US20070051668A1 - Apatite and method for producing the same, and apatite base material - Google Patents
Apatite and method for producing the same, and apatite base material Download PDFInfo
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- US20070051668A1 US20070051668A1 US11/594,829 US59482906A US2007051668A1 US 20070051668 A1 US20070051668 A1 US 20070051668A1 US 59482906 A US59482906 A US 59482906A US 2007051668 A1 US2007051668 A1 US 2007051668A1
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- apatite
- metal atoms
- atoms
- metal
- visible light
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Links
- 229910052586 apatite Inorganic materials 0.000 title claims abstract description 129
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 title claims abstract description 129
- 239000000463 material Substances 0.000 title claims abstract description 44
- 238000004519 manufacturing process Methods 0.000 title claims description 19
- 229910052751 metal Inorganic materials 0.000 claims abstract description 140
- 239000002184 metal Substances 0.000 claims abstract description 140
- 230000001699 photocatalysis Effects 0.000 claims abstract description 39
- 238000000034 method Methods 0.000 claims description 20
- 229910052804 chromium Inorganic materials 0.000 claims description 18
- 229910052719 titanium Inorganic materials 0.000 claims description 14
- 229910052791 calcium Inorganic materials 0.000 claims description 11
- 238000010304 firing Methods 0.000 claims description 11
- 229910052693 Europium Inorganic materials 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- 229910052788 barium Inorganic materials 0.000 claims description 10
- 229910052793 cadmium Inorganic materials 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 229910052742 iron Inorganic materials 0.000 claims description 10
- 229910052746 lanthanum Inorganic materials 0.000 claims description 10
- 229910052745 lead Inorganic materials 0.000 claims description 10
- 229910052749 magnesium Inorganic materials 0.000 claims description 10
- 229910052759 nickel Inorganic materials 0.000 claims description 10
- 229910052700 potassium Inorganic materials 0.000 claims description 10
- 229910052712 strontium Inorganic materials 0.000 claims description 10
- 238000007598 dipping method Methods 0.000 claims description 9
- 229910052727 yttrium Inorganic materials 0.000 claims description 9
- 229910052721 tungsten Inorganic materials 0.000 claims description 8
- 229910052726 zirconium Inorganic materials 0.000 claims description 8
- -1 lumber Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 2
- 239000010985 leather Substances 0.000 claims description 2
- 239000004745 nonwoven fabric Substances 0.000 claims description 2
- 239000000123 paper Substances 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 239000002759 woven fabric Substances 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 description 85
- 239000000243 solution Substances 0.000 description 25
- 239000011651 chromium Substances 0.000 description 24
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 23
- 239000011575 calcium Substances 0.000 description 22
- 239000007789 gas Substances 0.000 description 22
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 21
- 239000010936 titanium Substances 0.000 description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 11
- 229910002092 carbon dioxide Inorganic materials 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 11
- 239000001569 carbon dioxide Substances 0.000 description 10
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 10
- 239000000843 powder Substances 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 8
- PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical compound [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 description 8
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 238000000975 co-precipitation Methods 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- 239000004065 semiconductor Substances 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- JTCFNJXQEFODHE-UHFFFAOYSA-N [Ca].[Ti] Chemical compound [Ca].[Ti] JTCFNJXQEFODHE-UHFFFAOYSA-N 0.000 description 3
- 239000001506 calcium phosphate Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000005457 optimization Methods 0.000 description 3
- 239000011941 photocatalyst Substances 0.000 description 3
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 3
- 229910014497 Ca10(PO4)6(OH)2 Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- FRLUTTWFYRZGEN-UHFFFAOYSA-N [Ca][Cr][Ti] Chemical group [Ca][Cr][Ti] FRLUTTWFYRZGEN-UHFFFAOYSA-N 0.000 description 2
- 210000000988 bone and bone Anatomy 0.000 description 2
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 235000019700 dicalcium phosphate Nutrition 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229910052587 fluorapatite Inorganic materials 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910000348 titanium sulfate Inorganic materials 0.000 description 2
- 235000019731 tricalcium phosphate Nutrition 0.000 description 2
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 2
- 229940078499 tricalcium phosphate Drugs 0.000 description 2
- HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 1
- SXAMGRAIZSSWIH-UHFFFAOYSA-N 2-[3-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,2,4-oxadiazol-5-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NOC(=N1)CC(=O)N1CC2=C(CC1)NN=N2 SXAMGRAIZSSWIH-UHFFFAOYSA-N 0.000 description 1
- JQMFQLVAJGZSQS-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-N-(2-oxo-3H-1,3-benzoxazol-6-yl)acetamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC(=O)NC1=CC2=C(NC(O2)=O)C=C1 JQMFQLVAJGZSQS-UHFFFAOYSA-N 0.000 description 1
- YJLUBHOZZTYQIP-UHFFFAOYSA-N 2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)N1CC2=C(CC1)NN=N2 YJLUBHOZZTYQIP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 241000699670 Mus sp. Species 0.000 description 1
- 230000032912 absorption of UV light Effects 0.000 description 1
- 230000032900 absorption of visible light Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012567 medical material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 210000004746 tooth root Anatomy 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/32—Phosphates of magnesium, calcium, strontium, or barium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
Definitions
- the present invention relates to apatite and a method for producing the same, and an apatite base material.
