US20180112162A1 - Alcoholic beverage containing particles comprising a caviar-based foodstuff - Google Patents

Alcoholic beverage containing particles comprising a caviar-based foodstuff Download PDF

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Publication number
US20180112162A1
US20180112162A1 US15/560,797 US201615560797A US2018112162A1 US 20180112162 A1 US20180112162 A1 US 20180112162A1 US 201615560797 A US201615560797 A US 201615560797A US 2018112162 A1 US2018112162 A1 US 2018112162A1
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Prior art keywords
caviar
particles
food
alcoholic beverage
gelling
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US15/560,797
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English (en)
Inventor
Martine LELEU
Sébastien Bardon
Julie CANI
Thomas Delmas
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Pernod Ricard SA
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Pernod Ricard SA
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Assigned to PERNOD RICARD reassignment PERNOD RICARD ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: DELMAS, THOMAS, CANI, Julie, BARDON, Sébastien, LELEU, MARTINE
Publication of US20180112162A1 publication Critical patent/US20180112162A1/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L17/00—Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
    • A23L17/30—Fish eggs, e.g. caviar; Fish-egg substitutes
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/256—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin from seaweeds, e.g. alginates, agar or carrageenan
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/262—Cellulose; Derivatives thereof, e.g. ethers
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12G—WINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G1/00—Preparation of wine or sparkling wine
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12G—WINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G3/00—Preparation of other alcoholic beverages
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12G—WINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G3/00—Preparation of other alcoholic beverages
    • C12G3/04—Preparation of other alcoholic beverages by mixing, e.g. for preparation of liqueurs
    • C12G3/06—Preparation of other alcoholic beverages by mixing, e.g. for preparation of liqueurs with flavouring ingredients
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12G—WINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G2200/00—Special features
    • C12G2200/21—Wine additives, e.g. flavouring or colouring agents

