WO2000017141A1 - Verfahren zur herstellung von hochreinem monoethylenglykol - Google Patents

Verfahren zur herstellung von hochreinem monoethylenglykol Download PDF

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Publication number
WO2000017141A1
WO2000017141A1 PCT/EP1999/006968 EP9906968W WO0017141A1 WO 2000017141 A1 WO2000017141 A1 WO 2000017141A1 EP 9906968 W EP9906968 W EP 9906968W WO 0017141 A1 WO0017141 A1 WO 0017141A1
Authority
WO
WIPO (PCT)
Prior art keywords
column
monoethylene glycol
stream
dewatering
pressure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1999/006968
Other languages
German (de)
English (en)
French (fr)
Inventor
Gerhard Theis
Till Adrian
Bernd Bessling
Hans Hasse
Frans Vansant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP99969405A priority Critical patent/EP1115682B1/de
Priority to JP2000574053A priority patent/JP4427190B2/ja
Priority to US09/787,616 priority patent/US6605192B1/en
Priority to UA2001042717A priority patent/UA60383C2/uk
Priority to CA002345053A priority patent/CA2345053C/en
Priority to BRPI9913889-1A priority patent/BR9913889B1/pt
Priority to AU59801/99A priority patent/AU5980199A/en
Priority to PL99347580A priority patent/PL195588B1/pl
Priority to AT99969405T priority patent/ATE255084T1/de
Priority to DE59907884T priority patent/DE59907884D1/de
Publication of WO2000017141A1 publication Critical patent/WO2000017141A1/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S203/00—Distillation: processes, separatory
    • Y10S203/20—Power plant

Definitions

  • the bottom product of the second vacuum dewatering column is largely anhydrous glycol; it is fed to the monoethylene glycol distillation.
  • the bottom temperatures in the vacuum dewatering column (s) should as a rule not exceed 220 ° C., preferably 120 ° C. to 200 ° C., particularly preferably 160 ° C. to 180 ° C.
  • the discharge of secondary components in addition to the discharge in vacuum dewatering, is improved in the pressure dewatering stage.
  • the pressure dewatering column or at least the first pressure dewatering column of the cascade with at least one stripping section a separation stage, preferably 2 to 10 separation stages, particularly preferably equipped with 3 to 6 stages, part of the top stream of the dewatering column (s) being discharged with stripping section.
  • FIG. 2 shows a diagram of a particularly preferred method for obtaining glycol according to the invention
  • Figure 4 shows an embodiment of a method according to the invention with a pressure dewatering column with stripping section and an outlet for secondary components as a top stream and subsequent concentration in a partial condenser and a stripper.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
PCT/EP1999/006968 1998-09-23 1999-09-21 Verfahren zur herstellung von hochreinem monoethylenglykol Ceased WO2000017141A1 (de)

Priority Applications (10)

Application Number Priority Date Filing Date Title
EP99969405A EP1115682B1 (de) 1998-09-23 1999-09-21 Verfahren zur herstellung von hochreinem monoethylenglykol
JP2000574053A JP4427190B2 (ja) 1998-09-23 1999-09-21 高濃度モノエチレングリコールの製造方法
US09/787,616 US6605192B1 (en) 1998-09-23 1999-09-21 Method for producing highly pure monoethylene glycol
UA2001042717A UA60383C2 (uk) 1998-09-23 1999-09-21 Спосіб одержання високочистого моноетиленгліколю
CA002345053A CA2345053C (en) 1998-09-23 1999-09-21 Method for producing highly pure monoethylene glycol
BRPI9913889-1A BR9913889B1 (pt) 1998-09-23 1999-09-21 processo para a recuperação por destilação de monoetileno glicol de alta pureza.
AU59801/99A AU5980199A (en) 1998-09-23 1999-09-21 Method for producing highly pure monoethylene glycol
PL99347580A PL195588B1 (pl) 1998-09-23 1999-09-21 Sposób destylacyjnego odzyskiwania glikolu monoetylenowego o wysokiej czystości
AT99969405T ATE255084T1 (de) 1998-09-23 1999-09-21 Verfahren zur herstellung von hochreinem monoethylenglykol
DE59907884T DE59907884D1 (de) 1998-09-23 1999-09-21 Verfahren zur herstellung von hochreinem monoethylenglykol