- a semiconductor material such as titanium oxide has a photocatalytic function. Namely, when a semiconductor material such as titanium oxide absorbs light energy of a wavelength corresponding to a bandgap between a valence band and a conduction band, electrons in the valence band move to the conduction band by excitation, and positive electric charge (positive hole) is generated in the valence band. In a case where a foreign substance (such as organics) is adsorbed on the surface of the semiconductor material, electrons moving to the conduction band move to the organics on the surface of the semiconductor material and reduce the organics. In the valence band, the positive hole generated there seizes the electrons and oxidizes the organics.
- the positive hole in the titanium oxide has an extremely strong oxidizing power, it will decompose the organics into water and carbon dioxide ultimately.
- the photocatalytic function (oxidation-decomposition function) of the titanium oxide has been used. Specifically, titanium oxide has been used for an antibacterial agent, a disinfectant, a deodorant, an environmental clean-up antipollution agent, and the like. However, since the titanium oxide itself has no capability of adsorbing organics onto the surface, available oxidation-decomposition function is limited.
- Calcium hydroxyapatite Ca 10 (PO 4 ) 6 (OH) 2 as a main component of biological hard tissues such as teeth and bones will exchange ions easily with various cations and anions, and thus it has high bio-compatibility and adsorptivity. Therefore, applications of the apatite to medical materials such as artificial bones and artificial dental roots, and to various fields such as chromatography adsorbents, chemical sensors, ion exchangers and catalysts, have been studied keenly.
- the apatite has a particularly remarkable capability in adsorbing organics such as protein.
- light energy required for exciting the photocatalyst having a strong oxidizing power is 3.2 eV, which corresponds to a light wavelength of about 380 nm. Therefore, titanium oxide can be excited with near-ultraviolet light but cannot be excited with visible light. Since the content of the UV light in sunlight is 4-5%, the photocatalytic function of the titanium oxide cannot be sufficient. In particular, the photocatalytic function cannot be exhibited indoors under fluorescent light including substantially no UV light.
- the present invention relates to apatite containing metal atoms having a photocatalytic function and other metal atoms.
- the apatite is characterized in that the metal atoms having a photocatalytic function comprise metal atoms that absorb light energy of visible light.
- the present invention relates to also a method for producing apatite, and the method includes a step of preparing a solution containing metal atoms that absorb visible light at a concentration of not less than 1 ⁇ 10 ⁇ 6 mol/dm 3 and not more than 1 ⁇ 10 ⁇ 2 mol/dm 3 , and a step of dipping apatite in the solution.
- the present invention relates to also a method for producing apatite, and the method includes a step of preparing an apatite material solution containing metal atoms that absorb visible light and other metal atoms, where the content of the metal atoms that absorb visible light is not less than 0.5 mol % and not more than 3 mol % with respect to the whole metal atoms contained in the solution, and a step of coprecipitating components contained in the apatite material solution so as to deposit apatite.
- the present invention relates to also an apatite base material comprising apatite containing metal atoms that absorb visible light and other metal atoms.
- the apatite base material is characterized in that the metal atoms that absorb visible light are atoms of at least one kind of metal selected from the group consisting of Cr, Co, Cu, Fe and Ni, and the other metal atoms are atoms of at least one kind of metal selected from the group consisting of Ca, Al, La, Mg, Sr, Ba, Pb, Cd, Eu, Y, Ce, Na and K.
- FIG. 1 is a graph showing UV-visible reflection spectra for Example 1 and Comparative Example.
- FIG. 2 is a graph showing UV-visible reflection spectra for Example 8, Example 9 and Comparative Example.
