US20090007545A1 - Exhaust Purifier for Internal Combustion Engine - Google Patents

Exhaust Purifier for Internal Combustion Engine Download PDF

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Publication number
US20090007545A1
US20090007545A1 US11/816,280 US81628006A US2009007545A1 US 20090007545 A1 US20090007545 A1 US 20090007545A1 US 81628006 A US81628006 A US 81628006A US 2009007545 A1 US2009007545 A1 US 2009007545A1
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United States
Prior art keywords
addition
temperature
amount
exhaust gas
valve
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Abandoned
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US11/816,280
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English (en)
Inventor
Kazuaki Kameda
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Toyota Industries Corp
Toyota Motor Corp
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Toyota Industries Corp
Toyota Motor Corp
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Assigned to TOYOTA JIDOSHA KABUSHIKI KAISHA, KABUSHIKI KAISHA TOYOTA JIDOSHOKKI reassignment TOYOTA JIDOSHA KABUSHIKI KAISHA ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KAMEDA, KAZUAKI
Publication of US20090007545A1 publication Critical patent/US20090007545A1/en
Abandoned legal-status Critical Current

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02D—CONTROLLING COMBUSTION ENGINES
    • F02D41/00—Electrical control of supply of combustible mixture or its constituents
    • F02D41/02—Circuit arrangements for generating control signals
    • F02D41/021—Introducing corrections for particular conditions exterior to the engine
    • F02D41/0235—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus
    • F02D41/027—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus to purge or regenerate the exhaust gas treating apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9431—Processes characterised by a specific device
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N11/00—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity
    • F01N11/002—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity the diagnostic devices measuring or estimating temperature or pressure in, or downstream of the exhaust apparatus
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • F01N13/0097—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series the purifying devices are arranged in a single housing
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0814—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0821—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with particulate filters
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/0842—Nitrogen oxides
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0871—Regulation of absorbents or adsorbents, e.g. purging
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/105—General auxiliary catalysts, e.g. upstream or downstream of the main catalyst
    • F01N3/106—Auxiliary oxidation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2260/00—Exhaust treating devices having provisions not otherwise provided for
    • F01N2260/02—Exhaust treating devices having provisions not otherwise provided for for cooling the device
    • F01N2260/024—Exhaust treating devices having provisions not otherwise provided for for cooling the device using a liquid
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2510/00—Surface coverings
    • F01N2510/06—Surface coverings for exhaust purification, e.g. catalytic reaction
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2560/00—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
    • F01N2560/06—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being a temperature sensor
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2560/00—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
    • F01N2560/08—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being a pressure sensor
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2560/00—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
    • F01N2560/14—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics having more than one sensor of one kind
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/03—Adding substances to exhaust gases the substance being hydrocarbons, e.g. engine fuel
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/14—Arrangements for the supply of substances, e.g. conduits
    • F01N2610/1493—Purging the reducing agent out of the conduits or nozzle
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2900/00—Details of electrical control or of the monitoring of the exhaust gas treating apparatus
    • F01N2900/06—Parameters used for exhaust control or diagnosing
    • F01N2900/08—Parameters used for exhaust control or diagnosing said parameters being related to the engine
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2900/00—Details of electrical control or of the monitoring of the exhaust gas treating apparatus
    • F01N2900/06—Parameters used for exhaust control or diagnosing
    • F01N2900/18—Parameters used for exhaust control or diagnosing said parameters being related to the system for adding a substance into the exhaust
    • F01N2900/1806—Properties of reducing agent or dosing system
    • F01N2900/1811—Temperature
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/033—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
    • F01N3/035—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02D—CONTROLLING COMBUSTION ENGINES
    • F02D41/00—Electrical control of supply of combustible mixture or its constituents
    • F02D41/02—Circuit arrangements for generating control signals
    • F02D41/021—Introducing corrections for particular conditions exterior to the engine
    • F02D41/0235—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus
    • F02D2041/0265—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus to decrease temperature of the exhaust gas treating apparatus
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/40—Engine management systems

Definitions

  • the present invention relates to an exhaust gas purifying apparatus of an internal combustion engine, configured to provide an addition valve upstream of an exhaust gas purifying catalyst in an exhaust pipe for injection of a reducing agent, in addition to a fuel injection valve injecting fuel burnt in a combustion chamber of the internal combustion engine.
  • an NOx catalyst attaining a function to purify a nitrogen oxide NOx in the exhaust gas is provided in an exhaust pipe thereof.
  • the NOx catalyst for example, a catalyst carrying both an NOx absorbent capable of absorbing nitrogen oxide NOx in the presence of oxygen and a precious metal catalyst (precious metal) capable of oxidizing hydrocarbon HC on a honeycomb structure (carrier) made of porous ceramics is adopted.
  • the NOx catalyst has such a characteristic that it absorbs nitrogen oxide NOx in a state where oxygen concentration in the exhaust gas is high, while it emits nitrogen oxide NOx in a state where oxygen concentration in the exhaust gas is low.
  • the precious metal catalyst promotes oxidation reaction of hydrocarbon HC or carbon monoxide CO, so that oxidation-reduction reaction using nitrogen oxide NOx as an oxidation component and using hydrocarbon HC and carbon monoxide CO as a reduction component occurs therebetween.
  • hydrocarbon HC and carbon monoxide CO are oxidized to carbon dioxide CO 2 or water H 2 O, and nitrogen oxide NOx is reduced to nitrogen N 2 .
  • the NOx catalyst absorbs no more nitrogen oxide NOx even in a state where oxygen concentration in the exhaust gas is high. Accordingly, in the internal combustion engine provided with such an NOx catalyst in the exhaust pipe, an addition valve is provided upstream of the NOx catalyst in the exhaust pipe, separately from a fuel injection valve injecting fuel for combustion in the combustion chamber. By supplying a reducing agent such as light oil from the addition valve, nitrogen oxide NOx absorbed in the NOx catalyst is emitted and reduced and purified, so that NOx absorption capability of the NOx catalyst is recovered and the NOx absorption amount of the NOx catalyst does not reach the limit amount (see, for example, Japanese Patent Laying-Open No. 2003-120392).