Definitions

  • the present invention concerns an alcoholic beverage in which particles containing a caviar-based food are immersed.
  • alcoholic beverage a beverage containing ethyl alcohol obtained by alcoholic fermentation of the sugars contained in fruits, vegetables, cereals, plants, grains, herbs or roots which produce this alcohol.
  • the alcoholic strength by volume of an alcoholic beverage is defined by the ratio of the volume of pure alcohol present in the beverage at 20° C. to the total volume of said beverage at this same temperature. This ratio can be expressed in percentages.
  • the term «caviar» is used in its broadest sense. It refers not only to eggs of fish in general (for example eggs of sturgeon, salmon, trout, lumpfish, herring, cod) but also eggs of snail (snail caviar) or even eggs of a batrachian. Preferably, it consists of the sturgeon caviar.
  • the eggs of sturgeon, and in general, the eggs of fish or batrachian are complex elements containing among others water, proteins but also lipids, vitamins and minerals. These various constituents forming part of the composition of the eggs of fish or batrachian make these foods difficult to handle, and in particular when it is desired to add them in a beverage, particularly in an alcoholic beverage.
  • Some compounds of the caviar are very soluble in water, and therefore diffuse easily in an aqueous medium.
  • the proteins of the caviar precipitate in alcohol.
  • the lipids are partially soluble.
  • the encapsulation of caviar in a membrane based on a gelling polymer such as an alginate membrane does not allow stopping the precipitation of its proteins and thus causes the hardening of the egg.
  • the alginate membrane partially allows preventing the leakage of the egg out of said membrane, but it does not ensure complete sealing.
  • the egg hardens, its membrane becomes whitish and white filaments diffuse through the membrane into the alcoholic beverage.
  • the encapsulation of caviar for example with a membrane based on a gelling polymer, encounters difficulties and requires some optimization.
  • an alcoholic beverage of a caviar juice which comes from the rupture of the membrane of the eggs causes the precipitation of the proteins that it contains and which then form dense particles or clusters.
  • the beverage takes on a white-milky tint and becomes turbid.
  • the caviar juice is sensitive to water and alcohol.
  • the encapsulation of caviar juice in a gelling membrane such as a simple alginate membrane does not allow keeping encapsulated the molecules of size less than 20 nm that the caviar juice contains. These too small molecules diffuse and create a disorder in the alcoholic beverage in which they have been immersed.
  • This method described in the application FR 2 947 835 A1 allows extracting and concentrating the fragrances and the flavors of the caviar in alcoholic solutions without losing neither the volume percentage of alcohol nor the subtleties of the fragrance and the flavor of this food.
  • the alcoholic beverage thus obtained by this method delivers to the nose a fragrance of the macerated caviar and to the palate a taste of this food as if it had just been eaten.
  • the method described in the application FR 2 947 835 A1 purifies a large portion of this raw material, that is caviar, to retain only the volatile aromatic molecules which are thus present in the alcoholic beverage.
  • this method does not have to take account of the instability reactions of some of the non-volatile constituents of the caviar also known for their problems of ageing, oxidation and bad odor and which have been mentioned hereinabove, since it eliminates them.
  • the distillate obtained at the end of the method of the application FR 2 947 835 A1 does not contain these compounds of caviar which are problematic.
  • the appearance and the texture of this luxury food, that is caviar, are in no way preserved.
  • the alcoholic beverage obtained at the end of this method does not comprise caviar in suspension. This helps decreasing considerably the attraction for this alcoholic beverage flavored with caviar.
  • the inventors of the present invention have sought to develop an alcoholic beverage containing a caviar-based food which differs from the alcoholic beverage obtained by the method described in the application FR 2 947 835 A1, because not only does this beverage preserve the gustatory properties of the caviar, but also and above all it maintains the visual properties (in other words the appearance) and texture of the caviar.
  • the inventors of the present invention have thus produced new particles containing a caviar-based food, as well as an alcoholic beverage which contains these particles.
  • the particles according to the invention perfectly mimic the texture, the taste and the appearance of the caviar. To this end, the inventors have overcome all the difficulties mentioned hereinabove inherent to the complex and varied constituents of caviar-based foods.
  • the particle according to the invention encapsulates a caviar-based food. More precisely, in the particle according to the invention, the caviar-based food is encapsulated in the gelled network of the gelling polysaccharide.
  • the gelled network of the gelling polysaccharide comprises a set of chains of macromolecules, said macromolecular chains are in the gelled state.
  • the caviar-based food is a caviar juice.
  • the caviar juice has been obtained from caviar whose viscosity is comprised between 500 and 5000 Cps, preferably between 1000 and 3000 Cps.
