TWI744530B - 混成式鹼石灰矽酸鹽及鋁矽酸鹽玻璃物件 - Google Patents
混成式鹼石灰矽酸鹽及鋁矽酸鹽玻璃物件 Download PDFInfo
- Publication number
- TWI744530B TWI744530B TW107115664A TW107115664A TWI744530B TW I744530 B TWI744530 B TW I744530B TW 107115664 A TW107115664 A TW 107115664A TW 107115664 A TW107115664 A TW 107115664A TW I744530 B TWI744530 B TW I744530B
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- Prior art keywords
- equal
- glass
- mol
- less
- compressive stress
- Prior art date
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- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 title description 16
- 239000005368 silicate glass Substances 0.000 title description 15
- 239000005354 aluminosilicate glass Substances 0.000 title description 11
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 title description 3
- 239000011521 glass Substances 0.000 claims abstract description 237
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 33
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 23
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 5
- 239000006059 cover glass Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000377 silicon dioxide Substances 0.000 abstract description 2
- 229910018404 Al2 O3 Inorganic materials 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 114
- 230000035882 stress Effects 0.000 description 73
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 64
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 53
- 238000005342 ion exchange Methods 0.000 description 39
- 239000000395 magnesium oxide Substances 0.000 description 27
- 230000000052 comparative effect Effects 0.000 description 16
- 239000011734 sodium Substances 0.000 description 15
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 11
- 230000001965 increasing effect Effects 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- 239000002994 raw material Substances 0.000 description 9
- 229910001413 alkali metal ion Inorganic materials 0.000 description 7
- 230000035945 sensitivity Effects 0.000 description 7
- 229910010413 TiO 2 Inorganic materials 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 6
- 229910001409 divalent cation oxide Inorganic materials 0.000 description 6
- 239000006025 fining agent Substances 0.000 description 5
- 238000003426 chemical strengthening reaction Methods 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 238000005728 strengthening Methods 0.000 description 4
- 238000006124 Pilkington process Methods 0.000 description 3
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000005191 phase separation Methods 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000006060 molten glass Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 229910001414 potassium ion Inorganic materials 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000007372 rollout process Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910001415 sodium ion Chemical group 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical group [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- DHAHRLDIUIPTCJ-UHFFFAOYSA-K aluminium metaphosphate Chemical compound [Al+3].[O-]P(=O)=O.[O-]P(=O)=O.[O-]P(=O)=O DHAHRLDIUIPTCJ-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000003280 down draw process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005382 thermal cycling Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
- C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
- C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/18—Compositions for glass with special properties for ion-sensitive glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31—Surface property or characteristic of web, sheet or block
- Y10T428/315—Surface modified glass [e.g., tempered, strengthened, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Glass Compositions (AREA)
- Surface Treatment Of Glass (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361861667P | 2013-08-02 | 2013-08-02 | |
| US61/861,667 | 2013-08-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201829335A TW201829335A (zh) | 2018-08-16 |
| TWI744530B true TWI744530B (zh) | 2021-11-01 |
Family
ID=51301372
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW107115664A TWI744530B (zh) | 2013-08-02 | 2014-07-31 | 混成式鹼石灰矽酸鹽及鋁矽酸鹽玻璃物件 |
| TW103126241A TWI627149B (zh) | 2013-08-02 | 2014-07-31 | 混成式鹼石灰矽酸鹽及鋁矽酸鹽玻璃物件 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW103126241A TWI627149B (zh) | 2013-08-02 | 2014-07-31 | 混成式鹼石灰矽酸鹽及鋁矽酸鹽玻璃物件 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US10941071B2 (enExample) |
| EP (1) | EP3027571A1 (enExample) |
| JP (1) | JP2016529194A (enExample) |
| KR (1) | KR102341851B1 (enExample) |
| CN (1) | CN105593180A (enExample) |
| TW (2) | TWI744530B (enExample) |
| WO (1) | WO2015017598A1 (enExample) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9359251B2 (en) | 2012-02-29 | 2016-06-07 | Corning Incorporated | Ion exchanged glasses via non-error function compressive stress profiles |
