TW201341607A - 纖維結構、其製造方法以及纖維樹脂複合材料之用途 - Google Patents

纖維結構、其製造方法以及纖維樹脂複合材料之用途 Download PDF

Info

Publication number
TW201341607A
TW201341607A TW102103444A TW102103444A TW201341607A TW 201341607 A TW201341607 A TW 201341607A TW 102103444 A TW102103444 A TW 102103444A TW 102103444 A TW102103444 A TW 102103444A TW 201341607 A TW201341607 A TW 201341607A
Authority
TW
Taiwan
Prior art keywords
fiber
mol
copolyester
structure according
fibrous
Prior art date
Application number
TW102103444A
Other languages
English (en)
Other versions
TWI612189B (zh
Inventor
Ralf Hoppe
Original Assignee
Ems Patent Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ems Patent Ag filed Critical Ems Patent Ag
Publication of TW201341607A publication Critical patent/TW201341607A/zh
Application granted granted Critical
Publication of TWI612189B publication Critical patent/TWI612189B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C08L63/10—Epoxy resins modified by unsaturated compounds
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
    • D01F6/86—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from polyetheresters
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/40—Yarns in which fibres are united by adhesives; Impregnated yarns or threads
    • D02G3/402—Yarns in which fibres are united by adhesives; Impregnated yarns or threads the adhesive being one component of the yarn, i.e. thermoplastic yarn
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B21/14—Fabrics characterised by the incorporation by knitting, in one or more thread, fleece, or fabric layers, of reinforcing, binding, or decorative threads; Fabrics incorporating small auxiliary elements, e.g. for decorative purposes
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4209—Inorganic fibres
    • D04H1/4218—Glass fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4209—Inorganic fibres
    • D04H1/4242—Carbon fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4266—Natural fibres not provided for in group D04H1/425
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/52—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by applying or inserting filamentary binding elements
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542—Adhesive fibres
    • D04H1/544—Olefin series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/12—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with filaments or yarns secured together by chemical or thermo-activatable bonding agents, e.g. adhesives, applied or incorporated in liquid or solid form
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00—Producing multi-layer textile fabrics
    • D06M17/04—Producing multi-layer textile fabrics by applying synthetic resins as adhesives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y10T428/2967—Synthetic resin or polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y10T428/2967—Synthetic resin or polymer
    • Y10T428/2969—Polyamide, polyimide or polyester
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Reinforced Plastic Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)

Abstract

本發明係關於一種來自纖維材料以及來自用於其緊固和安定之物質之緊固及/或安定纖維結構。該緊固和安定之物質係一種結構共聚酯，其係形成自對苯二甲酸及任選的間苯二甲酸之二酸組分以及丁二醇、二乙二醇和參乙二醇之二醇組分。亦提供一種製造此纖維結構之方法。該纖維結構被用作為高分子基材，特別指環氧樹脂之強化材料。進一步提供含有至少一熱固性樹脂以及該根據本發明纖維結構之一種纖維複合材料。