  • the viscosity of the caviar is about 1500 Cps.
  • the caviar juice in the composition of the particles according to the invention has the advantage of preserving the visual and organoleptic qualities of the caviar while adapting, due to its liquid form, to the constraints of the manufacturing method of said particles which is described hereinafter and which is based on the milli-fluidic technique.
  • the inventors have thus exploited the known properties of formation of the network of macromolecular chains of a gelling polysaccharide to structure and contain caviar juice.
  • the encapsulation of the caviar juice into particles of a gelling polymer certainly allows having particles having the appearance of caviar, but these particles are not stable when they are immersed in an alcoholic beverage.
  • the inventors have discovered that the presence of an agent for reinforcing the gelled network of the gelling polysaccharide and which is further resistant to alcohol in the composition of particles encapsulating a caviar-based food allows maintaining the appearance of said particles when they are immersed in an alcoholic beverage, as well as the yield of formation of said particles, and this by decreasing the amount and the size of the satellite particles during the manufacture of said particles.
  • the presence of this agent for reinforcing the gelled network and which is resistant to alcohol in the composition of the particles according to the invention allows better controlling their production.
  • the agent for reinforcing the gelled network of the gelling polysaccharide and which is resistant to alcohol has a thickening function and it thus helps ensure that said particles according to the invention do not retract when they are immersed in an alcoholic beverage.
  • the gelling polysaccharide is chosen among the cation-reactive gelling polysaccharides.
  • cation-reactive polysaccharide a gelling polysaccharide capable of switching from a liquid state in an aqueous solution to a gelled state under the effect of contact with a solution containing ions of positive charge such as calcium, sodium and magnesium ions.
  • the gelling polysaccharide may be chosen among alginate salts such as sodium alginates or potassium alginates, gellans, carrageenans, pectins, gelatin and agar. It may be one of these compounds taken alone or in a mixture.
  • the gelling polysaccharide is a sodium alginate. It is known that the structural properties of sodium alginate allow it to form a dense and resistant network.
  • the alginate essentially comprises two monomers which are alpha-L-guluronic acid and beta-D-mannuronic acid.
  • the grade of sodium alginate is suitably chosen so that said alginate has a mass content of alpha-L-glucuronic acid which is greater than 50%, more preferably greater than 60% and even more preferably greater than 65%.
  • the alginate of the composition of the particles according to the invention has a mass content of alpha-L-guluronic acid which is greater than that of beta-D-mannuronic acid.
  • the gelled network of such an alginate has the advantage of being resistant; which also helps ensure that the particles according to the invention do not retract when they are immersed in an alcoholic beverage.
  • the sodium alginate has an average molar mass greater than 65 000.
  • Such a sodium alginate has a resistant gelled network.
  • the alginate has a mass content of alpha-L-guluronic acid greater than 50% and an average molar mass greater than 65 000.
  • the agent for reinforcing the gelled network of the gelling polysaccharide and which is resistant to alcohol may be chosen among hydroxypropylmethyl-cellulose (hereinafter abbreviated «HPMC»), carboxymethylcellulose, guar gum, xanthan or carob. It may be one of these compounds taken alone or in a mixture.
  • the agent for reinforcing the gelling polysaccharide and which is resistant to alcohol is HPMC.
  • HPMC is a semi-synthetic polymer of the cellulose ether type. Its emulsifying, thickening and suspensive properties coupled to its inertia in ionic and hydroalcoholic solutions make this polymer particularly suitable for reinforcing the gelled network of the gelling polysaccharide in the particles according to the invention.
  • HPMC has the advantage of being very resistant to alcohol compared to the gelling polysaccharide which may be sodium alginate and whose gel is retracted if it is immersed in a hydro-alcoholic solution such as an alcoholic beverage.
  • the HPMC reinforces the gelled network of the macromolecular chains of the gelling polysaccharide so that when said particles are immersed in an alcoholic beverage, they preserve their sphericity and do not retract.
  • the HPMC allows maintaining the cohesion of the constituents and the shape of the particles according to the invention, even when they are immersed in an alcoholic beverage.
  • At least one food surfactant is further embedded in the gelled network of the gelling polysaccharide.
  • food surfactant a compound having surface-active properties, adapted to the preparation of food products.
  • the surfactant facilitates obtaining the spherical shape of said particles during their manufacture.
  • the food surfactant is advantageously chosen among molecules having surface-active properties and which are authorized in the food industry.