| US11079309B2 (en) | 2013-07-26 | 2021-08-03 | Corning Incorporated | Strengthened glass articles having improved survivability |
| US9969644B2 (en) * | 2013-08-27 | 2018-05-15 | Corning Incorporated | Damage resistant glass with high coefficient of thermal expansion |
| US9517968B2 (en) | 2014-02-24 | 2016-12-13 | Corning Incorporated | Strengthened glass with deep depth of compression |
| CN106232543A (zh) | 2014-02-27 | 2016-12-14 | 康宁股份有限公司 | 用于三维成形的可离子交换玻璃制品 |
| TWI773291B (zh) | 2014-06-19 | 2022-08-01 | 美商康寧公司 | 無易碎應力分布曲線的玻璃 |
| CN108046589A (zh) | 2014-10-08 | 2018-05-18 | 康宁股份有限公司 | 包含金属氧化物浓度梯度的玻璃和玻璃陶瓷 |
| US10150698B2 (en) | 2014-10-31 | 2018-12-11 | Corning Incorporated | Strengthened glass with ultra deep depth of compression |
| KR102459339B1 (ko) | 2014-11-04 | 2022-10-26 | 코닝 인코포레이티드 | 비-취약성 응력 프로파일 및 이의 제조방법 |
| US9586857B2 (en) | 2014-11-17 | 2017-03-07 | International Business Machines Corporation | Controlling fragmentation of chemically strengthened glass |
| KR102640959B1 (ko) | 2015-06-26 | 2024-02-27 | 코닝 인코포레이티드 | 높은 표면 강도를 갖는 유리 |
| US11104602B2 (en) | 2015-06-26 | 2021-08-31 | Corning Incorporated | Glass with high surface strength |
| JP6774614B2 (ja) * | 2015-07-01 | 2020-10-28 | 日本電気硝子株式会社 | 強化用ガラス及び強化ガラス |
| US11613103B2 (en) | 2015-07-21 | 2023-03-28 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
| US9701569B2 (en) | 2015-07-21 | 2017-07-11 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
| WO2017068857A1 (ja) * | 2015-10-21 | 2017-04-27 | セントラル硝子株式会社 | 化学強化用ガラス板及び化学強化ガラス板の製造方法 |
| TWI675810B (zh) | 2015-12-11 | 2019-11-01 | 美商康寧公司 | 具有金屬氧化物濃度梯度之可熔融成形的玻璃基物件 |
| WO2017177109A1 (en) | 2016-04-08 | 2017-10-12 | Corning Incorporated | Glass-based articles including a stress profile comprising two regions, and methods of making |
| EP3904302A1 (en) | 2016-04-08 | 2021-11-03 | Corning Incorporated | Glass-based articles including a metal oxide concentration gradient |
| US11028007B2 (en) * | 2017-06-22 | 2021-06-08 | Corning Incorporated | Automotive glass compositions, articles and hybrid laminates |
| EP3844113A1 (en) | 2018-08-30 | 2021-07-07 | Corning Incorporated | Glass compositions for use in co-formed laminates |
| CN112703173A (zh) * | 2018-08-30 | 2021-04-23 | 康宁股份有限公司 | 用于层叠体的软的可化学强化玻璃 |
| JP2022513157A (ja) * | 2018-11-30 | 2022-02-07 | コーニング インコーポレイテッド | 高い圧縮応力を示すガラス物品、そのようなガラス物品を含む自動車内装システムおよび同ガラス物品を製造するための方法 |
| CN111268905A (zh) * | 2020-03-31 | 2020-06-12 | 台玻安徽玻璃有限公司 | 浮法玻璃的强化方法 |
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|---|---|---|---|---|
| TW200911759A (en) * | 2007-08-03 | 2009-03-16 | Nippon Electric Glass Co | Tempered glass substrate and method for fabricating the same |
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| US3524737A (en) | 1967-06-01 | 1970-08-18 | Corning Glass Works | Method for thermochemical strengthening of glass articles |
| JPS5152706Y2 (enExample) | 1971-10-26 | 1976-12-16 | ||
| US4192689A (en) | 1978-05-30 | 1980-03-11 | Ppg Industries, Inc. | Ion exchange strengthening of soda-lime-silica glass |
| US4726981A (en) * | 1985-06-10 | 1988-02-23 | Corning Glass Works | Strengthened glass articles and method for making |
| JPH03237036A (ja) * | 1989-08-24 | 1991-10-22 | Nippon Electric Glass Co Ltd | アルミナパッケージ用薄板状硼けい酸ガラス |
| GB2335423A (en) | 1998-03-20 | 1999-09-22 | Pilkington Plc | Chemically toughenable glass |
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| US9206079B2 (en) | 2011-09-29 | 2015-12-08 | Central Glass Company, Limited | Chemically strengthened glass plate and method for manufacturing same |
| EP2855384B1 (en) * | 2012-05-29 | 2020-12-09 | Corning Incorporated | Method for texturing a glass surface |
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2014
- 2014-07-15 US US14/331,753 patent/US10941071B2/en active Active
- 2014-07-31 WO PCT/US2014/048999 patent/WO2015017598A1/en not_active Ceased
- 2014-07-31 JP JP2016531877A patent/JP2016529194A/ja active Pending
- 2014-07-31 TW TW107115664A patent/TWI744530B/zh not_active IP Right Cessation
- 2014-07-31 CN CN201480054261.XA patent/CN105593180A/zh active Pending
- 2014-07-31 KR KR1020167005534A patent/KR102341851B1/ko not_active Expired - Fee Related
- 2014-07-31 TW TW103126241A patent/TWI627149B/zh not_active IP Right Cessation
- 2014-07-31 EP EP14750294.2A patent/EP3027571A1/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200911759A (en) * | 2007-08-03 | 2009-03-16 | Nippon Electric Glass Co | Tempered glass substrate and method for fabricating the same |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201505994A (zh) | 2015-02-16 |
| CN105593180A (zh) | 2016-05-18 |
| TW201829335A (zh) | 2018-08-16 |
| TWI627149B (zh) | 2018-06-21 |
| EP3027571A1 (en) | 2016-06-08 |
| JP2016529194A (ja) | 2016-09-23 |
| US10941071B2 (en) | 2021-03-09 |
| KR102341851B1 (ko) | 2021-12-21 |
| US20150037586A1 (en) | 2015-02-05 |
| WO2015017598A1 (en) | 2015-02-05 |
| KR20160040642A (ko) | 2016-04-14 |
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