Description

纖維結構、其製造方法以及纖維樹脂複合材料之用途
本發明係關於一種來自纖維材料以及來自用於其緊固和安定之物質之緊固及/或安定纖維結構。該緊固和安定之物質係一種結構共聚酯(statistical copolyester)，其係形成自對苯二甲酸及任選的間苯二甲酸之二酸組分以及丁二醇、二乙二醇和參乙二醇之二醇組分。亦提供一種製造此纖維結構之方法。該纖維結構被用作為高分子基材，特別指環氧樹脂之強化材料。進一步提供含有至少一熱固性樹脂以及該根據本發明纖維結構之一種纖維複合材料。
許多領域中需要強度、耐蝕性和低重量時經常使用製造自纖維複合材料之具有高強度質量比材料。此類纖維樹脂複合材料可因而輕易地被用於，例如航空部件。這些複合物同樣特別適用於運動用具例如網球拍或高爾夫球桿。
這些複合材料中存在同向長纖維型(unidirectional filaments)或橫向型(areal form)之加強元件，如玻纖網、梭織布或纖維非織物。
該纖絲或網格、梭織或非織物纖維必需被緊固或安定，其有助於簡化處理及容許藉由溫度或壓力接合個別表面結構或複數個這些表面結構。緊固或接合單層或多層表面結構之安定預成形同樣可藉由 溫度和壓力被控制。
然後將依此方法製造和預處理之強化材料埋入一高分子基材內。在此態樣中，強化材料和高分子基材間之黏合具有一特殊意義。
熱塑性纖維材料已為EP 1 705 269 A1所習知，其係紡成自含多羥基醚之原料。這些來自多羥基醚之纖維於埋入該高分子基材之前被用作為固定強化纖維之絲線。
此外，已知來自EP 0 698 649 A2之共聚酯熱融黏著物質，其顯示具有異常鍵結性能、低熔點、快速結晶以及對清洗和清潔具有良好抗性。
從此開始，本發明之目的係提供具有改良安定性之纖維結構。
藉由具有申請專利範圍第1項之纖維結構以及藉由其製造方法可滿足此目的。藉由具有申請專利範圍第11項特徵之纖維樹脂複合材料同樣可達到此目的。申請專利範圍第15項則說明根據本發明纖維結構之用途。
根據本發明，可從經緊固及/或安定纖維結構之纖維材料以及從其緊固和安定之物質獲得改善。
該用於緊固和安定之物質係一種根據本發明之結構共聚酯，其係形成自下列組分：從55至100莫耳%之對苯二甲酸；從0至45莫耳%之間苯二甲酸；從35至75莫耳%之丁二醇；從15至35莫耳%之二乙二醇； 從10至30莫耳%之參乙二醇。
在此態樣中，就分別為100莫耳%之總二酸和總二醇含量而言，對苯二甲酸和丁二醇之莫耳分率總和最大為150莫耳%。
該至少一種結構共聚酯較佳為形成自下列組分：從70至100莫耳%，較佳為85至100莫耳%之對苯二甲酸；從0至30莫耳%，較佳為0至15莫耳%之間苯二甲酸；從45至65莫耳%，較佳為47至57莫耳%之丁二醇；從20至30莫耳%，較佳為23至28莫耳%之二乙二醇；從15至25莫耳%，較佳為20至25莫耳%之參乙二醇。
在此態樣中，就分別為100莫耳%之總二酸和總二醇含量而言，對苯二甲酸和丁二醇之莫耳分率總和最大為150莫耳%。
在一較佳具體實施例中，該至少一種結構共聚酯可含有0至2%重量比，較佳為0.05至1%重量比特別指成核劑、安定劑、潤滑劑、消泡劑、縮合催化劑或其混合物之添加物，該共聚酯和添加物之總和為100%重量比。
按ISO/DIN 1133標準、於160℃和2.16 kg負載之下測定時，用於根據本發明之共聚酯較佳為具有範圍在100至3000 Pas，較佳為100至600 Pas，最佳為120至500 Pas以及極佳為150至300 Pas之熔融黏度。
若根據本發明共聚酯被用於定絲(fixing thread)例如纖維紗、多絲或單絲之形式，按ISO/DIN 1133標準、於160℃和2.16 kg負載之下測定時，其較佳為具有範圍在1000至3000 Pas，較佳為1500至2500 Pas，最佳為1700至2200 Pas之熔融黏度。