  • the food surfactant may be chosen among lecithins, methylcelluloses, fatty acid salts based on calcium, magnesium, potassium, sodium, lactic esters of fatty acid mono- and diglycerides, citric esters of fatty acid mono- and diglycerides, tartaric esters of fatty acid mono- and diglycerides, glycerol esters of diacetyltartaric acid and fatty acids, mixed acetic and tartaric esters of fatty acid mono- and diglycerides, succinyl monoglycerides, glycerol and propylene glycol esters of lactyl fatty acids, stearyl citrate, cholic acid, soybean hemicellulose, polyoxyethylene stearate 40, poloxyethylene sorbitan monolaurate 20, polyoxyethylene sorbitan monooleate 80, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate 20, polyoxyethylene sorbitan tristearate, phosphati
  • the surfactant may also be chosen among proteins coming, for example, from egg white, milk (whey, 3-lactoglobulin, casein), soybean, alfalfa leaf, fish as well as their derivatives and/or hydrolysates.
  • the food surfactant is chosen among sodium stearoyl-2-lactylate, polysorbate 20 and polysorbate 80. Most preferably, it consists of polysorbate 20.
  • in said gelled network is further embedded at least one compound chosen among food colorings and antioxidants.
  • the food coloring may be chosen among curcumin, riboflavin, tartrazine, quinoline yellow, orange yellow S, cochineal, carminic acid, azorubine, amaranth, cochineal red A, erythrosine, allura red, patented blue, indigotine, indigo carmine, bright blue FCF, copper-chlorophyll complexes, chlorophyll copper complexes, chlorophyll, green S, caramel, sulfite caramel, ammonium caramel, brilliant black BN, black PN, squid ink, brown HT, annatto, bixin, norbixin, paprika extract, capsanthin, capsorubin, lycopene, ⁇ -apocarotenal-8′, lutein, canthaxanthin, beet red, betanin, anthocyanins, titanium dioxide, iron oxide and hydroxide, aluminum, silver, gold, lithol rubin, aromatic plant extracts, fruit and vegetables juice
  • the coloring is carbon black or squid ink, taken alone or in a mixture.
  • the antioxidants are chosen among antioxidants authorized in the food industry.
  • the antioxidant may be chosen among ascorbic acid, sodium or calcium ascorbates, diacetyl 5-6-1-ascorbic acid, palmityl 6-1-ascorbic acid, butylhydroxyanisole, butylhydroxytoluol, octyl or dodecyl gallates, tocopherols, synthetic alpha-tocopherol, synthetic gamma-tocopherol or synthetic delta-tocopherol, all the tocopherols constituting the vitamin E, the extracts of lycopenes or beta-carotene, the plant extracts rich in polyphenols and/or flavonoids, tannins are extracted cocoa, coffee, tea, grapes, rosemary, anthocyanins and phenolic acids.
  • the particle may comprise, in mass percentages:
  • the particle comprises, in mass percentages:
  • the particle according to the invention comprises, in mass percentages:
  • the diameter of the particles according to the invention is comprised between 1 mm and 10 mm, preferably between 1.5 mm and 5 mm, even more preferably about 2.5 mm.
  • the particles according to the invention have a monophasic structure with a core filled with caviar-based food, such as caviar juice.
  • the density of the particles according to the invention is advantageously greater than 1.
  • the particles according to the invention have a characteristic odor and taste of caviar. Their texture is firm but melting.
  • Another object of the present invention is an alcoholic beverage which comprises particles according to the invention.
  • the alcoholic strength by volume of the alcoholic beverage according to the invention expressed in percentages is advantageously at least 1.2%, preferably comprised between 15% and 96%, more preferably comprised between 15% and 70%.
  • the alcoholic beverage may be a beverage chosen among vodka, gin, tequila, mescal, grappa, rum, whiskey, calvados, sake, baijiu, wines, beverages comprising wine, beverages obtained from fermented constituents of vegetable origin, taken alone or in mixtures.
  • the alcoholic beverage is vodka.
  • the alcoholic beverage according to the invention comprises, in mass percentages, between 0.5% and 50%, preferably between 2% and 10%, of particles according to the invention.
  • the particles according to the invention encapsulating a caviar-based food facilitate the diffusion of the caviar aromas without the dispersion of the caviar-based food in the alcoholic beverage.
  • the particles according to the invention which are therefore filled with a caviar-based food have a visual appearance very similar to that of caviar.
  • the particles immersed in the alcoholic beverage according to the invention perfectly imitate the caviar both by their appearance and taste.
  • the alcoholic beverage containing the particles containing a caviar-based food according to the invention further has the advantage of having a transparency visually identical to the alcoholic beverage devoid of these particles.
  • Another object of the present invention is a recipient filled with an alcoholic beverage according to the invention as described hereinabove (namely an alcoholic beverage which contains particles according to the invention).
  • the recipient may have the shape of a bottle or a carafe.
  • the recipient is characterized in that it further comprises a container configured to hold the particles according to the invention in suspension in said recipient (or, in other words, at a determined height in said recipient).
  • the particles according to the invention are disposed in said container and a recipient filled with an alcoholic beverage is thus obtained and in which the particles are held in suspension thanks to said container.
  • the container may include fastening means which are configured to hold the container at a determined height in the recipient.