- FIG. 3 is a graph showing changes in carbon dioxide gas concentrations and acetaldehyde gas concentrations for Example 1 and Comparative Example.
- FIG. 4 is a graph showing changes in carbon dioxide gas concentrations and acetaldehyde gas concentrations for Example 8 and Example 9.
- FIG. 5 is a graph showing relationships between chromium concentrations in aqueous solutions of chromium nitrate and decreases of acetaldehyde gases.
- FIG. 6 is a graph showing a relationship between a firing temperature and a carbon dioxide gas concentration.
- FIG. 7 is a graph showing a change in a carbon dioxide gas concentration and an acetaldehyde gas concentration for Example 14.
- An example of apatite of the present invention contains metal atoms A, metal atoms B and metal atoms C.
- the metal atoms A denote metal atoms contained in a normal apatite
- the metal atoms B denote metal atoms that absorb UV light
- the metal atoms C denote metal atoms that absorb visible light.
- apatite that can exhibit a photocatalytic function under not only UV light but also visible light, by adding to the apatite not only metal atoms that absorb UV light but metal atoms that absorb visible light.
- the apatite in this embodiment can be expressed generally with a Formula (1) below.
- the metal atoms A are atoms of at least one kind of metal selected from the group consisting of Ca, Al, La, Mg, Sr, Ba, Pb, Cd, Eu, Y, Ce, Na and K, and it is a main component contained in apatite.
- metals Ca is used most generally.
- the metal atoms B that absorb UV light are atoms of at least one kind of metal selected from the group consisting of Ti, Zr and W. Among them, Ti is most preferred. It is preferable that the content of the metal atoms B with respect to the whole metal atoms contained in the apatite is not less than 3 mol % and not more than 11 mol %, and more preferably, not less than 8 mol % and not more than 10 mol %.
- the metal atoms C that absorb visible light are atoms of at least one kind of metal selected from the group consisting of Cr, Co, Cu, Fe and Ni. Among them, Cr is most preferred. It is preferable that the content of the metal atoms C with respect to the whole metal atoms contained in the apatite is not less than 0.5 mol % and not more than 2 mol %, and more preferably, not less than 0.5 mol % and not more than 1.5 mol %.
- the metal atoms A form an apatite crystal structure, and the metal atoms A are substituted partially by the metal atoms B and the metal atoms C.
- D in the above formula denotes atoms such as P and S, and “O” denotes an oxygen atom.
- E denotes a hydroxyl group (—OH), a halogen atom (F, Cl, Br, I) or the like.
- Apatite expressed by the above formula is provided, for example, by substituting metal atoms contained in hydroxyapatite, fluoroapatite, chloroapatite, tricalcium phosphate, calcium hydrogenphosphate or the like with metal atoms that absorb UV light and metal atoms that absorb visible light.
- apatite used in this embodiment is calcium titanium chromium hydroxyapatite where the metal atom A denotes Ca, the metal atom.
- the metal atom C denotes Cr.
- D denotes P and E denotes a hydroxyl group.
- Apatite expressed by a Formula (2) below is preferred particularly. Ca 9 Ti 0.9 Cr 0.1 (PO 4 ) 6 (OH) 2 Formula (2)
- the apatite in this embodiment is fired at a temperature not lower than 500° C. and not higher than 700° C. Thereby, the crystallinity of the apatite can be improved and the photocatalytic effect under the visible light can be improved further.
- the apatite in this embodiment can be provided in various shapes and dimensions in accordance with the use, processing conditions or the like.
- Examples of the preferred shapes include a powder, a tablet, a rod, a plate, a block, a sheet, a film, and a membrane.
- apatite of the present invention contains metal atoms that absorb visible light and other metal atoms.
- the metal atoms that absorb visible light are atoms of at least one kind of metal selected from the group consisting of Cr, Co, Cu, Fe and Ni, and the other metal atoms are atoms of at least one kind of metal selected from the group consisting of Ca, Al, La, Mg, Sr, Ba, Pb, Cd, Eu, Y, Ce, Na and K.
- apatite exhibiting a visible photocatalytic function can be provided.
- This embodiment excludes metal atoms having a UV photocatalytic function.
- apatite in this embodiment is expressed by a Formula (3) below.
- the apatite in this embodiment is substantially same as the apatite expressed by the Formula (1).
