US20140378358A1 - Shock absorber oil composition - Google Patents

Shock absorber oil composition Download PDF

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Publication number
US20140378358A1
US20140378358A1 US14/373,473 US201214373473A US2014378358A1 US 20140378358 A1 US20140378358 A1 US 20140378358A1 US 201214373473 A US201214373473 A US 201214373473A US 2014378358 A1 US2014378358 A1 US 2014378358A1
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Prior art keywords
component
mass
shock absorber
oil composition
alkyl group
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English (en)
Inventor
Aya Aoki
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Idemitsu Kosan Co Ltd
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Idemitsu Kosan Co Ltd
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Assigned to IDEMITSU KOSAN CO., LTD. reassignment IDEMITSU KOSAN CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: AOKI, Aya
Publication of US20140378358A1 publication Critical patent/US20140378358A1/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/003—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046—Overbasedsulfonic acid salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/043—Ammonium or amine salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049—Phosphite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/02—Viscosity; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/08—Hydraulic fluids, e.g. brake-fluids

Definitions

  • the present invention relates to a shock absorber oil composition.
  • shock absorber used for effectively absorbing vibration
  • a hydraulic shock absorber is widely used in an automobile or the like.
  • the shock absorber is a functional component that plays an important role for vehicle handling, stability and ride quality, especially for ride quality.
  • Patent Literature 1 a technology for particularly improving ride quality during travel on an expressway by improving friction characteristics of a shock absorber oil composition used in a shock absorber.
  • Patent Literature 1 JP-A-2000-119677
  • the shock absorber oil composition disclosed in Patent Literature 1 transmits a rough vibration to a vehicle body during travel at a low speed, which may cause an insufficient ride quality.
  • An object of the invention is to provide a shock absorber oil composition providing an excellent ride quality during travel.
  • a shock absorber oil composition as follows is provided.
  • a shock absorber oil composition includes: a base oil: a component (A) that is at least one of phosphate, amine phosphate salt, phosphite and amine phosphite salt; a component (B) that is an amide compound; and a component (C) that is a primary amine.
  • the component (A) has an alkyl group or an alkenyl group, and the alkyl group or the alkenyl group has 12 to 20 carbon atoms.
  • the component (B) has an alkyl group, and the alkyl group has 12 to 20 carbon atoms.
  • the component (C) has an alkyl group or an alkenyl group, and the alkyl group or the alkenyl group has 12 to 20 carbon atoms.
  • a content of the component (A) is in a range of 0.1 mass % to 1 mass % of a total amount of the composition
  • a content of the component (B) is in a range of 0.1 mass % to 1 mass % of the total amount of the composition
  • a content of the component (C) is in a range of 0.01 mass % to 0.1 mass % of the total amount of the composition.
  • a shock absorber oil composition providing an excellent ride quality during travel can be provided.
  • a shock absorber oil composition of the invention (hereinafter, also referred to as “the composition”) is provided by blending to a base oil: (A) at least one of phosphate, amine phosphate salt, phosphite and amine phosphite salt; (B) an amide compound; and (C) a primary amine.
  • a base oil at least one of phosphate, amine phosphate salt, phosphite and amine phosphite salt
  • B an amide compound
  • C a primary amine
  • the base oil used in the composition may be a mineral lubricating base oil or a synthetic lubricating base oil.
  • the kind of the lubricating base oil is not particularly limited but may be suitably selected from any mineral oil and synthetic oil that have been conventionally used as a base oil of a shock absorber oil.
  • Examples of the mineral lubricating base oil include a paraffinic mineral oil and a naphthenic mineral oil.
  • examples of the lubricating base oil include polybutene, polyolefin, polyol ester, diacid ester, phosphate, polyphenyl ether, polyglycol, alkyl benzene, and alkyl naphthalene.
  • examples of the polyolefin include an ⁇ -olefin homopolymer and an ⁇ -olefin copolymer.
  • One of the above base oils may be singularly used or a combination of two or more thereof may be used.
  • a component (A) used in the composition is at least one of phosphate, amine phosphate salt, phosphite and amine phosphite salt.
  • the component (A) preferably has an alkyl group or an alkenyl group.
  • the alkyl group or alkenyl group preferably has 12 to 20 carbon atoms in terms of a friction coefficient between metals in the composition Examples of the alkyl group include a lauryl group, myristyl group, cetyl group, and stearyl group.
  • the alkenyl group is exemplified by an oleyl group.