按ISO 11357標準、於20 K/分加熱速率之下測定時，被用 於根據本發明之共聚酯較佳為具有60℃至160℃，較佳為70℃至150℃，以及最佳為90℃至140℃區域內之熔點。
聚酯之製造較佳為根據下列合成法。
將芳香族二羧酸或二羧酸混合物分散於二醇內；加入酯化催化劑和任選適當的熱安定劑，該二醇用量超過5至50莫耳%。在緩慢加熱之下，該酯化作用發生於200℃至280℃，較佳為210℃至260℃之溫度範圍內。於此過程中濾除生成水。
接著於溫度範圍220至270℃，較佳為230至260℃及視需要於存在聚縮合催化劑(相對聚酯用量為1至100 ppm，較佳為10至45 ppm)之惰化反應釜(inertized autoclave)內進行聚縮合反應。在這一點上，逐步施予真空以及萃取過量二醇使其極限真空(end vacuum)低於1 mbar。達到所欲黏度之後，移除、粒化和乾燥所產生之聚酯。
錳、鋅、鈣、錫、鈦或鎂等具有低脂肪醇之金屬鹽，例如丁醇，可被用作為酯化催化劑。銻、鈦、錫或鍺基化合物，例如三氧化銻，可被用作為聚縮合催化劑。酯化催化劑和聚縮合催化劑均為許多技術者所習知。
纖維材料較佳為含有或實質上由同向長纖維或橫向纖維材料之織物、羊毛、針織網或針織布或不織布群組所構成。亦可能使用混合長絲和橫向纖維材料。
該纖維材料較佳為選自下列群組：‧玻璃纖維，‧碳纖維，‧礦物纖維，‧合成纖維(特別指較佳為聚酯和聚醯胺，尤指聚芳醯胺之高分子纖 維)，天然纖維，特別指綿花、羊毛、木綿(kapok)、大麻、亞麻、黃麻(jute)或木棉以及‧其混合物。
根據本發明，提供一種製造先前所述纖維結構之方法，其係藉由粉點塗層法(powder point coating)、漿點塗層法(paste point coating)或分散塗層法(scatter coating)或作為糊劑、懸浮液、薄膜、網狀物、非織造物、固定非織造物或梭織物或噴熔物施予至少一種用於緊固和安定該纖維材料之物質，接著藉由溫度及/或壓力固定該纖維結構。
或者，亦可藉由利用製造自該至少一種結構共聚酯之定絲進行縫合。在此方法中，其已可達到緊固而不需其後溫度及/或壓力之效應。
分散塗層法或施予糊劑、懸浮液、薄膜、網狀物或噴熔物或縫合法為較佳之施用方法。其中以分散塗層法、網狀物、噴熔物或縫合法之施用法為最佳。
本發明進一步態樣係關於一種纖維樹脂複合材料，其含有至少一種熱固性樹脂以及至少一種先前所述纖維結構。
該熱固性樹脂較佳為一種環氧樹脂。
已驚訝地發現用於埋入根據本發明緊固該共聚酯之高分子基材可改善其結合力。
按美國試驗材料測試標準ASTM D2344M，該纖維樹脂複合材料於溫度23℃下測定時較佳為具有至少55 MPa，最佳為至少60 MPa之層間剪切強度(ILSS)。
於按照AITM 1.0010空中巴士標準測試衝擊後壓縮強度之 測定中，根據本發明之纖維樹脂複合材料更偏好為具有至少185 MPa，較佳為至少210 MPa，最佳為至少245 MPa之衝擊後壓縮強度(CAI)。
一種附加態樣係關於先前解釋纖維結構作為用於環氧樹脂強化材料，特別指其於運動、休閒、機械工業、電子、建築、醫學工程、交通工具和運輸以及航太工程領域之用途。
先前解釋之纖維結構作為用於環氧樹脂強化材料，其於運動、休閒、機械工業、電子、建築、醫學工程、交通工具和運輸以及航太工程領域之用途尤佳。
將在不侷泥於此處所示特定具體實施例之下參考下列實例更詳細地描述根據本發明之申請標的。
根據本發明之共聚酯組成物(成分A1至A4)以及比較法之組成物(CoPES I、CoPES II、EVA、PA 6/12/66、PA 12、PE)示於表1。
亦可使用Melthene MX06代替MX09。
根據下列標準及以下列樣本進行測試和測定。
拉伸剝落試驗
DIN 54310
測定溫度23℃
樣本製造