- An example of a method for producing apatite of the present invention is a method including a step of preparing a solution that contains metal atoms that absorb visible light at a concentration of not less than 1 ⁇ 10 ⁇ 6 mol/dm 3 and not more than 1 ⁇ 10 ⁇ 2 mol/dm 3 , and a step of dipping apatite in the solution. Namely, it is a producing method based on a so-called dipping process. Thereby, apatite that can exhibit a photocatalytic function even under visible light can be produced easily.
- the metal atoms that absorb visible light are atoms of at least one kind of metal selected from the group consisting of Cr, Co, Cu, Fe and Ni.
- the concentration of the metal atoms that absorb visible light in the solution is not less than 1 ⁇ 10 ⁇ 5 mol/dm 3 and not more than 1 ⁇ 10 ⁇ 3 mol/dm 3 , and more preferably, not less than 4 ⁇ 10 ⁇ 5 mol/dm 3 and not more than 2 ⁇ 10 ⁇ 4 mol/dm 3 .
- the visible photocatalytic function can be improved further when the concentration is in the above-mentioned range.
- the producing method in this embodiment includes further steps of drying the apatite dipped in the solution and then firing at a temperature not lower than 500° C. and not higher than 700° C.
- a temperature not lower than 500° C. and not higher than 700° C. By firing the photoresponsive apatite at a temperature not lower than 500° C. and not higher than 700° C., the crystallinity of the apatite can be improved and the visible photocatalytic function can be improved further. It is more preferable that the firing temperature is not lower than 550° C. and not higher than 650° C.
- the apatite for the above-mentioned hydroxyapatite, fluoroapatite, chloroapatite, tricalcium phosphate, calcium hydrogenphosphate or the like can be used.
- the apatite contains metal atoms of at least one kind of metal selected from the group consisting of Ca, Al, La, Mg, Sr, Ba, Pb, Cd, Eu, Y. Ce, Na and K.
- calcium hydroxyapatite Ca 10 (PO 4 ) 6 (OH) 2 is preferred particularly.
- the apatite contains further metal atoms of at least one kind of metal selected from the group consisting of Ti, Zr and W as metal atoms that absorb UV light.
- metal atoms that can exhibit a photocatalytic function under not only visible light but UV light can be produced easily.
- apatite calcium titanium hydroxyapatite Ca 9 Ti(PO 4 ) 6 (OH) 2 is preferred particularly.
- Another example of a method for producing apatite of the present invention includes a step of preparing an apatite material solution containing metal atoms that absorb visible light and other metal atoms, where the content of the metal atoms that absorb visible light is not less than 0.5 mol % and not more than 3 mol % with respect to the whole metal atoms contained in the solution, and a step of coprecipitating components contained in the apatite material solution so as to deposit apatite.
- the method is based on a so-called coprecipitation process. Thereby, apatite that can exhibit a photocatalytic function even under visible light can be produced easily.
- the metal atoms that absorb visible light are of at least one kind of metal selected from the group consisting of Cr, Co, Cu, Fe and Ni.
- the content of the metal atoms that absorb visible light in the solution is not less than 0.5 mol % and not more than 2 mol % with respect to the whole metal atoms contained in the solution, and more preferably, not less than 0.5 mol % and not more than 1.5 mol %.
- concentration is in this range, the visible photocatalytic function can be improved further.
- the other metal atoms are atoms of at least one kind of metal selected from the group consisting of Ca, Al, La, Mg, Sr, Ba, Pb, Cd, Eu, Y, Ce, Na and K. Among them, Ca is preferred particularly.
- the apatite contains further metal atoms of at least one kind of metal selected from the group consisting of Ti, Zr and W as metal atoms that absorb UV light.
- metal atoms that can exhibit a photocatalytic function under not only visible light but UV light can be produced easily.
- Ti is preferred particularly.
- the content of the metal atoms that absorb UV light in the solution is preferably not less than 3 mol % and not more than 11 mol % with respect to the whole metal atoms contained in the solution, and more preferably, not less than 8 mol % and not more than 10 mol %.
- the producing method in this embodiment includes further steps of drying the apatite dipped in the solution and then firing at a temperature not lower than 500° C. and not higher than 700° C.
- a temperature not lower than 500° C. and not higher than 700° C. By firing the photoresponsive apatite at a temperature not lower than 500° C. and not higher than 700° C., the crystallinity of the apatite can be improved and the visible photocatalytic function can be improved further. It is more preferable that the firing temperature is not lower than 550° C. and not higher than 650° C.
