (see FIG. 20) and the attachment liquid supply pipe 204 (see FIG. 23) is short, the cylindrical body 200 can be used. By projecting the rear side of the adjusting plate 60, a sufficient length L as the cylindrical body 200 can be secured.
  • a large number of through holes 200b large enough to prevent electric field leakage may be provided on the peripheral wall of the cylindrical body 200. This results in electric field leakage
  • the plating solution 10 flows through the through hole 200b provided in the peripheral wall of the cylindrical body 200 while preventing the plating solution 200 from flowing, so that the concentration of the plating solution 10 is biased inside and outside the cylindrical body 200. Can be prevented.
  • the shape of this through-hole may be other than that of this example. Examples include a slit-shaped long hole, a cross hole extending vertically and horizontally, and a combination thereof.
  • the adjusting plate 210 is formed of a plate having a sufficient thickness, and a through hole having a predetermined inner diameter is provided at a predetermined position of the adjusting plate 210.
  • a plating solution flow path 210a having a predetermined length L with an inner diameter D of the plating solution may be formed. In the case of this example, the number of members can be reduced.
  • a rectangular block 212 having a sufficient thickness is prepared, and a plating solution flow path having a predetermined inner diameter D and a predetermined length L is formed by a through hole provided in the rectangular block 212.
  • 210a may be formed, and this rectangular block 212 may be connected to the substrate W side surface of the adjusting plate 60 having the central hole 60a.
  • FIG. 28 shows a plating apparatus 170c according to still another embodiment of the present invention.
  • FIG. 29 shows an adjustment plate and a cylinder forming a plating solution flow path used in the plating apparatus 170c shown in FIG. 2 shows the body and the electric field adjustment ring.
  • the differences between the mounting device 170c and the example shown in FIGS. 20 and 21 are as follows. That is, an electric field adjusting ring 220 having an inner diameter equal to the inner diameter D of the cylindrical body 200 and having a width A is concentrically formed on the end face of the substrate W side of the cylindrical body 200 having the liquid flow path 2 OOa formed on the inner peripheral surface.
  • the electric field adjustment ring 220 is disposed close to the substrate W with a gap G1 from the substrate W.
  • a paddle-type stirring mechanism 64 having a plurality of paddles 62 that drop downward and reciprocate in parallel with the substrate W held by the substrate holder 160 to stir the plating solution is connected to the anode side chamber 40a side anode.
  • the plating solution 10 in the anode-side chamber 40a is agitated by the paddle-type agitation mechanism 64, which is disposed between the adjustment plate 60 and the adjustment plate 60.
  • Other configurations are the same as the examples shown in FIGS. 20 and 21.
  • the electric field adjusting ring 220 is made of, for example, PVC, PP, PEEK, PES, HT—PVC, PFA, PTFE, or the like, similarly to the adjusting plate 60 or the cylindrical body 200. Of a resin-based material.
  • the shape of the electric field adjusting ring 220 is appropriately set depending on the shape of the plating tank 1886 and the substrate W, the distance between the anode 56 and the substrate W, etc., and the width A is generally It is set to l to 20 mm, preferably 3 to 17 mm, and more preferably 5 to 15 mm.
  • the gap G1 between the electric field adjusting ring 220 and the substrate W is generally set to 0.5 to 3 O mm, preferably to 1 to 15 mm, and more preferably to 1.5 to 6 mm. Is done.
  • This electric field adjusting ring 220 is for adjusting the electric field of the outer peripheral portion of the substrate W by covering the outer peripheral portion of the substrate W with a predetermined width at a position close thereto.
  • the electric field formed between the anode 56 and the substrate W can be more uniformly spread over the entire surface of the substrate W.
  • the metal film P is further uniformized up to the edge of the substrate W, which is the power receiving unit, and the surface of the substrate W, including the edge of the substrate W, is further enhanced in-plane uniformity as shown in FIG. Can be formed.
  • FIG. 31 shows a plating apparatus 170 d according to still another embodiment of the present invention.
  • This plating device 170 d is provided between the anode 56 of the anode side chamber 40 a and the adjusting plate 60 instead of the paddle type stirring mechanism 64 in the plating device shown in FIGS. 28 and 29.
  • a plating solution jet type stirring mechanism 202 shown in FIG. 23 is disposed.
  • the plating solution 10 sent along with the driving of the pump 50 is supplied to the plating solution supply pipe 204, and the plating solution injection nozzle 206 and the cylindrical body 200 are supplied.
  • the liquid is sprayed toward the associated liquid flow path 200a, introduced into the plating tank 186, and further circulated by overflowing the upper end of the overflow weir 44.
  • Other configurations are the same as those shown in FIGS. 28 and 29.
  • the plating solution spray type stirring mechanism 202 is disposed in the anode side chamber 40a, and the plating solution is sprayed from the plating solution spray nozzle 206 to the cylindrical body 200 through the plating solution flow path 200a.
  • the gap G 1 between the electric field adjustment ring 220 and the substrate W held by the substrate holder 160 is narrow, the liquid flow path 200 a The plating solution can be supplied to the substrate W held by the substrate holder 160 You.
  • a fitting hole 60 b is provided in the adjustment plate 60, the inner diameter D, the length L, and the inner peripheral surface
  • a cylindrical body 200 having an electric field adjusting ring 220 attached to the end as an attachment liquid flow path 200a is fitted into the fitting hole 60b, and the length of the cylindrical body 200
  • the cylindrical body 200 may be held at a predetermined position along the direction.
  • the electric field is prevented from leaking to the peripheral wall of the cylindrical body 200 having the electric field adjusting ring 220 attached to the end face.
  • a large number of large through holes 200b are provided to prevent leakage of the electric field, and the liquid 10 flows through the inside of the through holes 200b provided in the peripheral wall of the cylindrical body 200. You may do so.
  • the electric field adjusting ring 220 is supported by the support 222 without being fixed to the end face of the cylindrical body 200, and the end face of the cylindrical body 200 on the substrate W side is provided. May be arranged with the gap G2 in front of the substrate W.
  • This gap G2 is generally 0.5 to 3 O mm, preferably 1 to 15 mm, and more preferably, similarly to the gap G1 between the electric field adjustment ring 220 and the substrate W. Set to 1.5 to 6 mm.
  • the selection range can be expanded by separating the cylindrical body 200 and the electric field adjustment ring 220.
  • a plating solution flow path 2 24 a having a predetermined inner diameter D and a length L is formed on the inner peripheral surface of the thick ring 22 4 having a sufficient thickness
  • the electric field adjusting ring 222b having a predetermined width A may be formed on the end face of the thick ring 222 on the substrate side.
  • the present invention is applied to a plating apparatus employing a so-called dip method.
  • the present invention can also be applied to a face-down type or face-up type employing a drilling apparatus.
  • Fig. 36 shows an example in which the present invention is applied to a plating apparatus employing the face-down method.
  • the following configuration is added to the conventional plating apparatus shown in FIG.
  • an adjustment plate 230 having a central hole 230a therein is disposed above the plating tank 12 and The inside of the plating tank 12 is shut off to the anode side chamber 12a and the substrate side chamber 12b, and the plating solution flow path 2 is formed on the upper surface of the adjusting plate 230 with the same inner diameter as the central hole 230a.
  • a cylindrical body 2332 having an inner peripheral surface forming 32a is mounted concentrically so as to protrude upward.
  • an electric field formed between the anode 16 and the substrate W in the plating tank 12 is formed along the plating solution flow path 23a, that is, the inside of the cylindrical body 23 is formed by the cylindrical body.
  • An electric field adjustment ring having an inner diameter equal to the inner diameter of the cylindrical body and having a predetermined width is concentrically attached to the upper end surface of the cylindrical body. To adjust the electric field at the outer peripheral portion of the substrate w, thereby making the electric field formed between the anode and the substrate more uniform up to the wedge portion of the substrate as the power receiving portion. It is a matter of course that a metal film having higher in-plane uniformity may be formed on the surface of the substrate, including the edge portion of the substrate.

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Abstract

A plating device has a plating vessel (40) for receiving plating liquid (10), an anode (56) installed so as to be immersed in the plating liquid (10) in the plating vessel (40), an adjustment plate (60) provided between the anode (56) and a substrate (W) that is provided so as to be opposed to the anode (56), and a plating power source (24) for performing plating by passing electricity between the anode (56) and the substrate (W). The adjustment plate (60) is provided so as to separate the plating liquid (10) received in the plating vessel (40) into the anode side and the side of an object to be plated. A perforation group (68) formed of a large number of through-perforations (66) is provided in the plate.

Description

明 細 書 めっき装置 技術分野  Description Plating equipment Technical field
本発明は、 例えば基板等の被めつき体の被めつき面にめっきを施すめつき装置、 特に半導体ゥエーハ等の表面に設けられた微細な配線用溝やホール、 ビアホール、 スルーホール、 レジスト開口部にめっき膜を形成したり、 半導体ゥエーハの表面 にパッケージの電極等と電気的に接続するバンプ (突起状電極) を形成したりす るのに使用されるめつき装置に関する。 背景技術  The present invention relates to a plating apparatus for plating a surface of a substrate such as a substrate, particularly a fine wiring groove or hole, a via hole, a through hole, a resist opening provided on a surface of a semiconductor wafer or the like. The present invention relates to a plating device used for forming a plating film on a portion or forming a bump (protruding electrode) on a surface of a semiconductor wafer to be electrically connected to a package electrode or the like. Background art
例えば、 T A B (Tape Automated Bonding) や F C (Flip Chip) においては、 配線が形成された半導体チップの表面の所定箇所 (電極) に金、 銅、 はんだ、 或 いは鉛フリ一はんだやニッケル、 更にはこれらを多層に積層した突起状接続電極 (バンプ) を形成し、 このバンプを介してパッケージの電極や T A B電極と電気 的に接続することが広く行われている。 このバンプの形成方法としては、 電気め つき法、 蒸着法、 印刷法、 ボールバンプ法といった種々の手法があるが、 半導体 チップの I ZO数の増加、 細ピッチ化に伴い、 微細化が可能で性能が比較的安定 している電気めつき法が多く用いられるようになってきている。  For example, in TAB (Tape Automated Bonding) or FC (Flip Chip), gold, copper, solder, or lead-free solder or nickel is applied to a predetermined location (electrode) on the surface of a semiconductor chip on which wiring is formed. It is widely used to form protruding connection electrodes (bumps) by laminating them in multiple layers, and to electrically connect to the package electrodes and TAB electrodes via these bumps. There are various methods for forming the bumps, such as an electroplating method, a vapor deposition method, a printing method, and a ball bump method, but with the increase in the number of IZOs and the finer pitch of semiconductor chips, miniaturization is possible. The electroplating method, whose performance is relatively stable, has been increasingly used.
電気めつき法によれば、 高純度な金属膜 (めっき膜) が容易に得られ、 しかも 金属膜の成膜速度が比較的速いばかりでなく、金属膜の膜厚の制御も比較的容易 に行うことができる。  According to the electroplating method, a high-purity metal film (plating film) can be easily obtained, and not only is the deposition rate of the metal film relatively high, but also the thickness of the metal film is relatively easily controlled. It can be carried out.
図 3 7は、 いわゆるフェースダウン方式を採用した従来のめっき装置の一例を 示す。 このめつき装置は、 内部にめっき液 1 0を保持する上方に開口しためっき 槽 1 2と、 基板 Wをその表面 (被めつき面) を下向き (フェースダウン) にして 着脱自在に保持する上下動自在な基板ホルダ 1 4を有している。 めっき槽 1 2の 底部には、 アノード 1 6が水平に配置され、 上部の周囲には、 オーバーフロー槽 1 8が設けられ、 更にめつき槽 1 2の底部にめっき液供給ノズル 2 0が連結され ている。 FIG. 37 shows an example of a conventional plating apparatus employing a so-called face-down method. The plating apparatus includes an open plating tank 12 for holding a plating solution 10 therein, and an upper and lower side for detachably holding a substrate W with its surface (covered surface) facing down (face down). It has a movable substrate holder 14. Plating tank 1 2 An anode 16 is disposed horizontally at the bottom, an overflow tank 18 is provided around the top, and a plating solution supply nozzle 20 is connected to the bottom of the plating tank 12.
これにより、 基板ホルダ 1 4で水平に保持した基板 Wを、 めっき槽 1 2の上端 開口部を塞ぐ位置に配置し、 この状態で、 めっき液供給ノズノレ 2 0からめつき槽 1 2の内部にめっき液 1 0を供給し、 このめつき液 1 0をめつき槽 1 2の上部か らオーバーフローさせることで、 基板ホルダ 1 4で保持した基板 Wの表面にめつ き液 1 0を接触させ、 同時に、 導線 2 2 aを介してアノード 1 6をめつき電源 2 4の陽極に、 導線 2 2 bを介して基板 Wをめつき電源 2 4の陰極にそれぞれ接続 する。 すると、 基板 Wとアノード 1 6との電位差により、 めっき液 1 0中の金属 イオンが基板 Wの表面より電子を受け取り、 基板 Wの表面に金属が析出して金属 膜が形成される。  As a result, the substrate W held horizontally by the substrate holder 14 is placed at a position to close the opening at the upper end of the plating tank 12, and in this state, the plating solution is supplied from the plating solution supply nozzle 20 to the inside of the plating tank 12. The plating liquid 10 is supplied, and the plating liquid 10 overflows from the top of the plating tank 12 so that the plating liquid 10 comes into contact with the surface of the substrate W held by the substrate holder 14. At the same time, the anode 16 is connected to the anode of the power supply 24 via the conductor 22a, and the substrate W is connected to the cathode of the power supply 24 via the conductor 22b. Then, due to the potential difference between the substrate W and the anode 16, metal ions in the plating solution 10 receive electrons from the surface of the substrate W, and the metal is deposited on the surface of the substrate W to form a metal film.
このめつき装置によれば、 アノード 1 6の大きさ、 アノード 1 6と基板 Wとの 極間距離および電位差、 めっき液供給ノズル 2◦力 ら供給されるめっき液 1 0の 供給速度等を調整することにより、 基板 Wの表面に形成される金属膜の膜厚の均 一性をある程度調節することができる。  According to this plating apparatus, the size of the anode 16, the distance between the anode 16 and the substrate W and the potential difference, the supply speed of the plating solution 10 supplied from the plating solution supply nozzle 2, and the like are adjusted. By doing so, the uniformity of the thickness of the metal film formed on the surface of the substrate W can be adjusted to some extent.
図 3 8は、 いわゆるディップ方式を採用した従来のめっき装置の一例を示す。 このめつき装置は、 内部にめっき液を保持するめつき槽 1 2 aと、 基板 Wをその 周縁部を水密的にシールし表面 (被めつき面) を露出させて着脱自在に保持する 上下動自在な基板ホルダ 1 4 aを有している。 めっき槽 1 2の内部には、 ァノー ド 1 6 aがアノードホルダ 2 6に保持されて垂直に配置され、 更に基板ホルダ 1 4 aで保持した基板 Wがアノード 1 6 aと対向する位置に配置された時に、 この アノード 1 6 aと基板 Wとの間に位置するように、 中央孔 2 8 aを有する誘電体 からなる調整板 (レギュレーションプレート) 2 8が配置されている。  FIG. 38 shows an example of a conventional plating apparatus employing a so-called dip method. This plating apparatus is composed of a plating tank 12a for holding the plating solution inside, and a substrate W that is sealed in a water-tight manner at its peripheral edge to expose the surface (covered surface) and to be detachably held. It has a flexible substrate holder 14a. Inside the plating tank 12, the anode 16 a is held vertically by the anode holder 26, and the substrate W held by the substrate holder 14 a is arranged at a position facing the anode 16 a. At this time, an adjustment plate (regulation plate) 28 made of a dielectric material having a central hole 28a is arranged between the anode 16a and the substrate W.
これにより、 これらのアノード 1 6、 基板 W及び調整板 2 8をめつき槽 1 2 a 内のめっき液中に浸漬し、 同時に、 導線 2 2 aを介してアノード 1 6 aをめつき 電源 2 4の陽極に、 導線 2 2 bを介して基板 Wをめつき電源 2 4の陰極にそれぞ れ接続することで、 前述と同様にして、 基板 Wの表面に金属が析出して金属膜が 形成される。 As a result, the anode 16, the substrate W and the adjustment plate 28 are immersed in the plating solution in the plating tank 12 a, and at the same time, the anode 16 a is plated through the conductor 22 a. Attach the substrate W to the anode of the power supply 4 and the cathode of the power supply 2 4 By the connection, the metal is deposited on the surface of the substrate W to form a metal film in the same manner as described above.
このめつき装置によれば、 アノード 1 6 aと該アノード 1 6 aと対向する位置 に配置される基板 Wとの間に、 中央孔 2 8 aを有する調整板 2 8を配置し、 この 調整板 2 8でめつき槽 1 2 a内の電位分布を調節することで、 基板 Wの表面に形 成される金属膜の膜厚分布をある程度調節することができる。  According to this plating apparatus, an adjustment plate 28 having a central hole 28a is arranged between the anode 16a and the substrate W arranged at a position facing the anode 16a. The thickness distribution of the metal film formed on the surface of the substrate W can be adjusted to some extent by adjusting the potential distribution in the plating tank 12 a with the plate 28.
図 3 9は、 いわゆるディップ方式を採用した従来のめっき装置の他の例を示す。 このめつき装置の図 3 8に示すものと異なる点は、 調整板を備えることなく、 リ ング状の擬似陰極 (擬似電極) 3 0を備え、 基板 Wの周囲に擬似陰極 3 0を配置 した状態で、 基板 Wを基板ホルダ 1 4 aに保持し、 更に、 めっき処理に際に、 導 線 2 2 cを介して、擬似陰極 3 0をめつき電源 2 4の陰極に接続するようにした ^^こある。  FIG. 39 shows another example of a conventional plating apparatus employing a so-called dip method. The difference of this plating device from that shown in Fig. 38 is that a ring-shaped pseudo cathode (pseudo electrode) 30 is provided without an adjustment plate, and the pseudo cathode 30 is arranged around the substrate W. In this state, the substrate W is held in the substrate holder 14a, and further, during the plating process, the pseudo cathode 30 is connected to the cathode of the power supply 24 via the conductor 22c. ^^ There are.
