TWI512154B - Halogen-containing flame retardant fibers and methods for their manufacture and flame retardant fiber products using the same - Google Patents
Halogen-containing flame retardant fibers and methods for their manufacture and flame retardant fiber products using the same Download PDFInfo
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- TWI512154B TWI512154B TW102133974A TW102133974A TWI512154B TW I512154 B TWI512154 B TW I512154B TW 102133974 A TW102133974 A TW 102133974A TW 102133974 A TW102133974 A TW 102133974A TW I512154 B TWI512154 B TW I512154B
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- halogen
- mass
- fiber
- parts
- flame
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- 239000000835 fiber Substances 0.000 title claims description 244
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- 150000002367 halogens Chemical class 0.000 title claims description 176
- 239000003063 flame retardant Substances 0.000 title claims description 85
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 84
- 238000004519 manufacturing process Methods 0.000 title claims description 47
- 238000000034 method Methods 0.000 title claims description 24
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- XIQGQTYUPQAUBV-UHFFFAOYSA-N prop-2-enoic acid;prop-1-en-2-ylbenzene;styrene Chemical compound OC(=O)C=C.C=CC1=CC=CC=C1.CC(=C)C1=CC=CC=C1 XIQGQTYUPQAUBV-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920006297 regenerated protein fiber Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 229920005792 styrene-acrylic resin Polymers 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000004950 technora Substances 0.000 description 1
- 239000004762 twaron Substances 0.000 description 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 1
- 229920006312 vinyl chloride fiber Polymers 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/38—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated nitriles as the major constituent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/42—Nitriles
- C08F20/44—Acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/02—Monomers containing chlorine
- C08F214/04—Monomers containing two carbon atoms
- C08F214/08—Vinylidene chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C09J123/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/08—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of halogenated hydrocarbons
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/32—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising halogenated hydrocarbons as the major constituent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Knitting Of Fabric (AREA)
- Woven Fabrics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012208759 | 2012-09-21 |
Publications (2)
| Publication Number | Publication Date |
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| TW201420823A TW201420823A (zh) | 2014-06-01 |
| TWI512154B true TWI512154B (zh) | 2015-12-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW102133974A TWI512154B (zh) | 2012-09-21 | 2013-09-18 | Halogen-containing flame retardant fibers and methods for their manufacture and flame retardant fiber products using the same |
Country Status (7)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI656290B (zh) * | 2014-06-13 | 2019-04-11 | 日商華爾卡股份有限公司 | 編織體及封軸襯墊 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110418814B (zh) * | 2017-07-11 | 2021-11-09 | 伊士曼化工公司 | 树脂组合物和树脂成型体 |
| CN107313168A (zh) * | 2017-08-31 | 2017-11-03 | 苏州英得福机电科技有限公司 | 一种环保复合型阻燃面料 |
| CN110067037A (zh) * | 2019-04-26 | 2019-07-30 | 中科国联劳动防护技术研究院(北京)有限公司 | 一种再生纤维素纤维 |
| CN113123157A (zh) * | 2021-03-18 | 2021-07-16 | 南京安堤特种材料有限公司 | 一种低毒烟量的生物基纳米阻燃纸的制备方法 |