- calcium titanium chromium hydroxyapatite Ca 9 Ti 0.9 Cr 0.1 (PO 4 ) 6 (OH) 2 is preferred.
- An example of an apatite base material according to the present invention is a base material of apatite containing metal atoms that absorb visible light and other metal atoms.
- the metal atoms that absorb UV light are atoms of at least one metal selected from the group consisting of Cr. Co, Cu, Fe and Ni, and the other metal atoms are atoms of at least one kind of metal selected from the group consisting of Ca, Al, La, Mg, Sr, Ba, Pb, Cd, Eu, Y, Ce, Na and K.
- the other metal atoms include at least one kind of metal selected from the group consisting of Ti, Zr and W
- the base material can be selected from the group consisting of paper, synthetic paper, woven fabric, nonwoven fabric, leather, lumber, glass, metal, ceramics, plastics, and printing ink.
- the shape of the base material can be a foil, a film, a sheet and a plate, for example.
- the apatite can be used in a state being applied/coated on at least one surface of the base material.
- the apatite can be contained in the base material.
- the apatite can be contained in the ink.
- the apatite can be used for a base material of various products to be arranged indoors, and thus the apatite can exhibit the photocatalytic function even indoors where substantially no UV light exists.
- the apatite base material in this embodiment when indoor wallpaper, clothes, and filters for air cleaners are produced by using the apatite base material in this embodiment, various bacteria, dust, bad smell, smoke of cigarettes indoors can be removed, and indoor environmental clean-up can be realized easily.
- peripheral equipment of computers, such as keyboards, mice, and cases with the apatite base material of this embodiment, adhesion of stains such as fingerprints can be prevented.
- the apatite base material in this embodiment can be used for sanitary goods such as masks, bandages, and antimicrobial gloves.
- any of the apatite mentioned in the embodiment can be used. It is preferable that the apatite is fired at a temperature not lower than 500° C. and not higher than 700° C.
- the present invention will be described below by referring to Examples.
- the description below for respective Examples refers to apatite generally containing the metal atoms A, B and C that are determined as Ca, Ti and Cr respectively in the Formula (1).
- similar effects can be obtained by using apatite containing a combination of any other metal atoms applicable in the present invention.
- Apatite was produced by a dipping process in the following manner.
- a commercially available calcium titanium hydroxyapatite Ca 9 Ti(PO 4 ) 6 (OH) 2 (trade name: “TiHAP0201” supplied by Taihei Chemical Industrial Co., Ltd.; hereinafter, referred to as TiHAP) of 1.5 g was added to 300 cm 3 of an aqueous solution of chromium nitrate of 1 ⁇ 10 ⁇ 4 mol/dm 3 , which was then stirred with a magnetic stirrer for 5 minutes. After stirring and filtering, the thus obtained product was washed in pure water of 4 dm 3 , dried in an oven at 100° C. so as to obtain a Cr-doped TiHAP powder. Subsequently, this TiHAP powder was heated to 650° C. in one hour to be fired, and thus a sample for Example 1 was obtained.
- Example 2 Samples for Examples 2-7 were produced in the same manner as in Example 1 except that aqueous solutions of chromium nitrate of concentrations as shown in Table 1 were used. TABLE 1 Concentration (mol/dm 3 ) Example 2 1 ⁇ 10 ⁇ 6 Example 3 1 ⁇ 10 ⁇ 5 Example 4 4 ⁇ 10 ⁇ 5 Example 5 2 ⁇ 10 ⁇ 4 Example 6 1 ⁇ 10 ⁇ 3 Example 7 1 ⁇ 10 ⁇ 2
- Apatite was produced by a coprecipitation process in the following manner. First, 21.25 g of calcium nitrate and 0.40 g of chromium nitrate were dissolved in decarbonated pure water. While stirring the solution with a magnetic stirrer, 5.55 cm 3 of 30% aqueous solution of titanium sulfate and 2.94 cm 3 of 95% aqueous solution of phosphoric acid were dripped. Finally, 10% aqueous ammonia was added quickly to adjust the pH to 9. Later, it was aged at 100° C. for 5 hours, filtered and washed in 4 dm 3 of pure water, dried in a 100° C. oven so as to obtain a Cr-doped TiHAP powder. This TiHAP powder was heated to 650° C. in one hour to be fired, and thus a sample for Example 8 was obtained.
- Example 10 A sample for Example 10 was produced in the same manner as in Example 8 except that the powder was heated to 300° C. in one hour to be fired.
