TW454030B - Reactive bis-, tris- or tetrakisazo dyes containing 2,4-diaminobenzene sulfonic acid as the bis-coupling component, their preparation and use - Google Patents
Reactive bis-, tris- or tetrakisazo dyes containing 2,4-diaminobenzene sulfonic acid as the bis-coupling component, their preparation and use Download PDFInfo
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- TW454030B TW454030B TW086100314A TW86100314A TW454030B TW 454030 B TW454030 B TW 454030B TW 086100314 A TW086100314 A TW 086100314A TW 86100314 A TW86100314 A TW 86100314A TW 454030 B TW454030 B TW 454030B
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- 239000000975 dye Substances 0.000 title claims description 49
- 238000010168 coupling process Methods 0.000 title claims description 8
- 238000005859 coupling reaction Methods 0.000 title claims description 8
- 238000002360 preparation method Methods 0.000 title claims description 6
- JVMSQRAXNZPDHF-UHFFFAOYSA-N 2,4-diaminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C(N)=C1 JVMSQRAXNZPDHF-UHFFFAOYSA-N 0.000 title description 4
- -1 1-pyridinyl Chemical group 0.000 claims abstract description 59
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims abstract description 56
- 238000004043 dyeing Methods 0.000 claims abstract description 43
- 150000001875 compounds Chemical class 0.000 claims abstract description 40
- 238000007639 printing Methods 0.000 claims abstract description 24
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 22
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 20
- 239000000985 reactive dye Substances 0.000 claims abstract description 19
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 17
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 13
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 12
- 239000000835 fiber Substances 0.000 claims abstract description 11
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims abstract description 10
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 10
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 8
- 150000002367 halogens Chemical class 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 6
- 125000005184 naphthylamino group Chemical group C1(=CC=CC2=CC=CC=C12)N* 0.000 claims abstract description 5
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims abstract description 3
- 229910004727 OSO3H Inorganic materials 0.000 claims abstract 2
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 claims abstract 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract 2
- 239000000460 chlorine Substances 0.000 claims description 31
- 238000011049 filling Methods 0.000 claims description 27
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- 125000003277 amino group Chemical group 0.000 claims description 14
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
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- 125000003282 alkyl amino group Chemical group 0.000 claims description 5
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
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- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- 230000008719 thickening Effects 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000001049 brown dye Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 125000002757 morpholinyl group Chemical group 0.000 claims description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 claims description 2
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 2
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- 239000000987 azo dye Substances 0.000 claims 2
- PCTMTFRHKVHKIS-BMFZQQSSSA-N (1s,3r,4e,6e,8e,10e,12e,14e,16e,18s,19r,20r,21s,25r,27r,30r,31r,33s,35r,37s,38r)-3-[(2r,3s,4s,5s,6r)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-19,25,27,30,31,33,35,37-octahydroxy-18,20,21-trimethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10 Chemical compound C1C=C2C[C@@H](OS(O)(=O)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2.O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C=C/C=C/C=C/[C@H](C)[C@@H](O)[C@@H](C)[C@H](C)OC(=O)C[C@H](O)C[C@H](O)CC[C@@H](O)[C@H](O)C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 PCTMTFRHKVHKIS-BMFZQQSSSA-N 0.000 claims 1
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-naphthylamine Chemical group C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 claims 1
- DJHGAFSJWGLOIV-UHFFFAOYSA-N Arsenic acid Chemical compound O[As](O)(O)=O DJHGAFSJWGLOIV-UHFFFAOYSA-N 0.000 claims 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- 101100087530 Caenorhabditis elegans rom-1 gene Proteins 0.000 claims 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical group NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims 1