  • a component that is likely to volatilize (hereinafter, referred to as a volatile component) in the reducing agent that passes the addition valve evaporates, and a remaining deposit component is adhered and deposited in an injection hole of the addition valve and its surroundings. It may be likely that the deposits clog the injection hole and the reducing agent is not appropriately injected from the injection hole.
  • the reducing agent at a low temperature passes the addition valve in a large amount, and the reducing agent removes the heat of the addition valve.
  • the temperature at the tip end portion of the addition valve including the injection hole is lowered, and clogging of the injection hole is suppressed.
  • the temperature of the NOx catalyst (catalyst bed temperature) is raised by the heat generated during combustion. If the NOx catalyst is excessively heated, the catalyst bed temperature may exceed the upper limit of a temperature range (allowable range) where the NOx catalyst appropriately functions.
  • the present invention was made in view of such situations, and an object of the present invention is to provide an exhaust gas purifying apparatus of an internal combustion engine capable of suppressing overheat of an exhaust gas purifying catalyst while suppressing clogging of an injection hole of an addition valve.
  • the present invention is directed to an exhaust gas purifying apparatus of an internal combustion engine, configured to provide an addition valve upstream of an exhaust gas purifying catalyst in an exhaust pipe connected to a combustion chamber in addition to a fuel injection valve injecting fuel for combustion in the combustion chamber of the internal combustion engine, and to inject a reducing agent from the addition valve in an addition amount in accordance with an operation state of the internal combustion engine.
  • the apparatus includes a control unit increasing the addition amount with increase in at least one of a temperature of the addition valve and a value corresponding thereto and controlling a parameter other than the addition amount, that varies in accordance with an operation of the internal combustion engine and affects a catalyst temperature of the exhaust gas purifying catalyst, such that the catalyst temperature does not exceed an upper limit of an allowable range.
  • the control unit increases the addition amount with the increase in the temperature of the addition valve and the increased reducing agent passes the addition valve, so that the heat of the addition valve is removed.
  • the temperature of the addition valve is lowered, evaporation of the volatile component in the reducing agent is suppressed, and clogging of the injection hole in the addition valve is suppressed.
  • the increased reducing agent burns, and the temperature of the exhaust gas purifying catalyst is raised by the heat generated during the combustion.
  • the control unit controls the parameter other than the addition amount that varies in accordance with the operation of the internal combustion engine and affects the temperature of the exhaust gas purifying catalyst.
  • overheat of the exhaust gas purifying catalyst can be suppressed by controlling the parameter, while clogging of the injection hole of the addition valve is suppressed by increasing the addition amount.
  • the control unit when at least one of the temperature of the addition valve and the corresponding value is high, the control unit makes a degree of increase in the addition amount greater than when at least one of the temperature of the addition valve and the corresponding value is low.
  • the degree of increase in the addition amount is made larger than when at least one of the temperature of the addition valve and the value corresponding thereto is low. In this manner, the degree of increase in the addition amount is varied in accordance with the temperature of the addition valve. Therefore, when the temperature of the addition valve is relatively low, excessive cooling of the addition valve due to excessive increase in the addition amount can be suppressed. In addition, when the temperature of the addition valve is high, such a phenomenon as clogging of the injection hole of the addition valve due to an insufficient addition amount and resultant insufficient cooling of the addition valve can be suppressed.
  • the addition valve is arranged in the vicinity of a coolant pipe provided in the internal combustion engine, and the control unit employs a temperature of a coolant that flows through the coolant pipe as the corresponding value.
  • the temperature of the addition valve tends to be affected by the heat of the coolant that flows in the coolant pipe.
  • the temperature of the coolant is not so high, such as during a low or intermediate load operation or the like of the internal combustion engine, the addition valve is cooled as a result of heat removal by the coolant, and clogging of the injection hole is unlikely.
  • efficiency in cooling the addition valve is lowered, and the temperature of the addition valve may exceed the temperature at which the volatile component in the reducing agent evaporates. Therefore, according to the present invention, the effect of the invention described above is reliably obtained by employing the temperature of the coolant as the value corresponding to the temperature of the addition valve and by increasing the addition amount based on the corresponding value.
  • control unit restricts an amount of fuel injection from the fuel injection valve, as control of the parameter.
  • the temperature of the exhaust gas and the catalyst is accordingly lowered.
  • the injection amount is thus restricted as in the present invention, so that the injection amount is decreased as compared with a case where the injection amount is not restricted, and the temperature of the exhaust gas is lowered. Then, the temperature of the catalyst is lowered, and it is less likely that the upper limit of the allowable range is exceeded. In this manner, according to the present invention, the effect of the invention described above is reliably obtained.
  • control unit restricts the amount of fuel injection to a larger extent than when at least one of the temperature of the addition valve and the corresponding value is low.
  • the injection amount is restricted to a larger extent, an amount of lowering in the temperature of the exhaust gas and the catalyst as a result of restriction becomes greater.
  • the injection amount is restricted to a larger extent than when at least one of the temperature of the addition valve and the value corresponding thereto is low.
  • the degree of restriction of the injection amount is varied in accordance with at least one of the temperature of the addition valve and the value corresponding thereto, so that undue lowering in the engine output due to excessive restriction of the injection amount can be suppressed when at least one of the temperature of the addition valve and the value corresponding thereto is relatively low.
  • at least one of the temperature of the addition valve and the value corresponding thereto is high, such a situation that restriction of the injection amount is insufficient (the injection amount is great) and the temperature of the catalyst consequently exceeds the upper limit of the allowable range can be suppressed.
  • control unit decreases an amount of fuel injection from the fuel injection valve, as control of the parameter.
  • the temperature of the exhaust gas and the catalyst is accordingly lowered.
  • the injection amount is thus decreased as in the present invention, so that the temperature of the exhaust gas is lowered as compared with a case where the injection amount is not decreased. Then, the temperature of the catalyst is lowered, and it is unlikely that the upper limit of the allowable range is exceeded. In this manner, according to the present invention, the effect of the invention described above is reliably obtained.