このめつき装置によれば、 擬似陰極 3 0の電位を調節することで、 基板 Wの表 面に形成される金属膜の膜厚の均一性を改善することができる。  According to this plating apparatus, the uniformity of the thickness of the metal film formed on the surface of the substrate W can be improved by adjusting the potential of the pseudo cathode 30.
一方、 例えば、 半導体基板 (ゥユーハ) の表面に配線用やバンプなどの金属膜 (めっき膜) を形成する際、 基板の全面に亘つて形成した金属膜の表面形状およ び膜厚の均一性が要求される。 近年の S O C、 W L— C S Pなどの高密度実装技 術においては、 高精度の均一性が益々要求されるようになってきたが、 これらの 従来のめっき装置では、 高精度の均一性に応えた金属膜を形成することは非常に 困難であった。  On the other hand, for example, when a metal film (plating film) for wiring or bumps is formed on the surface of a semiconductor substrate (ゥ uha), the uniformity of the surface shape and thickness of the metal film formed over the entire surface of the substrate is reduced. Is required. In recent years, high-density mounting technologies such as SOC and WL-CSP have increasingly required high-precision uniformity. However, these conventional plating equipment responded to high-precision uniformity. It was very difficult to form a metal film.
つまり、 図 3 7に示すめっき装置で基板にめっきを行うと、 めっき液の流れの 影響を強く受けた金属膜が形成され、 このめつき液の流れが速いと、 図 4 O Aに 示すように、 金属イオンの供給が十分な基板 Wの中央部の方が周辺部よりも金属 膜 Pの膜厚が厚くなる傾向が生じ、 これを防止するため、 めっき液の流れを非常 に弱くすると、 図 4 0 Bに示すように、 基板 Wの周縁部の方が中央部よりも金属 膜 Pの膜厚が厚くなる傾向が生じる。 また、 図 3 8に示すめっき装置で基板にめ つきを行うと、 中央に中央孔を有する調整板により電位分布を改善して、 基板の 全面に亘る金属膜の膜厚分布の均一性をある程度改善できるものの、 図 4 0 Cに 示すように、 基板 Wの中央部及び周辺部で金属膜 Pの膜厚が厚くなる、 波打った ような膜厚分布を有する金属膜 Pが形成される傾向が生じる。 更に、 図 3 9に示 すめつき装置でめっきを行った場合には、 擬似電極 (擬似陰極) の電圧の調整が 困難であるばかりでなく、 擬似電極の表面に付着した金属膜を除去する必要が生 じ、 この操作がかなり煩雑となってしまう。 In other words, when plating is performed on the substrate using the plating apparatus shown in Fig. 37, a metal film strongly affected by the flow of the plating solution is formed, and if the flow of the plating solution is fast, as shown in Fig. 4 OA However, the metal film P tends to be thicker in the central part of the substrate W than in the peripheral part where the supply of metal ions is sufficient. To prevent this, if the flow of the plating solution is made very weak, As shown in FIG. 40B, the peripheral portion of the substrate W tends to have a larger thickness of the metal film P than the central portion. When plating is performed on the substrate using the plating apparatus shown in Fig. 38, the potential distribution is improved by an adjustment plate with a central hole in the center, Although the uniformity of the film thickness distribution of the metal film over the entire surface can be improved to some extent, as shown in FIG. 40C, the film thickness of the metal film P becomes thicker and wavy at the central portion and the peripheral portion of the substrate W. There is a tendency that a metal film P having an appropriate film thickness distribution is formed. Furthermore, when plating is performed with the plating apparatus shown in Fig. 39, not only is it difficult to adjust the voltage of the pseudo electrode (pseudo cathode), but it is also necessary to remove the metal film attached to the surface of the pseudo electrode. This operation becomes quite complicated.
一般に従来のめっき装置では、 基板表面上に形成される表面電位分布により、 受電部である基板周辺部の膜厚が高くなり、 基板表面の膜圧分布が U字形になる 傾向があり (図 4 0 B参照) 、 膜厚均一性を損ねる大きな要因の一つとなってい る。 この現象を抑制するため、 基板表面への金属イオン供給の調整、 すなわちめ つき液の流れを調整する方法や、 基板表面の電位分布およびめつき槽内の電場を 制御 ·調整する方法として調整板や擬似電極による方法が採用されている。  Generally, in a conventional plating apparatus, the surface potential distribution formed on the substrate surface tends to increase the film thickness at the periphery of the substrate, which is the power receiving portion, and the film pressure distribution on the substrate surface tends to be U-shaped (see FIG. 4). However, this is one of the major factors that impair the film thickness uniformity. In order to suppress this phenomenon, adjustment plates are used to adjust the supply of metal ions to the substrate surface, that is, to adjust the flow of the plating solution, and to control and adjust the potential distribution on the substrate surface and the electric field in the plating tank. Or a method using a pseudo electrode.
めっき液の流れの調整や調整板による調節は、 金属イオンや電場を基板中央部 に集めて基板中央部のめっき膜を盛上げ、 これによつて、 基板の全面に亘るめつ き膜の膜厚分布を W字形に調整し、 平均膜厚からの膜厚変動を最小にする方法で ある (図 4 0 C参照) 。 したがって、 めっき液の流れの調整や調整板の位置 -中 央孔の大きさの選定と微調整が膜厚均一性に非常に重要な影響を及ぼし、 膜厚均 一性は、 調整 (チューニング) 具合に非常に左右されることになる。  Adjustment of the plating solution flow and adjustment by the adjustment plate is performed by collecting metal ions and electric fields at the center of the substrate and raising the plating film at the center of the substrate, thereby forming the film thickness of the plating film over the entire surface of the substrate. This method adjusts the distribution to a W-shape to minimize film thickness fluctuations from the average film thickness (see Fig. 40C). Therefore, the adjustment of the plating solution flow and the position of the adjustment plate-the selection of the center hole size and the fine adjustment have a very important effect on the film thickness uniformity, and the film thickness uniformity is adjusted (tuned). It depends very much on the condition.
一方、 擬似電極による方法は、 本来基板表面上だけの電位分布を、 基板外周の 擬似電極を含めた領域までに広げ、 受電部の膜厚の盛り上がりを擬似電極に寄せ て基板表面で極めて均一な膜厚を得るようにしている。 また、 この擬似電極によ る方法と等価なものとして、 基板内の周縁部近傍のパターンを "捨てチップ" と して擬似電極の役目を果たさせる方法もある。 擬似電極による方法では、 その電 圧調整が膜厚均一性を左右し、 また擬似電極に付着した金属膜 (めっき膜) を定 期的に除去する必要が生じて操作が煩雑となる。 また、 基板内の周縁部近傍のパ ターンを "捨てチップ" として擬似電極の役目を果たさせるようにすると、 基板 の 1枚あたりの有効チップが減少するため生産性の低下を招く。 上記のレ、ずれの方法も、 結果論的に膜厚分布を調整して均一な膜厚分布を得る ようにしたものである。 したがって、 アノードと力ソードである被めつき体との 間に形成されるめつき槽内の電場を積極的に制御 ·調整することで、 被めつき体 表面の電位分布を制御改善し、 これによつて、 本質的に U字形となる傾向のある めっき膜の膜厚分布を打ち消して改良するようにしたものではない。 発明の開示 On the other hand, in the method using a pseudo electrode, the potential distribution only on the substrate surface is originally spread to the area including the pseudo electrode on the outer periphery of the substrate, and the rise in the thickness of the power receiving portion is brought close to the pseudo electrode to make the potential distribution extremely uniform on the substrate surface. The film thickness is obtained. As a method equivalent to the method using the pseudo electrode, there is a method in which a pattern near the periphery of the substrate is used as a "disposal chip" to serve as a pseudo electrode. In the method using the pseudo electrode, the voltage adjustment affects the film thickness uniformity, and the operation becomes complicated because it is necessary to periodically remove the metal film (plating film) attached to the pseudo electrode. Also, if the pattern near the peripheral edge in the substrate is used as a dummy electrode so as to serve as a pseudo electrode, the number of effective chips per substrate decreases, which leads to a decrease in productivity. The above methods of deviation and deviation also result in adjusting the film thickness distribution to obtain a uniform film thickness distribution. Therefore, by positively controlling and adjusting the electric field in the plating tank formed between the anode and the plating object, which is a power source, the potential distribution on the surface of the plating object is controlled and improved. Therefore, the present invention does not cancel and improve the film thickness distribution of the plating film, which tends to be essentially U-shaped. Disclosure of the invention
本発明は、 上記事情に鑑みて為されたもので、 比較的簡単な装置構成で、 しか も複雑な運転方法や設定を必要とすることなく、 被めつき体の全体に亘ってより 均一な膜厚の金属膜 (めっき膜) を形成できるようにしためっき装置を提供する ことを目的とする。  The present invention has been made in view of the above circumstances, and has a relatively simple device configuration, and does not require complicated operation methods and settings, and is more uniform over the entire covering body. An object is to provide a plating apparatus capable of forming a metal film (plating film) having a thickness.
上記目的を達成するため、 本発明のめっき装置は、 めっき液を保持するめつき 槽と、 前記めつき槽内のめっき液に浸漬させて設置されるアノードと、 前記ァノ 一ドと該アノードと対向するように配置される被めつき体との間に設置される 調整板と、 前記アノードと被めつき体との間に通電してめつきを行うめっき電源 とを有し、 前記調整板は、 前記めつき槽内に保持されるめつき液を前記アノード 側と被めつき体側に遮断するように設置され、 内部に多数の通孔からなる通孔群 が設けられていることを特徴とする。  In order to achieve the above object, a plating apparatus of the present invention comprises: a plating tank for holding a plating solution; an anode immersed in the plating solution in the plating tank; and an anode and the anode. An adjusting plate provided between the cladding bodies arranged to face each other, and a plating power supply for energizing and plating between the anode and the cladding body; Is provided so as to block the plating liquid held in the plating tank between the anode side and the covering body side, and is provided with a through-hole group including a large number of through-holes therein. And
これにより、 めっき槽内に設置した調整板の内部に設けた多数の通孔内を電場 が漏れ、 漏れた電場が均一に拡がるようにすることで、 被めつき体の全面に亘る 電位分布をより均一にして、 被めつき体に形成される金属膜の面内均一性をより 高めることができる。 また、 めっき液がめっき槽内に設置した調整板の内部に設 けた多数の通孔内を通過するのを抑制することで、 このめつき液の流れによる影 響を受けて、 被めつき体に形成される金属膜の膜厚に不均一が生じることを防止 することができる。  As a result, the electric field leaks through a large number of through holes provided inside the adjusting plate installed in the plating tank, and the leaked electric field is spread evenly, so that the electric potential distribution over the entire surface of the covering body is reduced. By making it more uniform, the in-plane uniformity of the metal film formed on the covering body can be further improved. In addition, by suppressing the plating solution from passing through a large number of through-holes provided inside the adjustment plate installed in the plating tank, the plating solution is affected by the flow of the plating solution. Nonuniformity in the thickness of the metal film formed on the substrate can be prevented.
本発明の好ましい一態様によれば、 前記通孔群は、 スリット状に一方向に直線 状または円弧状に延びる複数の長穴からなることを特徴とする。 このように、 通 孔をスリット形状の長穴にすることで、 この長穴内のめっき液の流通を抑制しつ つ、 電場の漏れを促進することができる。 この長穴の幅は、 例えば 0 . 5〜2 0 mm、 好ましくは、 l〜1 5 mm程度であり、 長さは、 被めつき体の形状により 定められる。 According to a preferred aspect of the present invention, the through-hole group includes a plurality of elongated holes that extend linearly or arcuately in one direction in a slit shape. In this way, By making the holes into slit-shaped long holes, it is possible to promote the leakage of the electric field while suppressing the flow of the plating solution in the long holes. The width of the long hole is, for example, 0.5 to 20 mm, preferably about 1 to 15 mm, and the length is determined by the shape of the covering body.
本発明の好ましい一態様によれば、 前記通孔群は、 縦及び横方向に十字状に延 びる複数の十字穴からなることを特徴とする。  According to a preferred aspect of the present invention, the through-hole group includes a plurality of cross holes extending in a cross shape in the vertical and horizontal directions.
本発明の好ましい一態様によれば、 前記通孔群は、 複数の細孔、 径の異なる複 数の孔またはスリット状に延びる長穴の任意の組合せからなることを特徴とす る。 このように、 複数の細孔または径の異なる複数の孔の組合せで通孔群を形成 することで、生産性を向上させることができる。 この場合、細孔、更には小孔(周 辺孔) の直径は、例えば 1〜2 O mm、好ましくは 2〜1 0 mm程度で、大孔(中 央孔) の直径は、 例ぇば5 0〜3 0 0 111111、 好ましくは 3 0〜1 0 O mm程度で ある。  According to a preferred aspect of the present invention, the through-hole group is characterized by being composed of an arbitrary combination of a plurality of pores, a plurality of holes having different diameters, or a slit-shaped elongated hole. Thus, productivity can be improved by forming a through-hole group with a combination of a plurality of pores or a plurality of holes having different diameters. In this case, the diameter of the pores and further the small holes (peripheral holes) is, for example, 1 to 2 Omm, preferably about 2 to 10 mm, and the diameter of the large holes (center hole) is, for example, It is 50 to 300111111, preferably about 30 to 10 Omm.
前記通孔群は、 前記調整板の前記被めつき体と対面する領域のほぼ全域に亘り 該被めっき体と略相似形の領域内に形成されていることが好ましい。 このように 通孔群を形成することで、 被めつき体の全ての方向に対して良好な膜厚均一性を 有する金属膜を形成することができる。  It is preferable that the through-hole group is formed in a region substantially similar to the plated body over substantially the entire region of the adjustment plate facing the adhered body. By forming the through-hole group in this manner, a metal film having good film thickness uniformity in all directions of the covering body can be formed.
前記被めつき体と前記調整板との間に、 前記めつき槽で保持しためつき液を攪 拌する攪拌機構を有することが好ましい。 これにより、 被めつき体と調整板との 間のめっき液を、 めっき処理中に攪拌機構によって攪拌することで、 十分なィォ ンを被めつき体により均一に供給して、 より均一な膜厚の金属膜をより迅速に形 成することができる。  It is preferable that a stirring mechanism is provided between the to-be-coated body and the adjusting plate to stir the holding liquid held in the toning tank. Thus, by stirring the plating solution between the adherend and the adjusting plate by the agitating mechanism during the plating process, a sufficient amount of ion is supplied to the adherend uniformly and a more uniform A metal film having a thickness can be formed more quickly.
前記攪拌機構は、 好ましくは、 前記被めつき体と平行に往復運動をするパドル を有するパドル型攪拌機構である。 これにより、 めっき処理中に、 被めつき体と 平行に往復運動をするパドルでめっき液を攪拌することで、 めっき液の流れに方 向性をなくしな力 Sら、 十分なイオンを被めつき体に均一に供給することができる。 本発明の好ましい一態様によれば、 前記アノード及び前記調整板は、 鉛直方向 に設置されていることを特徴とする。 これにより、 設置面積が小さく、 保守性の 優れためつき装置を提供することができる。 The stirring mechanism is preferably a paddle-type stirring mechanism having a paddle that reciprocates in parallel with the covering body. As a result, during the plating process, the plating solution is agitated with a paddle that reciprocates in parallel with the object to be covered, so that sufficient force is applied to the plating solution, such as force S, which prevents the flow of the plating solution from becoming directional. It can be uniformly supplied to the attached body. According to a preferred aspect of the present invention, the anode and the adjustment plate are arranged in a vertical direction. It is characterized by being installed in. As a result, an installation device having a small installation area and excellent maintainability can be provided.
本発明の他のめっき装置は、 めっき液を保持するめつき槽と、 前記めつき槽内 のめつき液に浸漬させて設置されるアノードと、 前記アノードと該アノードと対 向するように配置される被めつき体との間に設置される調整板と、 前記アノード と被めつき体との間に通電してめつきを行うめっき電源とを有し、 前記調整板は、 前記めつき槽内に保持されるめつき液を前記ァノ一ド側と被めつき体側に遮断 するように設置され、 内部に電場を均一に通過させつつめっき液を流通させるめ つき液流路が設けられていることを特徴とするめつき装置である。  Another plating apparatus of the present invention includes a plating tank for holding a plating solution, an anode installed by being immersed in a plating solution in the plating tank, and disposed so as to face the anode and the anode. An adjusting plate installed between the anode and the body to be plated; and a plating power source for performing plating by energizing between the anode and the body to be adhered. The plating solution is installed so as to block the plating solution held therein between the anode side and the covering body side, and is provided with a plating solution flow path through which the plating solution flows while uniformly passing the electric field. The mounting device is characterized in that:
このように、 めっき槽内でアノードと被めつき体の間に形成される電場がめつ き液流路に沿って外部に漏れることなく均一に通過するようにすることで、 電場 の歪みや偏りを調整かつ修正し、 被めつき体の表面全面に亘る電位分布をより均 一にして、 被めつき体に形成される金属膜の面内均一性をより高めることができ る。  In this way, by making the electric field formed between the anode and the adherend in the plating tank pass uniformly along the plating liquid flow path without leaking to the outside, distortion and deviation of the electric field can be reduced. By adjusting and correcting, the potential distribution over the entire surface of the covering body can be made more uniform, and the in-plane uniformity of the metal film formed on the covering body can be further improved.
