US20150308004A1 - Cathode for electrolytic evolution of hydrogen - Google Patents

Cathode for electrolytic evolution of hydrogen Download PDF

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Publication number
US20150308004A1
US20150308004A1 US14/441,646 US201314441646A US2015308004A1 US 20150308004 A1 US20150308004 A1 US 20150308004A1 US 201314441646 A US201314441646 A US 201314441646A US 2015308004 A1 US2015308004 A1 US 2015308004A1
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Prior art keywords
layer
electrode according
rare earths
catalytic
thermal decomposition
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US14/441,646
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English (en)
Inventor
Marianna Brichese
Alice CALDERARA
Cecilia DEL CURTO
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Industrie de Nora SpA
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Industrie de Nora SpA
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Assigned to INDUSTRIE DE NORA S.P.A. reassignment INDUSTRIE DE NORA S.P.A. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BRICHESE, MARIANNA, CALDERARA, ALICE, DEL CURTO, Cecilia
Publication of US20150308004A1 publication Critical patent/US20150308004A1/en
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/0442—
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C25B9/73—Assemblies comprising two or more cells of the filter-press type
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/24—Halogens or compounds thereof
    • C25B1/26—Chlorine; Compounds thereof
    • C25B11/0405—
    • C25B11/0415—
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C25B11/093—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one noble metal or noble metal oxide and at least one non-noble metal oxide
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C25B11/097—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds comprising two or more noble metals or noble metal alloys
    • C25B9/10—
    • C25B9/18—
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells

Definitions

  • the invention relates to an electrode, with particular reference to a metal electrode for use as a cathode for evolution of hydrogen in industrial electrolytic processes and a method for its production.
  • a partial improvement in the adherence of the catalytic coating to the nickel substrate is obtainable by the addition of rare earths to the formulation of the catalytic layer, optionally as a porous external layer that performs a protective function against the underlying platinum-based catalytic layer; this type of cathode is sufficiently durable under normal operating conditions, being liable however to suffer serious damages following the occasional current reversals inevitably produced in case of malfunctioning of industrial plants.
  • a partial improvement in the resistance to current reversals is obtainable by activating the nickel cathode substrate with a coating consisting of two distinct phases, a first platinum-based catalytic phase added with rhodium and a second phase comprising palladium having a protective function.
  • This type of formulation requires high loads of platinum and rhodium in the catalytic phase, such as to determine a rather high production cost.
  • a less expensive catalytic coating which presents high activity combined with some resistance to current reversals is obtained from mixtures of ruthenium and rare earths, for example praseodymium; the resistance of electrodes obtained according to such a formulation can be increased by interposing a platinum-based thin layer between the cathode substrate and the catalytic coating.
  • the invention relates to an electrode suitable for use as a cathode in electrolytic processes comprising a substrate made of metal, for example nickel, provided with a catalytic coating formed by at least three distinct layers: an internal layer, in direct contact with the substrate, containing platinum, at least one intermediate layer consisting of a mixture of oxides containing 40-60% by weight of rhodium referred to the elements and an external ruthenium oxide-based layer.
  • Platinum in the internal layer is present predominantly in metallic form, especially in operating conditions under cathodic hydrogen evolution, however, is not excluded, especially prior to the first use, that platinum or a fraction thereof may be present in form of oxide.
  • the internal layer consists of a layer of platinum alone.
  • the external layer consists of a layer of ruthenium oxide alone.
  • ruthenium oxide indicates that such element is present, after the preparation of the electrode, mainly in oxide form; it is not excluded, especially in operating conditions under cathodic hydrogen evolution, that such oxide can be partially reduced to ruthenium metal.
  • the mixture of oxides of the intermediate layer further contains, besides rhodium, 10-30% by weight palladium and 20-40% by weight of rare earths; in one embodiment, the rare earth content consists entirely of praseodymium.
  • the term mixture of oxides indicates that the elements of the relative formulation are present, after the preparation of the electrode, mainly in form of oxides; is not excluded, especially in operating conditions under cathodic hydrogen evolution, that a fraction of such oxides can be reduced to metal or even form hydrides, as in the case of palladium.
  • formulations of this type impart a resistance to current reversals several times higher than the closest prior art formulations at substantially reduced specific loading of noble metal.
  • the specific loading of platinum in the internal layer is between 0.3 and 1.5 g/m 2
  • the sum of the specific loading of rhodium, palladium and rare earths in the intermediate layer is between 1 and 3 g/m 2
  • the specific loading of ruthenium in the external layer is between 2 and 5 g/m 2 .
  • the invention relates to a method for the preparation of an electrode which comprises the application in one or more coats of an acetic solution of Pt(NH 3 ) 2 (NO 3 ) 2 (platinum diamino dinitrate) to a metallic substrate, with subsequent drying at 80-100° C., thermal decomposition at 450-600° C.
  • the cycle until the desired loading is achieved (e.g., 0.3-1.5 g/m 2 of Pt as metal); the application in one or more coats of an acetic solution containing a rhodium nitrate and optionally nitrates of palladium and rare earths to the internal catalytic layer thus obtained, with subsequent drying at 80-100° C., thermal decomposition at 450-600° C.
  • desired loading e.g., 0.3-1.5 g/m 2 of Pt as metal
  • the desired loading e.g., 1-3 g/m 2 as the sum of Rh, Pd and rare earths
  • Ru nitrosyl nitrate designates a commercially available compound expressed by the formula Ru(NO)(NO 3 ) 3 , sometimes written as Ru(NO)(NO 3 ) x to indicate that the average oxidation state of ruthenium can slightly deviate from the value of 3.
  • the inventors have observed that the use of the specified precursors in the adopted preparation conditions favours the formation of catalysts with a particularly ordered crystal lattice, with a positive impact in terms of activity, durability and resistance to current reversals.
  • Pt diamino dinitrate, Pt(NH 3 ) 2 (NO 3 ) 2 corresponding to 40 g of Pt was dissolved in 160 ml of glacial acetic acid. The solution was stirred for 3 hours while maintaining the temperature at 50° C., and then brought to the volume of one litre with 10% by weight acetic acid (platinum solution).
  • Ru(NO)(NO 3 ) 3 An amount of Ru(NO)(NO 3 ) 3 corresponding to 200 g of Ru was dissolved in 600 ml of glacial acetic acid with addition of a few ml of concentrated nitric acid. The solution was stirred for three hours while maintaining the temperature at 50° C. The solution was then brought to a volume of 1 l with 10% by weight acetic acid (ruthenium solution).
  • Rh(NO 3 ) 3 , Pd(NO 3 ) 2 and Pr(NO 3 ) 3 .6H 2 O corresponding to 4.25 g of Rh, 1.7 g of Pd and 25.5 g of Pr expressed as metals were mixed under stirring (rhodium solution).
  • a mesh of nickel 200 of 100 mm ⁇ 100 mm ⁇ 0.89 mm size was subjected to a process of blasting with corundum, etching in 20% HCl at 85° C. for 2 minutes and thermal annealing at 500° C. for 1 hour.
  • the platinum solution was applied by brushing in a single cycle, carrying out a drying treatment for 10 minutes at 80-90° C. and a thermal decomposition for 10 minutes at 500° C., obtaining a specific loading of 0.8 g/m 2 of Pt.
  • the rhodium solution was then applied by brushing in three coats carrying out a drying treatment for 10 minutes at 80-90° C. and a thermal decomposition for 10 minutes at 500° C. after each coat, obtaining a specific loading of 1.4 g/m 2 of Rh, 0.6 g/m 2 of Pd and 0.84 g/m 2 of Pr.
  • the ruthenium solution was then applied by brushing in four coats carrying out a drying treatment for 10 minutes at 80-90° C. and a thermal decomposition for 10 minutes at 500° C. after each coat, obtaining a specific loading of 3 g/m 2 of Ru.
  • the sample was subjected to a performance test, showing an ohmic drop-corrected initial cathodic potential of ⁇ 930 mV/NHE at 3 kA/m 2 under hydrogen evolution in 33% NaOH, at a temperature of 90° C.
  • Pt diamino dinitrate, Pt(NH 3 ) 2 (NO 3 ) 2 corresponding to 40 g of Pt was dissolved in 160 ml of glacial acetic acid. The solution was stirred for 3 hours while maintaining the temperature at 50° C., and then brought to the volume of one litre with 10% by weight acetic acid (platinum solution).
  • Ru(NO)(NO 3 ) 3 An amount of Ru(NO)(NO 3 ) 3 corresponding to 200 g of Ru was dissolved in 600 ml of glacial acetic acid with addition of a few ml of concentrated nitric acid. The solution was stirred for three hours while maintaining the temperature at 50° C. The solution was then brought to a volume of 1 l with 10% by weight acetic acid (ruthenium solution).
  • Pr(NO 3 ) 2 corresponding to 200 g of Pr was dissolved in 600 ml of glacial acetic acid with addition of a few ml of concentrated nitric acid. The solution was stirred for three hours while maintaining the temperature at 50° C. The solution was then brought to a volume of 1 l with 10 % by weight acetic acid (rare earth solution). 480 ml of ruthenium solution were blended with 120 ml of rare earth solution and left under stirring for five minutes. The solution thus obtained was brought to 1 litre with 10% by weight acetic acid (ruthenium and praseodymium solution).
  • a mesh of nickel 200 of 100 mm ⁇ 100 mm ⁇ 0.89 mm size was subjected to a process of blasting with corundum, etching in 20% HCl at 85° C. for 2 minutes and thermal annealing at 500° C. for 1 hour.
  • the platinum solution was applied by brushing in a single cycle, carrying out a drying treatment for 10 minutes at 80-90° C. and a thermal decomposition for 10 minutes at 500° C., obtaining a specific loading of 1 g/m 2 of Pt.
  • the ruthenium and praseodymium solution was then applied by brushing in 4 successive coats, carrying out a drying treatment for 10 minutes at 80-90° C. and a thermal decomposition for 10 minutes at 500° C. after each coat, until obtaining the deposition of 4 g/m 2 of Ru and 1 g/m 2 Pr
  • the sample was subjected to a performance test, showing an ohmic drop-corrected initial cathodic potential of ⁇ 930 mV/NHE at 3 kA/m 2 under hydrogen evolution in 33% NaOH, at a temperature of 90° C.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Catalysts (AREA)
US14/441,646 2012-11-29 2013-11-11 Cathode for electrolytic evolution of hydrogen Abandoned US20150308004A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IT002030A ITMI20122030A1 (it) 2012-11-29 2012-11-29 Catodo per evoluzione elettrolitica di idrogeno
ITMI2012A002030 2012-11-29
PCT/EP2013/073490 WO2014082843A1 (en) 2012-11-29 2013-11-11 Cathode for electrolytic evolution of hydrogen

