WO1996012328A1 - Laser a semi-conducteur - Google Patents
Laser a semi-conducteur Download PDFInfo
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- WO1996012328A1 WO1996012328A1 PCT/JP1995/002118 JP9502118W WO9612328A1 WO 1996012328 A1 WO1996012328 A1 WO 1996012328A1 JP 9502118 W JP9502118 W JP 9502118W WO 9612328 A1 WO9612328 A1 WO 9612328A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/20—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
- H01S5/22—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure
- H01S5/223—Buried stripe structure
- H01S5/2238—Buried stripe structure with a terraced structure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y20/00—Nanooptics, e.g. quantum optics or photonic crystals
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/20—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
- H01S5/22—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure
- H01S5/223—Buried stripe structure
- H01S5/2231—Buried stripe structure with inner confining structure only between the active layer and the upper electrode
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/20—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
- H01S5/204—Strongly index guided structures
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/20—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
- H01S5/22—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure
- H01S5/2205—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure comprising special burying or current confinement layers
- H01S5/2218—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure comprising special burying or current confinement layers having special optical properties
- H01S5/222—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure comprising special burying or current confinement layers having special optical properties having a refractive index lower than that of the cladding layers or outer guiding layers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/30—Structure or shape of the active region; Materials used for the active region
- H01S5/34—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers
- H01S5/343—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser
- H01S5/34313—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser with a well layer having only As as V-compound, e.g. AlGaAs, InGaAs
- H01S5/3432—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser with a well layer having only As as V-compound, e.g. AlGaAs, InGaAs the whole junction comprising only (AI)GaAs
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- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04B—TRANSMISSION
- H04B10/00—Transmission systems employing electromagnetic waves other than radio-waves, e.g. infrared, visible or ultraviolet light, or employing corpuscular radiation, e.g. quantum communication
- H04B10/60—Receivers
- H04B10/66—Non-coherent receivers, e.g. using direct detection
- H04B10/67—Optical arrangements in the receiver
Definitions
- the present invention is used in communications, optical recording of optical disks, etc., laser printers, laser medicine, laser processing, etc., and is particularly suitable for exciting solid-state lasers and high-frequency conversion elements that require high-output laser beams.
- High-power semiconductor laser devices
- Semiconductor laser devices are broadly classified into gain-guided and index-guided types when classified by optical waveguide mechanisms.
- the former is a waveguide type in which the transverse mode is unstable and the direction parallel to the junction. Since the astigmatism which indicates the deviation of the beam waist (the position where the beam width becomes minimum) in the vertical direction increases, there are various disadvantages in application. On the other hand, the latter has the advantage that the transverse mode is stable and the astigmatism is small.
- An example of a refractive index guided semiconductor laser is a BH (Buried Heterostructure) laser.
- the BH laser Since the active layer is buried with a low-refractive-index material, the BH laser exhibits a perfect refractive index-guided type, has a low ⁇ value, low current Ith, oscillates in the fundamental transverse mode, and has a small astigmatic difference.
- BH lasers are not suitable for high-power lasers because the active layer is processed in the BH laser, and damage and impurities introduced into the active layer during processing are non-radiative recombination centers.
- CSP Channelled Substrate Planar
- VSIS lasers are types of lasers that create a refractive index distribution near the active layer to create a refractive index distribution and confine the transverse mode.
- a current confinement eyebrow with a large absorption coefficient for the laser light is built in the vicinity of the active 3 ⁇ 4, and a relatively small refractive index difference can be controlled, so that fundamental mode oscillation can be obtained even with a wide stripe width. Since this absorption becomes an internal loss, the energy value ⁇ current Ith increases. The differential efficiency decreases,
- FIG. 8 (a) is a structural diagram showing an example of the low-loss index-guided semiconductor laser using the doubling constriction layer without absorption
- FIG. 8 (b) is a graph showing the waveguide mode. is there.
- a cladding layer 7 made of A 1 GaAs a waveguide layer 6 made of A 1 GaAs, an active layer 5 made of GaAs, and A 1 on a buffer layer 8 made of Ga As
- the waveguide layer 4 made of GaAs, the cladding layer 2 made of A1GaAs, and the cap calendar 1 made of GaAs are sequentially formed, and the inside of the cladding layer 2 has a lower A1 composition than the cladding layer 2.
- the current constriction layer 3 having a refractive index is formed so as to sandwich the stripe-shaped active region 10. Thereby, a refractive index difference is provided between the active region 10 and the buried region 9 where the current confinement layer 3 exists, thereby forming a refractive index waveguide ellipse.
- This structure is different from the SCH (Separate Confinement Heterostructure) bezel normally used for high-power semiconductor lasers in that the current confinement layer 3 has a low refractive index by increasing the A1 composition from the cladding layer near the active layer 5.
- the current confinement layer 3 does not absorb laser light, so the internal loss is reduced and the fundamental transverse mode oscillation is realized up to high light output. ing.
- the index guided semiconductor laser shown in FIG. 8 has a very small manufacturing margin and a low manufacturing yield. That is, the effective refractive index difference ANeff between the active region and the buried region required for the refractive index waveguide structure to perform stable laser oscillation up to a relatively high optical output has been discussed in various documents.