めっき液流路の長さは、 めっき槽の形状、 アノードと被めつき体間の距離等に より適当に設定されるが、 一般には、 1 0〜9 O mm、 好ましくは、 2 0〜7 5 mm、 更に好ましくは、 3 0〜6 O mmに設定される。  The length of the plating solution flow path is appropriately set depending on the shape of the plating tank, the distance between the anode and the covering object, etc., but is generally 10 to 9 Omm, preferably 20 to 7 Omm. It is set to 5 mm, more preferably 30 to 60 mm.
前記めつき液流路は、 好ましくは、 筒状体または矩形ブロックの内周面に形成 される。 これにより、 構造の簡素化を図ることができる。  Preferably, the plating liquid flow path is formed on the inner peripheral surface of a cylindrical body or a rectangular block. Thereby, the structure can be simplified.
前記筒状体の周壁には、 電場の漏れを防止する大きさの多数の通孔が設けられ ていることが好ましい。 これにより、 電場の漏れを防止しつつ、 筒状体の周壁に 設けた通孔内をめつき液が流通するようにすることで、 筒状体の内外でめっき液 の濃度に偏りが生じてしまうことを防止することができる。 この通孔の形状とし ては、 例えば細孔ゃスリット形状の長穴、 縦横に延びる十字穴、 更にはこれらの 組合せが挙げられる。  It is preferable that a plurality of through-holes having a size to prevent electric field leakage are provided in the peripheral wall of the cylindrical body. This prevents the electric field from leaking and allows the plating solution to flow through the through-holes formed in the peripheral wall of the cylindrical body, thereby causing a bias in the concentration of the plating solution inside and outside the cylindrical body. Can be prevented. Examples of the shape of the through hole include a long hole of a pore-slit shape, a cross hole extending vertically and horizontally, and a combination thereof.
本発明の好ましい一態様によれば、 前記被めつき体と前記調整板との間または 前記力ソードと前記調整板との間の少なくとも一方には、 前記めつき槽で保持し ためつき液を攪拌する攪拌機構を有することを特徴とする。 これにより、 めっき 液をめつき処理中に攪拌することで、 めっき槽内の諸金属イオンや諸添加剤を含 むめつき液濃度をめつき槽内で均一にし、被めつき体に均一な濃度のめっき液を 供給することで、 より均一な膜厚の金属膜をより迅速に形成することができる。 前記攪拌機構は、 好ましくは、 前記被めつき体と平行に往復運動をするパドル を有するパドル型攪拌機構である。 According to a preferred aspect of the present invention, at least one of the space between the clad body and the adjustment plate or between the force sword and the adjustment plate is held by the plating tank. It is characterized in that it has a stirring mechanism for stirring the pouring liquid. As a result, the plating solution is agitated during the plating process so that the concentration of the plating solution containing various metal ions and various additives in the plating bath becomes uniform in the plating bath, and the plating solution has a uniform concentration. By supplying the plating solution, a metal film having a more uniform film thickness can be formed more quickly. The stirring mechanism is preferably a paddle-type stirring mechanism having a paddle that reciprocates in parallel with the covering body.
前記攪拌機構は、 前記被めつき体の方向に向けてめっき液を噴射する複数のめ つき液噴射ノズノレを有するめっき液噴射型攪拌機構であってもよレ、。 このように、 複数のめっき液噴射ノズルから被めっき体に向けてめっき液を噴射することで、 めっき槽内のめっき液を攪拌してめっき液濃度を均一にすると同時に、 被めつき 体にめっき液の各成分を十分に供給して、 より均一な膜厚の金属膜をより迅速に 形成することができる  The stirring mechanism may be a plating solution spraying type stirring mechanism having a plurality of plating solution spray nozzles for spraying a plating solution toward a direction of the body to be covered. In this way, by spraying the plating solution from the plurality of plating solution spray nozzles toward the body to be plated, the plating solution in the plating tank is agitated to make the concentration of the plating solution uniform and, at the same time, the plating on the body to be plated By supplying each component of the liquid sufficiently, a metal film with a more uniform thickness can be formed more quickly
前記めつき液流路は、 前記調整板の内部に該調整板と一体に設けられていても よい。 調整板として板厚の厚いものを使用し、 この調整板の内部に通孔を設ける ことで、 この通孔をめつき液流路となすようにしてもよい。  The plating liquid flow path may be provided inside the adjustment plate integrally with the adjustment plate. A thick plate may be used as the adjusting plate, and a through hole may be provided inside the adjusting plate so that the through hole serves as a liquid flow path.
本発明の更に他のめっき装置は、 めっき液を保持するめつき槽と、 前記めつき 槽内のめっき液に浸漬させて設置されるアノードと、 前記アノードと該アノード と対向するように配置される被めつき体との間に、 前記めつき槽内に保持される めっき液を前記アノード側と被めつき体側に遮断するように設置され、 内部に電 場を均一に通過させつつめっき液を流通させるめっき液流路が設けられ調整板 と、 前記アノードと被めつき体との間に通電してめつきを行うめっき電源と、 前 記めつき液流路の前記被めつき体側端部に位置して該被めっき体の外周部の電 場を調整する電場調整リングとを有することを特徴とするめつき装置である。 このように、 被めつき体の外周部の電場を電場調整リングで調整することで、 アノードと被めつき体の間に形成される電場を被めつき体の全面に亘つてより 均一に、 つまり受電部である被めつき体のエッジ部までより均一化して、 被めつ き体に形成される金属膜の面内均一性をより更に高めることができる。 電場調整リングの形状は、 めっき槽ゃ被めつき体の形状、 アノードと被めつき 体間の間隔等により適当に設定されるが、その幅は、一般的には、 1〜2 O mm、 好ましくは、 3〜1 7 mm、 更に好ましくは、 5〜 1 5 mmに設定される。 Still another plating apparatus of the present invention includes: a plating tank that holds a plating solution; an anode that is installed by being immersed in a plating solution in the plating tank; and an anode that is disposed to face the anode. A plating solution held in the plating tank is installed between the anode body and the body to be adhered between the anode body and the body to be adhered. An adjusting plate provided with a plating solution flow path to be circulated; a plating power supply for conducting plating between the anode and the body to be plated; and an end of the plating solution flow path on the side of the body to be plated. And an electric field adjusting ring for adjusting an electric field at an outer peripheral portion of the object to be plated. As described above, by adjusting the electric field at the outer peripheral portion of the cladding body with the electric field adjusting ring, the electric field formed between the anode and the cladding body can be more uniformly spread over the entire surface of the cladding body. In other words, it is possible to further uniformize the edge portion of the covered body, which is the power receiving unit, and to further improve the in-plane uniformity of the metal film formed on the covered body. The shape of the electric field adjustment ring is appropriately set depending on the plating tank, the shape of the body to be covered, the distance between the anode and the body to be covered, etc., and the width is generally 1 to 2 O mm, Preferably, it is set to 3 to 17 mm, more preferably to 5 to 15 mm.
前記電場調整リングと前記被めつき体との隙間は、 一般には、 0 . 5〜3 0 m m、好ましくは、 1〜 1 5 mm、更に好ましくは、 1 . 5〜6 mmに設定される。 本発明の好ましい一態様によれば、 前記めつき液流路は、 筒状体の内周面に形 成され、前記電場調整リングは、該筒状体の被めつき体側端部に連結されている。 前記めつき液流路は、 筒状体の内周面に形成され、 前記電場調整リングは、 該 筒状体の被めつき体側端部に該筒状体と分離して配置されるようにしてもよレ、。 このように、 めっき液流路を構成すると筒状体と電場調整リングとを分離させる ことで、 選択の幅を拡げることができる。  The gap between the electric field adjusting ring and the covering body is generally set to 0.5 to 30 mm, preferably 1 to 15 mm, and more preferably 1.5 to 6 mm. According to a preferred aspect of the present invention, the plating liquid flow path is formed on an inner peripheral surface of a tubular body, and the electric field adjusting ring is connected to a covered body side end of the tubular body. ing. The plating liquid flow path is formed on an inner peripheral surface of the cylindrical body, and the electric field adjusting ring is arranged separately from the cylindrical body at an end of the cylindrical body to be adhered to the body. You can. As described above, when the plating solution flow path is formed, the tubular body and the electric field adjusting ring are separated from each other, so that the range of options can be expanded.
前記めつき液流路は、 筒状体の内周面に形成され、 前記電場調整リングは、 該 筒状体の被めつき体側端面に形成されるようにしてもよい。 これにより、 部品点 数を減少させることができる。 図面の簡単な説明  The plating liquid flow path may be formed on an inner peripheral surface of a tubular body, and the electric field adjusting ring may be formed on an end face of the tubular body facing the covered body. Thereby, the number of parts can be reduced. BRIEF DESCRIPTION OF THE FIGURES
図 1は、 本宪明の実施の形態のめっき装置を備えためっき処理設備の全体配置 図である。  FIG. 1 is an overall layout diagram of a plating apparatus equipped with a plating apparatus according to an embodiment of the present invention.
図 2は、 図 1に示すめっき処理装置のめっき空間に備えられている搬送ロボッ トの概要図である。  FIG. 2 is a schematic diagram of a transport robot provided in a plating space of the plating apparatus shown in FIG.
図 3は、 図 1に示すめっき処理装置に備えられているめっき装置の概略断面図 である。  FIG. 3 is a schematic sectional view of a plating apparatus provided in the plating apparatus shown in FIG.
図 4は、 図 3に示すめっき装置の要部の概略斜視図である。  FIG. 4 is a schematic perspective view of a main part of the plating apparatus shown in FIG.
図 5は、 図 3に示すめっき装置に備えられている調整板の平面図である。  FIG. 5 is a plan view of an adjustment plate provided in the plating apparatus shown in FIG.
図 6は、 図 3に示すめっき装置で金属膜 (めっき膜) を形成した時の金属膜の 状態を模式的に示す図である。  FIG. 6 is a diagram schematically showing a state of a metal film when a metal film (plating film) is formed by the plating apparatus shown in FIG.
図 7 A乃至図 7 Eは、 基板上にバンプ (突起状電極) を形成する過程を工程順 に示す断面図である。 7A to 7E show a process of forming bumps (protruding electrodes) on a substrate in the order of steps. It is sectional drawing shown in FIG.
図 8は、 調整板の他の例を示す平面図である。  FIG. 8 is a plan view showing another example of the adjustment plate.
図 9は、 調整板の更に他の例を示す平面図である。  FIG. 9 is a plan view showing still another example of the adjustment plate.
図 1 0は、 調整板の更に他の例を示す平面図である。  FIG. 10 is a plan view showing still another example of the adjustment plate.
図 1 1は、 調整板の更に他の例を示す平面図である。  FIG. 11 is a plan view showing still another example of the adjustment plate.
図 1 2は、 調整板の更に他の例を示す平面図である。  FIG. 12 is a plan view showing still another example of the adjustment plate.
図 1 3は、 調整板の更に他の例を示す平面図である。  FIG. 13 is a plan view showing still another example of the adjustment plate.
図 1 4は、 調整板の更に他の例を示す平面図である。  FIG. 14 is a plan view showing still another example of the adjustment plate.
図 1 5は、 調整板の更に他の例を示す平面図である。  FIG. 15 is a plan view showing still another example of the adjustment plate.
図 1 6は、 調整板の更に他の例を示す平面図である。  FIG. 16 is a plan view showing still another example of the adjustment plate.
図 1 7は、 調整板の更に他の例を示す平面図である。  FIG. 17 is a plan view showing still another example of the adjustment plate.
図 1 8は、 調整板の更に他の例を示す平面図である。  FIG. 18 is a plan view showing still another example of the adjustment plate.
図 1 9は、 調整板の更に他の例を示す平面図である。  FIG. 19 is a plan view showing still another example of the adjustment plate.
図 2 0は、 本発明の他の実施の形態のめっき装置を示す概略断面図である。 図 2 1 Aは、 図 2 0に示すめっき装置に備えられている調整板及び円筒体を示 す斜視図である。  FIG. 20 is a schematic sectional view showing a plating apparatus according to another embodiment of the present invention. FIG. 21A is a perspective view showing an adjustment plate and a cylindrical body provided in the plating apparatus shown in FIG.
図 2 1 Bは、 図 2 1 Aの正面図である。  FIG. 21B is a front view of FIG. 21A.
図 2 2は、 図 2 0に示すめっき装置で金属膜 (めっき膜) を形成した時の金属 膜の状態を模式的に示す図である。  FIG. 22 is a diagram schematically showing a state of the metal film when a metal film (plating film) is formed by the plating apparatus shown in FIG.
図 2 3は、本発明の更に他の実施の形態のめっき装置を示す概略断面図である。 図 2 4 Aは、 調整板及び円筒体の更に他の例を示す斜視図である。  FIG. 23 is a schematic sectional view showing a plating apparatus according to still another embodiment of the present invention. FIG. 24A is a perspective view showing still another example of the adjusting plate and the cylindrical body.
図 2 4 Bは、 図 2 4 Aの正面図である。  FIG. 24B is a front view of FIG. 24A.
図 2 5 Aは、 調整板及び円筒体の他の例を示す斜視図である。  FIG. 25A is a perspective view showing another example of the adjusting plate and the cylindrical body.
図 2 5 Bは、 図 2 5 Aの正面図である。  FIG. 25B is a front view of FIG. 25A.
図 2 6 Aは、 調整板及び円筒体の更に他の例を示す斜視図である。  FIG. 26A is a perspective view showing still another example of the adjusting plate and the cylindrical body.
図 2 6 Bは、 図 2 6 Aの正面図である。  FIG. 26B is a front view of FIG. 26A.
図 2 7 Aは、 調整板及び円筒体の更に他の例を示す斜視図である。 図 2 7 Bは、 図 2 7 Aの正面図である。 FIG. 27A is a perspective view showing still another example of the adjusting plate and the cylindrical body. FIG. 27B is a front view of FIG. 27A.
図 2 8は、 本発明の更に他の実施の形態のめっき装置を示す概略断面図である。 図 2 9 Aは、 図 2 8に示すめっき装置に備えられている調整板、 円筒体及び電 場調整リングを示す斜視図である。  FIG. 28 is a schematic sectional view showing a plating apparatus according to still another embodiment of the present invention. FIG. 29A is a perspective view showing an adjustment plate, a cylindrical body, and an electric field adjustment ring provided in the plating apparatus shown in FIG.
図 2 9 Bは、 図 2 9 Aの正面図である。  FIG. 29B is a front view of FIG. 29A.
図 3 0は、 図 2 8に示すめっき装置で金属膜 (めっき膜) を形成した時の金属 膜の状態を模式的に示す図である。  FIG. 30 is a diagram schematically showing a state of the metal film when a metal film (plating film) is formed by the plating apparatus shown in FIG.
図 3 1は、 本発明の更に他の実施の形態のめっき装置を示す概略断面図である。 図 3 2 Aは、調整板、円筒体及び電場調整リングの他の例を示す斜視図である。 図 3 2 Bは、 図 3 2 Aの正面図である。  FIG. 31 is a schematic sectional view showing a plating apparatus according to still another embodiment of the present invention. FIG. 32A is a perspective view showing another example of the adjusting plate, the cylindrical body, and the electric field adjusting ring. FIG. 32B is a front view of FIG. 32A.
図 3 3 Aは、 調整板、 円筒体及び電場調整リングの更に他の例を示す斜視図で ある。  FIG. 33A is a perspective view showing still another example of the adjusting plate, the cylindrical body, and the electric field adjusting ring.
図 3 3 Bは、 図 3 3 Aの正面図である。  FIG. 33B is a front view of FIG. 33A.
図 3 4 Aは、 調整板、 円筒体及び電場調整リングの更に他の例を示す斜視図で ある。  FIG. 34A is a perspective view showing still another example of the adjusting plate, the cylindrical body, and the electric field adjusting ring.
図 3 4 Bは、 図 3 4 Aの正面図である。  FIG. 34B is a front view of FIG. 34A.
図 3 5 Aは、 調整板、 円筒体及び電場調整リングの更に他の例を示す斜視図で ある。  FIG. 35A is a perspective view showing still another example of the adjusting plate, the cylindrical body, and the electric field adjusting ring.
図 3 5 Bは、 図 3 5 Aの正面図である。  FIG. 35B is a front view of FIG. 35A.
図 3 6は、本発明の更に他の実施の形態のめっき装置を示す概略断面図である。 図 3 7は、 従来のめっき装置の一例を示す概略断面図である。  FIG. 36 is a schematic sectional view showing a plating apparatus according to still another embodiment of the present invention. FIG. 37 is a schematic sectional view showing an example of a conventional plating apparatus.
図 3 8は、 従来のめっき装置の他の例を示す概略斜視図である。  FIG. 38 is a schematic perspective view showing another example of the conventional plating apparatus.
図 3 9は、 従来のめっき装置の更に他の例を示す概略斜視図である。  FIG. 39 is a schematic perspective view showing still another example of the conventional plating apparatus.
図 4 O A乃至図 4 0 Cは、 従来のめっき装置によって形成された金属膜 (めつ き膜) のそれぞれ異なる状態を模式的に示す図である。 発明を実施するための最良の形態 FIGS. 4OA to 40C are diagrams schematically showing different states of a metal film (plated film) formed by a conventional plating apparatus. BEST MODE FOR CARRYING OUT THE INVENTION
以下、 本発明の実施の形態を図面を参照して説明する。 なお、 以下の実施の形 態では、 被めつき体として半導体ゥエーハ等の基板を使用した例を示す。  Hereinafter, embodiments of the present invention will be described with reference to the drawings. In the following embodiments, an example is shown in which a substrate such as a semiconductor wafer is used as a body to be covered.
