WO1998046712A1 - Produit gelifie de nettoyage de toilettes a chasse d'eau - Google Patents

Produit gelifie de nettoyage de toilettes a chasse d'eau Download PDF

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Publication number
WO1998046712A1
WO1998046712A1 PCT/EP1998/002123 EP9802123W WO9846712A1 WO 1998046712 A1 WO1998046712 A1 WO 1998046712A1 EP 9802123 W EP9802123 W EP 9802123W WO 9846712 A1 WO9846712 A1 WO 9846712A1
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WO
WIPO (PCT)
Prior art keywords
weight
amounts
particularly preferably
agents
composition according
Prior art date
Application number
PCT/EP1998/002123
Other languages
German (de)
English (en)
Inventor
Ronald Menke
Alexander Ditze
Frank Pessel
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Kommanditgesellschaft Auf Aktien filed Critical Henkel Kommanditgesellschaft Auf Aktien
Priority to AT98921455T priority Critical patent/ATE269389T1/de
Priority to JP54347498A priority patent/JP2001518969A/ja
Priority to EP98921455A priority patent/EP0975721B1/fr
Priority to DE59811584T priority patent/DE59811584D1/de
Priority to BR9811461-1A priority patent/BR9811461A/pt
Priority to US09/403,150 priority patent/US6336977B1/en
Priority to DK98921455T priority patent/DK0975721T3/da
Priority to CA002287449A priority patent/CA2287449A1/fr
Publication of WO1998046712A1 publication Critical patent/WO1998046712A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives

Definitions

  • the present invention relates to a gel-type cleaning agent which can preferably be used in flush toilets.
  • solid cleaning agents are used in piece form for automatically keeping toilets clean. These are either installed in the toilet bowl or in the water tank.
  • the moldings are overflowed with water during each rinsing process, whereby they gradually dissolve and release their active cleaning ingredients during this time.
  • These cleaning moldings usually contain additional perfume for room scenting or disinfectant agents for hygiene optimization.
  • the piece-shaped detergent tablets described are partially applied in suitable containers with special refill options.
  • the moldings described are generally produced by casting, pressing, extruding or granulating processes, which require a high level of technical outlay and frequently suffer undesirable perfume losses due to the temperature load (casting / extruding process) that occurs.
  • the object of the invention was to develop a system which does not have the disadvantages described. Surprisingly, it was found that special gel-like preparations with pseudoplastic properties significantly reduce the outlay for production and, because of the simple technique, are more cost-effective are to be produced. The problem of the individual refill possibility can also be solved by such pseudoplastic active substance preparations.
  • a special container which is particularly suitable for the gel-form cleaning agents according to the invention is described in DE-A-195 201 45.
  • the invention relates to a stable, gel-like and shear-thinning cleaning agent which, in addition to a polysaccharide, contains a C 8 to C 22 alkyl polyglycoside as a surfactant system and perfume components, the agent containing a polysaccharide in amounts of between 1 and 5% by weight as a component of the A C 8 to C 22 alkyl polyglucoside in amounts of between 3 and 25% by weight, the perfume component (s) in amounts of 2 to 15% by weight and possibly further ingredients such as cosurfactants, descaling agents, dyes, germ-inhibiting agents Contains agents, pearlescent agents, stabilizers, cleaning enhancers and odor absorbers and has a viscosity of 30,000 to 150,000 mPas; the viscosity was measured using a Brookfield rotary viscometer, type RVT with Helipath device and the spindle TA at 1 rpm and 23 ° C.
  • Another advantage is that the viscosity decreases with increasing shear rate, resulting in filling in the production process and easy handling by the consumer during metering / refilling.
  • the size of the air bubbles that z. B. on the stirring speed in the production process and the viscosity of the agent can be neither too large nor too small; in addition, the amount of air bubbles should also only be selected in a preferred range. If the presence of air bubbles is desired, it should not contain more than 30% by volume of air, preferably between 2 and 25% by volume of air and very particularly preferably between 5 and 20% by volume of air.
  • the most preferred embodiments contain air bubbles between 0.1 mm and 20 mm in diameter, most preferably between 1 mm and 15 mm in diameter.
  • the viscosity of the agents according to the invention also allows the air bubbles already entered in the production process by briefly applying a negative pressure which can be in a range just below room pressure to close to a vacuum.
  • the duration of the vacuum treatment depends on the strength of the vacuum. With a stronger negative pressure, the treatment does not have to be carried out as long.
  • the person skilled in the art also knows that if the negative pressure is too strong, undesirable side effects can occur, such as, for. B. the increased evaporation of volatile perfume components and u. U. Problems with the stirrability of the system. Degassing of the agents according to the invention by treatment in a centrifuge or by ultrafast stirring is possible, but less preferred.
  • the person skilled in the art according to the present invention avoids excessive action of shear forces on the agents according to the invention during and after the production process, since otherwise the properties according to the invention are often lost in the short to medium term and can only be recovered after longer waiting times.
  • water is in a commercial mixer, such as. B. a Beco mix system, submitted and the dye stirred.
  • a commercial mixer such as. B. a Beco mix system
  • the xanthan gum which is preferably used as the polysaccharide is preferred with solvent
  • Suspension is added to the initial charge and stirred at low speeds, for example 30 rpm.
  • the mixture is generally to be placed in a suitable container, depending on the viscosity, for a short time, for example 15 minutes, under reduced pressure or under a vacuum.
  • the disinfectant is then added, preferably selected from the group of isothiazolines, benzoates or salicylic acid or salicylates.
  • the filling can in this case, for. B. done in a commercial dosing bottle via a rotary bottle.
  • Brookfield viscometers were used, which are a spindle intended for gels have ready.
  • the viscosities according to the invention were measured with this Helipath spindle.
  • formulations according to the invention can contain the following components in a frame formulation:
  • complexing agent 2 0 to 5.0% by weight of complexing agent 2 to 15% by weight, preferably 2 to 12% by weight and in particular 3 to 8% by weight of perfume to 5.0% by weight, preferably 0.01 to 4 wt .-% solvent, such as Ethanol