- the current confinement layer is usually formed by etching. However, it is very difficult to process the current confinement layer with an accuracy of 0.1 m or less, so that the position and the thickness of the current confinement layer are limited.
- An object of the present invention is to provide a refractive index guided semiconductor laser device which is easy to manufacture with high output.
- the present invention provides an active layer
- a carrier block layer provided on both sides of the active layer and having a larger energy gap than the waveguide layer;
- a waveguide layer provided on the side opposite to the active layer with respect to the carrier block layer,
- a cladding layer provided on the side opposite to the active layer with respect to the waveguide layer and having a lower refractive index than the waveguide layer;
- a current confinement layer having a lower refractive index than the waveguide layer is formed so as to sandwich the stripe-shaped active region, and a refractive index difference is provided between the active region and the buried region where the current confinement layer exists to provide a refractive index difference.
- a semiconductor laser device having a waveguide structure. The present invention also provides an active layer,
- a carrier blocking layer provided on both sides of the active layer and having a larger energy gear than the waveguide layer;
- a waveguide provided on the side opposite to the active layer with respect to the carrier block layer;
- a cladding provided on the opposite side of the waveguide layer to the active layer and having a lower refractive index than the waveguide layer;
- a current confinement layer having a lower refractive index than the waveguide is formed so as to sandwich the stripe-shaped active region, and a refractive index difference is provided between the active region and the buried region where the current confinement layer exists to provide a refractive index difference.
- a semiconductor laser device characterized in that an imaginary effective refractive index of the active layer opposite to that of the current confinement layer is made lower than that of the current confinement layer.
- the virtual effective refractive index on one side is the same tank structure as the active layer.
- it is defined as the effective refractive index in a symmetric waveguide tank structure that is assumed to exist on the other side in a mirror image, and the effective refractive index can be obtained using the equivalent refractive index method.
- the virtual effective refractive index it is preferable to lower the virtual effective refractive index by lowering the refractive index of the waveguide layer on the side opposite to the current confinement layer with respect to the active layer.
- the thickness of the waveguide layer on the side opposite to the current confinement layer is smaller than the thickness of the current confinement layer with respect to the active layer.
- the current confinement layer is preferably formed in the waveguide layer so as to be adjacent to the clad.
- the current confinement layer is preferably formed in the waveguide layer so as to be separated from the cladding.
- the refractive index of the waveguide layer is N.
- the refractive index of the cladding layer is N 3
- the effective thickness between the cladding layers is d
- the oscillation wavelength of the semiconductor laser is ⁇
- r is the circular constant, and the refractive index of the waveguide layer is N.
- the refractive index and thickness of the carrier block layer are N 2 and d 2
- the refractive index of the cladding layer is N 3
- the thickness of the waveguide layer including the active layer, the barrier layer, the side barrier layer, and the carrier block layer is d 3
- the refractive index and thickness of the active layer be N, and d
- Vo (7 ⁇ ⁇ / ⁇ ) ⁇ ( ⁇ '1 ⁇ . 2 ) ° ⁇ 5
- the refractive index and thickness of the quantum well layer are N w and d w ,
- Vo (m ⁇ ⁇ ⁇ dw / ⁇ ) ⁇ ( ⁇ No 2 ) 0 ' 5
- V, ( ⁇ ⁇ d 2 / in) '(N. 2 — ⁇ 2 2 ) ° ⁇ 5
- V 2 ( ⁇ ⁇ d 3 / ⁇ ) ⁇ ( ⁇ 2 - ⁇ 3 2) 0 5
- the thickness of the carrier block layer is d 2 (unit angstrom), and the energy gap difference between the waveguide layer and the carrier block layer is E (unit eV. ) And when
- the effective refractive index difference ANefi between the active region and the buried region is ⁇ Neff ⁇ 0.001.
- X is preferably in the range of 0.0 to 0.7.
- the waveguide layer is preferably made of GaAs.
- the active layer is preferably made of InxGa! -XAs.
- the structure near the active layer according to the present invention will be described in comparison with the conventional SCH structure shown in FIG.
- the cladding layers 2 and 7 in the SCH structure in FIG. 8 have both functions of confining carriers and controlling the waveguide mode. For this reason, when the waveguide layers 4 and 6 are made thicker, the function of confining carriers is weakened and the differential efficiency is reduced.Therefore, the total thickness of the waveguide layer 4, the active layer 5 and the waveguide layer 6 is generally ⁇ ⁇ 4> um or less in many cases.
- FIG. 8 (b) is a graph showing the light intensity distribution of the guided mode along the Z-axis at the center of the active region 10.
- the active layer 5 and the waveguide layer 6, the sine function is shown.
- the light intensity changes exponentially in the range of the cladding layers 2 and 7, and the waveguide mode at this time has an exponential shape with an expanded base. Will be.
- the “Gaussian type” is more advantageous than the “index exponential type” for the waveguide mode for the following reasons. That is,
- the effect of the current confinement layer 3 is that the current confinement layer 3 is formed by forming a current confinement layer 3 having a low refractive index near the active layer 5 to form a refractive index difference in the lateral direction. It becomes more remarkable as the electric field strength at the insertion position becomes larger.