図 1は、 本発明の実施の形態におけるめっき装置を備えためっき処理設備の全 体配置図を示す。 このめつき処理設備は、 基板の前処理、 めっき処理及びめつき の後処理のめっき全工程を連続して自動的に行うようにしたもので、 外装パネル を取付けた装置フレーム 1 1 0の内部は、 仕切板 1 1 2によって、 基板のめっき 処理及びめつき液が付着した基板の処理を行うめっき空間 1 1 6と、 それ以外の 処理、 すなわちめっき液に直接には関わらない処理を行う清浄空間 1 1 4に区分 されている。 そして、 めっき空間 1 1 6と清浄空間 1 1 4とを仕切る仕切板 1 1 2で仕切られた仕切り部には、 基板ホルダ 1 6 0 (図 2参照) を 2枚並列に配置 して、 この各基板ホルダ 1 6 0との間で基板の脱着を行う、 基板受渡し部として の基板脱着台 1 6 2が備えられている。 清浄空間 1 1 4には、 基板を収納した基 板カセットを載置搭載するロード · アンロードポート 1 2 0が接続され、 更に、 装置フレーム 1 1 0には、 操作パネル 1 2 1が備えられている。  FIG. 1 is an overall layout diagram of a plating apparatus equipped with a plating apparatus according to an embodiment of the present invention. This plating treatment equipment automatically and continuously performs all the plating processes of the pre-treatment of the substrate, the plating treatment and the post-treatment of the plating, and the inside of the equipment frame 110 with the exterior panel attached. Is a plating space 1 16 where the partition plate 1 1 2 is used for plating the substrate and the processing of the substrate to which the plating liquid is attached, and a cleaning where other processing, that is, processing that is not directly related to the plating solution, is performed. It is divided into spaces 114. Then, two board holders 160 (see FIG. 2) are arranged in parallel in a partition part separated by a partition plate 112 that separates the plating space 116 from the clean space 111. A substrate attaching / detaching table 162 as a substrate transfer section for attaching / detaching the substrate to / from each substrate holder 160 is provided. A load / unload port 120 for mounting a substrate cassette containing substrates is connected to the clean space 114, and an operation panel 122 is provided for the device frame 110. ing.
清浄空間 1 1 4の内部には、 基板のオリフラやノッチなどの位置を所定方向に 合わせるァライナ 1 2 2と、 めっき処理後の基板を洗浄し高速回転させてスピン 乾燥させる 2台の洗浄 ·乾燥装置 1 2 4と、 基板の前処理、 この例では、 基板の 表面 (被めつき面) に向けて純水を吹きかけることで、 基板表面を純水で洗浄す るとともに、 純水で濡らして親水性を良くする水洗前処理を行う前処理装置 1 2 6力 その四隅に位置して配置されている。 更に、 これらの各処理装置、 つまり ァライナ 1 2 2、 洗浄'乾燥装置 1 2 4及び前処理装置 1 2 6のほぼ中心に位置 して、 これらの各処理装置 1 2 2 , 1 2 4 , 1 2 6、 前記基板脱着台 1 6 2及び 前記ロード.アンロードポート 1 2 0に搭載した基板カセットとの間で基板の搬 送と受渡しを行う第 1搬送ロボット 1 2 8が配置されている。  Inside the clean space 114, there is an aligner 122 that aligns the orientation of the board, such as the orientation flat and the notch, in a predetermined direction, and a board that cleans the plated board and spins it by rotating it at a high speed. Apparatus 124 and pretreatment of the substrate, in this example, by spraying pure water on the surface of the substrate (the surface to be covered), the substrate surface is washed with pure water and wetted with pure water. Pretreatment device for pre-washing with water to improve hydrophilicity 1 2 6 force It is located at its four corners. Furthermore, each of these processing units, that is, the aligner 122, the cleaning / drying unit 124, and the pre-processing unit 126 is located substantially at the center, and each of these processing units 122, 124, 1 26, a first transfer robot 128 for transferring and transferring a substrate between the substrate loading / unloading port 120 and the substrate cassette mounted on the load / unload port 120 is provided.
ここで、 清浄空間 1 1 4内に配置されたァライナ 1 2 2、 洗浄'乾燥装置 1 2 4及び前処理装置 1 2 6は、 表面を上向きにした水平姿勢で基板を保持して処理 するようになつており、 搬送ロボット 1 28は、 表面を上向きにした水平姿勢で 基板を保持して基板の搬送及び受渡しを行うようになっている。 Here, the aligner 1 2 2, the cleaning / drying device 1 2 4, and the pre-processing device 1 2 6 placed in the clean space 1 1 4 hold the substrate in a horizontal position with the surface facing upward and process it. The transfer robot 128 transfers and transfers the substrate while holding the substrate in a horizontal posture with the surface facing upward.
めっき空間 1 1 6内には、 仕切板 1 1 2側から順に、 基板ホルダ 1 60の保管 及び一時仮置きを行うストツ力 1 64、 例えば基板の表面に形成したシード層表 面の電気抵抗の大きい酸化膜を硫酸や塩酸などの薬液でエッチング除去する活 性化処理装置 1 66、 基板の表面を純水で水洗する第 1水洗装置 1 68 a、 めつ き処理を行うめっき装置 1 70、 第 2水洗装置 1 68 b及びめつき処理後の基板 の水切りを行うブロー装置 1 72が順に配置されている。 そして、 これらの装置 の側方に位置して、 2台の第 2搬送ロボット 1 74 a , 1 74 bがレール 1 76 に沿って走行自在に配置されている。 この一方の第 2搬送ロボット 1 74 aは、 基板脱着台 1 6 2とストツ力 1 64との間で基板ホルダ 1 60の搬送を行い、 他 方の第 2搬送ロボット 1 74 bは、 ストッカ 1 64、 活性化処理装置 1 66、 第 1水洗装置 1 68 a、 めっき装置 1 70、 第 2水洗装置 1 68 b及びブロー装置 1 72の間で基板ホルダ 1 60の搬送を行う。  In the plating space 1 16, in order from the partition plate 1 12 side, a stop force 1 64 for storing and temporarily placing the substrate holder 160, for example, the electric resistance of the surface of the seed layer formed on the surface of the substrate. Activator 166 for etching and removing large oxide films with chemicals such as sulfuric acid and hydrochloric acid, 1st rinsing unit 168a for rinsing the surface of the substrate with pure water, plating unit 1170 for plating, A second rinsing device 168b and a blow device 172 for draining the substrate after the plating process are arranged in this order. Further, two second transfer robots 174a and 174b are arranged to be able to travel along the rail 176 at the side of these devices. One of the second transfer robots 174a transfers the substrate holder 160 between the substrate attaching / detaching table 162 and the stock force 164, and the other second transfer robot 174b controls the stocker 1 The substrate holder 160 is transferred between the activation device 166, the first washing device 168a, the plating device 170, the second washing device 168b, and the blowing device 172.
この第 2搬送ロボット 1 74 a , 1 74 bは、 図 2に示すように、 鉛直方向に 延びるボディ 1 78と、 このボディ 1 78に沿って上下動自在でかつ軸心を中心 に回転自在なアーム 1 80を備えており、 このアーム 1 80に、 基板ホルダ 1 6 0を自在に着脱保持する基板ホルダ保持部 1 8 2が 2個並列に備えられている。 ここで、 基板ホルダ 1 60は、 表面を露出させ周縁部をシールした状態で基板 W を保持し、 基板 Wを自在に着脱するように構成されている。  As shown in FIG. 2, the second transfer robots 174a and 174b include a vertically extending body 178, a vertically movable body 178, and a rotatable shaft. An arm 180 is provided. The arm 180 is provided with two substrate holder holding portions 182 for freely attaching and detaching and holding the substrate holder 160. Here, the substrate holder 160 is configured to hold the substrate W in a state where the surface is exposed and the peripheral edge is sealed, and the substrate W is freely attached and detached.
ストッカ 1 64、 活性化処理装置 1 66、 水洗装置 1 6 8 a, 1 68 b及びめ つき装置 1 70は、 基板ホルダ 1 60の両端部に設けた外方に突出する突出部 1 60 aを引っ掛けて、 基板ホルダ 1 60を鉛直方向に吊り下げた状態で支持する ようになつている。 そして、 活性化処理装置 1 66には、 内部に薬液を保持する 2個の活性化処理槽 1 8 3が備えられ、 図 2に示すように、 基板 Wを装着した基 板ホルダ 1 6 0を鉛直状態で保持した第 2搬送ロボット 1 74 bのアーム 1 8 0を下降させ、 必要に応じて、 基板ホルダ 1 60を活性化処理槽 1 8 3の上端部 に引っ掛けて吊下げ支持することで、 基板ホルダ 1 6 0を基板 Wごと活性化処理 槽 1 8 3内の薬液に浸漬させて活性化処理 行うように構成されている。 The stocker 164, the activation processing unit 166, the rinsing unit 168a, 168b and the mounting unit 170 are provided with the outwardly projecting projections 160a provided at both ends of the substrate holder 160. The substrate holder 160 is hung vertically to be supported by being hooked. The activation processing apparatus 166 is provided with two activation processing tanks 183 for holding a chemical solution therein. As shown in FIG. 2, a substrate holder 160 on which a substrate W is mounted is provided. Lower the arm 180 of the second transfer robot 174 b held in a vertical state, and if necessary, move the substrate holder 160 to the upper end of the activation processing tank 18 3 The substrate holder 160 is immersed in the chemical solution in the activation tank 183 together with the substrate W to perform the activation treatment by hanging and supporting the substrate holder.
同様に、 水洗装置 1 6 8 a , 1 6 8 bには、 内部に純水を保持した各 2個の水 洗槽 1 8 4 a , 1 8 4 1)カ、 めっき装置 1 7 0には、 内部にめっき液を保持した 複数のめっき槽 1 8 6がそれぞれ備えられ、 前述と同様に、 基板ホルダ 1 6 0を 基板 Wごとこれらの水洗槽 1 8 4 a , 1 8 4 b内の純水またはめつき槽 1 8 6内 のめつき液に浸漬させることで、 水洗処理やめつき処理が行われるように構成さ れている。 またブロー装置 1 7 2は、 基板 Wを装着した基板ホルダ 1 6 0を鉛直 状態で保持した第 2搬送ロボット 1 7 4 bのアーム 1 8 0を下降させ、 この基板 ホルダ 1 6 0に装着した基板 Wにエアーや不活性ガスを吹きかけ基板ホルダ 1 6 0および基板 Wに付着している液を吹きとばして水切りを行うことで、 基板の ブロー処理を行うように構成されている。  Similarly, the washing devices 1 668a and 1 668b have two washing tanks 1 84a and 1 8 4 1) each containing pure water inside, and the plating device 1 7 0 A plurality of plating tanks 186 each holding a plating solution therein are provided. As described above, the substrate holder 160 is mounted together with the substrate W on the pure water in these washing tanks 184a and 184b. By immersing it in water or the plating solution in plating bath 186, it is configured to perform water washing treatment and plating treatment. In addition, the blower 1 72 lowered the arm 180 of the second transfer robot 1 74 b holding the substrate holder 160 loaded with the substrate W in a vertical state, and mounted the substrate holder 160 The substrate W is configured to be blown by blowing air or an inert gas onto the substrate W to blow off the liquid adhering to the substrate holder 160 and the substrate W to drain the water.
めっき装置 1 7 0の各めつき槽 1 8 6は、 図 3及び図 4に示すように、 内部に めっき液 1 0を保持するように構成され、 このめつき液 1 0中に、 基板ホルダ 1 6 0で周縁部を水密的にシールし表面 (被めつき面) を露出させて保持した基板 Wを浸漬させて配置するようになっている。  As shown in FIGS. 3 and 4, each plating tank 1886 of the plating apparatus 17 is configured to hold a plating solution 10 therein, and the substrate holder is contained in the plating solution 10. In step 160, the periphery is sealed in a water-tight manner, and the substrate W held with the surface (covered surface) exposed is immersed and arranged.
めっき槽 1 8 6の両側方には、 このめつき槽 1 8 6の溢流堰 4 4の上端をォー バーフローしためっき液 1 0を流すオーバーフロー槽 4 6が設けられ、 このォー バーフロー槽 4 6とめつき槽 1 8 6とは循環配管 4 8で結ばれている。 そして、 この循環配管 4 8の内部に、 循環ポンプ 5 0、 恒温ュニット 5 2及びフィルタ 5 4が介装されている。 これによつて、 循環ポンプ 5 0の駆動に伴ってめっき槽 1 8 6内に供給されためつき液 1 0は、めっき槽 1 8 6の内部を満たし、 しかる後、 溢流堰 4 4からオーバーフローしてオーバーフロー槽 4 6内に流れ込み、 循環ポ ンプ 5 0に戻って循環するように構成されている。  On both sides of the plating tank 18 6, there is provided an overflow tank 46 for flowing the plating solution 10 which overflows the upper end of the overflow weir 44 of the plating tank 1 86. The flow tank 46 and the plating tank 18 6 are connected by a circulation pipe 48. A circulation pump 50, a constant temperature unit 52, and a filter 54 are provided inside the circulation pipe 48. As a result, the drip liquid 10 supplied to the plating tank 1886 as the circulation pump 50 is driven fills the inside of the plating tank 1886, and then overflows from the overflow weir 44. Then, it flows into the overflow tank 46 and returns to the circulation pump 50 for circulation.
めっき槽 1 8 6の内部には、 基板 Wの形状に沿った円形のアノード 5 6がァノ 一ドホルダ 5 8に保持されて垂直に設置され、 めっき槽 1 8 6内にめっき液 1 0 を満たした時に、 このめつき液 1 0中にアノード 5 6が浸漬されるようになって いる。 更に、 アノード 56と基板ホルダ 160との間に位置して、 めっき槽 18 6の内部をアノード側室 40 aと基板側室 40 bに仕切り、 めっき槽 186内に 保持されるめつき液 1 0をアノード側と基板側に遮断する調整板 60が設置さ れている。 Inside the plating tank 1886, a circular anode 56 conforming to the shape of the substrate W is held vertically by the anode holder 58, and is vertically installed, and the plating solution 10 is placed in the plating tank 1886. When filled, the anode 56 is immersed in this plating solution 10 I have. Further, the inside of the plating tank 186 is partitioned between the anode 56 and the substrate holder 160 to partition the inside of the plating tank 186 into an anode side chamber 40a and a substrate side chamber 40b, and the plating liquid 10 held in the plating tank 186 is supplied to the anode An adjustment plate 60 is installed on the side and the substrate side.
基板ホルダ 160と調整板 60の間には、 下方に垂下する複数のパドル 62を 備え、 このパドル 62が基板側室 40 b内のめっき液 10の内部に位置して、 基 板ホルダ 160で保持された基板 Wと平行に往復動することで、 基板側室 40 b 内のめっき液を攪拌するパドル型攪拌機構 64が配置されている。  A plurality of paddles 62 hanging downward are provided between the substrate holder 160 and the adjustment plate 60, and the paddles 62 are positioned inside the plating solution 10 in the substrate side chamber 40b and held by the substrate holder 160. A paddle-type stirring mechanism 64 that stirs the plating solution in the substrate side chamber 40 b by reciprocating in parallel with the substrate W is disposed.
調整板 60は、 例えば肉厚が 0. 5〜: L Omm程度で、 PVC, PP, PEE K, PES, HT-PVC, P F A, PTFE, その他の樹脂系材料からなる誘 電体から構成されている。 そして、 この調整板 60の内部の所定の領域、 すなわ ち基板 Wを基板ホルダ 160で保持してめっき槽 1 86内の所定のめっき位置 に配置した時に、 この基板 Wの表面と対面する領域のほぼ全域に亘り、 かつ基板 Wと相似形な円形領域内に、 多数の通孔 66からなる通孔群 68が設けられてい る。  The adjusting plate 60 has, for example, a thickness of about 0.5 to about L Omm and is made of a dielectric material made of PVC, PP, PEEK, PES, HT-PVC, PFA, PTFE, and other resin-based materials. I have. Then, a predetermined area inside the adjustment plate 60, that is, an area facing the surface of the substrate W when the substrate W is held by the substrate holder 160 and arranged at a predetermined plating position in the plating tank 186. A through-hole group 68 including a large number of through-holes 66 is provided in substantially the entire area of the substrate and in a circular region similar to the substrate W.
ここで、 この例では、 図 5に詳細に示すように、 スリット状に横方向に直線状 に延びる長穴によって通孔 66が構成され、 この通孔 (長穴) 66を基板 Wの外 形に沿った円形のB域内に直線状かつ並列に配置することで、 通孔群 68が構成 されている。 この通孔 (長穴) 66の幅は、 一般的には、 0. 5〜20mm程度 で、 1〜15mm程度が好ましく、 この長さは、 基板 Wの大きさ (直径) に合わ せて任意に設定される。  Here, in this example, as shown in detail in FIG. 5, a through hole 66 is formed by a slit-like elongated hole extending linearly in the horizontal direction, and the through hole (elongated hole) 66 is formed in the outer shape of the substrate W. The through-hole group 68 is configured by being arranged linearly and side-by-side in a circular area B along. The width of the through hole (slot) 66 is generally about 0.5 to 20 mm, preferably about 1 to 15 mm, and the length is arbitrary according to the size (diameter) of the substrate W. Is set to
このように、 調整板 60の内部に多数の通孔 66からなる通孔群 68を設け、 めっき処理の際に、 この各通孔 66内を電場が漏れ、 漏れた電場が均一に拡がる ようにすることで、 基板 Wの表面 (被めつき面) の全面に亘る電位分布をより均 —にして、 基板 Wの表面に形成される金属膜の面内均一性をより高めることがで きる。 また、 めっき液 10がめつき槽 186内に設置した調整板 60の内部に設 けた多数の通孔 66内を通過するのを抑制することで、 このめつき液 10の流れ (めっき液の戻り) による影響を受けて、 基板 Wの表面に形成される金属膜の膜 厚に不均一が生じることを防止することができる。 In this way, a through-hole group 68 including a large number of through-holes 66 is provided inside the adjustment plate 60, and during plating, an electric field leaks through each of the through-holes 66 so that the leaked electric field spreads evenly. By doing so, the potential distribution over the entire surface (covered surface) of the substrate W can be made more uniform, and the in-plane uniformity of the metal film formed on the surface of the substrate W can be further improved. In addition, by suppressing the plating solution 10 from passing through the many through holes 66 provided in the adjusting plate 60 provided in the plating tank 186, the flow of the plating solution 10 is reduced. It is possible to prevent the thickness of the metal film formed on the surface of the substrate W from being uneven due to the influence of (return of the plating solution).
