TWI307705B - Flame-resistant polycarbonate moulding compositions - Google Patents
Flame-resistant polycarbonate moulding compositions Download PDFInfo
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- TWI307705B TWI307705B TW090104286A TW90104286A TWI307705B TW I307705 B TWI307705 B TW I307705B TW 090104286 A TW090104286 A TW 090104286A TW 90104286 A TW90104286 A TW 90104286A TW I307705 B TWI307705 B TW I307705B
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- 239000000203 mixture Substances 0.000 title claims description 89
- 238000000465 moulding Methods 0.000 title claims description 34
- 239000004417 polycarbonate Substances 0.000 title claims description 27
- 229920000515 polycarbonate Polymers 0.000 title claims description 26
- -1 polyoxyethylene Polymers 0.000 claims description 29
- 125000003118 aryl group Chemical group 0.000 claims description 28
- 229910010272 inorganic material Inorganic materials 0.000 claims description 22
- 239000000178 monomer Substances 0.000 claims description 20
- 239000011147 inorganic material Substances 0.000 claims description 19
- 229920000578 graft copolymer Polymers 0.000 claims description 18
- 239000000454 talc Substances 0.000 claims description 17
- 229910052623 talc Inorganic materials 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000003063 flame retardant Substances 0.000 claims description 11
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 10
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 9
- 229910052731 fluorine Inorganic materials 0.000 claims description 9
- 239000011737 fluorine Substances 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 238000012360 testing method Methods 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 8
- 229920001971 elastomer Polymers 0.000 claims description 7
- 229920000098 polyolefin Polymers 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 239000005060 rubber Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 238000004945 emulsification Methods 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 230000009477 glass transition Effects 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
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- 239000004609 Impact Modifier Substances 0.000 claims description 2
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- 150000001993 dienes Chemical class 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 229910052740 iodine Inorganic materials 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- 239000003607 modifier Substances 0.000 claims 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- 239000011630 iodine Substances 0.000 claims 1
- 239000006082 mold release agent Substances 0.000 claims 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 20
- 230000000875 corresponding effect Effects 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000004615 ingredient Substances 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 12
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 11
- 229920000728 polyester Polymers 0.000 description 11
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 10
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 10
- 229920006362 Teflon® Polymers 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 10
- 239000004809 Teflon Substances 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 8
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- 239000000243 solution Substances 0.000 description 8
- 239000000052 vinegar Substances 0.000 description 8
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- 229910019142 PO4 Inorganic materials 0.000 description 7
- KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 7
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 7
- 235000021317 phosphate Nutrition 0.000 description 7
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
- 229920002842 oligophosphate Polymers 0.000 description 6
- 229920001169 thermoplastic Polymers 0.000 description 6
