TWI563010B - Polyalkenyl coupling agent and conjugated diene polymers prepared therefrom - Google Patents

Polyalkenyl coupling agent and conjugated diene polymers prepared therefrom

Info

Publication number
TWI563010B
TWI563010B TW104115645A TW104115645A TWI563010B TW I563010 B TWI563010 B TW I563010B TW 104115645 A TW104115645 A TW 104115645A TW 104115645 A TW104115645 A TW 104115645A TW I563010 B TWI563010 B TW I563010B
Authority
TW
Taiwan
Prior art keywords
coupling agent
conjugated diene
prepared therefrom
polymers prepared
diene polymers
Prior art date
Application number
TW104115645A
Other languages
English (en)
Other versions
TW201609837A (zh
Inventor
Der Huizen Adriaan Albert Van
Wit Frank Wijnand De
Original Assignee
Kraton Polymers Us Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kraton Polymers Us Llc filed Critical Kraton Polymers Us Llc
Publication of TW201609837A publication Critical patent/TW201609837A/zh
Application granted granted Critical
Publication of TWI563010B publication Critical patent/TWI563010B/zh

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/02—Hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/28—Reaction with compounds containing carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
    • C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C2/00—Treatment of rubber solutions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments
    • C08F6/06—Treatment of polymer solutions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
TW104115645A 2014-05-16 2015-05-15 Polyalkenyl coupling agent and conjugated diene polymers prepared therefrom TWI563010B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL2012829 2014-05-16

Publications (2)

Publication Number Publication Date
TW201609837A TW201609837A (zh) 2016-03-16
TWI563010B true TWI563010B (en) 2016-12-21

Family

ID=51179110

Family Applications (1)

Application Number Title Priority Date Filing Date
TW104115645A TWI563010B (en) 2014-05-16 2015-05-15 Polyalkenyl coupling agent and conjugated diene polymers prepared therefrom

Country Status (10)

Country Link
US (1) US9951160B2 (zh)
EP (1) EP3143056B1 (zh)
JP (1) JP6325173B2 (zh)
KR (1) KR101856896B1 (zh)
CN (1) CN106414529B (zh)
BR (1) BR112016026642B1 (zh)
MY (1) MY173470A (zh)
RU (1) RU2655165C1 (zh)
TW (1) TWI563010B (zh)
WO (1) WO2015175812A1 (zh)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109503763B (zh) * 2017-09-14 2021-11-19 中国石油化工股份有限公司 丁二烯-异戊二烯共聚物及其制备方法和芳族乙烯基树脂及其制备方法
TWI662053B (zh) * 2018-03-26 2019-06-11 台光電子材料股份有限公司 預聚樹脂、其製備方法、樹脂組成物及其製品
CN108840980B (zh) * 2018-06-01 2021-02-26 广东众和高新科技有限公司 一种sebs弹性体及其制备方法
CN109181813B (zh) * 2018-07-31 2021-07-06 沈阳化工研究院有限公司 一种用于润滑油的星形黏度指数改进剂及其制备方法
CN111116814B (zh) * 2018-10-31 2022-08-30 台光电子材料(昆山)有限公司 预聚物、制备方法、树脂组合物及其制品
JP2020183526A (ja) * 2019-05-03 2020-11-12 クレイトン・ポリマーズ・リサーチ・ベー・フェー ブロックコポリマー及びその使用
CN115181277B (zh) * 2021-04-02 2023-12-01 中国科学院化学研究所 一种金属复合聚合物单链纳米颗粒的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
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US5360875A (en) * 1993-09-10 1994-11-01 Shell Oil Company Method for producing coupled asymmetric polymers
US5552493A (en) * 1995-05-30 1996-09-03 Shell Oil Company Method for producing asymmetric radial polymers
US6417270B1 (en) * 2001-01-09 2002-07-09 Firestone Polymers, Llc Means of producing high diblock content thermoplastic elastomers with functional termination