特に、 通孔 6 6として、 スリット形状の長穴を使用することで、 この通孔 (長 穴) 6 6内のめっき液 1 0の流通を抑制しつつ、 電場の漏れを促進することがで きる。 更に、 調整板 6 0の基板 Wの表面と対面する領域のほぼ全域に亘り、 かつ 基板 Wと相似形な円形領域内に、 多数の通孔 6 6からなる通孔群 6 8を形成する ことで、 基板 Wの表面の全ての方向に対して良好な膜厚均一性を有する金属膜を 形成することができる。  In particular, by using a slit-shaped long hole as the through hole 66, it is possible to promote the leakage of the electric field while suppressing the flow of the plating solution 10 in the through hole (the long hole) 66. Wear. Further, a through-hole group 68 including a large number of through-holes 66 is formed over substantially the entire region of the adjustment plate 60 facing the surface of the substrate W and in a circular region similar to the substrate W. Thus, a metal film having good film thickness uniformity in all directions on the surface of the substrate W can be formed.
このめつき装置 1 7 0によれば、 先ず、 前述のようにして、 めっき槽 1 8 6の 内部にめっき液 1 0を満たし、 めっき液 1 0を循環させておく。 この状態で、 基 板 Wを保持した基板ホルダ 1 6 0を下降させて、 基板 Wをめつき槽 1 8 6内のめ つき液 1 0に浸漬した所定の位置に配置する。 この状態で、 導線 2 2 aを介して アノード 5 6をめつき電源 2 4の陽極に、 導線 2 2 bを介して基板 Wをめつき電 源 2 4の陰極にそれぞれ接続し、 同時にパドル型攪拌機構 6 4を駆動させ、 パド ル 6 2を基板 Wの表面に沿って往復動させて基板側室 4 0 b内のめっき液 1 0 を攪拌し、 これによつて、 基板 Wの表面に金属を析出させて金属膜を形成する。 この時、 前述のように、 調整板 6 0の内部に設けた多数の通孔 6 6内を電場が 漏れ、漏れた電場が均 に拡がるようにすることで、基板 Wの表面(被めつき面) の全面に亘る電位分布をより均一にして、 図 6に示すように、 基板 Wの表面に面 内均一性をより高めた金属膜 Pを形成することができる。 しかも、 基板 Wと調整 板 6 0との間のめっき液 1 0を、 めっき処理中にパドル 6 2によって攪拌するこ とで、 めっき液の流れに方向性をなくしながら、 十分なイオンを基板 Wの表面に より均一に供給して、 より均一な膜厚の金属膜をより迅速に形成することができ る。  According to the plating apparatus 170, first, the plating solution 10 is filled in the plating tank 186 and the plating solution 10 is circulated as described above. In this state, the substrate holder 160 holding the substrate W is lowered, and the substrate W is placed at a predetermined position where the substrate W is immersed in the plating liquid 10 in the plating tank 186. In this state, the anode 56 is connected to the anode of the power supply 24 via the conductor 22a, and the substrate W is connected to the cathode of the power supply 24 via the conductor 22b. By driving the stirring mechanism 64, the paddle 62 is reciprocated along the surface of the substrate W to stir the plating solution 10 in the substrate side chamber 40b. Is deposited to form a metal film. At this time, as described above, the electric field leaks through the many through holes 66 provided inside the adjustment plate 60, and the leaked electric field is spread evenly, so that the surface of the substrate W (covering By making the potential distribution over the entire surface (surface) more uniform, it is possible to form a metal film P with higher in-plane uniformity on the surface of the substrate W as shown in FIG. Moreover, by agitating the plating solution 10 between the substrate W and the adjustment plate 60 with the paddle 62 during the plating process, sufficient ions can be removed from the substrate W while losing directionality in the flow of the plating solution. The metal film having a more uniform thickness can be formed more quickly by supplying the material more uniformly to the surface.
そして、 めっき終了後、 めっき電源 2 4を基板 W及びアノード 5 6から切り離 し、 基板ホルダ 1 6 0を基板 Wごと引き上げて、 基板 Wの水洗及びリンス等の必 要な処理を行った後、 めっき後の基板 Wを次工程に搬送する。 このように構成しためっき処理設備による一連のバンプめつき処理を、 図 7を 更に参照して説明する。 先ず、 図 7 Aに示すように、 表面に給電層としてのシー ド層 5 0 0を成膜し、 このシード層 5 0 0の表面に、 例えば高さ Hが 2 0〜 1 2 0 μ mのレジスト 5 0 2を全面に塗布した後、 このレジスト 5 0 2の所定の位置 に、 例えば直径 が 2 0〜2 0 0 /z m程度の開口部 5 0 2 aを設けた基板 Wを その表面 (被めつき面) を上にした状態で基板カセットに収容し、 この基板カセ ットをロード .アンロードポート 1 2 0に搭載する。 Then, after the plating is completed, the plating power source 24 is separated from the substrate W and the anode 56, and the substrate holder 160 is pulled up together with the substrate W, and after performing necessary processing such as washing and rinsing the substrate W. Then, the substrate W after plating is transferred to the next process. A series of bump attachment processing by the plating equipment configured as described above will be described with further reference to FIG. First, as shown in FIG. 7A, a seed layer 500 as a power supply layer is formed on the surface, and the height H is, for example, 20 to 120 μm on the surface of the seed layer 500. After applying the resist 502 on the entire surface, a substrate W provided with an opening 502 a having a diameter of, for example, about 20 to 200 / zm at a predetermined position of the resist 502 is placed on the surface thereof. (Substrate facing up), put it in a substrate cassette, and mount this substrate cassette on the load / unload port 120.
このロード ·アンロードポート 1 2 0に搭載した基板カセットカ ら、 第 1搬送 ロボット 1 2 8で基板 Wを 1枚取出し、 ァライナ 1 2 2に載せてオリフラゃノッ チなどの位置を所定の方向に合わせる。 このァライナ 1 2 2で方向を合わせた基 板 Wを第 1搬送ロボット 1 2 8で前処理装置 1 2 6に搬送する。 そして、 この前 処理装置 1 2 6で、 前処理液に純水を使用した前処理 (水洗前処理) を施す。 一 方、 ス トッカ 1 6 4内に鉛直姿勢で保管されていた基板ホルダ 1 6 0を第 2搬送 ロボット 1 7 4 aで取出し、 これを 9 0 ° 回転させた水平状態にして基板脱着台 1 6 2に 2個並列に載置する。  From the substrate cassette mounted on the load / unload port 120, one substrate W is taken out by the first transfer robot 128, placed on the aligner 122, and the position of the orientation notch is set in a predetermined direction. Match. The substrate W aligned in the direction by the aligner 122 is transferred to the pretreatment device 126 by the first transfer robot 128. Then, in this pretreatment device 126, pretreatment using pure water as a pretreatment liquid (rinsing pretreatment) is performed. On the other hand, the substrate holder 160 stored in the vertical position in the stocker 164 is taken out by the second transfer robot 174a, and it is rotated 90 ° and placed in a horizontal state to remove the substrate 1 6 Place two in parallel on 2.
そして、 前述の前処理 (水洗前処理) を施した基板 Wをこの基板脱着台 1 6 2 に載置された基板ホルダ 1 6 0に周縁部をシールして装着する。 そして、 この基 板 Wを装着した基板ホルダ 1 6 0を第 2搬送ロボッ ト 1 7 4 aで 2基同時に把 持し、 上昇させた後、 ス トッカ 1 6 4まで搬送し、 9 0 ° 回転させて基板ホルダ 1 6 0を垂直な状態となし、 しかる後、 下降させ、 これによつて、 2基の基板ホ ルダ 1 6 0をストツ力 1 6 4に吊下げ保持 (仮置き) する。 これを順次繰り返し て、 ス トッカ 1 6 4内に収容された基板ホルダ 1 6 0に順次基板を装着し、 ス ト ッカ 1 6 4の所定の位置に順次吊り下げ保持 (仮置き) する。  Then, the substrate W that has been subjected to the above-described pre-treatment (washing pre-treatment) is mounted on the substrate holder 160 mounted on the substrate attaching / detaching table 16 2 with its peripheral edge sealed. Then, the two substrate holders 160 on which the substrate W is mounted are simultaneously held by the second transport robot 1774a, raised, and then transported to the stocker 1664, and rotated 90 °. Then, the substrate holder 160 is set in a vertical state, and then lowered, whereby the two substrate holders 160 are suspended and held (temporarily placed) by the stop force 164. This operation is sequentially repeated, and the substrates are sequentially mounted on the substrate holders 160 accommodated in the stockers 1664, and are sequentially suspended and held (temporarily placed) at predetermined positions of the stockers 1664.
一方、 第 2搬送ロボット 1 7 4 bにあっては、 基板を装着しストツ力 1 6 4に 仮置きした基板ホルダ 1 6 0を 2基同時に把持し、 上昇させた後、 活性化処理装 置 1 6 6に搬送し、 活性化処理槽 1 8 3に入れた硫酸や塩酸などの薬液に基板を 浸漬させてシード層表面の電気抵抗の大きい酸化膜をエッチングし、 清浄な金属 面を露出させる。 更に、 この基板を装着した基板ホルダ 1 6 0を、 前記と同様に して、 第 1水洗装置 1 6 8 aに搬送し、 この水洗槽 1 8 4 aに入れた純水で基板 の表面を水洗する。 On the other hand, in the case of the second transfer robot 174b, the two substrate holders 160, on which the substrates are mounted and temporarily placed at the stocking force 164, are simultaneously held, raised, and then activated. The substrate is immersed in a chemical solution such as sulfuric acid or hydrochloric acid placed in the activation treatment tank 18 3 to etch the oxide film with high electrical resistance on the surface of the seed layer, and clean metal Expose the surface. Further, the substrate holder 160 on which the substrate is mounted is transported to the first rinsing device 168a in the same manner as described above, and the surface of the substrate is rinsed with pure water in the rinsing tank 184a. Wash with water.
水洗が終了した基板を装着した基板ホルダ 1 6 0を、 前記と同様にしてめっき 装置 1 7 0に搬送し、 めっき槽 1 8 6内のめっき液 1 0に浸漬させた状態でめつ き槽 1 8 6に吊り下げ支持することで、 基板 Wの表面にめっき処理を施す。 そし て、 所定時間経過後、 基板を装着した基板ホルダ 1 6 0を第 2搬送ロボット 1 7 4 bで再度保持してめっき槽 1 8 6から引き上げてめっき処理を終了する。  The substrate holder 160 on which the rinsed substrate is mounted is transferred to the plating apparatus 170 in the same manner as described above, and the plating tank is immersed in the plating solution 10 in the plating tank 186. The surface of the substrate W is plated by suspending and supporting it on 186. Then, after a lapse of a predetermined time, the substrate holder 160 on which the substrate is mounted is again held by the second transfer robot 174b, pulled up from the plating tank 186, and the plating process is completed.
そして、 前述と同様にして、 基板ホルダ 1 6 0を第 2水洗装置 1 6 8 bまで搬 送し、 この水洗槽 1 8 4 bに入れた純水に浸漬させて基板の表面を純水洗浄する。 しかる後、 この基板を装着した基板ホルダ 1 6 0を、 前記と同様にして、 ブロー 装置 1 7 2に搬送し、 ここで、 不活性ガスやエアーを基板に向けて吹き付けて、 基板ホルダ 1 6 0に付着しためっき液や水滴を除去する。 しかる後、 この基板を 装着した基板ホルダ 1 6 0を、 前記と同様にして、 ストッカ 1 6 4の所定の位置 に戻して吊下げ保持する。  Then, in the same manner as described above, the substrate holder 160 is transported to the second washing device 1668b, and is immersed in pure water in the washing tank 1884b to clean the surface of the substrate with pure water. I do. Thereafter, the substrate holder 160 on which the substrate is mounted is conveyed to the blower 172 in the same manner as described above, where an inert gas or air is blown toward the substrate, and the substrate holder 16 Remove the plating solution and water droplets attached to 0. Thereafter, the substrate holder 160 on which the substrate is mounted is returned to a predetermined position of the stocker 164 and suspended and held in the same manner as described above.
第 2搬送ロボット 1 7 4 bは、 上記作業を順次繰り返し、 めっきが終了した基 板を装着した基板ホルダ 1 6 0を順次ストツ力 1 6 4の所定の位置に戻して吊 下げ保持する。  The second transfer robot 174 b sequentially repeats the above operation, and returns the substrate holder 160 on which the plated substrate is mounted to the predetermined position of the stop force 164 in order, and suspends the substrate holder.
一方、 第 2搬送ロボット 1 7 4 aにあっては、 めっき処理後の基板を装着しス トツ力 1 6 4に戻した基板ホルダ 1 6 0を 2基同時に把持し、 前記と同様にして、 基板脱着台 1 6 2上に載置する。  On the other hand, in the second transfer robot 1774a, two substrates holders 160, which have mounted the plated substrate and returned to the stocking force 1664, are simultaneously held, and in the same manner as described above, It is placed on the substrate mounting table 1 62.
そして、 清浄空間 1 1 4内に配置された第 1搬送ロボット 1 2 8は、 この基板 脱着台 1 6 2上に載置された基板ホルダ 1 6 0力 ら基板を取出し、 いずれかの洗 浄 ·乾燥装置 1 2 4に搬送する。 そして、 この洗浄 ·乾燥装置 1 2 4で、 表面を 上向きにして水平に保持した基板を、 純水等で洗浄し、 高速回転させてスピン乾 燥させた後、 この基板を第 1搬送ロボット 1 2 8でロード 'アンロードポート 1 2 0に搭載した基板カセットに戻して、 一連のめっき処理を完了する。 これによ り、 図 7 Bに示すように、 レジスト 5 0 2に設けた開口部 5 0 2 a内にめっき膜 5 0 4を成長させた基板 Wが得られる。 Then, the first transfer robot 128 disposed in the cleaning space 114 removes the substrate from the substrate holder 160 placed on the substrate mounting table 162, and cleans the substrate. · Conveyed to drying device 1 2 4 Then, the substrate held horizontally with its surface facing upwards is washed with pure water or the like by this washing / drying device 124 and spin-dried by high-speed rotation. Return to the substrate cassette mounted on the loading / unloading port 120 at 28 to complete a series of plating processes. This As a result, as shown in FIG. 7B, a substrate W having a plated film 504 grown in the opening 502 a provided in the resist 502 is obtained.
そして、 前述のようにしてスピン乾燥させた基板 Wを、 例えば温度が 5 0〜6 0 °Cのアセトン等の溶剤に浸漬させて、 図 7 Cに示すように、 基板 W上のレジス ト 5 0 2を剥離除去し、 更に図 7 Dに示すように、 めっき後の外部に露出する不 要となったシード層 5 0 0を除去する。 次に、 この基板 Wに形成しためっき膜 5 0 4をリフローさせることで、 図 7 Eに示すように、 表面張力で丸くなつたバン プ 5 0 6を形成する。 更に、 この基板 Wを、 例えば、 1 0 0 °C以上の温度でァニ 一ノレし、 バンプ 5 0 6内の残留応力を除去する。  Then, the substrate W spin-dried as described above is immersed in a solvent such as acetone at a temperature of 50 to 60 ° C., for example, and a resist 5 on the substrate W is formed as shown in FIG. 7C. Then, as shown in FIG. 7D, unnecessary seed layer 500 exposed outside after plating is removed. Next, the plating film 504 formed on the substrate W is reflowed to form a bump 506 which is rounded by surface tension as shown in FIG. 7E. Further, the substrate W is subjected to annealing at a temperature of, for example, 100 ° C. or more to remove residual stress in the bumps 506.
この例によれば、 めっき空間 1 1 6内での基板の受渡しをめつき空間 1 1 6内 に配置した第 2搬送ロボット 1 7 4 a , 1 7 4 bで、 清浄空間 1 1 4内での基板 の受渡しを該清浄空間 1 1 4内に配置した第 1搬送ロボット 1 2 8でそれぞれ 行うことで、 基板の前処理、 めっき処理及びめつきの後処理の全めつき工程を連 続して行うめっき処理装置の内部における基板周りの清浄度を向上させるとと もに、 めっき処理装置としてのスループットを向上させ、 更にめつき処理装置の 付帯設備の負荷を軽減して、 めっき処理装置としてのより小型化を図ることがで きる。  According to this example, the transfer of the substrate in the plating space 1 16 is performed by the second transfer robots 17 4 a and 17 4 b arranged in the mounting space 1 16 in the clean space 1 14. The first transfer robot 1 28 arranged in the clean space 114 transfers the substrates of the respective substrates, thereby continuously performing the pre-processing of the substrate, the plating process, and the post-processing of the plating. In addition to improving the cleanliness around the substrate inside the plating equipment, the throughput of the plating equipment is improved, and the load on the auxiliary equipment of the plating equipment is further reduced. The size can be further reduced.
この例にあっては、 めっき処理を行うめっき装置 1 7 0として、 フットプリン トの小さいめっき槽 1 8 6を有するものを使用することで、 多数のめっき槽 1 8 6を有するめっき装置の更なる小型化を図るとともに、 工場付帯設備負荷をより 軽減することができる。 なお、 図 1において 2台設置されている洗浄 ·乾燥装置 1 2 4の一方を、 前処理装置に置き換えてもよい。  In this example, a plating apparatus having a small footprint and having a plating tank 186 is used as the plating apparatus 170 for performing the plating process. In addition to miniaturization, it is possible to further reduce the load on facilities attached to factories. In FIG. 1, one of the two washing / drying devices 124 installed may be replaced with a pretreatment device.