  • control unit decreases the amount of fuel injection by a larger amount than when at least one of the temperature of the addition valve and the corresponding value is low.
  • the injection amount is decreased
  • an amount of lowering in the temperature of the exhaust gas and the catalyst as a result of decrease becomes greater.
  • the injection amount is decreased more than when at least one of the temperature of the addition valve and the value corresponding thereto is low.
  • the degree of decrease in the injection amount is varied in accordance with at least one of the temperature of the addition valve and the value corresponding thereto, so that undue lowering in the engine output due to excessive decrease in the injection amount can be suppressed when at least one of the temperature of the addition valve and the value corresponding thereto is relatively low.
  • at least one of the temperature of the addition valve and the value corresponding thereto is high, such a situation that decrease in the injection amount is insufficient (the injection amount is great) and the temperature of the catalyst exceeds the upper limit of the allowable range can be suppressed.
  • FIG. 1 is a diagram showing a configuration of a first embodiment implementing the present invention.
  • FIG. 2 is a schematic plan view showing an addition valve and a portion around the same in an engine.
  • FIG. 3 is a timing chart illustrating a period during which a reducing agent is added and an interval of addition.
  • FIG. 4A is a flowchart showing a procedure for injection hole clogging suppression processing.
  • FIG. 4B is a flowchart showing a procedure for injection amount restriction processing.
  • FIG. 5 is a characteristic diagram showing relation of an engine coolant temperature, a catalyst bed temperature, an addition amount, and an injection amount upper limit.
  • FIG. 6 is a flowchart showing a procedure for injection amount decrease processing in a second embodiment of the present invention.
  • FIG. 7 is a characteristic diagram showing relation between an engine coolant temperature and a correction amount.
  • FIG. 8 is a characteristic diagram showing relation of an engine coolant temperature, a catalyst bed temperature, an addition amount, and a correction amount.
  • FIG. 1 shows a configuration of a multi-cylinder diesel engine (hereinafter, simply referred to as an engine) 11 serving as an internal combustion engine to which the present embodiment is applied and an exhaust gas purifying apparatus 12 .
  • FIG. 2 shows a schematic plan view of engine 11 .
  • Engine 11 generally includes an intake pipe 13 , a combustion chamber 14 for each cylinder 10 , and an exhaust pipe 15 .
  • An air cleaner 16 purifying air taken in intake pipe 13 is provided in a most upstream portion of intake pipe 13 .
  • an airflow meter 17 for detecting a flow rate of air in intake pipe 13 a compressor 18 A of a turbo charger 18 , an intercooler 19 , and an intake air throttle valve 21 are sequentially arranged toward the intake air downstream side of air cleaner 16 .
  • Intake pipe 13 is branched at an intake manifold 22 provided on the intake air downstream side of intake air throttle valve 21 , and connected to combustion chamber 14 for each cylinder 10 through the branch portion.
  • a fuel injection valve 24 injecting fuel for combustion in combustion chamber 14 is provided for each cylinder 10 .
  • Each fuel injection valve 24 is supplied with fuel from a fuel tank 26 through a fuel supply pipe 25 .
  • a fuel pump 27 suctioning fuel from fuel tank 26 and pressurizing and delivering the fuel and a common rail 28 serving as a high-pressure fuel pipe accumulating the delivered high-pressure fuel are provided.
  • Fuel injection valve 24 for each cylinder 10 is connected to common rail 28 .
  • exhaust pipe 15 a connection portion of exhaust pipe 15 and each combustion chamber 14 serves as an exhaust port 29 .
  • an exhaust manifold 31 for gathering the exhaust gas exhausted from each combustion chamber 14 through exhaust port 29 and a turbine 18 B of turbo charger 18 are provided.
  • engine 11 adopts an exhaust gas recirculation (hereinafter, referred to as “EGR”) apparatus 32 for recirculating a part of the exhaust gas in the intake air.
  • EGR apparatus 32 includes an EGR pipe 33 allowing communication between intake pipe 13 and exhaust pipe 15 .
  • An upstream side of EGR pipe 33 is connected to a portion of exhaust pipe 15 between exhaust manifold 31 and turbine 18 B.
  • an EGR cooler catalyst 34 purifying the recirculated exhaust gas
  • an EGR cooler 35 cooling the recirculated exhaust gas
  • an EGR valve 36 regulating a flow rate of the recirculated exhaust gas are provided sequentially from the upstream side.
  • the downstream side of EGR pipe 33 is connected to a portion of intake pipe 13 between intake air throttle valve 21 and intake manifold 22 .
  • the air taken in intake pipe 13 is purified in air cleaner 16 , and thereafter introduced in compressor 18 A of turbo charger 18 .
  • compressor 18 A the introduced air is compressed and delivered to intercooler 19 .
  • the air of which temperature is raised as a result of compression is cooled in intercooler 19 , and thereafter the air passes through intake air throttle valve 21 and intake manifold 22 , and distributed and supplied to combustion chamber 14 of each cylinder 10 .
  • the flow rate of the air in intake pipe 13 is regulated by controlling a degree of opening of intake air throttle valve 21 .
  • the flow rate of the air that is, the amount of intake air, is detected by airflow meter 17 .
  • combustion chamber 14 into which the air is introduced, fuel is injected from fuel injection valve 24 in the compression stroke of each cylinder 10 . Then, a mixture of the air introduced through intake pipe 13 and the fuel injected from fuel injection valve 24 is burnt in combustion chamber 14 .
  • the combustion gas at high temperature and high pressure generated at this time causes a piston 37 to carry out reciprocating motion, a crankshaft 38 serving as an output shaft rotates, and drive force (output torque) of engine 11 is obtained.
  • An NE sensor 39 detecting an engine speed NE indicating a rotation speed of crankshaft 38 is provided in engine 11 .
  • the exhaust gas generated as a result of combustion in combustion chamber 14 of each cylinder 10 is introduced in turbine 18 B of turbo charger 18 through exhaust manifold 31 .
