SE1730036A1 - Carbonylation process and ligand composition - Google Patents

Carbonylation process and ligand composition

Info

Publication number
SE1730036A1
SE1730036A1 SE1730036A SE1730036A SE1730036A1 SE 1730036 A1 SE1730036 A1 SE 1730036A1 SE 1730036 A SE1730036 A SE 1730036A SE 1730036 A SE1730036 A SE 1730036A SE 1730036 A1 SE1730036 A1 SE 1730036A1
Authority
SE
Sweden
Prior art keywords
ligand
carbonylation process
sacrificial
formula
ligand composition
Prior art date
Application number
SE1730036A
Inventor
Munslow Ian
Kangas Matias
Original Assignee
Perstorp Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Perstorp Ab filed Critical Perstorp Ab
Priority to SE1730036A priority Critical patent/SE1730036A1/en
Priority to PCT/SE2018/050120 priority patent/WO2018147793A1/en
Priority to CN201880011061.4A priority patent/CN110267936A/en
Publication of SE1730036A1 publication Critical patent/SE1730036A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/86—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/06—Formation or introduction of functional groups containing oxygen of carbonyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0073—Rhodium compounds

Abstract

Disclosed is a carbonylation process comprising subjecting at least one olefin to hydroformylation in presence of a syngas, comprising carbon monoxide and hydrogen, at least one Group VIII transition metal catalyst or catalyst precursor and at least one phosphite ligand of Formula (1)and at least one sacrificial ligand selected from the group consisting of tertiary phosphines, such as triaryl phosphines, dicycloaikylarylphosphines and/or cycloalkyldiarylphosphines. In a further aspect the present invention refers to a ligand mixture comprising at least one phosphite ligand of Formula (I) and at least one said sacrificial ligand.
SE1730036A 2017-02-09 2017-02-09 Carbonylation process and ligand composition SE1730036A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
SE1730036A SE1730036A1 (en) 2017-02-09 2017-02-09 Carbonylation process and ligand composition
PCT/SE2018/050120 WO2018147793A1 (en) 2017-02-09 2018-02-09 Carbonylation process and ligand composition comprising a bidentate phosphite ligand and a tertiary phosphine anti-oxidant
CN201880011061.4A CN110267936A (en) 2017-02-09 2018-02-09 Carbonylation method and ligand combination object comprising bidentate phosphite ester ligand and tertiary phosphine antioxidant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SE1730036A SE1730036A1 (en) 2017-02-09 2017-02-09 Carbonylation process and ligand composition

Publications (1)

Publication Number Publication Date
SE1730036A1 true SE1730036A1 (en) 2018-08-10

Family

ID=63107833

Family Applications (1)

Application Number Title Priority Date Filing Date
SE1730036A SE1730036A1 (en) 2017-02-09 2017-02-09 Carbonylation process and ligand composition

Country Status (3)

Country Link
CN (1) CN110267936A (en)
SE (1) SE1730036A1 (en)
WO (1) WO2018147793A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111138493A (en) * 2020-01-13 2020-05-12 上海华谊（集团）公司 Method for synthesizing diphosphite
CN115850041B (en) * 2022-11-30 2024-03-01 上海簇睿低碳能源技术有限公司 Method for preparing aldehyde by olefin hydroformylation, application of phenolic antioxidant and method for improving stability of catalytic system
CN116237086B (en) * 2023-03-23 2023-11-03 中国科学院长春应用化学研究所 Efficient catalyst system for preparing methyl propionate by ethylene carbonylation based on antioxidant strategy

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0839787A1 (en) * 1996-11-04 1998-05-06 Dsm N.V. Process for the preparation of an aldehyde
DE19717359B4 (en) * 1996-04-30 2014-10-30 Mitsubishi Chemical Corp. Bisphosphite compounds and process for their preparation
JP2000103797A (en) * 1998-09-29 2000-04-11 Mitsubishi Chemicals Corp Rhodium-(bidentate chelate ligand) binuclear complex
US6610891B1 (en) * 1999-12-03 2003-08-26 Mitsubishi Chemical Corporation Method of producing aldehydes
JP5364367B2 (en) * 2005-03-16 2013-12-11 ペルストルプ スペシヤルテイ ケミカルズ アーベー Hydroformylation process with improved iso-selectivity
JP5135729B2 (en) * 2006-07-26 2013-02-06 三菱化学株式会社 Method for isomerizing allyl compounds
CN1986055B (en) * 2006-12-22 2012-06-27 中国科学院上海有机化学研究所 Catalyst system and catalyzing method of propylene hydrogenation and formylation
MY158433A (en) * 2009-03-31 2016-10-14 Dow Technology Investments Llc Hydroformylation process with a doubly open-ended bisphosphite ligand
RU2584952C1 (en) * 2015-03-26 2016-05-20 Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" (ООО "РН-ЦИР") Hydride-carbonyl polyphosphite complex of rhodium with mixed organophosphorus ligands for catalysis of hydroformylation of olefins

Also Published As

Publication number Publication date
WO2018147793A1 (en) 2018-08-16
CN110267936A (en) 2019-09-20

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