図 8乃至図 1 9は、 調整板 6 0における多数の通孔からなる通孔群のそれぞれ 異なる例を示す。 すなわち、 図 8は、 スリツト状に縦方向に直線状に延びる長穴 によって通孔 6 6 aを構成し、 この通孔 (長穴) 6 6 aを基板 Wの外形に沿った 円形の領域内に直線状かつ並列に配置することで、 通孔群 6 8 aを構成したもの である。 図 9は、 基板 Wとして、 矩形状のものを使用する場合に適するように、 通孔 (長穴) 6 6 bを基板 Wの外形に沿った矩形状の領域内に直線状かつ並列に 配置して通孔群 6 8 bを構成したものである。 8 to 19 show different examples of the through-hole group including a large number of through-holes in the adjustment plate 60. FIG. That is, in FIG. 8, a through hole 66a is formed by a slit-shaped elongated hole extending linearly in the vertical direction, and the through hole (slot) 66a is formed in a circular area along the outer shape of the substrate W. The through-hole group 68a is configured by arranging them in a straight line and in parallel. Fig. 9 shows the case where a rectangular substrate is used as the substrate W. The through-holes (slots) 66 b are arranged linearly and in parallel in a rectangular area along the outer shape of the substrate W to form a through-hole group 68 b.
図 1 0は、 調整板 6 0の基板 Wの表面に対面する領域のほぼ全幅に亘つて、 ス リット状に直線状に延びる長孔からなる複数の通孔 (長孔) 6 6 cで通孔群 6 8 cを構成したものである。 この場合も、 基板 Wとして、 矩形状のものを使用する 場合には、 図 1 1に示すように、 通孔 (長穴) 6 6 dを基板 Wの外形に沿った矩 形状の領域内に並列に配置して通孔群 6 8 dを構成してもよい。 また、 図示しな いが、 これらの通孔 6 6 dが縦方向に直線状に延びるようにしてもよい。  FIG. 10 shows a plurality of through-holes (slots) 66 c formed of slits extending linearly over almost the entire width of a region of the adjustment plate 60 facing the surface of the substrate W. A hole group 68 c is formed. Also in this case, when a rectangular shape is used as the substrate W, the through hole (slot) 66 d is placed in a rectangular area along the outer shape of the substrate W as shown in FIG. The through-hole group 68 d may be arranged in parallel. Although not shown, these through holes 66d may extend linearly in the vertical direction.
図 1 2は、縦及び横方向に十字状に延びる十字穴からなる複数の通孔(十字穴) 6 6 eを円形領域内に均等に配置して通孔群 6 8 eを構成したものである。 この 場合も、基板 Wとして、矩形状のものを使用する場合には、図 1 3に示すように、 通孔 (十字穴) 6 6 f を基板 Wの外形に沿った矩形状の領域内に均等に配置して 通孔群 6 8 f を構成してもよレ、。  Fig. 12 shows a configuration in which a plurality of through-holes (cross-shaped holes) 66 e composed of cross-shaped holes extending in a cross shape in the vertical and horizontal directions are equally arranged in a circular area to form a through-hole group 68 e. is there. Also in this case, when a rectangular substrate is used as the substrate W, the through hole (cross-shaped hole) 66 f should be placed in the rectangular area along the outer shape of the substrate W as shown in FIG. The holes may be evenly arranged to form a through hole group 6 8 f.
図 1 4は、 細孔からなる複数の通孔 (細孔) 6 6 gを円形領域内に均等に分布 させて通孔群 6 8 gを構成したものである。この各通孔(細孔) 6 6 gの直径は、 この例では 2 mmに設定され、 図示の例では、 合計 6 3 3個設けられている。 こ の通孔 6 6 g、 更には下記の小孔 (周辺孔) 6 6 h 2〜6 6 h 5の直径は、 例えば 1〜2 O mmの範囲で任意に設定されるが、 2〜 1 0 mm程度が好ましい。 この ように、 通孔 (細孔) 6 6 gで通孔群 6 8 gを構成することで、 調整板 6 0の生 産性を向上させることができる。 Fig. 14 shows a group of 68 g of through-holes in which 66 g of a plurality of through-holes (pores) are evenly distributed in a circular region. The diameter of each through-hole (pore) 66 g is set to 2 mm in this example, and a total of 633 is provided in the example shown. The diameter of the through hole 66 g and the following small holes (peripheral holes) 66 h 2 to 66 h 5 are arbitrarily set, for example, in the range of 1 to 2 O mm. About 0 mm is preferable. In this way, by forming 66 g of the through-holes (pores) into 68 g of the through-hole group, the productivity of the adjusting plate 60 can be improved.
図 1 5は、 径の異なる複数の孔、 すなわち中央部に位置する大径の大孔 (中央 孔) 6 6 1^と、 この大孔 6 6 1^の外方に円周方向に沿って配置され、 直径方向 に行くに従って径が小さくなる複数列 (図示では 4列) の小孔 (周辺孔) 6 6 h 2 ~ 6 6 h 5からなる複数の通孔 6 6 hで通孔群 6 8 hを構成したものである。 こ の大孔 (中央孔) 6 6 1^の直径は、 この例では 8 4 mmに設定されているが、 例えば 5 0〜3 0 O mmの範囲で任意に設定され、 3 0〜1 0 O mm程度が好ま しい。 また、 小孔 (周辺孔) 6 6 h 2〜6 6 h cの直径は、 1 0 mm, 8 mm, 7 mm及び 6 mmにそれぞれ設定されている。 Figure 15 shows multiple holes with different diameters, that is, a large-diameter large hole (center hole) 6 6 1 ^ located at the center, and the outer periphery of the large hole 6 6 1 ^ along the circumferential direction. Plural rows (four rows in the figure) of small holes (peripheral holes) that are arranged and decrease in diameter as they go in the diameter direction 6 6 h 2 to 66 h 5 8 h. The diameter of this large hole (center hole) 66 1 ^ is set to 84 mm in this example, but is set arbitrarily in the range of 50 to 30 O mm, for example, to 30 to 10 0 mm. O mm is preferable. The diameter of the small holes (peripheral holes) 6 6 h 2 ~6 6 h c is, 1 0 mm, 8 mm, 7 mm and 6 mm respectively.
図 1 6は、 中央に位置する中央孔 6 6 i iと、 この中央孔 6 6 i の外方に配置 された、 複数列 (図示では 5列) の円周方向に延びる長孔 6 6 i 2〜66 i 6から なる複数の通孔 66 iで通孔群 6 8 iを構成したものである。 この中央孔 66 i 丄の直径は、 この例では、 34 mmに設定され、 長孔 66 i 2〜6 6 i 6の幅は、 2 7mm, 1 8. 5mm, 7 mm, 7 mm, 7 mmにそれぞれ設定されている。 図 1 7は、 中央部に位置する大径の大孔 (中央孔) 66 j iと、 この中央孔 6 6 j iの外方に円周方向に沿って配置された、 円周方向に延びる長孔 6 6 j 2と、 この長孔 66 j 2の外方に配置された、 直径方向に行くに従って径が小さくなる 複数列 (図示では 4列) の小孔 (周辺孔) 66 j 3〜66 j 6からなる複数の通孔 66 jで通孔群 68 jを構成したものである。 この大孔 (中央孔) 66 j iの直 径は、 この例では 6 7 mmに、 長孔 6 6 j 2の幅は 1 7 mmに、 小孔 (周辺孔) 66 j 3〜66 j 6の直径は、 9mm, 8mm, 7mm, 6mmにそれぞれ設定さ れている。 1 6 has a center hole 6 6 ii centrally located, the center hole 6 disposed outside the 6 i, a plurality of rows (in the illustrated five rows) extending in the circumferential direction of the slot 6 6 i 2 a plurality of through holes 66 i consisting of -66 i 6 is obtained by constituting the through hole groups 6 8 i. The diameter of the central hole 66 i丄, in this example, is set to 34 mm, the width of the slot 66 i 2 ~6 6 i 6 is, 2 7mm, 1 8. 5mm, 7 mm, 7 mm, 7 mm Are set respectively. Figure 17 shows a large-diameter large hole (central hole) 66ji located at the center, and a circumferentially extending long hole arranged outside the central hole 66ji along the circumferential direction. 6 6 and j 2, this is located outside of the long hole 66 j 2, small holes (peripheral holes) of a plurality of rows which diameter decreases toward the diameter direction (four rows in the figure) 66 j 3 -66 j A through hole group 68 j is constituted by a plurality of through holes 66 j composed of six . The diameter of the large hole (center hole) 66 ji is 67 mm in this example, the width of the long hole 66 j 2 is 17 mm, and the small hole (peripheral hole) 66 j 3 to 66 j 6 The diameters are set at 9mm, 8mm, 7mm and 6mm respectively.
図 1 8は、 中央部に位置する大径の大孔 (中央孔) 661^と、 この中央孔 6 6 kェの外方に円周方向に沿って配置された、 円周方向に延びる複数列 (図示で は 2列) の長孔 66 k 2, 66 k 3, この長孔 6 6 k 3の外方に配置された、 直径 方向に行くに従って径が小さくなる複数列 (図示では 2列) の小孔 (周辺孔) 6 6 k4, 66 k5からなる複数の通孔 6 6 kで通孔群 6 8 kを構成したものである。 この大孔 (中央孔) 66 k iの直径は、 この例では 80mmに、 長孔 66 k 2, 6 6 k 3の幅は 7 mmに、 小孔 (周辺孔) 66 k4, 66 k5の直径は、 6 mmと 4 mmにそれぞれ設定されている。 Figure 18 shows a large-diameter large hole (central hole) 661 ^ located at the center and a plurality of circumferentially extending holes arranged outside the central hole 66k along the circumferential direction. column long hole 66 k 2 of (in the illustrated two rows), 66 k 3, this is located outside of the slot 6 6 k 3, two rows in the plurality of rows (illustrated diameter decreases toward the diameter direction ) in which small holes (peripheral holes) constitute 6 6 k 4, 66 k plurality of through holes 6 6 k by passing hole group 6 8 k consisting of 5. The diameter of the large hole (center hole) 66 ki is 80 mm in this example, the width of the long holes 66 k 2 and 66 k 3 is 7 mm, and the small holes (peripheral holes) 66 k 4 and 66 k 5 The diameters are set at 6 mm and 4 mm, respectively.
図 1 9は、 中央に位置する大径の大孔 (中央孔) 6 6 1 iと、 この中央孔 66 1 iの外方に円周方向に沿った所定のピッチで配置された、 半径方向に直線状に 延びる複数のスリット状の長孔 66 1 2からなる複数の通孔 66 1で通孔群 68 1を構成したものである。 この長孔 66 1 2の幅は、 一般的には 0. 5〜20m m程度であり、 1〜1 5mm程度であることが好ましい。 また、 長さは、 被めつ き体の形状により任意に設定される。 Fig. 19 shows a large-diameter large hole (center hole) 661i located at the center, and a radially arranged outside the center hole 661i at a predetermined pitch along the circumferential direction. it is obtained by constituting the through hole groups 68 1 by a plurality of through holes 66 1 including a plurality of slit-like long holes 66 1 2 extending linearly in. The width of the long hole 66 1 2 is generally on the order of 0. 5 to 20 m m, is preferably about 1 to 1 5 mm. Also, the length is It is set arbitrarily according to the shape of the body.
このように、 複数の細孔、 径の異なる複数の孔またはスリット状に延びる長穴 等の任意の形状の複数の通孔を組合せて通孔群を構成することで、 めっきする場 所や条件等の任意の要求に合うようにすることができる。  By combining a plurality of through-holes of any shape, such as a plurality of fine holes, a plurality of holes having different diameters, or a long hole extending in a slit shape, a through-hole group is formed, thereby providing a plating place and conditions. And so on.
なお、 前述の図 14〜図 1 9に示す例では、 通孔を円形領域の内部に配置して 通孔群を形成した例を示しているが、 前述と同様に、 基板として、 矩形状のもの を使用する場合には、 これらの通孔を基板の外形に沿った矩形状の領域内に配置 して通孔群を構成してもよいことは勿論である。  In the examples shown in FIGS. 14 to 19 described above, the through holes are arranged inside the circular region to form a group of through holes. However, as described above, a rectangular substrate is used as the substrate. When the through holes are used, it is a matter of course that these through holes may be arranged in a rectangular area along the outer shape of the substrate to form a through hole group.
以上説明したように、 本発明によれば、 めっき槽内に設置した調整板の内部に 設けた多数の通孔内を電場が漏れ、 漏れた電場が均一に拡がるようにすることで、 被めつき体の全面に亘る電位分布をより均一にして、被めつき体に形成される金 属膜の面内均一性をより高めることができる。 また、 めっき液がめっき槽内に設 置した調整板の内部に設けた多数の通孔内を通過するのを抑制することで、 この めっき液の流れにより影響を受けて、 被めつき体に形成される金属膜の膜厚に不 均一が生じることを防止することができる。  As described above, according to the present invention, the electric field leaks through a large number of through-holes provided inside the adjustment plate installed in the plating tank, and the leaked electric field is uniformly spread, so that the covering is performed. By making the potential distribution over the entire surface of the attached body more uniform, the in-plane uniformity of the metal film formed on the attached body can be further improved. Also, by suppressing the plating solution from passing through a large number of through holes provided inside the adjustment plate installed in the plating tank, the plating solution is affected by the flow of the plating solution, and Nonuniformity in the thickness of the formed metal film can be prevented.
図 20は、本発明の他の実施の形態におけるめっき装置 1 70 aを、図 21は、 このめつき装置 170 aに使用されている調整板及びめつき液流路を形成する 円筒体をそれぞれ示す。 このめつき装置 170 aの図 3乃至図 5に示す例と異な る点は、調整板 60として、例えば肉厚が 0. 5〜 1 Omm程度で、その中央に、 基板ホルダ 160で保持した基板 Wに対向し該基板 Wの外径に見合った内径 D の中央孔 60 aを有するものを使用し、 更に、 この調整板 60の基板ホルダ 16 0側表面に、 内径が前述の中央孔 60 aの内径 Dと等しい円筒体 200を同心状 に連続させて連結し、 これによつて、 この円筒体 200の内周面に、 電場を均一 に通過させつつめっき液 10を流通させるめっき液流路 200 aを形成した点 にある。 この円筒体 200は、 調整板 60と同様に、 例えば P VC, P P, PE EK, PES, HT-PVC, P FA, PTFE, その他の樹脂系材料からなる 誘電体から構成されている。 その他の構成は、 図 3乃至図 5に示すものと同様で ある。 FIG. 20 shows a plating apparatus 170a according to another embodiment of the present invention, and FIG. 21 shows an adjusting plate and a cylindrical body forming a plating liquid flow path used in the plating apparatus 170a. Show. The difference from the example shown in FIGS. 3 to 5 of this plating device 170 a is that the adjusting plate 60 has a thickness of, for example, about 0.5 to 1 Omm and a substrate held by a substrate holder 160 at the center thereof. A central hole 60a having an inner diameter D facing the outer diameter of the substrate W and facing the W is used. A cylindrical body 200 equal to the inner diameter D of the cylindrical body 200 is connected concentrically and continuously, whereby the plating solution flow path through which the plating solution 10 flows through the inner peripheral surface of the cylindrical body 200 while allowing the electric field to pass uniformly. This is the point that formed 200a. This cylindrical body 200 is made of a dielectric material made of, for example, PVC, PP, PEEK, PES, HT-PVC, PFA, PTFE, and other resin-based materials, similarly to the adjustment plate 60. Other configurations are the same as those shown in FIGS. is there.
ここで、 調整板 6 0の中央孔及び円筒体 2 0 0の内径 Dは、 一般には、 基板 W のめつきされる表面の外径 (被めつき表面外径) と等しい径 ± 1 0 mm、 好まし くは、 被めつき表面外径と等しい径 ± 5 mm、 より好ましくは、 被めつき表面外 径と等しい径 ± l mm程度に設定されている。 また、 円筒体 2 0 0の長さ Lは、 めっき槽 1 8 6の形状、 アノード 5 6と基板 Wの距離等により適当に定められる 1S 一般的には、 1 0〜9 0 mm、 好ましくは、 2 0〜 7 5 mm、 更に好ましく は、 3 0〜6 O mmである。  Here, the central hole of the adjusting plate 60 and the inner diameter D of the cylindrical body 200 are generally equal to the outer diameter of the surface of the substrate W to be plated (the outer diameter of the surface to be covered) ± 10 mm. Preferably, the diameter is set to about ± 5 mm, which is equal to the outer diameter of the covering surface, and more preferably, about ± 1 mm, which is equal to the outer diameter of the covering surface. The length L of the cylindrical body 200 is appropriately determined by the shape of the plating tank 1886, the distance between the anode 56 and the substrate W, etc.1S In general, 10 to 90 mm, preferably , 20 to 75 mm, more preferably 30 to 60 mm.
このように、 めっき槽 1 8 6内でアノード 5 6と基板 Wの間に形成される電場 がめつき液流路 2 0 0 aに沿って、 つまり、 円筒体 2 0 0の内部を該円筒体 2 0 0の外部に漏れることなく均一に通過するようにすることで、 電場の歪みや偏り を調整かつ修正し、 基板 Wの表面全面に亘る電位分布をより均一にして、 図 2 2 に示すように、基板 Wの表面に、基板 Wのエッジ部でやや膜厚が厚くなるものの、 面内均一性をより高めた金属膜 Pを形成することができる。  As described above, the electric field formed between the anode 56 and the substrate W in the plating tank 1886 is arranged along the liquid flow path 200a, that is, the inside of the cylindrical body 200 is formed by the cylindrical body. By making it pass uniformly without leaking out of 200, the distortion and bias of the electric field are adjusted and corrected, and the potential distribution over the entire surface of the substrate W is made more uniform, as shown in Fig. 22. As described above, on the surface of the substrate W, it is possible to form the metal film P with slightly increased in-plane uniformity, although the film thickness is slightly increased at the edge of the substrate W.