  • turbine 18 B is driven by the stream of the introduced exhaust gas
  • compressor 18 A provided in intake pipe 13 is driven in synchronization, and the air is compressed as described above.
  • EGR pipe 33 a part of the exhaust gas generated as a result of combustion is introduced in EGR pipe 33 .
  • the exhaust gas introduced in EGR pipe 33 is purified by EGR cooler catalyst 34 and cooled in EGR cooler 35 , and thereafter recirculated in the air on the intake air downstream side of intake air throttle valve 21 in intake pipe 13 .
  • the flow rate of the exhaust gas thus recirculated is regulated by controlling the degree of opening of EGR valve 36 .
  • Exhaust gas purifying apparatus 12 for purifying the exhaust gas exhausted from engine 11 will now be described.
  • Exhaust gas purifying apparatus 12 includes not only an addition valve 41 but also a plurality of (three) catalytic converters (a first catalytic converter 42 , a second catalytic converter 43 , and a third catalytic converter 44 ) serving as exhaust gas purifying catalysts.
  • First catalytic converter 42 at the most upstream portion is arranged on the exhaust downstream side of turbine 18 B.
  • a storage-reduction type NOx catalyst is accommodated in first catalytic converter 42 .
  • the NOx catalyst is implemented, for example, in such a manner that a honeycomb structure is employed as a carrier and an NOx absorbent capable of absorbing nitrogen oxide NOx in the presence of oxygen and a precious metal catalyst (precious metal) capable of oxidizing hydrocarbon HC are carried thereon.
  • the NOx absorbent has such a characteristic that it absorbs nitrogen oxide NOx in a state where the oxygen concentration in the exhaust gas is high, while it emits nitrogen oxide NOx in a state where the oxygen concentration is low.
  • the precious metal catalyst promotes oxidation reaction of hydrocarbon HC or carbon monoxide CO, so that oxidation-reduction reaction employing nitrogen oxide NOx as an oxidation component and employing hydrocarbon HC and carbon monoxide CO as a reduction component occurs therebetween.
  • hydrocarbon HC and carbon monoxide CO are oxidized to carbon dioxide CO 2 or water H 2 O, and nitrogen oxide NOx is reduced to nitrogen N 2 .
  • Second catalytic converter 43 is arranged on the exhaust downstream side of first catalytic converter 42 .
  • a storage-reduction type NOx catalyst is accommodated in second catalytic converter 43 .
  • the NOx catalyst includes a porous material allowing passage of a gas component in the exhaust gas and preventing passage of particulate matter PM in the exhaust gas. This porous material is employed as the carrier of the NOx catalyst, and the carrier carries the NOx absorbent and the precious metal catalyst.
  • Third catalytic converter 44 is arranged on the exhaust downstream side of second catalytic converter 43 . In third catalytic converter 44 , an oxidizing catalyst purifying the exhaust gas through oxidation of hydrocarbon HC and carbon monoxide CO in the exhaust gas is carried.
  • Addition valve 41 is arranged in exhaust pipe 15 , upstream of first catalytic converter 42 .
  • addition valve 41 is attached to a portion in the vicinity of exhaust port 29 in cylinder head 23 .
  • Addition valve 41 is attached to cylinder head 23 in such a manner that an injection hole 41 A at the tip end is exposed in exhaust port 29 . As shown in FIG. 2 , this position is located around a water jacket 45 serving as a coolant pipe provided in cylinder head 23 . Addition valve 41 is attached to such a position, so that addition valve 41 is cooled by the engine coolant that flows through water jacket 45 .
  • addition valve 41 is connected to fuel pump 27 through a fuel pipe 46 , and injects and adds the fuel supplied from fuel pump 27 into the exhaust gas as the reducing agent.
  • the added fuel temporarily turns the exhaust gas to a reduction atmosphere, so that nitrogen oxide NOx stored in first catalytic converter 42 and second catalytic converter 43 is reduced and purified.
  • second catalytic converter 43 simultaneously purifies particulate matter PM.
  • a coolant temperature sensor 47 detecting a temperature of the engine coolant (engine coolant temperature THW) that flows through water jacket 45 is attached to cylinder head 23 .
  • an exhaust gas temperature sensor 48 detecting a temperature of the exhaust gas (exhaust gas temperature) that passes a space between first catalytic converter 42 and second catalytic converter 43 in exhaust pipe 15 , that is, the temperature of the exhaust gas before entering second catalytic converter 43 is arranged in that space.
  • an exhaust gas temperature sensor 49 detecting a temperature of the exhaust gas that passes through a space downstream of second catalytic converter 43 in exhaust pipe 15 , that is, the temperature of the exhaust gas immediately after passing through second catalytic converter 43 is arranged in that space.
  • a differential pressure sensor 51 detecting a differential pressure between the pressure of the exhaust gas on the exhaust upstream side of second catalytic converter 43 and the pressure of the exhaust gas on the exhaust downstream side thereof is arranged in exhaust pipe 15 .
  • oxygen sensors 52 , 53 detecting a concentration of oxygen in the exhaust gas are arranged on the exhaust upstream side of first catalytic converter 42 of exhaust pipe 15 , and between second catalytic converter 43 and third catalytic converter 44 , respectively.
  • An electronic control unit 61 serving as control means controls engine 11 and exhaust gas purifying apparatus 12 described above.
  • Electronic control unit 61 includes a CPU executing various types of processing involved with control of engine 11 , an ROM storing a program or data necessary for control, an RAM storing a result of processing or the like performed by the CPU, an input/output port for transmitting/receiving information to/from the outside, and the like.
  • an accelerator sensor 54 detecting how far the accelerator is pressed down by a driver
  • a common rail sensor 55 detecting an internal pressure (rail pressure) of common rail 28
  • a throttle valve sensor 56 detecting a position of intake air throttle valve 21 , and the like are connected to the input port of electronic control unit 61 .
  • intake air throttle valve 21 , fuel injection valve 24 , fuel pump 27 , addition valve 41 , EGR valve 36 , and the like are connected to the output port of electronic control unit 61 .
