TWI456352B - 圖案形成方法 - Google Patents

圖案形成方法 Download PDF

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Publication number
TWI456352B
TWI456352B TW101137316A TW101137316A TWI456352B TW I456352 B TWI456352 B TW I456352B TW 101137316 A TW101137316 A TW 101137316A TW 101137316 A TW101137316 A TW 101137316A TW I456352 B TWI456352 B TW I456352B
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group
photoresist film
forming method
pattern forming
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TW101137316A
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TW201321900A (zh
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Jun Hatakeyama
Daisuke Kori
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Shinetsu Chemical Co
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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/0045—Photosensitive materials with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/0046—Photosensitive materials with perfluoro compounds, e.g. for dry lithography
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/039—Macromolecular compounds which are photodegradable, e.g. positive electron resists
    • G03F7/0392—Macromolecular compounds which are photodegradable, e.g. positive electron resists the macromolecular compound being present in a chemically amplified positive photoresist composition
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/039—Macromolecular compounds which are photodegradable, e.g. positive electron resists
    • G03F7/0392—Macromolecular compounds which are photodegradable, e.g. positive electron resists the macromolecular compound being present in a chemically amplified positive photoresist composition
    • G03F7/0397—Macromolecular compounds which are photodegradable, e.g. positive electron resists the macromolecular compound being present in a chemically amplified positive photoresist composition the macromolecular compound having an alicyclic moiety in a side chain
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/09—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
    • G03F7/091—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers characterised by antireflection means or light filtering or absorbing means, e.g. anti-halation, contrast enhancement
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/09—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
    • G03F7/11—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers having cover layers or intermediate layers, e.g. subbing layers
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/26—Processing photosensitive materials; Apparatus therefor

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Structural Engineering (AREA)
  • Materials For Photolithography (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)

Claims (11)