つまり、 内部に中央孔 6 0 aを設けた調整板 6 0のみでは、 この調整板 6 0の 肉厚は、 一般に 0 . 5〜 1 0 mm程度と一般に薄く、 このため、 めっき槽 1 8 6 内でアノード 5 6と基板 Wの間に形成される電場の調整板 6 0のみによる規制 が不十分となって、 電場に歪みや偏りが生じ、 特に受電部である基板のエッジ部 の膜厚が厚くなる傾向があるが、 この例のように、 円筒体 2 0 0の長さ Lに亘っ て、 電場の通過を規制することで、 このような弊害を防止して、 金属膜の面内均 一性を高めることができる。  In other words, the thickness of the adjusting plate 60 is generally as thin as about 0.5 to 10 mm with only the adjusting plate 60 having the central hole 60a therein. The regulation of the electric field formed between the anode 56 and the substrate W by the adjustment plate 60 alone is insufficient, causing distortion and bias in the electric field, especially the film thickness at the edge of the substrate that is the power receiving part. However, as shown in this example, by restricting the passage of an electric field over the length L of the cylindrical body 200, such an adverse effect can be prevented and the in-plane surface of the metal film can be prevented. Uniformity can be improved.
なお、 この例では、 前述の図 3乃至図 5に示す例と同様に、 円筒体 2 0 0と基 板ホルダ 1 6 0で保持した基板 Wとの間に、 下方に垂下する複数のパドル 6 2を 備えたパドル型攪拌機構 6 4を配置し、 めっき中に、 パドル型攪袢機構 6 4を駆 動させ、 パドル 6 2を基板 Wの表面に沿って往復動させて基板側室 4 0 b内のめ つき液 1 0を攪拌することで、 めっき液の流れに方向性をなくしながら、 十分な ィオンを基板 Wの表面により均一に供給して、 より均一な膜厚の金属膜をより迅 速に形成することができるようにしている。 In this example, similarly to the examples shown in FIGS. 3 to 5 described above, a plurality of paddles 6 hanging down between the cylindrical body 200 and the substrate W held by the substrate holder 160 are provided. A paddle-type stirring mechanism 64 equipped with a paddle-type stirring mechanism 64 is disposed.During plating, the paddle-type stirring mechanism 64 is driven to reciprocate the paddle 62 along the surface of the substrate W, and the substrate side chamber 40 b By stirring the plating solution 10 inside, a sufficient ion is supplied more evenly to the surface of the substrate W while the direction of the plating solution flow is lost, and a metal film having a more uniform film thickness is more quickly formed. It can be formed quickly.
図 2 3は、 本発明の更に他の実施の形態におけるめっき装置 1 7 O bを示す。 このめつき装置 1 7 0 bの図 2 1及び図 2 2に示す例と異なる点は、 円筒体 2 0 0と基板ホルダ 1 6 0で保持した基板 Wとの間に、 パドル型攪拌機構 6 4の代わ りに、 めっき液噴射型攪拌機構 2 0 2を配置した点にある。 つまり、 このめつき 液噴射型攪拌機構 2 0 2は、 例えばリング状のパイプからなり、 循環配管 4 8と 連通しめつき槽 1 8 6のめつき液 1 0内に浸漬させて配置されるめつき液供給 管 2 0 4と、 このめつき液供給管 2 0 4の円周方向に沿った所定位置に取付けら れて、 めっき液 1 0を基板ホルダ 1 6◦で保持した基板 Wに向けて噴射する複数 のめつき液噴射ノズル 2 0 6とを有している。 そして、 ポンプ 5 0の駆動に伴つ て送られるめっき液 1 0は、 めっき液供給管 2 0 4に供給され、 めっき液噴射ノ ズル 2 0 6から基板に向けて噴射されてめつき槽 1 8 6内に導入され、 更に溢流 堰 4 4の上端をオーバーフローして循環するようになっている。  FIG. 23 shows a plating apparatus 17 Ob according to still another embodiment of the present invention. The difference from the example shown in FIGS. 21 and 22 of this plating device 170 b is that a paddle-type stirring mechanism 6 is provided between the cylindrical body 200 and the substrate W held by the substrate holder 160. 4 in that a plating solution jetting type stirring mechanism 202 is provided instead of 4. In other words, the plating liquid injection type stirring mechanism 202 is formed of, for example, a ring-shaped pipe, communicates with the circulation pipe 48, and is immersed in the plating liquid 10 of the plating tank 1886. Attached solution supply pipe 204 and this plating liquid supply pipe 204 are attached at predetermined positions along the circumferential direction, and are directed to substrate W holding plating solution 10 with substrate holder 16 °. And a plurality of plating liquid jet nozzles 206 for jetting. Then, the plating solution 10 sent with the driving of the pump 50 is supplied to the plating solution supply pipe 204, and is sprayed from the plating solution spray nozzle 206 toward the substrate, so that the plating tank 1. It is introduced into 86, and overflows at the upper end of the overflow weir 44 to circulate.
このように、 複数のめっき液噴射ノズノレ 2 0 6から基板 Wに向けてめっき液 1 0を噴射することで、 めっき槽 1 8 6内のめっき液 1 0を攪拌してめっき液濃度 を均一にすると同時に、 基板 Wにめつき液 1 0の各成分を十分に供給して、 より 均一な膜厚の金属膜をより迅速に形成することができる  In this way, by spraying the plating solution 10 from the plurality of plating solution spray nozzles 206 toward the substrate W, the plating solution 10 in the plating tank 186 is stirred to make the plating solution concentration uniform. At the same time, the components of the plating liquid 10 are sufficiently supplied to the substrate W, and a metal film having a more uniform film thickness can be formed more quickly.
なお、 前述の例では、 調整板 6 0の基板 W側表面に円筒体 2 0 0を連結するよ うにした例を示している力 図 2 4に示すように、 調整板 6 0に嵌着孔 6 0 bを 設け、 内径 D、 長さ で、 内周面をめつき液流路 2 0 0 aとした円筒体 2 0 0を 該嵌着孔 6 0 b内に嵌着して、 円筒体 2 0 0の長さ方向に沿った所定に位置で円 筒体 2 0 0を保持するようにしてもよい。 これにより、 調整板 6 0 とノ、"ドノレ 6 2 (図 2 0参照) やめつき液供給管 2 0 4 (図 2 3参照) との距離が短い場合にあ つても、 円筒体 2 0 0を調整板 6 0の後方に突出させることで、 円筒体 2 0 0と しての十分な長さ Lを確保するようにすることができる。  In the above-described example, a force is shown in which the cylindrical body 200 is connected to the surface of the adjustment plate 60 on the substrate W side. As shown in FIG. 24, a fitting hole is formed in the adjustment plate 60. A cylindrical body 200 having an inner diameter D and a length of 200 b and having a liquid flow path 200 a was fitted in the fitting hole 60 b, and a cylindrical body was provided. The cylindrical body 200 may be held at a predetermined position along the length direction of 200. As a result, even when the distance between the adjusting plate 60 and the “Donore 62” (see FIG. 20) and the attachment liquid supply pipe 204 (see FIG. 23) is short, the cylindrical body 200 can be used. By projecting the rear side of the adjusting plate 60, a sufficient length L as the cylindrical body 200 can be secured.
また、 図 2 5に示すように、 円筒体 2 0 0の周壁に、 電場の漏れを防止する大 きさの多数の通孔 2 0 0 bを設けるようにしてもよい。 これにより、 電場の漏れ を防止しつつ、 円筒体 200の周壁に設けた通孔 200 b内をめつき液 10が流 通するようにすることで、 円筒体 200の内外でめっき液 10の濃度に偏りが生 じてしまうことを防止することができる。 この通孔の形状としては、 この例の細 孔の他に。 スリット形状の長穴、 縦横に延びる十字穴、 更にはこれらの組合せが 挙げられる。 Further, as shown in FIG. 25, a large number of through holes 200b large enough to prevent electric field leakage may be provided on the peripheral wall of the cylindrical body 200. This results in electric field leakage The plating solution 10 flows through the through hole 200b provided in the peripheral wall of the cylindrical body 200 while preventing the plating solution 200 from flowing, so that the concentration of the plating solution 10 is biased inside and outside the cylindrical body 200. Can be prevented. The shape of this through-hole may be other than that of this example. Examples include a slit-shaped long hole, a cross hole extending vertically and horizontally, and a combination thereof.
更に、図 26に示すように、十分な肉厚を有する板体で調整板 210を構成し、 この調整板 210の所定の位置に所定の内径の貫通孔を設け、 この貫通孔で、 所 定の内径 Dで所定の長さ Lを有するめっき液流路 2 10 aを形成するようにし てもよレ、。 この例の場合、 部材点数を減少させることができる。  Further, as shown in FIG. 26, the adjusting plate 210 is formed of a plate having a sufficient thickness, and a through hole having a predetermined inner diameter is provided at a predetermined position of the adjusting plate 210. A plating solution flow path 210a having a predetermined length L with an inner diameter D of the plating solution may be formed. In the case of this example, the number of members can be reduced.
また、図 27に示すように、十分な肉厚を有する矩形ブロック 212を用意し、 この矩形ブロック 21 2に設けた貫通孔によって、 所定の内径 Dで所定の長さ L を有するめっき液流路 210 aを形成し、 この矩形ブロック 212を、 中央孔 6 0 aを有する調整板 60の基板 W側表面に連結するようにしてもよい。  Further, as shown in FIG. 27, a rectangular block 212 having a sufficient thickness is prepared, and a plating solution flow path having a predetermined inner diameter D and a predetermined length L is formed by a through hole provided in the rectangular block 212. 210a may be formed, and this rectangular block 212 may be connected to the substrate W side surface of the adjusting plate 60 having the central hole 60a.
図 28は、 本発明の更に他の実施の形態におけるめっき装置 1 70 cを、 図 2 9は、 図 28に示すめっき装置 170 cに使用されている調整板、 めっき液流路 を形成する円筒体及び電場調整リングを示す。 このめつき装置 170 cの図 20 及び図 21に示す例と異なる点は、 以下の通りである。 すなわち、 内周面にめつ き液流路 2 O O aを形成した円筒体 200の基板 W側端面に、 円筒体 200の内 径 Dと等しい内径で、 幅 Aの電場調整リング 220を同心状に取付けて、 この電 場調整リング 220を、 基板 Wと隙間 G 1をもって基板 Wに近接させて配置して いる。 更に、 下方に垂下し、 基板ホルダ 160で保持された基板 Wと平行に往復 動することでめっき液を攪拌する複数のパドル 62を備えたパドル型攪拌機構 64を、 ァノード側室 40 a側のアノード 56と調整板 60との間に配置し、 こ のパドル型攪拌機構 64でアノード側室 40 a内のめっき液 10を攪拌するよ うにしている。 その他の構成は、 図 20及び図 21に示す例と同様である。  FIG. 28 shows a plating apparatus 170c according to still another embodiment of the present invention. FIG. 29 shows an adjustment plate and a cylinder forming a plating solution flow path used in the plating apparatus 170c shown in FIG. 2 shows the body and the electric field adjustment ring. The differences between the mounting device 170c and the example shown in FIGS. 20 and 21 are as follows. That is, an electric field adjusting ring 220 having an inner diameter equal to the inner diameter D of the cylindrical body 200 and having a width A is concentrically formed on the end face of the substrate W side of the cylindrical body 200 having the liquid flow path 2 OOa formed on the inner peripheral surface. The electric field adjustment ring 220 is disposed close to the substrate W with a gap G1 from the substrate W. Further, a paddle-type stirring mechanism 64 having a plurality of paddles 62 that drop downward and reciprocate in parallel with the substrate W held by the substrate holder 160 to stir the plating solution is connected to the anode side chamber 40a side anode. The plating solution 10 in the anode-side chamber 40a is agitated by the paddle-type agitation mechanism 64, which is disposed between the adjustment plate 60 and the adjustment plate 60. Other configurations are the same as the examples shown in FIGS. 20 and 21.
ここで、 電場調整リング 220は、 調整板 60や円筒体 200と同様に、 例え ば PVC, P P, PEEK, PES, HT— PVC, PFA, PTFE, その他 の樹脂系材料からなる誘電体から構成されている。 電場調整リング 2 2 0の形状 は、 めっき槽 1 8 6や基板 Wの形状、 アノード 5 6と基板 W間の間隔等により適 当に設定されるが、 その幅 Aは、 一般的には、 l〜2 0 mm、 好ましくは、 3〜 1 7 mm, 更に好ましくは、 5〜1 5 mmに設定される。 また、 電場調整リング 2 2 0と基板 Wとの隙間 G 1は、 一般には、 0 . 5〜3 O mm、 好ましくは、 1 〜1 5 mm、 更に好ましくは、 1 . 5〜6 mmに設定される。 Here, the electric field adjusting ring 220 is made of, for example, PVC, PP, PEEK, PES, HT—PVC, PFA, PTFE, or the like, similarly to the adjusting plate 60 or the cylindrical body 200. Of a resin-based material. The shape of the electric field adjusting ring 220 is appropriately set depending on the shape of the plating tank 1886 and the substrate W, the distance between the anode 56 and the substrate W, etc., and the width A is generally It is set to l to 20 mm, preferably 3 to 17 mm, and more preferably 5 to 15 mm. The gap G1 between the electric field adjusting ring 220 and the substrate W is generally set to 0.5 to 3 O mm, preferably to 1 to 15 mm, and more preferably to 1.5 to 6 mm. Is done.
この電場調整リング 2 2 0は、 基板 Wの外周部を近接した位置で所定の幅で覆 つて、 この基板 Wの外周部の電場を調整するためのものである。 このように、 基 板 Wの外周部の電場を電場調整リング 2 2 0で調整することで、 アノード 5 6と 基板 Wの間に形成される電場を基板 Wの全面に亘つてより均一に、 つまり受電部 である基板 Wのエッジ部までより均一化して、 図 3 0に示すように、 基板 Wの表 面に、 基板 Wのエッジ部を含め、 面内均一性をより高めた金属膜 Pを形成するこ とができる。  This electric field adjusting ring 220 is for adjusting the electric field of the outer peripheral portion of the substrate W by covering the outer peripheral portion of the substrate W with a predetermined width at a position close thereto. As described above, by adjusting the electric field at the outer peripheral portion of the substrate W with the electric field adjusting ring 220, the electric field formed between the anode 56 and the substrate W can be more uniformly spread over the entire surface of the substrate W. In other words, the metal film P is further uniformized up to the edge of the substrate W, which is the power receiving unit, and the surface of the substrate W, including the edge of the substrate W, is further enhanced in-plane uniformity as shown in FIG. Can be formed.
図 3 1は、 本発明の更に他の実施の形態におけるめっき装置 1 7 0 dを示す。 このめつき装置 1 7 0 dは、 アノード側室 4 0 aのアノード 5 6と調整板 6 0と の間に、 図 2 8及び図 2 9に示すめっき装置におけるパドル型攪拌機構 6 4の代 わりに、 図 2 3に示すめっき液噴射型攪拌機構 2 0 2を配置したものである。 つ まり、 この例は、 ポンプ 5 0の駆動に伴って送られるめっき液 1 0をめつき液供 給管 2 0 4に供給し、 めっき液噴射ノズル 2 0 6から円筒体 2 0 0のめつき液流 路 2 0 0 aに向けて噴射してめっき槽 1 8 6内に導入し、 更に溢流堰 4 4の上端 をオーバーフローさせて循環させるようになつている。 その他の構成は、 図 2 8 及び図 2 9に示すものと同様である。  FIG. 31 shows a plating apparatus 170 d according to still another embodiment of the present invention. This plating device 170 d is provided between the anode 56 of the anode side chamber 40 a and the adjusting plate 60 instead of the paddle type stirring mechanism 64 in the plating device shown in FIGS. 28 and 29. A plating solution jet type stirring mechanism 202 shown in FIG. 23 is disposed. In other words, in this example, the plating solution 10 sent along with the driving of the pump 50 is supplied to the plating solution supply pipe 204, and the plating solution injection nozzle 206 and the cylindrical body 200 are supplied. The liquid is sprayed toward the associated liquid flow path 200a, introduced into the plating tank 186, and further circulated by overflowing the upper end of the overflow weir 44. Other configurations are the same as those shown in FIGS. 28 and 29.
このように、 めっき液噴射型攪拌機構 2 0 2をアノード側室 4 0 aに配置し、 めっき液をめつき液噴射ノズル 2 0 6から円筒体 2 0 0のめつき液流路 2 0 0 aに向けて噴射することで、 電場調整リング 2 2 0と基板ホルダ 1 6 0で保持し た基板 Wとの隙間 G 1が狭い場合にあっても、 このめつき液流路 2 0 0 aを通し て、 めっき液を基板ホルダ 1 6 0で保持した基板 Wに向けて供給することができ る。 In this way, the plating solution spray type stirring mechanism 202 is disposed in the anode side chamber 40a, and the plating solution is sprayed from the plating solution spray nozzle 206 to the cylindrical body 200 through the plating solution flow path 200a. When the gap G 1 between the electric field adjustment ring 220 and the substrate W held by the substrate holder 160 is narrow, the liquid flow path 200 a The plating solution can be supplied to the substrate W held by the substrate holder 160 You.
ここで、 図 3 2に示すように、 前述の図 2 4に示す場合とほぼ同様に、 調整板 6 0に嵌着孔 6 0 bを設け、 内径 D、 長さ Lで、 内周面をめつき液流路 2 0 0 a として端部に電場調整リング 2 2 0を取付けた円筒体 2 0 0を該嵌着孔 6 0 b 内に嵌着して、 円筒体 2 0 0の長さ方向に沿った所定に位置で円筒体 2 0 0を保 持するようにしてもよい。  Here, as shown in FIG. 32, almost the same as the case shown in FIG. 24 described above, a fitting hole 60 b is provided in the adjustment plate 60, the inner diameter D, the length L, and the inner peripheral surface A cylindrical body 200 having an electric field adjusting ring 220 attached to the end as an attachment liquid flow path 200a is fitted into the fitting hole 60b, and the length of the cylindrical body 200 The cylindrical body 200 may be held at a predetermined position along the direction.