  • Electronic control unit 61 controls these components connected to the output port based on the result of detection of each sensor, so as to control the operation of engine 11 , exhaust gas purification, and the like.
  • Electronic control unit 61 controls fuel injection, which represents one type of control involved with the operation of engine 11 .
  • fuel injection control a basic injection amount optimal for an operation state of engine 11 is calculated based on an accelerator pressing-down degree detected by accelerator sensor 54 and engine speed NE detected by NE sensor 39 .
  • a maximum injection amount is determined by correcting, based on signals from various sensors, the basic maximum injection amount determined by engine speed NE (the theoretically possible injection amount). Comparing the basic injection amount and the maximum injection amount with each other, the smaller amount is set as a target injection amount.
  • basic target injection timing is calculated based on the accelerator pressing-down degree and engine speed NE, that are corrected based on a signal from various sensors, and target injection timing optimal for the operation state of engine 11 at that time is calculated. Then, current supply to fuel injection valve 24 is controlled based on the target injection amount and the target injection timing, so as to open/close fuel injection valve 24 .
  • electronic control unit 61 controls the exhaust gas purifying catalyst, which represents one type of control involved with purification of the exhaust gas.
  • the exhaust gas purifying catalyst In order to control the exhaust gas purifying catalyst, four catalyst control modes, i.e., a catalyst regeneration control mode, a sulfur poisoning recovery control mode, an NOx reduction control mode, and a normal control mode, are set, and electronic control unit 61 selects the catalyst control mode in accordance with a state of catalytic converters 42 to 44 and executes that mode.
  • the catalyst regeneration control mode refers to a mode of control such that particulate matter PM deposited particularly in second catalytic converter 43 is burnt and exhausted as carbon dioxide CO 2 and water H 2 O.
  • the sulfur poisoning recovery control mode refers to a mode of control such that, when the NOx catalyst in first catalytic converter 42 and second catalytic converter 43 is poisoned with sulfur oxide SOx and storage capability of nitrogen oxide NOx is lowered, sulfur oxide SOx is released.
  • the NOx reduction control mode refers to such a mode that nitrogen oxide NOx absorbed in the NOx catalyst is released and reduced and purified so as to recover the NOx absorption capability of the NOx absorbent, by adding and supplying the reducing agent to upstream of first catalytic converter 42 in exhaust pipe 15 by means of addition valve 41 before the NOx absorption amount of the NOx absorbent in the NOx catalyst reaches the limit.
  • an open/close cycle consisting of valve-opening and valve-closing of addition valve 41 is repeated.
  • the reducing agent is supplied from addition valve 41 as a result of valve-opening, while supply is stopped as a result of valve-closing.
  • addition period a period during which addition valve 41 is open
  • additional interval a time period from the start of valve-opening until the start of next valve-opening
  • the state other than described above corresponds to the normal control mode, in which the reducing agent is not added from addition valve 41 .
  • addition valve 41 As injection hole 41 A of addition valve 41 is exposed in exhaust port 29 , the tip end portion of addition valve 41 including the portion around injection hole 41 A tends to be exposed to the exhaust gas and the temperature thereof tends to be high.
  • the temperature of the engine coolant engine coolant temperature THW
  • efficiency in cooling addition valve 41 by the engine coolant is lowered and the temperature of addition valve 41 tends to be high.
  • the volatile component contained in the reducing agent evaporates, and the remaining deposit component is adhered and deposited in injection hole 41 A of addition valve 41 and its surroundings.
  • the reducing agent may not appropriately be injected through injection hole 41 A and a spray state may be poorer. In order to overcome such defects, it is effective to moderately cool the tip end portion of addition valve 41 , particularly the portion around injection hole 41 A.
  • FIG. 4A is a flowchart showing a specific procedure for clogging suppression processing.
  • Electronic control unit 61 executes a series of processing shown in the flowchart as processing to be performed every prescribed time.
  • step 110 electronic control unit 61 calculates a target period of addition of the reducing agent, that is, a target valve-opening period of addition valve 41 , based on engine speed NE.
  • step 120 a target interval of addition of the reducing agent is calculated.
  • a map defining in advance relation, for example, of engine speed NE and the target injection amount with the target addition interval is referred to. In the map, it is defined such that the addition interval is shorter as engine speed NE is higher or as the target injection amount is greater. Then, the target addition interval corresponding to engine speed NE and the target injection amount at that time is found based on the map.
  • the target injection amount the injection amount separately calculated in fuel injection control described above is used.
  • step 130 the target addition interval calculated in step 120 above is corrected, using the temperature of addition valve 41 or a value corresponding thereto.
  • engine coolant temperature THW detected by coolant temperature sensor 47 is employed as the value corresponding to the temperature of addition valve 41 .
  • addition valve 41 is arranged in the vicinity of water jacket 45 provided in cylinder head 23 as described above, and the temperature of addition valve 41 tends to be affected by the heat of the engine coolant that flows through water jacket 45 .
  • the target addition interval in step 120 is corrected such that, when engine coolant temperature THW is high, the target addition interval is made shorter than when engine coolant temperature THW is low, that is, such that the number of times of addition per unit time is greater and the addition amount is increased.
  • step 140 current supply to addition valve 41 is controlled based on the target addition period in step 110 and the target addition interval corrected in step 130 .
  • addition valve 41 is opened/closed, and the reducing agent is injected through injection hole 41 A into exhaust port 29 .
  • addition valve 41 engine coolant temperature THW
  • degree of increase in the addition amount is great, and the amount of heat removed from addition valve 41 by the increased reducing agent is greater. Accordingly, such a phenomenon that increase in the addition amount is insufficient and addition valve 41 is not sufficiently cooled is less likely.
  • heat generated as a result of combustion of the reducing agent increased in the above-described manner causes increase in the temperature of the NOx catalyst (catalyst bed temperature) in first and second catalytic converters 42 , 43 . If the NOx catalyst is excessively heated, the upper limit of a temperature range (allowable range) where the NOx catalyst appropriately functions may be exceeded.
