TWI819021B - 過氧化氫水溶液之製造方法 - Google Patents
過氧化氫水溶液之製造方法 Download PDFInfo
- Publication number
- TWI819021B TWI819021B TW108123553A TW108123553A TWI819021B TW I819021 B TWI819021 B TW I819021B TW 108123553 A TW108123553 A TW 108123553A TW 108123553 A TW108123553 A TW 108123553A TW I819021 B TWI819021 B TW I819021B
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- TW
- Taiwan
- Prior art keywords
- zeolite membrane
- working solution
- hydrogen peroxide
- tower
- extraction
- Prior art date
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- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims description 246
- 238000004519 manufacturing process Methods 0.000 title claims description 67
- 238000000034 method Methods 0.000 title claims description 23
- 239000007864 aqueous solution Substances 0.000 title 1
- 239000012224 working solution Substances 0.000 claims description 226
- 229910021536 Zeolite Inorganic materials 0.000 claims description 187
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 187
- 239000010457 zeolite Substances 0.000 claims description 187
- 239000012528 membrane Substances 0.000 claims description 181
- 238000000605 extraction Methods 0.000 claims description 77
- 238000005984 hydrogenation reaction Methods 0.000 claims description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 51
- 238000007254 oxidation reaction Methods 0.000 claims description 31
- 239000012466 permeate Substances 0.000 claims description 31
- 230000003647 oxidation Effects 0.000 claims description 30
- 230000008929 regeneration Effects 0.000 claims description 28
- 238000011069 regeneration method Methods 0.000 claims description 28
- 150000004056 anthraquinones Chemical class 0.000 claims description 27
- 239000003054 catalyst Substances 0.000 claims description 25
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 239000007800 oxidant agent Substances 0.000 claims description 16
- 230000001590 oxidative effect Effects 0.000 claims description 15
- 239000012429 reaction media Substances 0.000 claims description 5
- 230000001172 regenerating effect Effects 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 description 18
- 230000000694 effects Effects 0.000 description 13
- 239000001257 hydrogen Substances 0.000 description 13
- 229910052739 hydrogen Inorganic materials 0.000 description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 11
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 11
- -1 etc.) Chemical compound 0.000 description 11
- 238000004140 cleaning Methods 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- 230000003068 static effect Effects 0.000 description 9
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 8
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 229920006395 saturated elastomer Polymers 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 7
- 238000010586 diagram Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 5
- 230000018044 dehydration Effects 0.000 description 5
- 238000006297 dehydration reaction Methods 0.000 description 5
- 239000012046 mixed solvent Substances 0.000 description 5
- 239000002798 polar solvent Substances 0.000 description 5
- OTBHDFWQZHPNPU-UHFFFAOYSA-N 1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1CCCC2 OTBHDFWQZHPNPU-UHFFFAOYSA-N 0.000 description 4
- GWHJZXXIDMPWGX-UHFFFAOYSA-N 1,2,4-trimethylbenzene Chemical compound CC1=CC=C(C)C(C)=C1 GWHJZXXIDMPWGX-UHFFFAOYSA-N 0.000 description 4
- SJEBAWHUJDUKQK-UHFFFAOYSA-N 2-ethylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC=C3C(=O)C2=C1 SJEBAWHUJDUKQK-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000012454 non-polar solvent Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- SNDGLCYYBKJSOT-UHFFFAOYSA-N 1,1,3,3-tetrabutylurea Chemical compound CCCCN(CCCC)C(=O)N(CCCC)CCCC SNDGLCYYBKJSOT-UHFFFAOYSA-N 0.000 description 3
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 3
- INPHIYULSHLAHR-UHFFFAOYSA-N 1-pentylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2CCCCC INPHIYULSHLAHR-UHFFFAOYSA-N 0.000 description 3