  • Xanthan is formed from a chain with ß-1, 4-bound glucose (cellulose) with side chains. The structure of the subgroups consists of glucose, mannose, glucuronic acid, acetate and pyruvate.
  • Xanthomonas campestris produces xanthan under aerobic conditions with a molecular weight of 2-15 X 10 6 .
  • Xanthan is produced in batch cultures and dried and ground with propanol after killing the culture and cases. Other suitable methods are also described in the literature.
  • the polysaccharide in particular xanthan gum, is preferably present in the compositions in amounts of between 1 and 4% by weight, in particular between 1.5 and 3.5% by weight and most preferably between 1, 8 and 3% by weight .
  • Alkyl polyglycosides are surfactants which can be obtained by the reaction of sugars and alcohols using the relevant methods of preparative organic chemistry, with a mixture of monoalkylated, oligomeric or polymeric sugars depending on the type of preparation.
  • Preferred alkyl polyglycosides can be alkyl polyglucosides, the alcohol being particularly preferably a long-chain fatty alcohol with alkyl chain lengths between C 8 and C 22 , preferably between C 8 and C ⁇ and particularly preferably between C 8 and C 12 or a mixture of long-chain fatty alcohols.
  • the degree of oligomerization of the sugars which is a calculated and therefore generally not an integer size, is between 1 and 10, preferably between 1, 1 and 5 and very particularly preferably between 1, 2 and 3 and extremely preferably between 1, 3 and 2 , 5th
  • the agents contain C 8 to C 22 alkyl polyglycosides, preferably in amounts of 4 to 20% by weight, in particular 5 to 17% by weight and extremely preferably 5 to 15% by weight, with amounts of up to 12% by weight also .-% can be advantageous.
  • Anionic co-surfactants according to the present invention can be aliphatic sulfates such as fatty alcohol sulfates, fatty alcohol ether sulfates, dialkyl ether sulfates, monoglyceride sulfates and aliphatic sulfonates such as alkane sulfonates, olefin sulfonates, ether sulfonates, n-alkyl ether sulfonates, ester sulfonates, and lignin sulfonates.
  • aliphatic sulfates such as fatty alcohol sulfates, fatty alcohol ether sulfates, dialkyl ether sulfates, monoglyceride sulfates and aliphatic sulfonates such as alkane sulfonates, olefin sulfonates, ether sulfonates, n-alkyl ether
  • Fatty acid cyanamides, sulfosuccinic acid esters, fatty acid isethionates, acylaminoalkanesulfonates (fatty acid taurides), fatty acid sarcosinates, ether carboxylic acids and alkyl (ether) phosphates are also usable within the scope of the present invention, but are not preferred.
  • Fatty alcohol sulfates and fatty alcohol ether sulfates are preferably used. So far, less good results have been achieved with alkylbenzenesulfonates.
  • the weight ratio of alkyl polyglycoside to cosurfactants is at least 1, ratios between 50: 1 and 1: 1, particularly preferably between 10: 1 and 1.5: 1 and very particularly preferably between 5: 1 and 1.8: 1, are particularly advantageous.
  • Nonionic co-surfactants can also be used.
  • Nonionic surfactants in the context of the present invention can be alkoxylated alcohols, such as polyglycol ethers, fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, end-capped polyglycol ethers, mixed ethers and hydroxy mixed ethers and fatty acid polyglycol esters.
  • alkoxylated alcohols such as polyglycol ethers, fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, end-capped polyglycol ethers, mixed ethers and hydroxy mixed ethers and fatty acid polyglycol esters.
  • Ethylene oxide, propylene oxide, block polymers and fatty acid alkanolamides can also be used
  • alkoxylated alcohols to mean the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, preferably the longer-chain alcohols in the sense of the present invention.
  • n moles of ethylene oxide and one mole of alcohol form a complex mixture of addition products of different degrees of ethoxylation, depending on the reaction conditions.
  • a further embodiment consists in the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide.
  • final etherification with short-chain alkyl groups such as preferably the butyl group, can also give the substance class of the “closed” alcohol ethoxylates, which can also be used for the purposes of the invention.
  • Highly preferred for the purposes of the present invention are highly ethoxylated fatty alcohols or their mixtures with end-capped fatty alcohol ethoxylates.
  • the formulations described can preferably contain inorganic or organic acids such as citric acid, acetic acid, lactic acid or their water-soluble salts in an amount of 1-12% by weight as descaling agents. Contents of 2-5% by weight are particularly preferred.
  • the agents according to the invention preferably contain dye, either for the coloring of the product or for the coloring of the liquid surrounding the container.
  • the content of water-soluble dyes is preferably ⁇ 1% by weight and serves to improve the appearance of the product. If an additional color signal is required during the flushing process, the content of water-soluble dyes can be up to 5% by weight.
  • the content is preferably in amounts of up to 3% by weight, in particular up to 2% by weight and very preferably up to 1% by weight.
  • the gels according to the invention already have an excellent cleaning action without this component, the hygienic action can be enhanced by the addition of germ-inhibiting agents.