- the current confinement layer 3 is actually formed at a distance of at least 0. 0 from the active layer 5.
- the current confinement layer 3 In the region of, the “Gaussian type” has a larger electric field strength and the current confinement layer 3 functions more effectively, so that a large ANef f can be obtained.
- FIG. 1 (a) is a structural diagram showing a refractive index guided semiconductor laser according to the present invention
- FIG. 1 (b) is a graph showing its waveguide mode.
- Carrier block layer 29 composed of n-A 1 GaAs and having larger energy gap than waveguide layer 29, Side barrier layer 28 composed of non-doped A 1 GaAs, two quantum wells composed of non-doped GaAs and non-doped Active layer 27 composed of one barrier layer composed of A 1 GaAs, side barrier layer composed of non-doped A 1 GaAs 26, carrier block layer composed of PA 1 GaAs and having a larger energy gap than the waveguide layer, P A waveguide layer 23 made of A 1 GaAs, a cladding layer 22 made of P-A 1 GaAs and having a lower refractive index than the waveguide layer, and a cap layer 21 made of P-GaAs are sequentially formed.
- a current confinement layer 24 having a lower refractive index by increasing the A1 composition than the waveguide layer 23 is formed so as to sandwich the stripe-shaped active region. Thereby, a refractive index difference is provided between the active region 34 and the buried region 33 in which the current confinement ring 24 exists, thereby forming a refractive index waveguide structure.
- the carrier blocking layers 25 and 29 play the role of confining the injected carriers, so that the thickness of the waveguide layers 23 and 30 can be freely designed independently of the carrier confinement. Therefore, if this structure is used, the region from the waveguide layer 23 to the waveguide layer 30 can be formed thick, and the waveguide mode along the Z axis at the center of the active region 34 is as shown in Fig. 1 (b ), It can be "Gaussian". As a result, an effective refractive index waveguide structure with a larger effective refractive index difference ANeff can be realized as compared with a conventional structure with a “index exponential number” waveguide mode.
- FIG. 1 (a) the carrier blocking layers 25 and 29 play the role of confining the injected carriers, so that the thickness of the waveguide layers 23 and 30 can be freely designed independently of the carrier confinement. Therefore, if this structure is used, the region from the waveguide layer 23 to the waveguide layer 30 can be formed thick, and the waveguide mode along the Z axis at the center of
- FIGS. 4 (a) and (b) show the results of the present invention.
- c) (d) is conventional.
- the A1 composition ratio X and film thickness of each layer used at this time are shown in the following table, where (Table 1) is for the present invention and (Table 2) is for the conventional one.
- P side carrier block layer 135 A 135 AA 1 X G a] - ⁇ s (X u .50)
- P-side side barrier layer 500 500 AI X G a ⁇ - ⁇ ⁇ s (X 0.20)
- N side side barrier hire 50 OA 500 A 1 X G aj- ⁇ s (X 0.20)
- n-side carrier layer 135 A 135 AA 1 X G ai- ⁇ s (X 0.50)
- Xb is the A1 composition ratio of the current confinement layer 24 in FIG. 1, (113 is the thickness of the current confinement layer 24 (unit is 111)), and dP is the carrier block layer. 25 shows the separation (unit: m) from the upper surface to the lower surface of the constriction layer 24.
- Xb is the A 1 composition ratio of the constriction layer 3 in FIG. (113 indicates the thickness of the current narrow layer 3
- dp indicates the distance from the upper surface of the waveguide layer 4 to the lower surface of the current narrow layer 3.
- a carrier block layer is provided on both sides of the active layer, a waveguide layer is provided on both outer sides of the carrier layer, and a cladding layer is provided on both outer sides of the waveguide layer.
- the virtual effective refractive index on the side opposite to the current confinement layer with respect to the active layer is changed to the virtual effective refractive index on the current confinement layer side.
- the specific structural design of the present invention is performed as follows.
- the following means can be exemplified as a specific method for forming a structure in which the virtual effective refractive index on the side opposite to the current confinement layer is lower than the virtual effective refractive index on the current confinement layer side with respect to the active layer.
- the active layer can be made asymmetric by lowering the refractive index of the cladding / cladding layer opposite to the current confinement layer.
- the analysis can be performed with an approximately asymmetric three-layer waveguide, where the asymmetry of the waveguide increases and the refractive index of the cladding layer decreases as the waveguide fit structure does not break down. The effect is greater.
- the active layer can be made asymmetric by lowering the refractive index of the waveguide on the side opposite to the current confinement ⁇ .
- the analysis can be performed by considering an approximately asymmetric four-layer waveguide, and the refractive index of the waveguide must be larger than that of the adjacent cladding layer.
- the thickness of the waveguide layer on the side opposite to the current confinement layer with respect to the active layer is made thinner than the thickness of the waveguide layer on the leg of the current confinement layer. Even above, the above-described effects can be obtained.
- the waveguide mode stands near the center of the waveguide layer. Therefore, the overlap between the active layer and the waveguide mode, the so-called coupling gain coefficient, decreases, but the narrow current layer can be formed close to the center of the waveguide mode, thus forming a refractive index waveguide structure. Can be expected to have an additional effect of being easier.
- Figure 2 shows the electric field distribution in the waveguide region and the A1 composition profile in the buried region when the above method is actually used.