- 239000004416 thermosoftening plastic Substances 0.000 description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229920007019 PC/ABS Polymers 0.000 description 4
- 239000006085 branching agent Substances 0.000 description 4
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 4
- 229920003244 diene elastomer Polymers 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 150000002825 nitriles Chemical class 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 4
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Polymers OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 4
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000005907 alkyl ester group Chemical group 0.000 description 3
- 150000008064 anhydrides Chemical class 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 239000004305 biphenyl Substances 0.000 description 3
- 238000012662 bulk polymerization Methods 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 229910052681 coesite Inorganic materials 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000002079 cooperative effect Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 230000009970 fire resistant effect Effects 0.000 description 3
- 238000004128 high performance liquid chromatography Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 150000002484 inorganic compounds Chemical class 0.000 description 3
- 150000002923 oximes Chemical class 0.000 description 3
- 229960003742 phenol Drugs 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920002959 polymer blend Polymers 0.000 description 3
- 229910052682 stishovite Inorganic materials 0.000 description 3
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- 229910052905 tridymite Inorganic materials 0.000 description 3
- 238000005199 ultracentrifugation Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 2
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
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- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
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- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
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- 238000000149 argon plasma sintering Methods 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
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- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
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- 239000002734 clay mineral Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
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- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
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- WVAFEFUPWRPQSY-UHFFFAOYSA-N 1,2,3-tris(ethenyl)benzene Chemical compound C=CC1=CC=CC(C=C)=C1C=C WVAFEFUPWRPQSY-UHFFFAOYSA-N 0.000 description 1
- QTPLEVOKSWEYAC-UHFFFAOYSA-N 1,2-diphenyl-9h-fluorene Chemical compound C=1C=CC=CC=1C1=C2CC3=CC=CC=C3C2=CC=C1C1=CC=CC=C1 QTPLEVOKSWEYAC-UHFFFAOYSA-N 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- XFZWGVNJWFVDPX-UHFFFAOYSA-N 1-[decoxy(methyl)phosphoryl]oxydecane Chemical compound CCCCCCCCCCOP(C)(=O)OCCCCCCCCCC XFZWGVNJWFVDPX-UHFFFAOYSA-N 0.000 description 1
- RMSGQZDGSZOJMU-UHFFFAOYSA-N 1-butyl-2-phenylbenzene Chemical group CCCCC1=CC=CC=C1C1=CC=CC=C1 RMSGQZDGSZOJMU-UHFFFAOYSA-N 0.000 description 1
- ZNJOCVLVYVOUGB-UHFFFAOYSA-N 1-iodooctadecane Chemical compound CCCCCCCCCCCCCCCCCCI ZNJOCVLVYVOUGB-UHFFFAOYSA-N 0.000 description 1
- LENBTPHYHQHCSR-UHFFFAOYSA-N 1-phenylethenethiol Chemical compound SC(=C)C1=CC=CC=C1 LENBTPHYHQHCSR-UHFFFAOYSA-N 0.000 description 1
- KAIRTVANLJFYQS-UHFFFAOYSA-N 2-(3,5-dimethylheptyl)phenol Chemical compound CCC(C)CC(C)CCC1=CC=CC=C1O KAIRTVANLJFYQS-UHFFFAOYSA-N 0.000 description 1
- LCROLLMFVYHCEN-UHFFFAOYSA-N 2-[2-(2-hydroxyphenyl)hydrazinyl]phenol Chemical compound OC1=CC=CC=C1NNC1=CC=CC=C1O LCROLLMFVYHCEN-UHFFFAOYSA-N 0.000 description 1
- NPSJHQMIVNJLNN-UHFFFAOYSA-N 2-ethylhexyl 4-nitrobenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=C([N+]([O-])=O)C=C1 NPSJHQMIVNJLNN-UHFFFAOYSA-N 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
