US20100087557A1 - Blowing agent composition of hydrofluoropropene and hydrochlorofluoroolefin - Google Patents

Blowing agent composition of hydrofluoropropene and hydrochlorofluoroolefin Download PDF

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Publication number
US20100087557A1
US20100087557A1 US12/532,194 US53219408A US2010087557A1 US 20100087557 A1 US20100087557 A1 US 20100087557A1 US 53219408 A US53219408 A US 53219408A US 2010087557 A1 US2010087557 A1 US 2010087557A1
Authority
US
United States
Prior art keywords
blowing agent
hfo
isomers
hcfo
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US12/532,194
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English (en)
Inventor
Benjamin Bin Chen
Joseph S. Costa
Brett L. Van Horn
Maher Y. Elsheikh
Philippe Bonnet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema Inc
Original Assignee
Arkema Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=39808678&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=US20100087557(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Arkema Inc filed Critical Arkema Inc
Priority to US12/532,194 priority Critical patent/US20100087557A1/en
Assigned to ARKEMA INC. reassignment ARKEMA INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BONNET, PHILIPPE, CHEN, BENJAMIN BIN, COSTA, JOSEPH S., ELSHEIKH, MAHER Y., VAN HORN, BRETT L.
Publication of US20100087557A1 publication Critical patent/US20100087557A1/en
Abandoned legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143Halogen containing compounds
    • C08J9/144Halogen containing compounds containing carbon, halogen and hydrogen only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143Halogen containing compounds
    • C08J9/144Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/149Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017Mixtures of compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/14Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/16Unsaturated hydrocarbons
    • C08J2203/162Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/18Binary blends of expanding agents
    • C08J2203/182Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00Characterised by the use of unspecified polymers
    • C08J2300/10Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C08J2300/104Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00Characterised by the use of unspecified polymers
    • C08J2300/10Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C08J2300/106Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing nitrogen atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
US12/532,194 2007-03-29 2008-03-28 Blowing agent composition of hydrofluoropropene and hydrochlorofluoroolefin Abandoned US20100087557A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US12/532,194 US20100087557A1 (en) 2007-03-29 2008-03-28 Blowing agent composition of hydrofluoropropene and hydrochlorofluoroolefin

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US90875107P 2007-03-29 2007-03-29
US12/532,194 US20100087557A1 (en) 2007-03-29 2008-03-28 Blowing agent composition of hydrofluoropropene and hydrochlorofluoroolefin
PCT/US2008/058604 WO2008121787A1 (en) 2007-03-29 2008-03-28 Blowing agent composition of hydrofluoropropene and hydrochlorofluoroolefin

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2008/058604 A-371-Of-International WO2008121787A1 (en) 2007-03-29 2008-03-28 Blowing agent composition of hydrofluoropropene and hydrochlorofluoroolefin

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US14/339,732 Division US20140336293A1 (en) 2007-03-29 2014-07-24 Blowing agent composition of hydrofluoropropene and hydrochlorofluoroolefin

Publications (1)

Publication Number Publication Date
US20100087557A1 true US20100087557A1 (en) 2010-04-08

Family

ID=39808678

Family Applications (8)

Application Number Title Priority Date Filing Date
US12/532,202 Active US9279039B2 (en) 2007-03-29 2008-03-28 Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin
US12/532,189 Abandoned US20100056657A1 (en) 2007-03-29 2008-03-28 Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin
US12/532,194 Abandoned US20100087557A1 (en) 2007-03-29 2008-03-28 Blowing agent composition of hydrofluoropropene and hydrochlorofluoroolefin
US14/305,287 Active US9228071B2 (en) 2007-03-29 2014-06-16 Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin
US14/339,732 Abandoned US20140336293A1 (en) 2007-03-29 2014-07-24 Blowing agent composition of hydrofluoropropene and hydrochlorofluoroolefin
US14/964,896 Abandoned US20160090462A1 (en) 2007-03-29 2015-12-10 Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin
US15/015,184 Active US9914815B2 (en) 2007-03-29 2016-02-04 Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin
US15/245,412 Abandoned US20160362531A1 (en) 2007-03-29 2016-08-24 Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin

Family Applications Before (2)

Application Number Title Priority Date Filing Date
US12/532,202 Active US9279039B2 (en) 2007-03-29 2008-03-28 Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin
US12/532,189 Abandoned US20100056657A1 (en) 2007-03-29 2008-03-28 Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin

Family Applications After (5)

Application Number Title Priority Date Filing Date
US14/305,287 Active US9228071B2 (en) 2007-03-29 2014-06-16 Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin
US14/339,732 Abandoned US20140336293A1 (en) 2007-03-29 2014-07-24 Blowing agent composition of hydrofluoropropene and hydrochlorofluoroolefin
US14/964,896 Abandoned US20160090462A1 (en) 2007-03-29 2015-12-10 Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin
US15/015,184 Active US9914815B2 (en) 2007-03-29 2016-02-04 Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin
US15/245,412 Abandoned US20160362531A1 (en) 2007-03-29 2016-08-24 Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin

Country Status (9)

Country Link
US (8) US9279039B2 (ja)
EP (3) EP2129714B1 (ja)
JP (3) JP5416086B2 (ja)
CN (6) CN101652412B (ja)
AT (3) ATE528341T1 (ja)
CA (3) CA2681838C (ja)
ES (3) ES2380080T3 (ja)
PL (3) PL2129714T3 (ja)
WO (3) WO2008121790A1 (ja)

Cited By (12)

* Cited by examiner, † Cited by third party
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US20100216904A1 (en) * 2009-02-24 2010-08-26 E. I. Du Pont De Nemours And Company Foam-forming compositions containing mixtures of 2-chloro-3,3,3-trifluoropropene and at least one hydrofluoroolefin and their uses in the preparation of polyisocyanate-based foams
US20110001080A1 (en) * 2008-03-07 2011-01-06 Arkema Inc. Stable formulated systems with chloro-3,3,3-trifluoropropene
US20110124758A1 (en) * 2008-08-13 2011-05-26 E.I. Du Pont De Nemours And Company Foam-forming compositions containing mixtures of 2-chloro-3,3,3-trifluoropropene and hydrocarbon and their uses in the preparation of polyisocyanate-based foams
US20110124756A1 (en) * 2009-05-21 2011-05-26 Huntsman International Llc Rigid polyurethane foam and system and method for making the same
US20120101177A1 (en) * 2007-03-29 2012-04-26 Arkema Inc. Blowing agent compositions of hydrochlorofluoroolefins
WO2012024252A3 (en) * 2010-08-17 2012-05-31 Honeywell International Inc. Compositions containing 1-chloro-3,3,3 trifluoropropene and 1-fluoro-1,1 dichloroethane
WO2013096727A1 (en) * 2011-12-22 2013-06-27 Honeywell International Inc. Azeotrope-like compositions including cis-1-chloro-3,3,3-trifluoropropene
US8680168B2 (en) 2010-11-17 2014-03-25 Fomo Products, Inc. Method for filling wall cavities with expanding foam insulation
US20150210818A1 (en) * 2014-01-27 2015-07-30 E I Du Pont De Nemours And Company Cryogenic insulation foam
WO2015168486A1 (en) * 2014-04-30 2015-11-05 Honeywell International Inc. Flexible, open-cell thermoset foams and blowing agents and methods for making same
US10113046B2 (en) 2009-10-23 2018-10-30 Arkema Inc Tetrafluorobutene blowing agent compositions for polyurethane foams
US10301236B2 (en) 2015-05-21 2019-05-28 The Chemours Company Fc, Llc Hydrofluorination of a halogenated olefin with SbF5 in the liquid phase

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US20090253820A1 (en) * 2006-03-21 2009-10-08 Honeywell International Inc. Foaming agents and compositions containing fluorine sustituted olefins and methods of foaming
US9499729B2 (en) * 2006-06-26 2016-11-22 Honeywell International Inc. Compositions and methods containing fluorine substituted olefins
TWI408162B (zh) 2005-06-24 2013-09-11 Honeywell Int Inc 含有經氟取代之烯烴之發泡劑及組合物,及發泡方法
US9695267B2 (en) * 2009-08-11 2017-07-04 Honeywell International Inc. Foams and foamable compositions containing halogenated olefin blowing agents
JP2010534254A (ja) * 2007-07-20 2010-11-04 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 組成物、およびポリイソシアネートベースの発泡体の製造におけるトランス−1,1,1,4,4,4−ヘキサフルオロ−2−ブテン発泡成形用組成物の使用
US8628681B2 (en) 2007-10-12 2014-01-14 Mexichem Amanco Holding S.A. De C.V. Heat transfer compositions
WO2009047542A1 (en) 2007-10-12 2009-04-16 Ineos Fluor Holdings Limited Heat transfer compositions
US8333901B2 (en) 2007-10-12 2012-12-18 Mexichem Amanco Holding S.A. De C.V. Heat transfer compositions
GB201002625D0 (en) 2010-02-16 2010-03-31 Ineos Fluor Holdings Ltd Heat transfer compositions
US8512591B2 (en) 2007-10-12 2013-08-20 Mexichem Amanco Holding S.A. De C.V. Heat transfer compositions
WO2009089400A1 (en) * 2008-01-11 2009-07-16 E. I. Du Pont De Nemours And Company Compositions and use of 2-chloro-3,3,3-trifluoropropene foam-forming composition in the preparation of polyisocyanate-based foams
SI2634231T1 (sl) * 2008-05-07 2022-10-28 The Chemours Company Fc, Llc Sestavki
US8163196B2 (en) * 2008-10-28 2012-04-24 Honeywell International Inc. Azeotrope-like compositions comprising 1-chloro-3,3,3-trifluoropropene
KR20110099702A (ko) * 2008-12-02 2011-09-08 멕시켐 아만코 홀딩 에스.에이. 데 씨.브이. 열전달 조성물
JP5684730B2 (ja) * 2009-01-29 2015-03-18 アーケマ・インコーポレイテッド テトラフルオロプロペン系発泡剤組成物
TW201103972A (en) 2009-04-01 2011-02-01 Solvay Fluor Gmbh Process for the manufacture of etched items
BRPI1008127A2 (pt) * 2009-06-02 2016-03-08 Du Pont "composição e processo para a preparação de uma espuma termoplástica ou termofixa"
CN102597035A (zh) * 2009-07-27 2012-07-18 阿科玛股份有限公司 用于聚氨酯泡沫中的HCFO-1233zd和多元醇共混物的组合物
DE102009028061A1 (de) 2009-07-29 2011-02-10 Evonik Goldschmidt Gmbh Verfahren zur Herstellung von Polyurethanschaum
SI3812360T1 (sl) * 2009-09-09 2024-02-29 Honeywell International Inc. Monoklorotrifluoropropenske spojine in sestavki ter postopki, ki jih uporabljajo
US8846754B2 (en) * 2009-12-16 2014-09-30 Honeywell International Inc. Azeotrope-like compositions of cis-1,1,1,4,4,4-hexafluoro-2-butene
MX2020010605A (es) 2009-12-22 2022-06-14 Du Pont Composiciones que comprenden 2,3,3,3-tetrafluoropropeno, 1,1,2,3-tetracloropropeno, 2-cloro-3,3,3-trifluoropropeno, o 2-cloro-1,1,1,2-tetrafluoropropano.
GB201002622D0 (en) 2010-02-16 2010-03-31 Ineos Fluor Holdings Ltd Heat transfer compositions
US8821749B2 (en) * 2010-04-26 2014-09-02 E I Du Pont De Nemours And Company Azeotrope-like compositions of E-1,1,1,4,4,4-hexafluoro-2-butene and 1-chloro-3,3,3-trifluoropropene
PL2571952T3 (pl) 2010-05-20 2016-01-29 Mexichem Fluor Sa De Cv Kompozycje do wymiany ciepła
KR20130082096A (ko) 2010-05-20 2013-07-18 멕시켐 아만코 홀딩 에스.에이. 데 씨.브이. 열전달 조성물
GB2481443B (en) 2010-06-25 2012-10-17 Mexichem Amanco Holding Sa Heat transfer compositions
US20120046372A1 (en) * 2010-08-18 2012-02-23 Honeywell International Inc. Blowing agents, foamable compositions and foams
US9145480B2 (en) * 2010-10-28 2015-09-29 Honeywell International Inc. Mixtures containing 1,1,1,3,3,3-hexafluorobutene and 1-chloro-3,3,3-trifluoropropene
US8734671B2 (en) * 2010-11-19 2014-05-27 Honeywell International Inc. Azeotrope-like compositions comprising 1-chloro-3,3,3-trifluoropropene
JP5881725B2 (ja) * 2010-11-25 2016-03-09 アルケマ フランス クロロトリフルオロプロペンとヘキサフルオロブテンとの組成物
FR2968310B1 (fr) * 2010-12-03 2012-12-07 Arkema France Compositions a base de 1,1,1,4,4,4-hexafluorobut-2-ene et de 3,3,4,4,4-pentafluorobut-1-ene
CN103339164B (zh) 2010-12-21 2016-08-17 陶氏环球技术有限责任公司 用于聚氨酯硬质泡沫体改进的低温表皮固化的多元醇配方
US9724684B2 (en) 2011-02-21 2017-08-08 The Chemours Company Fc, Llc Selective catalytical dehydrochlorination of hydrochlorofluorocarbons
FR2977256B1 (fr) * 2011-07-01 2013-06-21 Arkema France Compositions de 2,4,4,4-tetrafluorobut-1-ene et de cis-1,1,1,4,4,4-hexafluorobut-2-ene
MX353653B (es) * 2011-07-28 2018-01-23 Honeywell Int Inc Espumas y articulos pirorresistentes fabricados a partir de las espumas que contienen 1 - cloro - 3,3,3 - trifluoropropeno (1233zd).
US9896558B2 (en) 2011-08-01 2018-02-20 Basf Se HFO/water-blown rigid foam systems
JP6085299B2 (ja) 2011-08-01 2017-02-22 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se Hfo/水で発泡した硬質フォーム系
MX2014004563A (es) 2011-10-14 2014-08-01 Dow Global Technologies Llc Polioles de poliester-polieter hibridos para la expansion de desmoldeo mejorada en espumas rigidas de poliuretano.
JP6069335B2 (ja) 2011-10-20 2017-02-01 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company E−1−クロロ−2,3,3,3−テトラフルオロプロペンの共沸混合物様組成物およびそれらの使用
KR20140105739A (ko) * 2011-12-09 2014-09-02 허니웰 인터내셔널 인코포레이티드 Hcfo 또는 hfo 발포제를 함유하는 폼 및 폼으로 형성된 물품
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US9000239B2 (en) * 2012-05-15 2015-04-07 Honeywell International Inc. Methods for producing 1-chloro-3,3,3-trifluoropropene from 2-chloro-3,3,3-trifluoropropene
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CN109306069A (zh) 2013-03-15 2019-02-05 欧文斯科宁知识产权资产有限公司 在使用低全球变暖的潜在发泡剂制造挤出聚苯乙烯泡沫体中使用的加工助剂
CN103881131A (zh) * 2014-03-17 2014-06-25 浙江衢化氟化学有限公司 一种环保型发泡剂组合物
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