| WO2023171288A1 (ja) * | 2022-03-09 | 2023-09-14 | 株式会社カネカ | 難燃性アクリル系繊維、その製造方法、並びにそれを含む難燃性繊維集合体及び難燃性作業服 |
| WO2024004692A1 (ja) * | 2022-06-28 | 2024-01-04 | 株式会社カネカ | 難燃性布帛及び作業服 |
| WO2024182366A1 (en) * | 2023-02-27 | 2024-09-06 | Ascend Performance Materials Operations Llc | Chem/bio fabric or layer with metal oxide content |
| WO2024185346A1 (ja) * | 2023-03-08 | 2024-09-12 | 株式会社カネカ | モダクリル繊維、それを含む難燃性繊維集合体及びその製造方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11310688A (ja) * | 1998-04-27 | 1999-11-09 | Shin Etsu Chem Co Ltd | 半導体封止用エポキシ樹脂組成物及び半導体装置 |
| JP2000303306A (ja) * | 1999-04-15 | 2000-10-31 | Kanegafuchi Chem Ind Co Ltd | 難燃繊維複合体 |
| JP2005082668A (ja) * | 2003-09-08 | 2005-03-31 | Shin Etsu Chem Co Ltd | 難燃剤及びその製造方法、樹脂組成物 |
| WO2006008958A1 (ja) * | 2004-07-15 | 2006-01-26 | Kaneka Corporation | 難燃性合成繊維、難燃繊維複合体および難燃繊維複合体を用いた布張り家具製品 |
| WO2009101930A1 (ja) * | 2008-02-12 | 2009-08-20 | Teijin Techno Products Limited | 難燃性樹脂組成物、難燃性繊維、難燃性布帛および耐熱性防護服 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2765351A (en) * | 1955-04-05 | 1956-10-02 | Ethyl Corp | Dehydrochlorination process |
| GB1585085A (en) * | 1976-06-21 | 1981-02-25 | Ici Ltd | Polyamide compositions |
| JPH09263668A (ja) | 1996-03-28 | 1997-10-07 | Tsutsunaka Plast Ind Co Ltd | 硬質塩化ビニール系樹脂組成物 |
| JP3531358B2 (ja) | 1996-06-13 | 2004-05-31 | 鐘淵化学工業株式会社 | ハロゲン含有繊維を用いた難燃繊維複合体 |
| JP3443023B2 (ja) * | 1999-01-20 | 2003-09-02 | アキレス株式会社 | 難燃性壁紙 |
| JP2003082238A (ja) * | 2001-09-11 | 2003-03-19 | Asahi Kasei Corp | 優れた難燃性重合体組成物 |
| JP3824064B2 (ja) | 2001-11-06 | 2006-09-20 | 信越化学工業株式会社 | 半導体封止用難燃性エポキシ樹脂組成物及び半導体装置 |
| JP2006265417A (ja) * | 2005-03-24 | 2006-10-05 | Fuji Xerox Co Ltd | 難燃性樹脂組成物及び難燃性樹脂成形品 |
| WO2007060201A1 (en) * | 2005-11-25 | 2007-05-31 | Solvay Solexis, Inc. | Perfluoropolymer composition |
| CN102066625B (zh) * | 2008-07-24 | 2013-03-13 | 株式会社钟化 | 阻燃性合成纤维和阻燃纤维集合体及它们的制造方法、以及纤维制品 |
| JP5387229B2 (ja) | 2009-08-24 | 2014-01-15 | 住友ベークライト株式会社 | 塩化ビニル樹脂組成物およびその製造方法、塩化ビニル樹脂成形材料ならびに成形品 |
-
2013
- 2013-09-17 NO NO13840060A patent/NO2899302T3/no unknown
- 2013-09-17 CN CN201380049056.XA patent/CN104641025B/zh active Active
- 2013-09-17 WO PCT/JP2013/075037 patent/WO2014046087A1/ja active Application Filing
- 2013-09-17 JP JP2014536858A patent/JP5779723B2/ja active Active
- 2013-09-17 EP EP13840060.1A patent/EP2899302B1/en active Active
- 2013-09-18 TW TW102133974A patent/TWI512154B/zh active
-
2015
- 2015-03-19 US US14/662,769 patent/US20150191854A1/en not_active Abandoned
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11310688A (ja) * | 1998-04-27 | 1999-11-09 | Shin Etsu Chem Co Ltd | 半導体封止用エポキシ樹脂組成物及び半導体装置 |
| JP2000303306A (ja) * | 1999-04-15 | 2000-10-31 | Kanegafuchi Chem Ind Co Ltd | 難燃繊維複合体 |
| JP2005082668A (ja) * | 2003-09-08 | 2005-03-31 | Shin Etsu Chem Co Ltd | 難燃剤及びその製造方法、樹脂組成物 |
| WO2006008958A1 (ja) * | 2004-07-15 | 2006-01-26 | Kaneka Corporation | 難燃性合成繊維、難燃繊維複合体および難燃繊維複合体を用いた布張り家具製品 |
| WO2009101930A1 (ja) * | 2008-02-12 | 2009-08-20 | Teijin Techno Products Limited | 難燃性樹脂組成物、難燃性繊維、難燃性布帛および耐熱性防護服 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI656290B (zh) * | 2014-06-13 | 2019-04-11 | 日商華爾卡股份有限公司 | 編織體及封軸襯墊 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20150191854A1 (en) | 2015-07-09 |
| JP5779723B2 (ja) | 2015-09-16 |
| CN104641025B (zh) | 2018-03-23 |
| EP2899302B1 (en) | 2017-11-15 |
| NO2899302T3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 2018-04-14 |
| EP2899302A1 (en) | 2015-07-29 |
| CN104641025A (zh) | 2015-05-20 |
| TW201420823A (zh) | 2014-06-01 |
| EP2899302A4 (en) | 2016-04-27 |
| JPWO2014046087A1 (ja) | 2016-08-18 |
| WO2014046087A1 (ja) | 2014-03-27 |
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