- 229920003043 Cellulose fiber Polymers 0.000 claims 1
- HEFNNWSXXWATRW-UHFFFAOYSA-N Ibuprofen Chemical compound CC(C)CC1=CC=C(C(C)C(O)=O)C=C1 HEFNNWSXXWATRW-UHFFFAOYSA-N 0.000 claims 1
- 101100305983 Mus musculus Rom1 gene Proteins 0.000 claims 1
- 229910002651 NO3 Inorganic materials 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
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- 229940000488 arsenic acid Drugs 0.000 claims 1
- 235000014121 butter Nutrition 0.000 claims 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbamic acid group Chemical group C(N)(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims 1
- 210000005069 ears Anatomy 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
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- 239000000243 solution Substances 0.000 description 34
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- 125000001424 substituent group Chemical group 0.000 description 12
- 238000006467 substitution reaction Methods 0.000 description 9
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- UGEHFOSBNBEWMP-UHFFFAOYSA-N 2,3-diaminobenzenesulfonic acid Chemical compound NC1=CC=CC(S(O)(=O)=O)=C1N UGEHFOSBNBEWMP-UHFFFAOYSA-N 0.000 description 1
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- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000001755 vocal effect Effects 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000001043 yellow dye Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/002—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the linkage of the reactive group being alternatively specified
- C09B62/006—Azodyes
- C09B62/01—Disazo or polyazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/4401—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system
- C09B62/4403—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system the heterocyclic system being a triazine ring
- C09B62/4411—Azo dyes
- C09B62/4415—Disazo or polyazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
- C09B43/18—Preparation of azo dyes from other azo compounds by acylation of hydroxyl group or of mercapto group
- C09B43/24—Preparation of azo dyes from other azo compounds by acylation of hydroxyl group or of mercapto group with formation of —O—SO2—R or —O—SO3H radicals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/503—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl or mercaptoalkyl sulfonyl group, a quaternised or non-quaternised aminoalkyl sulfonyl group, a heterylmercapto alkyl sulfonyl group, a vinyl sulfonyl or a substituted vinyl sulfonyl group, or a thiophene-dioxide group
- C09B62/507—Azo dyes
- C09B62/513—Disazo or polyazo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/02—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using azo dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH15096 | 1996-01-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW454030B true TW454030B (en) | 2001-09-11 |
Family
ID=4180395
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW086100314A TW454030B (en) | 1996-01-19 | 1997-01-14 | Reactive bis-, tris- or tetrakisazo dyes containing 2,4-diaminobenzene sulfonic acid as the bis-coupling component, their preparation and use |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5817779A (enExample) |
| EP (1) | EP0785237B1 (enExample) |
| JP (1) | JP4171081B2 (enExample) |
| KR (1) | KR100433351B1 (enExample) |
| CN (1) | CN1097076C (enExample) |
| DE (1) | DE59703980D1 (enExample) |
| ES (1) | ES2159826T3 (enExample) |
| ID (1) | ID15914A (enExample) |
| MY (1) | MY117759A (enExample) |
| PT (1) | PT785237E (enExample) |
| SG (1) | SG79212A1 (enExample) |
| TW (1) | TW454030B (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG68660A1 (en) * | 1997-04-07 | 1999-11-16 | Ciba Sc Holding Ag | Mixtures of reactive dyes and their use |
| US5989298A (en) * | 1997-04-07 | 1999-11-23 | Ciba Speciality Chemicals Corporation | Mixtures of reactive dyes and their use |
| DE69903599T2 (de) | 1998-07-21 | 2003-06-12 | Dystar Textilfarben Gmbh & Co Deutschland Kg | Marineblaue Mischungen von faserreaktiven Azofarbstoffen |
| ATE316990T1 (de) * | 2001-10-12 | 2006-02-15 | Ciba Sc Holding Ag | Faserreaktive azofarbstoffe, deren herstellung und deren verwendung |
| WO2003040239A1 (en) * | 2001-11-07 | 2003-05-15 | Ciba Specialty Chemicals Holding Inc. | Fibre-reactive dyes, their preparation and their use |