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19843697.1 1998-09-23
DE19843697A DE19843697A1 (de) 1998-09-23 1998-09-23 Verfahren zur Herstellung von hochreinem Monoethylenglykol

Publications (1)

Publication Number Publication Date
WO2000017141A1 true WO2000017141A1 (de) 2000-03-30

Family

ID=7882020

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1999/006968 Ceased WO2000017141A1 (de) 1998-09-23 1999-09-21 Verfahren zur herstellung von hochreinem monoethylenglykol

Country Status (19)

Country Link
US (1) US6605192B1 (https=)
EP (1) EP1115682B1 (https=)
JP (1) JP4427190B2 (https=)
KR (1) KR100611284B1 (https=)
CN (1) CN1217898C (https=)
AR (1) AR020655A1 (https=)
AT (1) ATE255084T1 (https=)
AU (1) AU5980199A (https=)
BR (1) BR9913889B1 (https=)
CA (1) CA2345053C (https=)
DE (2) DE19843697A1 (https=)
ES (1) ES2212671T3 (https=)
MY (1) MY121383A (https=)
PL (1) PL195588B1 (https=)
RU (1) RU2235710C2 (https=)
SA (1) SA99200783B1 (https=)
TW (1) TW475925B (https=)
UA (1) UA60383C2 (https=)
WO (1) WO2000017141A1 (https=)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6372925B1 (en) 2000-06-09 2002-04-16 Shell Oil Company Process for operating the epoxidation of ethylene
US7095741B1 (en) * 2000-12-20 2006-08-22 Cisco Technology, Inc. Port isolation for restricting traffic flow on layer 2 switches
DE10321733A1 (de) * 2003-05-14 2004-12-02 Basf Ag Verfahren zur Herstellung von ameisensauren Formiaten
US8197645B2 (en) * 2005-12-29 2012-06-12 Basf Aktiengesellschaft Process for separating propylene glycol from aqueous compositions
RU2312696C1 (ru) * 2006-03-17 2007-12-20 Андрей Григорьевич Вендило Универсальная установка для очистки высококипящих растворителей вакуумной ректификацией и способы очистки вакуумной ректификацией на ней этиленгликоля, моноэтаноламина, метилцеллозольва, этилцеллозольва, бутилцеллозольва, n-метилпирролидона и бензилового спирта
WO2007144360A2 (en) * 2006-06-13 2007-12-21 Shell Internationale Research Maatschappij B.V. Glycol separation and purification
CA2739676A1 (en) * 2008-10-09 2010-04-15 Shell Internationale Research Maatschappij B.V. Process for the recovery of monoethylene glycol
CN106242945A (zh) * 2008-11-10 2016-12-21 陶氏技术投资有限公司 用于生产低色素二醇的方法
PL217778B1 (pl) 2011-06-20 2014-08-29 Piotr Medoń Sposób osuszania glikolu i układ do osuszania glikolu
CN103265401B (zh) * 2013-04-24 2014-12-17 河南朝歌日光新能源股份有限公司 一种煤制乙二醇工艺副产残液的回收方法
US9732019B1 (en) * 2016-04-01 2017-08-15 Cameron Solutions, Inc. System and method to remove organic acid from a rich MEG stream by stripping
GB201710508D0 (en) * 2017-06-30 2017-08-16 Johnson Matthey Davy Technologies Ltd Process
KR102663736B1 (ko) * 2017-11-23 2024-05-10 쉘 인터내셔날 리써취 마트샤피지 비.브이. 에틸렌 옥시드 및 에틸렌 글리콜 생산 방법
NL2025637B1 (en) * 2020-05-20 2021-12-07 Ioniqa Tech B V A separation method and reactor system for a glycol-water mixture
CN119868990B (zh) * 2025-03-12 2025-10-24 连云港石化有限公司 一种乙二醇预脱水塔装置及其使用方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2364151A1 (de) * 1972-12-22 1974-07-25 Sir Soc Italiana Resine Spa Verfahren zur abtrennung von aethylenglykol aus verduennten waessrigen loesungen
EP0032665A1 (de) * 1980-01-18 1981-07-29 Hoechst Aktiengesellschaft Verfahren zur Herstellung von hochreinem Monoethylenglykol