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US (1) US20150308004A1 (ko)
EP (1) EP2925909B1 (ko)
JP (1) JP6324402B2 (ko)
KR (1) KR20150089077A (ko)
CN (1) CN104769163B (ko)
AR (1) AR093390A1 (ko)
AU (1) AU2013351395C1 (ko)
BR (1) BR112015012177A8 (ko)
CA (1) CA2885810C (ko)
CL (1) CL2015001428A1 (ko)
DK (1) DK2925909T3 (ko)
EA (1) EA028211B1 (ko)
ES (1) ES2606306T3 (ko)
HU (1) HUE032149T2 (ko)
IL (1) IL237869A (ko)
IT (1) ITMI20122030A1 (ko)
MX (1) MX361261B (ko)
MY (1) MY183338A (ko)
PE (1) PE20151011A1 (ko)
PL (1) PL2925909T3 (ko)
PT (1) PT2925909T (ko)
SG (1) SG11201502482TA (ko)
TW (1) TWI592521B (ko)
UY (1) UY35125A (ko)
WO (1) WO2014082843A1 (ko)
ZA (1) ZA201502734B (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11668017B2 (en) 2018-07-30 2023-06-06 Water Star, Inc. Current reversal tolerant multilayer material, method of making the same, use as an electrode, and use in electrochemical processes