- Example 11 A sample for Example 11 was produced in the same manner as in Example 8 except that the powder was heated to 550° C. in one hour to be fired.
- Example 12 A sample for Example 12 was produced in the same manner as in Example 8 except that the powder was heated to 600° C. in one hour to be fired.
- Example 13 A sample for Example 13 was produced in the same manner as in Example 8 except that the powder was heated to 800° C. in one hour to be fired.
- Example 14 A sample for Example 14 was produced in the same manner as in Example 8 except that an aqueous solution of titanium sulfate was not dripped.
- UV-visible (UV-Vis) Reflection Spectra Measurement of UV-visible (UV-Vis) Reflection Spectra
- UV-Vis reflection spectra of the respective samples in Examples 1, 8, 9 and Comparative Example were measured.
- a UV/VIS Spectrophotometer “JASCO V-560” supplied by JASCO Corporation was used for the instrument.
- the results are shown in FIGS. 1 and 2 .
- FIGS. 1 and 2 illustrate that reflectance was lowered due to optical absorption not only for UV light (light having a wavelength of less than 380 nm) but also for visible light (light having a wavelength of 380 to 780 nm) in Examples 1, 8 and 9.
- reflectance decrease caused by absorption of visible light did not occur, while the reflectance was decreased due to absorption of UV light alone.
- the specific surface areas of the samples were measured by a BET method, and the samples were weighed on the basis of the values of the specific surface areas so that the surface areas would be 85.5 m 2 .
- the samples were pressed to form tablet-shape test samples.
- Each of the test samples was introduced into a closed glass vessel of a capacity of 500 cm 3 substituted by standard air, and an acetaldehyde gas (CH 3 CHO) was introduced until the gas phase concentration became 7500 ppm.
- CH 3 CHO acetaldehyde gas
- the product was irradiated with visible light for 3 hours and then irradiated with UV light for 2 hours.
- the concentration of the acetaldehyde gas in the closed glass vessel and the concentration of carbon dioxide gas (CO 2 ) generated due to decomposition of the acetaldehyde gas were measured every hour.
- a gas chromatograph “GC-390B” supplied by GL Sciences was used for the instrument.
- Alight beam (39500 lx) used for irradiation of visible light was obtained by removing UV light through a combination of a xenon light source “LA-251Xe” supplied by Hayashi Watch-Works Co., Ltd. and an L-42 filter.
- a black light (1 mW/cm 2 ) was used for irradiation of UV light.
- FIGS. 3 and 4 The results are shown in FIGS. 3 and 4 .
- “In dark, 1h” indicates that the product was kept in dark for 1 hour.
- “Vis-1h” indicates that visible light was irradiated for 1 hour, and “UV-1h” indicates that UV light was irradiated for 1 hour. The same will be applied in the following figures.
- FIGS. 3 and 4 illustrate that the acetaldehyde gas concentrations were decreased and the carbon dioxide gas concentrations were raised due to irradiation of visible light in Examples 1, 8 and 9. This tendency was maintained also by irradiation of UV light. Thereby, it was confirmed that the samples in Examples 1, 8 and 9 have not only a UV photocatalytic function but visible photocatalytic function.
- Comparative Example there were neither decrease in the acetaldehyde gas concentration or increase in the carbon dioxide gas concentration substantially in a case of irradiation of visible light.
- Comparative Example similarly in Comparative Example, the acetaldehyde gas concentration was decreased and the carbon dioxide gas concentration was increased by irradiation of UV light.
- FIG. 4 indicates that the chromium content in the apatite material solution in a coprecipitation process is not less than 0.5 mol % and not more than 2 mol % preferably with respect to the total of the titanium and chromium, and more preferably, not less than 0.5 mol % and not more than 1.5 mol %.
- FIG. 5 shows a decrease in the acetaldehyde gas concentration every hour of irradiation of visible light plotted for every concentration of the aqueous solution of chromium sulfate.
- the concentration of the aqueous solution of chromium sulfate (dipping solution) is preferably not less than 1 ⁇ 10 ⁇ 5 mol/dm 3 and not more than 1 ⁇ 10 ⁇ 3 mol/dm 3 , and more preferably, not less than 4 ⁇ 10 ⁇ 5 mol/dm 3 and not more than 2 ⁇ 10 ⁇ 3 mol/dm 3 .
- FIG. 6 shows a carbon dioxide gas concentrations measured at every time during irradiation with visible light and UV light.
