US20130288890A1 - Ammonia oxidation/decomposition catalyst - Google Patents

Ammonia oxidation/decomposition catalyst Download PDF

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Publication number
US20130288890A1
US20130288890A1 US13/883,302 US201113883302A US2013288890A1 US 20130288890 A1 US20130288890 A1 US 20130288890A1 US 201113883302 A US201113883302 A US 201113883302A US 2013288890 A1 US2013288890 A1 US 2013288890A1
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US
United States
Prior art keywords
catalyst
temperature
ceo
group
pellet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US13/883,302
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English (en)
Inventor
Susumu Hikazudani
Takuma Mori
Sadao Araki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanadevia Corp
Original Assignee
Hitachi Zosen Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=46050987&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=US20130288890(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Hitachi Zosen Corp filed Critical Hitachi Zosen Corp
Assigned to HITACHI ZOSEN CORPORATION reassignment HITACHI ZOSEN CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MORI, TAKUMA, ARAKI, SADAO, HIKAZUDANI, SUSUMU
Publication of US20130288890A1 publication Critical patent/US20130288890A1/en
Abandoned legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
    • C01B3/047—Decomposition of ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/038—Precipitation; Co-precipitation to form slurries or suspensions, e.g. a washcoat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/22—Fuel cells in which the fuel is based on materials comprising carbon or oxygen or hydrogen and other elements; Fuel cells in which the fuel is based on materials comprising only elements other than carbon, oxygen or hydrogen
    • H01M8/222—Fuel cells in which the fuel is based on compounds containing nitrogen, e.g. hydrazine, ammonia
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • the above catalyst has a property of being activated at room temperature, a property of being activated at a temperature lower than room temperature could not be exhibited. If the catalyst can be activated at a temperature even lower than room temperature, the range of application of the catalyst can be widened, and therefore such a catalyst is convenient.
  • the catalyst support As the catalyst support, four types of commercially available CeO 2 —ZrO 2 (manufactured by DAIICHI KIGENSO KAGAKU KOGYO Co., LTD.) in which the molar concentration of ZrO 2 is 10, 20, 50, and 80% were used.
  • each of the above metals on the catalyst support was performed as follows.
  • Each of the metal salts, which are precursors of the respective metals, was dissolved in pure water, to which the above catalyst support was immersed so as to make the metals dispersed on the supports such that the deposition amount of the catalytically active metal was 2% by weight (in terms of metal).

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Fuel Cell (AREA)
US13/883,302 2010-11-09 2011-11-09 Ammonia oxidation/decomposition catalyst Abandoned US20130288890A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2010-250538 2010-11-09
JP2010250538A JP5879029B2 (ja) 2010-11-09 2010-11-09 アンモニア酸化・分解触媒
PCT/JP2011/075775 WO2012063846A1 (ja) 2010-11-09 2011-11-09 アンモニア酸化・分解触媒

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2011/075775 A-371-Of-International WO2012063846A1 (ja) 2010-11-09 2011-11-09 アンモニア酸化・分解触媒

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US15/047,797 Continuation US9896332B2 (en) 2010-11-09 2016-02-19 Ammonia oxidation/decomposition catalyst

Publications (1)

Publication Number Publication Date
US20130288890A1 true US20130288890A1 (en) 2013-10-31

Family

ID=46050987

Family Applications (2)

Application Number Title Priority Date Filing Date
US13/883,302 Abandoned US20130288890A1 (en) 2010-11-09 2011-11-09 Ammonia oxidation/decomposition catalyst
US15/047,797 Active US9896332B2 (en) 2010-11-09 2016-02-19 Ammonia oxidation/decomposition catalyst

Family Applications After (1)

Application Number Title Priority Date Filing Date
US15/047,797 Active US9896332B2 (en) 2010-11-09 2016-02-19 Ammonia oxidation/decomposition catalyst

Country Status (5)

Country Link
US (2) US20130288890A1 (enExample)
EP (1) EP2638962A4 (enExample)
JP (1) JP5879029B2 (enExample)
CN (1) CN103338862B (enExample)
WO (1) WO2012063846A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018020463A1 (en) * 2016-07-29 2018-02-01 Basf Corporation Ruthenium impregnated ceria catalyst

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JP5352343B2 (ja) * 2009-05-21 2013-11-27 日立造船株式会社 水素製造触媒
JP2014067562A (ja) * 2012-09-25 2014-04-17 Nippon Shokubai Co Ltd 固体酸化物形燃料電池及びそれを用いた発電方法
JP6145921B2 (ja) * 2012-11-06 2017-06-14 国立大学法人 大分大学 アンモニアの酸化分解触媒、水素の製造方法及び水素製造装置
JP5991934B2 (ja) * 2013-02-15 2016-09-14 株式会社日本触媒 水素製造用触媒及びその触媒の製造方法
JP6027467B2 (ja) * 2013-03-14 2016-11-16 田中貴金属工業株式会社 アンモニア改質触媒及びその製造方法
JP2015150486A (ja) * 2014-02-13 2015-08-24 Ｊｘ日鉱日石エネルギー株式会社 水素製造用触媒、水素製造用触媒の製造方法及び水素製造方法
JP6308834B2 (ja) * 2014-03-28 2018-04-11 株式会社日本触媒 水素製造用触媒及び該触媒を用いた水素製造方法
EP3145860A1 (en) * 2014-05-22 2017-03-29 SABIC Global Technologies B.V. Mixed metal oxide catalysts for ammonia decomposition
JP6867179B2 (ja) * 2017-02-01 2021-04-28 日立造船株式会社 メタン化反応用触媒の製造方法およびメタンの製造方法
WO2019188219A1 (ja) * 2018-03-26 2019-10-03 昭和電工株式会社 アンモニア分解触媒及びその製造方法、並びに水素ガスの製造方法
WO2021126935A1 (en) * 2019-12-19 2021-06-24 Basf Corporation Exhaust treatment system for ammonia-fueled vehicles
CN112007641B (zh) * 2020-07-20 2023-05-16 浙江工业大学 一种高分散的Ru/ABOx负载型催化剂及其制备方法和应用
JP7539077B2 (ja) * 2020-09-14 2024-08-23 矢崎総業株式会社 水素製造装置
US11724245B2 (en) 2021-08-13 2023-08-15 Amogy Inc. Integrated heat exchanger reactors for renewable fuel delivery systems
US11994061B2 (en) 2021-05-14 2024-05-28 Amogy Inc. Methods for reforming ammonia
WO2022261488A1 (en) * 2021-06-11 2022-12-15 Amogy Inc. Systems and methods for processing ammonia
EP4352008A4 (en) 2021-06-11 2025-07-02 Amogy Inc AMMONIA TREATMENT SYSTEMS AND METHODS
US11539063B1 (en) 2021-08-17 2022-12-27 Amogy Inc. Systems and methods for processing hydrogen
US11912574B1 (en) 2022-10-06 2024-02-27 Amogy Inc. Methods for reforming ammonia
US11795055B1 (en) 2022-10-21 2023-10-24 Amogy Inc. Systems and methods for processing ammonia
US11866328B1 (en) 2022-10-21 2024-01-09 Amogy Inc. Systems and methods for processing ammonia

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US20100130350A1 (en) * 2007-05-21 2010-05-27 National University Corporation Kumamoto University Oxygen storage/release material and exhaust gas purifying catalyst comprising the same
US20100247409A1 (en) * 2007-06-25 2010-09-30 Johnson Matthy Public Limited Company Non-zeolite base metal scr catalyst

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JP5352343B2 (ja) * 2009-05-21 2013-11-27 日立造船株式会社 水素製造触媒
CN102858452A (zh) * 2010-03-31 2013-01-02 株式会社日本触媒 氨分解用催化剂以及该催化剂的制备方法、以及使用该催化剂的氢气制备方法
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US20050095188A1 (en) * 2002-02-15 2005-05-05 Takeshi Matsumoto Catalyst for clarifying exhaust emission from internal combustion engine, method for preparation thereof and method for clarifying exhaust emission from internal combustion engine
US20100130350A1 (en) * 2007-05-21 2010-05-27 National University Corporation Kumamoto University Oxygen storage/release material and exhaust gas purifying catalyst comprising the same
US20100247409A1 (en) * 2007-06-25 2010-09-30 Johnson Matthy Public Limited Company Non-zeolite base metal scr catalyst

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018020463A1 (en) * 2016-07-29 2018-02-01 Basf Corporation Ruthenium impregnated ceria catalyst
US10895183B2 (en) 2016-07-29 2021-01-19 Basf Corporation Ruthenium impregnated ceria catalyst

Also Published As

Publication number Publication date
CN103338862B (zh) 2015-05-06
JP5879029B2 (ja) 2016-03-08
US9896332B2 (en) 2018-02-20
EP2638962A1 (en) 2013-09-18
JP2012101157A (ja) 2012-05-31
US20160167962A1 (en) 2016-06-16
CN103338862A (zh) 2013-10-02
EP2638962A4 (en) 2014-06-18
WO2012063846A1 (ja) 2012-05-18

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Owner name: HITACHI ZOSEN CORPORATION, JAPAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:HIKAZUDANI, SUSUMU;MORI, TAKUMA;ARAKI, SADAO;SIGNING DATES FROM 20130703 TO 20130708;REEL/FRAME:030812/0299

STCB Information on status: application discontinuation

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