  • FIG. 4B is a flowchart showing a specific procedure for injection amount restriction processing.
  • Electronic control unit 61 executes a series of processing shown in the flowchart as processing to be performed every prescribed time.
  • step 210 electronic control unit 61 reads engine coolant temperature THW detected by coolant temperature sensor 47 at that time. Then, in step 220 , electronic control unit 61 determines whether engine coolant temperature THW in step 210 is higher than a threshold value a that has been set in advance. Threshold value ax represents an upper limit, or a value close thereto, of a range of temperature that engine coolant temperature THW may take on the condition that the catalyst bed temperature does not exceed the upper limit of the allowable range even if the reducing agent in an amount increased in accordance with the increase in engine coolant temperature THW is added.
  • Threshold value ax represents an upper limit, or a value close thereto, of a range of temperature that engine coolant temperature THW may take on the condition that the catalyst bed temperature does not exceed the upper limit of the allowable range even if the reducing agent in an amount increased in accordance with the increase in engine coolant temperature THW is added.
  • step 220 a determination condition in step 220 is satisfied (THW> ⁇ ). Then, if the fuel is injected in accordance with the target injection amount, the catalyst bed temperature may exceed the upper limit of the allowable range due to the heat of the exhaust gas, the heat generated during combustion of the reducing agent, and the like. Accordingly, in order to lower the temperature of the exhaust gas such that the catalyst bed temperature does not exceed the upper limit, in step 230 , the injection amount upper limit in accordance with engine coolant temperature THW in step 210 is set. When engine coolant temperature THW is high, the injection amount upper limit is set to a value lower than when engine coolant temperature THW is low. That is, when deviation from threshold value ⁇ of engine coolant temperature THW is great, the injection amount upper limit is set to a value lower than when deviation is small.
  • step 240 whether the target injection amount calculated separately in fuel injection control described above is greater than the injection amount upper limit in step 230 is determined. If this determination condition is satisfied (target injection amount>injection amount upper limit), the injection amount upper limit is set in step 250 as the final target injection amount to be instructed to addition valve 41 . That is, the target injection amount is restricted by the injection amount upper limit. After the processing in step 250 , a series of injection amount restriction processing ends.
  • the determination condition in step 220 above is not satisfied (THW ⁇ ) and if the determination condition in step 240 is not satisfied (target injection amount ⁇ injection amount upper limit), in both cases, it is considered that there is no possibility that the catalyst bed temperature exceeds the upper limit of the allowable range. Therefore, a series of injection amount restriction processing ends without performing the processing in steps 230 to 250 in the former case, or without performing the processing in step 250 in the latter case. In these cases, the target injection amount is not restricted but used as it is as the final target injection amount.
  • the amount of addition of the reducing agent from addition valve 41 is increased in order to suppress clogging of injection hole 41 A, and in addition, when engine coolant temperature THW is high, the degree of increase is made larger than when engine coolant temperature THW is low, whereby the catalyst bed temperature is raised.
  • the injection amount upper limit is set based on engine coolant temperature THW. The target injection amount is restricted so as not to exceed the injection amount upper limit.
  • the target injection amount exceeds the injection amount upper limit, the target injection amount is substantially decreased.
  • the target injection amount is made smaller than when it is not restricted, and the fuel in an amount in accordance with that target injection amount is injected and burnt, whereby the temperature of the exhaust gas is lowered.
  • the catalyst bed temperature is less likely to exceed the upper limit of the allowable range.
  • the injection amount upper limit is set to a value lower than when engine coolant temperature THW is low, and the target injection amount is restricted to a larger extent.
  • the degree of restriction of the target injection amount is varied in accordance with engine coolant temperature THW used for correcting the target addition interval (increase in the addition amount). Therefore, when engine coolant temperature THW is relatively low, that is, when the degree of increase in the addition amount is relatively small and when the increase in the catalyst bed temperature due to the increase in the addition amount is small, the degree of restriction of the target injection amount is small. Accordingly, such a phenomenon that the target injection amount is excessively restricted and output of engine 11 is unduly lowered is less likely.
  • FIG. 5 shows relation of engine coolant temperature THW, the catalyst temperature, the amount of addition of the reducing agent, and the injection amount upper limit.
  • restriction of the target injection amount by the injection amount upper limit is not carried out.
  • the amount of addition of the reducing agent is made larger than when engine coolant temperature THW is low.
  • the injection amount upper limit in accordance with engine coolant temperature THW is set.
  • the injection amount upper limit is set as the target injection amount, so that the target injection amount is made smaller, the temperature of the exhaust gas is lowered, and the catalyst bed temperature is accordingly lowered.
  • the catalyst bed temperature is suppressed.
  • deviation from the upper limit of the allowable range of the catalyst bed temperature is greater, further increase in the addition amount is permitted.
  • the addition amount is increased after engine coolant temperature THW attains to a prescribed value ⁇ (> ⁇ ), clogging of injection hole 41 A is suppressed.
  • the catalyst bed temperature is raised with the increase in the addition amount and approaches the upper limit of the allowable range.
  • the injection amount upper limit is set to a lower value with the increase in engine coolant temperature THW. As a result of restriction based on the injection amount upper limit, the target injection amount is made smaller, and the temperature of the exhaust gas and the catalyst bed temperature are lowered.
  • Engine coolant temperature THW is employed as the value corresponding to the temperature of addition valve 41 .
  • engine coolant temperature THW is high, the degree of increase in the addition amount is made larger than when engine coolant temperature THW is low.
  • the degree of increase in the addition amount is made larger than when engine coolant temperature THW is low.
  • the injection amount upper limit in accordance with engine coolant temperature THW is set.
  • the injection amount upper limit is set as the final target injection amount.
  • the target injection amount is made smaller than when no restriction is imposed, and the temperature of the exhaust gas is lowered. Accordingly, the catalyst bed temperature is lowered and less likely to exceed the upper limit of the allowable range. Therefore, the effect described in (1) above is reliably attained.