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US2510548A (en) * 1947-06-20 1950-06-06 Lummus Co Multiple-effect distillation
DE1942094A1 (de) 1968-08-22 1970-02-26 Union Carbide Corp Verfahren zur Reinigung von verunreinigten Glykolen
US4182659A (en) * 1977-10-31 1980-01-08 Davy International Aktiengesellschaft Method of concentrating a water-containing glycol
DE3338488A1 (de) 1982-10-29 1984-05-03 Basf Ag, 6700 Ludwigshafen Verfahren zur gewinnung von temperaturempfindlichen produkten durch thermisch schonende destillation mittels eines mit einer destillationskolonne verbundenen duennschichtverdampfers und eine anordnung zur durchfuehrung des verfahrens
JPS6089439A (ja) 1983-10-24 1985-05-20 Mitsui Toatsu Chem Inc エチレングリコ−ルの製造方法
FR2564458B1 (fr) 1984-05-15 1986-09-12 Atochem Procede de separation de l'ethyleneglycol sous forme concentree dans un procede de fabrication d'oxyde d'ethylene
DE4306144A1 (de) * 1993-02-27 1994-09-01 Brown John Deutsche Eng Gmbh Verfahren und Polykondensationsanlage zur Aufbereitung von verunreinigtem Ethylenglykol
DE19602116A1 (de) 1996-01-22 1997-07-24 Basf Ag Verfahren zur Gewinnung von Glykolen mit niedrigem Aldehydgehalt
RU2111949C1 (ru) * 1996-08-19 1998-05-27 Акционерное общество "Нижнекамскнефтехим" Способ извлечения моно- и диэтиленгликолей из кубового остатка процесса выделения моноэтиленгликоля
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Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2364151A1 (de) * 1972-12-22 1974-07-25 Sir Soc Italiana Resine Spa Verfahren zur abtrennung von aethylenglykol aus verduennten waessrigen loesungen
EP0032665A1 (de) * 1980-01-18 1981-07-29 Hoechst Aktiengesellschaft Verfahren zur Herstellung von hochreinem Monoethylenglykol

Non-Patent Citations (1)

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Title
WEBER, T ET AL.: "Ullmanns Encyclopädie der technischen Chemie, 4. Auflage, Band 8", 1974, VERLAG CHEMIE, WEINHEIM/BERGSTR., XP002127152 *

Also Published As

Publication number Publication date
MY121383A (en) 2006-01-28
CA2345053A1 (en) 2000-03-30
KR100611284B1 (ko) 2006-08-10
CN1319080A (zh) 2001-10-24
EP1115682B1 (de) 2003-11-26
ATE255084T1 (de) 2003-12-15
AR020655A1 (es) 2002-05-22
EP1115682A1 (de) 2001-07-18
UA60383C2 (uk) 2003-10-15
US6605192B1 (en) 2003-08-12
PL347580A1 (en) 2002-04-08
DE19843697A1 (de) 2000-03-30
AU5980199A (en) 2000-04-10
BR9913889B1 (pt) 2011-01-11
DE59907884D1 (de) 2004-01-08
JP2002526463A (ja) 2002-08-20
RU2235710C2 (ru) 2004-09-10
TW475925B (en) 2002-02-11
JP4427190B2 (ja) 2010-03-03
CN1217898C (zh) 2005-09-07
PL195588B1 (pl) 2007-10-31
BR9913889A (pt) 2001-07-03
ES2212671T3 (es) 2004-07-16
SA99200783B1 (ar) 2006-08-12
KR20010075276A (ko) 2001-08-09
CA2345053C (en) 2008-07-15

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