TWI722018B - 用於酚之烷基化的方法 - Google Patents
用於酚之烷基化的方法 Download PDFInfo
- Publication number
- TWI722018B TWI722018B TW105129476A TW105129476A TWI722018B TW I722018 B TWI722018 B TW I722018B TW 105129476 A TW105129476 A TW 105129476A TW 105129476 A TW105129476 A TW 105129476A TW I722018 B TWI722018 B TW I722018B
- Authority
- TW
- Taiwan
- Prior art keywords
- isobutylene
- weight
- butene
- reaction
- phenol
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0214—Aryloxylates, e.g. phenolates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
- C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
- C07C39/06—Alkylated phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
- B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15184850 | 2015-09-11 | ||
| EP15184850.4 | 2015-09-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201718449A TW201718449A (zh) | 2017-06-01 |
| TWI722018B true TWI722018B (zh) | 2021-03-21 |
Family
ID=54146988
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW105129476A TWI722018B (zh) | 2015-09-11 | 2016-09-10 | 用於酚之烷基化的方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US10196334B2 (ko) |
| EP (1) | EP3347336B1 (ko) |
| JP (1) | JP7527757B2 (ko) |
| KR (1) | KR20180053301A (ko) |
| CN (1) | CN108026010A (ko) |
| BR (1) | BR112018004647B1 (ko) |
| SA (1) | SA518391065B1 (ko) |
| TW (1) | TWI722018B (ko) |
| WO (1) | WO2017042181A1 (ko) |
| ZA (1) | ZA201802180B (ko) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1844071A (zh) * | 2006-03-24 | 2006-10-11 | 北京极易化工有限公司 | 一种高转化率高选择性的苯酚邻位烷基化方法 |
| TW201136882A (en) * | 2009-12-04 | 2011-11-01 | Si Group Inc | Process for producing a t-butyl phenol from a C4 raffinate stream |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2353282A (en) | 1941-10-15 | 1944-07-11 | Bakelite Corp | Preparation of substituted phenols |
| GB1062298A (en) | 1965-02-19 | 1967-03-22 | Ici Ltd | Process for the alkylation of phenol |
| DE2039062A1 (de) | 1970-08-06 | 1972-02-10 | Hoechst Ag | Verfahren zur Herstellung von 2,6-Ditert.-butylphenol |
| US3751509A (en) | 1972-07-17 | 1973-08-07 | A Liakumovich | Process for isolating isobutylene from butane-butylene fraction |
| US3970708A (en) | 1974-12-26 | 1976-07-20 | Chevron Research Company | Process for removing aluminum phenoxide catalyst from phenol alkylation products |
| SU783297A1 (ru) * | 1976-08-11 | 1980-11-30 | Стерлитамакский опытно-промышленный нефтехимический завод | Способ получени 2,6-ди-третбутилфенола |
| US4260833A (en) | 1979-11-30 | 1981-04-07 | Uop Inc. | Preparation of alkylphenols |
| JPS6052732B2 (ja) * | 1980-12-05 | 1985-11-21 | 三井化学株式会社 | ２，６−ジ−ｔ−ブチルフエノ−ルの製造方法 |
| JPS60255742A (ja) | 1984-06-01 | 1985-12-17 | Mitsui Petrochem Ind Ltd | ２、４−ジ−ｔｅｒｔ−ブチルフェノ−ルの製造方法 |
| JPS6136A (ja) * | 1984-06-09 | 1986-01-06 | Maruzen Sekiyu Kagaku Kk | ２．６−ジ−ｔｅｒｔ−ブチルフエノ−ルの製造方法 |
| JPS61200934A (ja) * | 1985-03-02 | 1986-09-05 | Maruzen Sekiyu Kagaku Kk | ｔｅｒｔ―ブチルフエノール類の製造方法 |
| JPH0725714B2 (ja) | 1986-12-26 | 1995-03-22 | 三井石油化学工業株式会社 | ２，４―ジ―ｔ―ブチルフェノールの製造方法 |
| US4870215A (en) * | 1988-06-24 | 1989-09-26 | Ethyl Corporation | Phenol alkylation process |
| CS276820B6 (cs) | 1990-05-28 | 1992-08-12 | Slovenska Technicke Univerzita | Sposob alkylácie a/alebo arylalkylácie fenolu a/alebo jeho derivátov |
| JPH0812611A (ja) * | 1994-06-30 | 1996-01-16 | Dainippon Ink & Chem Inc | ２，６−ジ−アルキルフェノールの製造方法 |