  • the component (A) examples include acidic phosphate of alcohol (e.g., lauryl alcohol and oleyl alcohol) and phosphoric acid, an amine salt of the acidic phosphate, phosphite of alcohol (e.g., lauryl alcohol and oleyl alcohol) and phosphorous acid, and an amine salt of the phosphite.
  • acidic phosphate of alcohol e.g., lauryl alcohol and oleyl alcohol
  • phosphoric acid an amine salt of the acidic phosphate
  • phosphite of alcohol e.g., lauryl alcohol and oleyl alcohol
  • a content of the component (A) is not particularly limited, but is preferably in a range of 0.1 mass % to 1 mass % of a total amount of the composition, more preferably in a range of 0.3 mass % to 0.7 mass %.
  • the content of the component (A) is excessively small, the composition tends to exhibit a high friction coefficient between metals during travel at a low speed.
  • the content of the component (A) is excessively large, an undissolved portion of the component (A) is left, which may not always provide advantageous effects for the content.
  • a component (B) used in the composition is an amide compound.
  • the component (B) preferably has an alkyl group.
  • the alkyl group preferably has 12 to 20 carbon atoms in terms of the friction coefficient between metals in the composition.
  • Examples of the component (B) include lauric acid amide, myristic acid amide, palmitic acid amide and stearic acid amide.
  • One of the components (B) may be singularly used or a combination of two or more thereof may be used.
  • a content of the component (B) is not particularly limited, but is preferably in a range of 0.1 mass % to 1 mass % of the total amount of the composition, more preferably in a range of 0.3 mass % to 0.7 mass %.
  • the content of the component (B) is excessively small, the composition tends to exhibit a high friction coefficient between metals during travel at a low speed.
  • the content of the component (B) is excessively large, an undissolved portion of the component (B) is left, which may not always provide advantageous effect for the content.
  • a component (C) used in the composition is a primary amine.
  • the component (C) preferably has an alkyl group or an alkenyl group.
  • the alkyl group or alkenyl group preferably has 12 to 20 carbon atoms in terms of a friction coefficient between metals in the composition
  • Examples of the alkyl group include a lauryl group, myristyl group, cetyl group, and stearyl group.
  • the alkenyl group is exemplified by an oleyl group.
  • Examples of the component (C) include a monooleyl amine, monolauryl amine, monomyristyl amine, monocetyl amine, and monostearyl amine.
  • One of the components (C) may be singularly used or a combination of two or more thereof may be used.
  • a content of the component (C) is not particularly limited, but is preferably in a range of 0.01 mass % to 0.1 mass % of the total amount of the composition, more preferably in a range of 0.03 mass % to 0.07 mass %.
  • the content of the component (C) is excessively small, the composition tends to exhibit a high friction coefficient between metals during travel at a low speed.
  • the content of the component (C) is excessively large, an undissolved portion of the component (C) is left, which may not always provide advantageous effect for the content.
  • composition satisfying the following conditions (i) to (iii) can be obtained by blending the components (A), (B) and (C) to the base oil.
  • the shock absorber oil composition providing an excellent ride quality during travel is obtainable.
  • composition may further contain various additives below as long as the advantageous effects of the invention are not impaired.
  • a viscosity index improver may be suitably blended to be used.
  • the viscosity index improver examples include a non-dispersed polymethacrylate, dispersed polymethacrylate, olefin copolymer, dispersed olefin copolymer and styrene copolymer.
  • a mass average molecular weight of the viscosity index improver for instance, dispersed and non-dispersed polymethacrylates preferably each have a mass average molecular weight in a range of 5000 to 300000.
  • the olefin copolymer preferably has a mass average molecular weight in a range of 800 to 100000.
  • One of the viscosity index improvers may be singularly used or a combination of two or more thereof may be used.
  • a content of the viscosity index improver is not particularly limited, but is preferably in a range of 0.5 mass % to 15 mass % of the total amount of the composition, more preferably in a range of 1 mass % to 10 mass %.
  • the pour point depressant is exemplified by polymethacrylate having a mass average molecular weight in a range of 5000 to 50000.
  • One of the pour point depressants may be singularly used or a combination of two or more thereof may be used.
  • a content of the pour point depressant is not particularly limited, but is preferably in a range of 0.1 mass % to 2 mass % of the total amount of the composition, more preferably in a range of 0.1 mass % to 1 mass %.
  • an ashless dispersant and a metal-base detergent may be used.
  • the ashless dispersant examples include a succinimide compound, a boron-based imide compound, and a Mannich dispersant.