  1. 一種圖案形成方法，其特徵為至少包含以下步驟：在晶圓上形成光阻膜，並於該光阻膜上使用光阻保護膜材料形成光阻保護膜，實施曝光後，實施該光阻膜之顯影；該光阻保護膜材料包含下列通式(1)所記載之含苯酚基之參茚并苯化合物； (通式(1)中，R1 、R2 、R3 為相同或不同之氫原子、羥基、羧基、氰基、硝基、胺基、鹵素原子、或碳數1~10之直鏈狀、分支狀、環狀之烷基、烷氧基、或醯氧基，且R4 、R5 、R6 各自為氫原子、羥基、或經取代或非經取代之苯酚基、或萘酚基，p、q、及r為1~5之整數，s、t、及u為1~4之整數)。
  2. 如申請專利範圍第1項之圖案形成方法，其中，該光阻保護膜材料係可溶於鹼顯影液者。
  3. 如申請專利範圍第1項之圖案形成方法，其係更包含將醇溶劑與醚溶劑或芳香族溶劑予以混合而得的有機溶劑。
  4. 如申請專利範圍第2項之圖案形成方法，其係更包含將醇溶劑與醚溶劑或芳香族溶劑予以混合而得的有機溶劑。
  5. 如申請專利範圍第1~4項中任一項之圖案形成方法，其中，該曝光係於真空中實施。
  6. 如申請專利範圍第1~4項中任一項之圖案形成方法，其中，該曝光係使用波長3~15nm之範圍之光、或電子束。
  7. 如申請專利範圍第5項中任一項圖案形成方法，其中，該曝光係使用波長3~15nm之範圍之光、或電子束。
  8. 如申請專利範圍第1~4項中任一項之圖案形成方法，其中，該顯影係使用鹼顯影液實施該光阻膜之顯影與該光阻保護膜之剝離。
  9. 如申請專利範圍第5項之圖案形成方法，其中，該顯影係使用鹼顯影液實施該光阻膜之顯影與該光阻保護膜之剝離。
  10. 如申請專利範圍第1~4項中任一項之圖案形成方法，其中，該光阻膜之形成，係在該晶圓上形成以由下列通式(2)所記載之重複單元a1、a2與下列通式(3)所記載之重複單元b1、b2構成，且平均分子量為1,000~500,000之範圍之高分子化合物作為基礎樹脂的該光阻膜； (上述通式(2)中，R7 、R9 各自獨立地表示氫原子或甲基，且R8 、R10 表示酸不穩定基；X1 表示單鍵、具有酯基、內酯環、伸苯基、或伸萘基中之任1種或2種以上之碳數1~14之連結基；X2 為單鍵、酯基、或醯胺基；該通式(3)中，R11 、R15 各自獨立地表示氫原子、氟原子、甲基、或三氟甲基，且R12 、R13 、R14 、R16 、R17 、R18 為相同或不同之碳數1~12之直鏈狀、分支狀或環狀之烷基，也可含有羰基、酯基或醚基，或表示碳數6~12之芳基、碳數7~20之芳烷基或苯硫基；Z0 為單鍵、亞甲基、伸乙基、伸苯基、經氟化的伸苯基、-O-R19 -、或-C(=O)-Z1 -R19 -；Z1 為氧原子或NH，R19 為碳數1~13之直鏈狀、分支狀或環狀之伸烷基、伸苯基或伸烯基，也可含羰基、酯基、醚基或羥基、也可經氟取代；0≦a1≦0.9、0≦a2≦0.9、0<a1+a2<1、0≦b1≦0.3、0≦b2≦0.3、0<b1+b2≦0.3、0<a1+a2+b1+b2≦1之範圍)。
  11. 如申請專利範圍第5項之圖案形成方法，其中，該光阻膜之形成，係在該晶圓上形成以由下列通式(2)所記載之重複單元a1、a2與下列通式(3)所記載之重複單元b1、b2構成，且平均分子量為1,000~500,000之範圍之高分 子化合物作為基礎樹脂的該光阻膜； (上述通式(2)中，R7 、R9 各自獨立地表示氫原子或甲基，且R8 、R10 表示酸不穩定基；X1 表示單鍵、具有酯基、內酯環、伸苯基、或伸萘基中之任1種或2種以上之碳數1~14之連結基；X2 為單鍵、酯基、或醯胺基；該通式(3)中，R11 、R15 各自獨立地表示氫原子、氟原子、甲基、或三氟甲基，且R12 、R13 、R14 、R16 、R17 、R18 為相同或不同之碳數1~12之直鏈狀、分支狀或環狀之烷基，也可含有羰基、酯基或醚基，或表示碳數6~12之芳基、碳數7~20之芳烷基或苯硫基；Z0 為單鍵、亞甲基、伸乙基、伸苯基、經氟化的伸苯基、-O-R19 -、或-C(=O)-Z1 -R19 -；Z1 為氧原子或NH，R19 為碳數1~13之直鏈狀、分支狀或環狀之伸烷基、伸苯基或伸烯基，也可含羰基、酯基、醚基或羥基、也可經氟取代；0≦a1≦0.9、0≦a2≦0.9、0<a1+a2<1、0≦b1≦0.3、0≦b2≦0.3、0<b1+b2≦0.3、0<a1+a2+b1+b2≦1之範圍)。
TW101137316A 2011-10-11 2012-10-09 圖案形成方法 TWI456352B (zh)

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US11822237B2 (en) 2020-03-30 2023-11-21 Taiwan Semiconductor Manufacturing Company, Ltd. Method of manufacturing a semiconductor device

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KR20130039299A (ko) 2013-04-19
TW201321900A (zh) 2013-06-01
US8846303B2 (en) 2014-09-30
KR101751550B1 (ko) 2017-06-27
JP2013083821A (ja) 2013-05-09
JP5650088B2 (ja) 2015-01-07
US20130089820A1 (en) 2013-04-11

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