  • the container may have very varied geometric shapes, for example a generally spherical, parallelepiped or ovoid shape.
  • the container can thus be a cage, a basket or still a rack, which is configured to receive the particles according to the invention and hold them in suspension in the recipient filled with an alcoholic beverage.
  • Another object of the present invention is a particle encapsulating at least one caviar-based food which is likely to be obtained by a manufacturing method which comprises at least the following steps:
  • the caviar-based food, the gelling polysaccharide and the agent for reinforcing the gelled network of the polysaccharide and which is resistant to alcohol may be chosen among those described hereinabove.
  • the caviar-based food is a caviar juice.
  • the caviar-based food is advantageously added last to the solution.
  • step b) compounds chosen among the food surfactants, food colorings and antioxidants which have been described hereinabove can be added to the solution.
  • the constituents and their respective amounts are chosen in a determined manner so that the viscous paste obtained at the end of step b) has a viscosity comprised between 1000 and 7000 Cps, preferably between 1500 and 5000 Cps, and even more preferably from about 1700 Cps.
  • Such viscosity of the viscous paste is particularly suitable for the formation during step d) of particles according to the invention having a shape and a size very similar to those of caviar.
  • the mass percentage of the gelling polysaccharide which has been dissolved in water at step a) is chosen in a determined manner to control the viscosity of the viscous paste obtained at step b) and thus to form during step d) particles having a quasi-spherical shape rather than particles in the form of drops which would therefore not have the visual appearance of the caviar.
  • Step b) is advantageously carried out under mechanical stirring.
  • step b the network of macromolecular chains of the gelling polysaccharide directly integrates the caviar-based food, and thus before the gelation of the gelling polysaccharide by the gelling solution of step d).
  • a viscous paste which may comprise, in mass percentages:
  • Step c) of forming drops from the viscous paste is carried out in a device for forming drops perfectly within the reach of those skilled in the art.
  • the device is configured to form drops having a size comprised between 1 mm and 10 mm, preferably between 1.5 mm and 5 mm.
  • the device for forming drops is in the milli-fluidic technical field.
  • the device for forming drops is equipped with a nozzle through which the viscous paste passes in such a way that at the end of said nozzle, drops as detailed above, are expelled.
  • the drop height of the drops (namely, the vertical height separating the end of the device for forming drops from which the drop of the surface of the gelling solution is expelled) is appropriately chosen to form drops of spherical shape.
  • the drop height is appropriately chosen to form drops of spherical shape.
  • the gelling solution of step d) of the manufacturing method is, for example, an aqueous solution of a salt of the XnMm type, where X may be a halide ion such as a chloride ion, a tartrate ion or still a lactate ion, or else a gluconate ion and M is advantageously a cation of an alkaline earth metal such as calcium, magnesium or sodium, and n and m are greater than or equal to 1.
  • the mass percentage of salt of XnMm type in the gelling solution is advantageously comprised between 5% and 20%.
  • the gelling solution is an aqueous solution of calcium lactate.
  • the water contained in said gelling solution is purified water.
  • the gelling solution is a solution comprising purified water, calcium lactate or calcium chloride.
  • the gelling solution comprises purified water and calcium lactate, the mass content of calcium lactate in this solution being advantageously 6%.
  • step d as soon as the drops fall into the gelling solution, they solidify immediately, since the network of the gelling polysaccharide is formed in contact with the ions which comprise the gelling solution.
  • the molecules of the gelling polysaccharide pass from a state in which they are free and disordered to a state in which they are more or less rigid. There is therefore a transition in the ordering of these molecules.
  • the individual macromolecular chains of the gelling polysaccharide form, with the cations of the gelling solution, a coherent three-dimensional network which retains the caviar-based food and prevents its flow out of the particle.
  • the gelling polysaccharide is a sodium alginate and the gelling solution is an aqueous solution of calcium lactate.
  • the alginate is a polymer of brown algae ( Laminaria macrocystis ) constituted by the repetition of monomers of D-mannuronic acid (block M) and alpha L-guluronic acid (block G). This polymer is a long chain molecule negatively charged by the presence of the carboxyl groups (CO 2 ⁇ ). During the gelation of this polymer, its negative charges are compensated by the calcium ions of the gelling solution.
  • the divalent character of the calcium ions allows forming a network by linking two chains of alginate.
  • the blocks G retain the calcium ions by coordination.
  • the aggregation of the parallel chains leads to a regular three-dimensional geometric assembly called an ionoreversible and non thermoreversible “egg box”.
  • the blocks G increase the plasticity of the gel as well as the size of the pores.