  • the amount of these agents depends strongly on the effectiveness of the particular compound and can be up to 5% by weight. At least 0.01% by weight is preferably incorporated into the gels. The range between 0.01% by weight and 3% by weight is particularly preferred. Isothiazoline mixtures, sodium benzoate or salicylic acid or salicylates are particularly suitable. Further preferred amounts are from 0.01 to 2% by weight, in particular from 0.01 to 1% by weight.
  • Solubilizers for example for dyes and perfume oils, can be used, for example, as alkanolamines, polyols such as ethylene glycol, representatives of the lower alcohols such as propylene glycol, glycerol and other mono- and polyhydric alcohols, and also alkylbenzenesulfonates with 1 to 3 carbon atoms in the alkyl radical.
  • Preferred amounts are up to 5% by weight, in particular 0.01 to 4% by weight, advantageously 0.1 to 4% by weight and very particularly preferably 0.5 to 3% by weight.
  • the usual thickeners which could also be used if required, include urea, sodium chloride, sodium sulfate, magnesium sulfate, ammonium chloride and magnesium chloride and the combination of these thickeners. However, the use of these additional thickeners is not preferred.
  • Water-soluble and water-insoluble builders may be present in the cleaning agents according to the invention. Then there are water-soluble builders preferred because they tend to have less tendency to form insoluble residues on hard surfaces.
  • Customary builders or complexing agents which can be present in the context of the invention are the low molecular weight polycarboxylic acids and their salts, the homopolymeric and copolymeric polycarboxylic acids and their salts, the citric acid and their salts, the carbonates, phosphates and silicates.
  • Water-insoluble builders include the zeolites, which can also be used, as well as mixtures of the abovementioned builder substances. The group of citrates is particularly preferred.
  • the agents according to the invention preferably contain builders or complexing agents in amounts of up to 10% by weight, in particular 0.1 to 8% by weight, particularly preferably 1 to 6% by weight and very particularly preferably 2 to 5% by weight.
  • the viscosity in the examples listed was measured using a Brookfield Roto viscometer, rotary viscometer, type RVT with Helipath device and the spindle TA at 1 rpm and 23 ° C.
  • 0.1 g of gel are foamed in 500 ml of tap water at 17 ° d in a 1000 ml measuring cylinder with 40 strokes at a rotation speed of 100 rpm.
  • the structure of the foam volume is read after 1, 3 and 10 min.
  • the measurement is carried out on an automatically controlled toilet system, which dispenses the contents of the water tank every 1 hour and refills the tank with 9 liters of tap water at 17 ° d and a water temperature of 15 - 16 ° C.
  • an automatically controlled toilet system which dispenses the contents of the water tank every 1 hour and refills the tank with 9 liters of tap water at 17 ° d and a water temperature of 15 - 16 ° C.
  • 1 filling of a vessel according to DE 195 201 45 is hung in the toilets and it is determined how many flushes are possible until it is completely used up.
  • the average results are determined from 5 parallel tests.
  • Pre-weighed white Carrara marble slabs measuring 75 x 150 x 5 mm are completely immersed in the gel in a plexiglass cell. This is done for a time of 10 seconds.
  • the plate is then removed and placed vertically in a stand provided for this purpose. This has to be done in such a way that adhering product can run off.
  • the exposure time of the adhesive Product is another 10 min.
  • the plate is then rinsed with water and the weight loss is determined after drying at 105 ° C.
  • the measurement was carried out electrochemically in the concentrate.
  • the storage took place in electrically controlled heat chambers.
  • the storage time at 40 ° C is 3 and 4 weeks, at 23 ° C 12 weeks. This was followed by a visual inspection of the stored goods.
  • Xanthan gum granulated e.g. Keltrol® RD 2.3
  • Rinsing behavior 220 rinses at 21 rinses / day
  • the production can be in a wide variety of batch sizes up to
  • Tone scale can be carried out.
  • water is in a commercial mixer, such as. B. submitted to a Beco mix system, and the dye stirred.
  • the xanthan gum used is slurried separately with solvent, preferably ethanol and the desired perfume oil.
  • Suspension is added to the aqueous template and with small
  • the mixture should, as a rule, be placed in a suitable container depending on the viscosity for a short time, for example 15 minutes under reduced pressure or under a vacuum.
  • the filling in the appropriate storage container can then, for. B. via a suitable commercially available tube filler.
  • Rinsing behavior 250 rinses at 21 rinses / day
  • Tone scale can be carried out.
  • the suspension is added to the template and with low
  • the filling can in this case, for. B. done in a commercial dosing bottle via a rotary bottle.
  • Rinsing behavior 230 rinses at 21 rinses / day
  • TTF Perfume oil apple note
  • TTF Perfume oil apple note
  • Rinsing behavior 300 rinses at 21 rinses / day
  • Foaming behavior 100 ml 1 min; 80 ml 3 min; 50 ml 10 min.
  • TTF Perfume oil apple note
  • Rinsing behavior 500 rinses at 21 rinses / day
  • Rinsing behavior 280 rinses at 21 rinses / day
  • TTF Perfume oil Cool water