| CN1193007A (zh) * | 1998-01-22 | 1998-09-16 | 义县精细化工总厂 | 混合型叔丁基苯酚的合成方法 |
| CN1935764A (zh) * | 2006-10-20 | 2007-03-28 | 上海金海雅宝精细化工有限公司 | 一种2.6－二叔丁基苯酚烷化液的制备方法 |
| CN1935763A (zh) | 2006-10-20 | 2007-03-28 | 上海金海雅宝精细化工有限公司 | 一种2.4－二叔丁基苯酚烷化液的制备方法 |
| CN102976901A (zh) * | 2012-12-06 | 2013-03-20 | 锦州惠发天合化学有限公司 | 混合型叔丁基苯酚的合成方法 |
-
2016
- 2016-09-07 EP EP16766880.5A patent/EP3347336B1/en active Active
- 2016-09-07 US US15/758,010 patent/US10196334B2/en active Active
- 2016-09-07 CN CN201680052276.1A patent/CN108026010A/zh active Pending
- 2016-09-07 BR BR112018004647-7A patent/BR112018004647B1/pt active IP Right Grant
- 2016-09-07 WO PCT/EP2016/071012 patent/WO2017042181A1/en active Application Filing
- 2016-09-07 KR KR1020187006572A patent/KR20180053301A/ko not_active Application Discontinuation
- 2016-09-07 JP JP2018513373A patent/JP7527757B2/ja active Active
- 2016-09-10 TW TW105129476A patent/TWI722018B/zh active
-
2018
- 2018-03-05 SA SA518391065A patent/SA518391065B1/ar unknown
- 2018-04-04 ZA ZA2018/02180A patent/ZA201802180B/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1844071A (zh) * | 2006-03-24 | 2006-10-11 | 北京极易化工有限公司 | 一种高转化率高选择性的苯酚邻位烷基化方法 |
| TW201136882A (en) * | 2009-12-04 | 2011-11-01 | Si Group Inc | Process for producing a t-butyl phenol from a C4 raffinate stream |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3347336A1 (en) | 2018-07-18 |
| WO2017042181A1 (en) | 2017-03-16 |
| ZA201802180B (en) | 2019-06-26 |
| SA518391065B1 (ar) | 2022-03-09 |
| JP7527757B2 (ja) | 2024-08-05 |
| US10196334B2 (en) | 2019-02-05 |
| BR112018004647B1 (pt) | 2020-12-08 |
| EP3347336B1 (en) | 2019-06-12 |
| KR20180053301A (ko) | 2018-05-21 |
| BR112018004647A2 (pt) | 2018-09-25 |
| JP2018526425A (ja) | 2018-09-13 |
| CN108026010A (zh) | 2018-05-11 |
| TW201718449A (zh) | 2017-06-01 |
| US20180244595A1 (en) | 2018-08-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9938205B2 (en) | Apparatus and process for producing gasoline, olefins and aromatics from oxygenates | |
| JP5908655B2 (ja) | パラキシレンの回収法におけるスチレンの除去 | |
| SG194981A1 (en) | Method for producing conjugated diolefin and apparatus for production | |
| TW201313315A (zh) | 製備包括磷改質沸石的觸媒的方法以及該沸石的用途 | |
| CA2960785C (fr) | Procede de deshydratation isomerisante d'une charge alcool primaire substitue en position 2 par un groupement alkyl sur un catalyseur comprenant une zeolithe de type fer | |
| US20170253540A1 (en) | Method and apparatus for producing hydrocarbons | |
| TWI570102B (zh) | 從ｃ萃餘物之物流製造三級丁基酚之方法 | |
| CA2548574C (en) | Improvements in or relating to catalysed reactions | |
| JP5586693B2 (ja) | 触媒の再生方法 | |
| KR20170013947A (ko) | 크실렌의 제조 방법 | |
| WO2006126727A1 (ja) | 固体リン酸触媒およびそれを用いたオレフィンの二量化反応方法 | |
| TWI722018B (zh) | 用於酚之烷基化的方法 | |
| BR112017027711B1 (pt) | Processo para fabricar éter metil terc-butílico (mtbe) e hidrocarbonetos | |
| US4532368A (en) | Process for making meta- and para-alkylphenols | |
| TW201601834A (zh) | 烯烴的寡聚物化觸媒及烯烴二聚物的製造方法 | |
| JPH0237898B2 (ko) | ||
| TW200800845A (en) | Process for the preparation of propylene | |
| US20170253541A1 (en) | Method and apparatus for producing hydrocarbons | |
| WO2022208416A1 (en) | Metallocene catalyzed propylene oligomerisation without separation of alkane and olefin | |
| WO2015000939A1 (en) | A method of converting oxygenates to olefins |