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3440241A1 (de) 2016-04-07 2019-02-13 Covestro Deutschland AG Bifunktionelle elektrode und elektrolysevorrichtung für die chlor-alkali-elektrolyse
CN107815703B (zh) * 2016-09-14 2019-09-10 蓝星(北京)化工机械有限公司 析氢活性阴极及其制备方法和包含所述析氢活性阴极的电解槽
KR102283328B1 (ko) * 2016-11-28 2021-07-30 주식회사 엘지화학 환원 전극의 재생방법
US10815578B2 (en) 2017-09-08 2020-10-27 Electrode Solutions, LLC Catalyzed cushion layer in a multi-layer electrode
CN108070877B (zh) * 2017-11-09 2020-07-07 江苏安凯特科技股份有限公司 一种用于电解生产的阴极及其制备方法
US20220243338A1 (en) * 2019-06-12 2022-08-04 Olin Corporation Electrode coating
CN112080756B (zh) * 2019-06-14 2021-07-06 中国科学院大连化学物理研究所 一种析氢电极及其制备和应用
CN113337845B (zh) * 2020-02-17 2024-02-09 马赫内托特殊阳极（苏州）有限公司 一种能够极性反转的电极及其用途
IT202100020735A1 (it) 2021-08-02 2023-02-02 Industrie De Nora Spa Elettrodo per evoluzione elettrolitica di idrogeno

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1128136A (en) * 1966-05-04 1968-09-25 Tsurumi Soda Kk Improvements in or relating to anodes for electrolytic cells
EP0046447A1 (en) * 1980-08-18 1982-02-24 Eltech Systems Corporation Electrode with electrocatalytic surface and method of manufacture
US4459189A (en) * 1982-02-18 1984-07-10 Vance Christopher J Electrode coated with lead or a lead alloy and method of use
EP0209427A1 (fr) * 1985-06-24 1987-01-21 Elf Atochem S.A. Cathode pour électrolyse et un procédé de fabrication de la dite cathode
US5419824A (en) * 1992-11-12 1995-05-30 Weres; Oleh Electrode, electrode manufacturing process and electrochemical cell
US6217729B1 (en) * 1999-04-08 2001-04-17 United States Filter Corporation Anode formulation and methods of manufacture
US20090194411A1 (en) * 2006-10-11 2009-08-06 Industrie De Nora S.P.A. Cathode For Electrolytic Processes
US20090223815A1 (en) * 2008-03-07 2009-09-10 Permelec Electrode Ltd. Cathode for hydrogen generation
US20110259758A1 (en) * 2008-01-31 2011-10-27 Casale Chemicals S.A. High Performance Cathodes for Water Electrolysers
WO2012150307A1 (en) * 2011-05-03 2012-11-08 Industrie De Nora S.P.A. Electrode for electrolytic processes and method of manufacturing thereof
US20120279853A1 (en) * 2009-12-25 2012-11-08 Asahi Kasei Chemicals Corporation Cathode, electrolytic cell for electrolysis of alkali metal chloride, and method for producing negative electrode
US20120305494A1 (en) * 2011-06-06 2012-12-06 Dimascio Felice Electrolytic method of generating chloride dioxide

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1118384A (zh) * 1994-09-08 1996-03-13 广州有色金属研究院 电解冶金工业用涂层电极
US5948222A (en) * 1995-05-01 1999-09-07 Occidental Chemical Corporation Reactivation of deactivated anodes
FR2797646B1 (fr) * 1999-08-20 2002-07-05 Atofina Cathode utilisable pour l'electrolyse de solutions aqueuses
CN101235513B (zh) * 2007-11-14 2010-08-18 福州大学 一种新型涂层钛阳极
ITMI20091719A1 (it) * 2009-10-08 2011-04-09 Industrie De Nora Spa Catodo per processi elettrolitici
CN102352517B (zh) * 2011-10-21 2014-04-30 重庆大学 一种高活性阴极及其制备方法