Abstract

L'objet de l'invention est d'améliorer la stabilité, le pouvoir odorant et nettoyant et la capacité de recharge d'un produit gélifié de nettoyage, de préférence de toilettes à chasse d'eau. A cet effet, on prépare un produit gélifié de nettoyage diluant qui contient entre 1 et 5 % en poids d'un polysaccharide, 3 à 25 % en poids d'un alkylpolyglycoside en C8 à C22 comme élément constitutif du système tensioactif, jusqu'à 15 % en poids d'un élément odoriférant, ainsi que d'autres ingrédients tels que des antitartres, des colorants, des agents bactéricides, des agents lustrants, des stabilisateurs, des renforçateurs du pouvoir de nettoyage et des absorbants d'odeurs. Ces produits gélifiés ont une viscosité comprise entre 30.000 et 150.000 mPas.
PCT/EP1998/002123 1997-04-16 1998-04-11 Produit gelifie de nettoyage de toilettes a chasse d'eau WO1998046712A1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
AT98921455T ATE269389T1 (de) 1997-04-16 1998-04-11 Gelförmiges reinigungsmittel für spültoiletten
JP54347498A JP2001518969A (ja) 1997-04-16 1998-04-11 水洗トイレ用ゲル状洗浄剤
EP98921455A EP0975721B1 (fr) 1997-04-16 1998-04-11 Produit gelifie de nettoyage de toilettes a chasse d'eau
DE59811584T DE59811584D1 (de) 1997-04-16 1998-04-11 Gelförmiges reinigungsmittel für spültoiletten
BR9811461-1A BR9811461A (pt) 1997-04-16 1998-04-11 Produto de limpeza na forma de gel para vasos sanitários
US09/403,150 US6336977B1 (en) 1998-04-11 1998-04-11 Gelled cleaning agent for flush toilets
DK98921455T DK0975721T3 (da) 1997-04-16 1998-04-11 Gelformigt rengöringsmiddel til skylletoiletter
CA002287449A CA2287449A1 (fr) 1997-04-16 1998-04-11 Produit gelifie de nettoyage de toilettes a chasse d'eau

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19715872.2 1997-04-16
DE19715872A DE19715872C2 (de) 1997-04-16 1997-04-16 Gelförmiges Reinigungsmittel für Spültoiletten

Publications (1)

Publication Number Publication Date
WO1998046712A1 true WO1998046712A1 (fr) 1998-10-22

Family

ID=7826682

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1998/002123 WO1998046712A1 (fr) 1997-04-16 1998-04-11 Produit gelifie de nettoyage de toilettes a chasse d'eau

Country Status (9)

Country Link
EP (1) EP0975721B1 (fr)
JP (1) JP2001518969A (fr)
AT (1) ATE269389T1 (fr)
BR (1) BR9811461A (fr)
CA (1) CA2287449A1 (fr)
DE (2) DE19715872C2 (fr)
DK (1) DK0975721T3 (fr)
ES (1) ES2224390T3 (fr)
WO (1) WO1998046712A1 (fr)

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WO1999066017A1 (fr) * 1998-06-12 1999-12-23 Buck-Chemie Gmbh & Co. Produit d'assainissement adhesif
GB2360293A (en) * 2000-03-14 2001-09-19 Procter & Gamble Detergent compositions
GB2364709A (en) * 2000-07-12 2002-02-06 Johnson & Son Inc S C Lavatory freshening and/or cleaning system
GB2364710A (en) * 2000-07-12 2002-02-06 Johnson & Son Inc S C Lavatory freshening and/or cleaning system
US7048205B2 (en) 2000-07-12 2006-05-23 S.C. Johnson & Son, Inc. Lavatory freshening and/or cleaning system and method
US7541325B2 (en) * 2001-01-11 2009-06-02 Joker Ag Agent for removing solid particles
EP2212408A1 (fr) * 2007-11-01 2010-08-04 The Clorox Company Compositions acides de nettoyage
WO2011014241A1 (fr) * 2009-07-31 2011-02-03 S. C. Johnson & Son, Inc. Composition de nettoyage ayant une auto-adhésion élevée et fournissant des avantages résiduels
EP2662435A1 (fr) 2012-05-11 2013-11-13 Eurvest Composition hygiénique
WO2014180579A1 (fr) 2013-05-10 2014-11-13 Eurvest Sa Nouvelle composition sanitaire
US9169456B2 (en) 2008-02-21 2015-10-27 S.C. Johnson & Son, Inc. Cleaning composition comprising an ethoxylated alcohol blend, having high self-adhesion and providing residual benefits
US9175248B2 (en) 2008-02-21 2015-11-03 S.C. Johnson & Son, Inc. Non-ionic surfactant-based cleaning composition having high self-adhesion and providing residual benefits
US9410111B2 (en) 2008-02-21 2016-08-09 S.C. Johnson & Son, Inc. Cleaning composition that provides residual benefits
US9481854B2 (en) 2008-02-21 2016-11-01 S. C. Johnson & Son, Inc. Cleaning composition that provides residual benefits