  • the target injection amount can be decreased only when the catalyst bed temperature is likely to exceed the upper limit of the allowable range, that is, only when necessary. Therefore, unnecessary decrease in the target injection amount can be suppressed, as compared with a case where the target injection amount is decreased without exception when engine coolant temperature THW exceeds threshold value ⁇ .
  • the injection amount upper limit is set to a value lower than when engine coolant temperature THW is low, whereby the target injection amount is restricted to a larger extent.
  • the temperature of addition valve 41 is affected not only by engine coolant temperature THW but also by the heat of the exhaust gas.
  • the temperature of the exhaust gas tends to vary in accordance with the fuel injection amount and tends to lower as the fuel injection amount is smaller.
  • the target injection amount is restricted and decreased. Therefore, not only by increasing the addition amount but also by decreasing the target injection amount, the temperature of addition valve 41 is lowered and the clogging phenomenon of injection hole 41 A can further effectively be suppressed.
  • a second embodiment implementing the present invention will now be described with reference to FIGS. 6 to 8 .
  • the second embodiment is different from the first embodiment in that the target injection amount is decreased, instead of restricting the same, for control such that the catalyst bed temperature does not exceed the upper limit of the allowable range with the increase in the addition amount of the reducing agent.
  • the configuration of engine 11 and exhaust gas purifying apparatus 12 is the same as in the first embodiment, description thereof will not be repeated.
  • FIG. 6 is a flowchart showing a specific procedure for injection amount decrease processing.
  • Electronic control unit 61 executes a series of processing shown in the flowchart as processing to be performed every prescribed time.
  • step 310 electronic control unit 61 reads engine coolant temperature THW detected by coolant temperature sensor 47 at that time. Then, in step 320 , electronic control unit 61 determines whether engine coolant temperature THW in step 310 is higher than threshold value ⁇ . Threshold value ⁇ is the same as described in the first embodiment.
  • step 320 a determination condition in step 320 above is satisfied (THW> ⁇ ). Then, if the fuel is injected in accordance with the target injection amount as it is, the catalyst bed temperature may exceed the upper limit of the allowable range due to the heat of the exhaust gas, the heat generated during combustion of the reducing agent, and the like. Accordingly, the processing for lowering the temperature of the exhaust gas such that the catalyst bed temperature does not exceed the upper limit is performed. Specifically, in step 330 , a correction amount (>0) for decreasing the target injection amount is calculated based on engine coolant temperature THW in step 310 . For example, as shown in FIG.
  • the correction amount can be set such that the correction amount is smaller when engine coolant temperature THW is low, while the correction amount is greater as engine coolant temperature THW is higher, that is, as deviation from threshold value ⁇ of engine coolant temperature THW is greater.
  • step 340 in controlling fuel injection described above, the correction amount in step 330 is subtracted from the target injection amount calculated in a different routine, and the subtraction result is set as the final target injection amount to be instructed to fuel injection valve 24 .
  • a series of injection amount decrease processing ends.
  • step 320 above determines whether the catalyst bed temperature exceeds the upper limit of the allowable range even though the addition amount is increased with the increase in engine coolant temperature THW. Therefore, in this case, a series of injection amount decrease processing ends without performing the processing in steps 330 and 340 .
  • the target injection amount is not corrected but used as it is as the final target injection amount.
  • the amount of addition of the reducing agent from addition valve 41 is increased in order to suppress clogging of injection hole 41 A, and in addition, when engine coolant temperature THW is high, the degree of increase is made larger than when engine coolant temperature THW is low, whereby the catalyst bed temperature becomes higher.
  • the correction amount is calculated based on engine coolant temperature THW. As a result of correction using the correction amount, the target injection amount is decreased. As the fuel in the decreased target injection amount is injected and burnt, the temperature of the exhaust gas is lowered. As the increase in the catalyst bed temperature due to the exhaust gas is made smaller, it is less likely that the catalyst bed temperature exceeds the upper limit of the allowable range.
  • the correction amount is set to a value greater than when engine coolant temperature THW is low, and the target injection amount is corrected to a lower value.
  • the degree of decrease in the target injection amount is varied in accordance with engine coolant temperature THW used for correcting the target addition interval (correction for increase in the addition amount). Therefore, when engine coolant temperature THW is relatively low, that is, when the degree of increase in the addition amount is relatively small and when the increase in the catalyst bed temperature due to the increase in the addition amount is small, the degree of decrease in the target injection amount is small. Accordingly, such a phenomenon that the target injection amount is excessively decreased and the output of engine 11 is unduly lowered is less likely.
  • FIG. 8 shows relation of engine coolant temperature THW, the catalyst bed temperature, the amount of addition of the reducing agent, and the correction amount for the target injection amount.
  • the target injection amount is not decreased.
  • the degree of increase is made larger than when engine coolant temperature THW is low, so that the amount of addition of the reducing agent becomes greater.
  • the catalyst bed temperature is also raised and approaches to the upper limit of the allowable range.
  • the correction amount in accordance with engine coolant temperature THW is set, so that the target injection amount is decreased using that correction amount.
  • the temperature of the exhaust gas is lowered. Therefore, such a situation that the catalyst bed temperature exceeds the upper limit of the allowable range can reliably be suppressed by lowering the catalyst bed temperature.
  • the present invention can be implemented in another embodiment shown below.