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1128136A (en) * 1966-05-04 1968-09-25 Tsurumi Soda Kk Improvements in or relating to anodes for electrolytic cells
EP0046447A1 (en) * 1980-08-18 1982-02-24 Eltech Systems Corporation Electrode with electrocatalytic surface and method of manufacture
US4459189A (en) * 1982-02-18 1984-07-10 Vance Christopher J Electrode coated with lead or a lead alloy and method of use
EP0209427A1 (fr) * 1985-06-24 1987-01-21 Elf Atochem S.A. Cathode pour électrolyse et un procédé de fabrication de la dite cathode
US5419824A (en) * 1992-11-12 1995-05-30 Weres; Oleh Electrode, electrode manufacturing process and electrochemical cell
US6217729B1 (en) * 1999-04-08 2001-04-17 United States Filter Corporation Anode formulation and methods of manufacture
US20090194411A1 (en) * 2006-10-11 2009-08-06 Industrie De Nora S.P.A. Cathode For Electrolytic Processes
US20110259758A1 (en) * 2008-01-31 2011-10-27 Casale Chemicals S.A. High Performance Cathodes for Water Electrolysers
US20090223815A1 (en) * 2008-03-07 2009-09-10 Permelec Electrode Ltd. Cathode for hydrogen generation
US20120279853A1 (en) * 2009-12-25 2012-11-08 Asahi Kasei Chemicals Corporation Cathode, electrolytic cell for electrolysis of alkali metal chloride, and method for producing negative electrode
WO2012150307A1 (en) * 2011-05-03 2012-11-08 Industrie De Nora S.P.A. Electrode for electrolytic processes and method of manufacturing thereof
US20140008215A1 (en) * 2011-05-03 2014-01-09 Industrie De Nora S.P.A. Electrode for electrolytic processes and method of manufacturing thereof
US20120305494A1 (en) * 2011-06-06 2012-12-06 Dimascio Felice Electrolytic method of generating chloride dioxide

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Madaeni Treatment of saturated brine in chlor-alkali process using membranes, Separation and Purification Technology, 61, 2008, pages 6874 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11668017B2 (en) 2018-07-30 2023-06-06 Water Star, Inc. Current reversal tolerant multilayer material, method of making the same, use as an electrode, and use in electrochemical processes

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TWI592521B (zh) 2017-07-21
EA201590751A1 (ru) 2015-09-30
HUE032149T2 (en) 2017-08-28
EP2925909B1 (en) 2016-09-07
PE20151011A1 (es) 2015-08-02
CN104769163A (zh) 2015-07-08
JP2016502606A (ja) 2016-01-28
AU2013351395C1 (en) 2017-12-14
CA2885810C (en) 2020-04-14
JP6324402B2 (ja) 2018-05-16
ES2606306T3 (es) 2017-03-23
ZA201502734B (en) 2016-11-30
EA028211B1 (ru) 2017-10-31
BR112015012177A8 (pt) 2018-09-11
SG11201502482TA (en) 2015-05-28
PL2925909T3 (pl) 2017-02-28
IL237869A (en) 2017-07-31
MX361261B (es) 2018-11-30
UY35125A (es) 2014-06-30
KR20150089077A (ko) 2015-08-04
CN104769163B (zh) 2017-04-19
CA2885810A1 (en) 2014-06-05
WO2014082843A1 (en) 2014-06-05
TW201420817A (zh) 2014-06-01
CL2015001428A1 (es) 2015-07-31
MX2015006588A (es) 2015-08-05
MY183338A (en) 2021-02-18
DK2925909T3 (en) 2016-12-19
BR112015012177A2 (pt) 2017-07-11
AU2013351395B2 (en) 2017-07-13
AU2013351395A1 (en) 2015-04-09
EP2925909A1 (en) 2015-10-07
PT2925909T (pt) 2016-11-01
AR093390A1 (es) 2015-06-03
ITMI20122030A1 (it) 2014-05-30

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