また、 図 3 3に示すように、 前述の図 2 5に示す場合とほぼ同様に、 端面に電 場調整リング 2 2 0を取付けた円筒体 2 0 0の周壁に、 電場の漏れを防止する大 きさの多数の通孔 2 0 0 bを設けて、 電場の漏れを防止しつつ、 円筒体 2 0 0の 周壁に設けた通孔 2 0 0 b内をめつき液 1 0が流通するようにしてもよい。  In addition, as shown in FIG. 33, almost the same as the case shown in FIG. 25 described above, the electric field is prevented from leaking to the peripheral wall of the cylindrical body 200 having the electric field adjusting ring 220 attached to the end face. A large number of large through holes 200b are provided to prevent leakage of the electric field, and the liquid 10 flows through the inside of the through holes 200b provided in the peripheral wall of the cylindrical body 200. You may do so.
更に、 図 3 4に示すように、 電場調整リング 2 2 0を円筒体 2 0 0の端面に固 着することなく、 サポート 2 2 2で支持して、 円筒体 2 0 0の基板 W側端面の前 方に該基板 Wと隙間 G 2をもって配置するようにしてもよい。 この隙間 G 2は、 前述の電場調整リング 2 2 0と基板 Wとの隙間 G 1と同様に、 一般には、 0 . 5 〜 3 O mm、 好ましくは、 1〜 1 5 mm、 更に好ましくは、 1 . 5〜6 mmに設 定される。 このように、 めっき液流路 2 0 0 aを構成すると円筒体 2 0 0と電場 調整リング 2 2 0とを分離させることで、 選択の幅を拡げることができる。  Further, as shown in FIG. 34, the electric field adjusting ring 220 is supported by the support 222 without being fixed to the end face of the cylindrical body 200, and the end face of the cylindrical body 200 on the substrate W side is provided. May be arranged with the gap G2 in front of the substrate W. This gap G2 is generally 0.5 to 3 O mm, preferably 1 to 15 mm, and more preferably, similarly to the gap G1 between the electric field adjustment ring 220 and the substrate W. Set to 1.5 to 6 mm. As described above, when the plating solution flow path 200a is configured, the selection range can be expanded by separating the cylindrical body 200 and the electric field adjustment ring 220.
また、図 3 5に示すように、十分な肉厚を有する厚肉リング 2 2 4の内周面で、 所定の内径 D及び長さ Lを有するめっき液流路 2 2 4 aを構成し、 この厚肉リン グ 2 2 4の基板側端面で所定の幅 Aを有する電場調整リング 2 2 4 bを構成す るようにしてもよレ、。 これにより、 部品点数を削減することができる。  Further, as shown in FIG. 35, a plating solution flow path 2 24 a having a predetermined inner diameter D and a length L is formed on the inner peripheral surface of the thick ring 22 4 having a sufficient thickness, The electric field adjusting ring 222b having a predetermined width A may be formed on the end face of the thick ring 222 on the substrate side. Thereby, the number of parts can be reduced.
なお、 前述の各例にあっては、 いわゆるディップ方式を採用しためっき装置に 適用した例を示しているが、 フェースダウン方式やフェースアップ方式を採用し ためつき装置にも適用することができる。  In each of the above-described examples, an example is shown in which the present invention is applied to a plating apparatus employing a so-called dip method. However, the present invention can also be applied to a face-down type or face-up type employing a drilling apparatus.
図 3 6は、 フェースダウン方式を採用しためっき装置に適用した例を示す。 こ の例は、 図 3 7に示す従来のめっき装置に以下の構成を付加している。 つまり、 めっき槽 1 2の上部に、 内部に中央孔 2 3 0 aを有する調整板 2 3 0を配置して、 めっき槽 1 2の内部をアノード側室 1 2 aと基板側室 1 2 bに遮断し、 更に、 調 整板 2 3 0の上面に、 この中央孔 2 3 0 aと同じ内径でめっき液流路 2 3 2 aを 形成する内周面を有する円筒体 2 3 2を同心状に上方に突出させて取付けてい る。 これによつて、 めっき槽 1 2内でアノード 1 6と基板 Wの間に形成される電 場がめっき液流路 2 3 2 aに沿って、 つまり、 円筒体 2 3 2の内部を該円筒体 2 3 2の外部に漏れることなく均一に通過するようにすることで、 電場の歪みや偏 りを調整かつ修正し、 基板 Wの表面全面に亘る電位分布をより均一にすることが できる。 Fig. 36 shows an example in which the present invention is applied to a plating apparatus employing the face-down method. In this example, the following configuration is added to the conventional plating apparatus shown in FIG. In other words, an adjustment plate 230 having a central hole 230a therein is disposed above the plating tank 12 and The inside of the plating tank 12 is shut off to the anode side chamber 12a and the substrate side chamber 12b, and the plating solution flow path 2 is formed on the upper surface of the adjusting plate 230 with the same inner diameter as the central hole 230a. A cylindrical body 2332 having an inner peripheral surface forming 32a is mounted concentrically so as to protrude upward. As a result, an electric field formed between the anode 16 and the substrate W in the plating tank 12 is formed along the plating solution flow path 23a, that is, the inside of the cylindrical body 23 is formed by the cylindrical body. By allowing the electric field to pass uniformly without leaking to the outside of the body 232, the electric field can be adjusted and corrected for distortion and deviation, and the electric potential distribution over the entire surface of the substrate W can be made more uniform.
なお、 円筒体の上端面に、 円筒体の内径と等しい内径で、 所定の幅を有する電 場調整リングを同心状に取付け、 この電場調整リングで、 基板 Wの外周部を近接 した位置で所定の幅で覆って、 この基板 wの外周部の電場を調整し、 これによつ て、 アノードと基板の間に形成される電場を受電部である基板のェッジ部までよ り均一化して、 基板の表面に、 基板のエッジ部を含め、 面内均一性をより高めた 金属膜を形成するようにしてもよいことは勿論である。  An electric field adjustment ring having an inner diameter equal to the inner diameter of the cylindrical body and having a predetermined width is concentrically attached to the upper end surface of the cylindrical body. To adjust the electric field at the outer peripheral portion of the substrate w, thereby making the electric field formed between the anode and the substrate more uniform up to the wedge portion of the substrate as the power receiving portion. It is a matter of course that a metal film having higher in-plane uniformity may be formed on the surface of the substrate, including the edge portion of the substrate.

Claims

請求の範囲 The scope of the claims
1 . めっき液を保持するめつき槽と、 1. A plating bath for holding the plating solution,
前記めつき槽内のめっき液に浸漬させて設置されるアノードと、  An anode installed by being immersed in a plating solution in the plating tank;
前記アノードと該アノードと対向するように配置される被めつき体との間に 設置される調整板と、  An adjusting plate installed between the anode and a cladding body arranged to face the anode;
前記アノードと被めつき体との間に通電してめつきを行うめっき電源とを有 し、  A plating power supply for performing plating by energizing between the anode and the body to be plated;
前記調整板は、 前記めつき槽内に保持されるめっき液を前記ァノ一ド側と被め つき体側に遮断するように設置され、 内部に多数の通孔からなる通孔群が設けら れていることを特徴とするめつき装置。  The adjusting plate is installed so as to block the plating solution held in the plating tank between the anode side and the covering body side, and a through hole group including a large number of through holes is provided therein. A mounting device characterized in that it is mounted.
2 . 前記通孔群は、 スリット状に一方向に直線状または円弧状に延びる複数の長 穴からなることを特徴とする請求項 1記載のめっき装置。 2. The plating apparatus according to claim 1, wherein the through-hole group includes a plurality of elongated holes extending linearly or arcuately in one direction in a slit shape.
3 . 前記通孔群は、 縦及び横方向に十字状に延びる複数の十字穴からなることを 特徴とする請求項 1記載のめっき装置。 3. The plating apparatus according to claim 1, wherein the through hole group includes a plurality of cross holes extending in a cross shape in the vertical and horizontal directions.
4 . 前記通孔群は、 複数の細孔、 径の異なる複数の孔またはスリット状に延びる 長穴の任意の組合せからなることを特徴とする請求項 1記載のめっき装置。 4. The plating apparatus according to claim 1, wherein the through-hole group is composed of an arbitrary combination of a plurality of pores, a plurality of holes having different diameters, or slits extending in a slit shape.
5 . 前記通孔群は、 前記調整板の前記被めつき体と対面する領域のほぼ全域に亘 り該被めつき体と略相似形の領域内に形成されていることを特徴とする請求項 1記載のめっき装置。 5. The through-hole group is formed in a region substantially similar to the covered body over substantially the entire area of the adjustment plate facing the covered body. Item 1. The plating apparatus according to item 1.
6 . 前記被めつき体と前記調整板との間に、 前記めつき槽で保持しためっき液を 攪拌する攪拌機構を有することを特徴とする請求項 1記載のめっき装置。 6. The plating apparatus according to claim 1, further comprising a stirring mechanism for stirring the plating solution held in the plating tank, between the adherend and the adjustment plate.
7 . 前記攪拌機構は、 前記被めつき体と平行に往復運動をするパドルを有するパ ドル型攪拌機構であることを特徴とする請求項 6記載のめっき装置。 7. The plating apparatus according to claim 6, wherein the stirring mechanism is a paddle-type stirring mechanism having a paddle that reciprocates in parallel with the covering body.
8 . 前記アノード及び前記調整板は、 鉛直方向に設置されていることを特徴とす る請求項 1記載のめっき装賡。 8. The plating apparatus according to claim 1, wherein the anode and the adjustment plate are installed in a vertical direction.
9 . めっき液を保持するめつき槽と、 9. A plating bath for holding the plating solution,
前記めつき槽内のめっき液に浸漬させて設置されるアノードと、  An anode installed by being immersed in a plating solution in the plating tank;
前記アノードと該アノードと対向するように配置される被めつき体との間に 設置される調整板と、  An adjusting plate installed between the anode and a cladding body arranged to face the anode;
前記アノードと被めつき体との間に通電してめつきを行うめっき電源とを有 し、  A plating power supply for performing plating by energizing between the anode and the body to be plated;
前記調整板は、 前記めつき槽内に保持されるめつき液を前記アノード側と被め つき体側に遮断するように設置され、 内部に電場を均一に通過させつつめっき液 を流通させるめっき液流路が設けられていることを特徴とするめつき装置。  The adjusting plate is provided so as to block the plating solution held in the plating tank between the anode side and the covering body side, and allows the plating solution to flow while uniformly passing an electric field therein. A plating device comprising a flow path.
1 0 . 前記めつき液流路の長さは、 1 0〜 9 O mmに設定されていることを特徴 とする請求項 9記載のめっき装置。 10. The plating apparatus according to claim 9, wherein the length of the plating liquid flow path is set to 10 to 9 O mm.
1 1 . 前記めつき液流路は、 筒状体または矩形ブロックの内周面に形成されてい ることを特徴とする請求項 9記載のめっき装置。 11. The plating apparatus according to claim 9, wherein the plating liquid flow path is formed on an inner peripheral surface of a cylindrical body or a rectangular block.
1 2 . 前記筒状体の周壁には、 電場の漏れを防止する大きさの多数の通孔が設け られていることを特徴とする請求項 1 1記載のめっき装置。 12. The plating apparatus according to claim 11, wherein a plurality of through-holes having a size for preventing leakage of an electric field are provided in a peripheral wall of the cylindrical body.
1 3 . 前記被めつき体と前記調整板との間または前記力ソードと前記調整板との 間の少なくとも一方には、 前記めつき槽で保持しためっき液を攪拌する攪拌機構 を有することを特徴とする請求項 9記載のめっき装置。 13. At least one of between the adhered body and the adjusting plate or between the force sword and the adjusting plate has a stirring mechanism for stirring the plating solution held in the plating tank. The plating apparatus according to claim 9, wherein
1 4 . 前記攪拌機構は、 前記被めつき体と平行に往復運動をするパドルを有する パドル型攪拌機構であることを特徴とする請求項 1 3記載のめっき装置。 14. The plating apparatus according to claim 13, wherein the stirring mechanism is a paddle-type stirring mechanism having a paddle that reciprocates in parallel with the covering body.
1 5 . 前記攪拌機構は、 前記被めつき体の方向に向けてめっき液を噴射する複数 のめつき液噴射ノズルを有するめっき液噴射型攪拌機構であることを特徴とす る請求項 1 3記載のめっき装置。 15. The stirring mechanism according to claim 13, wherein the stirring mechanism is a plating solution spraying type stirring mechanism having a plurality of plating solution spray nozzles for spraying a plating solution toward the body to be covered. The plating apparatus described in the above.
1 6 . 前記めつき液流路は、 前記調整板の内部に該調整板と一体に設けられてい ることを特徴とする請求項 1 3記載のめっき装置。 16. The plating apparatus according to claim 13, wherein the plating liquid flow path is provided integrally with the adjustment plate inside the adjustment plate.
1 7 . めっき液を保持するめつき槽と、 1 7. A plating bath for holding the plating solution,
前記めつき槽内のめっき液に浸漬させて設置されるアノードと、  An anode installed by being immersed in a plating solution in the plating tank;
前記アノードと該アノードと対向するように配置される被めつき体との間に、 前記めつき槽内に保持されるめっき液を前記アノード側と被めつき体側に遮断 するように設置され、 内部に電場を均一に通過させつつめっき液を流通させるめ つき液流路が設けられ調整板と、  A plating solution held in the plating tank is disposed between the anode and the plating object disposed so as to face the anode, so as to block the plating solution between the anode side and the plating object side, An adjusting plate provided with a plating liquid flow path through which the plating solution flows while allowing the electric field to uniformly pass therethrough,
前記アノードと被めつき体との間に通電してめつきを行うめっき電源と、 前記めつき液流路の前記被めつき体側端部に位置して該被めっき体の外周部 の電場を調整する電場調整リングとを有することを特徴とするめつき装置。  A plating power supply for performing plating by energizing between the anode and the body to be plated; and an electric field at an outer peripheral portion of the body to be plated which is located at an end of the plating liquid flow path on the side of the body to be plated. An electric field adjusting ring for adjusting the electric field.
1 8 . 前記電場調整リングの幅は、 1〜2 O mmに設定されていることを特徴と する請求項 1 7記載のめっき装置。 18. The plating apparatus according to claim 17, wherein the width of the electric field adjustment ring is set to 1 to 2 O mm.
1 9 . 前記電場調整リングと前記被めつき体との隙間は、 0 . 5〜3 O mmに設 定されていることを特徴とする請求項 1 7記載のめっき装置。 19. The plating apparatus according to claim 17, wherein a gap between the electric field adjusting ring and the covering body is set to 0.5 to 3 Omm.
2 0 .前記めつき液流路は、筒状体の内周面に形成され、前記電場調整リングは、 該筒状体の被めつき体側端部に連結されていることを特徴とする請求項 1 7記 載のめっき装置。 20. The plating liquid flow path is formed on an inner peripheral surface of a tubular body, and the electric field adjusting ring is connected to an end of the tubular body that is attached to the tubular body. Plating equipment described in Item 17.
2 1 . 前記筒状体の周壁には、 電場の漏れを防止する大きさの多数の通孔が設け られていることを特徴とする請求項 2 0記載のめっき装置。 21. The plating apparatus according to claim 20, wherein a plurality of through-holes having a size for preventing leakage of an electric field are provided in a peripheral wall of the cylindrical body.
2 2 .前記めつき液流路は、筒状体の内周面に形成され、前記電場調整リングは、 該筒状体の被めつき体側端部に該筒状体と分離して配置されていることを特徴 とする請求項 1 7記載のめっき装置。 22.The plating liquid flow path is formed on the inner peripheral surface of the cylindrical body, and the electric field adjustment ring is arranged separately from the cylindrical body at an end of the cylindrical body to be covered. The plating apparatus according to claim 17, characterized in that:
2 3 .前記めつき液流路は、筒状体の内周面に形成され、前記電場調整リングは、 該筒状体の被めつき体側端面に形成されていることを特徴とする請求項 1 7記 載のめっき装置。 23. The plating liquid flow path is formed on an inner peripheral surface of a cylindrical body, and the electric field adjusting ring is formed on an end surface of the cylindrical body that is covered with the body. 17 The plating equipment described in 7.
2 4 . 前記被めつき体と前記調整板との間または前記力ソードと前記調整板との 間の少なくとも一方には、 前記めつき槽で保持しためっき液を攪拌する攪拌機構 を有することを特徴とする請求項 1 7記載のめっき装置。 24. At least one of between the adhered body and the adjustment plate or between the force sword and the adjustment plate has a stirring mechanism for stirring the plating solution held in the plating tank. The plating apparatus according to claim 17, characterized in that:
2 5 . 前記攪拌機構は、 前記被めつき体と平行に往復運動をするパドルを有する パドル型攪拌機構であることを特徴とする請求項 2 4記載のめっき装置。 25. The plating apparatus according to claim 24, wherein the stirring mechanism is a paddle-type stirring mechanism having a paddle that reciprocates in parallel with the covering body.
2 6 . 前記攪拌機構は、 前記被めつき体の方向に向けてめっき液を噴射する複数 のめつき液噴射ノズルを有するめっき液噴射型攪拌機構であることを特徴とす る請求項 2 4記載のめっき装置。 26. The stirring mechanism according to claim 24, wherein the stirring mechanism is a plating solution spraying type stirring mechanism having a plurality of plating solution spray nozzles for spraying a plating solution toward the direction of the body to be covered. The plating apparatus described in the above.
PCT/JP2003/009144 2002-07-18 2003-07-18 Plating device WO2004009879A1 (en)

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