將受試熱塑性塑膠之平面薄膜(每單位面積塗佈量為200 g/m2)藉由雙鋼帶壓縮裝置層合於聚酯羊毛織物(55/45%重量比，棕色，每單位面積塗佈量為210 g/m2，製造商德國Becker Tuche或義大利Marzotto)上。 熱塑性塑膠之層合溫度為高於熔點30℃。該層合板於50℃儲存24小時之後將其切割成24x8 cm樣本。將一塑膠框(15x5 cm)置於該樣本上，並且在其窄邊下放置一蠟紙條。將該框內充填至3 mm之新配製脫氣環氧化物混合物。將環氧化物於23℃固化12至16小時。然後卸除該塑膠框。使該蠟紙條與熱塑性塑膠膜分開並且環氧化物呈覆蓋約3 cm長度。
該環氧化物係以2：1重量比例混合自0.520至0.550當量/100 g環氧值(Grilonit G 1302,EMS-CHEMIE AG)以及290至350 KOH/g胺值(Grilonit H 84048,EMS-CHEMIE AG)之雙酚A環氧樹脂。
層間剪切強度(ILSS)
ASTM D2344M
測定溫度23℃和80℃
樣本製造
先藉由樹脂轉注成形(RTM)製造330x330x4 mm尺寸之平板。基於此目的，將具有每單位面積塗佈量為298 g/m2之單向碳纖維絲手動地置入具有利用一篩具均勻分散18 g熱塑粉於其上並且重複此過程15次之預熱至80℃熱壓機模孔(mold cavity)內，其第2層單向碳纖維絲相對第1層為旋轉-45°、第3層為+45°及第4層為90°。該16層構造之第5層因此與第1層具有相同方向。18 g熱塑粉除了第16層之外被分佈於每一層。於關閉模具之後，在真空(剩餘壓力為0.05 mbar)下將其加熱至120℃，然後當到達該溫度時倒入預熱至80℃之單組分環氧樹脂(來自美國Hexcel公司之HexFlow RTM6)。於180℃和6 bar壓力下固化90分鐘。隨後降低壓力以及同時進行冷卻。維持真空直至模具被開啟為止。利用日本Toho Tenax 公司之IMS 60 E13作為單向碳纖維絲。利用超音波檢測該平板品質之後，將樣本切割成24x8x4 mm之尺寸。檢測前60分鐘樣本可到達測量溫度。壓力係產生自人工氣候室。
製造用於比較試驗中碳纖維絲間無任何熱塑粉之樣本。
衝擊後壓縮強度(CAI)之測定
AITM 1.0010(空中巴士標準)
測定溫度23°
樣本之製造
如同層間剪切強度(ILSS)試驗中所述製造該平板。利用超音波檢測品質之後，將該樣本切割成150x100x4 mm之尺寸。
製造用於比較試驗中碳纖維絲間無任何熱塑粉之樣本。
於強度試驗之前，利用落塔(drop tower)施予30 J之衝擊。利用超音波測定此衝擊所產生之脫層面積。接著，以相同樣本測定於壓縮時之其餘強度。
熔融黏度(MV)或熔體流動指數(MFR)
ISO 1133
粒化
熔點
ISO標準11357
粒化
於20 K/分之加熱速率下進行示差掃描量熱法(DSC)。求出最大峰值之溫度。
利用根據本發明所稱材料以及比較材料進行針對材料性質之比較試驗。
在此態樣中，拉伸剝落試驗之結果示於表2。
根據本發明(實例1至實例4)共聚酯(A1)至(A4)所獲得之黏力值至少3.7倍較高於作為熱固性塑膠之非根據本發明共聚酯、乙烯醋酸乙烯酯、各種聚醯胺或低密度PE(比較實例5至10)。因此下列中僅針對根據本發明之共聚酯進行測試。
層間剪切強度(ILSS)之測定結果示於表3。
實例11至實例14顯示由於使用根據本發明之共聚酯，因此其複合材料於23℃和於80℃測量溫度時與無根據本發明共聚酯之複合材料(比較實例15)相比具有較高強度。
衝擊後壓縮(CAI)試驗之結果示於表4，亦即先前施予30 J衝擊之後測定該樣本時其脫層面積已顯著增加。
實例16至實例19與不使用根據本發明共聚酯之複合材料(比較實例20)相比顯示由於使用根據本發明共聚酯之複合材料而大為提昇其強度以及具有實質上較小脫層面積。