  • One of the ashless dispersants may be singularly used or a combination of two or more thereof may be used.
  • a content of the ashless dispersant is not particularly limited, but is preferably in a range of 0.1 mass % to 20 mass % of the total amount of the composition.
  • the metal-base detergent examples include alkali metal sulfonate, alkali metal phenate, alkali metal salicylate, alkali metal naphthenate, alkaline earth metal sulfonate, alkaline earth metal phenate, alkaline earth metal salicylate, and alkaline earth metal naphthenate.
  • One of the metal-base detergents may be singularly used or a combination of two or more thereof may be used.
  • a content of the metal-base detergent is not particularly limited, but is preferably in a range of 0.1 mass % to 10 mass % of the total amount of the composition.
  • antioxidants examples include an amine antioxidant, a phenol antioxidant, and a sulfur antioxidant.
  • One of the antioxidants may be singularly used or a combination of two or more thereof may be used.
  • a content of the antioxidant is not particularly limited, but is preferably in a range of 0.05 mass % to 7 mass % of the total amount of the composition.
  • the antiwear agent/extreme pressure agent is exemplified by a sulfur extreme pressure agent.
  • the sulfur extreme pressure agent include an olefin sulfide, a sulfurized fat and oil, an ester sulfide, thiocarbonates, dithiocarbamates and polysulfides.
  • One of the antiwear agents/extreme pressure agents may be singularly used or a combination of two or more thereof may be used.
  • a content of the antiwear agent/the extreme pressure agent is not particularly limited, but is preferably in a range of 0.1 mass % to 20 mass % of the total amount of the composition.
  • the friction reducing agent examples include a fatty acid ester, fatty acid, aliphatic alcohol, aliphatic amine, and aliphatic ether.
  • the friction reducing agent includes at least one alkyl group or alkenyl group having 6 to 30 carbon atoms in a molecule.
  • One of the friction reducing agents may be singularly used or a combination of two or more thereof may be used.
  • a content of the friction reducing agent is not particularly limited, but is preferably in a range of 0.01 mass % to 2 mass % of the total amount of the composition, more preferably in a range of 0.01 mass % to 1 mass %.
  • metal deactivator examples include a benzotriazole metal deactivator, tolyltriazole metal deactivator, thiadiazole metal deactivator, and imidazole metal deactivator.
  • One of the metal deactivators may be singularly used or a combination of two or more thereof may be used.
  • a content of the metal deactivator is not particularly limited, but is preferably in a range of 0.01 mass % to 3 mass % of the total amount of the composition, more preferably in a range of 0.01 mass % to 1 mass %.
  • rust inhibitor examples include petroleum sulfonate, alkylbenzene sulfonate, dinonylnaphthalene sulfonate, alkenyl succinic ester and multivalent alcohol ester.
  • One of the rust inhibitors may be singularly used or a combination of two or more thereof may be used.
  • a content of the rust inhibitor is not particularly limited, but is preferably in a range of 0.01 mass % to 1 mass % of the total amount of the composition, more preferably in a range of 0.05 mass % to 0.5 mass %.
  • the surfactant/anti-emulsifier is exemplified by a polyalkylene glycol non-ionic surfactant.
  • Specific examples of the surfactant/anti-emulsifier include polyoxyethylenealkylether, polyoxyethylenealkylphenylether, and polyoxyethylenealkylnaphthylether.
  • One of the surfactants/anti-emulsifiers may be singularly used or a combination of two or more thereof may be used.
  • a content of the surfactant/anti-emulsifier is not particularly limited, but is preferably in a range of 0.01 mass % to 3 mass % of the total amount of the composition, more preferably in a range of 0.01 mass % to 1 mass %.
  • antifoaming agent examples include silicone oil, fluorosilicone oil, and fluoroalkylether.
  • One of the antifoaming agents may be singularly used or a combination of two or more thereof may be used.
  • a content of the antifoaming agent is not particularly limited, but is preferably in a range of 0.005 mass % to 0.5 mass % of the total amount of the composition, more preferably in a range of 0.01 mass % to 0.2 mass %.
  • anticorrosive agent examples include a benzotriazole anticorrosive agent, a benzimidazole anticorrosive agent, a benzothiazole anticorrosive agent and a thiadiazole anticorrosive agent.
  • One of the anticorrosive agents may be singularly used or a combination of two or more thereof may be used.
  • a content of the anticorrosive agent is not particularly limited, but is preferably in a range of 0.01 mass % to 1 mass % of the total amount of the composition.