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NL296137A (zh) 1963-08-02 1900-01-01
US3595942A (en) 1968-12-24 1971-07-27 Shell Oil Co Partially hydrogenated block copolymers
US4894397A (en) 1988-04-21 1990-01-16 S. C. Johnson & Son, Inc. Stable emulsion polymers and methods of preparing same
US5070131A (en) * 1990-09-28 1991-12-03 Shell Oil Company Gear oil viscosity index improvers
US5563204A (en) * 1993-01-08 1996-10-08 The Dow Chemical Company High-strength films of block copolymer latices
US5296547A (en) 1993-01-28 1994-03-22 Minnesota Mining And Manufacturing Company Block copolymer having mixed molecular weight endblocks
US5395787A (en) 1993-12-01 1995-03-07 At&T Corp. Method of manufacturing shallow junction field effect transistor
US5458791A (en) * 1994-07-01 1995-10-17 Shell Oil Company Star polymer viscosity index improver for oil compositions
EP0718330B1 (en) * 1994-12-23 2000-05-31 Shell Internationale Researchmaatschappij B.V. Process for manufacturing multiarmed asymmetrical radial block copolymers
JPH1028879A (ja) 1996-07-19 1998-02-03 Mitsubishi Chem Corp 水洗性の改良されたイオン交換樹脂ならびにその製造方法
CN1187386C (zh) * 2002-12-16 2005-02-02 江苏圣杰实业有限公司 共轭二烯和单乙烯基芳烃嵌段共聚物的制备方法
JP4134835B2 (ja) 2003-07-28 2008-08-20 株式会社日立製作所 高誘電率低誘電正接複合材料組成物、硬化性フィルム，硬化物とその製法
EP1935925A1 (en) 2006-12-21 2008-06-25 Kraton Polymers Research B.V. Process for the preparation of an artificial latex
CN101434887B (zh) * 2007-11-17 2011-02-02 中国石油化工股份有限公司 一种润滑油粘度指数改进剂及其制备方法
KR101692089B1 (ko) * 2009-01-23 2017-01-02 가부시키가이샤 브리지스톤 폴리시아노 화합물로 관능화된 중합체
BRPI1014609B1 (pt) * 2009-06-30 2021-09-08 Bridgestone Corporation Polímeros funcionalizados com difenil-etileno contendo grupo de hidroxila
CN102453303B (zh) * 2010-10-28 2014-05-14 中国石油化工股份有限公司 单乙烯基芳烃和共轭二烯烃嵌段共聚物组合物及其制备方法
CN103382241B (zh) * 2012-05-04 2016-06-08 中国石油天然气股份有限公司 星形异戊二烯-b-丁二烯苯乙烯三元共聚物及其制备方法
CN102731739B (zh) * 2012-07-05 2013-11-06 富阳经略化工技术有限公司 用作润滑油粘度指数改进剂的星形聚合物及其制备方法和应用

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5360875A (en) * 1993-09-10 1994-11-01 Shell Oil Company Method for producing coupled asymmetric polymers
US5552493A (en) * 1995-05-30 1996-09-03 Shell Oil Company Method for producing asymmetric radial polymers
US6417270B1 (en) * 2001-01-09 2002-07-09 Firestone Polymers, Llc Means of producing high diblock content thermoplastic elastomers with functional termination

Also Published As

Publication number Publication date
EP3143056A1 (en) 2017-03-22
BR112016026642A2 (zh) 2017-08-15
WO2015175812A1 (en) 2015-11-19
US9951160B2 (en) 2018-04-24
TW201609837A (zh) 2016-03-16
BR112016026642B1 (pt) 2021-08-31
CN106414529A (zh) 2017-02-15
KR101856896B1 (ko) 2018-05-10
US20170114161A9 (en) 2017-04-27
US20160333122A1 (en) 2016-11-17
JP6325173B2 (ja) 2018-05-16
MY173470A (en) 2020-01-28
KR20170008797A (ko) 2017-01-24
JP2017521544A (ja) 2017-08-03
EP3143056A4 (en) 2018-04-18
EP3143056B1 (en) 2021-01-13
RU2655165C1 (ru) 2018-05-24
CN106414529B (zh) 2019-05-10

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