  • the blocks M make the gel more elastic and reduce the size of the pores.
  • the particles remain immersed in the gelling solution during a determined duration in such a way that the ions contained in the gelling solution have the time to diffuse to the core of the particle. A too short immersion time in the gelling solution could make the particles fragile and misshapen.
  • the choice of the duration of immersion of the particles in the gelling solution is within the reach of those skilled in the art.
  • the gelation duration has an effect on the elasticity level of the particle according to the invention.
  • the particles can be incorporated into an alcoholic beverage.
  • Another object of the present invention is an alcoholic beverage which contains these particles likely to be obtained by the manufacturing method as described hereinabove.
  • the alcoholic beverage may be a beverage as described hereinabove.
  • the alcoholic beverage comprises, in mass percentages, between 0.5% and 50%, preferably between 2% and 10%, of said particles likely to be obtained by the manufacturing method as described hereinabove.
  • the alcoholic strength by volume of the alcoholic beverage is advantageously at least 1.2%, preferably comprised between 15% and 96%, more preferably comprised between 15% and 70%.
  • tests 1 to 6 different viscous pastes (tests 1 to 6) were prepared by varying the mass contents of HPMC and sodium alginate and the viscosity of the viscous pastes thus obtained, was measured.
  • the viscous pastes were prepared by performing steps a) to b) of the particle manufacturing method which has been described hereinabove, namely:
  • polysorbate 20 is a food surfactant.
  • Vegetable carbon is a coloring used to color the viscous paste.
  • the caviar juice was an emulsion coming from the rupture of the sturgeon egg membrane.
  • This emulsion is more viscous than water. It has a density of 1.09 and contains heterogeneous particle size.
  • test no. 5 was a test which resulted in obtaining a viscous paste such as obtained at the end of step b) of the method for manufacturing particles according to the invention.
  • the other tests are comparative tests, since they are devoid of caviar juice, HPMC or sodium alginate, depending on the case.
  • the viscous paste containing only HPMC (namely, test no. 4) is much more elastic and shiny than the viscous paste containing only sodium alginate (namely, test no. 1). That is why, a viscous paste containing only HPMC would not be suitable for the formation of particles according to the invention.
  • Particles were prepared according to the method for manufacturing particles according to the invention which has been described hereinabove, namely:
  • step d) immersing the drops obtained at step d) in a gelling solution containing calcium lactate and purified water, the mass content of calcium lactate in said solution was 6%.
  • the polysorbate 20 is a food surfactant.
  • the caviar juice was an emulsion coming from the rupture of the sturgeon egg membrane. This emulsion is more viscous than water. It has a density of 1.09 and contains heterogeneous particle size.
  • the particles have an acceptable sphericity as from a mass content of 1.2% sodium alginate.
  • the amount and size of the satellite particles increase when the percentage of sodium alginate decreases.
  • the test no. 11 shows as many satellite particles as test no. 7, but these satellite particles are smaller. However, these satellite particles are larger and more numerous than those of the particles of test no. 12.
  • the presence of 0.1% more sodium alginate in the viscous paste of test no. 12 than in the viscous paste of test no. 11 has the effect of increasing the viscosity of the viscous paste and decreasing the size and amount of the satellite particles.
  • the particles have lost their sphericity. Indeed, the particles of test no. 12 are no longer spherical.
  • caviar juice particles were prepared in the same manner as for tests no. 7 to 12, by fixing the mass percentage of sodium alginate in the viscous paste at 1.2% and by varying the mass content of HPMC, so as to determine the optimum mass contents of HPMC of caviar juice particles.
  • test no. 13 shows that HPMC allows reducing the size and the amount of the satellite particles.
  • the drop height directly correlated with the viscosity, indicates that the HPMC plays an important role in the viscosity of the viscous paste.
  • the decrease in the mass content of the polysorbate 20 has no influence on the viscosity of the viscous paste, because the number and the amount and the quality of the particles remained globally identical during these additional tests.
  • particles according to the invention having the following composition in mass percentages were used:
  • the particles according to the invention have been formed from a gelling solution containing in mass percentages: 6% calcium lactate and 94% purified water.
  • the graph of FIG. 1 indicates the time of diffusion of the caviar juice aromas in the vodka at ambient temperature, the aromatic intensity in taste and odor as a function of the time of maceration of the particles in this vodka according to the invention.
  • the results in FIG. 1 indicate a gradual infusion over the 12 days.
  • the odor of caviar appears on the 6 th day. It becomes stronger the following days.
  • the taste appears on the 2 nd day and becomes more intense day by day.
  • the samples After 12 days, the samples have the odor and taste of the control sample at 5 g/L of caviar juice in vodka.

