TWI504586B - 使用雙開端雙亞磷酸酯配位基之氫甲醯化方法 - Google Patents
使用雙開端雙亞磷酸酯配位基之氫甲醯化方法 Download PDFInfo
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- TWI504586B TWI504586B TW098142834A TW98142834A TWI504586B TW I504586 B TWI504586 B TW I504586B TW 098142834 A TW098142834 A TW 098142834A TW 98142834 A TW98142834 A TW 98142834A TW I504586 B TWI504586 B TW I504586B
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- Prior art keywords
- ligand
- hydroformylation
- group
- organic
- transition metal
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- 239000003446 ligand Substances 0.000 title claims description 110
- 238000000034 method Methods 0.000 title claims description 76
- 238000007037 hydroformylation reaction Methods 0.000 title claims description 53
- 238000006243 chemical reaction Methods 0.000 claims description 46
- 239000003054 catalyst Substances 0.000 claims description 37
- 239000001257 hydrogen Substances 0.000 claims description 29
- 229910052739 hydrogen Inorganic materials 0.000 claims description 29
- 125000003118 aryl group Chemical group 0.000 claims description 26
- 239000012530 fluid Substances 0.000 claims description 26
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 23
- 229910052723 transition metal Inorganic materials 0.000 claims description 23
- 150000003624 transition metals Chemical group 0.000 claims description 23
- 229910052751 metal Inorganic materials 0.000 claims description 22
- 239000002184 metal Substances 0.000 claims description 22
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 20
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 20
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- 230000000717 retained effect Effects 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
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- 238000011105 stabilization Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
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- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 description 1
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- 238000005829 trimerization reaction Methods 0.000 description 1
- ITHPEWAHFNDNIO-UHFFFAOYSA-N triphosphane Chemical compound PPP ITHPEWAHFNDNIO-UHFFFAOYSA-N 0.000 description 1
- 125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
- C07C45/505—Asymmetric hydroformylation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
- C07C45/294—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with hydrogen peroxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
- C07C45/298—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with manganese derivatives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16503909P | 2009-03-31 | 2009-03-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201035033A TW201035033A (en) | 2010-10-01 |
| TWI504586B true TWI504586B (zh) | 2015-10-21 |
Family
ID=42537699
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW098142834A TWI504586B (zh) | 2009-03-31 | 2009-12-15 | 使用雙開端雙亞磷酸酯配位基之氫甲醯化方法 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US8513469B2 (enExample) |
| EP (1) | EP2414314B1 (enExample) |
| JP (1) | JP5603407B2 (enExample) |
| KR (1) | KR101706797B1 (enExample) |
| CN (1) | CN102365258B (enExample) |
| CA (1) | CA2756936A1 (enExample) |
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| PL (1) | PL2414314T3 (enExample) |
| RU (1) | RU2541537C2 (enExample) |
| TW (1) | TWI504586B (enExample) |
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| DE102013020320B4 (de) | 2013-12-05 | 2019-04-04 | Oxea Gmbh | Verfahren zur Herstellung von 2-Methylbuttersäure mit einem vermindertem Gehalt an 3-Methylbuttersäure aus den bei der Herstellung von Pentansäuren anfallenden Nebenströmen |
| DE102013020322B4 (de) | 2013-12-05 | 2019-04-18 | Oxea Gmbh | Verfahren zur Gewinnung von 2-Methylbutanal aus den bei der Herstellung von Gemischen isomerer a,ß-ungesättigter Decenale anfallenden Nebenströmen |