Claims (15)

  1. 一種來自纖維材料以及來自用於其緊固和安定之物質之緊固及/或安定纖維結構，其特徵在於該用於緊固和安定之物質係至少一種形成自下列組分之結構共聚酯：從55至100莫耳%之對苯二甲酸；從0至45莫耳%之間苯二甲酸；從35至75莫耳%之丁二醇；從15至35莫耳%之二乙二醇；從10至30莫耳%之參乙二醇，其中就分別為100莫耳%之總二酸和總二醇含量而言，對苯二甲酸和丁二醇之莫耳分率總和最大為150莫耳%。
  2. 根據申請專利範圍第1項所述之纖維結構，其特徵在於該至少一種結構共聚酯係形成自下列組分：從70至100莫耳%，較佳為85至100莫耳%之對苯二甲酸；從0至30莫耳%，較佳為0至15莫耳%之間苯二甲酸；從45至65莫耳%，較佳為47至57莫耳%之丁二醇；從20至30莫耳%，較佳為23至28莫耳%之二乙二醇；從15至25莫耳%，較佳為20至25莫耳%之參乙二醇，其中就分別為100莫耳%之總二酸和總二醇含量而言，對苯二甲酸和丁二醇之莫耳分率總和最大為150莫耳%。
  3. 根據上述申請專利範圍中任一項所述之纖維結構，其特徵在於該至少一種結構共聚酯可含有0至2%重量比，較佳為0.05至1%重量比特別指成核劑、安定劑、潤滑劑、消泡劑、縮合催化劑之添加物，該共聚酯和添加物之總和為100%重量比。
  4. 根據上述申請專利範圍中任一項所述之纖維結構，其特徵在於按ISO/DIN 1133標準、於160℃和2.16 kg負載之下測定時，該至少一種共聚酯具有範圍在100至3000 Pas，較佳為100至600 Pas，最佳為120至500 Pas以及極佳為150至300 Pas之熔融黏度。
  5. 根據申請專利範圍第1項至第3項中任一項所述之纖維結構，其特徵在於按ISO/DIN 1133標準、於160℃和2.16 kg負載之下測定時，該至少一種被用於定絲之共聚酯具有範圍在1000至3000 Pas，較佳為1500至2500 Pas，最佳為1700至2200 Pas之熔融黏度。
  6. 根據上述申請專利範圍中任一項所述之纖維結構，其特徵在於按ISO 11357標準、於20 K/分加熱速率之下測定時，該至少一種共聚酯具有範圍在60℃至160℃，較佳為70℃至150℃，以及最佳為90℃至140℃之熔點。
  7. 根據上述申請專利範圍中任一項所述之纖維結構，其特徵在於該纖維材料係來自織物、羊毛、針織網或針織、或不織布或其組合之同向長纖維或橫向纖維材料。
  8. 根據上述申請專利範圍中任一項所述之纖維結構，其特徵在於該纖維材料係選自下列群組包括：‧玻璃纖維，‧碳纖維，‧礦物纖維，‧合成纖維，特別指聚酯和聚醯胺，尤指聚芳醯胺之高分子纖維，‧天然纖維，特別指綿花、羊毛、木綿、大麻、亞麻、黃麻或木綿以及 ‧其混合物。
  9. 一種製造根據上述申請專利範圍中任一項所述纖維結構之方法，其中藉由粉點塗層法、漿點塗層法或分散塗層法或作為糊劑、懸浮液、薄膜、網狀物、非織造物、固定非織造物或梭織物或噴熔物施予該至少一種用於緊固和安定該纖維材料之物質，接著藉由溫度及/或壓力固定該纖維結構。
  10. 一種製造根據上述申請專利範圍第1項至第8項中任一項所述纖維結構之方法，其中藉由縫合製造自該至少一種結構共聚酯之定絲進行該纖維材料之緊固和安定。
  11. 一種纖維樹脂複合材料，其含有至少一種熱固性樹脂以及至少一種申請專利範圍第1項至第8項中任一項所述之纖維結構。
  12. 根據申請專利範圍第10項所述之纖維樹脂複合材料，其特徵在於該至少一種熱固性樹脂係環氧樹脂。
  13. 根據申請專利範圍第10項或第11項中所述之纖維樹脂複合材料，其特徵在於該纖維樹脂複合材料於溫度23℃下測定時具有至少55 MPa，較佳為至少60 MPa之層間剪切強度(ILSS)。
  14. 根據申請專利範圍第10項至第12項中所述之纖維樹脂複合材料，其特徵在於該纖維樹脂複合材料於衝擊後壓縮強度之測定中具有至少185 MPa，較佳為至少210 MPa，以及最佳為至少245 MPa之衝擊後壓縮強度(CAI)。
  15. 一種根據上述申請專利範圍中任一項所述纖維結構作為用於環氧樹脂強化材料，特別指其於運動、休閒、機械工業、電子、建築、醫學工程、交通工具和運輸以及航太工程領域之用途。
TW102103444A 2012-02-24 2013-01-30 纖維結構、其製造方法以及纖維樹脂複合材料之用途 TWI612189B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12156901.6A EP2631337B1 (de) 2012-02-24 2012-02-24 Faserharzverbundwerkstoff sowie Verfahren zu dessen Herstellung
??12156901.6 2012-02-24

