TWI377185B - Alkali-free glasses containing iron and tin as fining agents - Google Patents
Alkali-free glasses containing iron and tin as fining agents Download PDFInfo
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- TWI377185B TWI377185B TW096142838A TW96142838A TWI377185B TW I377185 B TWI377185 B TW I377185B TW 096142838 A TW096142838 A TW 096142838A TW 96142838 A TW96142838 A TW 96142838A TW I377185 B TWI377185 B TW I377185B
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- 239000011521 glass Substances 0.000 title claims description 263
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 158
- 229910052742 iron Inorganic materials 0.000 title claims description 74
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 title claims description 30
- 239000006025 fining agent Substances 0.000 title claims description 4
- 238000000034 method Methods 0.000 claims description 51
- 239000012535 impurity Substances 0.000 claims description 36
- 238000002844 melting Methods 0.000 claims description 36
- 230000008018 melting Effects 0.000 claims description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 36
- 229910052718 tin Inorganic materials 0.000 claims description 33
- 230000008569 process Effects 0.000 claims description 28
- 239000002994 raw material Substances 0.000 claims description 28
- 229910052906 cristobalite Inorganic materials 0.000 claims description 27
- 229910052681 coesite Inorganic materials 0.000 claims description 26
- 229910052682 stishovite Inorganic materials 0.000 claims description 26
- 229910052905 tridymite Inorganic materials 0.000 claims description 26
- 238000005352 clarification Methods 0.000 claims description 22
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 21
- 229910052593 corundum Inorganic materials 0.000 claims description 21
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 21
- 229910052785 arsenic Inorganic materials 0.000 claims description 16
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 16
- -1 9.0 to 12.0 Inorganic materials 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 10
- 239000008395 clarifying agent Substances 0.000 claims description 8
- 239000006060 molten glass Substances 0.000 claims description 7
- 239000011593 sulfur Substances 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 229910052787 antimony Inorganic materials 0.000 claims description 5
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- 240000000560 Citrus x paradisi Species 0.000 claims 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 73
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 72
- 239000000395 magnesium oxide Substances 0.000 description 32
- 239000000758 substrate Substances 0.000 description 30
- 239000000203 mixture Substances 0.000 description 29
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 27
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Inorganic materials [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 description 22
- 230000007547 defect Effects 0.000 description 20
- 239000001301 oxygen Substances 0.000 description 20
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- XOLBLPGZBRYERU-UHFFFAOYSA-N SnO2 Inorganic materials O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 19
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- 230000000694 effects Effects 0.000 description 18
- 239000013078 crystal Substances 0.000 description 17
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 16
- 239000007791 liquid phase Substances 0.000 description 16
- 239000007788 liquid Substances 0.000 description 15
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- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 7
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- 239000002689 soil Substances 0.000 description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- 230000009102 absorption Effects 0.000 description 6
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- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 6
- 238000003280 down draw process Methods 0.000 description 6
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- 229910011255 B2O3 Inorganic materials 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
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- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 4
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- 229910052707 ruthenium Inorganic materials 0.000 description 4
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- 239000010409 thin film Substances 0.000 description 4
- 229910001887 tin oxide Inorganic materials 0.000 description 4
- 241001674044 Blattodea Species 0.000 description 3
- 229910052684 Cerium Inorganic materials 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 3
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- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
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- 210000003298 dental enamel Anatomy 0.000 description 2
- GWWPLLOVYSCJIO-UHFFFAOYSA-N dialuminum;calcium;disilicate Chemical compound [Al+3].[Al+3].[Ca+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] GWWPLLOVYSCJIO-UHFFFAOYSA-N 0.000 description 2
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- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- PWYYWQHXAPXYMF-UHFFFAOYSA-N strontium(2+) Chemical compound [Sr+2] PWYYWQHXAPXYMF-UHFFFAOYSA-N 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 229910052645 tectosilicate Inorganic materials 0.000 description 1
- XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910001407 tin (II) carbonate Inorganic materials 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
- 235000019786 weight gain Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/598,378 US7534734B2 (en) | 2006-11-13 | 2006-11-13 | Alkali-free glasses containing iron and tin as fining agents |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200848378A TW200848378A (en) | 2008-12-16 |
| TWI377185B true TWI377185B (en) | 2012-11-21 |
Family
ID=39111914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW096142838A TWI377185B (en) | 2006-11-13 | 2007-11-12 | Alkali-free glasses containing iron and tin as fining agents |
Country Status (7)
| Country | Link |
|---|---|
| US (3) | US7534734B2 (enExample) |
| EP (2) | EP2081875B1 (enExample) |
| JP (3) | JP4967026B2 (enExample) |
| KR (1) | KR101025374B1 (enExample) |
| CN (2) | CN102515521B (enExample) |
| TW (1) | TWI377185B (enExample) |
| WO (1) | WO2008063459A1 (enExample) |
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- 2006-11-13 US US11/598,378 patent/US7534734B2/en active Active
-
2007
- 2007-11-12 TW TW096142838A patent/TWI377185B/zh active
- 2007-11-13 KR KR1020097012285A patent/KR101025374B1/ko active Active
- 2007-11-13 EP EP07840018.1A patent/EP2081875B1/en active Active
- 2007-11-13 WO PCT/US2007/023737 patent/WO2008063459A1/en not_active Ceased
- 2007-11-13 EP EP12166903.0A patent/EP2484645B1/en active Active
- 2007-11-13 CN CN201110329039.4A patent/CN102515521B/zh active Active
- 2007-11-13 CN CN200780049762A patent/CN101626988A/zh active Pending
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| JP5909263B2 (ja) | 2016-04-26 |
| JP2011225447A (ja) | 2011-11-10 |
| JP2010509180A (ja) | 2010-03-25 |
| EP2484645B1 (en) | 2017-07-12 |
| JP5603833B2 (ja) | 2014-10-08 |
| US20100197477A1 (en) | 2010-08-05 |
| US7935649B2 (en) | 2011-05-03 |
| KR101025374B1 (ko) | 2011-03-28 |
| KR20090085105A (ko) | 2009-08-06 |
| CN101626988A (zh) | 2010-01-13 |
| CN102515521A (zh) | 2012-06-27 |
| JP4967026B2 (ja) | 2012-07-04 |
| EP2484645A3 (en) | 2013-11-13 |
| EP2081875B1 (en) | 2014-10-01 |
| TW200848378A (en) | 2008-12-16 |
| EP2081875A1 (en) | 2009-07-29 |
| JP2015027942A (ja) | 2015-02-12 |
| US20090133441A1 (en) | 2009-05-28 |
| EP2484645A2 (en) | 2012-08-08 |
| WO2008063459A1 (en) | 2008-05-29 |
| CN102515521B (zh) | 2015-02-04 |
| US7696113B2 (en) | 2010-04-13 |
| US20080110208A1 (en) | 2008-05-15 |
| US7534734B2 (en) | 2009-05-19 |
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