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US15/560,797 2015-03-26 2016-03-23 Alcoholic beverage containing particles comprising a caviar-based foodstuff Abandoned US20180112162A1 (en)

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FR1552524A FR3033985B1 (fr) 2015-03-26 2015-03-26 Boisson alcoolisee contenant des particules comprenant un aliment a base de caviar
FR15/52524 2015-03-26
PCT/FR2016/050639 WO2016151244A1 (fr) 2015-03-26 2016-03-23 Boisson alcoolisée contenant des particules comprenant un aliment à base de caviar

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CN113322140A (zh) * 2021-05-28 2021-08-31 西北农林科技大学 一种葡萄酒分子美食“红酒珠”的制作方法

Families Citing this family (2)

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FR3051481B1 (fr) * 2016-05-19 2019-07-26 Luvienz Procede de fabrication d'une boisson contenant du caviar et la boisson ainsi obtenue
CN115736166A (zh) * 2022-12-26 2023-03-07 浙江旺林生物科技有限公司 一种包含植物炭黑的墨鱼汁粉的加工方法

Family Cites Families (18)

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JPS5816859B2 (ja) * 1978-10-09 1983-04-02 明司 小谷 魚卵風球状ゲル食品の製造法
JPS58205492A (ja) * 1982-05-27 1983-11-30 Q P Corp 酒類用顆粒の製法
US4507327A (en) * 1983-05-23 1985-03-26 Q.P. Corporation Process for preparing edible products in the form of capsules
JPH01157344A (ja) * 1987-12-11 1989-06-20 San Ei Chem Ind Ltd ゼリー状物の製造法
JPH04320655A (ja) * 1991-04-19 1992-11-11 Dainippon Pharmaceut Co Ltd 成形おにぎり具材
AU2003286418A1 (en) * 2002-12-23 2004-07-14 Eirikur Vignisson Fish roe and method for reconstitution of fish roe
RU54902U1 (ru) * 2004-08-24 2006-07-27 Александр Петрович Клюков Бутылка
US7393963B2 (en) * 2004-12-10 2008-07-01 Archer-Daniels-Midland Company Conversion of 2,5-(hydroxymethyl)furaldehyde to industrial derivatives, purification of the derivatives, and industrial uses therefor
JP2006174778A (ja) * 2004-12-24 2006-07-06 Shin Etsu Chem Co Ltd 油分含有カプセルの製造方法
US20060280843A1 (en) * 2005-02-23 2006-12-14 Ralf Jager Filler for a beverage container
JP5450939B2 (ja) * 2007-07-23 2014-03-26 サントリーホールディングス株式会社 ゼリー入りアルコール飲料及びその製造方法
JP2009055879A (ja) * 2007-09-03 2009-03-19 Suntory Ltd ゼリー入り飲料及びその製造方法
RU2412602C2 (ru) * 2009-02-19 2011-02-27 Федеральное государственное образовательное учреждение высшего профессионального образования "Дальневосточный государственный технический рыбохозяйственный университет" Напиток из молочной сыворотки
BE1018814A5 (fr) * 2009-07-07 2011-09-06 Renzo Franco Procede de fabrication d'une boisson alcoolisee a partir de caviar de luxe et produit ainsi obtenu.
EP2305742B1 (fr) * 2009-10-01 2017-02-22 Symrise AG Particule coeur/enveloppe sphérique
EP3023484A1 (fr) * 2010-08-18 2016-05-25 Pernod-Ricard Composition liquide alcoolique avec particules supendues
CN201920362U (zh) * 2011-03-24 2011-08-10 谢小猛 一种茶杯
CA2997734C (fr) 2013-09-13 2022-01-04 Phood Station Produits alimentaires encapsules et procedes pour les fabriquer

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BR112017020398A2 (pt) 2018-06-05
AU2016238687A1 (en) 2017-09-14
AU2016238687B2 (en) 2019-08-29
CN107427052B (zh) 2021-07-30
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US11753611B2 (en) 2023-09-12
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ES2754791T3 (es) 2020-04-20
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RU2707256C2 (ru) 2019-11-25
BR112017020398B1 (pt) 2022-06-07
SG11201707930WA (en) 2017-10-30
EP3274438B1 (fr) 2019-08-14
CA2974886C (fr) 2023-03-07
KR20170129727A (ko) 2017-11-27
CA2974886A1 (fr) 2016-09-29
MX2017012092A (es) 2018-06-22
EP3274438A1 (fr) 2018-01-31

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