- PCFMUWBCZZUMRX-UHFFFAOYSA-N 9,10-Dihydroxyanthracene Chemical compound C1=CC=C2C(O)=C(C=CC=C3)C3=C(O)C2=C1 PCFMUWBCZZUMRX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- HXQPUEQDBSPXTE-UHFFFAOYSA-N Diisobutylcarbinol Chemical compound CC(C)CC(O)CC(C)C HXQPUEQDBSPXTE-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 239000003849 aromatic solvent Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- BVEIKFLZWBDLJG-UHFFFAOYSA-N 1-butylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2CCCC BVEIKFLZWBDLJG-UHFFFAOYSA-N 0.000 description 2
- RKMPHYRYSONWOL-UHFFFAOYSA-N 1-ethyl-1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(CC)CCC2 RKMPHYRYSONWOL-UHFFFAOYSA-N 0.000 description 2
- HSKPJQYAHCKJQC-UHFFFAOYSA-N 1-ethylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2CC HSKPJQYAHCKJQC-UHFFFAOYSA-N 0.000 description 2
- RBGUKBSLNOTVCD-UHFFFAOYSA-N 1-methylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C RBGUKBSLNOTVCD-UHFFFAOYSA-N 0.000 description 2
- LZNGSHFBWBKBFH-UHFFFAOYSA-N 1-pentyl-1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(CCCCC)CCC2 LZNGSHFBWBKBFH-UHFFFAOYSA-N 0.000 description 2
- NJWGQARXZDRHCD-UHFFFAOYSA-N 2-methylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(C)=CC=C3C(=O)C2=C1 NJWGQARXZDRHCD-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- QOSATHPSBFQAML-UHFFFAOYSA-N hydrogen peroxide;hydrate Chemical compound O.OO QOSATHPSBFQAML-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- IMXBRVLCKXGWSS-UHFFFAOYSA-N methyl 2-cyclohexylacetate Chemical compound COC(=O)CC1CCCCC1 IMXBRVLCKXGWSS-UHFFFAOYSA-N 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- FYGHSUNMUKGBRK-UHFFFAOYSA-N trimethylbenzene Natural products CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- AKIIJALHGMKJEJ-UHFFFAOYSA-N (2-methylcyclohexyl) acetate Chemical compound CC1CCCCC1OC(C)=O AKIIJALHGMKJEJ-UHFFFAOYSA-N 0.000 description 1
- GNRPVZNNVOGXHD-UHFFFAOYSA-N 1,2-dimethylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C(C)C(C)=CC=C3C(=O)C2=C1 GNRPVZNNVOGXHD-UHFFFAOYSA-N 0.000 description 1
- NJMCYPCKTIZMIZ-UHFFFAOYSA-N 1-butyl-1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(CCCC)CCC2 NJMCYPCKTIZMIZ-UHFFFAOYSA-N 0.000 description 1
- JQLVCHDTPJYDIN-UHFFFAOYSA-N 1-methyl-1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(C)CCC2 JQLVCHDTPJYDIN-UHFFFAOYSA-N 0.000 description 1
- JMAKRFSLJOYECP-UHFFFAOYSA-N 1-propyl-1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound C(CC)C1CCCC=2C(C3=CC=CC=C3C(C12)=O)=O JMAKRFSLJOYECP-UHFFFAOYSA-N 0.000 description 1
- QDQRAKVTIKNTPJ-UHFFFAOYSA-N 1-propylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2CCC QDQRAKVTIKNTPJ-UHFFFAOYSA-N 0.000 description 1
- ZRYMONUIRTWHAP-UHFFFAOYSA-N 2,7-dimethyl-1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound O=C1C2=CC(C)=CC=C2C(=O)C2=C1CC(C)CC2 ZRYMONUIRTWHAP-UHFFFAOYSA-N 0.000 description 1
- RATJDSXPVPAWJJ-UHFFFAOYSA-N 2,7-dimethylanthracene-9,10-dione Chemical compound C1=C(C)C=C2C(=O)C3=CC(C)=CC=C3C(=O)C2=C1 RATJDSXPVPAWJJ-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- JORLUGVBYJSSAW-UHFFFAOYSA-N 2-ethyl-1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1CC(CC)CC2 JORLUGVBYJSSAW-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- WJCQJHNUBJYFBW-UHFFFAOYSA-N 2-methyl-1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1CC(C)CC2 WJCQJHNUBJYFBW-UHFFFAOYSA-N 0.000 description 1
- UMWZLYTVXQBTTE-UHFFFAOYSA-N 2-pentylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(CCCCC)=CC=C3C(=O)C2=C1 UMWZLYTVXQBTTE-UHFFFAOYSA-N 0.000 description 1
- JBIIAJUNHWBZRG-UHFFFAOYSA-N 2-propan-2-yl-1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1CC(C(C)C)CC2 JBIIAJUNHWBZRG-UHFFFAOYSA-N 0.000 description 1
- BQUNPXRABCSKJZ-UHFFFAOYSA-N 2-propan-2-ylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)C)=CC=C3C(=O)C2=C1 BQUNPXRABCSKJZ-UHFFFAOYSA-N 0.000 description 1
- GRVQOVOAEKOZNN-UHFFFAOYSA-N 2-propyl-1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound C(CC)C1CC=2C(C3=CC=CC=C3C(C2CC1)=O)=O GRVQOVOAEKOZNN-UHFFFAOYSA-N 0.000 description 1
- ZPQUFYIADDJOEF-UHFFFAOYSA-N 2-propylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(CCC)=CC=C3C(=O)C2=C1 ZPQUFYIADDJOEF-UHFFFAOYSA-N 0.000 description 1