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DE19853110A1 (de) 1998-11-18 2000-05-25 Cognis Deutschland Gmbh Gelförmiges Reinigungsmittel für Spültoiletten
DE19906481A1 (de) * 1999-02-17 2000-08-24 Cognis Deutschland Gmbh Gelförmige Reinigungsmittel für Spültoiletten
DE19910788A1 (de) * 1999-03-11 2000-09-14 Cognis Deutschland Gmbh Gelförmiges Reinigungsmittel für Spültoiletten
DE19918188A1 (de) 1999-04-22 2000-10-26 Cognis Deutschland Gmbh Reinigungsmittel für harte Oberflächen
DE19918184A1 (de) * 1999-04-22 2000-10-26 Cognis Deutschland Gmbh Reinigungsmittel für harte Oberflächen
DE19918186A1 (de) * 1999-04-22 2000-10-26 Cognis Deutschland Gmbh Reinigungsmittel für harte Oberflächen
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DE19918192A1 (de) * 1999-04-22 2000-10-26 Cognis Deutschland Gmbh Reinigungsmittel für harte Oberflächen
DE19918191A1 (de) * 1999-04-22 2000-10-26 Cognis Deutschland Gmbh Reinigungsmittel für harte Oberflächen
DE19918185A1 (de) * 1999-04-22 2000-10-26 Cognis Deutschland Gmbh Reinigungsmittel für harte Oberflächen
DE19918189A1 (de) * 1999-04-22 2000-10-26 Cognis Deutschland Gmbh Reinigungsmittel für harte Oberflächen
DE19924368A1 (de) * 1999-05-27 2000-11-30 Henkel Ecolab Gmbh & Co Ohg Tensidhaltige Reinigungsformkörper
DE10012949A1 (de) 2000-03-16 2001-09-27 Henkel Kgaa Kieselsäureester-Mischungen
DE10048887A1 (de) * 2000-09-29 2002-04-18 Buck Chemie Gmbh Haftendes Sanitärreinigungs- und Beduftungsmittel
JP4541076B2 (ja) * 2004-09-07 2010-09-08 京都リフレ新薬株式会社 尿石付着防止剤
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EP1894990A1 (fr) * 2006-09-01 2008-03-05 The Procter and Gamble Company Dose d'unité de la composition pâteuse pour des articles sanitaires
EP1894578A1 (fr) * 2006-09-01 2008-03-05 The Procter and Gamble Company Procédé d'application d'une composition pâteuse pour articles sanitaires
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MX2010009161A (es) 2008-02-21 2010-09-14 Johnson & Son Inc S C Composicion de limpieza que tiene autoadhesion superior y proporciona beneficios residuales.
DE102009001841A1 (de) * 2009-03-25 2010-09-30 Henkel Ag & Co. Kgaa System aus Reinigungsmittel und Abgabevorrichtung
JP5579593B2 (ja) * 2010-12-22 2014-08-27 ニュートリー株式会社 ゼリー状洗浄組成物
ES2627549T3 (es) * 2013-04-25 2017-07-28 Unilever N.V. Composiciones de limpieza con propiedades de suspensión y distribución mejoradas
DE102013226098A1 (de) 2013-12-16 2015-06-18 Henkel Kgaa Silylenolether von Riechstoffketonen oder -aldehyden
DE102013226216A1 (de) 2013-12-17 2015-06-18 Henkel Ag & Co. Kgaa Michael-Systeme für die Duftstoff-Stabilisierung
DE102013226602A1 (de) 2013-12-19 2015-06-25 Henkel Ag & Co. Kgaa Verwendung von CNGA2-Agonisten zur Verstärkung der olfaktorischen Wirkung eines Riechstoffs
EP2963103A1 (fr) 2014-07-04 2016-01-06 Henkel AG & Co. KGaA Nanocapsules sensibles au pH
DE102017123282A1 (de) 2017-10-06 2019-04-11 Henkel Ag & Co. Kgaa Hydrolyselabile Silylenolether von Riechstoffketonen oder -aldehyden
DE102017124611A1 (de) 2017-10-20 2019-04-25 Henkel Ag & Co. Kgaa Thermolabile Duftspeicherstoffe von Riechstoffketonen
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DE102017127776A1 (de) 2017-11-24 2019-05-29 Henkel Ag & Co. Kgaa Hydrolyselabile Heterocyclen von Riechstoffketonen oder -aldehyden
DE102018210801A1 (de) * 2018-06-29 2020-01-02 Henkel Ag & Co. Kgaa Selbsthaftende schäumende Sanitärmittel
EP3722401B1 (fr) * 2019-04-10 2024-01-17 Henkel AG & Co. KGaA Moyen sanitaire sous la forme de gel permettant d'éviter un biofilm
EP4098734A1 (fr) 2021-06-02 2022-12-07 Henkel AG & Co. KGaA Système de toilettes à composition gel multiphasée
DE102022121759A1 (de) 2022-08-29 2024-02-29 Henkel Ag & Co. Kgaa Temperaturstabile gelzusammensetzungen
DE102022121761A1 (de) 2022-08-29 2024-02-29 Henkel Ag & Co. Kgaa Wasserverlust-stabile gelzusammensetzung