Publications (2)

Publication Number Publication Date
TW201341607A true TW201341607A (zh) 2013-10-16
TWI612189B TWI612189B (zh) 2018-01-21

Family

ID=45656682

Family Applications (1)

Application Number Title Priority Date Filing Date
TW102103444A TWI612189B (zh) 2012-02-24 2013-01-30 纖維結構、其製造方法以及纖維樹脂複合材料之用途

Country Status (22)

Country Link
US (2) US9346943B2 (zh)
EP (1) EP2631337B1 (zh)
JP (1) JP6151037B2 (zh)
KR (1) KR102017502B1 (zh)
CN (1) CN103290687B (zh)
AR (1) AR090092A1 (zh)
AU (1) AU2013200689B2 (zh)
BR (1) BR102013003950B1 (zh)
CA (1) CA2805922C (zh)
CL (1) CL2013000505A1 (zh)
DK (1) DK2631337T3 (zh)
ES (1) ES2551587T3 (zh)
HU (1) HUE026449T2 (zh)
MX (1) MX345583B (zh)
MY (1) MY172629A (zh)
NZ (1) NZ606809A (zh)
PL (1) PL2631337T3 (zh)
PT (1) PT2631337E (zh)
RU (1) RU2622117C2 (zh)
SG (1) SG193080A1 (zh)
SI (1) SI2631337T1 (zh)
TW (1) TWI612189B (zh)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6105332B2 (ja) * 2012-03-09 2017-03-29 帝人株式会社 強化繊維及びそれからなる強化繊維束
EP3044356B1 (en) 2013-09-11 2021-04-14 Raytheon Technologies Corporation Rigidized fiber array
CN104476852A (zh) * 2014-12-04 2015-04-01 常熟市东宇绝缘复合材料有限公司 吸温性小的玻纤喷射纱
CN104451948B (zh) * 2014-12-19 2016-12-07 常熟涤纶有限公司 一种高强涤纶纤维及其生产工艺
US10556388B2 (en) * 2015-04-22 2020-02-11 Eastman Chemical Company Polyester-based tape composites for wood reinforcement
CN104893069A (zh) * 2015-06-09 2015-09-09 苏州德翔装饰工程有限公司 一种家具用聚乙烯木塑复合材料及其制备方法
US20190224929A1 (en) * 2016-06-23 2019-07-25 Fpinnovations Wood pulp fiber- or cellulose filament-reinforced bulk molding compounds, composites, compositions and methods for preparation thereof
PL3260436T3 (pl) * 2016-06-23 2020-06-01 Evonik Operations Gmbh Zbrojony bloczek budowlany wykonany z autoklawizowanego betonu napowietrzonego (ABN)
WO2018046984A1 (en) * 2016-09-09 2018-03-15 Prysmian S.P.A. Optical fibre coated with a polyester coating
CN108819378A (zh) * 2018-06-28 2018-11-16 西安工程大学 一种利用牛仔布制备牛仔纤维增强复合材料的方法
EP3841238A1 (en) 2018-08-21 2021-06-30 Owens Corning Intellectual Capital, LLC Multiaxial reinforcing fabric with a stitching yarn for improved fabric infusion
US11913148B2 (en) 2018-08-21 2024-02-27 Owens Corning Intellectual Capital, Llc Hybrid reinforcement fabric
US11413795B1 (en) 2021-08-12 2022-08-16 King Abdulaziz University Method of making composite from green material
CN114507937B (zh) * 2021-12-08 2023-05-16 吉祥三宝高科纺织有限公司 一种阻燃的仿鹅绒保暖材料