| DE102013020323B3 (de) | 2013-12-05 | 2015-01-08 | Oxea Gmbh | Verfahren zur Herstellung von isomeren Hexansäuren aus den bei der Herstellung von Pentanalen anfallenden Nebenströmen |
| CN105498841A (zh) * | 2015-12-15 | 2016-04-20 | 上海华谊（集团）公司 | 含双膦配体的络合催化剂 |
| CN105413747A (zh) * | 2015-12-15 | 2016-03-23 | 上海华谊（集团）公司 | 含单膦配体的络合催化剂 |
| CN105363493A (zh) * | 2015-12-15 | 2016-03-02 | 上海华谊（集团）公司 | 提高烯烃氢甲酰化催化剂存储稳定性的方法 |
| ES2746318T3 (es) * | 2016-11-08 | 2020-03-05 | Evonik Operations Gmbh | Bisfosfitos con unidades 2,4-terc-butilfenilo y su empleo como ligandos en la hidroformilación |
| SE1730036A1 (en) * | 2017-02-09 | 2018-08-10 | Perstorp Ab | Carbonylation process and ligand composition |
| US11098163B2 (en) | 2017-06-26 | 2021-08-24 | Dow Silicones Corporation | Method for hydrosilylation of aliphatically unsaturated alkoxysilanes and hydrogen terminated organosiloxane oligomers to prepare alkoxysilyl terminated polymers useful for functionalizing polyorganosiloxanes using a rhodium catalyst |
| US10968317B2 (en) | 2017-06-26 | 2021-04-06 | Dow Silicones Corporation | Method for hydrosilylation of aliphatically unsaturated alkoxysilanes and hydrogen terminated organosiloxane oligomers to prepare alkoxysilyl terminated polymers useful for functionalizing polyorganosiloxanes using an iridium catalyst |
| WO2019005713A1 (en) | 2017-06-26 | 2019-01-03 | Dow Silicones Corporation | METHOD FOR HYDROSILYLATION OF ALIPHATICALLY UNSATURATED ALCOXYSILANES AND HYDROGEN-TERMINATING ORGANOSILOXANE OLIGOMERS FOR PREPARING ALCOXYSILYL-TERMINATED POLYMERS USEFUL FOR FUNCTIONALIZING POLYORGANOSILOXANES USING A COBALT CATALYST |
| MY207749A (en) * | 2018-05-30 | 2025-03-16 | Dow Technology Investments Llc | Catalyst composition comprising the combination of a monophopsphine, a tetraphosphine ligand and a hydroformylation process using it |
| CN120271422A (zh) * | 2018-05-30 | 2025-07-08 | 陶氏技术投资有限责任公司 | 在加氢甲酰化过程中减缓催化剂失活和/或减缓四膦配位体使用的方法 |
| CN111138493A (zh) * | 2020-01-13 | 2020-05-12 | 上海华谊（集团）公司 | 一种合成双亚磷酸酯的方法 |
| GB202213997D0 (en) | 2022-09-26 | 2022-11-09 | Johnson Matthey Davy Technologies Ltd | Parallel zone hydroformylation reaction |
| CN115999643B (zh) * | 2023-01-09 | 2024-07-19 | 中国海洋石油集团有限公司 | 一种油溶性纳米催化剂及其制备方法和用途 |
| GB202303617D0 (en) | 2023-03-13 | 2023-04-26 | Johnson Matthey Davy Technologies Ltd | Method and apparatus for producing aldehyde |
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2009
- 2009-12-10 EP EP09795616.3A patent/EP2414314B1/en active Active
- 2009-12-10 KR KR1020117025674A patent/KR101706797B1/ko active Active
- 2009-12-10 CA CA2756936A patent/CA2756936A1/en not_active Abandoned
- 2009-12-10 WO PCT/US2009/067416 patent/WO2010117391A1/en not_active Ceased
- 2009-12-10 JP JP2012503408A patent/JP5603407B2/ja active Active
- 2009-12-10 MX MX2011010379A patent/MX2011010379A/es active IP Right Grant
- 2009-12-10 CN CN200980158418.2A patent/CN102365258B/zh active Active
- 2009-12-10 US US13/260,572 patent/US8513469B2/en active Active
- 2009-12-10 RU RU2011143929/04A patent/RU2541537C2/ru active
- 2009-12-10 MY MYPI2011004634A patent/MY158433A/en unknown
- 2009-12-10 PL PL09795616T patent/PL2414314T3/pl unknown
- 2009-12-15 TW TW098142834A patent/TWI504586B/zh active
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Also Published As
| Publication number | Publication date |
|---|---|
| JP5603407B2 (ja) | 2014-10-08 |
| CA2756936A1 (en) | 2010-10-14 |
| RU2011143929A (ru) | 2013-05-10 |
| CN102365258A (zh) | 2012-02-29 |
| CN102365258B (zh) | 2014-09-10 |
| US20120029242A1 (en) | 2012-02-02 |
| KR101706797B1 (ko) | 2017-02-15 |
| JP2012522048A (ja) | 2012-09-20 |
| TW201035033A (en) | 2010-10-01 |
| MY158433A (en) | 2016-10-14 |
| ZA201107180B (en) | 2012-12-27 |
| KR20110134930A (ko) | 2011-12-15 |
| WO2010117391A1 (en) | 2010-10-14 |
| EP2414314B1 (en) | 2017-09-13 |
| RU2541537C2 (ru) | 2015-02-20 |
| EP2414314A1 (en) | 2012-02-08 |
| PL2414314T3 (pl) | 2018-02-28 |
| MX2011010379A (es) | 2011-10-17 |
| US8513469B2 (en) | 2013-08-20 |
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