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- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
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- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L85/02—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers containing phosphorus
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10010941A DE10010941A1 (de) | 2000-03-06 | 2000-03-06 | Flammwidrige Polycarbonat-Formmassen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TWI307705B true TWI307705B (en) | 2009-03-21 |
Family
ID=7633745
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW090104286A TWI307705B (en) | 2000-03-06 | 2001-02-26 | Flame-resistant polycarbonate moulding compositions |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6828366B2 (enExample) |
| EP (1) | EP1268648B1 (enExample) |
| JP (1) | JP4780890B2 (enExample) |
| KR (1) | KR100729334B1 (enExample) |
| CN (2) | CN1408008A (enExample) |
| AR (1) | AR033667A1 (enExample) |
| AT (1) | ATE304034T1 (enExample) |
| AU (1) | AU2001240640A1 (enExample) |
| BR (1) | BR0109041B1 (enExample) |
| CA (1) | CA2401785C (enExample) |
| DE (2) | DE10010941A1 (enExample) |
| ES (1) | ES2244590T3 (enExample) |
| MX (1) | MXPA02008701A (enExample) |
| TW (1) | TWI307705B (enExample) |
| WO (1) | WO2001066635A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI745364B (zh) * | 2016-03-23 | 2021-11-11 | 德商科思創德意志股份有限公司 | 具改良之耐水解性之聚碳酸酯組成物 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9807180D0 (en) | 1998-04-04 | 1998-06-03 | Ecc Int Ltd | Pigment products |
| AU759343B2 (en) | 1999-04-01 | 2003-04-10 | Imerys Pigments, Inc. | Kaolin pigments, their preparation and use |
| BR0009522A (pt) | 1999-04-01 | 2002-01-15 | Imerys Pigments Inc | Produto, composição de revestimento, e, métodos para revestir uma folha de papel e calandrar o papel para formar sobre ele um revestimento de lustro, e para produzir um produto de pigmento |
| US6554892B1 (en) | 1999-07-02 | 2003-04-29 | Imerys Kaolin, Inc. | Compositions and methods for making a coarse platey, high brightness kaolin product |
| DE10036057A1 (de) * | 2000-07-25 | 2002-02-07 | Bayer Ag | Flammwidrige Polycarbonat-Zusammensetzungen |
| GB0020182D0 (en) | 2000-08-17 | 2000-10-04 | Imerys Minerals Ltd | Particulate kaolin |
| GB0020179D0 (en) | 2000-08-17 | 2000-10-04 | Imerys Minerals Ltd | Kaolin products and their use |
| GB0020180D0 (en) | 2000-08-17 | 2000-10-04 | Imerys Minerals Ltd | Kaolin products and their production |
| US20030085012A1 (en) | 2001-09-07 | 2003-05-08 | Jones J Philip E | Hyperplaty clays and their use in paper coating and filling, methods for making same, and paper products having improved brightness |
| DE10152318A1 (de) | 2001-10-26 | 2003-05-08 | Bayer Ag | Schlagzähmodifizierte flammwidrig ausgerüstete Polycarbonat-Formmassen |
| US6808559B2 (en) | 2002-02-26 | 2004-10-26 | Imerys Pigments, Inc. | Kaolin clay pigments suited to rotogravure printing applications and method for preparing the same |
| US7294399B2 (en) * | 2002-04-02 | 2007-11-13 | Arkema France | Weather-resistant, high-impact strength acrylic compositions |
| JP2008516695A (ja) * | 2004-10-18 | 2008-05-22 | ナノスケール マテリアルズ アイエヌシー． | 煙除去および火災鎮静用の金属酸化物ナノ粒子 |
| US7446144B2 (en) | 2005-09-14 | 2008-11-04 | Bayer Materialscience Llc | Thermoplastic molding composition and articles thermoformed therefrom |
| WO2007106380A2 (en) * | 2006-03-10 | 2007-09-20 | E. I. Du Pont De Nemours And Company | Apparatus having improved wear-resistant properties |
| DE102006012988A1 (de) * | 2006-03-22 | 2007-09-27 | Bayer Materialscience Ag | Flammgeschützte schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
| DE102006012990A1 (de) * | 2006-03-22 | 2007-09-27 | Bayer Materialscience Ag | Flammgeschützte schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
| US8871858B2 (en) * | 2006-05-31 | 2014-10-28 | Sabic Global Technologies B.V. | Thermoplastic polycarbonate compositions |
