TW477803B - Stabilization of phenol-free polyolefin fibres - Google Patents

Info

Publication number

TW477803B

TW477803B TW086109364A TW86109364A TW477803B TW 477803 B TW477803 B TW 477803B TW 086109364 A TW086109364 A TW 086109364A TW 86109364 A TW86109364 A TW 86109364A TW 477803 B TW477803 B TW 477803B

Authority

TW

Taiwan

Prior art keywords

cns

page

alkyl

please read

ministry

Prior art date

1996-07-05

Links

• Espacenet
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• 229920000098 polyolefin Polymers 0.000 title claims description 39
• 230000006641 stabilisation Effects 0.000 title description 6
• 238000011105 stabilization Methods 0.000 title description 6
• 150000001875 compounds Chemical class 0.000 claims abstract description 159
• 239000003381 stabilizer Substances 0.000 claims abstract description 51
• 230000015556 catabolic process Effects 0.000 claims abstract description 18
• 238000006731 degradation reaction Methods 0.000 claims abstract description 18
• 238000011049 filling Methods 0.000 claims description 132
• 239000000203 mixture Substances 0.000 claims description 101
• 125000000217 alkyl group Chemical group 0.000 claims description 98
• 239000001257 hydrogen Substances 0.000 claims description 84
• 229910052739 hydrogen Inorganic materials 0.000 claims description 84
• 230000002079 cooperative effect Effects 0.000 claims description 70
• 125000004432 carbon atom Chemical group C* 0.000 claims description 61
• 229910052760 oxygen Inorganic materials 0.000 claims description 39
• 239000001301 oxygen Substances 0.000 claims description 39
• 239000000126 substance Substances 0.000 claims description 39
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 38
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 34
• 239000004615 ingredient Substances 0.000 claims description 28
• 125000003545 alkoxy group Chemical group 0.000 claims description 23
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 18
• NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims description 16
• 239000000654 additive Substances 0.000 claims description 15
• 238000000034 method Methods 0.000 claims description 14
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 13
• 230000003647 oxidation Effects 0.000 claims description 12
• 238000007254 oxidation reaction Methods 0.000 claims description 12
• 230000000087 stabilizing effect Effects 0.000 claims description 4
• 150000003839 salts Chemical class 0.000 claims description 3
• OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 2
• 150000002431 hydrogen Chemical class 0.000 claims 3
• 101100515517 Arabidopsis thaliana XI-I gene Proteins 0.000 claims 1
• 238000006757 chemical reactions by type Methods 0.000 claims 1
• 235000021419 vinegar Nutrition 0.000 claims 1
• 239000000052 vinegar Substances 0.000 claims 1
• 150000001412 amines Chemical class 0.000 abstract description 29
• 239000011368 organic material Substances 0.000 abstract description 7
• ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical compound C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 abstract description 4
• 230000001590 oxidative effect Effects 0.000 abstract 1
• -1 sulfonic acid ester compounds Chemical class 0.000 description 436
• 239000000835 fiber Substances 0.000 description 61
• 125000004435 hydrogen atom Chemical class [H]* 0.000 description 48
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 41
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 41
• 229910052799 carbon Inorganic materials 0.000 description 40
• 229920001577 copolymer Polymers 0.000 description 39
• 229910052717 sulfur Inorganic materials 0.000 description 38
• 239000011593 sulfur Substances 0.000 description 34
• JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 30
• 239000004743 Polypropylene Substances 0.000 description 28
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 28
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 27
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 27
• UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 26
• 229920000642 polymer Polymers 0.000 description 26
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 25
• 239000002253 acid Substances 0.000 description 23
• 229910052757 nitrogen Inorganic materials 0.000 description 23
• 239000002585 base Substances 0.000 description 22
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• 125000002947 alkylene group Chemical group 0.000 description 21
• 150000002148 esters Chemical class 0.000 description 19
• 238000012545 processing Methods 0.000 description 19
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• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
• 125000003118 aryl group Chemical group 0.000 description 18
• 125000001797 benzyl group Chemical class [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 18
• 239000000155 melt Substances 0.000 description 18
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• 125000003342 alkenyl group Chemical group 0.000 description 17
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 17
• 229910052740 iodine Inorganic materials 0.000 description 17
• 229920001155 polypropylene Polymers 0.000 description 17
• 238000012360 testing method Methods 0.000 description 16
• 239000003795 chemical substances by application Substances 0.000 description 15
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• 229920000768 polyamine Polymers 0.000 description 15
• 239000005977 Ethylene Substances 0.000 description 14
• ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 14
• 125000000753 cycloalkyl group Chemical group 0.000 description 14
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• NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 12
• 239000005062 Polybutadiene Substances 0.000 description 11
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical group CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 11
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• 239000002184 metal Substances 0.000 description 11
• 229920002857 polybutadiene Polymers 0.000 description 11
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• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 11
• 238000004383 yellowing Methods 0.000 description 11
• UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 10
• 239000004305 biphenyl Substances 0.000 description 10
• DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 10
• 125000003884 phenylalkyl group Chemical group 0.000 description 10
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
• 239000007983 Tris buffer Substances 0.000 description 9
• XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 9
• ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 9
• 239000010408 film Substances 0.000 description 9
• 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 9
• 229910052736 halogen Inorganic materials 0.000 description 9
• 150000002367 halogens Chemical class 0.000 description 9
• 239000004700 high-density polyethylene Substances 0.000 description 9
• 229960003742 phenol Drugs 0.000 description 9
• 229920000570 polyether Polymers 0.000 description 9
• 229920000573 polyethylene Polymers 0.000 description 9
• 239000004814 polyurethane Substances 0.000 description 9
• 239000000047 product Substances 0.000 description 9
• 125000004076 pyridyl group Chemical group 0.000 description 9
• PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 8
• 239000004698 Polyethylene Substances 0.000 description 8
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 8
• 238000005562 fading Methods 0.000 description 8
• 229920001903 high density polyethylene Polymers 0.000 description 8
• GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
• 239000000843 powder Substances 0.000 description 8
• 150000003254 radicals Chemical class 0.000 description 8
• RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 8
• KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 7
• 239000004721 Polyphenylene oxide Substances 0.000 description 7
• XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical group NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 7
• WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 7
• 125000005605 benzo group Chemical group 0.000 description 7
• WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 7
• CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 7
• 235000013539 calcium stearate Nutrition 0.000 description 7
• 239000008116 calcium stearate Substances 0.000 description 7
• 239000003054 catalyst Substances 0.000 description 7
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• 229910052801 chlorine Inorganic materials 0.000 description 7
• 150000001993 dienes Chemical class 0.000 description 7
• 238000002845 discoloration Methods 0.000 description 7
• 125000002971 oxazolyl group Chemical group 0.000 description 7
• 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 7
• WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 7
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• 229920000728 polyester Polymers 0.000 description 7
• 229920006324 polyoxymethylene Polymers 0.000 description 7
• 229920002635 polyurethane Polymers 0.000 description 7
• 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
• 229940116351 sebacate Drugs 0.000 description 7
• CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 7
• 239000011701 zinc Substances 0.000 description 7
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• 125000001931 aliphatic group Chemical group 0.000 description 6
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