CN114736495B (zh) * 2022-06-13 2022-10-28 南通开普乐工程塑料有限公司 一种碳纤维增强pbt材料及其制备方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2801189A (en) * 1952-10-08 1957-07-30 Owens Corning Fiberglass Corp Glass fiber article and process of plural coated fiber and process of preparation
US4857405A (en) * 1984-07-18 1989-08-15 Allied-Signal Inc. Fiber for reinforcing plastic composites and reinforced plastic composites therefrom
JPH06200480A (ja) * 1992-12-28 1994-07-19 Unitika Ltd ガラス織物のほつれ防止固着剤
JPH06200468A (ja) 1992-12-29 1994-07-19 Unitika Ltd 補強物品の製造方法
DE4430048C2 (de) * 1994-08-24 1997-10-09 Inventa Ag Copolyesterschmelzklebemassen und deren Verwendung
EP0698649A1 (de) 1994-08-26 1996-02-28 Basf Aktiengesellschaft Verwendung von thermoplastisch verarbeitbaren, langzeitstabilen elektrolumineszenten Materialien
DE19632474C2 (de) 1996-08-12 2000-06-29 Inventa Ag Copolyetheresterschmelzklebemassen
US6020063A (en) * 1997-07-31 2000-02-01 Virginia Tech Intellectual Properties, Inc. Composites of thermosetting resins and carbon fibers having polyhydroxyether sizings
PL191120B1 (pl) * 1997-12-02 2006-03-31 Henkel Kgaa Klej poliestrowy ulegający biodegradacji
US6428900B1 (en) 2000-03-09 2002-08-06 Ato Findley, Inc. Sulfonated copolyester based water-dispersible hot melt adhesive
DE10109622B4 (de) * 2001-02-28 2004-03-25 Ems-Chemie Ag Verfahren zur Verklebung einer Copolyetheresterfolie mit Copolyester
US20030207639A1 (en) * 2002-05-02 2003-11-06 Tingdong Lin Nonwoven web with improved adhesion and reduced dust formation
WO2004078443A1 (en) * 2003-03-06 2004-09-16 Vestas Wind Systems A/S Pre-form and method of preparing a pre-form
JP2005060879A (ja) * 2003-08-12 2005-03-10 Toyobo Co Ltd 連続繊維用油剤及びそれを用いた連続繊維束及び複合材料
FR2864073B1 (fr) * 2003-12-17 2006-03-31 Saint Gobain Vetrotex Fils de verre ensimes a impregnation rapide pour le renforcement de matieres polymeres
EP1705269B1 (de) 2005-03-22 2008-01-16 Ems-Chemie Ag Aus einem Polyhydroxyether enthaltenden Rohstoff gesponnenes thermoplastisches Fasermaterial, Verfahren zu seiner Herstellung und Verwendungen dafür
DE102006048739A1 (de) 2006-10-12 2008-04-17 Henkel Kgaa Expandierbare, thermisch härtbare Zusammensetzung auf Basis von Epoxidharzen mit verbesserten Fließeigenschaften
US8288447B2 (en) * 2006-06-07 2012-10-16 Henkel Ag & Co. Kgaa Foamable compositions based on epoxy resins and polyesters
US7687594B2 (en) * 2007-11-27 2010-03-30 Industrial Technology Research Institute Random amorphous copolymer and manufacturing method thereof