| US20090215949A1 (en) * | 2008-02-21 | 2009-08-27 | Sabic Innovative Plastics Ip B.V. | Flame retardant polycarbonate compositions |
| ES2459500T3 (es) * | 2008-08-06 | 2014-05-09 | Styron Europe Gmbh | Composición de polímero de carbonato resistente a la ignición |
| RU2414492C2 (ru) * | 2008-10-07 | 2011-03-20 | Федеральное Государственное Унитарное Предприятие "Центральный Научно-Исследовательский Институт Конструкционных Материалов "Прометей" (Фгуп "Цнии Км "Прометей") | Полимерный нанокомпозит и способ его получения |
| DE102009014878A1 (de) * | 2009-03-25 | 2010-09-30 | Bayer Materialscience Ag | Flammgeschützte schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
| KR101104050B1 (ko) * | 2009-08-12 | 2012-01-09 | 삼성중공업 주식회사 | 보강형 방파제 |
| KR101104030B1 (ko) * | 2009-08-12 | 2012-01-06 | 삼성중공업 주식회사 | 부유식 방파제 |
| WO2011133228A2 (en) | 2010-04-23 | 2011-10-27 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| EP2632849A4 (en) | 2010-10-27 | 2014-12-31 | Pixelligent Technologies Llc | SYNTHESIS, COVERAGE AND DISPERSION OF NANOCRYSTALLES |
| US9359689B2 (en) | 2011-10-26 | 2016-06-07 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| CN103804874A (zh) * | 2012-11-15 | 2014-05-21 | 常熟市沈氏塑业有限公司 | Abs改性聚碳酸酯的制备方法 |
| US10017640B2 (en) * | 2013-03-08 | 2018-07-10 | Covestro Llc | Halogen free flame retarded polycarbonate |
| US9732220B2 (en) * | 2013-03-13 | 2017-08-15 | Covestro Llc | Polymers and polymer blends with enhanced gloss level |
| CN104151803A (zh) * | 2013-05-14 | 2014-11-19 | 常熟市沈氏塑业有限公司 | Abs改性的聚碳酸酯合金材料的制备方法 |
| CN103589297B (zh) * | 2013-10-24 | 2016-10-05 | 中科院广州化学有限公司 | 一种含端乙烯基氟硅接枝共聚物光固化复合涂料及制备方法 |
| KR102029355B1 (ko) * | 2016-12-14 | 2019-10-07 | 롯데첨단소재(주) | 전기적 특성이 우수한 열가소성 수지 조성물 및 이를 이용하여 제조된 성형품 |
| KR102041596B1 (ko) | 2016-12-21 | 2019-11-06 | 롯데첨단소재(주) | 전기적 특성이 우수한 열가소성 수지 조성물 및 이를 이용하여 제조된 성형품 |
| EP3697847A1 (de) * | 2017-10-16 | 2020-08-26 | Covestro Deutschland AG | Flammwidrige, füllstoff-verstärkte polycarbonat-zusammensetzung mit geringem bisphenol-a gehalt |
| KR20200059242A (ko) * | 2017-10-16 | 2020-05-28 | 코베스트로 도이칠란트 아게 | 감소된 비스페놀-a 함량을 갖는 난연성 폴리카르보네이트 조성물 |
| WO2019076493A1 (de) * | 2017-10-16 | 2019-04-25 | Covestro Deutschland Ag | Flammwidrige polycarbonat-acrylat-kautschuk-zusammensetzung mit geringem bisphenol-a-gehalt |
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| DE3819081A1 (de) * | 1988-06-04 | 1989-12-07 | Bayer Ag | Flammwidrige, schlagzaehe polycarbonat-formmassen |
| NL8802346A (nl) * | 1988-09-22 | 1990-04-17 | Gen Electric | Polymeermengsel met aromatisch polycarbonaat, styreen bevattend copolymeer en/of entpolymeer en een vlamvertragend middel, daaruit gevormde voorwerpen. |
| US5204394A (en) | 1988-09-22 | 1993-04-20 | General Electric Company | Polymer mixture having aromatic polycarbonate, styrene I containing copolymer and/or graft polymer and a flame-retardant, articles formed therefrom |
| US5091461A (en) | 1989-04-07 | 1992-02-25 | The Dow Chemical Company | Filled polymeric blend |
| DE4328656A1 (de) | 1993-08-26 | 1995-03-02 | Bayer Ag | Flammwidrige, spannungsrißbeständige Polycarbonat-ABS-Formmassen |
| JPH07278318A (ja) * | 1994-04-08 | 1995-10-24 | Asahi Chem Ind Co Ltd | 難燃性ｃｄ−ｒｏｍ帰属部品 |
| JP3128187B2 (ja) * | 1995-03-02 | 2001-01-29 | 出光石油化学株式会社 | 難燃性ポリカーボネート樹脂組成物 |
| JPH08319406A (ja) * | 1995-05-26 | 1996-12-03 | Kanegafuchi Chem Ind Co Ltd | 難燃性樹脂組成物 |
| DE19530200A1 (de) * | 1995-08-17 | 1997-02-20 | Bayer Ag | Feinstteilige anorganische Pulver als Flammschutzmittel in thermoplastischen Formmassen |
| JPH0995610A (ja) * | 1995-09-30 | 1997-04-08 | Nippon G Ii Plast Kk | 難燃樹脂組成物 |
| DE19538892A1 (de) * | 1995-10-19 | 1997-04-24 | Bayer Ag | Flammgeschützte, spannungsrißbeständige Polycarbonat/ABS-Blends |
| JP3396485B2 (ja) * | 1996-02-29 | 2003-04-14 | 鐘淵化学工業株式会社 | 難燃性熱可塑性樹脂組成物 |
| AT404835B (de) * | 1996-03-05 | 1999-03-25 | Danubia Petrochem Polymere | Zur herstellung lackierbarer teile geeignete glasmattenverstärkte thermoplasten und daraus hergestellte teile |