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  • Combustion & Propulsion (AREA)
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  • Mechanical Engineering (AREA)
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  • Exhaust Gas After Treatment (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Electrical Control Of Air Or Fuel Supplied To Internal-Combustion Engine (AREA)
  • Combined Controls Of Internal Combustion Engines (AREA)
US11/816,280 2005-04-08 2006-04-06 Exhaust Purifier for Internal Combustion Engine Abandoned US20090007545A1 (en)

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JP2005112847A JP4485400B2 (ja) 2005-04-08 2005-04-08 内燃機関の排気浄化装置
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8156734B2 (en) 2006-11-14 2012-04-17 Robert Bosch Gmbh Method for operating a reagent metering valve and apparatus for carrying out the method
US20140251286A1 (en) * 2013-03-08 2014-09-11 GM Global Technology Operations LLC Emission system and method of selectively directing exhaust gas and air within an internal combustion engine
US9567889B2 (en) 2013-04-19 2017-02-14 Toyota Jidosha Kabushiki Kaisha Exhaust purification system for internal combustion engine
CN108457728A (zh) * 2017-02-21 2018-08-28 丰田自动车株式会社 燃料添加装置

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* Cited by examiner, † Cited by third party
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JP4798019B2 (ja) * 2007-02-23 2011-10-19 トヨタ自動車株式会社 ディーゼルエンジン制御装置
JP4349423B2 (ja) 2007-03-01 2009-10-21 トヨタ自動車株式会社 内燃機関の排気浄化システム
JP4888380B2 (ja) * 2007-12-26 2012-02-29 トヨタ自動車株式会社 内燃機関の排気浄化装置
WO2009082035A1 (ja) * 2007-12-26 2009-07-02 Toyota Jidosha Kabushiki Kaisha 内燃機関の排気浄化装置
JP5142048B2 (ja) * 2008-04-08 2013-02-13 株式会社デンソー 内燃機関の排気浄化装置
JP5310166B2 (ja) * 2009-03-23 2013-10-09 マツダ株式会社 エンジンの排気浄化装置
SE535931C2 (sv) * 2010-06-21 2013-02-26 Scania Cv Ab Förfarande och anordning för undvikande av överhettning hos en doseringsenhet vid ett HC-doseringssystem
JP5150702B2 (ja) * 2010-10-15 2013-02-27 株式会社豊田自動織機 内燃機関の排気浄化装置
JP2013007305A (ja) * 2011-06-23 2013-01-10 Toyota Motor Corp 内燃機関
WO2014038067A1 (ja) * 2012-09-07 2014-03-13 トヨタ自動車 株式会社 内燃機関の添加剤供給装置
JP5880514B2 (ja) * 2013-10-02 2016-03-09 株式会社デンソー エンジンの排気浄化システム

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5894728A (en) * 1995-06-27 1999-04-20 Komatsu Ltd. Exhaust emission control device for diesel engines
US6192677B1 (en) * 1998-12-07 2001-02-27 Siemens Aktiengesellschaft Apparatus and method for the after-treatment of exhaust gases from an internal combustion engine operating with excess air
US7500355B2 (en) * 2003-09-30 2009-03-10 Nissan Diesel Motor Co., Ltd. Exhaust emission purifying apparatus for engine
US7607292B2 (en) * 2005-09-09 2009-10-27 Toyota Jidosha Kabushiki Kaisha Fuel addition apparatus
US7614213B2 (en) * 2003-09-19 2009-11-10 Nissan Diesel Motor Co., Ltd. Engine exhaust emission purification apparatus

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3557815B2 (ja) * 1996-11-01 2004-08-25 トヨタ自動車株式会社 内燃機関の排気浄化装置
JP3855444B2 (ja) * 1998-03-24 2006-12-13 トヨタ自動車株式会社 内燃機関の還元剤供給装置
JP3642273B2 (ja) * 1999-10-21 2005-04-27 日産自動車株式会社 排気ガス浄化システム
JP3984834B2 (ja) * 2001-12-28 2007-10-03 株式会社日本自動車部品総合研究所 排気用触媒の燃料供給装置
JP4218251B2 (ja) * 2002-03-20 2009-02-04 株式会社デンソー 還元剤供給装置
JP3861746B2 (ja) * 2002-05-17 2006-12-20 トヨタ自動車株式会社 内燃機関の排気浄化装置
JP4075746B2 (ja) * 2003-09-04 2008-04-16 トヨタ自動車株式会社 内燃機関の排気浄化装置
JP2005106047A (ja) * 2003-09-08 2005-04-21 Toyota Motor Corp 排気浄化装置
JP4452525B2 (ja) * 2004-03-02 2010-04-21 株式会社日本自動車部品総合研究所 内燃機関の排気浄化装置
JP2005344682A (ja) * 2004-06-07 2005-12-15 Toyota Motor Corp 排気浄化装置

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5894728A (en) * 1995-06-27 1999-04-20 Komatsu Ltd. Exhaust emission control device for diesel engines
US6192677B1 (en) * 1998-12-07 2001-02-27 Siemens Aktiengesellschaft Apparatus and method for the after-treatment of exhaust gases from an internal combustion engine operating with excess air
US7614213B2 (en) * 2003-09-19 2009-11-10 Nissan Diesel Motor Co., Ltd. Engine exhaust emission purification apparatus
US7500355B2 (en) * 2003-09-30 2009-03-10 Nissan Diesel Motor Co., Ltd. Exhaust emission purifying apparatus for engine
US7607292B2 (en) * 2005-09-09 2009-10-27 Toyota Jidosha Kabushiki Kaisha Fuel addition apparatus

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8156734B2 (en) 2006-11-14 2012-04-17 Robert Bosch Gmbh Method for operating a reagent metering valve and apparatus for carrying out the method
US20140251286A1 (en) * 2013-03-08 2014-09-11 GM Global Technology Operations LLC Emission system and method of selectively directing exhaust gas and air within an internal combustion engine
US9255550B2 (en) * 2013-03-08 2016-02-09 GM Global Technology Operations LLC Emission system and method of selectively directing exhaust gas and air within an internal combustion engine
US9567889B2 (en) 2013-04-19 2017-02-14 Toyota Jidosha Kabushiki Kaisha Exhaust purification system for internal combustion engine
CN108457728A (zh) * 2017-02-21 2018-08-28 丰田自动车株式会社 燃料添加装置
US10443468B2 (en) * 2017-02-21 2019-10-15 Soken, Inc. Fuel addition system

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DE602006014115D1 (de) 2010-06-17
JP2006291821A (ja) 2006-10-26
JP4485400B2 (ja) 2010-06-23
EP1867854B1 (de) 2010-05-05
EP1867854A4 (de) 2009-04-15
WO2006109850A1 (ja) 2006-10-19

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