- the conditions used for the calculation are shown in (Table 3). From the figure, it is possible to shift the waveguide mode by using any of the above methods, and when the current confinement layer is inserted, the overlap with the same layer becomes large, so that the predetermined refractive index difference AN eff Can be obtained. '
- FIG. 3 shows the refractive index difference AN eff between the waveguide region and the buried region when asymmetry is not performed and when asymmetry is introduced using each of the above methods.
- the calculation is performed using the so-called equivalent refractive index method, the active region and the buried region are each analyzed as a multilayer slab waveguide, the effective refractive index is calculated, and the effective refractive index difference is calculated as the difference between the two values. Seeking N eff.
- the calculation conditions at this time are as shown in (Table 3).
- the above methods can be used together, or the refractive index of other existing layers can be reduced, or a new low refractive index layer can be provided. Further, it is also possible to obtain a desired refractive index by changing the refractive index stepwise in the layer.
- the current confinement with a smaller A 1 composition compared to a symmetric structure is more stable in process.
- the layer can be formed at a greater distance from the active layer.
- the current confinement layer 24 is often formed inside the waveguide layers 23 and 30 as a result. Without the carrier block layer, holes and electrons contributing to laser oscillation coexist inside the waveguide layer.If a processed surface is introduced into the waveguide layer, the carrier will recombine non-radiatively, reducing the oscillation efficiency. In many cases, it drops significantly, making it impossible to oscillate. However, in this structure, outside the carrier blocking layers 25 and 29 with respect to the active layer, only one of the electrons and the holes exists in the waveguides 23 and 30. It has the characteristic that the waveguide layer can be processed without impairing the characteristics of the laser, which cannot occur.
- FIG. 9 shows a manufacturing process of the conventional SAS type semiconductor laser shown in FIG.
- the MBE method, MOCVD method, etc. are used to fabricate an n-GaAs substrate.
- a buffer layer 8, a cladding layer 7, a waveguide layer 6, an active layer 5, a waveguide layer 4, a cladding layer 2, a convection confinement layer 3, and a process cap layer 11 composed of GaAs are sequentially grown.
- FIG. 9 (b) after a photoresist 12 is applied on the process cap layer 11, a striped window is formed, and the process cap ⁇ 11 and the current confinement layer 3 are etched using this as a mask. , To form a striped lecture.
- FIG. 9C after removing the photoresist 12 and the process cap layer 11, the upper clad layer 2 and the cap layer 1 are formed in the second crystal growth.
- the current confinement layer 3 is usually formed by wet etching, and then the cladding layer 2 and the cap layer 1 are regrown above the current confinement layer 3, the regrowth interface between the current confinement layer 3 and the lower cladding layer 2 is formed. Is released to the atmosphere once during the formation of the laminated film. At this time, it is inevitable that the regrowth interface is oxidized, and the film quality of the upper cathode layer 2 and the cap layer 1 formed near or after the interface is remarkably deteriorated. For the purpose of reducing this effect, surface treatment with an ammonium sulfide-hydrochloric acid-based or sulfuric acid-based treatment solution is performed after wet etching, but it is difficult to completely remove the effect of oxidation.
- the current confinement layer 24 is formed in the waveguide layer 23, and the A1 content of the waveguide layer 23 is generally smaller than that of the cladding layer 22. Therefore, the influence of oxidation in the manufacturing process can be suppressed low, and the film quality of the regrowth interface or a layer formed thereafter can be kept good.
- the waveguide layer can be formed of GaAs that does not include A1, and the present invention is applied to this structure. Then, in the process of forming the current confinement layer, there is no oxidation at the regrowth interface, and a good film can be formed. As a result, a refractive index waveguide structure can be formed without deteriorating the characteristics of the laser.
- the wave-guiding function of the active layer and the carrier block layer is canceled out by setting the refractive index of the wave-guiding layer to N if the thickness of both layers is less than one-seventh of the oscillation wavelength.
- the refractive index and thickness of the active layer N, and d,, to the refractive index and thickness of the carrier blocking layer and the N 2 and d 2 When
- the active layer is formed of multiple layers such as a multiple quantum well tank structure, i corresponding to the left side of each layer is calculated, and a value obtained by adding i thereto may be used for the left side.
- the composition of the barrier layer between the quantum well is equal to the composition of the waveguide layer, the refractive index and thickness of N w, m layer active layer ing from the quantum wells of dw is
- ⁇ 0 (7 ⁇ ⁇ ⁇ import). ( ⁇ , 2 — N. 2 ) 0 S
- the active layer is composed of m quantum well layers
- Vo ( ⁇ ⁇ -du / ⁇ ) ⁇ (N-N. 2 ) 0 5
- V, ( ⁇ ⁇ d z / ⁇ ) - ( ⁇ : - ⁇ 2 2) ° ⁇ 5 '
- the active layer, barrier layer, side barrier layer, and the thickness of the waveguide layer including the carrier block layer and d 3, and the refractive index of the cladding layer was set to N 3, the V 2,
- V 2 (7 ⁇ ⁇ d 3 ⁇ ) ⁇ (No 2 - N 3 2) ° ⁇ 5
- ⁇ is the oscillation wavelength of the laser.
- V is evident from the above equation.
- V,, V 2 is active employment, the carrier blocking layer for each waveguide layer, and corresponds to the normalized frequency of the waveguide layer and the cladding layer, V.
- V 2 is an index of the waveguide function
- V is an index of the anti-guide function. If the anti-guiding function of the carrier block layer is too large, a depression occurs near the active layer in the guided mode. As a result, the optical confinement ratio decreases, and the threshold current increases. Therefore, the effect of the carrier block layer on the waveguide mode must be small. From prototypes of various semiconductor lasers, V, ⁇ V 2/1 0
- the carrier block layer is particularly effective under the following conditions for canceling the waveguide mode of the active layer.
- V, ( ⁇ d, / ⁇ )-( ⁇ 2 - ⁇ 3 2 ) ° 5
- the standardized frequency V is preferably 2 ⁇ or less.
- ⁇ If the refractive index of the waveguide layer is constant, it takes that constant value, but if the refractive index has a distribution in the waveguide layer, it means the maximum value.
- the effective thickness d is defined as ⁇ «(X) where the refractive index at an arbitrary position (X) between the two cladding layers is described above, and the positions of the interface near the active debris of the ⁇ -side cladding layer are x'l and P Assuming that the position of the interface of the side cladding layer near the active layer is X2, it can be obtained by the following equation.
- the carrier layer must effectively confine the carrier to the active layer.
- the thickness of the carrier block layer is d 2 (angstrom) and the energy gap difference between the waveguide layer and the carrier block layer is E (unit eV. However, if there is a distribution in one energy gap, the minimum value is adopted).
- a carrier block layer having an anti-guiding function with a large band gap and a low refractive index is provided on both sides of the active layer. It plays the role of confining injected electrons and holes in the active layer. As a result, the waveguide layer does not need to consider the carrier confinement function so much, and the degree of freedom in designing the waveguide layer is increased, so that the waveguide mode can be made closer to “Gaussian”.
- the current confinement layer for forming the refractive index waveguide structure has a lower A1 composition and is formed at a greater distance from the active layer, so that a predetermined refractive index can be obtained within a region where cut-off can be avoided. The difference can be obtained, and a semiconductor laser that is stable in process and high in reliability can be obtained.
- the present invention only one of the electron and the hole exists in the waveguide layer outside the carrier block layer with respect to the active layer, so that the laser layer does not lose its characteristics.
- a current confinement layer can be formed in the region.
- lowering the overall A1 composition greatly contributes to lowering electrical resistance and thermal resistance.
- the guided mode “Gaussian”
- the beam quality of the emitted beam can be improved, and at the same time, the peak light intensity at a constant light output can be suppressed, and instantaneous damage to the light emitting end face can be prevented.
- a carrier block layer is provided on both sides of an active layer, a waveguide layer is provided on both outer sides of the carrier block layer, and a waveguide layer is provided on both outer sides of the waveguide layer.
- the virtual effective refractive index on the side opposite to the current confinement layer with respect to the active layer is set on the current confinement layer side. Lower than the effective refractive index.
- the waveguide mode has a large overlap with the current confinement layer, the effect of the same layer can be effectively enjoyed.
- the design of the current confinement layer is facilitated, and the manufacturing magazine is expanded.
- FIG. 1 (a) is a diagram showing a refractive index guided semiconductor laser according to the present invention
- FIG. 1 (b) is a graph showing the waveguide mode.
- FIG. 2 is a graph showing the electric field distribution in the waveguide region and the A1 composition profile of the buried region in the asymmetric structure obtained by each method.
- Figure 3 shows the refractive index difference ⁇ between the waveguide region and the buried region for the A1 composition xb of the current confinement layer. It is a graph which shows Neff.
- FIG. 4 is a graph showing the results of calculating the effect of the current confinement layer in the A 1 Ga As / Gas-based semiconductor laser, and FIGS. 4 (a) and (b) show the results of the present invention.
- FIG. 5 is a process chart illustrating a method for manufacturing a semiconductor laser device according to the present invention.
- FIG. 1 is a structural view showing an example of a ridge-type refractive index guided semiconductor laser to which the present invention can be applied.
- FIG. 7 is a structural diagram showing an example of a TJS type refractive index guided semiconductor laser to which the present invention can be applied.
- FIG. 8 (a) is a structural diagram showing an example of a conventional index guided semiconductor laser using a current confinement layer
- FIG. 8 (b) is a graph showing the waveguide mode.
- FIG. 9 is a process chart showing a manufacturing process of the conventional SAS semiconductor laser shown in FIG.
- FIG. 10 (a) is a diagram showing a current-light output characteristic of the semiconductor laser shown in Example 1
- FIG. 10 (b) is a diagram showing a far-field image.
- FIG. 5 is a process diagram illustrating a method for manufacturing a semiconductor laser device according to the first embodiment of the present invention.
- a buffer layer 32 (0.5 .mu.m thick) composed of G.sub.A As on an n--G.sub.A As substrate, and A.sub.1.
- N Gawashirubeha layer 30 made of A s (thickness 0.5 5 ⁇ M), AI 0. S0 Ga.
- the n-side carrier block layer 29 (thickness 0.015 35 m) composed of S0 As, A1. 2 . G a. 8 .
- Ga n-side barrier layer 28 As Ga n-side barrier layer 28 (thickness 0.05 jum), two GaAs quantum well layers (thickness 0.011 jum), and A 1 .. 20 Ga 0 interpolating between them .
- barrier layer made of e .as (thickness ⁇ . 006 urn) active layer 27 which is ⁇ by (thickness 0. 028 um), a l .. 20 Ga. P -side side barrier consisting B .as Layer 26 (thickness 0 ⁇ 05 m), A 1. ⁇ S. G a ⁇ S0 Carrier block layer 25 (thickness: 0,135 m), A 1. 2.
- a .A s made of p Gawashirubeha layer 23 (thickness: 0. 2 m), A 1 .. 4 .G a. ⁇ s. current confinement layer 24 made of A s (thickness 0. 5Aim), GaAs process cache Step JB35 (thickness 0.1 Aim) is grown sequentially.
- MOCVD method was used for the first crystal growth, other crystal growth methods such as the MB method can be used.
- FIG. 5 (b) a photoresist 36 is applied on the process cap layer 35, and a window having a desired stripe width is formed on the photoresist by photolithography.
- A1 is used in the second crystal growth. 2 . Ga. 8 .
- the upper P-side waveguide layer 23 made of As (thickness 0.3 m), A1. 33 Ga.
- a p-side cladding layer 22 (0.8 m thick) made of S7 As and a cap layer 21 (2 ⁇ m thick) made of P—Ga As are sequentially formed, the book shown in Fig. 5 (c) is obtained.
- the semiconductor laser device of the invention is obtained. After that, when an electrode is formed on the substrate and the cap layer 21 and a current is passed, laser oscillation is enabled by carrier injection.
- the substrate being manufactured is exposed to the air.At this time, the oxide film was formed on the surface because the A1 composition on the processed surface was high in the past, and the subsequent crystal Although the crystallinity was reduced, in the present invention, the degree of oxidation was small because the A1 composition on the processed surface was low, and therefore, crystal growth with high crystallinity and high reliability was possible. From the calculation results shown in Fig. 4 (b), the ANeff at this time is 0.008, indicating that a refractive index difference sufficient to realize a refractive index guided ellipse can be obtained.
- the inter-value current was 4 OmA and the thrower efficiency was 1.0 WZA with 96% ⁇ 4% coating.
- good current-light output characteristics with good linearity without kink were obtained up to an output of 20 OmW, and the far-field pattern of the laser beam was a unimodal Gaussian with a good refractive index. It could be confirmed that it was guided wave casting.
- n- GaA s buffer layer 32 made of GaA s on a substrate (thickness 0. 5 m), A 1 o . 12 G a.
- B8 A n-side cladding layer 31 made of As (thickness 0.9 mm), n-side waveguide layer 30 made of GaAs 30 (thickness 0.6 / m), A 1. 3 . G a. 7 .
- GaA s made of n-side support Idobaria layer 28 (thickness 0. 05 um>, 3 pieces of I n .. 20 Ga 0. e .
- the active layer 27 (0.033 zm thickness) composed of a barrier layer (thickness: 0.006 m) consisting of As quantum wells (thickness 0.007 ⁇ m) and two GaAs interpolating them.
- P-side side barrier layer 26 made of GaA s (thickness 0.5 05 ⁇ M), A 1. 3 .Ga. "P -side carrier blocking layer 25 made of A s (thickness 0.
- GaA current constriction layer 24 (0.5 m thick) consisting of P-side waveguide layer 23 (thickness 0.2 «m), 8 1 .. 20 0 & 8 .
- a process cap layer 35 (thickness 0.1 lm) is sequentially grown.
- a photoresist 36 is applied on the process cap layer 35, a window having a desired stripe width is formed in the photoresist, and the current confinement layer 24 is subjected to photo-etching using this as a mask. To form a clear part 37.
- the upper p-side waveguide layer 23 made of GaAs (0.4 ⁇ m thick) is formed.
- a semiconductor laser of the present invention shown in FIG. 5 (c) An element is obtained.
- laser oscillation is enabled by carrier injection.
- the regrowth interface is made of GaAs, A1 oxidation can be avoided. Therefore, crystal growth with good crystallinity and high reliability can be achieved.
- the semiconductor laser device obtained in this way had an intermediate current of 30 mA and a slope efficiency of 1.0 WA. Good linearity without kink up to 10 OmW output As a result, it was confirmed that the far-field pattern of the laser beam was of a unimodal Gaussian type, and that it had a good refractive index waveguide structure.
- the A1 composition is lower than before, and a good refractive index waveguide structure can be formed by the flow constriction layer formed at a position farther from the active layer.
- a semiconductor laser having high performance can be obtained.
- FIG. 6 is a structural drawing showing an example of a ridge-type refractive index guided semiconductor laser to which the present invention can be applied.
- n-G a As on a substrate (not shown), n-GaA s a buffer layer 32 (thickness of 0.5, a cladding layer composed of n- A 1. 33 Ga .. S7 A s 31 (thickness 0.5 8 ⁇ M), 11 - 1 .. 2.0 & .. 3:. 5 waveguiding layer 30 made of (thickness 0., n- A 10.
- S .G a .. 5 carrier Pro click layer 29 made of .A s (thickness 0. 01 35 m), an undoped 1 0:...
- Dobaria layer 28 (thickness 0.0, undoped G a A two ⁇ well layer made of s (thickness 0. 01 1 m) and a 1 .. 2 .Ga. eo a s of the barrier debris (thickness 0. 006 um) in an active layer including 27 (thickness 0. 028> um), non Da A 1 .. 2 .G a .. a .A s consisting Sai Dobaria ⁇ 2 O (thickness 0.5 05 ⁇ m), P- A 1 .. 50 G a .. 5 .A carrier block layer 25 made of s (thickness 0. 01 35 M m), P- A 1.
- a wave guide layer 23 made of s (thickness 0.5 m), p — A 1 .. 33 Ga .. S7
- a cladding layer 22 made of s (thickness 0. 8 m), and p sequentially formed process key Yap layer comprising one GaA s.
- an inorganic film such as SiO 2 is formed by vapor deposition or the like, and a window having a desired stripe width is formed thereon by using a photolithography method. 22 and a part of the waveguide layer 23 are removed. Then, as the second crystal growth, A1. .-. 0. 6 . A current confinement layer 24 composed of 8.3 is buried. At this time, selective growth is used. After removing the inorganic film used as a mask, a cap layer 21 (thickness 2 jum) made of P-GaAs is formed by the third crystal growth. Thereafter, when an electrode is formed on the substrate and the cap layer 21 and an electric current flows, laser oscillation is enabled by carrier injection.
- a flow constriction layer 24 having a lower refractive index by increasing the A1 composition than the waveguide layer 23 is formed so as to sandwich the stripe-shaped active region 34. Thereby, a refractive index difference is provided between the active region 34 and the buried region 33 where the current confinement layer 24 exists, thereby forming a refractive index waveguide structure.
- the refractive index waveguide structure can be easily realized by the current constriction formed at a distance lower than the active layer and the A 1 composition as compared with the conventional structure.
- the semiconductor laser device thus obtained had a threshold current of 30 mA and a slope efficiency of 1.0 W / A.
- a current-light output characteristic with good linearity without kink can be obtained up to an output of 10 OmW, and the far-field image of the laser beam is a unimodal Gaussian type with a good refractive index waveguide ellipse. It was confirmed that.
- FIG. 7 shows a structure of an example of a TJS type refractive index guided semiconductor laser to which the present invention can be applied! It is.
- a buffer layer 32 made of n-GaAs a cladding layer 31 made of n-A1GaAs, a waveguide layer 30 made of n-A1GaAs, and a layer made of n-A1GaAs Carrier blocking layer 29, side barrier layer 28 made of non-doped A1GaAs, active layer 27 consisting of two quantum well layers made of non-doped GaAs and barrier layer made of non-doped A1GaAs, non-doped A Side barrier layer 26 composed of 1 GaAs, carrier block layer 25 composed of p-A 1 GaAs, waveguide layer 23 composed of p-A 1 GaAs, cladding composed of P-Al GaAs A layer 22 and a cap layer 21 made of P-GaAs are sequentially formed.
- carrier block layer 25 composed of p
- a semiconductor laser device was manufactured using the same process as in Example 1.
- composition and thickness of each layer used at this time are as shown in (Table 4).
- the semiconductor laser device thus obtained has a stripe current of 96% / 4% with a stripe width of 6 ⁇ and a cavity length of 500 jum. O mA, Slope efficiency 1. O WZA. In addition, good current-light output characteristics with good linearity without kink can be obtained up to an output power of 20 O mW.
- the far-field pattern of the laser beam is a single-peak Gaussian type, with a good refractive index waveguide structure. It was confirmed that there was.
- a large AN eff can be obtained even if a current confinement layer having an A1 composition lower than that of the reference example (symmetric) is obtained due to asymmetry, and a good element is produced.
- the same effect can be expected even if the distance from the carrier block layer is increased instead of decreasing the A1 composition of the current confinement layer. By increasing the distance, an element can be manufactured with a larger margin.
- the material forming the semiconductor laser does not need to include all of Ga, Al, and As, and it is also possible to use other materials in addition to the material. It can be applied to any refractive index guided semiconductor laser such as a strained quantum well laser using s. In addition, the present invention can be applied to a so-called GRIN (Graded-Index) structure, DH (Double Heterostructure) structure, and the like even if the active layer has an oval shape.
- GRIN Gramded-Index
- DH Double Heterostructure
- the carrier blocking layer plays a role of confining the injected carriers in the active layer, and the desired effect is obtained by forming the low-current composition narrowing layer having a low A 1 composition far from the active layer. Since the refractive index difference can be ensured, it is possible to realize a refractive index guided semiconductor laser device which is easy to manufacture and has high reliability.
- the adoption of the asymmetric waveguide shifts the waveguide mode to the current confinement layer, so that a larger refractive index difference can be formed.Therefore, there is a margin for the distance between the current confinement layer from the active layer and the A1 composition ratio. Spread, easy to manufacture and large design flexibility Become.
- composition of A1 in employment other than ⁇ ⁇ ⁇ can be kept low, the influence of oxidation can be reduced, and the electrical, thermal and optical properties can be improved. Thus, it is possible to obtain a high-output and easy-to-manufacture refractive index guided semiconductor laser device.
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Description
Claims
Priority Applications (6)
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JP51310396A JP3576560B2 (ja) | 1994-10-18 | 1995-10-16 | 半導体レーザ素子 |
EP95934310A EP0788203B1 (en) | 1994-10-18 | 1995-10-16 | Semiconductor laser device |
US08/817,602 US6118799A (en) | 1994-10-18 | 1995-10-16 | Semiconductor laser device |
CA002203117A CA2203117C (en) | 1994-10-18 | 1995-10-16 | Semiconductor laser device |
DE69517044T DE69517044T2 (de) | 1994-10-18 | 1995-10-16 | Halbleiterlaservorrichtung |
KR1019970702436A KR100309952B1 (ko) | 1994-10-18 | 1995-10-16 | 반도체레이저소자 |
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JP25243194 | 1994-10-18 | ||
JP6/252431 | 1994-10-18 | ||
JP6/328766 | 1994-12-28 | ||
JP32876694 | 1994-12-28 |
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WO1996012328A1 true WO1996012328A1 (fr) | 1996-04-25 |
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PCT/JP1995/002118 WO1996012328A1 (fr) | 1994-10-18 | 1995-10-16 | Laser a semi-conducteur |
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US (1) | US6118799A (ja) |
EP (1) | EP0788203B1 (ja) |
JP (1) | JP3576560B2 (ja) |
KR (1) | KR100309952B1 (ja) |
CA (1) | CA2203117C (ja) |
DE (1) | DE69517044T2 (ja) |
WO (1) | WO1996012328A1 (ja) |
Cited By (2)
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US6171878B1 (en) | 1997-09-18 | 2001-01-09 | Mitsui Chemicals Inc. | Method of fabricating semiconductor laser using selective growth |
US6487225B2 (en) * | 1998-02-04 | 2002-11-26 | Mitsui Chemicals Inc. | Surface-emitting laser device |
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JP3859839B2 (ja) * | 1997-09-30 | 2006-12-20 | 富士フイルムホールディングス株式会社 | 屈折率導波型半導体レーザ装置 |
JPH11163458A (ja) * | 1997-11-26 | 1999-06-18 | Mitsui Chem Inc | 半導体レーザ装置 |
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US6577658B1 (en) | 1999-09-20 | 2003-06-10 | E20 Corporation, Inc. | Method and apparatus for planar index guided vertical cavity surface emitting lasers |
JP2001210910A (ja) * | 1999-11-17 | 2001-08-03 | Mitsubishi Electric Corp | 半導体レーザ |
US6597717B1 (en) * | 1999-11-19 | 2003-07-22 | Xerox Corporation | Structure and method for index-guided, inner stripe laser diode structure |
JP2002314203A (ja) * | 2001-04-12 | 2002-10-25 | Pioneer Electronic Corp | 3族窒化物半導体レーザ及びその製造方法 |
JP3797151B2 (ja) * | 2001-07-05 | 2006-07-12 | ソニー株式会社 | レーザダイオード、光学ピックアップ装置、光ディスク装置および光通信装置 |
US7177336B2 (en) * | 2002-04-04 | 2007-02-13 | Sharp Kabushiki Kaisha | Semiconductor laser device |
EP1492209B1 (en) | 2003-06-27 | 2008-01-09 | Nichia Corporation | Nitride semiconductor laser device having current blocking layer and method of manufacturing the same |
EP2015412B1 (en) * | 2007-07-06 | 2022-03-09 | Lumentum Operations LLC | Semiconductor laser with narrow beam divergence. |
CN102204040B (zh) * | 2008-10-31 | 2013-05-29 | 奥普拓能量株式会社 | 半导体激光元件 |
CN109417276B (zh) * | 2016-06-30 | 2021-10-15 | 新唐科技日本株式会社 | 半导体激光器装置、半导体激光器模块及焊接用激光器光源系统 |
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- 1995-10-16 JP JP51310396A patent/JP3576560B2/ja not_active Expired - Lifetime
- 1995-10-16 EP EP95934310A patent/EP0788203B1/en not_active Expired - Lifetime
- 1995-10-16 WO PCT/JP1995/002118 patent/WO1996012328A1/ja active IP Right Grant
- 1995-10-16 DE DE69517044T patent/DE69517044T2/de not_active Expired - Lifetime
- 1995-10-16 US US08/817,602 patent/US6118799A/en not_active Expired - Lifetime
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Also Published As
Publication number | Publication date |
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JP3576560B2 (ja) | 2004-10-13 |
US6118799A (en) | 2000-09-12 |
DE69517044T2 (de) | 2000-10-26 |
EP0788203A1 (en) | 1997-08-06 |
DE69517044D1 (de) | 2000-06-21 |
CA2203117C (en) | 2001-12-25 |
KR100309952B1 (ko) | 2001-12-17 |
EP0788203B1 (en) | 2000-05-17 |
KR970707620A (ko) | 1997-12-01 |
CA2203117A1 (en) | 1996-04-25 |
EP0788203A4 (en) | 1997-12-10 |
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