| US5864004A (en) * | 1997-03-27 | 1999-01-26 | Samyang Corporation | Flame retardant polymer resin composition having improved heat distortion temperature and mechanical properties |
| DE19713509A1 (de) * | 1997-04-01 | 1998-10-08 | Bayer Ag | Pfropfpolymerisat-Formmassen mit reduzierter Belagsbildung |
| DE19734661A1 (de) * | 1997-08-11 | 1999-02-18 | Bayer Ag | Flammwidrige, spannungsrißbeständige Polycarbonat ABS-Formmassen |
| US6613820B2 (en) * | 1997-08-29 | 2003-09-02 | General Electric Company | Polycarbonate resin composition |
| GB9719929D0 (en) * | 1997-09-18 | 1997-11-19 | Kobe Steel Europ Ltd | Flame retardant polycarbonate-styrene(or acrylate)polymers,and/or copolymers and/or graft polymer/copolymer mixtures |
| DE19801198A1 (de) | 1998-01-15 | 1999-07-22 | Bayer Ag | Flammwidrige Polycarbonat-ABS-Formmassen |
| EP0933396A3 (en) * | 1998-01-28 | 1999-12-15 | General Electric Company | Flame retardant polycarbonate resin/abs graft copolymer blends |
| JP2002504611A (ja) | 1998-02-27 | 2002-02-12 | ゼネラル・エレクトリック・カンパニイ | 難燃性ポリマーブレンド |
| EP1076675A1 (en) | 1998-05-01 | 2001-02-21 | General Electric Company | Flame retardant polycarbonate/rubber-modified graft copolymer resin blends having a low fluorine content |
| JP3616792B2 (ja) * | 1998-10-16 | 2005-02-02 | 出光興産株式会社 | 難燃性熱可塑性樹脂組成物および射出成形品 |
| TW483921B (en) | 1998-10-16 | 2002-04-21 | Idemitsu Petrochemical Co | Flame-retardant thermoplastic resin composition |
| DE19914139A1 (de) | 1999-03-27 | 2000-09-28 | Bayer Ag | Flammwidrige, schlagzähmodifizierte Polycarbonat-Formmassen |
-
2000
- 2000-03-06 DE DE10010941A patent/DE10010941A1/de not_active Withdrawn
-
2001
- 2001-02-21 CA CA2401785A patent/CA2401785C/en not_active Expired - Fee Related
- 2001-02-21 EP EP01911668A patent/EP1268648B1/de not_active Expired - Lifetime
- 2001-02-21 JP JP2001565798A patent/JP4780890B2/ja not_active Expired - Fee Related
- 2001-02-21 KR KR1020027011641A patent/KR100729334B1/ko not_active Expired - Lifetime
- 2001-02-21 CN CN01805975A patent/CN1408008A/zh active Pending
- 2001-02-21 AU AU2001240640A patent/AU2001240640A1/en not_active Abandoned
- 2001-02-21 CN CN2007101482016A patent/CN101117434B/zh not_active Ceased
- 2001-02-21 AT AT01911668T patent/ATE304034T1/de not_active IP Right Cessation
- 2001-02-21 DE DE50107364T patent/DE50107364D1/de not_active Expired - Lifetime
- 2001-02-21 MX MXPA02008701A patent/MXPA02008701A/es active IP Right Grant
- 2001-02-21 US US10/220,646 patent/US6828366B2/en not_active Expired - Lifetime
- 2001-02-21 ES ES01911668T patent/ES2244590T3/es not_active Expired - Lifetime
- 2001-02-21 BR BRPI0109041-0A patent/BR0109041B1/pt not_active IP Right Cessation
- 2001-02-21 WO PCT/EP2001/001925 patent/WO2001066635A1/de not_active Ceased
- 2001-02-26 TW TW090104286A patent/TWI307705B/zh not_active IP Right Cessation
- 2001-02-26 AR ARP010100859A patent/AR033667A1/es unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI745364B (zh) * | 2016-03-23 | 2021-11-11 | 德商科思創德意志股份有限公司 | 具改良之耐水解性之聚碳酸酯組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2244590T3 (es) | 2005-12-16 |
| ATE304034T1 (de) | 2005-09-15 |
| EP1268648A1 (de) | 2003-01-02 |
| AR033667A1 (es) | 2004-01-07 |
| AU2001240640A1 (en) | 2001-09-17 |
| WO2001066635A1 (de) | 2001-09-13 |
| CN101117434A (zh) | 2008-02-06 |
| CA2401785C (en) | 2010-08-24 |
| KR100729334B1 (ko) | 2007-06-18 |
| KR20020079944A (ko) | 2002-10-19 |
| BR0109041A (pt) | 2003-06-03 |
| MXPA02008701A (es) | 2003-04-14 |
| CA2401785A1 (en) | 2001-09-13 |
| CN1408008A (zh) | 2003-04-02 |
| US20030105196A1 (en) | 2003-06-05 |
| DE10010941A1 (de) | 2001-09-13 |
| EP1268648B1 (de) | 2005-09-07 |
| JP2003526718A (ja) | 2003-09-09 |
| CN101117434B (zh) | 2012-09-05 |
| DE50107364D1 (de) | 2005-10-13 |
| US6828366B2 (en) | 2004-12-07 |
| JP4780890B2 (ja) | 2011-09-28 |
| BR0109041B1 (pt) | 2011-11-16 |
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Legal Events
| Date | Code | Title | Description |
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| MM4A | Annulment or lapse of patent due to non-payment of fees |