- RONQEQAXCQKPRV-UHFFFAOYSA-N 2-tert-butyl-1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1CC(C(C)(C)C)CC2 RONQEQAXCQKPRV-UHFFFAOYSA-N 0.000 description 1
- AGWLDLJEVPKXBR-UHFFFAOYSA-N 4,4-dimethyl-2,3-dihydro-1H-anthracene-9,10-dione Chemical compound CC1(CCCC=2C(C3=CC=CC=C3C(C12)=O)=O)C AGWLDLJEVPKXBR-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- XAIKOVRFTSBNNU-UHFFFAOYSA-N anthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1.C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 XAIKOVRFTSBNNU-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000005373 pervaporation Methods 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/013—Separation; Purification; Concentration
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Catalysts (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2018131688A JP7322363B2 (ja) | 2018-07-11 | 2018-07-11 | 過酸化水素水溶液の製造方法 |
| JP2018-131688 | 2018-07-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW202010706A TW202010706A (zh) | 2020-03-16 |
| TWI819021B true TWI819021B (zh) | 2023-10-21 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW108123553A TWI819021B (zh) | 2018-07-11 | 2019-07-04 | 過氧化氫水溶液之製造方法 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP7322363B2 (ko) |
| KR (1) | KR102714300B1 (ko) |
| CN (2) | CN110713174A (ko) |
| TW (1) | TWI819021B (ko) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7322363B2 (ja) * | 2018-07-11 | 2023-08-08 | 三菱瓦斯化学株式会社 | 過酸化水素水溶液の製造方法 |
| CN112551541B (zh) * | 2020-12-08 | 2022-10-11 | 中触媒新材料股份有限公司 | 一种用于蒽醌法制备双氧水工作液的再生剂及其应用 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1176628A (zh) * | 1995-02-28 | 1998-03-18 | 凯默夏尔公司 | 用于生产过氧化氢的设备 |
| CN1334235A (zh) * | 2000-07-15 | 2002-02-06 | 中国石油化工股份有限公司巴陵分公司 | 蒽醌法生产过氧化氢的后处理 |
| TWI383951B (zh) * | 2006-05-09 | 2013-02-01 | Mitsubishi Gas Chemical Co | 包含動作溶液之再生步驟的過氧化氫之製造方法 |
| JP2016041419A (ja) * | 2014-08-14 | 2016-03-31 | 日本碍子株式会社 | 分離方法及び分離装置 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS475662U (ko) * | 1971-02-13 | 1972-09-19 | ||
| JPH06106046A (ja) * | 1992-09-30 | 1994-04-19 | Toray Ind Inc | 過酸化水素の製造方法 |
| JP3372412B2 (ja) | 1995-11-10 | 2003-02-04 | 三菱重工業株式会社 | 浸透気化脱水精製法 |
| SE508111C2 (sv) | 1996-12-23 | 1998-08-31 | Kvaerner Process Systems As | Förfarande för framställning av väteperoxid genom hydrering av en kinonlösning samt anordning för utövande av förfarandet |
| JP2003002620A (ja) | 2001-06-18 | 2003-01-08 | Mitsubishi Gas Chem Co Inc | 過酸化水素の製造方法 |
| WO2007119286A1 (ja) | 2006-03-14 | 2007-10-25 | Ngk Insulators, Ltd. | 脱水方法、脱水装置及び膜型反応装置 |
| CN104370331B (zh) | 2013-08-15 | 2016-08-17 | 上海安赐环保科技股份有限公司 | 一种蒽醌法生产双氧水萃余液除水工艺 |
| JP6289852B2 (ja) * | 2013-10-03 | 2018-03-07 | オルガノ株式会社 | 液体有機物と水の分離システム及び分離方法 |
| JP5965945B2 (ja) | 2014-07-22 | 2016-08-10 | 日立造船株式会社 | Ｃｏ２のゼオライト膜分離回収システム |
| JP6271405B2 (ja) | 2014-12-05 | 2018-01-31 | 三井造船株式会社 | ゼオライト膜を用いた脱水方法 |
| JP2017018848A (ja) | 2015-07-07 | 2017-01-26 | 東ソー株式会社 | ゼオライト膜を用いたエチレンアミンの脱水濃縮方法 |
| JP7322363B2 (ja) * | 2018-07-11 | 2023-08-08 | 三菱瓦斯化学株式会社 | 過酸化水素水溶液の製造方法 |
-
2018
- 2018-07-11 JP JP2018131688A patent/JP7322363B2/ja active Active
-
2019
- 2019-07-04 TW TW108123553A patent/TWI819021B/zh active
- 2019-07-09 KR KR1020190082786A patent/KR102714300B1/ko active IP Right Grant
- 2019-07-09 CN CN201910613916.7A patent/CN110713174A/zh active Pending
- 2019-07-09 CN CN201921062747.4U patent/CN211226336U/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1176628A (zh) * | 1995-02-28 | 1998-03-18 | 凯默夏尔公司 | 用于生产过氧化氢的设备 |
| CN1334235A (zh) * | 2000-07-15 | 2002-02-06 | 中国石油化工股份有限公司巴陵分公司 | 蒽醌法生产过氧化氢的后处理 |
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Also Published As
| Publication number | Publication date |
|---|---|
| KR20200006929A (ko) | 2020-01-21 |
| CN211226336U (zh) | 2020-08-11 |
| TW202010706A (zh) | 2020-03-16 |
| KR102714300B1 (ko) | 2024-10-07 |
| JP2020007201A (ja) | 2020-01-16 |
| JP7322363B2 (ja) | 2023-08-08 |
| CN110713174A (zh) | 2020-01-21 |
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