Also Published As

Publication number Publication date
TWI612189B (zh) 2018-01-21
KR102017502B1 (ko) 2019-10-14
CL2013000505A1 (es) 2013-07-26
AU2013200689B2 (en) 2016-03-03
US20160168783A1 (en) 2016-06-16
EP2631337A1 (de) 2013-08-28
ES2551587T3 (es) 2015-11-20
BR102013003950A2 (pt) 2015-10-06
EP2631337B1 (de) 2015-09-23
KR20130097658A (ko) 2013-09-03
SG193080A1 (en) 2013-09-30
AR090092A1 (es) 2014-10-15
HUE026449T2 (en) 2016-05-30
BR102013003950B1 (pt) 2020-09-15
PL2631337T3 (pl) 2015-12-31
PT2631337E (pt) 2015-11-17
CN103290687B (zh) 2018-06-12
JP6151037B2 (ja) 2017-06-21
CA2805922C (en) 2018-10-23
CA2805922A1 (en) 2013-08-24
AU2013200689A1 (en) 2013-09-12
MY172629A (en) 2019-12-06
US20130225721A1 (en) 2013-08-29
MX2013002018A (es) 2013-09-03
DK2631337T3 (en) 2015-11-02
NZ606809A (en) 2014-06-27
JP2013174037A (ja) 2013-09-05
RU2622117C2 (ru) 2017-06-13
US9346943B2 (en) 2016-05-24
CN103290687A (zh) 2013-09-11
RU2013106917A (ru) 2014-08-20
MX345583B (es) 2017-02-07
SI2631337T1 (sl) 2015-12-31

Similar Documents

Publication Publication Date Title
TWI612189B (zh) 纖維結構、其製造方法以及纖維樹脂複合材料之用途
JP6140862B2 (ja) 複合ポリアミド物品
TWI475055B (zh) 經粒子韌化纖維強化之聚合物複合物
TWI480325B (zh) 經粒子韌化之聚合物組合物
JP5571671B2 (ja) 複合ポリアミド物品
JP6734440B2 (ja) 繊維−マトリックス半完成製品
US20140087178A1 (en) Prepreg, fiber reinforced composite material, and manufacturing method for fiber reinforced composite material
JP5090701B2 (ja) 部分含浸プリプレグとそれを用いた繊維強化複合材料の製造方法
JP6330327B2 (ja) Ｒｔｍ成形法用プリフォーム用のバインダー樹脂組成物を用いたｒｔｍ成形法用強化繊維基材、ｒｔｍ成形法用プリフォームおよび繊維強化複合材料
EP2607411A1 (en) Improvements in or relating to fibre reinforced materials
CN104870512A (zh) 快速固化环氧树脂体系
CN107073875A (zh) 包含半芳族聚酰胺的复合材料的声发射减少
RU2704185C2 (ru) Термопластичная композиция с высокой текучестью
TWI815628B (zh) 碳纖維束、預浸體、纖維強化複合材料
JP6957914B2 (ja) プリプレグ及び炭素繊維強化複合材料
JPH04227639A (ja) 高性能アラミドマトリツクス複合材料

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees