Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
  • C08G64/04—Aromatic polycarbonates
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
  • C08G64/04—Aromatic polycarbonates
  • C08G64/06—Aromatic polycarbonates not containing aliphatic unsaturation
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
  • B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
  • C08K5/005—Stabilisers against oxidation, heat, light, ozone
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/04—Oxygen-containing compounds
  • C08K5/05—Alcohols; Metal alcoholates
  • C08K5/053—Polyhydroxylic alcohols
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/04—Oxygen-containing compounds
  • C08K5/10—Esters; Ether-esters
  • C08K5/101—Esters; Ether-esters of monocarboxylic acids
  • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/49—Phosphorus-containing compounds
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/49—Phosphorus-containing compounds
  • C08K5/51—Phosphorus bound to oxygen
  • C08K5/52—Phosphorus bound to oxygen only
  • C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
  • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
  • B29K2069/00—Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
  • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
  • B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
  • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2369/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2469/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L2201/00—Properties
  • C08L2201/10—Transparent films; Clear coatings; Transparent materials
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L2205/00—Polymer mixtures characterised by other features
  • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
  • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Definitions

• the present invention relates to a polycarbonate resin composition for a thin optical component, and a method for producing a thin optical component. More specifically, the present invention relates to a polycarbonate resin composition for a thin optical component, having favorable fluidity as well as excellent strength, and a method for producing a thin optical component.
• planar light source devices are incorporated for complying with demands for thinning, weight reduction, power saving, and achievement of higher definition.
• planar light source devices are provided with a light guide plate having a wedge-shaped cross-section having a uniformly inclined plane on one side, or a flat-plate-shaped light guide plate.
• the light guide plate has an irregular pattern formed on its surface, for imparting light-scattering function.
• Such a light guide plate is obtained by injection molding of a thermoplastic resin, and the irregular pattern described above is imparted by transfer of irregularity formed on a surface of an insert.
• resin materials such as polymethyl methacrylate (PMMA).
• PMMA polymethyl methacrylate
• PMMA has an advantage in that thin-wall molding is easily possible because of its excellent fluidity, it has a drawback in that its low impact resistance easily causes cracking upon molding or handling, and upon incorporation into a liquid crystal display device.
• polycarbonate resins have excellent impact resistance, their fluidity is low compared to PMMA. Therefore, molding of very thin light guide plates has been very difficult therewith.
• Patent Document 1 a composition for a light guide plate, which composition achieves more than a certain level of impact resistance while suppressing a decrease in the fluidity by inclusion of a polycarbonate resin having a molecular weight within a particular range, has been proposed.
• the molecular weights of polycarbonate resins have become even lower for further improvement of the fluidity, causing a problem that cracking occurs upon molding or handling, or upon incorporation into a liquid crystal display device.
• Patent Document 3 describes a polycarbonate resin having improved fluidity containing bisphenol A and bisphenol E.
• Patent Documents 4 and 5 also describe polycarbonate resins having improved fluidity using particular bisphenol compounds.
• such polycarbonate resins also have a problem in that they are impractical because of their extremely low heat resistance, and that, since their fluidity and impact resistance are insufficient for obtaining light guide plates, thin molded articles cannot be obtained.
• Patent Document 5 JP 59-131623 A
• the present invention was made in view of such facts, and aims to provide a polycarbonate resin composition for a thin optical component, which composition has favorable fluidity as well as favorable strength, and a method for producing a thin optical component.
• a polycarbonate resin composition for a thin optical component having high fluidity and high strength can be obtained by inclusion of an aromatic polycarbonate copolymer (B) containing a particular amount of a structural unit derived from a particular aromatic dihydroxy compound, in an aromatic polycarbonate resin (A) having a viscosity average molecular weight (Mv) of 10,000 to 15,000, thereby completing the present invention. That is, the present invention is constituted by the following [1] to [7].
• a polycarbonate resin composition for a thin optical component comprising:
• R 1 represents C 8 -C 24 alkyl or alkenyl
• R 2 and R 3 each independently represent a C 1 -C 15 monovalent hydrocarbon group
• a and b each independently represent an integer of 0 to 4
• a carbonate structural unit (ii) represented by the following Formula (2):
• a method for producing a thin optical component the method comprising the step of molding the polycarbonate resin composition recited in any one of [1] to [4].
• the strength of a molded article after molding can be increased while fluidity sufficient for molding of a thin optical member can be maintained. Therefore, cracking, which may occur in a thin optical member, can be remarkably reduced.
• the term “to” in the present description is used such that the values described before and after it are included as the lower limit and the upper limit, respectively.
• the term “part” means part by mass, which is expressed on a mass basis.
• the type of the aromatic polycarbonate resin (A) used for the polycarbonate resin composition for a thin optical component of the present invention is not limited.
• the aromatic polycarbonate resin (A) is a polycarbonate resin that is different from the aromatic polycarbonate copolymer (B).
• a single type of aromatic polycarbonate resin (A) may be used, or two or more types of aromatic polycarbonate resins (A) may be used in an arbitrary combination at arbitrary ratios.
• Examples of the aromatic polycarbonate resin (A) of the present invention include aromatic polycarbonate resins prepared by reacting an aromatic dihydroxy compound with a carbonate-forming compound. In this process, in addition to the aromatic dihydroxy compound and the carbonate-forming compound, a polyhydroxy compound and/or the like may be reacted.
• the aromatic polycarbonate resin (A) may be either linear or branched.
• the polycarbonate resin (A) may be a homopolymer, which is composed of a single kind of repeat units, or may be a copolymer, which includes two or more kinds of repeat units. This copolymer may be selected from various forms of copolymers including random copolymers and block copolymers. Such polycarbonate polymers are normally thermoplastic resins.
• aromatic dihydroxy compound as a material of the aromatic polycarbonate resin (A) include: dihydroxybenzenes such as 1,2-dihydroxybenzene, 1,3-dihydroxybenzene (that is, resorcinol), and 1,4-dihydroxybenzene; dihydroxybiphenyls such as 2,5-dihydroxybiphenyl, 2,2′-dihydroxybiphenyl, and 4,4′-dihydroxybiphenyl; dihydroxynaphthalenes such as 2,2′-dihydroxy-1,1′-binaphthyl, 1,2-dihydroxynaphthalene, 1,3-dihydroxynaphthalene, 2,3-dihydroxynaphthalene, 1,6-dihydroxynaphthalene, 2,6-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, and 2,7-dihydroxynaphthalene; dihydroxydiaryl ethers such as 2,2′-dihydroxydipheny
• bis(hydroxyaryl)alkanes such as 2,2-bis(4-hydroxyphenyl)propane (that is, bisphenol A), 1,1-bis(4-hydroxyphenyl)propane, 2,2-bis(3-methyl-4-hydroxyphenyl)propane, 2,2-bis(3-methoxy-4-hydroxyphenyl)propane, 2-(4-hydroxyphenyl)-2-(3-methoxy-4-hydroxyphenyl)propane, 1,1-bis(3-tert-butyl-4-hydroxyphenyl)propane, 2,2-bis(3,5-dimethyl-4-hydroxyphenyl)propane, 2,2-bis(3-cyclohexyl-4-hydroxyphenyl)propane, 2-(4-hydroxyphenyl)-2-(3-cyclohexyl-4-hydroxyphenyl)propane, ⁇ , ⁇ ′-bis(4-hydroxyphenyl)-1,4-diisopropylbenzene, 1,3-bis[2-(4-
• bis(hydroxyaryl)cycloalkanes such as 1,1-bis(4-hydroxyphenyl)cyclopentane, 1,1-bis(4-hydroxyphenyl)cyclohexane, 1,1-bis(4-hydroxyphenyl)-3,3-dimethylcyclohexane, 1,1-bis(4-hydroxyphenyl)-3,4-dimethylcyclohexane, 1,1-bis(4-hydroxyphenyl)-3,5-dimethylcyclohexane, 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane, 1,1-bis(4-hydroxy-3,5-dimethylphenyl)-3,3,5-trimethylcyclohexane, 1,1-bis(4-hydroxyphenyl)-3-propyl-5-methylcyclohexane, 1,1-bis(4-hydroxyphenyl)-3-tert-butyl-cyclohexane, 1,1-bis(4-hydroxyphenyl
• cardo structure-containing bisphenols such as 9,9-bis(4-hydroxyphenyl)fluorene and 9,9-bis(4-hydroxy-3-methylphenyl)fluorene; dihydroxydiaryl sulfides such as 4,4′-dihydroxydiphenyl sulfide and 4,4′-dihydroxy-3,3′-dimethyldiphenyl sulfide; dihydroxydiaryl sulfoxides such as 4,4′-dihydroxydiphenyl sulfoxide and 4,4′-dihydroxy-3,3′-dimethyldiphenyl sulfoxide; and
• dihydroxydiaryl sulfones such as 4,4′-dihydroxydiphenyl sulfone and 4,4′-dihydroxy-3,3′-dimethyldiphenyl sulfone.
• bis(hydroxyaryl)alkanes are preferred, and bis(4-hydroxyphenyl)alkanes are more preferred.
• 2,2-bis(4-hydroxyphenyl)propane that is, bisphenol A is preferred.
• a single type of aromatic dihydroxy compound may be used, or two or more types of aromatic dihydroxy compounds may be used in an arbitrary combination at arbitrary ratios.
• examples of the carbonate-forming compound include carbonyl halides and carbonate esters.
• a single type of carbonate-forming compound may be used, or two or more types of carbonate-forming compounds may be used in an arbitrary combination at arbitrary ratios.
• carbonyl halides include phosgene; haloformates such as bischloroformate bodies of dihydroxy compounds, and monochloroformate bodies of dihydroxy compounds.
• carbonate esters include diaryl carbonates such as diphenyl carbonate and ditolyl carbonate; dialkyl carbonates such as dimethyl carbonate and diethyl carbonate; and biscarbonate bodies of dihydroxy compounds, monocarbonate bodies of dihydroxy compounds, and carbonate bodies of dihydroxy compounds such as cyclic carbonates.
• the method for producing the aromatic polycarbonate resin (A) used in the present invention is not limited, and an arbitrary method may be employed therefor.
• Examples of the method include interfacial polymerization, melt transesterification, pyridine method, ring-opening polymerization of cyclic carbonate compounds, and solid-phase transesterification of prepolymers. Preferred methods among these are concretely described below.
• the aromatic polycarbonate resin is produced by interfacial polymerization.
• the pH is usually maintained at not less than 9 in the presence of an organic solvent inert to the reaction, and an aqueous alkali solution.
• a carbonate-forming compound preferably phosgene
• interfacial polymerization is carried out in the presence of a polymerization catalyst to obtain an aromatic polycarbonate resin.
• a molecular weight modifier may be allowed to be present, and, for prevention of oxidation of the aromatic dihydroxy compound, an antioxidant may be allowed to present.
• the aromatic dihydroxy compound and the carbonate-forming compound are as described above.
• carbonate-forming compounds phosgene is preferably used.
• the method is specifically called the phosgene method.
• organic solvent inert to the reaction examples include chlorinated hydrocarbons such as dichloromethane, 1,2-dichloroethane, chloroform, monochlorobenzene, and dichlorobenzene; and aromatic hydrocarbons such as benzene, toluene, and xylene.
• chlorinated hydrocarbons such as dichloromethane, 1,2-dichloroethane, chloroform, monochlorobenzene, and dichlorobenzene
• aromatic hydrocarbons such as benzene, toluene, and xylene.
• a single type of organic solvent may be used, or two or more types of organic solvents may be used in an arbitrary combination at arbitrary ratios.
• alkali compound contained in the aqueous alkali solution examples include alkali metal compounds such as sodium hydroxide, potassium hydroxide, lithium hydroxide, and sodium hydrogen carbonate; and alkaline earth metal compounds. Sodium hydroxide and potassium hydroxide are especially preferred. A single type of alkali compound may be used, or two or more types of alkali compounds may be used in an arbitrary combination at arbitrary ratios.
• the concentration of the alkali compound in the aqueous alkali solution is not limited.
• the alkali compound is usually used in an amount of 5 to 10% by mass for the purpose of controlling the pH of the aqueous alkali solution to 10 to 12 for the reaction.
• the molar ratio between the bisphenol compound and the alkali compound is preferably adjusted to usually 1:1.9 or more, especially 1:2.0 or more, and usually 1:3.2 or less, especially 1:2.5 or less.
• polymerization catalyst examples include aliphatic tertiary amines such as trimethylamine, triethylamine, tributylamine, tripropylamine, and trihexylamine; alicyclic tertiary amines such as N,N′-dimethylcyclohexylamine and N,N′-diethylcyclohexylamine; aromatic tertiary amines such as N,N′-dimethylaniline and N,N′-diethylaniline; quaternary ammonium salts such as trimethylbenzylammonium chloride, tetramethylammonium chloride, and triethylbenzylammonium chloride; pyridine; guanine; and salts of guanidine.
• a single type of polymerization catalyst may be used, or two or more types of polymerization catalysts may be used in an arbitrary combination at arbitrary ratios.
• the molecular weight modifier examples include aromatic phenols having a monovalent phenolic hydroxyl group; aliphatic alcohols such as methanol and butanol; mercaptan; and phthalic imide. Aromatic phenols are especially preferred.
• aromatic phenols include alkyl-substituted phenols such as m-methylphenol, p-methylphenol, m-propylphenol, p-propylphenol, p-tert-butylphenol, and p-long-chain alkyl-substituted phenols; vinyl-containing phenols such as isopropenylphenol; epoxy-containing phenols; and carboxyl-containing phenols such as o-hydroxybenzoic acid and 2-methyl-6-hydroxyphenylacetic acid.
• a single type of molecular weight modifier may be used, or two or more types of molecular weight modifiers may be used in an arbitrary combination at arbitrary ratios.
• the amount of the molecular weight modifier used is usually not less than 0.5 mole, preferably not less than 1 mole, and usually not more than 50 moles, preferably not more than 30 moles, with respect to 100 moles of the aromatic dihydroxy compound. In cases where the amount of the molecular weight modifier is within this range, thermal stability and hydrolysis resistance of the thermoplastic resin composition can be increased.
• a reaction substrate(s), reaction medium/media, catalyst(s), additive(s), and/or the like may be mixed in an arbitrary order as long as a desired polycarbonate resin can be obtained.
• An appropriate order may be arbitrarily set.
• a molecular weight modifier may be mixed at an arbitrary timing between the reaction of the aromatic dihydroxy compound with phosgene (phosgenation) and the beginning of the polymerization reaction.
• the reaction temperature is usually 0 to 40° C.
• the reaction time is usually several minutes (for example, 10 minutes) to several hours (for example, 6 hours).
• the aromatic dihydroxy compound is as described above.
• examples of the diester carbonate include dialkyl carbonate compounds such as dimethyl carbonate, diethyl carbonate, and di-tert-butyl carbonate; diphenyl carbonate; and substituted diphenyl carbonates such as ditolyl carbonate.
• diphenyl carbonate and substituted diphenyl carbonates are preferred.
• Diphenyl carbonates are more preferred.
• a single type of diester carbonate may be used, or two or more types of diester carbonates may be used in an arbitrary combination at arbitrary ratios.
• the ratio between the aromatic dihydroxy compound and the diester carbonate is not limited as long as a desired polycarbonate resin can be obtained.
• the amount of the diester carbonate used is preferably not less than an equimolar amount, more preferably not less than 1.01 moles, with respect to 1 mole of the aromatic dihydroxy compound.
• the upper limit is usually 1.30 moles. In cases where the ratio is within this range, the amount of terminal hydroxyl groups can be adjusted to within a preferred range.
• an aromatic polycarbonate resin In an aromatic polycarbonate resin, the amount of its terminal hydroxyl groups tends to have a significant influence on the thermal stability, hydrolytic stability, color tone, and the like. Thus, the amount of terminal hydroxyl groups may be adjusted by an arbitrary known method, if necessary.
• an aromatic polycarbonate resin having a controlled amount of terminal hydroxyl groups can be usually obtained by controlling the mixing ratio between the diester carbonate and the aromatic dihydroxy compound, the degree of pressure reduction during the transesterification reaction, and/or the like. This operation usually also enables control of the molecular weight of the aromatic polycarbonate resin obtained.
• the mixing ratio is as described above.
• Examples of more positive control methods include a method in which a terminating agent is separately mixed during the reaction.
• Examples of the terminating agent in this process include monovalent phenols, monovalent carboxylic acids, and diester carbonates.
• a single type of terminating agent may be used, or two or more types of terminating agents may be used in an arbitrary combination at arbitrary ratios.
• a transesterification catalyst is used.
• An arbitrary transesterification catalyst may be used.
• an alkali metal compound(s) and/or an alkaline earth metal compound(s) is/are preferably used.
• a basic compound(s) such as a basic boron compound(s), basic phosphorus compound(s), basic ammonium compound(s), and/or amine compound(s) may be supplementarily used in combination.
• a single type of transesterification catalyst may be used, or two or more types of transesterification catalysts may be used in an arbitrary combination at arbitrary ratios.
• the reaction temperature is usually 100 to 320° C.
• the reaction is usually carried out under a reduced pressure of not more than 2 mmHg. More specifically, the operation may be carried out by allowing melt polycondensation reaction to proceed under the above conditions while removing by-products such as aromatic hydroxy compounds.
• the melt polycondensation reaction may be carried out by either a batch method or a continuous method.
• a reaction substrate(s), reaction medium/media, catalyst(s), additive(s), and/or the like may be mixed in an arbitrary order as long as a desired aromatic polycarbonate resin can be obtained.
• An appropriate order may be arbitrarily set.
• the melt polycondensation reaction is preferably carried out by a continuous method.
• a catalyst deactivator may be used, if necessary.
• a compound that neutralizes the transesterification catalyst may be arbitrarily used.
• the catalyst deactivator include sulfur-containing acidic compounds and derivatives thereof.
• a single type of catalyst deactivator may be used, or two or more types of catalyst deactivators may be used in an arbitrary combination at arbitrary ratios.
• the amount of the catalyst deactivator used is usually not less than 0.5 equivalent, preferably not less than 1 equivalent, and usually not more than 10 equivalents, preferably not more than 5 equivalents, with respect to the alkali metal or alkaline earth metal contained in the transesterification catalyst. Further, the amount of the catalyst deactivator is usually not less than 1 ppm, and usually not more than 100 ppm, preferably not more than 20 ppm, with respect to the aromatic polycarbonate resin.
• the viscosity average molecular weight [Mv] as calculated from the solution viscosity of the aromatic polycarbonate resin (A) used in the present invention is usually 10,000 to 15,000. In cases where the viscosity average molecular weight is not less than the lower limit of this range, the mechanical strength of the polycarbonate resin composition for a thin optical component of the present invention can be further increased, and therefore the strength of the thin optical component such as a light guide plate obtained by molding of the composition can be increased, so that the component becomes less likely to be cracked.
• the viscosity average molecular weight [Mv] of the aromatic polycarbonate resin (A) is preferably not less than 10,500, more preferably not less than 11,000, and preferably not more than 14,500, more preferably not more than 14,000, still more preferably not more than 13,500, especially preferably not more than 13,000.
• Two or more kinds of aromatic polycarbonate resins having different viscosity average molecular weights may be used as a mixture.
• an aromatic polycarbonate resin having a viscosity average molecular weight that is outside the preferred range may be mixed.
• the limiting viscosity [ ⁇ ] is a value obtained by measuring the specific viscosity [ ⁇ sp ] at each solution concentration [C] (g/dl) and applying the resulting value to the following equation.
• the concentration of terminal hydroxyl groups in the polycarbonate resin (A) is arbitrary, and may be appropriately selected. It is usually not more than 1000 ppm, preferably not more than 800 ppm, more preferably not more than 600 ppm. By this, the residence heat stability of the polycarbonate resin composition for a thin optical component of the present invention can be further increased. Regarding the lower limit, the residence heat stability is usually not less than 10 ppm, preferably not less than 30 ppm, more preferably not less than 40 ppm. By this, a decrease in the molecular weight can be suppressed, and the color tone of the polycarbonate resin composition for a thin optical component of the present invention can be further improved.
• the terminal hydroxyl group concentration is represented by the mass, expressed in ppm units, of the terminal hydroxyl groups with respect to the mass of the aromatic polycarbonate resin.
• colorimetry by the titanium tetrachloride/acetic acid method is used.
• the polycarbonate resin composition for a thin optical component of the present invention contains an aromatic polycarbonate copolymer (B) composed of a carbonate structural unit (i) represented by the following Formula (1) and a carbonate structural unit (ii) represented by the following Formula (2).
• an aromatic polycarbonate copolymer (B) composed of a carbonate structural unit (i) represented by the following Formula (1) and a carbonate structural unit (ii) represented by the following Formula (2).
• R 1 represents C 8 -C 24 alkyl or alkenyl.
• the carbon number of the alkyl group or alkenyl group in R 1 in the Formula (1) is more preferably not less than 9, still more preferably not less than 10, especially preferably not less than 11.
• the carbon number of the alkyl group or alkenyl group in R 1 in the carbonate structural unit of the Formula (1) is not more than 24.
• the carbon number of the R 1 is more preferably not more than 22, still more preferably not more than 18, especially preferably not more than 16.
• Examples of the C 8 -C 24 alkyl include linear or branched alkyl groups, and alkyl groups partially having a cyclic structure.
• the C 8 -C 24 alkyl is preferably a linear or branched alkyl group.
• linear alkyl groups include n-octyl, n-nonyl, n-decyl, n-undecyl, n-dodecyl, n-tridecyl, n-tetradecyl, n-pentadecyl, n-hexadecyl, n-heptadecyl, n-octadecyl, n-nonadecyl, n-icosyl, n-icosyl, n-henicosyl, n-docosyl, n-tricosyl, and n-tetracosyl.
• n-Nonyl, n-decyl, n-undecyl, n-dodecyl, n-hexadecyl, and n-octadecyl are preferred.
• n-Nonyl, n-decyl, n-undecyl, and n-dodecyl are more preferred.
• n-Dodecyl is especially preferred.
• branched alkyl groups include methylheptyl, methyloctyl, methylnonyl, methyldecyl, methylundecyl, methyldodecyl, methyltridecyl, methyltetradecyl, methylpentadecyl, methylhexadecyl, methylheptadecyl, methyloctadecyl, methylnonadecyl, methylicosyl, methylicosyl, methylhenicosyl, methyldocosyl, methyltricosyl,
• dimethylheptyl dimethyloctyl, dimethylnonyl, dimethyldecyl, dimethylundecyl, dimethyldodecyl, dimethyltridecyl, dimethyltetradecyl, dimethylpentadecyl, dimethylhexadecyl, dimethylheptadecyl, dimethyloctadecyl, dimethylnonadecyl, dimethylicosyl, dimethylicosyl, dimethylhenicosyl, dimethyldocosyl,
• the alkenyl group is not limited as long as it has a structure wherein one or more carbon-carbon double bonds are included in the structure of a linear alkyl group or branched alkyl group described above.
• Specific examples of the alkenyl group include octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, icosenyl, henicosenyl, docosenyl, tricosenyl, tetracosenyl, and 4,8,12-trimethyltridecyl.
• R 2 and R 3 in the carbonate structural unit (i) of Formula (1) represent C 1 -C 15 monovalent hydrocarbon groups.
• the aromatic polycarbonate resin composition for a thin optical component of the present invention can have increased fluidity, strength, hardness, chemical resistance, and the like.
• Preferred examples of the C 1 -C 15 monovalent hydrocarbon groups include C 1 -C 15 alkyl groups and C 2 -C 15 alkenyl groups. These may be linear, branched, or cyclic.
• Examples of such monovalent hydrocarbon groups include methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, pentyl, n-hexyl, cyclohexyl, n-heptyl, n-octyl, n-nonyl, n-decyl, n-undecyl, n-dodecyl, n-tridecyl, n-tetradecyl, n-pentadecyl, phenyl, and tolyl.
• methyl is preferred.
• a and b in the carbonate structural unit (i) each independently represent an integer of 0 to 4, preferably 0 to 2, more preferably 0 or 1, still more preferably 0.
• the carbonate structural unit (i) include the structural units represented by the following Formulae (3) to (12). Among these, the structural units of Formulae (3) to (10) are more preferred; the structural units of Formulae (4) to (7) are still more preferred; the structural units of Formulae (4) and (6) are especially preferred; and the structural unit of Formula (6) is most preferred.
• the carbonate structural unit (i) represented by the Formula (1) in the aromatic polycarbonate copolymer (B) contained in the polycarbonate resin composition for a thin optical component of the present invention include the structural units represented by the following Formulae (13) to (15).
• the structural unit represented by Formula (13) is more preferred since it tends to increase the thermal stability.
• the isomeric structures of Formulae (14) and (15) may also be included at arbitrary ratios.
• more preferred specific examples of the carbonate structure (i) include the structural units represented by the following Formulae (16) to (25).
• the structural units of Formulae (16) to (23) are more preferred; the structural units of Formulae (17) to (20) are still more preferred; the structural units of Formulae (17) and (19) are especially preferred; and the structural unit of Formula (19) is most preferred.
• the carbonate structural unit (ii) represented by the Formula (2) in the aromatic polycarbonate copolymer (B) in the polycarbonate resin composition for a thin optical component of the present invention is preferably the bisphenol A-derived structural unit represented by the following Formula (26).
• the isomeric structural unit represented by Formula (27) may also be included at an arbitrary ratio.
• the ratio of the carbonate structural unit (i) represented by Formula (1) is more than 10 mol % and less than 39 mol % with respect to a total of 100 mol % of the carbonate structural unit (i) represented by the Formula (1) and the carbonate structural unit (ii) represented by the Formula (2) in the aromatic polycarbonate copolymer (B).
• the ratio of the carbonate structural unit represented by the Formula (1) is preferably not less than 12 mol %, more preferably not less than 14 mol %, still more preferably not less than 16 mol %, especially preferably not less than 18 mol %, most preferably not less than 22 mol %.
• the ratio is preferably not more than 38.5 mol %, more preferably not more than 38 mol %, still more preferably not more than 37.5 mol %, especially preferably not more than 37 mol %, most preferably not more than 36.5 mol %.
• the molecular weight of the aromatic polycarbonate copolymer (B) contained in the polycarbonate resin composition for a thin optical component of the present invention is not limited, and usually 5000 to 50,000 in terms of the viscosity average molecular weight (Mv) as calculated from the solution viscosity.
• Mv viscosity average molecular weight
• the mechanical properties of the polycarbonate resin composition for a thin optical component of the present invention are likely to be poor, and the aromatic polycarbonate copolymer (B) tends to cause bleeding.
• the viscosity average molecular weight exceeds the upper limit, the fluidity tends to be insufficient, which is not preferred.
• the viscosity average molecular weight (Mv) of the aromatic polycarbonate copolymer (B) is preferably not less than 9,000, more preferably not less than 10,000, still more preferably not less than 11,000, and preferably not more than 30,000, more preferably not more than 25,000, still more preferably not more than 20,000, especially preferably not more than 18,000.
• the definition and the measurement method for the viscosity average molecular weight (Mv) of the aromatic polycarbonate copolymer (B) are the same as those for the viscosity average molecular weight (Mv) of the aromatic polycarbonate resin (A) described above.
• the amount of terminal hydroxyl groups in the aromatic polycarbonate copolymer (B) contained in the polycarbonate resin composition for a thin optical component of the present invention is not limited, and usually 10 to 2000 ppm.
• the amount is preferably not less than 20 ppm, more preferably not less than 50 ppm, still more preferably not less than 100 ppm.
• the amount is preferably not more than 1500 ppm, more preferably not more than 1000 ppm, still more preferably not more than 700 ppm.
• the amount of terminal hydroxyl groups is not less than the lower limit of this range, the hue and the productivity of the aromatic polycarbonate copolymer (B) of the present invention can be further improved.
• the amount is not more than the upper limit of this range, the thermal stability and the moist heat stability of the polycarbonate resin composition for a thin optical component of the present invention can be further improved.
• the unit of the terminal hydroxyl group concentration is the same as in the measurement method and the definition for the terminal hydroxyl groups in the aromatic polycarbonate resin (A) described above.
• the aromatic polycarbonate copolymer (B) is obtained by polycondensation of an aromatic dihydroxy compound(s) necessary for forming the carbonate structures with a carbonate-forming compound(s).
• aromatic dihydroxy compound necessary for forming the carbonate structural unit (i) include the aromatic dihydroxy compounds represented by the following Formula (28).
• aromatic dihydroxy compound necessary for forming the carbonate structural unit (i) include the aromatic dihydroxy compounds represented by the following Formulae (29) to (31).
• the aromatic dihydroxy compounds represented by Formula (29) are more preferred since they tend to increase the thermal stability.
• the aromatic dihydroxy compounds of Formulae (30) and (31) may also be included at arbitrary ratios.
• R 1 , R 2 , R 3 , a, and b are the same as those of the carbonate structural unit (i) represented by the Formula (1). From such a point of view, more preferred specific examples of the aromatic dihydroxy compound necessary for forming the carbonate structural unit (i) include the following:
• the aromatic dihydroxy compound necessary for forming the carbonate structural unit (i) of the aromatic polycarbonate copolymer (B) is more preferably 1,1-bis(4-hydroxyphenyl) octane, 1,1-bis(4-hydroxyphenyl)nonane, 1,1-bis(4-hydroxyphenyl)decane, 1,1-bis(4-hydroxyphenyl)undecane, 1,1-bis(4-hydroxyphenyl)dodecane, 1,1-bis(4-hydroxyphenyl)tridecane, 1,1-bis(4-hydroxyphenyl)tetradecane, 1,1-bis(4-hydroxyphenyl)pentadecane, 1,1-bis(4-hydroxyphenyl)hexadecane, 1,1-bis(4-hydroxyphenyl)heptadecane, 1,1-bis(4-hydroxyphenyl)octadecane, or 1,1-
• aromatic dihydroxy compound necessary for forming the carbonate structural unit (ii) include 2,2-bis(4-hydroxyphenyl)propane, 2,2-bis(2-hydroxyphenyl)propane, and 2-(2-hydroxyphenyl)-2-(4-hydroxyphenyl)propane.
• 2,2-bis(4-hydroxyphenyl)propane the so-called bisphenol A is more preferred.
• Examples of the carbonate-forming compound include carbonyl halides and carbonate esters.
• a single type of carbonate-forming compound may be used, or two or more types of carbonate-forming compounds may be used in an arbitrary combination at arbitrary ratios.
• carbonyl halides include phosgene; haloformates such as bischloroformate bodies of dihydroxy compounds, and monochloroformate bodies of dihydroxy compounds.
• carbonate esters include the compounds represented by the following Formula (32), for example, aryl carbonates; dialkyl carbonates; biscarbonate bodies of dihydroxy compounds; monocarbonate bodies of dihydroxy compounds; and carbonate bodies of dihydroxy compounds such as cyclic carbonates.
• Formula (32) for example, aryl carbonates; dialkyl carbonates; biscarbonate bodies of dihydroxy compounds; monocarbonate bodies of dihydroxy compounds; and carbonate bodies of dihydroxy compounds such as cyclic carbonates.
• R 4 and R 5 each independently represent C 1 -C 30 alkyl, aryl, or arylalkyl.
• the carbonate ester may be referred to as dialkyl carbonate
• R 4 and R 5 when R 4 and R 5 are aryl, the carbonate ester may be referred to as diaryl carbonate.
• both R 4 and R 5 are preferably aryl.
• the carbonate ester is more preferably a diaryl carbonate represented by the following Formula (33).
• R 6 and R 7 each independently represent a halogen atom, nitro, cyano, C 1 -C 20 alkyl, C 1 -C 20 alkoxycarbonyl, C 4 -C 20 cycloalkyl, or C 6 -C 20 aryl, and p and q each independently represent an integer of 0 to 5.
• Such a carbonate ester include dialkyl carbonates such as dimethyl carbonate, diethyl carbonate, and di-t-butyl carbonate; and (substituted) diaryl carbonates such as diphenyl carbonate, bis(4-methylphenyl)carbonate, bis(4-chlorophenyl)carbonate, bis(4-fluorophenyl)carbonate, bis(2-chlorophenyl)carbonate, bis(2,4-difluorophenyl)carbonate, bis(4-nitrophenyl)carbonate, bis(2-nitrophenyl)carbonate, bis(methylsalicylphenyl)carbonate, and ditolyl carbonate.
• diphenyl carbonate is preferred.
• These carbonate esters may be used individually, or two or more of these may be used as a mixture.
• the carbonate ester may be substituted with a dicarboxylic acid(s) and/or dicarboxylic acid ester(s).
• dicarboxylic acid(s) and/or dicarboxylic acid ester(s) include terephthalic acid, isophthalic acid, diphenyl terephthalate, and diphenyl isophthalate. In cases of substitution with such a dicarboxylic acid(s) and/or dicarboxylic acid ester(s), a polyester carbonate is obtained.
• the method for producing the aromatic polycarbonate copolymer (B) is the same as the method described above as an example of the production method for the aromatic polycarbonate resin (A).
• the polycarbonate resin composition for a thin optical component of the present invention preferably contains a polyalkylene glycol or a fatty acid ester thereof (C).
• a polyalkylene glycol or a fatty acid ester thereof (C) By the inclusion of such a polyalkylene glycol or a fatty acid ester thereof (C), the transmittance, hue, and brightness of the polycarbonate resin composition for a thin optical component of the present invention can be increased.
• polyalkylene glycol examples include homopolymers and copolymers of alkylene glycols, and derivatives thereof.
• specific examples of the polyalkylene glycol include C 2 -C 6 polyalkylene glycols such as polyethylene glycol, polypropylene glycol, and polytetramethylene glycol; random or block copolymers of polyoxyethylene-polyoxypropylene; and copolymers such as glyceryl ethers of polyoxyethylene-polyoxypropylene, and monobutyl ethers of polyoxyethylene-polyoxypropylene.
• polyalkylene glycol examples include polymers containing an oxyethylene unit, for example, polyethylene glycol, polypropylene glycol, poly(2-methyl)ethylene ether glycol, polytetramethylene ether glycol, polypropylene ether glycol, polytrimethylene ether glycol, polytetramethylene ether glycol, polypentamethylene ether glycol, polyhexamethylene ether glycol, and polyoxyethylene-polyoxypropylene copolymers, and derivatives thereof.
• polyethylene glycol polypropylene glycol
• poly(2-methyl)ethylene ether glycol polytetramethylene ether glycol
• polypropylene ether glycol polytrimethylene ether glycol
• polytetramethylene ether glycol polypentamethylene ether glycol
• polyhexamethylene ether glycol polyoxyethylene-polyoxypropylene copolymers
• the number average molecular weight of the polyalkylene glycol is usually 500 to 500,000, preferably 1000 to 100,000, more preferably 1000 to 50,000.
• the number average molecular weight of the polyalkylene glycol copolymer is the number average molecular weight calculated based on the hydroxyl value measured according to JIS K1577.
• fatty acid ester of the polyalkylene glycol fatty acid ester either a linear or branched fatty acid ester may be used.
• the fatty acid constituting the fatty acid ester may be either a saturated fatty acid or an unsaturated fatty acid.
• Fatty acid esters in which a part of the hydrogen atoms are substituted with a substituent(s) such as hydroxyl may also be used.
• fatty acid constituting the fatty acid ester examples include monovalent or divalent fatty acids having a carbon number of not less than 10, for example, monovalent saturated fatty acids such as capric acid, lauric acid, tridecylic acid, myristic acid, pentadecylic acid, palmitic acid, heptadecylic acid, stearic acid, nonadecanoic acid, arachic acid, behenic acid, lignoceric acid, cerotic acid, heptacosanoic acid, montanic acid, melissic acid, and lacceric acid; monovalent unsaturated fatty acids having a carbon number of not less than 10 such as unsaturated fatty acids including oleic acid, elaidic acid, linoleic acid, linolenic acid, arachidonic acid, cetoleic acid, and erucic acid; and divalent fatty acids having a carbon number of not less than 10 such as sebacic acid, undecan
• polyalkylene glycol fatty acid ester examples include polyethylene glycol monopalmitate, polyethylene glycol dipalmitate, polyethylene glycol monostearate, polyethylene glycol distearate, polyethylene glycol (monopalmitate-monostearate), polypropylene glycol monopalmitate, polypropylene glycol dipalmitate, polypropylene glycol monostearate, polypropylene glycol distearate, and polypropylene glycol (monopalmitate-monostearate).
• the content of the polyalkylene glycol or a fatty acid ester thereof (C) is preferably 0.01 to 1 part by mass with respect to a total of 100 parts by mass of the aromatic polycarbonate resin (A) and the aromatic polycarbonate copolymer (B).
• the content is more preferably not less than 0.02 part by mass, still more preferably not less than 0.03 part by mass, and more preferably not more than 0.9 part by mass, still more preferably not more than 0.8 part by mass, still more preferably not more than 0.7 part by mass, especially preferably not more than 0.6 part by mass.
• improvement of the hue and suppression of yellowing are likely to be insufficient, while in cases where the content exceeds 1 part by mass, yellowing and a decrease in the light transmittance are likely to occur.
• the polycarbonate resin composition for a thin optical component of the present invention preferably contains a heat stabilizer (D).
• a heat stabilizer By the inclusion of such a heat stabilizer, the hue and the thermal stability of the polycarbonate resin composition for a thin optical component of the present invention can be increased.
• the heat stabilizer (D) used in the polycarbonate resin composition for a thin optical component of the present invention is not limited as long as it is a known heat stabilizer, and examples of the heat stabilizer include phosphorus-based heat stabilizers, sulfur-based heat stabilizers, and hindered phenol antioxidants. Among these, phosphorus-based heat stabilizers and hindered phenol antioxidants are preferred since these are likely to allow production of a polycarbonate resin composition for a thin optical component having an excellent hue and residence heat stability. In particular, phosphorus-based heat stabilizers are effective for improvement of the initial hue, and hindered phenol antioxidants are effective for suppressing deterioration of the color tone and a decrease in the molecular weight during molding at high temperature.
• a phosphorus-based heat stabilizer(s) and a hindered phenol antioxidant(s) is preferred since, by this, an excellent hue and residence heat stability can be achieved, and deterioration of the color tone and a decrease in the molecular weight during molding at high temperature can be suppressed.
• Examples of the phosphorus-based heat stabilizer used in the present invention include phosphorous acid, phosphoric acid, phosphorous acid esters, and phosphoric acid esters. Phosphorous acid esters such as phosphite and phosphonite are preferred.
• phosphorus-based heat stabilizer examples include phosphorous acid esters represented by the following Formula (34).
• R 8 represents aryl or alkyl, and these may be either the same or different.
• R 8 is preferably aryl represented by the following Formula (35), Formula (36), or Formula (37).
• R 9 and R 10 each independently represent C 1 -C 10 alkyl.
• Examples of such a phosphorous acid ester include bis(2,4-di-tert-butylphenyl)pentaerythritol diphosphite, bis(2,6-di-tert-butyl-4-methylphenyl)pentaerythritol diphosphite, and bis(2,4-dicumylphenyl)pentaerythritol diphosphite.
• Specific examples of the phosphorous acid ester include commercially available products such as “Adekastab PEP-24G” and “Adekastab PEP-36”, manufactured by ADEKA Corporation; and “Doverphos S-9228”, manufactured by Dover Chemical Corporation.
• the alkyl group of R 8 is preferably C 1 -C 30 alkyl.
• Specific examples of the phosphorous acid ester include distearyl pentaerythritol diphosphite and dinonyl pentaerythritol diphosphite. Distearyl pentaerythritol diphosphite is especially preferred.
• phosphorus-based heat stabilizer examples include phosphorous acid esters represented by the following General Formula (38).
• each of R 11 to R 15 represents a hydrogen atom, aryl, or C 1 -C 20 alkyl, and these may be either the same or different.
• examples of the aryl or the alkyl in R 11 to R 15 include phenyl, methyl, ethyl, propyl, n-propyl, n-butyl, and tert-butyl.
• phenolic antioxidant examples include hindered phenol antioxidants.
• specific examples of the hindered phenol antioxidants include pentaerythritol tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, thiodiethylene bis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], N,N′-hexane-1,6-diylbis[3-(3,5-di-tert-butyl-4-hydroxyphenylpropionamide), 2,4-dimethyl-6-(1-methylpentadecyl)phenol, diethyl[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methyl]phosphonate, 3,3′,3′′,5,5′,5′′-
• pentaerythritol tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate] and octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate are preferred.
• Specific examples of such phenolic antioxidants include “Irganox 1010” and “Irganox 1076”, manufactured by BASF; and “Adekastab AO-50” and “Adekastab AO-60”, manufactured by ADEKA Corporation.
• the polycarbonate resin composition for a thin optical component of the present invention may contain one kind of heat stabilizer (D) or a mixture of two or more kinds of heat stabilizers (D).
• the content of the heat stabilizer(s) (D) is preferably 0.005 to 0.5 part by mass with respect to a total of 100 parts by mass of the aromatic polycarbonate resin (A) and the aromatic polycarbonate copolymer (B).
• the content of the thermal stabilizer (D) is more preferably not less than 0.01 part by mass, still more preferably not less than 0.02 part by mass, especially preferably not less than 0.05 part by mass. Further, the content is more preferably not more than 0.3 part by mass, still more preferably not more than 0.2 part by mass, especially preferably not more than 0.1 part by mass.
• an epoxy compound (E) a compound having one or more epoxy groups in the molecule may be used.
• Preferred specific examples of the compound include phenyl glycidyl ether, allyl glycidyl ether, t-butylphenyl glycidyl ether, 3,4-epoxycyclohexylmethyl-3′,4′-epoxycyclohexyl carboxylate, 3,4-epoxy-6-methylcyclohexylmethyl-3′,4′-epoxy-6′-methylcyclohexyl carboxylate, 2,3-epoxycyclohexylmethyl-3′,4′-epoxycyclohexyl carboxylate, 4-(3,4-epoxy-5-methylcyclohexyl)butyl-3′,4′-epoxycyclohexyl carboxylate, 3,4-epoxycyclohexylethylene oxide, cyclohexylmethyl 3,4-epoxycyclohexyl
• the epoxy compounds may be used individually, or two or more of the epoxy compounds may be used in combination.
• the content of the epoxy compound (E) is 0.0005 to 0.2 part by mass, preferably not less than 0.001 part by mass, more preferably not less than 0.003 part by mass, still more preferably not less than 0.005 part by mass, and preferably not more than 0.15 part by mass, more preferably not more than 0.1 part by mass, still more preferably not more than 0.05 part by mass, with respect to a total of 100 parts by mass of the aromatic polycarbonate resin (A) and the aromatic polycarbonate copolymer (B).
• the ratio between the contents of the phosphorus-based heat stabilizer (D) and the epoxy compound (E) is preferably within the range of 0.5 to 10 in terms of the mass ratio of (D)/(E). In cases where the mass ratio of (D)/(E) is below 0.5, the hue, especially the initial YI value, is poor, while in cases where the mass ratio exceeds 10, the heat discoloration resistance is poor.
• the mass ratio of (D)/(E) is preferably not less than 0.7, more preferably not less than 0.8, and preferably not more than 8, more preferably not more than 7, still more preferably not more than 6.
• the polycarbonate resin composition for a thin optical component of the present invention may further contain various additives as long as the effect of the present invention is not deteriorated.
• additives include flame retardants, mold release agents, ultraviolet absorbers, dyes and pigments, fluorescent brightening agents, anti-drip agents, antistatic agents, anti-clouding agents, lubricants, anti-blocking agents, dispersants, and antimicrobial agents.
• the melt viscosity of the polycarbonate resin composition for a thin optical component of the present invention is not limited, and may be appropriately selected depending on the shape of the molded article of interest.
• the flow value (Q value) as measured using a Koka flow tester according to Appendix C of JIS (1999) K7210 at 240° C. at 160 kgf/cm 2 is usually preferably not less than 6 (unit: 10 ⁇ 2 cm 3 /sec.), more preferably not less than 10, still more preferably not less than 17, especially preferably not less than 20, most preferably not less than 25.
• the Q value is an index of the melt viscosity. A higher Q value indicates a lower viscosity and a better fluidity.
• the upper limit of the Q value is not limited as long as the excellent physical properties of the polycarbonate resin composition for a thin optical component of the present invention are not deteriorated.
• the Q value is usually not more than 100, preferably not more than 90, more preferably not more than 80, still more preferably not more than 70, especially preferably not more than 60.
• the method for producing the polycarbonate resin composition for a thin optical component of the present invention is not limited, and known methods for producing polycarbonate resin compositions may be widely employed. Examples of such methods include methods in which the aromatic polycarbonate resin (A), the aromatic polycarbonate copolymer (B), and other components to be blended as required, are preliminarily mixed together using a mixer such as a tumbler or Henschel mixer, and then the resulting mixture is melt-kneaded in a mixer such as a Banbury mixer, roll, Brabender, single-screw kneading extruder, twin-screw kneading extruder, kneader, or the like.
• a mixer such as a tumbler or Henschel mixer
• the temperature during the melt kneading is usually within the range of 210 to 320° C., preferably 220 to 280° C., most preferably 225 to 260° C.
• the melt kneading temperature is too low, the mixture is exposed to significant shear during kneading, resulting in a local increase in the temperature. This may lead to deterioration of the color tone and occurrence of resin burning, which is not preferred.
• the melt kneading temperature is too high, the resin tends to suffer from yellowing, and may have a poor color tone, which is not preferred.
• the polycarbonate resin composition for a thin optical component of the present invention can be used for production of a thin optical component by pelletizing the polycarbonate resin composition and molding the resulting pellets by various molding methods.
• the composition is especially preferably used for molding of a thin optical component by injection molding.
• the resin temperature during the injection molding is usually 260 to 380° C.
• the molding is preferably carried out at a resin temperature higher than 260 to 300° C., that is, higher than the temperatures generally applied to injection molding of a polycarbonate resin.
• the resin temperature is preferably 305 to 380° C., more preferably 310 to 375° C., still more preferably 315 to 370° C., especially preferably 320 to 365° C.
• the temperature set for the barrel is understood as the resin temperature.
• the thin molded article in the present invention means a molded article having a plate-like portion with a thickness of usually not more than 1 mm, preferably not more than 0.8 mm, more preferably not more than 0.6 mm.
• the plate-like portion may be either a flat plate or a bent plate, and may have either a flat surface or an irregular surface.
• a cross-section of the plate-like portion may have an inclined plane, or may be a wedge-shaped cross-section or the like.
• the thin optical component examples include components of devices/appliances that directly or indirectly use light sources such as LEDs, organic EL, incandescent lamps, fluorescent lamps, and cathode lamps.
• Representative examples of such components include light guide plates and members for surface emitters.
• a light guide plate is used for guiding light from a light source such as an LED in a liquid crystal backlight unit, or in a display device or an illuminating device.
• a light guide plate allows light to enter from its lateral side or back side, and usually diffuses the light through irregularities provided on its surface to cause emission of uniform light. It usually has a flat-plate shape, and may or may not have irregularities on its surface.
• Light guide plates are usually preferably molded by injection molding, ultra-high-speed injection molding, injection compression molding, or the like.
• the light guide plate by the polycarbonate resin composition for a thin optical component of the present invention can be favorably used in the fields of liquid crystal backlight units, and various display devices and illuminating devices.
• Examples of such devices include mobile terminals such as mobile phones, mobile notebooks, netbooks, slate PCs, tablet PCs, smartphones, and tablet terminals; cameras; watches/clocks; notebook PCs; displays; and illuminating devices.
• An aromatic polycarbonate copolymer (B) was produced according to the following Production Example.
• a raw material mixture was prepared by mixing 40 parts by mass of 1,1-bis(4-hydroxyphenyl)dodecane, 60 parts by mass of 2,2-bis(4-hydroxyphenyl)propane (bisphenol A), 107 parts by mass of diphenyl carbonate, and, as a catalyst, 2 wt % aqueous cesium carbonate solution such that cesium carbonate was contained at 0.5 ⁇ mol per 1 mol of total dihydroxy compounds.
• the resulting mixture was fed to a first reactor equipped with a stirrer, heating medium jacket, vacuum pump, and reflux condenser. After replacing the atmosphere with nitrogen, a heating medium at a temperature of 230° C.
• the pressure in the first reactor was reduced from 101.3 kPa (760 Torr) to 13.3 kPa (100 Torr) for 40 minutes, during which phenol produced as a by-product of oligomerization reaction of the aromatic dihydroxy compounds and diphenyl carbonate was removed by distillation.
• transesterification reaction was carried out for 80 minutes.
• the oligomer in the first reactor was transferred into a second reactor at an internal temperature of 240° C. equipped with a stirrer, heating medium jacket, vacuum pump, and reflux condenser. While stirring the oligomer at 38 rpm, the internal temperature was increased using the heating medium jacket.
• the pressure in the second reactor in terms of the absolute pressure, was reduced from 101.3 kPa to 13.3 kPa for 40 minutes.
• the temperature was kept increased, and the internal pressure, in terms of the absolute pressure, was reduced from 13.3 kPa to 399 Pa (3 Torr) for 40 minutes while removing distilled phenol to the outside of the system.
• the temperature was further kept increased, and when the absolute pressure in the second reactor reached 70 Pa (about 0.5 Torr), the pressure of 70 Pa was maintained to perform polycondensation reaction.
• the final internal temperature of the second reactor was 255° C.
• the stirring power of the stirrer in the second reactor reached a predetermined value, the polycondensation reaction was stopped. After restoring the pressure in the rector with nitrogen, pressure was applied to allow extraction from the bottom of the tank. By cooling in a water-cooling tank, an aromatic polycarbonate copolymer was obtained.
• butyl paratoluenesulfonate was mixed at 5 ppm with the obtained aromatic polycarbonate copolymer, and the resulting mixture was melt-kneaded in a 30-mm diameter twin-screw extruder at 240° C. to form a strand-shaped product, followed by cutting it with a pelletizer to obtain a pellet-shaped aromatic polycarbonate copolymer.
• the ratio of the carbonate structure (i) derived from the Formula (19) to the total carbonate structural units was 30 mol %, and the viscosity average molecular weight (Mv) was 15,000.
• Aromatic A1 An aromatic polycarbonate resin produced by polycarbonate interfacial polymerization using bisphenol A resin (A) as a starting material. Viscosity average molecular weight (Mv): 14,000 A2 An aromatic polycarbonate resin produced by interfacial polymerization using bisphenol A as a starting material. Viscosity average molecular weight (Mv): 12,500 Aromatic B An aromatic polycarbonate copolymer composed polycarbonate of the structural units of Formula (19) and copolymer (B) Formula (26).
• Table 1 Each component shown in Table 1 was blended at the ratio (part by mass) described in Table 2, and the resulting mixture was mixed in a tumbler for 20 minutes. Thereafter, the mixture was melt-kneaded in a twin-screw extruder having a screw diameter of 22 mm with a vent (“TEM26SX”, manufactured by Toshiba Machine Co., Ltd.) at a cylinder temperature of 240° C. and a screw speed of 180 rpm, and pellets were obtained by strand cutting.
• TEM26SX manufactured by Toshiba Machine Co., Ltd.
• the flow value (Q value; unit, cc/sec.) was measured using a CFT-500D type flow tester manufactured by Shimadzu Corporation and an orifice of 1-mm diameter ⁇ 10 mm according to Appendix C of JIS (1999) K7210 at 240° C. at 160 kgf/cm 2 with a preheating time of 7 minutes.
• Table 2 shows the values obtained. A higher flow value (Q value) indicates a higher fluidity and better moldability, while a lower flow value (Q value) indicates a lower fluidity and poorer moldability.
• Injection molding was carried out using an injection molding machine (J55-60H, manufactured by Japan Steel Works, Ltd.) at a cylinder temperature of 260° C. and a mold temperature of 80° C. with a molding cycle of 50 seconds to mold an ISO multi-purpose test piece (3 mm).
• the prepared ISO multi-purpose test piece (3-mm thickness) was subjected to notch processing, and the Charpy notched impact strength (unit: kJ/m 2 ) was measured at 23° C.
• a flat-plate-shaped light guide plate with a short side of 61 mm, a long side of 110 mm, and a thickness of 0.45 mm having a prism on its mold-fixed side was molded by injection molding.
• the prism was provided with a pattern having a 50- ⁇ m pitch and a 14- ⁇ m depth.
• the injection molding was carried out using an injection molding machine “HSP100A” manufactured by Sodick Plustech Co., Ltd. at a mold temperature of 40° C., a cylinder temperature of 360° C., and an injection speed of 400 mm/sec. The molding was carried out for 50 shots, and the number of cracked plates was counted.
• the light guide plate obtained as described above was subjected to a light guide plate bending test using Instron (Type 5544, manufactured by Instron), wherein the support span was 10 mm; the test speed was 10 mm/min.; the bend direction was parallel to the direction of the flow during molding; the molded article was placed such that the prism pattern faced downward; and a jig having a width of 3 mm and a point angle of 30° was used.
• the maximum point load (unit: N) was measured. A higher maximum point load indicates a higher strength, which means that cracking is less likely to occur.
• the obtained pellets were dried using a hot air circulation dryer at 100° C. for 5 to 7 hours, and then molded into a long-optical-path molded article (300 mm ⁇ 7 mm ⁇ 4 mm) using an injection molding machine (“EC100SX-2A”, manufactured by Toshiba Machine Co., Ltd.) at a resin temperature of 360° C. and a mold temperature of 80° C.
• E100SX-2A manufactured by Toshiba Machine Co., Ltd.
• This long-optical-path molded article was subjected to measurement of the YI value (the degree of yellowing) at an optical path length of 300 mm.
• the measurement was carried out using a Long Pathlength Transmission Spectrophotometer (“ASA 1”, manufactured by Nippon Denshoku Industries Co., Ltd.; C light source; viewing angle, 2°).
• ASA 1 Long Pathlength Transmission Spectrophotometer
• Examples 1 to 4 each of which contains the aromatic polycarbonate copolymer (B) in the present invention, have improved impact strength compared to Comparative Example 1, which does not contain the aromatic polycarbonate copolymer (B), when the fluidity was adjusted to similar levels.
• Example 3 which contains the aromatic polycarbonate copolymer (B) in the present invention, exhibited a better balance between the fluidity and the impact resistance compared to Comparative Examples 2 and 3, which do not contain the aromatic polycarbonate copolymer (B).
• Example 3 shows a much lower level of cracking in molding of the light guide plate.
• the polycarbonate resin composition for a thin optical component of the present invention containing both the aromatic polycarbonate resin (A) and the aromatic polycarbonate copolymer (B), has an excellent balance between the fluidity and the impact resistance, and exhibits sufficient strength even in cases where it is formed into a thin optical component such as a light guide plate. It is therefore clear that the composition can be suitably used for such a component.
• the strength of a molded article after molding can be increased while fluidity sufficient for molding of a thin optical member can be maintained. Therefore, cracking, which may occur in a thin optical member, can be remarkably reduced.
• the composition can be extremely favorably used for thin optical components, and its industrial applicability is very high.

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