| DE10212771A1 (de) * | 2002-03-22 | 2003-10-02 | Dystar Textilfarben Gmbh & Co | Wasserlösliche Mono- und Disazofarbstoffe |
| CN1918245B (zh) * | 2004-02-13 | 2010-11-03 | 西巴特殊化学品控股有限公司 | 活性染料混合物及其用途 |
| CN1317336C (zh) * | 2004-09-16 | 2007-05-23 | 明德国际仓储贸易(上海)有限公司 | 季铵盐双偶氮反应性染料及其应用 |
| CN1847324A (zh) * | 2005-04-13 | 2006-10-18 | 明德国际仓储贸易(上海)有限公司 | 纤维反应性染料 |
| CH695613A5 (de) * | 2005-06-08 | 2006-07-14 | Bezema Ag | Mischungen von schwermetallfreien faserreaktiven Farbstoffen auf der Basis von Triazo-Verbindungen, deren Herstellung und Verwendung. |
| DE102005047391A1 (de) | 2005-10-05 | 2007-04-12 | Dystar Textilfarben Gmbh & Co. Deutschland Kg | Farbstoffe und Farbstoffmischungen von faserreaktiven Azofarbstoffen, ihre Herstellung und ihre Verwendung |
| DE102006028229A1 (de) * | 2006-06-20 | 2008-01-10 | Dystar Textilfarben Gmbh & Co Deutschland Kg | Farbstoffmischungen von faserreaktiven Azofarbstoffen, ihre Herstellung und ihre Verwendung |
| DE102007005795A1 (de) | 2007-02-06 | 2008-08-07 | Dystar Textilfarben Gmbh & Co. Deutschland Kg | Mischungen von faserreaktiven Azofarbstoffen |
| CN101235216B (zh) * | 2008-01-22 | 2010-07-21 | 天津德凯化工股份有限公司 | 一种橙色活性染料及其制备方法 |
| US8349029B2 (en) | 2008-12-09 | 2013-01-08 | Dystar Colours Deutschland Gmbh | Fiber-reactive azo dyes and dye mixtures, preparation thereof and use thereof |
| DE102008054404A1 (de) | 2008-12-09 | 2010-06-10 | Dystar Textilfarben Gmbh & Co. Deutschland Kg | Faserreaktive Azofarbstoffe und Farbstoffmischungen, Verfahren zu ihrer Herstellung und ihre Verwendung |
| CN103703083A (zh) | 2011-08-04 | 2014-04-02 | 亨斯迈先进材料（瑞士）有限公司 | 活性染料的混合物及其用途 |
| CN102329522B (zh) * | 2011-09-29 | 2016-08-03 | 天津德凯化工股份有限公司 | 一种活性染料及其制备方法 |
| KR101965472B1 (ko) * | 2012-06-18 | 2019-04-03 | 다이스타 컬러스 디스트리뷰션 게엠베하 | 무금속 반응성 염료, 그의 제조 방법 및 그의 용도 |
| CN104119692A (zh) * | 2013-04-28 | 2014-10-29 | 浙江科永化工有限公司 | 一种活性橙染料化合物及其应用 |
| CN104119693A (zh) * | 2013-04-28 | 2014-10-29 | 浙江科永化工有限公司 | 一种橙色活性染料化合物及其应用 |
| CN104119694A (zh) * | 2013-04-28 | 2014-10-29 | 浙江科永化工有限公司 | 一种活性橙染料化合物及应用 |
| EP2862902A1 (en) * | 2013-08-29 | 2015-04-22 | DyStar Colours Distribution GmbH | Dye mixtures of metal free reactive dyes, production and use |
| CN105176139B (zh) * | 2015-05-26 | 2020-09-29 | 浙江龙盛集团股份有限公司 | 一种多偶氮棕色活性染料化合物及其制备方法和应用 |
| ES2901929T3 (es) * | 2018-02-16 | 2022-03-24 | Huntsman Adv Mat Switzerland | Procedimiento para la curtición y tinción simultáneas de material fibroso que contiene colágeno |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2032927C3 (de) * | 1970-07-03 | 1979-06-13 | Hoechst Ag, 6000 Frankfurt | Wasserlösliche Metallkomplex-Disazofarbstoffe, Verfahren zu ihrer Herstellung und ihre Verwendung zum Färben oder Bedrucken von Wolle, Seide, Leder, Polyamidoder Polyurethanfasern oder nativen oder regenerierten Cellulosefasern |
| KR900004223B1 (ko) * | 1987-06-10 | 1990-06-18 | 이화산업 주식회사 | 반응성 디스아조 염료의 제조방법 |
| KR940002560B1 (ko) * | 1991-04-19 | 1994-03-25 | 주식회사 경인양행 | 반응성 흑색염료 조성물 |
| TW279889B (enExample) * | 1993-10-07 | 1996-07-01 | Ciba Geigy Ag |
-
1997
- 1997-01-06 MY MYPI97000036A patent/MY117759A/en unknown
- 1997-01-10 PT PT97810011T patent/PT785237E/pt unknown
- 1997-01-10 EP EP97810011A patent/EP0785237B1/de not_active Expired - Lifetime
- 1997-01-10 DE DE59703980T patent/DE59703980D1/de not_active Expired - Lifetime
- 1997-01-10 ES ES97810011T patent/ES2159826T3/es not_active Expired - Lifetime
- 1997-01-14 JP JP00436397A patent/JP4171081B2/ja not_active Expired - Fee Related
- 1997-01-14 TW TW086100314A patent/TW454030B/zh not_active IP Right Cessation
- 1997-01-15 US US08/783,183 patent/US5817779A/en not_active Expired - Lifetime
- 1997-01-15 SG SG9700090A patent/SG79212A1/en unknown
- 1997-01-17 ID IDP970130A patent/ID15914A/id unknown
- 1997-01-17 CN CN97102273A patent/CN1097076C/zh not_active Expired - Lifetime
- 1997-01-17 KR KR1019970001207A patent/KR100433351B1/ko not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| JPH09194749A (ja) | 1997-07-29 |
| ID15914A (id) | 1997-08-21 |
| CN1097076C (zh) | 2002-12-25 |
| EP0785237B1 (de) | 2001-07-11 |
| JP4171081B2 (ja) | 2008-10-22 |
| CN1163291A (zh) | 1997-10-29 |
| ES2159826T3 (es) | 2001-10-16 |
| KR100433351B1 (ko) | 2005-09-12 |
| EP0785237A1 (de) | 1997-07-23 |
| PT785237E (pt) | 2001-12-28 |
| MY117759A (en) | 2004-08-30 |
| US5817779A (en) | 1998-10-06 |
| DE59703980D1 (de) | 2001-08-16 |
| KR970059234A (ko) | 1997-08-12 |
| SG79212A1 (en) | 2001-03-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GD4A | Issue of patent certificate for granted invention patent | ||
| MM4A | Annulment or lapse of patent due to non-payment of fees |