- the results in FIG. 6 and the result in the above Example 8 indicate that preferably the firing temperature is not lower than 500° C. and not higher than 700° C., and more preferably, not lower than 550° C. and not higher than 650° C.
- the photocatalytic function of the sample in Example 14 was measured in the same manner as mentioned above. The results are shown in FIG. 7 .
- visible light alone was irradiated for 5 hours.
- the sample in Example 14 does not contain titanium for absorbing UV light, it exhibited a visible photocatalytic function substantially same as that in Example 1, since the sample in Example 14 contains chromium that absorbs visible light. Thereby, it is shown that chromium substantially alone serves to exhibit a visible catalytic function.
- the present invention provides apatite having novel constitution and a method for producing the same, and an apatite base material.
- a photocatalytic function can be exhibited even indoors by using the apatite base material for various products to be arranged indoors.
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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US20060199729A1 (en) * | 2005-03-01 | 2006-09-07 | Fujitsu Limited | Broad band light absorbing photocatalyst, process for producing thereof, broad band light absorbing photocatalyst composition, and molded article |
US20070215006A1 (en) * | 2006-03-20 | 2007-09-20 | Fujitsu Limited | Photocatalyst, method for manufacturing the same, and molded articles |
US20070232487A1 (en) * | 2006-03-29 | 2007-10-04 | Fujitsu Limited | Photocatalytic apatite composition as well as production method and article thereof |
US20080050440A1 (en) * | 2006-07-27 | 2008-02-28 | Fujitsu Limited | Plant epidemic prevention agent, plant epidemic prevention method, plant epidemic prevention system, plant, and plant cultivation method |
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US20160074288A1 (en) * | 2013-05-28 | 2016-03-17 | Fujitsu Limited | Intraoral fixing composition |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5009898A (en) * | 1988-09-29 | 1991-04-23 | Kabushiki Kaisha Sangi | Antimicrobial hydroxyapatite powders and methods for preparing them |
US20030219624A1 (en) * | 2002-05-21 | 2003-11-27 | Fujitsu Limited | Method of forming antibacterial layer containing metal-modified apatite |
US20050064075A1 (en) * | 2002-03-27 | 2005-03-24 | Masato Wakamura | Method for preserving food using metal-modified apatite and food container used therein |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1260539A (en) * | 1969-05-05 | 1972-01-19 | British Petroleum Co | Improvements relating to catalysts, their preparation and their use |
JPH0390007A (ja) * | 1989-09-01 | 1991-04-16 | Nippon Chem Ind Co Ltd | 抗菌剤 |
JPH0413605A (ja) * | 1990-05-01 | 1992-01-17 | Sangi Co Ltd | 無機抗菌剤及びその製造法 |
JP3228955B2 (ja) * | 1991-04-11 | 2001-11-12 | 日本化学工業株式会社 | アパタイト粉末の製造方法 |
JPH061708A (ja) * | 1992-06-18 | 1994-01-11 | Sangi Co Ltd | 抗菌性リン酸カルシウム系セラミックス |
JP3177039B2 (ja) | 1992-12-03 | 2001-06-18 | 日本化学工業株式会社 | リン酸塩系抗菌剤およびその製造法 |
JPH08245208A (ja) | 1995-03-07 | 1996-09-24 | Fujitsu Ltd | アパタイト構造金属化合物およびその合成方法 |
JPH10273322A (ja) * | 1997-01-30 | 1998-10-13 | Kubota Corp | 抗菌性複合チタン酸化合物およびその製造方法 |
JP3678606B2 (ja) * | 1999-05-21 | 2005-08-03 | 富士通株式会社 | 金属修飾アパタイト及びその製造方法 |
JP3697608B2 (ja) | 2001-03-30 | 2005-09-21 | 富士通株式会社 | 金属修飾アパタイト材料及びその製造方法 |
WO2003007719A1 (en) | 2001-07-18 | 2003-01-30 | National Institute Of Advanced Industrial Science And Technology | Cleansers, cleansing system, bleaching agents and compositions for enviromental conservation |
JP4157943B2 (ja) | 2001-09-07 | 2008-10-01 | 独立行政法人産業技術総合研究所 | 光活性を有する化合物及びその用途 |