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EP2212408A1 (fr) * 2007-11-01 2010-08-04 The Clorox Company Compositions acides de nettoyage
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US10392583B2 (en) 2008-02-21 2019-08-27 S. C. Johnson & Son, Inc. Cleaning composition with a hydrophilic polymer having high self-adhesion and providing residual benefits
US10266798B2 (en) 2008-02-21 2019-04-23 S. C. Johnson & Son, Inc. Cleaning composition that provides residual benefits
US9399752B2 (en) 2008-02-21 2016-07-26 S. C. Johnson & Son, Inc. Cleaning composition having high self-adhesion and providing residual benefits
US9410111B2 (en) 2008-02-21 2016-08-09 S.C. Johnson & Son, Inc. Cleaning composition that provides residual benefits
US9481854B2 (en) 2008-02-21 2016-11-01 S. C. Johnson & Son, Inc. Cleaning composition that provides residual benefits
US9771544B2 (en) 2008-02-21 2017-09-26 S. C. Johnson & Son, Inc. Cleaning composition having high self-adhesion and providing residual benefits
US9982224B2 (en) 2008-02-21 2018-05-29 S. C. Johnson & Son, Inc. Cleaning composition having high self-adhesion and providing residual benefits comprising a cationic/nonionic surfactant system
AU2010276734B2 (en) * 2009-07-31 2012-12-06 S. C. Johnson & Son, Inc. Cleaning composition having high self-adhesion and providing residual benefits
WO2011014241A1 (fr) * 2009-07-31 2011-02-03 S. C. Johnson & Son, Inc. Composition de nettoyage ayant une auto-adhésion élevée et fournissant des avantages résiduels
EP2662435A1 (fr) 2012-05-11 2013-11-13 Eurvest Composition hygiénique
WO2014180579A1 (fr) 2013-05-10 2014-11-13 Eurvest Sa Nouvelle composition sanitaire

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BR9811461A (pt) 2000-09-12
ATE269389T1 (de) 2004-07-15
CA2287449A1 (fr) 1998-10-22
EP0975721A1 (fr) 2000-02-02
DK0975721T3 (da) 2004-10-25
DE59811584D1 (de) 2004-07-22
JP2001518969A (ja) 2001-10-16
DE19715872C2 (de) 1999-04-29
DE19715872A1 (de) 1998-10-22
EP0975721B1 (fr) 2004-06-16
ES2224390T3 (es) 2005-03-01

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