  • Examples of the friction modifier include an organic molybdenum compound, fatty acid, higher alcohol, fatty acid ester, oils and fats, amine, and ester sulfide.
  • One of the friction modifiers may be singularly used or a combination of two or more thereof may be used.
  • a content of the friction modifier is not particularly limited, but is preferably in a range of 0.01 mass % to 10 mass % of the total amount of the composition.
  • oiliness agent examples include aliphatic monocarboxylic acid, polymerized fatty acid, hydroxy fatty acid, and aliphatic monoalcohol.
  • One of the oiliness agents may be singularly used or a combination of two or more thereof may be used.
  • a content of the oiliness agent is not particularly limited, but is preferably in a range of 0.01 mass % to 10 mass % of the total amount of the composition.
  • an epoxy compound may be used as the acid scavenger.
  • the acid scavenger include phenyl glycidyl ether, alkyl glycidyl ether, alkylene glycol glycidyl ether, cyclohexene oxide, ⁇ -olefin oxide and epoxidized soybean oil.
  • One of the acid scavengers may be singularly used or a combination of two or more thereof may be used.
  • a content of the acid scavenger is not particularly limited, but is preferably in a range of 0.005 mass % to 5 mass % of the total amount of the composition.
  • sample oils were prepared from the following materials according to the blending composition shown in Table 1. Properties of the sample oils and actual ride quality were evaluated according to the following methods.
  • Friction coefficients between metals were measured under the following conditions using a reciprocating friction tester. A friction coefficient between metals at a speed of 10 mm/s (a high-speed intermetal friction coefficient ⁇ ) and a friction coefficient between metals at a speed of 0.3 mm/s (a low-speed intermetal friction coefficient ⁇ ) were measured. A ratio between the friction coefficients between metals (low-speed intermetal friction coefficient ⁇ /high-speed intermetal friction coefficient ⁇ ) was calculated.
  • Vehicles provided with shock absorbers using the sample oils were prepared.
  • the drivers respectively evaluated the vehicles on a five-point scale in terms of ten items including a ride feeling (good ride comfort), a hardness feeling (a beat feeling (a feeling on the foot sole and the hip when driving on a cracked road surface and the like), balance (for keeping the vehicle in balance), straight-running stability and the like.
  • the obtained points were averaged to provide an evaluation point of the actual ride comfort test. The ride quality is more superior as the point is higher.
  • Example 1 Example 2
  • Example 3 Example 4 Comp. 1 Comp. 2 Comp. 3 Blending Base oil 95.33 95.33 95.33 95.33 95.33 95.33 95.33 Composition Viscosity index 2.20 2.20 2.20 2.20 2.20 2.20 (mass %) improver Detergent dispersant 1 — — — — — 0.50 —
  • Detergent dispersant 2 — — — — — 0.50
  • Component (B) Detergent dispersant 3 0.50 0.50 0.50 0.50 0.50 — — Component (A) Antiwear agent 1 0.50 — — — 0.50 0.50 0.50 Component (A) Antiwear agent 2 — 0.50 — — — — Component (A) Antiwear agent 3 — — 0.50 — — — Component (A) Antiwear agent 4 — — — 0.50 — — Component (C) Oilness agent 1 0.50 0.50 0.50 — 0.50 0.50 0.50 0.50 0.50 0.
  • a shock absorber oil composition of the invention is suitable as a shock absorber oil composition used for a shock absorber (e.g., monotube and multi-tube types) of an automobile (e.g., a motorcycle and a four-wheel vehicle).
  • a shock absorber e.g., monotube and multi-tube types
  • an automobile e.g., a motorcycle and a four-wheel vehicle.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Engineering & Computer Science (AREA)
US14/373,473 2012-01-31 2012-12-13 Shock absorber oil composition Abandoned US20140378358A1 (en)

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JP2012018843A JP5907743B2 (ja) 2012-01-31 2012-01-31 緩衝器油組成物
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JP6702763B2 (ja) * 2016-03-07 2020-06-03 出光興産株式会社 緩衝器用潤滑油組成物、及び緩衝器用潤滑油組成物の製造方法
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US10138440B2 (en) 2018-11-27
CN104066826A (zh) 2014-09-24
EP2811008A4 (en) 2015-12-09
CN104066826B (zh) 2017-03-22
JP2013155349A (ja) 2013-08-15
WO2013114740A1 (ja) 2013-08-08
EP2811008A1 (en) 2014-12-10
JP5907743B2 (ja) 2016-04-26
US20160230114A1 (en) 2016-08-11

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