KR100425024B1 (ko) * | 2001-11-01 | 2004-03-27 | 주식회사 성원인더스트리 | 다기능성 복합소재 |
JP4061061B2 (ja) | 2001-12-12 | 2008-03-12 | 富士通株式会社 | 光触媒機能を有する金属修飾アパタイト膜の形成方法および金属修飾アパタイト被膜材 |
JP4385115B2 (ja) | 2002-02-27 | 2009-12-16 | 独立行政法人産業技術総合研究所 | 紫外・可視光活性触媒による滅菌システム |
KR20030097322A (ko) | 2002-06-20 | 2003-12-31 | (주)세렉트론 | 탈취 코팅제 및 탈취 코팅막 제조 방법 |
-
2004
- 2004-05-13 JP JP2006513471A patent/JP4368379B2/ja not_active Expired - Fee Related
- 2004-05-13 KR KR1020107024151A patent/KR20100131504A/ko not_active Application Discontinuation
- 2004-05-13 DE DE112004002861.2T patent/DE112004002861B4/de not_active Expired - Fee Related
- 2004-05-13 KR KR1020067023854A patent/KR101000821B1/ko active IP Right Grant
- 2004-05-13 WO PCT/JP2004/006462 patent/WO2005110598A1/ja active Application Filing
- 2004-05-13 CN CN2004800430199A patent/CN1953808B/zh not_active Expired - Fee Related
- 2004-05-13 KR KR1020107002484A patent/KR20100023976A/ko active Search and Examination
-
2006
- 2006-11-09 US US11/594,829 patent/US20070051668A1/en not_active Abandoned
-
2011
- 2011-06-28 US US13/067,816 patent/US8846563B2/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5009898A (en) * | 1988-09-29 | 1991-04-23 | Kabushiki Kaisha Sangi | Antimicrobial hydroxyapatite powders and methods for preparing them |
US20050064075A1 (en) * | 2002-03-27 | 2005-03-24 | Masato Wakamura | Method for preserving food using metal-modified apatite and food container used therein |
US20030219624A1 (en) * | 2002-05-21 | 2003-11-27 | Fujitsu Limited | Method of forming antibacterial layer containing metal-modified apatite |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060199729A1 (en) * | 2005-03-01 | 2006-09-07 | Fujitsu Limited | Broad band light absorbing photocatalyst, process for producing thereof, broad band light absorbing photocatalyst composition, and molded article |
US7579296B2 (en) | 2005-03-01 | 2009-08-25 | Fujitsu Limited | Broad band light absorbing photocatalyst, process for producing thereof, broad band light absorbing photocatalyst composition, and molded article |
US20070215006A1 (en) * | 2006-03-20 | 2007-09-20 | Fujitsu Limited | Photocatalyst, method for manufacturing the same, and molded articles |
US20070232487A1 (en) * | 2006-03-29 | 2007-10-04 | Fujitsu Limited | Photocatalytic apatite composition as well as production method and article thereof |
US7635659B2 (en) | 2006-03-29 | 2009-12-22 | Fujitsu Limited | Photocatalytic apatite composition as well as production method and article thereof |
US20080050440A1 (en) * | 2006-07-27 | 2008-02-28 | Fujitsu Limited | Plant epidemic prevention agent, plant epidemic prevention method, plant epidemic prevention system, plant, and plant cultivation method |
EP2799135A4 (en) * | 2011-12-28 | 2015-09-09 | Fujitsu Ltd | PHOTOCATALYSTS AND PROCESS FOR PREPARING PHOTOCATALYSTS |
US20160074288A1 (en) * | 2013-05-28 | 2016-03-17 | Fujitsu Limited | Intraoral fixing composition |
CN103537253A (zh) * | 2013-10-21 | 2014-01-29 | 哈尔滨工业大学 | 一种用羟基磷灰石制备介孔材料的方法 |
CN103537253B (zh) * | 2013-10-21 | 2015-08-05 | 哈尔滨工业大学 | 一种用羟基磷灰石制备介孔材料的方法 |
US11475023B2 (en) | 2014-11-05 | 2022-10-18 | Ab Initio Technology Llc | Impact analysis |
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US20110263414A1 (en) | 2011-10-27 |
US8846563B2 (en) | 2014-09-30 |
KR20100131504A (ko) | 2010-12-15 |
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DE112004002861T5 (de) | 2007-04-19 |
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CN1953808B (zh) | 2011-07-27 |
JP4368379B2 (ja) | 2009-11-18 |
WO2005110598A1 (ja) | 2005-11-24 |
KR20070022266A (ko) | 2007-02-26 |
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